DE1669702C3 - Verfahren zur Herstellung von schlagzähen thermoplastischen Polyamid-Formmassen - Google Patents
Verfahren zur Herstellung von schlagzähen thermoplastischen Polyamid-FormmassenInfo
- Publication number
- DE1669702C3 DE1669702C3 DE1669702A DE1669702A DE1669702C3 DE 1669702 C3 DE1669702 C3 DE 1669702C3 DE 1669702 A DE1669702 A DE 1669702A DE 1669702 A DE1669702 A DE 1669702A DE 1669702 C3 DE1669702 C3 DE 1669702C3
- Authority
- DE
- Germany
- Prior art keywords
- polyamides
- polyamide
- acids
- weight
- impact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000465 moulding Methods 0.000 title claims description 18
- 150000001875 compounds Chemical class 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000000034 method Methods 0.000 title claims description 7
- 229920006345 thermoplastic polyamide Polymers 0.000 title 1
- 239000004952 Polyamide Substances 0.000 claims description 23
- 229920002647 polyamide Polymers 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 239000004014 plasticizer Substances 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 4
- -1 hexamethylenediamine Chemical class 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 3
- 230000002087 whitening effect Effects 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims 5
- 229920003023 plastic Polymers 0.000 claims 5
- 230000002378 acidificating effect Effects 0.000 claims 4
- 150000007513 acids Chemical class 0.000 claims 4
- 150000001336 alkenes Chemical class 0.000 claims 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 150000004985 diamines Chemical class 0.000 claims 3
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims 1
- YQPCHPBGAALCRT-UHFFFAOYSA-N 2-[1-(carboxymethyl)cyclohexyl]acetic acid Chemical compound OC(=O)CC1(CC(O)=O)CCCCC1 YQPCHPBGAALCRT-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical class NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000003776 cleavage reaction Methods 0.000 claims 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical class OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 239000004413 injection moulding compound Substances 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 238000004898 kneading Methods 0.000 claims 1
- 150000003951 lactams Chemical class 0.000 claims 1
- 125000005395 methacrylic acid group Chemical group 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 239000012778 molding material Substances 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical group 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 230000007017 scission Effects 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 150000003460 sulfonic acids Chemical class 0.000 claims 1
- 150000003509 tertiary alcohols Chemical class 0.000 claims 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
- 238000009757 thermoplastic moulding Methods 0.000 claims 1
- 238000004804 winding Methods 0.000 claims 1
- 229920002292 Nylon 6 Polymers 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 125000005521 carbonamide group Chemical group 0.000 description 3
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US735961A US3700751A (en) | 1967-06-19 | 1968-06-11 | Molding material from polyamide and acrylic ester of a t-aliphatic alcohol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB0093077 | 1967-06-19 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1669702A1 DE1669702A1 (de) | 1971-03-25 |
| DE1669702B2 DE1669702B2 (de) | 1973-05-30 |
| DE1669702C3 true DE1669702C3 (de) | 1975-10-23 |
Family
ID=6986752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1669702A Expired DE1669702C3 (de) | 1967-06-19 | 1967-06-19 | Verfahren zur Herstellung von schlagzähen thermoplastischen Polyamid-Formmassen |
Country Status (7)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2654168A1 (de) * | 1976-11-30 | 1978-06-01 | Bayer Ag | Polyamidlegierungen |
| DE2713537A1 (de) * | 1977-03-26 | 1978-09-28 | Bayer Ag | Polyamidlegierungen |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2454770C2 (de) * | 1974-11-19 | 1985-10-03 | Basf Ag, 6700 Ludwigshafen | Thermoplastische Formmassen mit erhöhter Schlagzähigkeit |
| DE3220380A1 (de) * | 1982-05-29 | 1983-12-01 | Basf Ag, 6700 Ludwigshafen | Schlagzaehe polyamid-formmassen |
| DE3700330A1 (de) * | 1987-01-08 | 1988-07-21 | Basf Ag | Schlagzaehe polyamid-formmassen |
| DE3806271A1 (de) * | 1988-02-27 | 1989-09-07 | Basf Ag | Thermoplastische formmassen auf der basis von polyamiden und ethylencopolymerisaten |
| CN113017195B (zh) * | 2021-04-13 | 2022-07-12 | 温州市三盟鞋业有限公司 | 一种耐撕裂鞋跟钉及其制备工艺 |
-
1967
- 1967-06-19 DE DE1669702A patent/DE1669702C3/de not_active Expired
-
1968
- 1968-06-13 FR FR1568637D patent/FR1568637A/fr not_active Expired
- 1968-06-17 NL NL6808502.A patent/NL156428B/xx not_active IP Right Cessation
- 1968-06-18 BE BE716760D patent/BE716760A/xx not_active IP Right Cessation
- 1968-06-18 GB GB1238070D patent/GB1238070A/en not_active Expired
- 1968-06-18 CH CH902068A patent/CH532625A/de not_active IP Right Cessation
- 1968-06-19 AT AT587968A patent/AT280595B/de not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2654168A1 (de) * | 1976-11-30 | 1978-06-01 | Bayer Ag | Polyamidlegierungen |
| DE2713537A1 (de) * | 1977-03-26 | 1978-09-28 | Bayer Ag | Polyamidlegierungen |
Also Published As
| Publication number | Publication date |
|---|---|
| BE716760A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-12-18 |
| DE1669702A1 (de) | 1971-03-25 |
| NL156428B (nl) | 1978-04-17 |
| DE1669702B2 (de) | 1973-05-30 |
| GB1238070A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1971-07-07 |
| NL6808502A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-12-20 |
| FR1568637A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1969-05-23 |
| AT280595B (de) | 1970-04-27 |
| CH532625A (de) | 1973-01-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0001241B1 (de) | Schlagzähe Polyamidmasse und deren Verwendung in Formkörpern | |
| EP0000583B2 (de) | Hochschlagzähe Polyamidmasse und deren Verwendung in Formkörpern | |
| DE2907729C2 (de) | Verstärkungs- oder Füllstoffmaterial enthaltende Polyäthylenterephthalat-Zusammensetzung | |
| DE3752169T2 (de) | Stabilisierte Polyacetalzubereitungen | |
| DE2454770C2 (de) | Thermoplastische Formmassen mit erhöhter Schlagzähigkeit | |
| US3472916A (en) | Copolymers of ethylene and alkyl acrylates as plasticizers in polycarbonamide resins | |
| EP0096264A1 (de) | Schlagzähe Polyamid-Formmassen | |
| DE1694296B2 (de) | Herstellung von formstabilen und schlagfesten Spritzgußteilen aus PoIyäthylenterephthalat-Gemi sehen | |
| DE2447101B2 (de) | Glasfaserverstärktes Polyamidharze- . Formmaterial | |
| EP0523445A2 (de) | Thermoplastische Formmassen aus semikristallinem und amorphem Polyamid, deren Verwendung und Verfahren zu ihrer Herstellung | |
| CH634087A5 (de) | Thermoplastische formmassen auf der basis von polyamiden aus omega-aminocarbonsaeuren bzw. lactamen mit mehr als 10 kohlenstoffatomen mit hoher flexibilitaet und kaelteschlagzaehigkeit. | |
| CH630657A5 (de) | Hochschlagzaehe thermoplastische formmasse. | |
| EP0112542B1 (de) | Polyamide mit verminderter Wasseraufnahme | |
| DE2612011A1 (de) | Verfahren zur herstellung von schlagzaehen thermoplastischen formmassen | |
| EP0388583B1 (de) | In der Kälte schlagzähe thermoplastische Formmassen | |
| DE3804392A1 (de) | Fuellstoffhaltige polyamid-formmassen mit verbesserter oberflaeche und lackierbarkeit | |
| DE1669702C3 (de) | Verfahren zur Herstellung von schlagzähen thermoplastischen Polyamid-Formmassen | |
| US3700751A (en) | Molding material from polyamide and acrylic ester of a t-aliphatic alcohol | |
| EP0194523B1 (de) | Hydrophobierte, leichtfliessende thermoplastische Polyamide | |
| US3475368A (en) | Plasticized nylon composition and process for making the same | |
| EP0591731B1 (de) | Fliessfähige Polyamidformmassen | |
| EP0291796B1 (de) | Schlagzähe Polyamidformmassen | |
| DE2654168C2 (de) | Polyamidlegierungen | |
| EP0275518B1 (de) | Thermoplastische Formmassen auf der Basis von Polyamiden und Ethylencopolymerisaten | |
| EP0204118B1 (de) | Mit Monoisocyanaten modifizierte Polyamide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8330 | Complete disclaimer |