DE102020123739A1 - Lithium-kalium-element-oxid-verbindungen als li-supraionenleiter, festelektrolyt und beschichtungsschicht für lithiummetallbatterie und lithiumionenbatterie - Google Patents

Lithium-kalium-element-oxid-verbindungen als li-supraionenleiter, festelektrolyt und beschichtungsschicht für lithiummetallbatterie und lithiumionenbatterie Download PDF

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Publication number
DE102020123739A1
DE102020123739A1 DE102020123739.1A DE102020123739A DE102020123739A1 DE 102020123739 A1 DE102020123739 A1 DE 102020123739A1 DE 102020123739 A DE102020123739 A DE 102020123739A DE 102020123739 A1 DE102020123739 A1 DE 102020123739A1
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Germany
Prior art keywords
solid
lithium ion
state lithium
formula
lithium
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Pending
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DE102020123739.1A
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German (de)
English (en)
Inventor
Yifei Mo
Qiang Bai
Xingfeng HE
Chen Ling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
University of Maryland College Park
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Toyota Motor Engineering and Manufacturing North America Inc
University of Maryland College Park
Toyota Engineering and Manufacturing North America Inc
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Application filed by Toyota Motor Engineering and Manufacturing North America Inc, University of Maryland College Park, Toyota Engineering and Manufacturing North America Inc filed Critical Toyota Motor Engineering and Manufacturing North America Inc
Publication of DE102020123739A1 publication Critical patent/DE102020123739A1/de
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G30/00—Compounds of antimony
    • C01G30/006—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G30/00—Compounds of antimony
    • C01G30/02—Antimonates; Antimonites
    • C01G30/026—Antimonates; Antimonites containing at least two metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C01G33/006—Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00—Compounds of tungsten
    • C01G41/006—Compounds containing tungsten, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/002—Compounds containing ruthenium, rhodium, palladium, osmium, iridium or platinum, with or without oxygen or hydrogen, and containing two or more other elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/665—Composites
    • H01M4/667—Composites in the form of layers, e.g. coatings
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Conductive Materials (AREA)
DE102020123739.1A 2019-09-13 2020-09-11 Lithium-kalium-element-oxid-verbindungen als li-supraionenleiter, festelektrolyt und beschichtungsschicht für lithiummetallbatterie und lithiumionenbatterie Pending DE102020123739A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/570,888 US11018375B2 (en) 2019-09-13 2019-09-13 Lithium potassium element oxide compounds as Li super-ionic conductor, solid electrolyte and coating layer for lithium metal battery and lithium-ion battery
US16/570,888 2019-09-13

Publications (1)

Publication Number Publication Date
DE102020123739A1 true DE102020123739A1 (de) 2021-03-18

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Application Number Title Priority Date Filing Date
DE102020123739.1A Pending DE102020123739A1 (de) 2019-09-13 2020-09-11 Lithium-kalium-element-oxid-verbindungen als li-supraionenleiter, festelektrolyt und beschichtungsschicht für lithiummetallbatterie und lithiumionenbatterie

Country Status (4)

Country Link
US (1) US11018375B2 (https=)
JP (1) JP7582823B2 (https=)
CN (1) CN112510252B (https=)
DE (1) DE102020123739A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112186242B (zh) * 2020-09-29 2022-04-15 清华大学深圳国际研究生院 无机氧化物固态电解质材料、制备方法、锂离子电池及电子装置
JP2023080494A (ja) * 2021-11-30 2023-06-09 国立大学法人信州大学 イリジウム固溶マンガン酸化物

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668593A (en) 1986-08-29 1987-05-26 Eltron Research, Inc. Solvated electron lithium electrode for high energy density battery
DE102004010892B3 (de) 2004-03-06 2005-11-24 Christian-Albrechts-Universität Zu Kiel Chemisch stabiler fester Lithiumionenleiter
US7300722B2 (en) * 2005-04-11 2007-11-27 The Gillette Company Lithium battery containing bismuth metal oxide
US8784512B2 (en) 2007-08-13 2014-07-22 University Of Virginia Patent Foundation Thin film battery synthesis by directed vapor deposition
JP5298558B2 (ja) * 2007-08-30 2013-09-25 ソニー株式会社 二次電池用負極およびその製造方法、二次電池およびその製造方法、ならびに電子機器
JP5525388B2 (ja) 2009-09-03 2014-06-18 日本碍子株式会社 セラミックス材料及びその製造方法
DE102011013018B3 (de) 2011-03-04 2012-03-22 Schott Ag Lithiumionen leitende Glaskeramik und Verwendung der Glaskeramik
CN103000934B (zh) * 2011-09-16 2016-03-30 苏州宝时得电动工具有限公司 锂硫电池
JPWO2013137224A1 (ja) * 2012-03-15 2015-08-03 株式会社村田製作所 全固体電池およびその製造方法
US9070950B2 (en) 2012-03-26 2015-06-30 Semiconductor Energy Laboratory Co., Ltd. Power storage element, manufacturing method thereof, and power storage device
CN104078647B (zh) * 2013-03-27 2016-04-27 比亚迪股份有限公司 一种锂离子电池负极及其制备方法和锂离子电池
JP2016091995A (ja) 2014-10-30 2016-05-23 株式会社デンソー リチウム空気電池及びリチウム空気電池装置
US10446872B2 (en) * 2015-08-04 2019-10-15 Samsung Electronics Co., Ltd. Solid electrolyte and lithium battery including the same
DE102015217749A1 (de) * 2015-09-16 2017-03-16 Robert Bosch Gmbh Beschichtetes Kathodenaktivmaterial für eine Batteriezelle
FR3046498B1 (fr) 2015-12-31 2019-11-29 I-Ten Batterie entierement solide comprenant un electrolyte solide et une couche de materiau conducteur ionique
CN106229447A (zh) * 2016-08-10 2016-12-14 东莞永蓝电子科技有限公司 一种锂离子电池
CN208489305U (zh) * 2018-06-27 2019-02-12 江西星盈科技有限公司 一种由复合型固态电解质组成的全固态锂电池

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Publication number Publication date
JP2021048127A (ja) 2021-03-25
CN112510252B (zh) 2024-05-24
JP7582823B2 (ja) 2024-11-13
CN112510252A (zh) 2021-03-16
US20210083319A1 (en) 2021-03-18
US11018375B2 (en) 2021-05-25

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Owner name: UNIVERSITY OF MARYLAND, COLLEGE PARK, COLLEGE , US

Free format text: FORMER OWNERS: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, INC., PLANO, TX, US; UNIVERSITY OF MARYLAND, COLLEGE PARK, COLLEGE PARK, MD, US

Owner name: TOYOTA JIDOSHA KABUSHIKI KAISHA, TOYOTA-SHI, JP

Free format text: FORMER OWNERS: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, INC., PLANO, TX, US; UNIVERSITY OF MARYLAND, COLLEGE PARK, COLLEGE PARK, MD, US