DE19964603B4 - Sterisch gehinderte Aminether und deren Verwendung als Stabilisatoren für organisches Material - Google Patents

Sterisch gehinderte Aminether und deren Verwendung als Stabilisatoren für organisches Material Download PDF

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Publication number
DE19964603B4
DE19964603B4 DE19964603A DE19964603A DE19964603B4 DE 19964603 B4 DE19964603 B4 DE 19964603B4 DE 19964603 A DE19964603 A DE 19964603A DE 19964603 A DE19964603 A DE 19964603A DE 19964603 B4 DE19964603 B4 DE 19964603B4
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Germany
Prior art keywords
alkyl
formula
tert
group
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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DE19964603A
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German (de)
English (en)
Inventor
Alessandro Zedda
Gianluca Ferri
Massimiliano Sala
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BASF SE
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Ciba Holding AG
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Filing date
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Priority claimed from IT98MI000366A external-priority patent/ITMI980366A1/it
Application filed by Ciba Holding AG filed Critical Ciba Holding AG
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Publication of DE19964603B4 publication Critical patent/DE19964603B4/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56Nitrogen atoms
    • C07D211/58Nitrogen atoms attached in position 4
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94Oxygen atom, e.g. piperidine N-oxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D251/00Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40Nitrogen atoms
    • C07D251/54Three nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066Flame-proofing or flame-retarding additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3435Piperidines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • C08K5/34926Triazines also containing heterocyclic groups other than triazine groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/30Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Hydrogenated Pyridines (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
DE19964603A 1998-02-25 1999-02-24 Sterisch gehinderte Aminether und deren Verwendung als Stabilisatoren für organisches Material Expired - Lifetime DE19964603B4 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
ITMI98A000366 1998-02-25
IT98MI000366A ITMI980366A1 (it) 1998-02-25 1998-02-25 Preparazione di eteri amminici stericamente impediti
US10471898A 1998-06-25 1998-06-25
US09/104,718 1998-06-25

Publications (1)

Publication Number Publication Date
DE19964603B4 true DE19964603B4 (de) 2013-02-28

Family

ID=26331570

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19907945A Expired - Lifetime DE19907945B4 (de) 1998-02-25 1999-02-24 Herstellung von sterisch gehinderten Aminethern
DE19964603A Expired - Lifetime DE19964603B4 (de) 1998-02-25 1999-02-24 Sterisch gehinderte Aminether und deren Verwendung als Stabilisatoren für organisches Material

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19907945A Expired - Lifetime DE19907945B4 (de) 1998-02-25 1999-02-24 Herstellung von sterisch gehinderten Aminethern

Country Status (17)

Country Link
JP (2) JP4798815B2 (enrdf_load_stackoverflow)
KR (1) KR100561146B1 (enrdf_load_stackoverflow)
CN (2) CN1202085C (enrdf_load_stackoverflow)
AR (1) AR015238A1 (enrdf_load_stackoverflow)
BE (1) BE1014990A5 (enrdf_load_stackoverflow)
BR (1) BR9900807B1 (enrdf_load_stackoverflow)
CA (2) CA2643170C (enrdf_load_stackoverflow)
CZ (1) CZ302752B6 (enrdf_load_stackoverflow)
DE (2) DE19907945B4 (enrdf_load_stackoverflow)
ES (1) ES2159462B1 (enrdf_load_stackoverflow)
FR (1) FR2777004B1 (enrdf_load_stackoverflow)
GB (1) GB2334717B (enrdf_load_stackoverflow)
ID (1) ID23225A (enrdf_load_stackoverflow)
MY (1) MY123467A (enrdf_load_stackoverflow)
NL (1) NL1011394C2 (enrdf_load_stackoverflow)
RU (1) RU2224758C2 (enrdf_load_stackoverflow)
SG (1) SG74700A1 (enrdf_load_stackoverflow)

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SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
JP3540759B2 (ja) * 2000-04-06 2004-07-07 三菱レイヨン株式会社 難燃性ポリプロピレン繊維及びその製造方法
JP2004083913A (ja) * 2000-04-06 2004-03-18 Mitsubishi Rayon Co Ltd 難燃性ポリプロピレンフィルム
TW572896B (en) 2000-05-26 2004-01-21 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
EP1038912A3 (en) * 2000-06-22 2000-12-27 Ciba SC Holding AG High molecular weight hindered hydrocarbyloxyamine stabilizers
TWI273115B (en) * 2000-12-12 2007-02-11 Ciba Sc Holding Ag Improved weatherability of flame retardant polyolefin
TW200407307A (en) * 2001-11-26 2004-05-16 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
AU2003227594A1 (en) * 2002-04-17 2003-10-27 Ciba Specialty Chemicals Holding Inc. Flame retardant polymer compositions containing hydroxylamine esters
JP4167522B2 (ja) * 2002-05-31 2008-10-15 サンテーラ株式会社 オレフィン系樹脂組成物およびそれからなる積層フィルム
CN101010369B (zh) * 2004-08-31 2010-12-22 西巴特殊化学品控股有限公司 有机材料的稳定
EP2993168B1 (en) * 2004-11-02 2017-05-17 Basf Se Process for the synthesis of n-alkoxyamines
CN101541787B (zh) * 2006-11-23 2015-02-04 西巴控股有限公司 N-烯丙基空间位阻的叔胺的制备方法
CN101990555A (zh) * 2007-12-21 2011-03-23 巴斯夫欧洲公司 纳米结构的uv吸收剂
US20120145241A1 (en) * 2009-08-18 2012-06-14 Basf Se Photovoltaic module with stabilized polymeric encapsulant
KR101994057B1 (ko) * 2009-09-10 2019-06-27 바스프 에스이 입체 장애 아민 안정화제
ES2541284T3 (es) * 2010-10-20 2015-07-17 Basf Se Fotoestabilizadores a base de aminas estéricamente impedidas con funcionalización mixta
EP2514800B2 (de) 2011-04-21 2018-03-07 Merck Patent GmbH Verbindungen und flüssigkristallines Medium
EP3526288B1 (en) 2016-10-14 2021-08-04 Basf Se Stabilizer composition
WO2018177846A1 (en) * 2017-03-28 2018-10-04 Basf Se Light stabilizer mixture
CN109503554B (zh) * 2018-12-13 2020-10-30 天津利安隆新材料股份有限公司 一种聚合型受阻胺类光稳定剂ha-88的制备方法
WO2020182587A1 (en) * 2019-03-08 2020-09-17 Basf Se Sterically hindered amine stabilizer mixtures
CN112126060B (zh) * 2019-06-25 2022-05-31 北京天罡助剂有限责任公司 一种聚合型高分子空间位阻胺及其制备方法
CN113354813B (zh) * 2021-06-02 2023-07-04 宿迁联盛科技股份有限公司 一种低碱性受阻胺光稳定剂nor 371的制备方法
JP2025511683A (ja) 2022-04-04 2025-04-16 ジェネアスケム・アーゲー 立体障害ニトロキシルエーテルを調製するためのプロセス
WO2025067782A1 (en) 2023-09-27 2025-04-03 Geneuschem Ag Preparation of n-alkoxyamine hals from corresponding hydroxylamines

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309402A1 (en) * 1987-09-21 1989-03-29 Ciba-Geigy Ag N-substituted hindered amine stabilizers
EP0366057A2 (en) * 1988-10-24 1990-05-02 ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) Light stabilizing flame retardants
EP0389428A2 (en) * 1989-03-21 1990-09-26 Ciba-Geigy Ag N,N-Bis(l-hydroxycarbyloxy-2,2,6,6-tetramethyl-piperidin-4-yl) amino triazines and stabilized compositions
US5004770A (en) * 1988-10-19 1991-04-02 Ciba-Geigy Corporation Polymeric substrates stabilized with N-substituted hindered amines
US5096950A (en) * 1988-10-19 1992-03-17 Ciba-Geigy Corporation Polyolefin compositions stabilized with NOR-substituted hindered amines
US5124378A (en) * 1987-09-21 1992-06-23 Ciba-Geigy Corporation Stabilization of ambient cured coatings
US5393812A (en) * 1993-08-31 1995-02-28 Hercules Incorporated Flame retardant, light stable composition
EP0792911A2 (en) * 1996-02-27 1997-09-03 Fmc Corporation Flame resistant polyolefin compositions

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IT1215462B (it) * 1987-05-07 1990-02-14 Ciba Geigy Spa Composti piperidinici utilizzabili come stabilizzanti alla luce, al calore e all'ossidazione per polimeri sintetici.
US4824884A (en) * 1987-08-12 1989-04-25 Pennwalt Corporation Cyclic anhydride derivatives of hydrazide functionalized hindered amine light stabilizers
US5204473A (en) * 1987-09-21 1993-04-20 Ciba-Geigy Corporation O-substituted N-hydroxy hindered amine stabilizers
US4921962A (en) * 1988-10-19 1990-05-01 Ciba-Geigy Corporation Process for preparing N-hydrocarbyloxy derivatives of sterically hindered amines
DE68926960T2 (de) * 1989-02-13 1997-03-06 Atochem North America Elf Reaktive gehinderte aminlichtstabilisatoren
DE69012617T2 (de) * 1989-03-21 1995-01-26 Ciba Geigy Ag Azoverbindungen mit einer sterisch gehinderten Aminogruppe geringer Basizität.
DE69012615T2 (de) * 1989-03-21 1995-01-26 Ciba Geigy Ag Äthylenisch ungesättigte Verbindungen, die 1-Hydrocarbyloxy-2,2,6,6-tetramethylpiperidine-Teile enthalten, und Polymere, Copolymere und stabilisierte Zusammensetzungen.
DE69026747T2 (de) * 1989-03-21 1996-11-14 Ciba Geigy Ag Nichtwandernde 1-Hydrocarbyloxy-gehinderte Amineverbindungen als Polymerstabilisatoren
IT1246170B (it) * 1990-07-24 1994-11-16 Ciba Geigy Spa Composizione stabilizzante per polipropilene comprendente composti triazinici contenenti gruppi piperidinici e composti metallici
US5180830A (en) * 1991-04-24 1993-01-19 Himont Incorporated Process for preparing hindered amine light stabilizers
US5216156A (en) * 1992-05-05 1993-06-01 Ciba-Geigy Corporation Non-migrating 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine 1,3,5-triazine derivatives
IT1263993B (it) * 1993-04-05 1996-09-06 Ciba Geigy Spa Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici
TW270131B (enrdf_load_stackoverflow) * 1993-07-13 1996-02-11 Ciba Geigy
IT1264946B1 (it) * 1993-07-16 1996-10-17 Ciba Geigy Spa Derivati del 2,2,6,6-tetrametil-4-piperidinolo utili come stabilizzanti alla luce ed all'ossidazione per materiali organici.
US5380828A (en) * 1993-10-05 1995-01-10 Ciba-Geigy Corporation Azodicarboxylic acid derivatives containing hindered amine moieties as polymer stabilizers
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US6046304A (en) * 1995-12-04 2000-04-04 Ciba Specialty Chemicals Corporation Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
EP0782994B1 (en) * 1995-12-04 2003-02-05 Ciba SC Holding AG Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
JPH09292682A (ja) * 1996-04-23 1997-11-11 Fuji Photo Film Co Ltd ハロゲン化銀カラー写真感光材料
WO1998033760A1 (fr) * 1997-02-03 1998-08-06 Fuji Photo Film Co., Ltd. Composes phenidone utiles pour la photographie en couleurs basee sur l'utilisation d'halogenures d'argent et procede pour preparer ces composes
ITMI980366A1 (it) * 1998-02-25 1999-08-25 Ciba Spec Chem Spa Preparazione di eteri amminici stericamente impediti

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309402A1 (en) * 1987-09-21 1989-03-29 Ciba-Geigy Ag N-substituted hindered amine stabilizers
US5124378A (en) * 1987-09-21 1992-06-23 Ciba-Geigy Corporation Stabilization of ambient cured coatings
US5004770A (en) * 1988-10-19 1991-04-02 Ciba-Geigy Corporation Polymeric substrates stabilized with N-substituted hindered amines
US5096950A (en) * 1988-10-19 1992-03-17 Ciba-Geigy Corporation Polyolefin compositions stabilized with NOR-substituted hindered amines
EP0366057A2 (en) * 1988-10-24 1990-05-02 ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) Light stabilizing flame retardants
EP0389428A2 (en) * 1989-03-21 1990-09-26 Ciba-Geigy Ag N,N-Bis(l-hydroxycarbyloxy-2,2,6,6-tetramethyl-piperidin-4-yl) amino triazines and stabilized compositions
US5393812A (en) * 1993-08-31 1995-02-28 Hercules Incorporated Flame retardant, light stable composition
EP0792911A2 (en) * 1996-02-27 1997-09-03 Fmc Corporation Flame resistant polyolefin compositions

Also Published As

Publication number Publication date
CN1202085C (zh) 2005-05-18
JP4798815B2 (ja) 2011-10-19
MY123467A (en) 2006-05-31
FR2777004B1 (fr) 2005-12-30
CN1235159A (zh) 1999-11-17
CA2643170C (en) 2013-04-16
KR100561146B1 (ko) 2006-03-15
CA2262435C (en) 2009-12-22
DE19907945A1 (de) 1999-08-26
AR015238A1 (es) 2001-04-18
NL1011394A1 (nl) 1999-08-26
CN1552758A (zh) 2004-12-08
BE1014990A5 (fr) 2004-08-03
GB2334717A (en) 1999-09-01
SG74700A1 (en) 2000-08-22
JP2011006443A (ja) 2011-01-13
ES2159462A1 (es) 2001-10-01
FR2777004A1 (fr) 1999-10-08
KR19990072904A (ko) 1999-09-27
RU2224758C2 (ru) 2004-02-27
JPH11315067A (ja) 1999-11-16
BR9900807B1 (pt) 2013-06-11
GB2334717B (en) 2000-04-26
CN100384826C (zh) 2008-04-30
BR9900807A (pt) 2000-03-28
DE19907945B4 (de) 2013-06-06
ES2159462B1 (es) 2002-05-01
NL1011394C2 (nl) 1999-10-26
CA2643170A1 (en) 1999-08-25
CA2262435A1 (en) 1999-08-25
GB9903463D0 (en) 1999-04-07
ID23225A (id) 2000-03-30
CZ302752B6 (cs) 2011-10-19

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