DE102008025681A1 - Piston pin for an internal combustion engine - Google Patents
Piston pin for an internal combustion engine Download PDFInfo
- Publication number
- DE102008025681A1 DE102008025681A1 DE200810025681 DE102008025681A DE102008025681A1 DE 102008025681 A1 DE102008025681 A1 DE 102008025681A1 DE 200810025681 DE200810025681 DE 200810025681 DE 102008025681 A DE102008025681 A DE 102008025681A DE 102008025681 A1 DE102008025681 A1 DE 102008025681A1
- Authority
- DE
- Germany
- Prior art keywords
- piston pin
- piston
- hydrogen content
- internal combustion
- combustion engine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0605—Carbon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J1/00—Pistons; Trunk pistons; Plungers
- F16J1/10—Connection to driving members
- F16J1/14—Connection to driving members with connecting-rods, i.e. pivotal connections
- F16J1/16—Connection to driving members with connecting-rods, i.e. pivotal connections with gudgeon-pin; Gudgeon-pins
Abstract
Es wird ein Kolbenbolzen mit einer DLC-Schicht vorgestellt, die weniger als 1 At-% Silizium und einen Wasserstoffanteil von >= 20 und <= 65 At-% aufweist.A piston pin with a DLC layer is presented that has less than 1 at% silicon and a hydrogen content of> = 20 and <= 65 at%.
Description
Technisches GebietTechnical area
Die Erfindung betrifft einen Kolbenbolzen für einen Verbrennungsmotor.The The invention relates to a piston pin for an internal combustion engine.
Kolbenbolzen dienen in Verbrennungsmotoren im Wesentlichen der Übertragung der Bewegung des Kolbens auf ein Pleuel, dessen Bewegung wiederum auf die Kurbelwelle übertragen wird. Zwischen dem Kolbenbolzen und den sogenannten Bolzenaugen des Kolbens und/oder dem Auge des Pleuels tritt Relativbewegung auf. Zur Verringerung des Kraftstoffverbrauchs ist somit in diesem Bereich die Reibung möglichst gering zu halten. Ferner ist es stets wünschenswert, den Verschleiß zu minimieren, und damit die ”Fressneigung” zu reduzieren.piston pin serve in internal combustion engines essentially the transmission the movement of the piston on a connecting rod, whose movement in turn is transmitted to the crankshaft. Between the piston pin and the so-called pin bosses of the piston and / or the eye of the Pleuels occurs relative motion. To reduce fuel consumption Thus, the friction is as low as possible in this area to keep. Furthermore, it is always desirable to wear too minimize, and thus reduce the "predation".
Stand der TechnikState of the art
Zu diesem Zweck ist es bekannt, DLC(diamond like carbon)-Beschichtungen vorzusehen.To For this purpose it is known DLC (diamond like carbon) coatings provided.
Diesbezüglich
beschreibt die
Die
Darstellung der ErfindungPresentation of the invention
Der Erfindung liegt die Aufgabe zugrunde, einen Kolbenbolzen zu schaffen, der im Hinblick auf die Reib- und Verschleißeigenschaften verbessert ist.Of the Invention has for its object to provide a piston pin, in terms of friction and wear properties is improved.
Die Lösung dieser Aufgabe erfolgt durch den im Anspruch 1 beschriebenen Kolbenbolzen.The This object is achieved by the method described in claim 1 Piston pins.
Demzufolge weist dieser eine DLC-Schicht mit weniger als 1 At-% Silizium und einen Wasserstoffanteil von 20 At-% oder mehr und 65 At-% oder weniger auf. Es wurde festgestellt, dass mit einer derartigen Beschichtung die günstigen Reib- und Verschleißeigenschaften der DLC-Schicht auch bei erhöhten Temperaturen beibehalten werden können. Es sei erwähnt, dass die DLC-Beschichtungen auch als amorphe Kohlenstoffschichten bezeichnet werden. Im Hinblick auf den Wasserstoffgehalt zeigen erste Untersuchungen, dass das Reib- und Verschleißverhalten der Beschichtungen bei erhöhten Temperaturen mit steigendem Wasserstoffgehalt verbessert wird. Somit können diese Eigenschaften eines Kolbenbolzens durch die erfindungsgemäße Beschichtung verbessert werden, und die Fressneigung kann reduziert werden.As a result, this has a DLC layer with less than 1 at% silicon and a hydrogen content of 20 at.% or more and 65 at.% or less on. It was found that with such a coating the favorable friction and wear properties the DLC layer maintained even at elevated temperatures can be. It should be noted that the DLC coatings also be referred to as amorphous carbon layers. In terms of on the hydrogen content, initial studies show that the Friction and wear behavior of the coatings at elevated temperatures is improved with increasing hydrogen content. Thus, you can these properties of a piston pin by the invention Coating can be improved, and the tendency to eat can be reduced become.
Bevorzugt ist die DLC-Beschichtung unmittelbar auf das Grundmaterial des Kolbenbolzens aufgebracht. Jedoch kann insbesondere bei einem Wasserstoffanteil von mehr als 30 At-% auch eine Zwischenschicht zwischen der DLC-Beschichtung und dem Grundmaterial des Kolbens, Kolbenrings oder Kolbenbolzens vorgesehen sein.Prefers is the DLC coating directly on the base material of the piston pin applied. However, especially at a hydrogen content greater than 30 at%, also an intermediate layer between the DLC coating and the base material of the piston, piston ring or piston pin be provided.
Als Wirkmechanismus, auf den die Erfindung jedoch keineswegs beschränkt ist, sei erwähnt, dass die Kohlenstoff-Wasserstoff-Verbindungen insbesondere bei erhöhten Temperaturen stabiler sind als die Kohlenstoff-Kohlenstoff-Bindungen. Hierdurch wird die Bindungswechselwirkung mit dem Gegenkörper, also im Fall des Kolbenbolzens mit den Bolzenaugen und/oder dem Auge des Pleuels, geschwächt, und das sogenannte Anti-Sticking-Verhalten steigt. Ferner sinkt die Wahrscheinlichkeit, dass die DLC-Schicht graphitisiert wird, was einem Zerfall der DLC-Schicht gleich kommt. Ferner haben erste Untersuchungen gezeigt, dass durch die erfindungsgemäße Beschichtungszusammensetzung auch die Härte und das Eindringmodul der Oberfläche erhöht werden können.When Mechanism of action, however, to which the invention is by no means limited It is worth mentioning that the carbon-hydrogen compounds especially at elevated temperatures are more stable than the carbon-carbon bonds. This becomes the binding interaction with the counter body, so in the case of the piston pin with the pin eyes and / or the eye of the connecting rod, weakened, and the so-called anti-sticking behavior is increasing. It also drops the probability that the DLC layer will be graphitized which is equivalent to a decay of the DLC layer. Furthermore, have first Studies have shown that by the inventive Coating composition also the hardness and the penetration modulus the surface can be increased.
Vorteilhafte Weiterbildungen des erfindungsgemäßen Kolbenbolzens sind in den weiteren Ansprüchen beschrieben.advantageous Further developments of the piston pin according to the invention are described in the further claims.
Bei ersten Untersuchungen hat sich insbesondere ein Wasserstoffanteil von mehr als 25 At-% in der DLC-Schicht als günstig erwiesen.at In particular, the first studies have a hydrogen content of more than 25 at% in the DLC layer proved to be favorable.
Dies gilt in besonderer Weise für einen ggf. Wasserstoffanteil von mehr als 30 At-%. Mit diesem Merkmal, kombiniert mit den oben und/oder nachstehend genannten weiteren Merkmalen ist auch ein Kolben oder Kolbenring mit einer derartigen Beschichtung, im Fall des Kolbens bevorzugt am Kolbenschaft, als Gegenstand der Erfindung anzusehen.This applies in a special way for a possibly hydrogen content of more than 30 at%. With this feature, combined with the above and / or other features mentioned below is also a piston or piston ring with such a coating, in the case of the piston preferably on the piston skirt to be considered as the subject of the invention.
Eine weitere Verbesserung konnte ferner für einen Wasserstoffanteil von mehr als 40 At-% festgestellt werden. Es sei für diesen Fall erwähnt, dass hier günstige Eigenschaften der DLC-Beschichtung auch für Siliziumanteile von 1 At-% oder mehr zu erwarten sind.A Further improvement could also be made for a hydrogen content of more than 40 at%. It is for this Case mentioned that here are favorable properties the DLC coating also for silicon shares of 1 at% or more are expected.
Schließlich ist insbesondere im Bereich eines Wasserstoffanteils von mehr als 50 At-% eine besondere Verbesserung der Eigenschaften des beschichteten Kolbenbolzens, Kolbens oder Kolbenrings zu erwarten.After all is especially in the range of a hydrogen content of more than 50 at% a particular improvement in the properties of the coated Piston pin, piston or piston ring to be expected.
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- - WO 2007/020139 A1 [0004] - WO 2007/020139 A1 [0004]
- - EP 1783349 A1 [0005] - EP 1783349 A1 [0005]
Claims (5)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200810025681 DE102008025681A1 (en) | 2008-05-29 | 2008-05-29 | Piston pin for an internal combustion engine |
PCT/EP2009/054301 WO2009144076A1 (en) | 2008-05-29 | 2009-04-09 | Piston pin for an internal combustion engine |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200810025681 DE102008025681A1 (en) | 2008-05-29 | 2008-05-29 | Piston pin for an internal combustion engine |
Publications (1)
Publication Number | Publication Date |
---|---|
DE102008025681A1 true DE102008025681A1 (en) | 2009-12-10 |
Family
ID=40780165
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE200810025681 Ceased DE102008025681A1 (en) | 2008-05-29 | 2008-05-29 | Piston pin for an internal combustion engine |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE102008025681A1 (en) |
WO (1) | WO2009144076A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010051682A1 (en) * | 2010-11-17 | 2012-05-24 | Daimler Ag | Lightweight crankshaft and manufacturing process thereof |
DE202013002328U1 (en) | 2013-03-09 | 2013-03-26 | Wieland-Werke Ag | storage system |
DE102013004151A1 (en) | 2013-03-09 | 2014-09-11 | Wieland-Werke Ag | storage system |
EP2813720A1 (en) | 2013-03-09 | 2014-12-17 | Wieland-Werke AG | bearing system |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3063122A1 (en) * | 2017-02-21 | 2018-08-24 | Peugeot Citroen Automobiles Sa | MOTION TRANSMISSION DEVICE FOR THERMAL MOTOR |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5198285A (en) * | 1989-12-28 | 1993-03-30 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Hard and lubricant thin film of iron base metallic material coated with amorphous carbon-hydrogen-silicon |
US5237967A (en) * | 1993-01-08 | 1993-08-24 | Ford Motor Company | Powertrain component with amorphous hydrogenated carbon film |
DE4434428A1 (en) * | 1994-09-27 | 1996-03-28 | Widia Gmbh | Composite body, use of this composite body and method for its production |
EP1052307A2 (en) * | 1999-05-10 | 2000-11-15 | Nanyang Technological University | Heat transfer surface |
EP1484534A1 (en) * | 2003-06-06 | 2004-12-08 | Nissan Motor Company, Limited | Engine piston-pin sliding structure |
DE102004054193A1 (en) * | 2004-11-10 | 2006-06-01 | Thomas Kronenberger | Hard coating on any, preferably flexible substrate, comprising at least two morphologically different layers useful in applications involving friction pairs has outer layer comprising hard layer of amorphous, diamond-like carbon (DLC) |
WO2007020139A1 (en) | 2005-08-18 | 2007-02-22 | Nv Bekaert Sa | Substrate coated with a layered structure comprising a tetrahedral carbon layer and a softer outer layer |
EP1783349A1 (en) | 2004-07-06 | 2007-05-09 | Toyota Jidosha Kabushiki Kaisha | Piston ring, piston, cylinder and piston pin having amorphous and hard carbon film |
-
2008
- 2008-05-29 DE DE200810025681 patent/DE102008025681A1/en not_active Ceased
-
2009
- 2009-04-09 WO PCT/EP2009/054301 patent/WO2009144076A1/en active Application Filing
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5198285A (en) * | 1989-12-28 | 1993-03-30 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Hard and lubricant thin film of iron base metallic material coated with amorphous carbon-hydrogen-silicon |
US5237967A (en) * | 1993-01-08 | 1993-08-24 | Ford Motor Company | Powertrain component with amorphous hydrogenated carbon film |
DE4434428A1 (en) * | 1994-09-27 | 1996-03-28 | Widia Gmbh | Composite body, use of this composite body and method for its production |
EP1052307A2 (en) * | 1999-05-10 | 2000-11-15 | Nanyang Technological University | Heat transfer surface |
EP1484534A1 (en) * | 2003-06-06 | 2004-12-08 | Nissan Motor Company, Limited | Engine piston-pin sliding structure |
EP1783349A1 (en) | 2004-07-06 | 2007-05-09 | Toyota Jidosha Kabushiki Kaisha | Piston ring, piston, cylinder and piston pin having amorphous and hard carbon film |
DE102004054193A1 (en) * | 2004-11-10 | 2006-06-01 | Thomas Kronenberger | Hard coating on any, preferably flexible substrate, comprising at least two morphologically different layers useful in applications involving friction pairs has outer layer comprising hard layer of amorphous, diamond-like carbon (DLC) |
WO2007020139A1 (en) | 2005-08-18 | 2007-02-22 | Nv Bekaert Sa | Substrate coated with a layered structure comprising a tetrahedral carbon layer and a softer outer layer |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010051682A1 (en) * | 2010-11-17 | 2012-05-24 | Daimler Ag | Lightweight crankshaft and manufacturing process thereof |
DE102010051682B4 (en) * | 2010-11-17 | 2012-07-12 | Daimler Ag | Lightweight crankshaft and manufacturing process thereof |
DE202013002328U1 (en) | 2013-03-09 | 2013-03-26 | Wieland-Werke Ag | storage system |
DE102013004151A1 (en) | 2013-03-09 | 2014-09-11 | Wieland-Werke Ag | storage system |
EP2813720A1 (en) | 2013-03-09 | 2014-12-17 | Wieland-Werke AG | bearing system |
DE102013004151B4 (en) * | 2013-03-09 | 2015-11-26 | Wieland-Werke Ag | storage system |
US9464668B2 (en) | 2013-03-09 | 2016-10-11 | Wieland-Werke Ag | Bearing system |
Also Published As
Publication number | Publication date |
---|---|
WO2009144076A1 (en) | 2009-12-03 |
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Legal Events
Date | Code | Title | Description |
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OP8 | Request for examination as to paragraph 44 patent law | ||
8131 | Rejection |