DE2363697C3 - Verfahren zum Herstellen von Homopolymerisaten des Äthylens oder Copolymerisaten des Äthylens mit a -Monoolefinen BASF AG, 6700 Ludwigshafen - Google Patents
Verfahren zum Herstellen von Homopolymerisaten des Äthylens oder Copolymerisaten des Äthylens mit a -Monoolefinen BASF AG, 6700 LudwigshafenInfo
- Publication number
- DE2363697C3 DE2363697C3 DE2363697A DE2363697A DE2363697C3 DE 2363697 C3 DE2363697 C3 DE 2363697C3 DE 2363697 A DE2363697 A DE 2363697A DE 2363697 A DE2363697 A DE 2363697A DE 2363697 C3 DE2363697 C3 DE 2363697C3
- Authority
- DE
- Germany
- Prior art keywords
- weight
- titanium
- parts
- reaction product
- catalyst component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 40
- 238000004519 manufacturing process Methods 0.000 title claims description 38
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 18
- 239000005977 Ethylene Substances 0.000 title claims description 18
- 229920000573 polyethylene Polymers 0.000 title claims description 12
- 229920001577 copolymer Polymers 0.000 title claims description 5
- 229920001519 homopolymer Polymers 0.000 title claims description 4
- 150000005673 monoalkenes Chemical class 0.000 title description 2
- 239000003795 chemical substances by application Substances 0.000 title 1
- 239000010936 titanium Substances 0.000 claims description 117
- 229910052719 titanium Inorganic materials 0.000 claims description 112
- 239000003054 catalyst Substances 0.000 claims description 109
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 104
- 239000007795 chemical reaction product Substances 0.000 claims description 90
- -1 aluminum compound Chemical class 0.000 claims description 44
- 238000006116 polymerization reaction Methods 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 26
- 229910052782 aluminium Inorganic materials 0.000 claims description 20
- 238000003746 solid phase reaction Methods 0.000 claims description 15
- 150000002681 magnesium compounds Chemical class 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000000460 chlorine Substances 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 229910052740 iodine Inorganic materials 0.000 claims description 2
- 239000011630 iodine Substances 0.000 claims description 2
- 150000002736 metal compounds Chemical class 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 100
- 239000000725 suspension Substances 0.000 description 50
- 238000003756 stirring Methods 0.000 description 22
- 239000000047 product Substances 0.000 description 21
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 15
- 229910052749 magnesium Inorganic materials 0.000 description 15
- 239000011777 magnesium Substances 0.000 description 15
- 159000000003 magnesium salts Chemical class 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- 239000007790 solid phase Substances 0.000 description 11
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 10
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 238000010992 reflux Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- QUVMSYUGOKEMPX-UHFFFAOYSA-N 2-methylpropan-1-olate;titanium(4+) Chemical compound [Ti+4].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] QUVMSYUGOKEMPX-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000012084 conversion product Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical compound CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- JEVCWSUVFOYBFI-UHFFFAOYSA-N cyanyl Chemical compound N#[C] JEVCWSUVFOYBFI-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical class O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000013519 translation Methods 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 244000236655 Diospyros kaki Species 0.000 description 1
- 235000008597 Diospyros kaki Nutrition 0.000 description 1
- 101100180320 Mus musculus Itln1 gene Proteins 0.000 description 1
- 101100180325 Oncorhynchus mykiss itln gene Proteins 0.000 description 1
- 241000212342 Sium Species 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000003542 behavioural effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000027939 micturition Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- SUSQOBVLVYHIEX-UHFFFAOYSA-N phenylacetonitrile Chemical compound N#CCC1=CC=CC=C1 SUSQOBVLVYHIEX-UHFFFAOYSA-N 0.000 description 1
- 125000003884 phenylalkyl group Chemical group 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 208000011117 substance-related disease Diseases 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2363697A DE2363697C3 (de) | 1973-12-21 | 1973-12-21 | Verfahren zum Herstellen von Homopolymerisaten des Äthylens oder Copolymerisaten des Äthylens mit a -Monoolefinen BASF AG, 6700 Ludwigshafen |
| IT29358/74A IT1025555B (it) | 1973-12-21 | 1974-11-12 | Processo per la preparazione di folimeri olefinici |
| AU76355/74A AU498151B2 (en) | 1973-12-21 | 1974-12-12 | Catalyst component for olefin polymerisation |
| BE151524A BE823378A (fr) | 1973-12-21 | 1974-12-16 | Procede de preparation de polymeres d'olefines et catalyseurs utilises |
| NO744558A NO744558L (enrdf_load_stackoverflow) | 1973-12-21 | 1974-12-17 | |
| SE7416070A SE7416070L (enrdf_load_stackoverflow) | 1973-12-21 | 1974-12-19 | |
| FR7442037A FR2255318B1 (enrdf_load_stackoverflow) | 1973-12-21 | 1974-12-19 | |
| GB5485374A GB1456410A (en) | 1973-12-21 | 1974-12-19 | Catalyst component for olefin polymerization |
| AT1022274A AT333501B (de) | 1973-12-21 | 1974-12-20 | Verfahren zur herstellung von olefinpolymerisaten |
| JP49145800A JPS5096686A (enrdf_load_stackoverflow) | 1973-12-21 | 1974-12-20 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2363697A DE2363697C3 (de) | 1973-12-21 | 1973-12-21 | Verfahren zum Herstellen von Homopolymerisaten des Äthylens oder Copolymerisaten des Äthylens mit a -Monoolefinen BASF AG, 6700 Ludwigshafen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2363697A1 DE2363697A1 (de) | 1975-07-03 |
| DE2363697B2 DE2363697B2 (de) | 1980-04-30 |
| DE2363697C3 true DE2363697C3 (de) | 1981-01-15 |
Family
ID=5901474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2363697A Expired DE2363697C3 (de) | 1973-12-21 | 1973-12-21 | Verfahren zum Herstellen von Homopolymerisaten des Äthylens oder Copolymerisaten des Äthylens mit a -Monoolefinen BASF AG, 6700 Ludwigshafen |
Country Status (10)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5274686A (en) * | 1975-12-18 | 1977-06-22 | Sumitomo Chem Co Ltd | Process for polymerizing olefins |
-
1973
- 1973-12-21 DE DE2363697A patent/DE2363697C3/de not_active Expired
-
1974
- 1974-11-12 IT IT29358/74A patent/IT1025555B/it active
- 1974-12-12 AU AU76355/74A patent/AU498151B2/en not_active Expired
- 1974-12-16 BE BE151524A patent/BE823378A/xx unknown
- 1974-12-17 NO NO744558A patent/NO744558L/no unknown
- 1974-12-19 GB GB5485374A patent/GB1456410A/en not_active Expired
- 1974-12-19 SE SE7416070A patent/SE7416070L/xx unknown
- 1974-12-19 FR FR7442037A patent/FR2255318B1/fr not_active Expired
- 1974-12-20 AT AT1022274A patent/AT333501B/de not_active IP Right Cessation
- 1974-12-20 JP JP49145800A patent/JPS5096686A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| IT1025555B (it) | 1978-08-30 |
| DE2363697A1 (de) | 1975-07-03 |
| SE7416070L (enrdf_load_stackoverflow) | 1975-06-23 |
| JPS5096686A (enrdf_load_stackoverflow) | 1975-07-31 |
| ATA1022274A (de) | 1976-03-15 |
| GB1456410A (en) | 1976-11-24 |
| FR2255318B1 (enrdf_load_stackoverflow) | 1978-03-24 |
| AU498151B2 (en) | 1979-02-15 |
| BE823378A (fr) | 1975-06-16 |
| DE2363697B2 (de) | 1980-04-30 |
| AU7635574A (en) | 1976-06-17 |
| AT333501B (de) | 1976-11-25 |
| NO744558L (enrdf_load_stackoverflow) | 1975-07-21 |
| FR2255318A1 (enrdf_load_stackoverflow) | 1975-07-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |