DE1668922C3 - Verfahren zur Herstellung von Äthylenaminen - Google Patents
Verfahren zur Herstellung von ÄthylenaminenInfo
- Publication number
- DE1668922C3 DE1668922C3 DE1668922A DEJ0035793A DE1668922C3 DE 1668922 C3 DE1668922 C3 DE 1668922C3 DE 1668922 A DE1668922 A DE 1668922A DE J0035793 A DEJ0035793 A DE J0035793A DE 1668922 C3 DE1668922 C3 DE 1668922C3
- Authority
- DE
- Germany
- Prior art keywords
- reactor
- concentration
- product
- ammonia
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 19
- -1 ethylene amines Chemical class 0.000 title claims description 9
- 239000005977 Ethylene Substances 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 39
- 229910021529 ammonia Inorganic materials 0.000 claims description 17
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 16
- 150000001412 amines Chemical class 0.000 claims description 16
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 18
- 238000002474 experimental method Methods 0.000 description 15
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 14
- 229940012017 ethylenediamine Drugs 0.000 description 14
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 9
- 238000009835 boiling Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- VKPPFDPXZWFDFA-UHFFFAOYSA-N 2-chloroethanamine Chemical compound NCCCl VKPPFDPXZWFDFA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical group NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
- C07C209/08—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Water Treatments (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61936767A | 1967-02-28 | 1967-02-28 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1668922A1 DE1668922A1 (de) | 1972-03-16 |
| DE1668922B2 DE1668922B2 (de) | 1977-10-20 |
| DE1668922C3 true DE1668922C3 (de) | 1978-06-15 |
Family
ID=24481602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1668922A Expired DE1668922C3 (de) | 1967-02-28 | 1968-02-27 | Verfahren zur Herstellung von Äthylenaminen |
Country Status (5)
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3742060A (en) * | 1969-11-24 | 1973-06-26 | Gulf Research Development Co | Preparation of amines |
| US4404405A (en) * | 1981-09-30 | 1983-09-13 | Union Carbide Corporation | Process for the preparation of polyethylene polyamines |
| JPS5920322A (ja) * | 1982-07-28 | 1984-02-02 | Toyo Soda Mfg Co Ltd | ポリエチレンポリアミンの製造方法 |
| US4806234A (en) * | 1987-11-02 | 1989-02-21 | Phillips Petroleum Company | Ore flotation |
| US4990656A (en) * | 1987-11-02 | 1991-02-05 | Phillips Petroleum Company | Polyamine substituted dithiocarbamate and process for producing the same |
| US5904829A (en) * | 1997-08-18 | 1999-05-18 | Ppg Industries, Inc. | Method of converting amine hydrohalide into free amine |
| US5906722A (en) * | 1997-08-18 | 1999-05-25 | Ppg Industries, Inc. | Method of converting amine hydrohalide into free amine |
| US5882501A (en) * | 1997-08-18 | 1999-03-16 | Ppg Industries, Inc. | Method of converting amine hydrohalide into free amine |
| US5900133A (en) * | 1997-08-18 | 1999-05-04 | Ppg Industries, Inc. | Method of converting amine hydrohalide into free amine |
| DE102005048552A1 (de) * | 2005-10-11 | 2007-04-12 | Basf Ag | Verfahren zur Herstellung von Ethylenaminen |
| CN103130653A (zh) * | 2011-11-22 | 2013-06-05 | 上海氯碱化工股份有限公司 | 管式反应器连续生产乙烯胺的方法及装置 |
| KR20150055924A (ko) * | 2013-11-14 | 2015-05-22 | 한화케미칼 주식회사 | 에틸렌아민류의 제조 방법 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2769841A (en) * | 1953-12-23 | 1956-11-06 | Dow Chemical Co | Production of ethylene polyamines |
-
1967
- 1967-02-28 US US619367A patent/US3484488A/en not_active Expired - Lifetime
-
1968
- 1968-02-13 GB GB7147/68A patent/GB1195781A/en not_active Expired
- 1968-02-23 FR FR1555162D patent/FR1555162A/fr not_active Expired
- 1968-02-26 BE BE711259D patent/BE711259A/xx unknown
- 1968-02-27 DE DE1668922A patent/DE1668922C3/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1195781A (en) | 1970-06-24 |
| DE1668922B2 (de) | 1977-10-20 |
| BE711259A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-08-26 |
| DE1668922A1 (de) | 1972-03-16 |
| FR1555162A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1969-01-24 |
| US3484488A (en) | 1969-12-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| EHJ | Ceased/non-payment of the annual fee |