DE2605041C3 - Verfahren zur Epoxydation von Olefinen - Google Patents

Verfahren zur Epoxydation von Olefinen

Info

Publication number
DE2605041C3
DE2605041C3 DE19762605041 DE2605041A DE2605041C3 DE 2605041 C3 DE2605041 C3 DE 2605041C3 DE 19762605041 DE19762605041 DE 19762605041 DE 2605041 A DE2605041 A DE 2605041A DE 2605041 C3 DE2605041 C3 DE 2605041C3
Authority
DE
Germany
Prior art keywords
hydrogen peroxide
mmol
acid
selectivity
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE19762605041
Other languages
German (de)
English (en)
Other versions
DE2605041B2 (de
DE2605041A1 (de
Inventor
Jean-Pierre Oullins Schirmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PCUK-PRODUITS CHIMIQUES UGINE KUHLMANN 92400 COURBEVOIE HAUTS-DE-SEINE FR
Original Assignee
PCUK-PRODUITS CHIMIQUES UGINE KUHLMANN 92400 COURBEVOIE HAUTS-DE-SEINE FR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PCUK-PRODUITS CHIMIQUES UGINE KUHLMANN 92400 COURBEVOIE HAUTS-DE-SEINE FR filed Critical PCUK-PRODUITS CHIMIQUES UGINE KUHLMANN 92400 COURBEVOIE HAUTS-DE-SEINE FR
Publication of DE2605041A1 publication Critical patent/DE2605041A1/de
Publication of DE2605041B2 publication Critical patent/DE2605041B2/de
Application granted granted Critical
Publication of DE2605041C3 publication Critical patent/DE2605041C3/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
DE19762605041 1975-02-11 1976-02-10 Verfahren zur Epoxydation von Olefinen Expired DE2605041C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7504149A FR2300765A1 (fr) 1975-02-11 1975-02-11 Procede d'epoxydation

Publications (3)

Publication Number Publication Date
DE2605041A1 DE2605041A1 (de) 1976-08-26
DE2605041B2 DE2605041B2 (de) 1981-05-27
DE2605041C3 true DE2605041C3 (de) 1982-04-22

Family

ID=9151023

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19762605041 Expired DE2605041C3 (de) 1975-02-11 1976-02-10 Verfahren zur Epoxydation von Olefinen

Country Status (7)

Country Link
JP (1) JPS51125303A (enrdf_load_stackoverflow)
BE (1) BE848521Q (enrdf_load_stackoverflow)
CH (1) CH610318A5 (enrdf_load_stackoverflow)
DE (1) DE2605041C3 (enrdf_load_stackoverflow)
FR (1) FR2300765A1 (enrdf_load_stackoverflow)
GB (1) GB1491635A (enrdf_load_stackoverflow)
NL (1) NL7601323A (enrdf_load_stackoverflow)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4242285A (en) 1979-03-16 1980-12-30 The Dow Chemical Company Novel 2,6-dinitrophenyl selenium compounds and their use as epoxidation catalysts
NL8004084A (nl) * 1979-07-19 1981-01-21 Donegani Guido Ist Werkwijze voor de katalytische epoxydatie van alkenen met waterstofperoxyde.
US5274140A (en) * 1979-07-19 1993-12-28 Instituto Guido Donegani, S.P.A. Process for catalytically epoxidizing olefin with hydrogen peroxide
JPS5839676A (ja) * 1981-09-04 1983-03-08 Mitsubishi Gas Chem Co Inc オレフインオキシドの製造法
EP0074259B1 (en) * 1981-09-04 1985-07-17 Mitsubishi Gas Chemical Company, Inc. Catalytic epoxidation of olefins
IT1186782B (it) * 1985-10-18 1987-12-16 Montedison Spa Processo per la preparazione di fenilpropanoni
CN104211665B (zh) * 2013-05-31 2016-10-05 中国石油化工股份有限公司 一种烯烃氧化的方法
CN104803953B (zh) * 2014-01-28 2017-09-29 中国石油化工股份有限公司 一种烯烃环氧化的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2786854A (en) * 1957-03-26 Process of making oxirane compounds
US2833787A (en) * 1955-03-15 1958-05-06 Shell Dev Epoxidation process using hydrogen peroxide and an acid salt of a heavy metal peracid
US2833788A (en) * 1955-12-28 1958-05-06 Shell Dev Production of epoxides
FR2127063A6 (en) * 1971-02-22 1972-10-13 Continental Oil Co Catalysed oxidation of olefins in a hetero-generous system
GB1324763A (en) * 1971-03-19 1973-07-25 Continental Oil Co Phase transfer catalysis of heterogeneous reactions by quaternary salts

Also Published As

Publication number Publication date
DE2605041B2 (de) 1981-05-27
GB1491635A (en) 1977-11-09
FR2300765A1 (fr) 1976-09-10
BE848521Q (fr) 1977-05-20
FR2300765B1 (enrdf_load_stackoverflow) 1979-02-23
CH610318A5 (en) 1979-04-12
JPS5519216B2 (enrdf_load_stackoverflow) 1980-05-24
DE2605041A1 (de) 1976-08-26
NL7601323A (nl) 1976-08-13
JPS51125303A (en) 1976-11-01

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
8339 Ceased/non-payment of the annual fee