DE1542452C3 - Verfahren zur Herstellung von Katalysatoren für die Niederdruck Polymerisation von Olefinen - Google Patents
Verfahren zur Herstellung von Katalysatoren für die Niederdruck Polymerisation von OlefinenInfo
- Publication number
- DE1542452C3 DE1542452C3 DE1542452A DE1542452A DE1542452C3 DE 1542452 C3 DE1542452 C3 DE 1542452C3 DE 1542452 A DE1542452 A DE 1542452A DE 1542452 A DE1542452 A DE 1542452A DE 1542452 C3 DE1542452 C3 DE 1542452C3
- Authority
- DE
- Germany
- Prior art keywords
- compound
- transition metal
- reaction
- catalysts
- hydroxychloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 19
- 238000006116 polymerization reaction Methods 0.000 title claims description 18
- 150000001336 alkenes Chemical class 0.000 title claims description 8
- 238000002360 preparation method Methods 0.000 title claims description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 150000003623 transition metal compounds Chemical class 0.000 claims description 15
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 10
- -1 transition metal compound Hydroxy chloride Chemical class 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000011282 treatment Methods 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 230000004913 activation Effects 0.000 claims description 2
- 230000007717 exclusion Effects 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims 5
- 150000003624 transition metals Chemical class 0.000 claims 5
- 239000011777 magnesium Substances 0.000 claims 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 3
- 239000007795 chemical reaction product Substances 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 229910052749 magnesium Inorganic materials 0.000 claims 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 claims 3
- 230000007704 transition Effects 0.000 claims 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 239000000969 carrier Substances 0.000 claims 2
- 150000002736 metal compounds Chemical class 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 150000004703 alkoxides Chemical class 0.000 claims 1
- 239000002981 blocking agent Substances 0.000 claims 1
- 238000001311 chemical methods and process Methods 0.000 claims 1
- 239000012084 conversion product Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 229910000765 intermetallic Inorganic materials 0.000 claims 1
- 125000002524 organometallic group Chemical group 0.000 claims 1
- 239000002574 poison Substances 0.000 claims 1
- 231100000614 poison Toxicity 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 230000004043 responsiveness Effects 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 238000002474 experimental method Methods 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 239000011949 solid catalyst Substances 0.000 description 5
- 239000011343 solid material Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
- C01G1/06—Halides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR22396A FR1448320A (fr) | 1965-06-25 | 1965-06-25 | Procédé perfectionné pour la préparation d'un composé solide d'un métal de transition et produits obtenus selon ce procédé |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1542452A1 DE1542452A1 (de) | 1970-04-16 |
| DE1542452B2 DE1542452B2 (de) | 1973-03-29 |
| DE1542452C3 true DE1542452C3 (de) | 1973-10-25 |
Family
ID=8583143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1542452A Expired DE1542452C3 (de) | 1965-06-25 | 1966-04-02 | Verfahren zur Herstellung von Katalysatoren für die Niederdruck Polymerisation von Olefinen |
Country Status (8)
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL137056C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1966-10-21 | |||
| US4056668A (en) * | 1966-10-21 | 1977-11-01 | Solvay & Cie | Process for the polymerization and copolymerization of olefins with a solid support catalyst |
| NL137364C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-03-22 | |||
| NL135327C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-06-20 | Solvay | ||
| DE1770730C2 (de) * | 1968-06-27 | 1982-05-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Homo- und Mischpolymerisation von Äthylen |
| DE1795197C2 (de) * | 1968-08-21 | 1981-08-13 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Polymerisation von -Olefinen |
| DK133012C (da) * | 1968-11-21 | 1976-08-09 | Montedison Spa | Katalysator til polymerisation af alkener |
| YU35844B (en) * | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| GB1275641A (en) * | 1969-01-06 | 1972-05-24 | Solvay | Catalysts for the polymerisation and copolymerisation of olefins |
| SE366484B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1969-01-10 | 1974-04-29 | Montedison Spa | |
| NL162921B (nl) * | 1969-01-10 | 1980-02-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de polymerisatie van alkenen-1. |
| DK157556C (da) * | 1969-03-24 | 1990-06-11 | Montedison Spa | Katalysatorer til polymerisation af ethylen og dettes blandinger med alkener |
| US4016344A (en) * | 1971-07-01 | 1977-04-05 | Gulf Research & Development Company | Olefin polymerization catalyst |
| US3888789A (en) * | 1972-12-15 | 1975-06-10 | Universal Oil Prod Co | Preparation of polymerization catalyst systems |
| US3875075A (en) * | 1973-04-16 | 1975-04-01 | Standard Oil Co | Catalyst for the polymerization of ethylene and terminal olefins |
| NO155245C (no) * | 1978-07-24 | 1987-03-04 | Phillips Petroleum Co | Fremgangsmaate til fremstilling av en polymerisasjonskatalysator og anvendelse av katalysatoren til alkenpolymerisering. |
| US4363746A (en) * | 1979-05-29 | 1982-12-14 | Phillips Petroleum Company | Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst |
| IT1132230B (it) * | 1980-07-24 | 1986-06-25 | Anic Spa | Procedimento per la produzione dell'enzima colesterolo-esterasi e per idrolisi degli esteri con acidi grassi del colesterolo mediante l'impiego dell'enzima stesso |
| US4394291A (en) * | 1981-03-04 | 1983-07-19 | Phillips Petroleum Company | Polyolefin polymerization process and catalyst |
| US4391736A (en) * | 1981-06-05 | 1983-07-05 | Phillips Petroleum Company | Alpha-olefin polymerization |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3400110A (en) * | 1963-08-01 | 1968-09-03 | Solvay | Polymerization of olefins in the presence of a catalyst comprising an organometallic compound and the reaction product of a transition metal compound and a hydroxychloride of a bivalent metal |
| FR1375127A (fr) * | 1963-08-01 | 1964-10-16 | Solvay | Procédé pour la polymérisation et la copolymérisation des oléfines |
-
0
- NL NL135604D patent/NL135604C/xx active
-
1965
- 1965-06-25 FR FR22396A patent/FR1448320A/fr not_active Expired
-
1966
- 1966-04-02 DE DE1542452A patent/DE1542452C3/de not_active Expired
- 1966-05-02 US US546537A patent/US3454547A/en not_active Expired - Lifetime
- 1966-05-11 CH CH684366A patent/CH462790A/fr unknown
- 1966-05-26 ES ES0327186A patent/ES327186A1/es not_active Expired
- 1966-05-27 NL NL6607398A patent/NL6607398A/xx unknown
- 1966-05-31 BE BE681805D patent/BE681805A/xx not_active IP Right Cessation
- 1966-06-22 GB GB27952/66A patent/GB1085679A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL135604C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| CH462790A (fr) | 1968-09-30 |
| GB1085679A (en) | 1967-10-04 |
| FR1448320A (fr) | 1966-08-05 |
| BE681805A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1966-11-30 |
| DE1542452B2 (de) | 1973-03-29 |
| NL6607398A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1966-12-27 |
| DE1542452A1 (de) | 1970-04-16 |
| US3454547A (en) | 1969-07-08 |
| ES327186A1 (es) | 1967-07-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SH | Request for examination between 03.10.1968 and 22.04.1971 | ||
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 |