DE2157733A1 - Method of making a joint between parts made of a porous synthetic resin - Google Patents

Method of making a joint between parts made of a porous synthetic resin

Info

Publication number
DE2157733A1
DE2157733A1 DE19712157733 DE2157733A DE2157733A1 DE 2157733 A1 DE2157733 A1 DE 2157733A1 DE 19712157733 DE19712157733 DE 19712157733 DE 2157733 A DE2157733 A DE 2157733A DE 2157733 A1 DE2157733 A1 DE 2157733A1
Authority
DE
Germany
Prior art keywords
synthetic resin
weldable
porous
layers
brought
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19712157733
Other languages
German (de)
Inventor
Gordon John Sheldon Birminghamshire; Bennet Derek Roger CoIdfield Warwickshire; Shotton (Großbritannien). B29c 27-02
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZF International UK Ltd
Original Assignee
Lucas Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucas Industries Ltd filed Critical Lucas Industries Ltd
Publication of DE2157733A1 publication Critical patent/DE2157733A1/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/91Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/914Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux
    • B29C66/9141Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the temperature
    • B29C66/91411Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the temperature of the parts to be joined, e.g. the joining process taking the temperature of the parts to be joined into account
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0078Measures or configurations for obtaining anchoring effects in the contact areas between layers
    • B29C37/0082Mechanical anchoring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/08Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using ultrasonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/50Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
    • B29C65/5057Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like positioned between the surfaces to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/302Particular design of joint configurations the area to be joined comprising melt initiators
    • B29C66/3022Particular design of joint configurations the area to be joined comprising melt initiators said melt initiators being integral with at least one of the parts to be joined
    • B29C66/30223Particular design of joint configurations the area to be joined comprising melt initiators said melt initiators being integral with at least one of the parts to be joined said melt initiators being rib-like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/303Particular design of joint configurations the joint involving an anchoring effect
    • B29C66/3034Particular design of joint configurations the joint involving an anchoring effect making use of additional elements, e.g. meshes
    • B29C66/30341Particular design of joint configurations the joint involving an anchoring effect making use of additional elements, e.g. meshes non-integral with the parts to be joined, e.g. making use of extra elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/43Joining a relatively small portion of the surface of said articles
    • B29C66/433Casing-in, i.e. enclosing an element between two sheets by an outlined seam
    • B29C66/4332Casing-in, i.e. enclosing an element between two sheets by an outlined seam by folding a sheet over
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53Joining single elements to tubular articles, hollow articles or bars
    • B29C66/534Joining single elements to open ends of tubular or hollow articles or to the ends of bars
    • B29C66/5346Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/61Joining from or joining on the inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/727General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being porous, e.g. foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7311Thermal properties
    • B29C66/73115Melting point
    • B29C66/73116Melting point of different melting point, i.e. the melting point of one of the parts to be joined being different from the melting point of the other part
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/91Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/919Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
    • B29C66/9192Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams
    • B29C66/91921Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature
    • B29C66/91931Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to the fusion temperature or melting point of the material of one of the parts to be joined
    • B29C66/91935Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges in explicit relation to another variable, e.g. temperature diagrams in explicit relation to another temperature, e.g. to the softening temperature or softening point, to the thermal degradation temperature or to the ambient temperature in explicit relation to the fusion temperature or melting point of the material of one of the parts to be joined lower than said fusion temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4815Hot melt adhesives, e.g. thermoplastic adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/303Particular design of joint configurations the joint involving an anchoring effect
    • B29C66/3032Particular design of joint configurations the joint involving an anchoring effect making use of protrusions or cavities belonging to at least one of the parts to be joined
    • B29C66/30325Particular design of joint configurations the joint involving an anchoring effect making use of protrusions or cavities belonging to at least one of the parts to be joined making use of cavities belonging to at least one of the parts to be joined
    • B29C66/30326Particular design of joint configurations the joint involving an anchoring effect making use of protrusions or cavities belonging to at least one of the parts to be joined making use of cavities belonging to at least one of the parts to be joined in the form of porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/12Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
    • B29K2027/18PTFE, i.e. polytetrafluorethene, e.g. ePTFE, i.e. expanded polytetrafluorethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0065Permeability to gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0068Permeability to liquids; Adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0093Other properties hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/34Electrical apparatus, e.g. sparking plugs or parts thereof
    • B29L2031/3468Batteries, accumulators or fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/547Terminals characterised by the disposition of the terminals on the cells
    • H01M50/55Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/552Terminals characterised by their shape
    • H01M50/553Terminals adapted for prismatic, pouch or rectangular cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Plasma & Fusion (AREA)
  • Cell Separators (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Description

PATENTANWÄLTE ZlDf /OO PATENTANWÄLTE ZlDf / OO

DipWng. WERNER COHAUSZ · Dipl.-lng. WILHELM FLORACK · DipUng. RUDOLF KNAUF DipWng. WERNER COHAUSZ Dipl.-Ing. WILHELM FLORACK DipUng. RUDOLF KNAUF

4 Düsseldorf, Schumannsfraße 974 Düsseldorf, Schumannsfraße 97

Jospph Lucas (Industries) LimitedJospph Lucas (Industries) Limited

Great King StreetGreat King Street

GB-Birmingham 17. November 1971GB Birmingham 17th November 1971

Verfahren zur Herstellung einer Verbindung zwischen Teilen, von denen eines aus einem porösen Kunstaharz bestehtMethod of making a connection between parts, of one of which is made of a porous synthetic resin

Die Erfindung betrifft ein Verfahren zur Herstellung einer Verbindung zwischen Teilen, von denen eines aus einem porösen Kunstharz besteht.The invention relates to a method for producing a connection between parts, one of which is made of a porous synthetic resin.

Ein Verfahren gemäß der Erfindung ist dadurch gekennzeichnet, daß das eine Teil, das aus dem porösen Kunstharz besteht, in Anlage an einem zweiten Teil gebracht wird, das aus einem Material mit einem niedrigeren Schmelzpunkt afis das Kunstharz besteht,und daß mindestens eine Partie des zweiten Teils zum Schmelzen ohne ein Schmelzen des einen Teils gebracht wird, derart, daß die geschmolzene Partie in die Poren des einen Teils fließt und bei Abkühlung eine Verbindung zwischen dem einen Teil und dem anderen Teil entsteht. A method according to the invention is characterized in that the one part consisting of the porous synthetic resin is in contact is brought to a second part, which consists of a material with a lower melting point than the synthetic resin, and that at least a portion of the second part is brought to melt without melting the one part, such that the melted Part flows into the pores of one part and when it cools down, a connection is created between one part and the other.

Zum anderen besteht die Erfindung in einem Verfahren zur Herstellung einer Verbindung zwischen Teilen, von denen eines aus einem porösen, nicht-schweißfähigen, hydrophoben Kunstharz besteht, das dadurch gekennzeichnet ist, daß das eine Teil, das aus dem porösen, nicht-schweißfähigen hydrophoben Material besteht, in Anlage an einem zweiten Teil gebracht wird, das aus einem schweißfähigen Material besteht, und daß mindestens eine Partie des zweiten schweißfähigen Teils zum Schmelzen gebracht wird, derart, daß die geschmol zene Partie in die Poren des einen Teils fließt und bei Abkühlung eine Verbindung zwischen dem einen Teil und dem anderen Teil ent-On the other hand, the invention consists in a method for production a bond between parts, one of which is made of a porous, non-weldable, hydrophobic synthetic resin that characterized in that the one part, which consists of the porous, non-weldable hydrophobic material, is in contact with it a second part is brought, which is made of a weldable material exists, and that at least a portion of the second weldable part is brought to melt, such that the molten part flows into the pores of one part and when it cools down a connection between one part and the other

25 559 209823/0765 25 559 209823/0765

T,7a/Ti - 2 - T , 7a / Ti - 2 -

steht.stands.

Vorzugsweise wird ein weiteres poröses, nicht-schweißfähiges, hydrophobes Kunstharzteil in Anlage an das zweite schweißfähige Teil gebracht, derart, daß dann, wenn eine Partie des zweiten schweißfähigen Teils zum Schmelzen gebracht wird, die geschmolzene Partie in die Poren des einen Teils und des weiteren Teils fließt und "bei Abkühlung eine Verbindung zwischen dem einen Teil und dem weiteren Teil entsteht.Another porous, non-weldable, hydrophobic one is preferred Resin part brought into contact with the second weldable part, such that when a portion of the second weldable Part is brought to melt, the melted part flows into the pores of one part and the other part and "at Cooling creates a connection between one part and the other Part is created.

Vorzugsweise wird als Kunstharz für das eine Teil Eiytetrafluoräthylen verwendet, und vorzugsweise wird auch für das Kunstharz des weiteren Teils Polytetrafluorethylen verwendet.The synthetic resin used for one part is preferably ethyl tetrafluoroethylene is used, and preferably polytetrafluoroethylene is also used for the synthetic resin of the further part.

Vorzugsweise wird die Partie des zweiten schweißfähigen Teils dadurch zum Schmelzen gebracht, daß Ultraschallenergie darauf zur Einwirkung gebracht wird.Preferably, the portion of the second weldable part is thereby melted by applying ultrasonic energy to it.

Die Erfindung ist im nachfolgenden unter Bezugnahme auf die Zeichnung näher erläutert. In der Zeichnung sind:The invention is described below with reference to the drawing explained in more detail. In the drawing are:

Fig. 1 und 2 Phasen im Verfahren gemäß einem ersten Ausführungsbeispiel der Erfindung und1 and 2 phases in the method according to a first embodiment of the invention and

Pig. 3 und 4 Phasen in einem Verfahren gemäß einem zweiten Ausführungsbeispiel der Erfindung.Pig. 3 and 4 phases in a method according to a second embodiment the invention.

Gemäß Pig. 1 und 2 soll eine leckfreie Verbindung zwischen einer porösen Polytetrafluoräthylen-Lage 11 und einem Rahmen 12 hergestellt werden, der aus einem schweißfähigen Kunstharz besteht, beispielsweise Polystyrol, derart, daß ein metallisches Gitter 15 zwischen der Lage 11 und dem Rahmen 12 eingeschlossen wird. Der Rahmen 12 ist mit einem einstückigen Ansatz 14 versehen, der den Bereich des Rahmens 12 bildet, mit dem die Lage 11 verbunden werden muß. TJm die Verbindung zu bewirken, wird die Lage 11 in Anlage an den Rahmen 12 gebracht, wobei das metallische Gitter 13, das ausAccording to Pig. 1 and 2 are intended to produce a leak-free connection between a porous polytetrafluoroethylene layer 11 and a frame 12 are made of a weldable synthetic resin, such as polystyrene, such that a metallic grid 15 between the layer 11 and the frame 12 is included. The frame 12 is provided with a one-piece extension 14, which the area of the frame 12, with which the layer 11 must be connected. To effect the connection, layer 11 is attached to brought the frame 12, the metallic grid 13, which is made of

209823/0765 _ 5 .209823/0765 _ 5 .

gestreckten Haschen gebildet ist, zwischen die Lage 11 und den Rahmen 12 gelegt ist, und dann vrird TTltraschallenergie an den Ansatz 14 durch die Lage 11 und das Gitter 13 angelegt, während Druck zwischen der Lage 11 und dem Rahmen 12 ausgeübt wird. Der Ansatz 14 schmilzt, und das geschmolzene Material fließt durch das Gitter 13 in die Poren der Lage 11, wodurch bei Abkühlung eine Verbindung zwischen der Lage 11, dem Gitter 15 und dem Rahmen entsteht.elongated loop is formed, is placed between the layer 11 and the frame 12, and then ultrasonic energy is applied to the approach 14 applied by the layer 11 and the grid 13 while Pressure between the layer 11 and the frame 12 is exerted. Of the Approach 14 melts, and the molten material flows through the grid 13 into the pores of the layer 11, thereby cooling down a connection between the layer 11, the grid 15 and the frame arises.

Im oben beschriebenen Verfahren bildet der Rahmen 12 den halben Zellenrahmen einer Luftelektrode einer primären Metall/Luft-Bat- f terie, und er ist mit einem in der Mitte liegenden Loch 15 versehen. Venn die Verbindung zwischen der Lage 11 und dem Rahmen 12 hergestellt worden ist, wird das aktive Material der Luftelektrode auf das Gitter 15 gegeben, und ein poröses isolierendes Trennstück (nicht dargestellt) wird in das Loch 15 gesetzt, um das aktive Material am Gitter 13 zu halten. Das Gitter 15 dient zum Tragen des aktiven Materials der Luftelektrode und wirkt als ein Dtromkollektor in der fertigen Batterie.In the method described above, the frame 12 forms half the cell frame of an air electrode of a primary metal / air battery terie, and it is provided with a hole 15 in the middle. When the connection between the sheet 11 and the frame 12 has been made, the active material becomes the air electrode placed on the grid 15, and a porous insulating separator (not shown) is placed in the hole 15 to the active To hold material on the grid 13. The grid 15 is used for carrying of the active material of the air electrode and acts as a current collector in the finished battery.

In einer Abwandlung (nicht dargestellt) des vorstehend beschriebenden Ausführungsbeispiels wird das aktive Material der Luftelektrode auf das Gitter 13 gegeben, ehe die Lage 11 mit dem Rahmen g 12 verbunden wird, wobei der Verbindungsvorgang auch dazu dient, das isolierende Trennstück am aktiven Material und zwischen dem Rahmen 12 und der Lage 11 zu halten.In a modification (not shown) of the embodiment described above, the active material of the air electrode is placed on the grid 13 before the layer 11 is connected to the frame g 12, the connecting process also serving to the insulating separator on the active material and between the frame 12 and the layer 11 to hold.

In einer weiteren Abwandlung (nicht dargestellt) des vorstehenden Ausführungsbeispiels wird der halbe Zellenrahmen 12 durch einen kompletten Zellenrahmen ersetzt, der an einr Seite entlang offen ist, um eine Anode in eine Ausnehmung einsetzen zu können, die innerhalb dee Rahmens gebildet ist. In dieser Variante werden die beiden Elektroden, die mit der Anode eine Einzelzelle in der fertigen Batterie bilden, in einem Arbeitsgang angebracht, indem entweder zwei getrennte Polytetrafluoräths^len-Lagen oder eine einzigeIn a further modification (not shown) of the above embodiment, the half cell frame 12 is through a replaced complete cell frame, which is open along one side in order to insert an anode into a recess, the is formed within the frame. In this variant, the Both electrodes, which form a single cell in the finished battery with the anode, are attached in one operation by either two separate polytetrafluoroethylene layers or a single one

209823/0765 " 4"209823/0765 " 4 "

Polytetrafluoräthylen-Lage verwendet werden bzw. wird, die über eine verbundene Geite des Hahmens gefaltet wird, wobei die Lage oder die Lagen mit angebrachten Gittern versehen ist bzw. sind und eine Beschichtung mit dem aktiven Material vorgesehen ist.Polytetrafluoroethylene layer can be used, which is folded over a connected Geite of the frame, wherein the layer or layers is or are provided with attached grids and a coating with the active material is provided .

In einem zweiten Ausführungsbeispiel der Erfindung gemäß Fig. 3 und 4 muß eine Zelle einer primären Metall/Luft-Batterie hergestellt werden, wobei die Zelle zwei Luftelektroden aufweist, die auf gegenüberliegenden Seiten einer Hetallanode 16 sitzen und ihr gegenüber isoliert sind und jeweils aktives Haterial 17 aufweisen, das auf einem porösen Polytetrafluoräthylen-Träger getragen ist. Die Zelle wird dadurch hergestellt, daß eine Lage des aktiven Haterials 17 auf einen porösen Polytetrafltioräthylen-Ctreifen 18 gelegt wird, und dann wird das aktive Haterial 17 Eiit einem Streifen 19 aus einem porösen, isolierenden, schweißfähigen Katerial belegt, das im wesentlichen die gleichen Abmessungen wie der Streifen 18 hat. Der Streifen 19 wird vorzugsweise in der Form eines porösen Polyamids verwendet, das unter dem ¥arennakmen "BOlTDIIiA" zu erhalten ist. Die Metallanode 16 wird dann auf den Streifen 19 gelegt, und der Streifen 18 wird um seine Mittellinie herum gefaltet, derart, daß die Anode 16 zwischen gefalteten Partien des Ctreifens 19 eingefangen wird, wobei durch Stromzuführungen 21 bzw. 22 elektrische Verbindungen mit der Anode 16 bzw. mit dem aktiven Haterial 17 hergestellt werden. Ferner wird ein herausnehmbarer Stift 24 auf den Streifen 19 an der Anode 16 gelegt, derart, daß er sich parallel zu den Stromzuführungen 21, 22 erstreckt und über den Rand der Streifen 18 und 19 vorsteht. Die Zelle wird dann durch Herstellung einer flüssigkeitsdichten Verbindung zwischen den gefalteten Partien des Streifens 18 versiegelt, wobei sich die Verbindung um die Metallanode 16 herum erstreckt, wie das durch die Linien 25 in Fig. 4 angezeigt ist. Die Versiegelung entsteht durch TTltraschallverschweißen, das ein Schmelzen einer Partie des schweißfähigen Streifens 19 bewirkt, wobei die geschmolzene Partie in die Poren des Polytetrafluoräthylen-Streifens 18 fließt, so daß bei Ab- In a second embodiment of the invention according to FIGS. 3 and 4, a cell of a primary metal / air battery has to be produced, the cell having two air electrodes which are seated on opposite sides of a metal anode 16 and are insulated from it and in each case active material 17 have, which is carried on a porous polytetrafluoroethylene support. The cell is made by laying a layer of the active material 17 on a porous polytetrafluoroethylene strip 18 and then overlaying the active material 17 with a strip 19 of porous, insulating, weldable material having substantially the same dimensions like the strip 18 has. The strip 19 is preferably used in the form of a porous polyamide, which is available under the name "BOlTDIIiA". The metal anode 16 is then placed on the strip 19 and the strip 18 is folded about its center line so that the anode 16 is trapped between folded portions of the strip 19, with electrical connections to the anode 16 through power leads 21 and 22, respectively or with the active material 17 are produced. Furthermore, a removable pin 24 is placed on the strip 19 on the anode 16 in such a way that it extends parallel to the power supply lines 21, 22 and protrudes over the edge of the strips 18 and 19. The cell is then sealed by making a liquid-tight connection between the folded portions of the strip 18, the connection extending around the metal anode 16 as indicated by lines 25 in FIG. The seal is created by ultrasonic welding, which causes a portion of the weldable strip 19 to melt, the melted portion flowing into the pores of the polytetrafluoroethylene strip 18 so that when

209823/0765 " 5 "209823/0765 " 5 "

kühlung eine flüssigkeitsdichte Versiegelung zwischen den gefalteten Partien des Streifens 18 entsteht. Der Stift 24 wird dann aus der Zelle herausgezogen, damit ein Zugang zu der Zellenkammer entsteht, die innerhalb der versiegelten Partie des Streifens gebildet ist, so daß ein Elektrolyt eingegeben werden kann.cooling creates a liquid-tight seal between the folded Parts of the strip 18 arise. The pin 24 will then pulled out of the cell to allow access to the cell chamber formed within the sealed portion of the strip so that an electrolyte can be added.

Es versteht sich, daß andere Verfahren zum Verschweißen außer das TTltraschallverschweißen verwendet werden können, um das schweißfähige Haterail in den vorstehend beschriebenen Beispielen zum Schmelzen zu bringen. Ferner versteht es sich, daß zwar in den vor- ^ stehenden Beispielen Polytetrafluorethylen verwendet wird, bei dem es sich um ein poröses, nicht-schweißfähiges, hydrophobes Kunstharz handelt, das derfindungsgemäße Verfahren aber auch zur Verbindung zweier Teile verwendet werden kann, bei denen eines aus einem porösen Kunstharz besteht, bie§pielsweise PVC, das sowohl schweißfähig als auch nicht-hydrophob ist, vorausgesetet, daß der Schmelzpunkt des anderen Teils unter dem des porösen Kunstharzes liegt. Entsprechend können auch poröse, nicht-schweißfähige, hydrophobe Kunstharze außer Polytetrafluorethylen verwendet werden.It will be understood that methods of welding other than ultrasonic welding can be used to create the weldable Melting Haterail in the examples described above. Furthermore, it goes without saying that although in the previous ^ Examples of polytetrafluoroethylene is used, in which it is a porous, non-weldable, hydrophobic synthetic resin acts, the inventive method but also for connection two parts can be used, in which one consists of a porous synthetic resin, e.g. PVC, which is both weldable as well as non-hydrophobic, provided that the melting point the other part is lower than that of the porous synthetic resin. Correspondingly, porous, non-weldable, hydrophobic Synthetic resins other than polytetrafluoroethylene can be used.

PatentansprücheClaims

209823/0765209823/0765

Claims (1)

PatentansprücheClaims f 1 λ Verfahren zur Herstellung einer Verbindung zwischen Teilen, von denen eines aus einem porösen Kunstharz besteht, dadAurch gekennzeichnet, daß das eine Teil, das aus dem porösen Kunstharz besteht, in Anlage an einem zweiten Teil gebracht wird, das aus einem Haterial mit einem niedrigeren Schmelzpunkt als das Kunstharz besteht, und daß mindestens eine Partie des zweiten Teils zum Schmelzen ohne ein Schmelzen des einen Teils gebracht wird, derart, daß die geschmolzene Partie in die Poren des einen Teils fließt und bei Abkühlung eine Verbindung zwischen dem einen Teil und dem anderen Teil entsteht.f 1 λ A method for producing a connection between parts, one of which consists of a porous synthetic resin, characterized in that the one part, which consists of the porous synthetic resin, is brought into contact with a second part, which consists of a material with a lower melting point than the synthetic resin, and that at least one part of the second part is brought to melt without melting the one part, such that the molten part flows into the pores of the one part and, when cooled, a connection between the one part and the other part arises. 2, Verfahren zur Herstellung einer Verbindung zwischen Teilen, von denen eines aus einem porösen, nicht-schweißfähigen, hydrophoben Kunstharz besteht, dadurch gekennzeichnet, daß das eine Teil, das aus dem porösen, nicht-schweißfähigen hydrophoben Haterial besteht, in Anlage an einem zweiten Teil gebracht wird, das aus einem schweißfähigen Material besteht, und daß mindestens eine Partie des zweiten schweißfähigen Materials zum Schmelzen gebracht wird, derart, daß die geschmolzene Partie in die Poren des einen Teils fließt und bei Abkühlung eine Verbindung zwischen dem einen Teil und dem anderen Teil entsteht.2, a method for producing a connection between parts, one of which consists of a porous, non-weldable, hydrophobic synthetic resin, characterized in that one part, which consists of the porous, non-weldable hydrophobic material, is in contact with a second Part is brought, which consists of a weldable material, and that at least one part of the second weldable material is brought to melt, such that the molten part flows into the pores of one part and, when cooled, a connection between one part and the other Part is created. 5. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß ein weiteres poröses, nicht-schweißfähiges, hydrophobes Kunstharzteil in Anlage an das zweite schweißfähige Teil gebracht, derart, daß dann, wenn eine Partie des zvreiten aiiweißfähigen Teils zum Schmelzen gebracht wird, die geschmolzene Partie in die Poren des einen Teils und des weiteren Teils fließt und bei Abkühlung eine Verbindung zwischen dem einen Teil und dem weiteren Teil entsteht.5. The method according to claim 2, characterized in that a further porous, non-weldable, hydrophobic synthetic resin part is brought into contact with the second weldable part, in such a way that when a part of the second weldable part is melted, the melted part flows into the pores of one part and the other part and a connection is created between the one part and the other part when it cools down. 4. Verfahren nach Anspruch 2 oder 3, dadurch gekennzeichnet, daß für das Kunstharz des einen Teils Polytetrafluorethylen verwendet wird.4. The method according to claim 2 or 3, characterized in that polytetrafluoroethylene is used for the synthetic resin of one part. 25 559 209823/0765 25 559 209823/0765 Va/Ti - 2 -Va / Ti - 2 - 5. Verfahren nach Anspruch J, dadurch feekennzeichnet, daß für das kunstharz des weiteren Teils Polytetrafluorethylen verwendet wird.5. The method according to claim J, characterized in that polytetrafluoroethylene is used for the synthetic resin of the further part. 6. Verfahren nach einem der Ansprüche 1 bis 5» dadurch gekennzeichnet, daß die Partie des zweiten schveißfähigen Teils dadurch zum Schmelzen gebracht wird, daß Ultraschallenergie darauf zur Einwirkung gebracht wird.6. The method according to any one of claims 1 to 5 » characterized in that the portion of the second weldable part is brought to melt that ultrasonic energy is applied to it. 7. Verfahren zur Herstellung eines porösen Kunstharzbehältnisses,7. Process for the production of a porous synthetic resin container, dadurch gekennzeichnet, daß man von zwei Lagen porösen Kunstharzes λ ausgeht, zwischen den lagen ein aus einem schweißfähigen Haterial gebildetes Teil mit einem niedrigeren Schmelzpunkt als das Kunstharz einschließt und eine Partie des Teils zum Schmelzen bringt, ohne daß ein Schmelzen der Kunstharzlagen erfolgt, derart, daß die geschmolzene Partie in die Poren der Lagen fließt und die Lagen mit dem Teil zur Herstellung des Behältnisses verbindet. characterized in that one starts from two layers of porous synthetic resin λ , between the layers enclosing a part formed from a weldable material with a lower melting point than the synthetic resin and causing a portion of the part to melt without melting the synthetic resin layers, in such a way that that the molten part flows into the pores of the layers and connects the layers with the part for making the container. 8. Verfahren zur Herstellung eines Behältnisses aus einem porösen, nicht-schweißfähigen, hydrophoben Kunstharz, dadurch gekennzeichnet, daß man von zwei Lagen des porösen, nicht-schweißfähigen, hydrophoben Kunstharzes ausgeht, zwischen den Lagen ein aus einem schweißfähigen Material gebildetes Teil mit einem niedrigeren Schmelzpunkt als das Kunstharz einschließt und eine Partie des Teils zum Schmel- % zen bringt, ohne daß die Lagen aus Kunstharz schmelzen, derart, daß die geschmolzene Partie in die Poren der Lagen fließt und die Lagen mit dem Teil zur Herstellung des Behältnisses verbaindet.8. A method for producing a container from a porous, non-weldable, hydrophobic synthetic resin, characterized in that one starts from two layers of the porous, non-weldable, hydrophobic synthetic resin, between the layers a part formed from a weldable material with a lower one Melting point as the resin and causes a portion of the part to melt % without melting the layers of synthetic resin, such that the molten portion flows into the pores of the layers and connects the layers to the part to make the container. 9 . Verfahren nach Anspruch 7 oder 8, dadurch gekennzeichnet, daß beiden Materiallagen durch Teile eines einzigen Haterialstreifens gebildet werden, wobei man den Streifen faltet, derart, daß ein Einschließen des schweißfähigen Teils zwischen gefalteten Partien des Ctreifens ermöglicht wird.9. Method according to Claim 7 or 8, characterized in that the two layers of material are formed by parts of a single strip of material, the strip being folded in such a way that the weldable part can be enclosed between folded portions of the strip. 209823/07 65209823/07 65 LeerseiteBlank page
DE19712157733 1970-11-21 1971-11-22 Method of making a joint between parts made of a porous synthetic resin Pending DE2157733A1 (en)

Applications Claiming Priority (1)

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GB5552070A GB1365483A (en) 1970-11-21 1970-11-21 Method of joining parts wherein one of the parts is formed of a porous hydrophobic non stick synthetic resin material

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DE2157733A1 true DE2157733A1 (en) 1972-05-31

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DE (1) DE2157733A1 (en)
FR (1) FR2115263B1 (en)
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775189A (en) * 1972-02-25 1973-11-27 Gould Inc Forming sealed housings for electrochemical cells
DE2626975C3 (en) * 1976-06-16 1979-04-26 Varta Batterie Ag, 3000 Hannover Positive electrode for air / zinc elements
US4092464A (en) * 1976-07-19 1978-05-30 P. R. Mallory & Co. Inc. Flexible cells and batteries formed therefrom
CA1129946A (en) * 1977-10-14 1982-08-17 Joannes J.P. Leyen Method for the manufacture of an electrochemical cell or battery
US4218275A (en) * 1978-02-03 1980-08-19 Olin Corporation Method of sealing separators for electrolytic cells for alkali metal chloride brines
JPWO2003059611A1 (en) * 2002-01-09 2005-05-19 旭化成メディカル株式会社 Welded product of non-porous body and porous body

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GB1365483A (en) 1974-09-04

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