DE102004055104A1 - Cold/temperature hardenable coating solution, useful for e.g. decorating and/or functionalizing ceramic substrates e.g. bricks and tiles, comprises effective pigments and silicon-, aluminum-, boron- and/or zirconium containing stabilizers - Google Patents
Cold/temperature hardenable coating solution, useful for e.g. decorating and/or functionalizing ceramic substrates e.g. bricks and tiles, comprises effective pigments and silicon-, aluminum-, boron- and/or zirconium containing stabilizers Download PDFInfo
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- DE102004055104A1 DE102004055104A1 DE200410055104 DE102004055104A DE102004055104A1 DE 102004055104 A1 DE102004055104 A1 DE 102004055104A1 DE 200410055104 DE200410055104 DE 200410055104 DE 102004055104 A DE102004055104 A DE 102004055104A DE 102004055104 A1 DE102004055104 A1 DE 102004055104A1
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- aluminum
- tiles
- coating solution
- silicon
- boron
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- 238000000576 coating method Methods 0.000 title claims abstract description 22
- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 239000000049 pigment Substances 0.000 title claims abstract description 18
- 239000000919 ceramic Substances 0.000 title claims abstract description 8
- 239000003381 stabilizer Substances 0.000 title claims abstract description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 title claims abstract 3
- 229910052726 zirconium Inorganic materials 0.000 title claims abstract 3
- 239000000758 substrate Substances 0.000 title claims description 6
- 239000011449 brick Substances 0.000 title claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title abstract 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 title abstract 2
- 239000004927 clay Substances 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000007306 functionalization reaction Methods 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 235000013980 iron oxide Nutrition 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000233805 Phoenix Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000002529 flux (metallurgy) Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0009—Pigments for ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5037—Clay, Kaolin
- C04B41/504—Engobes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00586—Roofing materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Üblicherweise werden Keramiken zur Veredlung der Oberfläche mit Glasuren oder Engoben überzogen und anschließend gebrannt. Diese Überzugsmassen, die sowohl dekorative als auch funktionelle Aspekte der Veredlung tragen, sind seit langem Stand der Technik. Es besteht nach wie vor ein sehr hoher Bedarf an dekorativen Beschichtungen, sowohl im Innen- als auch im Außenbereich.Usually Ceramics are coated with glazes or engobes to refine the surface and subsequently burned. These coating compositions, the decorative as well as functional aspects of the finishing wear, have long been state of the art. It persists after a very high demand for decorative coatings, both indoors as well as outdoors.
Auch
die zur Dekoration verwendeten Effektpigmente wurden bereits in
zahlreichen Patenten und Patentanmeldungen (
Die mit diesen Pigmenten gefüllten Engoben oder Glasuren zeigen üblicherweise eine schlechte Haftung auf Tondachsteinen und sind auf Betondachsteinen oder Fassadenbauteilen (innen und außen), die keine Temperaturbehandlung erfahren, nicht einsetzbar.The filled with these pigments Engobes or glazes usually show a bad adhesion on clay roof tiles and are on concrete roof tiles or facade components (inside and outside) that do not require heat treatment experienced, not usable.
Bisher ist keine Beschichtungsvariante bekannt, die hohe Farbbrillianz einer Vielzahl von Metallik- und Perglanzfarben mit hervorragender Haftung auf dem Substrat verbindet. Überraschenderweise wurde nun gefunden, dass Beschichtungslösungen durch Zugabe verschiedener Substanzen, wie z.B. Silikonharze, Wassergläsern, Kieselsolen, Borsäure, Aluminiumphosphate, also in der Regel durch Silizium- und/oder Aluminium- und/oder Bor- und/oder zikronhaltigen Verbindungen, eine überaus hohe Haftung und extrem hohe Brillianz der Effektschicht zeigen. Insbesondere temperaturempfindliche Perlglanzpigmente werden durch diese Additive stabilisiert, s.d. sie sich z.B. in einer Engobe selbst bei 1.200°C brennen lassen. Wichtig ist daher, das Verwenden oligo- oder polymerer Siliziumverbindungen als Stabilisator für die verwendeten, teilweise temperaturempflindlichen, Pigmente.So far No coating variant is known, the high color brilliance a variety of metallic and pearlescent colors with excellent Bonding on the substrate connects. Surprisingly, now found that coating solutions by adding various substances, e.g. Silicone resins, water glasses, silica sols, boric acid, aluminum phosphates, So usually by silicon and / or aluminum and / or boron and / or zikronhaltigen Connections, a very high Show adhesion and extremely high brilliance of the effect layer. Especially temperature-sensitive pearlescent pigments are stabilized by these additives, s.d. they are e.g. burn in an engobe even at 1200 ° C to let. It is therefore important to use oligomeric or polymeric silicon compounds as a stabilizer for the used, partially temperaturempflindlichen, pigments.
Diese Aufgaben werden erfindungsgemäß durch die beanspruchte Beschichtungslösung sowie das Verfahren zur Herstellung dieser Beschichtung gelöst.These Tasks are performed according to the invention the claimed coating solution and the method for producing this coating solved.
Durch die Erfindung konnte das Farbspektrum von Metall- und Perlglanzeffekten für keramische Bauteile, wie Ziegel, Fliesen und Fassaden deutlich erweitert werden.By The invention has been able to provide the color spectrum of metal and pearlescent effects for ceramic components, as bricks, tiles and facades are significantly expanded.
Die erfindungsgemäßen Beschichtungslösungen enthalten 1 Gew% bis 70 Gew% Effektpigment, vorzugsweise 5 Gew% bis 40 Gew% und insbesondere 5 Gew% bis 15 Gew% Effektstoff. Hierbei kann es sich auch um ein Gemisch von zwei oder mehreren Effektstoffen, um Gemische mit einem oder mehreren Pigmenten (farbige Metalloxide oder färbende organische Pigmente) und um Gemische aus einem oder mehreren Effektstoffen und/oder einem oder mehreren Pigmenten und Metallfarbsalzen handeln.The Contain coating solutions according to the invention 1% by weight to 70% by weight of effect pigment, preferably 5% by weight to 40% by weight and in particular 5% by weight to 15% by weight of effect substance. It can do this It is also a mixture of two or more effect substances Mixtures with one or more pigments (colored metal oxides or coloring organic pigments) and mixtures of one or more effect substances and / or one or more pigments and metal color salts.
Die erfindungsgemäße Beschichtungslösung enthält des Weiteren zwischen 1 Gew% und 95 Gew% Wasser, zwischen 1 Gew% und 60 Gew% eines silizium-, und/oder aluminium-, und/oder Bor-, und/oder zikronhaltigen Stabilisators und ein oder mehrere Additive (z.B. Dispergiermittel, Antiabsetzmittel, Benetzungshilfen, Verlaufsmittel, Verdicker, Flußmittel usw.).The The coating solution of the invention further contains between 1% by weight and 95% by weight of water, between 1% by weight and 60% by weight a silicon, and / or aluminum, and / or boron, and / or zikronhaltigen Stabilizer and one or more additives (e.g., dispersants, Anti-settling agents, wetting aids, leveling agents, thickeners, fluxes etc.).
Die Beschichtungslösung enthält, je nach Härtebedingungen unterschiedliche Anteile an Tonen, Silikaten, und Aluminiumphosphaten. Bei brandhärtenden Beschichtungen werden üblicherweise typische Engobenzusammensetzungen in Kombination mit den siliziumhaltigen Stabilisatoren für die Effektpigmente eingesetzt. Die kalthärtenden Systeme (10°C bis 250°C) enthalten anstelle der Tonmineralien Bestandteile von Mineralfarben und/oder Silanen, Silikonharze, Phosphate, usw..The coating solution contains depending on hardening conditions different proportions of clays, silicates, and aluminum phosphates. For fire-hardening Coatings become common typical engobe compositions in combination with the siliceous ones Stabilizers for the effect pigments used. The cold-curing systems (10 ° C to 250 ° C) contain Instead of the clay minerals components of mineral paints and / or Silanes, silicone resins, phosphates, etc ..
Die Mahlfeinheit liegt, je nach Anwendung und gewünschter Oberflächenstrukturierung, zwischen 50 nm und 300 μm, vorzugsweise zwischen 200 nm und 30 μm. Als Mahlverfahren kommen sowohl Trocken- als auch Nassmahlverfahren zur Anwendung. Das Effektpigment kann vor oder nach dem Mahlvorgang untergemischt werden.The Grinding fineness is, depending on the application and desired surface structuring, between 50 nm and 300 μm, preferably between 200 nm and 30 μm. As a milling process come Both dry and wet grinding method for use. The effect pigment can be mixed in before or after the grinding process.
Die fertige Beschichtungslösung kann mit den üblichen Applikationsverfahren (Pinseln, Rollen, Dippen, Sprühen, Walzen, usw.) aufgetragen werden. Die brandhärtenden Systeme können sowohl unter oxidierenden als auch unter reduzierenden Bedingungen gebrannt werden. Wahlweise sind diese Beschichtungslösungen auch schnellbrandgeeignet.The finished coating solution can with the usual application methods (brushes, rollers, dipping, spraying, rolling, etc.) are applied. The fire-hardening systems can be fired under both oxidizing and reducing conditions. Alternatively, these coating solutions are also suitable for rapid firing.
Die Beschichtungslösung dient zum Dekorieren und/oder zum Funktionalisieren keramischer Bauteile, wie Tondachziegel, Schiefer, Betondachsteinen, Klinker, Fliesen, Fassaden, und anderer Ton- und Keramikwaren.The coating solution serves for decorating and / or functionalizing ceramic components, like clay roof tiles, slates, concrete roof tiles, clinker, tiles, Facades, and other clay and ceramic goods.
Die folgenden Beispiele zeigen auszugsweise die Zusammensetzung der erfindungsgemäßen Beschichtungslösung, ohne Anspruch auf Vollständigkeit der Farb- und Effektreihe.The The following examples show in part the composition of coating solution according to the invention, without right to completeness the color and effect series.
Beispiel 1:Example 1:
GelbSilber optimaler Brennbereich 1090°C–1170°C)Yellow silver optimal burning range To 1090 ° C-1170 ° C)
- 21 g Budapur 2 (MAP)21 g of Budapest 2 (MAP)
- 18g Silres ME 4018g Silres ME 40
- 33g Engobe aus M500 (Mühlenbach) mit Litergewicht 1280–1320g/l; <18μm33g Engobe from M500 (Mühlenbach) with liter weight 1280-1320g / l; <18μm
- 17g Iriodin Gold Star 30717g Iriodin Gold Star 307
- 2g Ammoniummolybdat2g ammonium molybdate
Beispiel 2:Example 2:
CremeSilber: optimaler Brennbereich 1050°C–1190°C)CreamSilver: optimal Burning range 1050 ° C-1190 ° C)
- 12g Wacker BS 100112g Wacker BS 1001
- 11 g Kieselsol (40%)11 g silica sol (40%)
- 38g Engobe aus Setlitzer Kaolin (Mühlenbach) mit Litergewicht 1300g/l; <15μm38g Engobe from Setlitzer kaolin (mill stream) with liter weight 1300g / l; <15 microns
- 15g Phoenix Pigment PX 400015g Phoenix Pigment PX 4000
- 1 g Nanocor1 g Nanocor
- 1,5g Ammoniumvanadat1.5g ammonium vanadate
- 1g PVP K60 (ISP)1g PVP K60 (ISP)
Beispiel 3:Example 3:
BraunSilber: optimaler Brennbereich 1110°C–1220°C)BraunSilber: optimal Firing range 1110 ° C-1220 ° C)
- 30g Lithiumwasserglas aus eigener Herstellung (Li2O : 6,1 SiO2)30g lithium water glass from own production (Li 2 O: 6,1 SiO 2 )
- 40g Engobe aus Odenwälder Ton mit Litergewicht 1400 g/l; <5μm40g engobe from Odenwälder Clay with a liter weight of 1400 g / l; <5 microns
- 18g Iriodin 53218g Iriodin 532
- 1,75g Zirkonnitrat (50 % Lösung)1.75g zirconium nitrate (50% solution)
- 1,5g Böhmit1,5g boehmite
- 1,1 g Walocell 40000 PV1.1 g Walocell 40000 PV
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200410055104 DE102004055104A1 (en) | 2004-11-15 | 2004-11-15 | Cold/temperature hardenable coating solution, useful for e.g. decorating and/or functionalizing ceramic substrates e.g. bricks and tiles, comprises effective pigments and silicon-, aluminum-, boron- and/or zirconium containing stabilizers |
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Application Number | Priority Date | Filing Date | Title |
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DE200410055104 DE102004055104A1 (en) | 2004-11-15 | 2004-11-15 | Cold/temperature hardenable coating solution, useful for e.g. decorating and/or functionalizing ceramic substrates e.g. bricks and tiles, comprises effective pigments and silicon-, aluminum-, boron- and/or zirconium containing stabilizers |
Publications (1)
Publication Number | Publication Date |
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DE102004055104A1 true DE102004055104A1 (en) | 2006-05-24 |
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DE200410055104 Ceased DE102004055104A1 (en) | 2004-11-15 | 2004-11-15 | Cold/temperature hardenable coating solution, useful for e.g. decorating and/or functionalizing ceramic substrates e.g. bricks and tiles, comprises effective pigments and silicon-, aluminum-, boron- and/or zirconium containing stabilizers |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102008047307A1 (en) | 2008-09-16 | 2010-05-12 | JODLAUK, Jörg | Composition of a frit-free coating mass, where the frit and flux are replaced against silicon-free particle of large specific surface, useful to produce e.g. protective coatings for boilers, combustion boilers and furnace linings |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3121670A1 (en) * | 1981-05-30 | 1982-12-16 | Herberts Gmbh, 5600 Wuppertal | Pigmented, air-drying varnish and use thereof |
US4518726A (en) * | 1981-04-27 | 1985-05-21 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Metallic base paint |
EP0562531A1 (en) * | 1992-03-27 | 1993-09-29 | Kansai Paint Co., Ltd. | Method of forming coating films |
US20040116554A1 (en) * | 2001-11-29 | 2004-06-17 | Nirupama Karunaratne | White pearlescent paint compositions and coatings |
-
2004
- 2004-11-15 DE DE200410055104 patent/DE102004055104A1/en not_active Ceased
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4518726A (en) * | 1981-04-27 | 1985-05-21 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Metallic base paint |
DE3121670A1 (en) * | 1981-05-30 | 1982-12-16 | Herberts Gmbh, 5600 Wuppertal | Pigmented, air-drying varnish and use thereof |
EP0562531A1 (en) * | 1992-03-27 | 1993-09-29 | Kansai Paint Co., Ltd. | Method of forming coating films |
US20040116554A1 (en) * | 2001-11-29 | 2004-06-17 | Nirupama Karunaratne | White pearlescent paint compositions and coatings |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008047307A1 (en) | 2008-09-16 | 2010-05-12 | JODLAUK, Jörg | Composition of a frit-free coating mass, where the frit and flux are replaced against silicon-free particle of large specific surface, useful to produce e.g. protective coatings for boilers, combustion boilers and furnace linings |
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