DE2616541A1 - Blockmischpolyesteramide als mahlgut - Google Patents
Blockmischpolyesteramide als mahlgutInfo
- Publication number
- DE2616541A1 DE2616541A1 DE19762616541 DE2616541A DE2616541A1 DE 2616541 A1 DE2616541 A1 DE 2616541A1 DE 19762616541 DE19762616541 DE 19762616541 DE 2616541 A DE2616541 A DE 2616541A DE 2616541 A1 DE2616541 A1 DE 2616541A1
- Authority
- DE
- Germany
- Prior art keywords
- polyamide
- molecular weight
- linear aliphatic
- polyester
- chain links
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920006149 polyester-amide block copolymer Polymers 0.000 title description 9
- 239000004952 Polyamide Substances 0.000 claims description 28
- 229920002647 polyamide Polymers 0.000 claims description 28
- 229920000728 polyester Polymers 0.000 claims description 13
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000006068 polycondensation reaction Methods 0.000 claims description 8
- 229920003232 aliphatic polyester Polymers 0.000 claims description 5
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 4
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 150000002148 esters Chemical group 0.000 claims 2
- 238000003801 milling Methods 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 27
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000002844 melting Methods 0.000 description 10
- 230000008018 melting Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000012299 nitrogen atmosphere Substances 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- YWJUZWOHLHBWQY-UHFFFAOYSA-N decanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCC(O)=O YWJUZWOHLHBWQY-UHFFFAOYSA-N 0.000 description 1
- -1 diamine salts Chemical class 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940100630 metacresol Drugs 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/44—Polyester-amides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7511606A FR2307834A1 (fr) | 1975-04-15 | 1975-04-15 | Copolyesteramides sequences comme produits a mouler |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2616541A1 true DE2616541A1 (de) | 1976-10-28 |
Family
ID=9153919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762616541 Withdrawn DE2616541A1 (de) | 1975-04-15 | 1976-04-14 | Blockmischpolyesteramide als mahlgut |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS51127198A (cs) |
| BE (1) | BE840709A (cs) |
| BR (1) | BR7602299A (cs) |
| CA (1) | CA1092284A (cs) |
| CH (1) | CH609992A5 (cs) |
| CS (1) | CS189761B2 (cs) |
| DD (1) | DD125621A5 (cs) |
| DE (1) | DE2616541A1 (cs) |
| FR (1) | FR2307834A1 (cs) |
| GB (1) | GB1532062A (cs) |
| IT (1) | IT1059115B (cs) |
| NL (1) | NL7603994A (cs) |
| PL (1) | PL101867B1 (cs) |
| SU (1) | SU591153A3 (cs) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2837687A1 (de) * | 1977-09-02 | 1979-03-15 | Ato Chimie | Verfahren zur herstellung von zur fertigung von erzeugnissen durch giessen, extrudieren oder verspinnen verwendbaren polyaether-ester-amid-ketten |
| DE2932234A1 (de) * | 1979-08-09 | 1981-02-19 | Huels Chemische Werke Ag | Verfahren zur herstellung von polyether(ester)amiden |
| EP0270809A3 (en) * | 1986-12-08 | 1988-10-26 | General Electric Company | Functionalized thermoplastic polymers, blends prepared therefrom, and methods for preparing blends |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2318185A1 (fr) * | 1975-07-17 | 1977-02-11 | Ato Chimie | Procede de preparation de copolyesteramides comme produits a mouler |
| JPS54119595A (en) * | 1978-03-09 | 1979-09-17 | Agency Of Ind Science & Technol | Biodegradable copolymer and its preparation |
| CH658062A5 (de) * | 1983-08-04 | 1986-10-15 | Inventa Ag | Verfahren zur herstellung von blockpolyetheresteramiden. |
| US5852155A (en) * | 1995-03-01 | 1998-12-22 | General Electric Company | Compositions of polyesteramides |
| CN108102090A (zh) * | 2016-11-24 | 2018-06-01 | 上海杰事杰新材料(集团)股份有限公司 | 超韧热稳定聚酰胺树脂及其制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3849514A (en) * | 1967-11-17 | 1974-11-19 | Eastman Kodak Co | Block polyester-polyamide copolymers |
-
1975
- 1975-04-15 FR FR7511606A patent/FR2307834A1/fr active Granted
-
1976
- 1976-04-12 DD DD19232176A patent/DD125621A5/xx unknown
- 1976-04-12 GB GB1482376A patent/GB1532062A/en not_active Expired
- 1976-04-13 CA CA250,156A patent/CA1092284A/fr not_active Expired
- 1976-04-14 NL NL7603994A patent/NL7603994A/xx not_active Application Discontinuation
- 1976-04-14 SU SU762343707A patent/SU591153A3/ru active
- 1976-04-14 BE BE166126A patent/BE840709A/xx not_active IP Right Cessation
- 1976-04-14 CH CH476176A patent/CH609992A5/xx not_active IP Right Cessation
- 1976-04-14 DE DE19762616541 patent/DE2616541A1/de not_active Withdrawn
- 1976-04-14 BR BR7602299A patent/BR7602299A/pt unknown
- 1976-04-14 PL PL18876976A patent/PL101867B1/pl unknown
- 1976-04-15 IT IT2233476A patent/IT1059115B/it active
- 1976-04-15 CS CS251276A patent/CS189761B2/cs unknown
- 1976-04-15 JP JP4190376A patent/JPS51127198A/ja active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2837687A1 (de) * | 1977-09-02 | 1979-03-15 | Ato Chimie | Verfahren zur herstellung von zur fertigung von erzeugnissen durch giessen, extrudieren oder verspinnen verwendbaren polyaether-ester-amid-ketten |
| DE2932234A1 (de) * | 1979-08-09 | 1981-02-19 | Huels Chemische Werke Ag | Verfahren zur herstellung von polyether(ester)amiden |
| EP0270809A3 (en) * | 1986-12-08 | 1988-10-26 | General Electric Company | Functionalized thermoplastic polymers, blends prepared therefrom, and methods for preparing blends |
Also Published As
| Publication number | Publication date |
|---|---|
| CS189761B2 (en) | 1979-04-30 |
| CH609992A5 (en) | 1979-03-30 |
| JPS5546412B2 (cs) | 1980-11-22 |
| BR7602299A (pt) | 1976-10-12 |
| FR2307834B1 (cs) | 1977-11-25 |
| SU591153A3 (ru) | 1978-01-30 |
| PL101867B1 (pl) | 1979-02-28 |
| GB1532062A (en) | 1978-11-15 |
| IT1059115B (it) | 1982-05-31 |
| BE840709A (fr) | 1976-08-02 |
| NL7603994A (nl) | 1976-10-19 |
| JPS51127198A (en) | 1976-11-05 |
| FR2307834A1 (fr) | 1976-11-12 |
| DD125621A5 (cs) | 1977-05-04 |
| CA1092284A (fr) | 1980-12-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8128 | New person/name/address of the agent |
Representative=s name: VON FUENER, A., DIPL.-CHEM. DR.RER.NAT. EBBINGHAUS |
|
| 8130 | Withdrawal |