DE1694539C3 - Verfahren zur Herstellung von selbstverlöschenden Mischpolymerisaten aus Styrol und Acrylnitril - Google Patents
Verfahren zur Herstellung von selbstverlöschenden Mischpolymerisaten aus Styrol und AcrylnitrilInfo
- Publication number
- DE1694539C3 DE1694539C3 DE1694539A DE1694539A DE1694539C3 DE 1694539 C3 DE1694539 C3 DE 1694539C3 DE 1694539 A DE1694539 A DE 1694539A DE 1694539 A DE1694539 A DE 1694539A DE 1694539 C3 DE1694539 C3 DE 1694539C3
- Authority
- DE
- Germany
- Prior art keywords
- latex
- red phosphorus
- copolymers
- extinguishing
- acrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 30
- 229920001577 copolymer Polymers 0.000 title claims description 21
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 37
- 239000004816 latex Substances 0.000 claims description 26
- 229920000126 latex Polymers 0.000 claims description 26
- 239000004033 plastic Substances 0.000 claims description 10
- 229920003023 plastic Polymers 0.000 claims description 10
- 239000003063 flame retardant Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000000704 physical effect Effects 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- 101150046432 Tril gene Proteins 0.000 claims 1
- 230000003466 anti-cipated effect Effects 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 description 10
- 239000011574 phosphorus Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004159 Potassium persulphate Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- -1 alkyl mercaptan Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 210000000626 ureter Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK0062479 | 1967-06-06 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1694539A1 DE1694539A1 (de) | 1971-09-02 |
| DE1694539B2 DE1694539B2 (de) | 1973-03-08 |
| DE1694539C3 true DE1694539C3 (de) | 1973-10-18 |
Family
ID=7230626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1694539A Expired DE1694539C3 (de) | 1967-06-06 | 1967-06-06 | Verfahren zur Herstellung von selbstverlöschenden Mischpolymerisaten aus Styrol und Acrylnitril |
Country Status (8)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951908A (en) * | 1969-12-31 | 1976-04-20 | Badische Anilin- & Soda Fabrik Aktiengesellschaft | Flame-proofing, high melting point thermoplastic polymers with lactam-impregnated red phosphorus |
| BE787449A (fr) * | 1971-08-11 | 1973-02-12 | Basf Ag | Masses a mouler auto-extinctrices a base de polyoxymethylene renforce par des fibres de verre |
| US3943194A (en) * | 1972-05-25 | 1976-03-09 | Hoechst Aktiengesellschaft | Flameproof moulding compositions based on polyolefins |
| DE2308104A1 (de) * | 1973-02-19 | 1974-08-22 | Hoechst Ag | Formmasse aus thermoplastischen kunststoffen |
| FR2303837A1 (fr) * | 1975-03-13 | 1976-10-08 | Rhone Poulenc Ind | Compositions thermostables ignifugees a base de prepolymeres obtenus a partir de bis-imides et de diamines |
| IT1134333B (it) * | 1980-11-19 | 1986-08-13 | F F A Spa Sa | Processo per stabilizzare mediante incapsulamento il fosforo rosso per impiego come ritardante di fiamma dei materiali polimerici e prodotto cosi' ottenuto |
| IT1157253B (it) * | 1982-02-09 | 1987-02-11 | Saffa Spa | Procedimento per rendere autoestinguenti, mediante fosforo rosso, materiali termoplastici sintetici e prodotti cosi' ottenuti |
| JP2005205157A (ja) * | 2003-12-26 | 2005-08-04 | Uniplas Shiga Kk | 難燃ナイロンカーペットおよびその製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE483422A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1946-12-13 | |||
| LU31096A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1950-11-20 | |||
| US2964490A (en) * | 1957-03-12 | 1960-12-13 | Us Rubber Co | Butadiene copolymer rubber-silica masterbatch and process of preparation |
| GB1047482A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1963-01-23 | 1900-01-01 | ||
| US3322716A (en) * | 1963-08-19 | 1967-05-30 | American Cyanamid Co | Flame retardant compositions consisting essentially of a thermoplastic material and a phosphinic acid |
| DE1289653B (de) * | 1963-09-25 | 1969-02-20 | Basf Ag | Schwer entflammbare Formmassen aus Styrolpolymerisaten |
| US3294712A (en) * | 1963-11-29 | 1966-12-27 | Stauffer Chemical Co | Flame resistant polyurethane compositions containing p4 s3 or p4 s7 |
| US3373135A (en) * | 1964-12-01 | 1968-03-12 | Kalk Chemische Fabrik Gmbh | Shaped articles of self-extinguishing epoxy resins |
-
1967
- 1967-06-06 DE DE1694539A patent/DE1694539C3/de not_active Expired
-
1968
- 1968-05-17 CH CH733168A patent/CH492746A/de not_active IP Right Cessation
- 1968-05-28 GB GB25524/68A patent/GB1157419A/en not_active Expired
- 1968-05-31 US US733308A patent/US3546160A/en not_active Expired - Lifetime
- 1968-06-04 AT AT530068A patent/AT282968B/de not_active IP Right Cessation
- 1968-06-05 NL NL6807881.A patent/NL156166B/xx not_active IP Right Cessation
- 1968-06-06 BE BE716175D patent/BE716175A/xx unknown
- 1968-06-06 FR FR1567768D patent/FR1567768A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL156166B (nl) | 1978-03-15 |
| CH492746A (de) | 1970-06-30 |
| BE716175A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-12-06 |
| GB1157419A (en) | 1969-07-09 |
| FR1567768A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1969-05-16 |
| NL6807881A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-12-09 |
| DE1694539B2 (de) | 1973-03-08 |
| US3546160A (en) | 1970-12-08 |
| AT282968B (de) | 1970-07-27 |
| DE1694539A1 (de) | 1971-09-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8339 | Ceased/non-payment of the annual fee |