DE102005025332A1

DE102005025332A1 - Tensidcompound

Tensidcompound Download PDF

Info

Publication number: DE102005025332A1
Authority: DE; Germany
Prior art keywords: acid; weight; surfactant; preferred; radical
Prior art date: 2005-05-31
Legal status : Withdrawn

Application number

DE102005025332A

Other languages

German (de)

English (en)

Inventor

Arnd Kessler

Ulrich Dr. Pegelow

Current Assignee

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date

2005-05-31

Filing date

2005-05-31

Publication date

2006-12-07

2005-05-31 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2005-05-31 Priority to DE102005025332A priority Critical patent/DE102005025332A1/de

2006-05-04 Priority to PCT/EP2006/004161 priority patent/WO2006128543A1/fr

2006-12-07 Publication of DE102005025332A1 publication Critical patent/DE102005025332A1/de

Status Withdrawn legal-status Critical Current

Links

239000004094 surface-active agent Substances 0.000 title claims abstract description 87
150000001875 compounds Chemical class 0.000 title claims abstract description 74
239000002736 nonionic surfactant Substances 0.000 claims abstract description 69
150000003751 zinc Chemical class 0.000 claims abstract description 27
125000004432 carbon atom Chemical group C* 0.000 claims description 58
239000003599 detergent Substances 0.000 claims description 52
238000004851 dishwashing Methods 0.000 claims description 36
229920006395 saturated elastomer Polymers 0.000 claims description 36
238000005406 washing Methods 0.000 claims description 36
239000012459 cleaning agent Substances 0.000 claims description 32
239000007787 solid Substances 0.000 claims description 29
125000000217 alkyl group Chemical group 0.000 claims description 20
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 15
239000011521 glass Substances 0.000 claims description 12
230000007797 corrosion Effects 0.000 claims description 10
238000005260 corrosion Methods 0.000 claims description 10
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 8
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
230000015572 biosynthetic process Effects 0.000 claims description 6
238000005469 granulation Methods 0.000 claims description 6
230000003179 granulation Effects 0.000 claims description 6
230000001603 reducing effect Effects 0.000 claims description 6
101100379079 Emericella variicolor andA gene Proteins 0.000 claims description 3
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 3
229940045872 sodium percarbonate Drugs 0.000 claims description 3
239000011787 zinc oxide Substances 0.000 claims description 3
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
229960001763 zinc sulfate Drugs 0.000 claims description 3
229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
230000000694 effects Effects 0.000 abstract description 13
-1 alkyl glycosides Chemical class 0.000 description 102
229920000642 polymer Polymers 0.000 description 57
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 46
239000000178 monomer Substances 0.000 description 43
239000002253 acid Substances 0.000 description 39
239000000203 mixture Substances 0.000 description 35
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KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 28
235000010980 cellulose Nutrition 0.000 description 27
239000003795 chemical substances by application Substances 0.000 description 24
239000011734 sodium Substances 0.000 description 24
239000000126 substance Substances 0.000 description 24
150000003254 radicals Chemical class 0.000 description 23
150000003839 salts Chemical class 0.000 description 23
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229940088598 enzyme Drugs 0.000 description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
150000007513 acids Chemical class 0.000 description 20
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239000003205 fragrance Substances 0.000 description 19
150000001298 alcohols Chemical class 0.000 description 18
239000007844 bleaching agent Substances 0.000 description 18
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 17
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 17
125000006850 spacer group Chemical group 0.000 description 17
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 15
235000019832 sodium triphosphate Nutrition 0.000 description 15
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 14
125000003118 aryl group Chemical group 0.000 description 14
150000001735 carboxylic acids Chemical class 0.000 description 14
125000002091 cationic group Chemical group 0.000 description 14
239000003086 colorant Substances 0.000 description 13
239000011572 manganese Substances 0.000 description 13
239000000463 material Substances 0.000 description 13
229910052751 metal Inorganic materials 0.000 description 13
239000002184 metal Substances 0.000 description 13
239000013042 solid detergent Substances 0.000 description 13
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 12
150000004760 silicates Chemical class 0.000 description 12
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 12
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229910019142 PO4 Inorganic materials 0.000 description 11
238000004140 cleaning Methods 0.000 description 11
235000021317 phosphate Nutrition 0.000 description 11
239000012190 activator Substances 0.000 description 10
125000001931 aliphatic group Chemical group 0.000 description 10
229910052708 sodium Inorganic materials 0.000 description 10
125000000542 sulfonic acid group Chemical group 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 9
239000003513 alkali Substances 0.000 description 9
229910052783 alkali metal Inorganic materials 0.000 description 9
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 9
235000014113 dietary fatty acids Nutrition 0.000 description 9
229930195729 fatty acid Natural products 0.000 description 9
239000000194 fatty acid Substances 0.000 description 9
229930195733 hydrocarbon Natural products 0.000 description 9
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 9
239000011976 maleic acid Substances 0.000 description 9
238000000034 method Methods 0.000 description 9
125000000896 monocarboxylic acid group Chemical group 0.000 description 9
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 8
239000004215 Carbon black (E152) Substances 0.000 description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 8
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
238000002844 melting Methods 0.000 description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
229910052757 nitrogen Inorganic materials 0.000 description 8
235000000346 sugar Nutrition 0.000 description 8
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 7
235000019270 ammonium chloride Nutrition 0.000 description 7
229910017052 cobalt Inorganic materials 0.000 description 7
239000010941 cobalt Substances 0.000 description 7
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 7
150000004665 fatty acids Chemical class 0.000 description 7
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
239000001257 hydrogen Substances 0.000 description 7
125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
229910052748 manganese Inorganic materials 0.000 description 7
230000008018 melting Effects 0.000 description 7
239000002304 perfume Substances 0.000 description 7
229920005646 polycarboxylate Polymers 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
239000000047 product Substances 0.000 description 7
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 6
229920002245 Dextrose equivalent Polymers 0.000 description 6
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 6
108091005804 Peptidases Proteins 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
239000004365 Protease Substances 0.000 description 6
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 6
150000002191 fatty alcohols Chemical class 0.000 description 6
LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 6
125000004435 hydrogen atom Chemical class [H]* 0.000 description 6
230000007062 hydrolysis Effects 0.000 description 6
238000006460 hydrolysis reaction Methods 0.000 description 6
239000004615 ingredient Substances 0.000 description 6
150000002763 monocarboxylic acids Chemical class 0.000 description 6
230000003647 oxidation Effects 0.000 description 6
238000007254 oxidation reaction Methods 0.000 description 6
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 6
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229920001451 polypropylene glycol Polymers 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
239000011591 potassium Substances 0.000 description 6
238000003860 storage Methods 0.000 description 6
239000001226 triphosphate Substances 0.000 description 6
229920001353 Dextrin Polymers 0.000 description 5
239000004375 Dextrin Substances 0.000 description 5
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
239000013543 active substance Substances 0.000 description 5
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125000000129 anionic group Chemical group 0.000 description 5
235000019425 dextrin Nutrition 0.000 description 5
239000008103 glucose Substances 0.000 description 5
239000008187 granular material Substances 0.000 description 5
239000003112 inhibitor Substances 0.000 description 5
239000007788 liquid Substances 0.000 description 5
229910052760 oxygen Inorganic materials 0.000 description 5
239000002245 particle Substances 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
239000010452 phosphate Substances 0.000 description 5
229910052709 silver Inorganic materials 0.000 description 5
239000004332 silver Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
239000003760 tallow Substances 0.000 description 5
229910052723 transition metal Inorganic materials 0.000 description 5
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
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CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
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KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
239000002535 acidifier Substances 0.000 description 4
239000000654 additive Substances 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
150000001340 alkali metals Chemical class 0.000 description 4
150000001447 alkali salts Chemical class 0.000 description 4
235000001014 amino acid Nutrition 0.000 description 4
229940024606 amino acid Drugs 0.000 description 4
150000001413 amino acids Chemical class 0.000 description 4
150000003863 ammonium salts Chemical class 0.000 description 4
235000019418 amylase Nutrition 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000000975 dye Substances 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
238000005187 foaming Methods 0.000 description 4
239000007789 gas Substances 0.000 description 4
229940093915 gynecological organic acid Drugs 0.000 description 4
VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 4
229910052742 iron Inorganic materials 0.000 description 4
239000010410 layer Substances 0.000 description 4
235000019421 lipase Nutrition 0.000 description 4
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235000017550 sodium carbonate Nutrition 0.000 description 4
229910052719 titanium Inorganic materials 0.000 description 4
239000010936 titanium Substances 0.000 description 4
150000003628 tricarboxylic acids Chemical class 0.000 description 4
UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 4
229910052720 vanadium Inorganic materials 0.000 description 4
ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 4
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 3
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VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
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229920002125 Sokalan® Polymers 0.000 description 3
239000004480 active ingredient Substances 0.000 description 3
229910000288 alkali metal carbonate Inorganic materials 0.000 description 3
150000008041 alkali metal carbonates Chemical class 0.000 description 3
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ATGAWOHQWWULNK-UHFFFAOYSA-I pentapotassium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ATGAWOHQWWULNK-UHFFFAOYSA-I 0.000 description 3
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