DE102008025681A1 - Piston pin for an internal combustion engine - Google Patents

Piston pin for an internal combustion engine Download PDF

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Publication number
DE102008025681A1
DE102008025681A1 DE200810025681 DE102008025681A DE102008025681A1 DE 102008025681 A1 DE102008025681 A1 DE 102008025681A1 DE 200810025681 DE200810025681 DE 200810025681 DE 102008025681 A DE102008025681 A DE 102008025681A DE 102008025681 A1 DE102008025681 A1 DE 102008025681A1
Authority
DE
Germany
Prior art keywords
piston pin
piston
hydrogen content
internal combustion
combustion engine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE200810025681
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German (de)
Inventor
Roman Morgenstern
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Federal Mogul Nuernberg GmbH
Original Assignee
Federal Mogul Nuernberg GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Federal Mogul Nuernberg GmbH filed Critical Federal Mogul Nuernberg GmbH
Priority to DE200810025681 priority Critical patent/DE102008025681A1/en
Priority to PCT/EP2009/054301 priority patent/WO2009144076A1/en
Publication of DE102008025681A1 publication Critical patent/DE102008025681A1/en
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0605Carbon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/26Deposition of carbon only
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16JPISTONS; CYLINDERS; SEALINGS
    • F16J1/00Pistons; Trunk pistons; Plungers
    • F16J1/10Connection to driving members
    • F16J1/14Connection to driving members with connecting-rods, i.e. pivotal connections
    • F16J1/16Connection to driving members with connecting-rods, i.e. pivotal connections with gudgeon-pin; Gudgeon-pins

Abstract

Es wird ein Kolbenbolzen mit einer DLC-Schicht vorgestellt, die weniger als 1 At-% Silizium und einen Wasserstoffanteil von >= 20 und <= 65 At-% aufweist.A piston pin with a DLC layer is presented that has less than 1 at% silicon and a hydrogen content of> = 20 and <= 65 at%.

Description

Technisches GebietTechnical area

Die Erfindung betrifft einen Kolbenbolzen für einen Verbrennungsmotor.The The invention relates to a piston pin for an internal combustion engine.

Kolbenbolzen dienen in Verbrennungsmotoren im Wesentlichen der Übertragung der Bewegung des Kolbens auf ein Pleuel, dessen Bewegung wiederum auf die Kurbelwelle übertragen wird. Zwischen dem Kolbenbolzen und den sogenannten Bolzenaugen des Kolbens und/oder dem Auge des Pleuels tritt Relativbewegung auf. Zur Verringerung des Kraftstoffverbrauchs ist somit in diesem Bereich die Reibung möglichst gering zu halten. Ferner ist es stets wünschenswert, den Verschleiß zu minimieren, und damit die ”Fressneigung” zu reduzieren.piston pin serve in internal combustion engines essentially the transmission the movement of the piston on a connecting rod, whose movement in turn is transmitted to the crankshaft. Between the piston pin and the so-called pin bosses of the piston and / or the eye of the Pleuels occurs relative motion. To reduce fuel consumption Thus, the friction is as low as possible in this area to keep. Furthermore, it is always desirable to wear too minimize, and thus reduce the "predation".

Stand der TechnikState of the art

Zu diesem Zweck ist es bekannt, DLC(diamond like carbon)-Beschichtungen vorzusehen.To For this purpose it is known DLC (diamond like carbon) coatings provided.

Diesbezüglich beschreibt die WO 2007/020139 A1 Beschichtungen für Kolben und Kolbenringe, die als DLC-Schicht ausgeführt sind und stets mittels einer Zwischenschicht auf die genannten Bauteile aufgebracht werden. Ferner können die Beschichtungen einen Wasserstoffanteil von 20 bis 30 At-% (Atomprozent) aufweisen.This describes the WO 2007/020139 A1 Coatings for pistons and piston rings, which are designed as DLC layer and are always applied by means of an intermediate layer on said components. Further, the coatings may have a hydrogen content of 20 to 30 at% (atomic%).

Die EP 1 783 349 A1 beschreibt Kolben, Kolbenringe und Kolbenbolzen mit DLC-Beschichtungen, die Wasserstoffanteile von 20 bis 40 At-% haben. Es ist jedoch stets ein erheblicher Anteil von Silizium in der DLC-Schicht vorgesehen.The EP 1 783 349 A1 describes pistons, piston rings and piston pins with DLC coatings that have hydrogen contents of 20 to 40 at%. However, there is always a significant amount of silicon in the DLC layer.

Darstellung der ErfindungPresentation of the invention

Der Erfindung liegt die Aufgabe zugrunde, einen Kolbenbolzen zu schaffen, der im Hinblick auf die Reib- und Verschleißeigenschaften verbessert ist.Of the Invention has for its object to provide a piston pin, in terms of friction and wear properties is improved.

Die Lösung dieser Aufgabe erfolgt durch den im Anspruch 1 beschriebenen Kolbenbolzen.The This object is achieved by the method described in claim 1 Piston pins.

Demzufolge weist dieser eine DLC-Schicht mit weniger als 1 At-% Silizium und einen Wasserstoffanteil von 20 At-% oder mehr und 65 At-% oder weniger auf. Es wurde festgestellt, dass mit einer derartigen Beschichtung die günstigen Reib- und Verschleißeigenschaften der DLC-Schicht auch bei erhöhten Temperaturen beibehalten werden können. Es sei erwähnt, dass die DLC-Beschichtungen auch als amorphe Kohlenstoffschichten bezeichnet werden. Im Hinblick auf den Wasserstoffgehalt zeigen erste Untersuchungen, dass das Reib- und Verschleißverhalten der Beschichtungen bei erhöhten Temperaturen mit steigendem Wasserstoffgehalt verbessert wird. Somit können diese Eigenschaften eines Kolbenbolzens durch die erfindungsgemäße Beschichtung verbessert werden, und die Fressneigung kann reduziert werden.As a result, this has a DLC layer with less than 1 at% silicon and a hydrogen content of 20 at.% or more and 65 at.% or less on. It was found that with such a coating the favorable friction and wear properties the DLC layer maintained even at elevated temperatures can be. It should be noted that the DLC coatings also be referred to as amorphous carbon layers. In terms of on the hydrogen content, initial studies show that the Friction and wear behavior of the coatings at elevated temperatures is improved with increasing hydrogen content. Thus, you can these properties of a piston pin by the invention Coating can be improved, and the tendency to eat can be reduced become.

Bevorzugt ist die DLC-Beschichtung unmittelbar auf das Grundmaterial des Kolbenbolzens aufgebracht. Jedoch kann insbesondere bei einem Wasserstoffanteil von mehr als 30 At-% auch eine Zwischenschicht zwischen der DLC-Beschichtung und dem Grundmaterial des Kolbens, Kolbenrings oder Kolbenbolzens vorgesehen sein.Prefers is the DLC coating directly on the base material of the piston pin applied. However, especially at a hydrogen content greater than 30 at%, also an intermediate layer between the DLC coating and the base material of the piston, piston ring or piston pin be provided.

Als Wirkmechanismus, auf den die Erfindung jedoch keineswegs beschränkt ist, sei erwähnt, dass die Kohlenstoff-Wasserstoff-Verbindungen insbesondere bei erhöhten Temperaturen stabiler sind als die Kohlenstoff-Kohlenstoff-Bindungen. Hierdurch wird die Bindungswechselwirkung mit dem Gegenkörper, also im Fall des Kolbenbolzens mit den Bolzenaugen und/oder dem Auge des Pleuels, geschwächt, und das sogenannte Anti-Sticking-Verhalten steigt. Ferner sinkt die Wahrscheinlichkeit, dass die DLC-Schicht graphitisiert wird, was einem Zerfall der DLC-Schicht gleich kommt. Ferner haben erste Untersuchungen gezeigt, dass durch die erfindungsgemäße Beschichtungszusammensetzung auch die Härte und das Eindringmodul der Oberfläche erhöht werden können.When Mechanism of action, however, to which the invention is by no means limited It is worth mentioning that the carbon-hydrogen compounds especially at elevated temperatures are more stable than the carbon-carbon bonds. This becomes the binding interaction with the counter body, so in the case of the piston pin with the pin eyes and / or the eye of the connecting rod, weakened, and the so-called anti-sticking behavior is increasing. It also drops the probability that the DLC layer will be graphitized which is equivalent to a decay of the DLC layer. Furthermore, have first Studies have shown that by the inventive Coating composition also the hardness and the penetration modulus the surface can be increased.

Vorteilhafte Weiterbildungen des erfindungsgemäßen Kolbenbolzens sind in den weiteren Ansprüchen beschrieben.advantageous Further developments of the piston pin according to the invention are described in the further claims.

Bei ersten Untersuchungen hat sich insbesondere ein Wasserstoffanteil von mehr als 25 At-% in der DLC-Schicht als günstig erwiesen.at In particular, the first studies have a hydrogen content of more than 25 at% in the DLC layer proved to be favorable.

Dies gilt in besonderer Weise für einen ggf. Wasserstoffanteil von mehr als 30 At-%. Mit diesem Merkmal, kombiniert mit den oben und/oder nachstehend genannten weiteren Merkmalen ist auch ein Kolben oder Kolbenring mit einer derartigen Beschichtung, im Fall des Kolbens bevorzugt am Kolbenschaft, als Gegenstand der Erfindung anzusehen.This applies in a special way for a possibly hydrogen content of more than 30 at%. With this feature, combined with the above and / or other features mentioned below is also a piston or piston ring with such a coating, in the case of the piston preferably on the piston skirt to be considered as the subject of the invention.

Eine weitere Verbesserung konnte ferner für einen Wasserstoffanteil von mehr als 40 At-% festgestellt werden. Es sei für diesen Fall erwähnt, dass hier günstige Eigenschaften der DLC-Beschichtung auch für Siliziumanteile von 1 At-% oder mehr zu erwarten sind.A Further improvement could also be made for a hydrogen content of more than 40 at%. It is for this Case mentioned that here are favorable properties the DLC coating also for silicon shares of 1 at% or more are expected.

Schließlich ist insbesondere im Bereich eines Wasserstoffanteils von mehr als 50 At-% eine besondere Verbesserung der Eigenschaften des beschichteten Kolbenbolzens, Kolbens oder Kolbenrings zu erwarten.After all is especially in the range of a hydrogen content of more than 50 at% a particular improvement in the properties of the coated Piston pin, piston or piston ring to be expected.

ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION

Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Zitierte PatentliteraturCited patent literature

  • - WO 2007/020139 A1 [0004] - WO 2007/020139 A1 [0004]
  • - EP 1783349 A1 [0005] - EP 1783349 A1 [0005]

Claims (5)

Kolbenbolzen für einen Verbrennungsmotor mit einer DLC-Schicht mit weniger als 1 At-% Silizium und einem Wasserstoffanteil von ≥ 20 und ≤ 65 At-%.Piston pin for an internal combustion engine with a DLC layer with less than 1 at% silicon and one hydrogen content of ≥20 and ≤65 at%. Kolbenbolzen nach Anspruch 1, dadurch gekennzeichnet, dass der Wasserstoffanteil mehr als 25 At-% beträgt.Piston pin according to claim 1, characterized that the hydrogen content is more than 25 at%. Kolbenbolzen nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der Wasserstoffanteil mehr als 30 At-% beträgt.Piston pin according to claim 1 or 2, characterized that the hydrogen content is more than 30 at%. Kolbenbolzen nach einem der vorigen Ansprüche, dadurch gekennzeichnet, dass der Wasserstoffanteil mehr als 40 At-% beträgt.Piston pin according to one of the preceding claims, characterized in that the hydrogen content is more than 40 at% is. Kolbenbolzen nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet dass der Wasserstoffanteil mehr als 50 At-% beträgt.Piston pin according to one of the preceding claims, characterized in that the hydrogen content is more than 50 at% is.
DE200810025681 2008-05-29 2008-05-29 Piston pin for an internal combustion engine Ceased DE102008025681A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE200810025681 DE102008025681A1 (en) 2008-05-29 2008-05-29 Piston pin for an internal combustion engine
PCT/EP2009/054301 WO2009144076A1 (en) 2008-05-29 2009-04-09 Piston pin for an internal combustion engine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE200810025681 DE102008025681A1 (en) 2008-05-29 2008-05-29 Piston pin for an internal combustion engine

Publications (1)

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DE102008025681A1 true DE102008025681A1 (en) 2009-12-10

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WO (1) WO2009144076A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010051682A1 (en) * 2010-11-17 2012-05-24 Daimler Ag Lightweight crankshaft and manufacturing process thereof
DE202013002328U1 (en) 2013-03-09 2013-03-26 Wieland-Werke Ag storage system
DE102013004151A1 (en) 2013-03-09 2014-09-11 Wieland-Werke Ag storage system
EP2813720A1 (en) 2013-03-09 2014-12-17 Wieland-Werke AG bearing system

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3063122A1 (en) * 2017-02-21 2018-08-24 Peugeot Citroen Automobiles Sa MOTION TRANSMISSION DEVICE FOR THERMAL MOTOR

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198285A (en) * 1989-12-28 1993-03-30 Kabushiki Kaisha Toyota Chuo Kenkyusho Hard and lubricant thin film of iron base metallic material coated with amorphous carbon-hydrogen-silicon
US5237967A (en) * 1993-01-08 1993-08-24 Ford Motor Company Powertrain component with amorphous hydrogenated carbon film
DE4434428A1 (en) * 1994-09-27 1996-03-28 Widia Gmbh Composite body, use of this composite body and method for its production
EP1052307A2 (en) * 1999-05-10 2000-11-15 Nanyang Technological University Heat transfer surface
EP1484534A1 (en) * 2003-06-06 2004-12-08 Nissan Motor Company, Limited Engine piston-pin sliding structure
DE102004054193A1 (en) * 2004-11-10 2006-06-01 Thomas Kronenberger Hard coating on any, preferably flexible substrate, comprising at least two morphologically different layers useful in applications involving friction pairs has outer layer comprising hard layer of amorphous, diamond-like carbon (DLC)
WO2007020139A1 (en) 2005-08-18 2007-02-22 Nv Bekaert Sa Substrate coated with a layered structure comprising a tetrahedral carbon layer and a softer outer layer
EP1783349A1 (en) 2004-07-06 2007-05-09 Toyota Jidosha Kabushiki Kaisha Piston ring, piston, cylinder and piston pin having amorphous and hard carbon film

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198285A (en) * 1989-12-28 1993-03-30 Kabushiki Kaisha Toyota Chuo Kenkyusho Hard and lubricant thin film of iron base metallic material coated with amorphous carbon-hydrogen-silicon
US5237967A (en) * 1993-01-08 1993-08-24 Ford Motor Company Powertrain component with amorphous hydrogenated carbon film
DE4434428A1 (en) * 1994-09-27 1996-03-28 Widia Gmbh Composite body, use of this composite body and method for its production
EP1052307A2 (en) * 1999-05-10 2000-11-15 Nanyang Technological University Heat transfer surface
EP1484534A1 (en) * 2003-06-06 2004-12-08 Nissan Motor Company, Limited Engine piston-pin sliding structure
EP1783349A1 (en) 2004-07-06 2007-05-09 Toyota Jidosha Kabushiki Kaisha Piston ring, piston, cylinder and piston pin having amorphous and hard carbon film
DE102004054193A1 (en) * 2004-11-10 2006-06-01 Thomas Kronenberger Hard coating on any, preferably flexible substrate, comprising at least two morphologically different layers useful in applications involving friction pairs has outer layer comprising hard layer of amorphous, diamond-like carbon (DLC)
WO2007020139A1 (en) 2005-08-18 2007-02-22 Nv Bekaert Sa Substrate coated with a layered structure comprising a tetrahedral carbon layer and a softer outer layer

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010051682A1 (en) * 2010-11-17 2012-05-24 Daimler Ag Lightweight crankshaft and manufacturing process thereof
DE102010051682B4 (en) * 2010-11-17 2012-07-12 Daimler Ag Lightweight crankshaft and manufacturing process thereof
DE202013002328U1 (en) 2013-03-09 2013-03-26 Wieland-Werke Ag storage system
DE102013004151A1 (en) 2013-03-09 2014-09-11 Wieland-Werke Ag storage system
EP2813720A1 (en) 2013-03-09 2014-12-17 Wieland-Werke AG bearing system
DE102013004151B4 (en) * 2013-03-09 2015-11-26 Wieland-Werke Ag storage system
US9464668B2 (en) 2013-03-09 2016-10-11 Wieland-Werke Ag Bearing system

Also Published As

Publication number Publication date
WO2009144076A1 (en) 2009-12-03

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