DE1568208B - - Google Patents

Info

Publication number

DE1568208B

DE1568208B DE1568208B DE 1568208 B DE1568208 B DE 1568208B DE 1568208 B DE1568208 B DE 1568208B

Authority

DE

Germany

Prior art keywords

acrylonitrile

hydrogen peroxide

reaction

reaction mixture

glycidamide

Prior art date

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

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• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 33
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 19
• 238000006243 chemical reaction Methods 0.000 claims 12
• 239000011541 reaction mixture Substances 0.000 claims 8
• FMAZQSYXRGRESX-UHFFFAOYSA-N Glycidamide Chemical compound NC(=O)C1CO1 FMAZQSYXRGRESX-UHFFFAOYSA-N 0.000 claims 7
• 238000000034 method Methods 0.000 claims 7
• 239000000243 solution Substances 0.000 claims 6
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical class O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
• 150000002978 peroxides Chemical class 0.000 claims 5
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 3
• 238000004519 manufacturing process Methods 0.000 claims 3
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
• 239000007864 aqueous solution Substances 0.000 claims 2
• 239000007900 aqueous suspension Substances 0.000 claims 2
• 229910052799 carbon Inorganic materials 0.000 claims 2
• 229910052739 hydrogen Inorganic materials 0.000 claims 2
• 239000001257 hydrogen Substances 0.000 claims 2
• 238000002844 melting Methods 0.000 claims 2
• 230000008018 melting Effects 0.000 claims 2
• 238000002156 mixing Methods 0.000 claims 2
• 150000002825 nitriles Chemical class 0.000 claims 2
• HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 2
• 239000000126 substance Substances 0.000 claims 2
• PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
• -1 acrylic acid nitrile Chemical class 0.000 claims 1
• 238000013459 approach Methods 0.000 claims 1
• 239000001569 carbon dioxide Substances 0.000 claims 1
• 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
• 239000003245 coal Substances 0.000 claims 1
• 238000001816 cooling Methods 0.000 claims 1
• 239000012043 crude product Substances 0.000 claims 1
• 230000006378 damage Effects 0.000 claims 1
• 238000004821 distillation Methods 0.000 claims 1
• 239000012153 distilled water Substances 0.000 claims 1
• 239000000975 dye Substances 0.000 claims 1
• 238000004817 gas chromatography Methods 0.000 claims 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
• 229910052751 metal Inorganic materials 0.000 claims 1
• 239000002184 metal Substances 0.000 claims 1
• 229910044991 metal oxide Inorganic materials 0.000 claims 1
• 150000004706 metal oxides Chemical class 0.000 claims 1
• 229910052763 palladium Inorganic materials 0.000 claims 1
• 239000004014 plasticizer Substances 0.000 claims 1
• 239000011814 protection agent Substances 0.000 claims 1
• 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
• 235000011152 sodium sulphate Nutrition 0.000 claims 1
• 239000002904 solvent Substances 0.000 claims 1
• 238000003756 stirring Methods 0.000 claims 1
• 239000004753 textile Substances 0.000 claims 1
• 238000004448 titration Methods 0.000 claims 1
• 238000010626 work up procedure Methods 0.000 claims 1