DE10206796A1 - Sunscreen composition, comprises separate water-in-oil emulsion and lipophilic or aqueous phases, at least one of which is not transparent or translucent - Google Patents

Abstract

Two-phase sunscreen composition comprises a water-in-oil (w/o) emulsion phase and a lipophilic or aqueous phase and includes a w/o emulsifier and a UV filter, where at least one of the phases is not transparent or translucent. An Independent claim is also included for production of a sunscreen composition as above by preparing the two phases in separate containers and then combining them.

Description

The present invention relates to two-phase cosmetic and / or dermatological Sunscreen preparations, one phase of which is a W / O emulsion and the other Phase contain a lipophilic or aqueous phase, with at least one phase is not transparent and / or translucent, and their use.

The trend away from the paleness towards "healthy, sporty brown skin" is unbroken for years. To achieve this, people put their skin on the Solar radiation, since this is pigment formation in the sense of melanin formation causes. However, the ultraviolet radiation from sunlight also has one harmful effects on the skin. In addition to acute damage (sunburn) occur Long-term damage such as an increased risk of developing skin cancer if excessive Irradiation with light from the UVB range (wavelength: 280-320 nm). The excessive exposure to UVB and UVA radiation (wavelength: 320-400 nm) in addition to a weakening of the elastic and collagen fibers of the Connective tissue. This leads to numerous phototoxic and photoallergic Reactions and results in premature skin aging.

A number of light protection filter substances were therefore used to protect the skin developed that can be used in cosmetic preparations. This UVA and UVB filters are in the form of positive lists like that in most industrialized countries Appendix 7 of the Cosmetics Ordinance summarized.

In order to be able to estimate the effectiveness of the sun protection filters for the skin, Schulze introduced the sun protection factor (SPF or LF) and sun protection factor (SF) in the 1950s. It is defined as follows:

The UV light protection filters approved for cosmetic applications also include compounds of the triazine framework:

Another class of UV light protection filters is derived from benzimidazole sulfonic acids:

A third class of advantageous light protection filters is based on the structural element of benzotriazole:

Sun protection preparations are usually offered in the form of emulsions. However, these homogeneous preparations are increasingly considered by consumers felt monotonous and boring. The possibilities of using these formulations visually However, making them more attractive is limited. They are increasingly Consumers are also tired of the flood of ready-to-use finished products and of that The desire is animated to prepare the cosmetic formulations yourself then do "something good". To this innovative drive of consumers Two-phase cosmetic preparations are increasingly being accommodated offered by the customer by simply shaking it into a homogeneous emulsion can transfer and then apply. To give customers the joy of "themselves To mix "before each application, the homogeneous emulsion must be however, separate again in a reasonable time. Only in this way can the instinct of play Consumers met and the enjoyment of the application can be guaranteed. Not finally, the two-phase products enable completely new types of optical Design options.

Unfortunately, according to the current state of the art, there are only transparent two-phase ones cosmetic sunscreen preparations based on one lipophilic and one each formulate aqueous phase. However, these have the disadvantage that they are in the Usually segregate too quickly after homogenization by shaking. In addition, it has not hitherto been possible to use pigmentary organic and / or inorganic UV Use filters in these preparations to ensure high sun protection factors to reach. Last but not least, these products do not awaken them due to their appearance Association of care and UV protection, usually with white-colored preparations of creamy consistency.

It was therefore the object of the present invention to address the shortcomings of the prior art Technique to eliminate and two-phase cosmetic and / or dermatological Develop sunscreen preparations with high UV protection on the basis of which at least one phase is not transparent.

• a) eine W/O-Emulsion,
• b) eine lipophile oder wässrige Phase,
• c) mindestens einen W/O-Emulgator,
• d) mindestens eine organische und/oder anorganische UV-Filtersubstanz,

dadurch gekennzeichnet, dass mindestens eine Phase nicht durchsichtig und/oder durchscheinend ist. Surprisingly, the object is achieved by containing two-phase cosmetic and / or dermatological sunscreen preparations

• a) a W / O emulsion,
• b) a lipophilic or aqueous phase,
• c) at least one W / O emulsifier,
• d) at least one organic and / or inorganic UV filter substance,

characterized in that at least one phase is not transparent and / or translucent.

According to the invention, W / O stands for water-in-oil emulsion or emulsifier.

Two-phase cosmetic and / or dermatological sun protection preparation in the sense of the present invention means that the W / O emulsion and the lipophilic or aqueous phase are separately layered on top of each other. The W / O emulsion is at considered this as a phase, although of course to those skilled in the art it is known that W / O emulsions per se consist of two homogenized with each other Phases are formed. The W / O emulsion is long-term stable. This means that it is not to separate even over a longer period (months, years) or phase separation comes. The peculiarity of the present Invention, which is to be expressed with the term two-phase, lies now in that the W / O emulsion and the lipophilic separately present as the second phase or the aqueous phase is separated from one another and is layered on top of one another. These two For example, phases or layers can be briefly divided into one by shaking emulsify homogeneous emulsion, which is not stable in the long term, but itself rather over a period of minutes, hours or days Separate the layered W / O emulsion and lipophilic or aqueous phase.

It is advantageous according to the invention if the amount of lipophilic or aqueous phase 5 to 95% by volume, in particular 10 to 90% by volume based on the total volume of the formulation.

The sun protection preparations according to the invention are characterized in that one or more W / O emulsifiers in a concentration of 0.1 to 3% by weight contain.

With the help of the emulsifier concentration, the separation rate of the adjust the preparation according to the invention homogenized by shaking.

According to the invention, the W / O emulsifier (s) can be selected from the group of silicone emulsifiers. Advantageously from the group of alkyl methicon copolyols and / or alkyl dimethicone copolyols, in particular from the group of compounds which are characterized by the following chemical structure:


in which X and Y are selected independently of one another from the group H (hydrogen) and the branched and unbranched alkyl groups, acyl groups and alkoxy groups with 1-24 carbon atoms, p represents a number from 0-200, q represents a number from 1-40, and r represents a number from 1-100.

An example for particularly advantageous in the sense of the present invention Silicone emulsifiers used are dimethicone copolyols, which are available from society Goldschmidt AG under the trade names ABIL® B 8842, ABIL® B 8843, ABIL® B 8847, ABIL® B 8851, ABIL® B 8852, ABIL® B 8863, ABIL® B 8873 and ABIL® B 88183 are sold.

Another example for particularly advantageous in the sense of the present invention The surfactant used is the cetyl dimethicone copolyol, which by the company Th. Goldschmidt AG under the trade name ABIL® EM 90 on sale is.

Another example for particularly advantageous in the sense of the present invention The surfactant used is cyclomethicone Dimethicone copolyol, which is sold by Th. Goldschmidt AG under the trade name ABIL® EM 97 is sold.

The emulsifier lauryl methicone copolyol has also proven to be particularly advantageous highlighted, which under the trade name Dow Corning® 5200 Formulation Aid from Dow Corning Ltd. is available.

Another advantageous silicone emulsifier is 'octyl dimethicone ethoxy glucoside' Wacker company.

Furthermore, the W / O emulsifier (s) according to the invention can preferably be selected from the following group:
Sorbitan stearate, sorbitan oleate, lecithin, glyceryl alcoholate, lanolin, ozokerite, hydrogenated castor oil, glyceryl isostearate, polyglyceryl 3 oleate, wool wax acid mixtures, wool wax alcohol mixtures, pentaerythrithyl isostearate, polyglyceryl 3-di-glucosostearate, polyglyceryl-3-diisostylate-isolate, isocyanate-methyl-isocyanate-4-diisostearate-4 Hexyl laurate, acrylate / C _10-30 alkyl acrylate crosspolymer, sorbitan isostearate, poloxamer 101, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl 4-dipolyhydroxystearate, PEG-30-dipolyhydroxystearate, diisostearoylpolyglyceryl-3-diisostearate, polyglyceryl-3-diisostearate, 3 dioleate.

The following combinations of lipophilic components and emulsifiers are advantageous:
Sorbitan oleate in a mixture with hydrogenated castor oil, beeswax (Cera alba) and stearic acid, sodium dihydroxycetylphosphate in a mixture with isopropylhydroxycetyl ether, methyl glucose dioleate in a mixture with hydroxystearate and beeswax, mineral oil in a mixture with petrolatum, ozokerite, glyceryl oleate, petroleum alcohol, ricinolated alcohol, with lanolin alcohol and lanolin alcohol , Glyceryl isostearate and polyglyceryl-3-oleate, sorbitan oleate in a mixture with PEG-2 hydrogenated castor oil, ozokerite and hydrogenated castor oil, sorbitan isostearate in a mixture with PEG-2 hydrogenated castor oil.

According to the invention, these are particularly advantageous as W / O emulsifiers Cetyldimethicone copolyol, glyceryl isostearate, polyglyceryl-2-dipolyhydroxystearate and / or PEG-30 dipolyhydroxystearate used.

Embodiments of the invention which are advantageous according to the invention can also contain additional O / W emulsifiers (oil-in-water emulsifiers) as coemulsifiers. According to the invention, the O / W emulsifier (s) are preferably selected from the following group:
Ceteareth-20, trilaureth-4 phosphate, cetyl phosphate, cetearyl sulfate, PEG-40 stearate, PEG-100 stearate, Polysorbate-60 and / or Polysorbate-65.

As O / W emulsifiers which are particularly advantageous according to the invention - as coemulsifiers - glyceryl stearate citrate, cetearyl sulfate, ethoxylated fatty acids (PEG-40 stearate, PEG-100 stearate) and / or phosphate emulsifiers (e.g. cetyl phosphate) are used.

It is also advantageous in the sense of the present invention, cosmetic and to create dermatological preparations, the main purpose of which is not to protect against Sunlight is, but still contains other UV protection substances contain. So z. B. in day care products or make-up products usually UV-A or UV-B filter substances incorporated. Also provide UV protection substances, as well as antioxidants and, if desired, preservatives, one effective protection of the preparations themselves against spoilage.

Accordingly, the preparations contain within the meaning of the present invention preferably at least one UV-A, UV-B and / or broadband filter substance and / or at least one inorganic pigment reflecting and / or absorbing UV light. The Formulations may, although not necessary, also include an or contain several organic and / or inorganic pigments as UV filter substances, which can be in the water and / or oil phase.

According to the invention are all embodiments in which the UV protective substances exclusively in one of the two phases or in both phases of the Preparations according to the invention are.

The preparations according to the invention can also advantageously be in the form of so-called oil-free cosmetic or dermatological preparations are present, which a water phase and at least one UV filter substance that is liquid at room temperature included as another phase.

Particularly advantageous UV filter substances liquid at room temperature in the sense of present invention are homomenthyl salicylate (INCI: homosalate), 2-ethylhexyl-2- cyano-3,3-diphenyl acrylate (INCI: octocrylene), 2-ethylhexyl-2-hydroxybenzoate (2-ethylhexyl salicylate, octyl salicylate, INCI: ethylhexyl salicylate) and esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester (2-ethylhexyl-4-methoxycinnamate, INCI: ethylhexyl methoxycinnamate) and isopentyl 4-methoxycinnamate (isopentyl-4- methoxycinnamate, INCI: Isoamyl p-methoxycinnamate) and polymeric UV filters like that (3- (4- (2,2-bis-ethoxycarbonylvinyl) phenoxy) propenyl) -methylsiloxan / dimethylsiloxane Copolymer, which, for example, at Hoffmann-La Roche under the Trade name Parsol SLX is available.

Preferred inorganic pigments are metal oxides and / or other metal compounds which are sparingly soluble or insoluble in water, in particular oxides of titanium (TiO ₂ ), zinc (ZnO), iron (e.g. Fe ₂ O ₃ ), zirconium (ZrO ₂ ), silicon ( SiO ₂ ), manganese (e.g. MnO), aluminum (Al ₂ O ₃ ), cerium (e.g. Ce ₂ O ₃ ), mixed oxides of the corresponding metals as well as mixtures of such oxides and the sulfate of barium (BaSO ₄ ).

For the purposes of the present invention, the pigments can also advantageously be in the form commercially available oily or aqueous predispersions are used. These predispersions can advantageously be dispersing agents and / or Solubilization promoters may be added.

According to the invention, the pigments can advantageously be surface-treated ("coated") be, for example, a hydrophilic, amphiphilic or hydrophobic character should be formed or preserved. This surface treatment can be in it exist that the pigments according to known methods with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer. The various surface coatings can be used in the sense of the present Invention also contain water.

Inorganic surface coatings in the sense of the present invention can consist of aluminum oxide (Al ₂ O ₃ ), aluminum hydroxide Al (OH) ₃ , or aluminum oxide hydrate (also: alumina, CAS no .: 1333-84-2), sodium hexametaphosphate (NaPO ₃ ) ₆ , sodium metaphosphate (NaPO ₃ ) _n , silicon dioxide (SiO ₂ ) (also: silica, CAS No .: 7631-86-9), barium sulfate (BaSO ₄ ) or iron oxide (Fe ₂ O ₃ ). These inorganic surface coatings can occur alone, in combination and / or in combination with organic coating materials.

Organic surface coatings in the sense of the present invention can consist of vegetable or animal aluminum stearate, vegetable or animal Stearic acid, lauric acid, dimethylpolysiloxane (also: Dimethicone), methylpolysiloxane (Methicone), Simethicone (a mixture of dimethylpolysiloxane with a average chain length of 200 to 350 dimethylsiloxane units and silica gel) or Alginic acid. These organic surface coatings can be used alone, in combination and / or occur in combination with inorganic coating materials.

Zinc oxide particles and predispersions of zinc oxide particles suitable according to the invention are available under the following trade names from the listed companies:

Suitable titanium dioxide particles and predispersions of titanium dioxide particles are available under the following trade names from the companies listed:

Advantageous UV-A filter substances in the sense of the present invention are Dibenzoylmethane derivatives, especially the 4- (tert-butyl) -4'-methoxydibenzoylmethane (CAS no. 70356-09-1), which is available from Givaudan under the Parsol® 1789 brand and from Merck under the trade name Eusolex® 9020 is sold.

• - Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure und ihre Salze, besonders die entsprechenden Natrium-, Kalium- oder Triethanolammonium-Salze, insbesondere das Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure-bis-natriumsalz mit der INCI-Bezeichnung Disodium Phenyl Dibenzimidazole Tetrasulfonate (CAS-Nr.: 180898-37-7), welches beispielsweise unter der Handelsbezeichnung Neo Heliopan AP bei Haarmann & Reimer erhältlich ist;
• - Salze der 2-Phenylbenzimidazol-5-sulfonsäure, wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz sowie die Sulfonsäure selbst mit der INCI Bezeichnung Phenylbenzimidazole Sulfonsäure (CAS.-Nr. 27503-81-7), welches beispielsweise unter der Handelsbezeichnung Eusolex 232 bei Merck oder unter Neo Heliopan Hydro bei Haarmann & Reimer erhältlich ist;
• - 1,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)-Benzol (auch: 3,3'-(1,4-Phenylendimethylene)-bis-(7,7-dimethyl-2-oxo-bicyclo-[2.2.1]hept-1-ylmethan Sulfonsäure) und dessen Salze (besonders die entprechenden 10-Sulfato-verbindungen, insbesondere das entsprechende Natrium-, Kalium- oder Triethanolammonium-Salz), das auch als Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) bezeichnet wird. Benzol-1,4- di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) hat die INCI-Bezeichnung Terephtalidene Dicampher Sulfonsäure (CAS.-Nr.: 90457-82-2) und ist beispielsweise unter dem Handelsnamen Mexoryl SX von der Fa. Chimex erhältlich;
• - Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z. B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bomylidenmethyl)sulfonsäure und deren Salze.
• - Hydroxybenzophenon-Derivate, wie z. B. 2-(4-Diethylamino-2-hydroxybenzoyl)- benzoic acid hexylester, welches beispielsweise von der Firma BASF unter dem Handelsnamen Uvinul® A Plus erhältlich ist.
• - Benzoxazol-Derivate, wie z. B. das 2,4-bis-[5-1(dimethylpropyl)benzossazol-2-yl-(4- phenyl)-imino]-6-(2-ethylhexyl)-imino-1,3,5-triazin (CAS-Nr.: 288254-16-0), welches beispielsweise von der Firma 3 V Sigma erhältlich ist.

Advantageous further UV filter substances in the sense of the present invention are sulfonated, water-soluble UV filters, such as. B .:

• - Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and its salts, especially the corresponding sodium, potassium or triethanolammonium salts, especially the phenylene-1,4 -bis- (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt with the INCI name Disodium Phenyl Dibenzimidazole Tetrasulfonate (CAS No .: 180898-37-7), which, for example, under the Trade name Neo Heliopan AP is available from Haarmann &Reimer;
• - Salts of 2-phenylbenzimidazole-5-sulfonic acid, such as its sodium, potassium or triethanolammonium salt and the sulfonic acid itself with the INCI name phenylbenzimidazole sulfonic acid (CAS No. 27503-81-7), which, for example, under the Trade name Eusolex 232 is available from Merck or under Neo Heliopan Hydro from Haarmann &Reimer;
• - 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) -benzene (also: 3,3 '- (1,4-phenylenedimethylene) -bis- (7,7-dimethyl-2-oxo- bicyclo- [2.2.1] hept-1-ylmethane sulfonic acid) and its salts (especially the corresponding 10-sulfato compounds, especially the corresponding sodium, potassium or triethanolammonium salt), which is also called benzene-1,4- di (2-oxo-3-bornylidenemethyl-10-sulfonic acid) Benzene-1,4-di (2-oxo-3-bornylidenemethyl-10-sulfonic acid) has the INCI name Terephtalidene Dicampher Sulfonic Acid (CAS no .: 90457-82-2) and is available, for example, under the trade name Mexoryl SX from Chimex;
• - Sulfonic acid derivatives of 3-benzylidene camphor, such as. B. 4- (2-oxo-3-bornylidene methyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidene methyl) sulfonic acid and salts thereof.
• - Hydroxybenzophenone derivatives, such as. B. 2- (4-Diethylamino-2-hydroxybenzoyl) benzoic acid hexyl ester, which is available for example from BASF under the trade name Uvinul® A Plus.
• - Benzoxazole derivatives, such as. B. 2,4-bis- [5-1 (dimethylpropyl) benzossazol-2-yl- (4-phenyl) imino] -6- (2-ethylhexyl) imino-1,3,5-triazine (CAS -No .: 288254-16-0), which is available for example from the company 3 V Sigma.

Advantageous UV filter substances in the sense of the present invention are furthermore so-called broadband filters, d. H. Filter substances that contain both UV-A and UV-B radiation absorb.

• - 2,4-Bis-{[4-(2-Ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), welches unter der Handelsbezeichnung Tinosorb® S bei der CiBA-Chemikalien GmbH erhältlich ist;
• - Diethylhexylbutylamidotriazon (INCI: Diethylhexyl Butamido Triazone), welches unter der Handelsbezeichnung UVASORB HEB bei Sigma 3 V erhältlich ist;
• - 4,4',4"-(1,3,5-Triazin-2,4,6-triyltriimino)-tris-benzoesäure-tris(2-ethylhexylester), auch: 2,4,6-Tris-[anilino-(p-carbo-2'-ethyl-1'-hexyloxy)]-1,3,5-triazin (INCI: Ethylhexyl Triazone), welches von der BASF Aktiengesellschaft unter der Warenbezeichnung UVINUL® T 150 vertrieben wird.

Advantageous broadband filters or UV-B filter substances are, for example, triazine derivatives, such as, for. B.

• - 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine ), which is available under the trade name Tinosorb® S from CiBA-Chemicals GmbH;
• - Diethylhexylbutylamidotriazon (INCI: Diethylhexyl Butamido Triazone), which is available under the trade name UVASORB HEB from Sigma 3 V;
• - 4,4 ', 4 "- (1,3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester), also: 2,4,6-tris [anilino - (p-carbo-2'-ethyl-1'-hexyloxy)] - 1,3,5-triazine (INCI: Ethylhexyl Triazone), which is sold by BASF Aktiengesellschaft under the trade name UVINUL® T 150.

An advantageous broadband filter in the sense of the present invention is also that 2,2'-methylene-bis- (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol), CAS No .: 103597-45-1, which is sold under the trade name Tinosorb® M by CIBA- Chemicals GmbH is available.

An advantageous broadband filter in the sense of the present invention is that 2- (2H-benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [(trimethylsilyl) oxy] disiloxanyl] propyl] phenol (CAS No .: 155633-54-8) with the INCI name Drometrizole Trisiloxanes, which is sold under the trade name Mexoryl® XL by Chimex is available.

The other UV filter substances can be oil-soluble or water-soluble.

• - 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3- Benzylidencampher;
• - 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2- ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• - Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2- Hydroxy-4-methoxy-4'-methylbenzophenon, 2,2'-Dihydroxy-4-methoxybenzophenon
• - sowie an Polymere gebundene UV-Filter.
• - 3-(4-(2,2-bis Ethoxycarbonylvinyl)-phenoxy)propenyl)-methoxysiloxan/Dimethylsiloxan- Copolymer welches beispielsweise unter der Handelsbezeichnung Parsol® SLX bei Hoffmann La Roche erhältlich ist.

Advantageous oil-soluble UV-B and / or broadband filter substances in the sense of the present invention are e.g. B .:

• - 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• - 4-aminobenzoic acid derivatives, preferably 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester, 4- (dimethylamino) benzoic acid amyl ester;
• - Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone
• - As well as UV filters bound to polymers.
• - 3- (4- (2,2-bis-ethoxycarbonylvinyl) phenoxy) propenyl) methoxysiloxane / dimethylsiloxane copolymer which is available, for example, under the trade name Parsol® SLX from Hoffmann La Roche.

Particularly advantageous preparations in the sense of the present invention are: are characterized by a high or very high UV-A and / or UV-B protection, in addition to the filter substance (s) according to the invention preferably also contain further UV-A and / or broadband filters, especially dibenzoylmethane derivatives [for example the 4- (tert-butyl) -4'-methoxydibenzoylmethane], phenylene-1,4-bis- (2- benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and / or its salts, the 2- (4-diethylamino-2- hydroxybenzoyl) benzoic acid hexyl ester and / or the 2,4-bis - {[4- (2-ethylhexyloxy) -2- hydroxy] phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine and / or the 2,4-bis- [5- 1 (dimethylpropyl) benzossazol-2-yl- (4-phenyl) imino] -6- (2-ethylhexyl) imino-1,3,5-triazine, individually or in any combination with each other.

The list of UV filters mentioned, used in the sense of the present invention of course, should not be limiting.

The UV light protection filters advantageous according to the invention are preferably in one Concentration of 0.1 to 30% by weight, especially in a concentration of 0.5 up to 15% by weight, based on the total weight of the formulation.

The sunscreen preparations advantageous according to the invention contain as organic Filters asymmetrically substituted triazines, bisimidazylates and / or benzotriazoles.

According to the cosmetic and / or dermatological Light protection formulations are composed as usual and the cosmetic and / or dermatological light protection, also for the treatment, care and cleaning of the skin and / or the hair and as a make-up product in decorative cosmetics.

The cosmetic and dermatological preparations are used according to the invention in the usual manner for cosmetics on the skin and / or the hair sufficient amount applied.

The cosmetic and dermatological preparations according to the invention can Contain cosmetic auxiliaries, as is usually the case in such preparations be used, e.g. B. preservatives, preservation aids, complexing agents, Bactericides, perfumes, substances to prevent or increase foaming, Dyes, pigments that have a coloring effect, thickeners, moisturizing and / or moisturizing substances, fillers that improve the feeling on the skin, fats, Oils, waxes or other common ingredients of a cosmetic or dermatological formulation such as alcohols, polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

An additional level of antioxidants is generally preferred. According to the invention can be used as cheap antioxidants all for cosmetic and / or dermatological Applications suitable or customary antioxidants can be used.

The antioxidants are advantageously selected from the group consisting of amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D, L-carnosine, D- Carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. As dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and Lauryl, palmitoyl, oleyl, γ-linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (e.g. B. Buthioninsulfoximine, Homocysteinsulfoximin, Buthioninsulf one, penta-, hexa-, heptathioninsulfoximine) in very low tolerable doses (e.g. B. pmol to µmol / kg), also (metal) chelators (e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acid, Bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g. γ-linolenic acid, linoleic acid, oleic acid), folic acid and their derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and derivatives (e.g. Ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (e.g. vitamin E acetate), vitamin A and derivatives (vitamin A palmitate) and coniferyl benzoate of benzoic acid, rutinic acid and its derivatives, α- (z. B. ZnO, ZnSO ₄₎ rutin, ferulic acid, Furfurylidenglucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, Nordihydroguajakharzsäure, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and derivatives thereof, mannose and derivatives thereof, zinc and derivatives thereof Selenium and its derivatives (e.g. B. selenomethionine), stilbenes and their derivatives (for example stilbene oxide, trans-stilbene oxide) and the derivatives suitable according to the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these active substances.

The amount of the aforementioned antioxidants (one or more compounds) in the Preparations is preferably 0.001 to 10% by weight, particularly preferably 0.05-7% by weight, in particular 0.1-5 wt .-%, based on the total weight of the Preparation.

If vitamin E and / or its derivatives are the antioxidant (s) advantageous, their respective concentrations in the range of 0.001-5% by weight, based on the total weight of the formulation.

If vitamin A, or vitamin A derivatives, or carotenes or their derivatives, the or the antioxidants are advantageous, their respective concentrations from the Range of 0.001-5% by weight based on the total weight of the formulation choose.

In addition, selected recipes according to the invention are suitable, which e.g. B. known anti-wrinkle active ingredients such as flavone glycosides (in particular α-glycosyl rutin), Contain coenzyme Q10, vitamin E and / or derivatives and the like, in particular advantageous for the prophylaxis and treatment of cosmetic or dermatological Skin changes, such as z. B. occur with skin aging (e.g. wrinkles and fine lines). Farther they are advantageous against the appearance of dry or rough skin.

If α-glycosylrutin is the antioxidant, the respective one is advantageous Concentrations in the range of 0.001-5 wt .-%, based on the Total weight of the formulation to choose.

An aqueous phase present as a second, independent water phase or the Water phase of the W / O emulsion of the preparations according to the invention can be advantageous Contain conventional cosmetic auxiliaries, such as alcohols, in particular such a low C number, preferably ethanol and / or isopropanol, diols or polyols low C number and their ethers, preferably propylene glycol, glycerol, Butylene glycol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, Propylene glycol monomethyl, monoethyl or monobutyl ether, Diethylene glycol monomethyl or monoethyl ether and analog products, polymers, Foam stabilizers, electrolytes and in particular one or more thickeners, which one or which can advantageously be selected from the group silicon dioxide, Aluminum silicates, polysaccharides or their derivatives, e.g. B. hyaluronic acid, Xanthan gum, hydroxypropylmethyl cellulose, particularly advantageous from the group of Polyacrylates, preferably a polyacrylate from the group of the so-called carbopols [from from Bf. Goodrich], for example carbopole types 980, 981, 1382, 2984, 5984, ETD 2020, ETD 2050, Ultrez 10, each individually or in combination.

The preparations according to the invention can also advantageously be used Contain self-tanning substances, such as dihydroxyacteon and / or melanin derivatives in Concentrations of 1 wt .-% up to 10 wt .-%, based on the total weight of the Preparation.

The preparations according to the invention can also advantageously be repellents for Protection against mosquitoes, ticks and spiders and the like included. Z are advantageous. B. N, N-diethyl-3-methylbenzamide (trade name: Meta-delphene, "DEET"), Dimethyl phthalate (trade name: Palatinol M, DMP) and in particular 3- (N-n-butyl- N-acetylamino) propionic acid ethyl ester (under the trade name Insekt Repellent® 3535 available from Merck). The repellents can be used both individually and in Combination can be used.

Substances or mixtures of substances are referred to as moisturizers, which are cosmetic or give dermatological preparations the property after application or Distribute the release of moisture from the horny layer on the skin surface (also reduce transepidermal water loss (TEWL) and / or hydration To influence the horny layer positively.

Advantageous moisturizers in the sense of the present invention are, for example Glycerol, lactic acid and / or lactates, especially sodium lactate, butylene glycol, Propylene glycol, Biosaccaride Gum-1, Glycine soy, ethylhexyloxyglycerin, pyrrolidone carboxylic acid and urea. Furthermore, it is particularly advantageous to polymerize moisturizers from the Group of water-soluble and / or water-swellable and / or with the help of To use water gellable polysaccharides. Are particularly advantageous for example hyaluronic acid, chitosan and / or a fucose-rich polysaccharide, which in the Chemical Abstracts filed under registration number 178463-23-5 and z. B. under the name Fucogel®1000 from the company SOLABIA S.A. is available. Moisturizers can also be used advantageously as anti-wrinkle agents for prophylaxis and Treatment of cosmetic or dermatological skin changes, such as z. B. at the Skin aging occur.

The cosmetic or dermatological preparations according to the invention can further advantageous, although not mandatory, contain fillers which, for. B. the further improve the sensory and cosmetic properties of the formulations and for example, to create or intensify a velvety or silky feeling on the skin. Advantageous fillers for the purposes of the present invention are starch and starch derivatives (such as z. B. tapioca starch, distarch phosphate, aluminum or sodium starch octenyl succinate and the like), pigments that have neither primarily UV filter nor coloring effect have (such as boron nitride etc.) and / or Aerosile® (CAS No. 7631-86-9).

A second lipophilic phase, which is an independent oil phase, or the oil phase of the W / O emulsion of the formulations according to the invention is advantageously chosen from the Group of polar oils, for example from the group of lecithins and Fatty acid triglycerides, specifically the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 8 to 24, especially 12 to 18 carbon atoms. The fatty acid triglycerides can be advantageous, for example are selected from the group of synthetic, semi-synthetic and natural oils, such as B. cocoglyceride, olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, Palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, Macadamia nut oil and the like.

According to the invention, z. B. natural animal and waxes of vegetable origin, such as beeswax and other insect waxes, as well Berry wax, shea butter and / or lanolin (wool wax).

Further advantageous polar oil components can be used for the purposes of the present invention furthermore selected from the group of the esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 3 to 30 C atoms and saturated and / or unsaturated, branched and / or unbranched Alcohols with a chain length of 3 to 30 carbon atoms and from the group of esters aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms. Such Ester oils can then advantageously be selected from the group octyl palmitate, Octyl cocoate, octyl isostearate, octyldodeceyl myristate, octyldodekanol, cetearyl isononanoate, Isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n- Hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyilaurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, Stearyl heptanoate, oleyl oleate, olerlerucate, erucyl oleate, erucylerucate, tridecyl stearate, Tridecyltrimellitat, as well as synthetic, semi-synthetic and natural mixtures of such esters, such as z. B. Jojoba oil.

Furthermore, the oil phases can advantageously be selected from the group of dialkyl ethers and dialkyl carbonates, z. B. dicaprylyl ether (Cetiol OE) and / or Dicaprylyl carbonate, for example that under the trade name Cetiol CC at Cognis available.

It is further preferred that the oil component or components from the group isoeikosan, neopentyl glycol diheptanoate, propylene glycol dicaprylate / dicaprate, caprylic / capric / diglyceryl succinate, butylene glycol dicaprylate / dicaprate, C _12-13 alkyl lactate, di-C 12- aryl triethyl, di-C _12-13 aryl Hexacaprylate / hexacaprate, propylene glycol monoisostearate, tricaprylin, dimethyl isosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of C _12-15 alkyl benzoate or consists entirely of this.

Advantageous oil components are also e.g. B. butyl octyl salicylate (for example, under Hallbrite BHB available from CP Hall), Hexadecyl benzoate and butyl octyl benzoate and mixtures thereof (Hallstar AB) and / or Diethylhexyl naphthalate (Hallbrite TQ or Corapan TQ from H&R).

Any mixtures of such oil and wax components are also advantageous in To use the sense of the present invention.

The oil phases can also advantageously also contain non-polar oils, for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, especially mineral oil, petroleum jelly (petrolatum), Paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes and Isohexadecane. Among the polyolefins, polydecenes are the preferred substances.

The oil phases can also advantageously have a cyclic or linear content Have silicone oils or consist entirely of such oils, although preferred will, in addition to the silicone oil or oils, an additional content of others To use oil phase components.

Silicone oils are high-molecular synthetic polymeric compounds in which silicon atoms are linked in a chain and / or network-like manner via oxygen atoms and the remaining valences of silicon by hydrocarbon residues (mostly methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated. The silicone oils are systematically referred to as polyorganosiloxanes. The methyl-substituted polyorganosiloxanes, which are the most important compounds of this group in terms of quantity and are characterized by the following structural formula


are also known as polydimethylsiloxane or dimethicone (INCI). Dimethicone is available in different chain lengths or with different molecular weights.

Particularly advantageous polyorganosiloxanes for the purposes of the present invention are for example dimethylpolysiloxanes [poly (dimethylsiloxane)], which, for example, under the trade names Abil 10 to 10,000 are available from Th. Goldschmidt. Phenylmethylpolysiloxanes (INCI: Phenyl Dimethicone, Phenyl) are also advantageous Trimethicones), cyclic silicones (octamethylcyclotetrasiloxane or Decamethylcyclopentasiloxane), which according to INCI are also called cyclomethicones, amino-modified silicones (INCI: Amodimethicone) and silicone waxes, e.g. B. polysiloxane-polyalkylene Copolymers (INCI: Stearyl Dimethicone and Cetyl Dimethicone) and Dialkoxydimethylpolysiloxane (Stearoxy Dimethicone and Behenoxy Stearyl Dimethicone), which as various Abil-Wax types are available from Th. Goldschmidt. But others too Silicone oils are to be used advantageously for the purposes of the present invention, for example Cetyldimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, Poly (methylphenylsiloxane).

• a) Siloxanelastomere, welche die Einheiten R₂SiO und RSiO_1,5 und/oder R₃SiO_0,5 und/oder SiO₂ enthalten,
  wobei die einzelnen Reste R jeweils unabhängig voneinander Wasserstoff, C_1-24 -Alkyl (wie beispielsweise Methyl, Ethyl, Propyl) oder Aryl (wie beispielsweise Phenyl oder Tolyl), Alkenyl (wie beispielsweise Vinyl) bedeuten und das Gewichtsverhältnis der Einheiten R₂SiO zu RSiO_1,5 aus dem Bereich von 1 : 1 bis 30 : 1 gewählt wird;
• b) Siloxanelastomere, welche in Silikonöl unlöslich und quellfähig sind, die durch die Additionsreaktion eines Organopolysiloxans (1), das siliciumbebundenen Wasserstoff enthält, mit einem Organopolysiloxan (2), das ungesättigte aliphatische Gruppen enthält, erhältlich sind,
  wobei die verwendeten Mengenateile so gewählt werden, daß die Menge des Wasserstoffes des Organopolysiloxans (1) oder der ungesättigten aliphatischen Gruppen des Organopolysiloxans (2)
  • - im Bereich von 1 bis 20 mol-% liegt, wenn das Organopolysiloxan nicht cyclisch ist und
  • - im Bereich von 1 bis 50 mol-% liegt, wenn das Organopolysiloxan cyclisch ist.

The preparations according to the invention can furthermore advantageously contain one or more substances from the following group of siloxane elastomers, for example in order to increase the water resistance and / or the sun protection factor of the products:

• a) siloxane elastomers which contain the units R ₂ SiO and RSiO _1.5 and / or R ₃ SiO _0.5 and / or SiO ₂ ,
  where the individual radicals R each independently represent hydrogen, C _1-24 alkyl (such as methyl, ethyl, propyl) or aryl (such as phenyl or tolyl), alkenyl (such as vinyl) and the weight ratio of the units R ₂ SiO RSiO _{1.5 is selected} from the range from 1: 1 to 30: 1;
• b) siloxane elastomers which are insoluble and swellable in silicone oil, which can be obtained by the addition reaction of an organopolysiloxane (1) which contains silicon-bonded hydrogen with an organopolysiloxane (2) which contains unsaturated aliphatic groups,
  the proportions used are chosen so that the amount of hydrogen of the organopolysiloxane (1) or the unsaturated aliphatic groups of the organopolysiloxane (2)
  • - Is in the range of 1 to 20 mol% when the organopolysiloxane is not cyclic and
  • - Is in the range of 1 to 50 mol% when the organopolysiloxane is cyclic.

The siloxane elastomer (s) are advantageous in the sense of the present invention In the form of spherical powder or in the form of gels.

Advantageous siloxane elastomers in the form of spherical powder according to the invention are those with the INCI name Dimethicone / Vinyl Dimethicone Crosspolymer, for example that of DOW CORNING under the trade name DOW CORNING 9506 powder available.

It is particularly preferred if the siloxane elastomer is combined with oils Hydrocarbons of animal and / or vegetable origin, synthetic oils, synthetic esters, synthetic ethers or mixtures thereof is used.

It is very particularly preferred if the siloxane elastomer in combination with unbranched silicone oils that are liquid or pasty at room temperature or cyclic Silicone oils or their mixtures is used. Are particularly advantageous Organopolysiloxane elastomers with the INCI name Dimethicone / Polysilicone-11, whole especially the Gransil types GCM, GCM-5, available from Grant Industries Inc. DMG-6, CSE Gel, PM-Gel, LTX, ININ Gel, AM-18 Gel and / or DMCM-5.

It is very exceptionally preferred if the siloxane elastomer is in the form of a gel from siloxane elastomer and a lipid phase is used, the content of the Siloxane elastomer in the gel is 1 to 80% by weight, preferably 0.1 to 60% by weight, each based on the total weight of the gel.

It is advantageous for the purposes of the present invention to determine the total amount of Siloxane elastomers (active content) in the range from 0.01 to 10% by weight, advantageously from 0.1 up to 5% by weight, based in each case on the total weight of the formulation.

The cosmetic and dermatological preparations according to the invention can contain dyes and / or color pigments, in particular if they are in the form of decorative cosmetics. According to the invention, the individual phases of the preparation can advantageously be colored differently. Embodiments of the invention in which only one of the two phases is colored are also advantageous according to the invention. The dyes and pigments can be selected from the corresponding positive list in the Cosmetics Ordinance or the EC list of cosmetic colorants. In most cases, they are identical to the colorants approved for food. Advantageous color pigments are, for example, titanium dioxide, mica, iron oxides (for example Fe ₂ O ₃ , Fe ₃ O ₄ , FeO (OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chrome oxide green, ultramarine blue and / or manganese violet. It is particularly advantageous to choose the dyes and / or color pigments from the Rowe Color Index, 3rd edition, Society of Dyers and Colorists, Bradford, England, 1971.

If the formulations according to the invention are in the form of products which applied to the face, it is beneficial to dye one or more Select substances from the following group: 2,4-dihydroxyazobenzene, 1- (2'-chloro-4'-nitro-1'- phenylazo) -2-hydroxynaphthalene, ceres red, 2- (sulfo-1-naphthylazo) -1-naphthol-4-sulfonic acid, calcium salt of 2-hydroxy-1,2'-azonaphthalene-1'-sulfonic acid, calcium and Barium salts of 1- (2-sulfo-4-methyl-1-phenylazo) -2-naphthylcarboxylic acid, calcium salt of 1- (2-sulfo-1-naphthylazo) -2-hydroxynaphthalene-3-carboxylic acid, aluminum salt of 1- (4- Sulfo-1-phenylazo) -2-naphthol-6-sulfonic acid, aluminum salt of 1- (4-sulfo-1-naphthylazo) -2-naphthol-3,6-disulfonic acid, 1- (4-sulfo-1-naphthylazo) -2-naphthol-6,8-disulfonic acid, Aluminum salt of 4- (4-Sulfo-1-phenylazo) -1- (4-sulfophenyl) -5-hydroxy-pyrazolone-3-carboxylic acid, aluminum and zirconium salts of 4,5-dibromofluorescein, aluminum and Zirconium salts of 2,4,5,7-tetrabromofluorescein, 3 ', 4', 5 ', 6'-tetrachloro-2,4,5,7-tetrabromofluorescein and its aluminum salt, aluminum salt of 2,4,5,7-tetraiodofluorescein, Aluminum salt of quinophthalone disulfonic acid, aluminum salt of indigo disulfonic acid, red and black iron oxide (CIN: 77 491 (red) and 77 499 (black)), iron oxide hydrate (CIN: 77 492), manganese ammonium diphosphate and titanium dioxide.

Also advantageous are oil-soluble natural dyes, such as. B. paprika extracts, β-carotene or Cochineal.

• 1. Natürliche Perlglanzpigmente, wie z. B.
  • - "Fischsilber" (Guanin/Hypoxanthin-Mischkristalle aus Fischschuppen) und
  • - "Perlmutt" (vermahlene Muschelschalen)
• 2. Monokristalline Perlglanzpigmente wie z. B. Bismuthoxychlorid (BiOCl)
• 3. Schicht-Substrat Pigmente: z. B. Glimmer/Metalloxid.

Formulations containing pearlescent pigments are also advantageous for the purposes of the present invention. The types of pearlescent pigments listed below are particularly preferred:

• 1. Natural pearlescent pigments, such as. B.
  • - "fish silver" (guanine / hypoxanthine mixed crystals from fish scales) and
  • - "mother-of-pearl" (ground mussel shells)
• 2. Monocrystalline pearlescent pigments such as B. Bismuth oxychloride (BiOCl)
• 3. Layer-substrate pigments: e.g. B. mica / metal oxide.

Pearlescent pigments are based, for example, on powdered pigments or Castor oil dispersions of bismuth oxychloride and / or titanium dioxide and bismuth oxychloride and / or Titanium dioxide on mica. Particularly advantageous is e.g. B. under the CIN 77163 listed gloss pigment.

The following pearlescent pigment types based on mica / metal oxide are also advantageous:

Z are particularly preferred. B. from the Merck company under the trade names Pearlescent pigments available from Timiron, Colorona or Dichrona.

The list of the pearlescent pigments mentioned is of course not intended to be limiting. Pearlescent pigments which are advantageous in the sense of the present invention can be obtained in numerous ways known per se. For example, other substrates besides mica can be coated with other metal oxides, such as. B. silica and the like. Z are advantageous. B. with TiO ₂ and Fe ₂ O ₃ coated SiO ₂ particles ("Ronaspheren"), which are sold by Merck and are particularly suitable for the optical reduction of fine wrinkles.

It can also be beneficial to move entirely towards a substrate such as mica dispense. Iron pearlescent pigments are particularly preferred, which without the Be made using mica. Such pigments are e.g. B. under the Trade names Sicopearl Kupfer 1000 available from BASF.

Also particularly advantageous are effect pigments, which under the Trade name Metasomes Standard / Glitter in different colors (yello, red, green, blue) from are available from Flora Tech. The glitter particles are mixed with them various auxiliaries and dyes (such as the dyes with the color Index (CI) numbers 19140, 77007, 77289, 77491).

The dyes and pigments can be present both individually and in combination and be mutually coated with one another, with different Coating thicknesses are generally caused by different color effects. The The total amount of dyes and coloring pigments is advantageous from the range from Z. B. 0.1% by weight to 30% by weight, preferably from 0.5 to 15% by weight, chosen in particular from 1.0 to 10% by weight, in each case based on the total weight of the Preparations.

Advantageous preservatives in the sense of the present invention are For example, formaldehyde releasers (such as DMDM hydantoin, which, for example, under the trade name Glydant ™ is available from Lonza), Iodopropylbutylcarbamate (e.g. those sold under the trade names Glycacil-L, Glycacil-S by Lonza available and / or Dekaben LMB from Jan Dekker), parabens (i.e. p-hydroxybenzoic acid alkyl esters, such as methyl, ethyl, propyl and / or butyl paraben), Phenoxyethanol, ethanol, benzoic acid and the like. This usually includes Preservation system according to the invention also advantageously preservation aids such as for example octoxyglycerin, glycine soy etc.

Advantageous complexing agents in the sense of the present invention are, for example EDTA, [S, S] -Ethylenediamindisuccinat (EDDS), which, for example, under the Trade name Octaquest is available from Octel, Pentasodium ethylenediaminetetramethylene phosphonate, which, for. B. under the trade name Dequest 2046 from the Monsanto is available and / or iminodisuccinic acid, which u. a. from Bayer AG under the trade names Iminodisuccinat VP OC 370 (approx. 30% solution) and Baypure CX 100 is firmly available.

According to the invention, the storage of the invention is also advantageous Preparation in clear and / or translucent packaging containers.

The viscosities of the preparations according to the invention are advantageously between watery thin (0-700 mPas) up to a flowable consistency (700-4000 mPas). The very low viscosity preparations could be used in containers with pump systems Spray or be used as a fluid.

In the two-phase preparation according to the invention, it is possible to choose which phase floats on top of each other in a simple way that is obvious to the expert establish. Because, as is well known, the layer sequence of the individual phases of their density depends. This can be done by varying the concentration of individuals Adjust components of the respective phases almost arbitrarily. Furthermore, the Experts know, of course, that the rate of segregation of the two Phases after the preparation has been homogenized by shaking over the choice the density of the individual phases can be set, whereby the principle applies that the separation rate with the difference in density of the two phases increases. Since the compositions of both phases vary according to the invention leaves, are also the layer sequence and the segregation rate variable according to the invention.

According to the invention, the preparations according to the invention can advantageously be used as a cream or lotion can be used. Their use in the form of a spray, for. B. one Pump sprays advantageous according to the invention, the preparations advantageously can also be foamed.

In addition, the use of W / O emulsifiers for adjustment is according to the invention the phase separation speed of homogenized sunscreen preparations and the use of preparations according to the invention as sunscreens, after homogenizing by shaking.

The preparations according to the invention are particularly preferred according to the invention stored and presented in transparent or translucent packaging.

In principle, 2 methods are suitable for the preparations according to the invention Production.

Procedure 1 Step 1

Production of a W / O emulsion by a process common to the person skilled in the art.

2nd step

Production of an aqueous or lipophilic phase by optionally heating up to 90 ° C to dissolve more difficult to dissolve substances.

3rd step

Mix the W / O emulsion produced in step 1 with that in step 2 prepared aqueous or lipophilic phase. Mixing can be done easily Stir until strong homogenization take place. For this, the W / O emulsion in placed in a sufficiently large container and then the aqueous - or the lipophilic Phase added with stirring. By the strength of the stirring or also Homogenization can influence the segregation rate. By becomes a high energy input as opposed to a low energy input (simple stirring) the complete separation of the two phases is slowed down. It it is advisable to have a sufficiently good one before filling into the final containers Ensure homogenization. Or else both phases will be in succession (layered) filled in the final containers. With this type of filling, i. d. R. the volumes of the individual phases can be set even more precisely.

In this process, the phase-volume for the 2-phase product Ratios of the W / O emulsion to the aqueous or lipophilic phase in one Ratio from 1: 3 to 3: 1 can be set.

Procedure 2

In this method, the two-phase system is operated according to a method known to the person skilled in the art Process for producing a W / O emulsion. After manufacturing begins the aqueous or lipophilic phase changes within 1 sec. to 1 hour deposit.

In contrast to method 1, for this production the W / O- Emulsion set the phase-volume ratio. I.e. for a 2-phase system consisting of a W / O emulsion and a lipophilic phase which over this Process to be produced, the total oil phase concentration can be between 10 and 95 wt .-%, in particular between 15 and 90 wt .-%. For a 2-phase System consisting of a W / O emulsion and an aqueous phase which over this process is to be produced, the total water phase Concentration between 10 and 95% by weight, in particular between 15 and 90% by weight lie. For filling 2-phase systems that are manufactured using process 2 have been a particularly good homogenization before Bottling or, on the other hand, bottling with stirring. With both filling variants it must be ensured that a constant phase volume ratio is maintained.

The following examples are intended to illustrate the present invention without restricting it. Unless otherwise stated, all quantities, proportions and percentages are based on the weight and the total amount or on the total weight of the preparations. EXAMPLES 1. Two-phase systems produced by process 1 with a W / O emulsion and a lipophilic phase

The respective phases (a) and (b) can be in phase-volume ratios of 3: 1 to 1: 3 to be mixed with each other. The separation speed until a clear separation the phases, is between 1 minute and 1 hour.

The 2-phase systems produced in this way can be used as very low-viscosity sprays or also as low-viscosity / free-flowing lotions / fluids. 2. 2-phase systems produced by method 1 with a W / O emulsion and an aqueous phase

The respective phases (a) and (b) can be in phase-volume ratios of 3: 1 to 1: 3 to be mixed with each other. The separation speed until a clear separation the phases, is between 1 minute and 1 hour.

The 2-phase systems produced in this way can be used as very low-viscosity sprays or also as low-viscosity / free-flowing lotions / fluids. 3. 2-phase systems manufactured according to method 2 with a W / O emulsion and an aqueous phase

The 2-phase systems produced in this way - using method 2 - can be used as very low-viscosity sprays or also as low-viscosity / free-flowing lotions / fluids. 4. 2-phase systems produced by method 2 with a W / O emulsion and a lipophilic phase

The 2-phase systems produced in this way - using method 2 - can be very useful low-viscosity sprays or as low-viscosity / free-flowing lotions / fluids be used.

Claims (10)

1. Containing two-phase cosmetic and / or dermatological sunscreen preparations a) a W / O emulsion, b) a lipophilic or aqueous phase, c) at least one W / O emulsifier, d) at least one organic and / or inorganic UV filter, thereby characterized in that at least one phase is not transparent and / or translucent. 2. Sun protection preparations according to claim 1, characterized in that they a lipophilic or aqueous phase in an amount of 5 to 95% by volume, in particular 10 to 90 vol .-%, based on the total volume of the formulation contain. 3. Sun protection preparations according to claim 1 or 2, characterized in that one or more W / O emulsifiers in a concentration of 0.1 to 3 % By weight included. 4. Sun protection preparations according to claim 1 to 3, characterized in that as W / O emulsifiers cetyldimethicone copolyol, glyceryl isostearate, polyglyceryl-2 dipolyhydroxystearate and / or PEG-30 dipolyhydroxystearate can be used. 5. Sun protection preparations according to claim 1 to 4, characterized in that triazines, bisimidazylates substituted asymmetrically as organic UV filters, Benzotriazoles and / or UV filters that are liquid at room temperature are used. 6. Sun protection preparations according to claim 1 to 5, characterized in that titanium dioxide and / or zinc oxide is used as the inorganic-pigmentary UV filter. 7. Sun protection preparations according to claim 1 to 6, characterized in that they are kept in clear and / or translucent packaging containers and be applied out of these. 8. Process for the preparation of sunscreen preparations according to one of the preceding claims, characterized in that the W / O emulsion and the lipophilic or aqueous phase initially in separate vessels prepared and then combined. 9. Use of W / O emulsifiers according to one of the preceding claims Setting the phase separation speed of homogenized Sun protection preparations according to one of claims 1 to 7. 10. Use of sun protection preparations according to one of the preceding Claims as a sunscreen after it is homogenized by shaking has been.