CZ367592A3 - Process for preparing a freely flowing particulate composition for softening textile materials - Google Patents

Abstract

A process of producing a free-flowing spray dried particulate fabric softening composition is provided and comprises the steps of: (a) forming a crutcher slurry containing: (i) from about 5 to 40%, by weight, of a cationic quaternary ammonium softening compound; (ii) from about 0.5 to 15%, by weight, of an anionic and/or a nonionic detergent compound; (iii) from about 45 to 85%, by weight, of urea, the above percentages being based on the solios content of the slurry, in the absence of water; (b) mixing the crutcher slurry formed in (a) to provide a uniform mixture or dispersion having an average particle size of less than about 1.0 micron and thereafter; (c) spray drying the aforesaid mixture or dispersion in a spray tower wherein the water content of the mixture is substantially evaporated to provide free-flowing particles of a softening composition capable of being readily dispersed in water.

Description

TECHNICAL FIELD

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Vynále2 relates free tekoucí.J kohcěrS: róvarté particulate composition, spray-dried ^- softening textile fabrics which is readily dispersible in water, a process for preparing such composition and use thereof. In particular, the present invention relates to an effective fabric softening composition in a form suitable for conventional use, which may contain a relatively high proportion of cationic fabric softener and which can be economically packaged and shipped.

BACKGROUND OF THE INVENTION

Compositions suitable for softening or treating textile fabrics intended for use in household washing machines are widespread and commonly found on the market both in the United States and Europe. Usually, these compositions are aqueous liquids containing a cationic quartz as the principal active ingredient. an ammonium compound which provides a softening effect on the fabric to be treated in the washing process. Typically, these fabric softeners (commonly referred to as such softener compositions) contain about 5 to about 8% active cationic softener compound. In the United States, about 90 grams of a 6% active liquid fabric softener is typically added to a washing machine containing about 65 liters of water to the rinse cycle to achieve the desired &quot; acceptable fabric softening &quot;.

However, liquid fabric softeners have certain disadvantages related to the nature of these agents. The level of active cationic quaternary ammonium compound that can be introduced into an aqueous system is usually limited by such properties as the solubility of the quaternary ammonium compound and the flowability of the final product obtained.

Typically, the fabric softening compositions added in the rinse cycle contain quaternary ammonium compounds which typically have two long alkyl chains and which are substantially water insoluble materials. These softening compositions are therefore typically in the form of an aqueous dispersion or emulsion. It follows from the above that at higher concentrations of the active cationic softener compound, usually at concentrations above about 6% by weight, there are problems associated with the preparation of these products, stability (i.e., product separation), gel formation, and related problems with water dispersibility. At concentrations above about 9% by weight of the quaternary ammonium compound, the viscosity and stability of the aqueous liquid plasticizer are often unacceptable for conventional commercial purposes.

There are also economic disadvantages associated with the sale of liquid fabric softeners. In particular, these drawbacks are associated with the considerable cost of packaging and shipping bottles containing only dilute aqueous liquid products having a relatively low level of active softening agent. This packaging method also presents an environmental problem. The manufacture and disposal of plastic packaging, which is typically used for the manufacture of liquid household products, is incompatible with the requirements of customers in the United States and Europe that require recyclable materials that are readily biodegradable. Accordingly, there is a need in the art to develop particulate fabric softening compositions which can achieve relatively high concentrations of the active softening component, which compositions can be delivered in economical packaging forms.

Textile emollients in powder form are known from the patent literature. For example, U.S. Patent No. 2,940,816 discloses a fabric softening composition of a defined quaternary ammonium compound in combination with urea. U.S. Pat. No. 3,256,180 discloses a process for preparing a fabric softener comprising reacting urea with a quaternary ammonium compound in the presence of water to obtain a granular product. U.S. Patent Nos. 3,356,526 and 3,573,091 to Woldman et al. Disclose processes for preparing a quaternary ammonium compound based plasticizer powder by spraying a quaternary ammonium compound solution onto a carrier material in a quaternary ammonium compound. in particulate form, such as urea or sodium tripolyphosphate, to form carrier particles having a plasticizer as a coating.

U.S. Pat. No. 4,427,558 to David discloses a fabric softener in particulate form comprising quaternary ammonium compounds, urea, and lime soap, such as lime tallow soap. The process for preparing the plasticizer comprises preparing a liquid mixture containing the desired components, cooling the liquid to form a solid product, and then milling the product to form particles. Prior to milling, the solid product is allowed to ventilate for several hours, the term ventilation means a process whereby the solid product is left until the water content of these particles is brought to equilibrium with respect to the environment. According to the patent, the particulate product can also be prepared by spray cooling, by cooling the spray liquid mixture 2a to form a solid product without loss of water. The solid thus obtained is then milled and then vented.

European Patent Application No. 1315 (Procter & Gamble) discloses a process wherein molten particles of a quaternary ammonium compound and a dispersion inhibitor such as a fatty alcohol or a fatty acid are contacted with spray-dried granules of a basic detergent, which comprises a surfactant and a filler. The emphasis in this patent and other prior art patents is to prevent the cationic softening compound from being dispersed in the wash water to prevent inactivation of the softening compound in the wash solution. However, in the case of solutions according to these patents, in which an attempt is made to prepare quaternary ammonium compounds in the form of a dispersible powder in cold water, with particular focus on the application of the powder in a rinse (or rinse) cycle, at higher concentrations of said quaternary compounds.

SUMMARY OF THE INVENTION

The present invention provides a highly concentrated particulate fabric softening composition which can be prepared by spray drying to form particles of a softening composition containing, inter alia, up to about 40% of a cationic softening compound in combination with a nonionic and / or anionic surface coating. The particles thus obtained are readily dispersible in water and provide effective softening of the textile fabric.

Accordingly, the present invention provides a free flowing particulate fabric softening composition that is readily dispersible in water, comprising:

(a) about 5 to about 40% by weight of a cationic quaternary ammonium softening compound, (b) about 0.5 to about 15% by weight of an anionic and / or non-ionic detergent compound, and (c) about 45 to about 85% by weight of urea, the rest is water.

Preferably, the composition further comprises about 1 to about 10% by weight of the fatty acid alkanolamide.

The present invention also provides a process for the preparation of this free-flowing particulate fabric softening composition prepared by spray drying, which is readily dispersible in water, the process comprising:

(a) preparing a slurry (mixing with a crutcher) containing:

(i) about 5 to about 40% by weight of a cationic quaternary ammonium softening compound, (ii) about 0.5 to about 15% by weight of an anionic and / or nonantic detergent compound, (iii) about 1 to about 10% by weight of alkanolamide, and ( iv) about 45 to about 85% by weight of urea, wherein the percentages above are based on the solids content of the suspension in the absence of water, (b) mixing the stirred suspension obtained according to step (a) to prepare a homogeneous mixture or dispersion with average particle size less than about 1.0 microns, followed by (c) spray drying the above mixture or dispersion in a spray tower where substantially all of the water contained in the mixture is evaporated to form a free-flowing particulate softening composition that is readily disperse in water.

The present invention is based on the discovery that a fabric softening composition can be prepared in particulate form by spray drying to provide a composition that is much more concentrated than the commonly used liquid softeners used in the rinse (or rinse) cycle. The spray-dried particles thus obtained are dispersible in water, and these products can effectively soften the textile fibers in a wash or rinse cycle (or rinse) in a water bath. A major advantage of the composition of the present invention is that it is prepared in the form of homogeneous spray-drying particles by mixing the slurry before spraying itself so that the substances contained in the slurry are dispersed properly to form a mixture or dispersion with an average size. particles less than about 1.0 microns. These homogeneous mixtures of this type may be prepared by a variety of methods using various types of equipment, such as, for example, agitators, grinders or pumps, which are well known and used in the prior art, but according to the present invention it is preferred to use a so-called homogenizer. is, for example, a Gaulin homogenizer from Gaulin Corporation of Everett, Massachusetts, USA or Hilversum, The Netherlands, which consists essentially of a positive displacement pump connected to a homogenization valve unit to prepare a well-mixed mixture with an average particle diameter of less than 1 0.1 micrometer, and preferably having an average particle diameter of less than about 0.75 micrometer. In a preferred embodiment, the maximum particle size in the composition is less than about 5.0 microns, and more preferably less than about 3.0 microns.

The spray-drying process of the present invention employs, for the most part, the well-known technologies and equipment for producing particulate detergent compositions. Generally, in the process of the present invention, an aqueous mixed slurry is first prepared (agitated with a crutcher stirrer) which contains a mixture of water with a large proportion or most of the components required to form the fabric softening composition of the present invention. The solids content of the slurry is typically from about 20% to about 70%, preferably from about 30% to about 60%, and most preferably from about 40% to about 50%, with the remainder water.

The slurry thus obtained is atomized by pumping the slurry and passing it through an atomizing nozzle at a pressure in the range of about 6,895 kPa to about 13,790 kPa, and the atomized particles thus formed are dispersed in a spray drying column which is typically of conventional size. towers for similar purposes, i.e., a height in the range of about 10.67 meters to about 30.48 meters, and a diameter in the range of about 3.66 meters to about 9.14 meters. At the bottom, air at a temperature ranging from about 149 ° C to about 538 ° C is blown into the spray tower, which is in contact with the atoraized slurry, which air is a hot drying gas for the suspended particulate slurry and is thereby removed. of said suspension particles most of the contained water. The particles or grains thus obtained are collected at the bottom of the tower, with moisture and heating air rising to the top of the apparatus. Heat or water-sensitive components, such as perfume ingredients, can be added in addition to the particles thus obtained in the tower in a process of subsequently mixing or blending with other optional components used.

The slurry is preferably prepared by sequentially adding the various components of the slurry in such a way as to obtain the best miscible and readily pumpable suspension to the spray drying stage. The order of addition of the individual components may be varied depending on the circumstances. In a conventional embodiment, it is preferable to first add all or almost all the water to a crutcher with a crutcher (component mixing phase), which is preferably carried out at the temperature at which the treatment is carried out, and then the other components, urea, a quaternary ammonium softening compound, anionic and / or nonionic surfactant, fatty acid alkanolamides, and optional additional ingredients such as pigments, antioxidants and bactericidal (disinfectant) agents.

The temperature of the aqueous medium in the crutcher stirrer (component mixing phase) is typically in the room temperature range or higher, typically in the range of 20 to 70 ° C, and preferably in the range of about 25 ° C. up to 40 ° C.

The mixing phase of the components (in a mixer with a crutcher) to prepare a properly mixed homogeneous suspension can take place for any length of time, i.e. from as short intervals as about five minutes in small mixers and in the case of suspensions with high moisture content up to of about one hour intervals used in some particular cases, but preferably an interval limited by the upper limit of 30 minutes is used. After mixing the individual components in a crutcher stirrer, the slurry thus obtained is sent for further mixing into a homogenizer or other similar mixer or pump to obtain a homogeneous dispersion or mixture as above having an average particle size of less than about 1, 0 micrometer

The dispersion thus obtained is then transferred in a conventional manner to a spray drying tower which is located in the vicinity of the crutcher stirrer. The dispersion thus obtained is then injected at high pressure into the spray nozzles located in the spray tower (in which a countercurrent or co-current drying process is carried out), in which the spray particles of the suspension come into contact with the hot drying gas as they fall. or grains of a softening composition for softening textile fabrics while evaporating substantially all of the water. The moisture content of these particles is preferably about 2 to 4% by weight.

Among the cationic quaternary ammonium compounds which are a fabric softening compound are preferably imidazolinium salts, di-alkyl quaternary ammonium salts with long alkyl chains and di-alkyl quaternary ammonium salts with short alkyl chains of diesterified fatty acids with a long chain. Preferred imidazolinium salts of the present invention are represented by the following formula (I):

CH (I) wherein:

R is an aliphatic group having from 8 to 30 carbon atoms, and preferably an alkyl group or an alkenyl group containing 14 to 18 carbon atoms,

R ₂ and R ₃ independently represent any of the same substituents as or preferably represent lower alkyl or substituted alkyl having 1 to 4 carbon atoms such as haloalkyl, hydroxyalkyl, acylaminoalkyl and the like, and

X represents a water-soluble anion such as chloride, bromide, iodide, fluoride, sulfate, methosulfate, nitrite, nitrate, phosphate and carboxylate (i.e., acetate, adipate, phthalate, benzoate, oleate, and the like).

Me2i typical imidazolinium softening compounds include:

2-heptadecyl-1-methyl-1-oleylamidoethylimidazolinium ethosulfate,

2-heptadecyl-1-methyl-1- (2-stearoylamido) ethylimidazolinium sulfate,

2-heptadecyl-1-methyl-1- (2-stearoylamido) ethylimidazolinium chloride,

2-coconut-1- (2-hydroxyethyl) -1-benzylimidazolinium chloride, 2-coconut-1- (hydroxyethyl) -1- (4-chlorobutyl) imidazolinium chloride,

2-coconut-1- (2-hydroxyethyl) -1-octadecenylimidazolinium chloride,

2-tall oil fatty-1- (2-hydroxy-´1) -1-benzylimidazolinium chloride,

2-tall oil-1- (2-hydroxyethyl) -1- (4-chlorobutyl) 12 imidazolinium chloride,

2-heptadecenyl-1- (2-hydroxyethyl) -1- (4-chlorobutyl) imidazolinium chloride,

2-heptadecenyl-1- (2-hydroxyethyl) -1-benzylimidazolinium chloride, and

2-Heptadecenyl-1- (hydroxyethyl) -1-octadecylimidazolinium ethyl sulfate.

The general formula of long-chain di-alkyl quaternary ammonium salts can be represented by the following general formula II:

+

Y '(II)

R

AND

R-N-R!

R in which means:

R is selected from the group consisting of aliphatic radicals having 1 to 30 carbon atoms, preferably an alkyl or alkenyl group, further an aryl group (i.e. a phenyl group, a tolyl group, a cumyl group, etc.), an aralkyl group (i.e. a benzyl group) , phenethyl, methylbenzyl, etc.) and halo, amide, hydroxyl and carboxyl substituents of such groups, such as haloalkyl of 2 to 6 carbon atoms (such as 2-chloroethyl), and hydroxyalkyl of 2; up to 6 carbon atoms (such as

With the proviso that at least two of these substituents R are C 12 to C 30 and preferably C 12 to C 22 and the other are lower alkyl, and more preferably at least two R is C 12 -C 18 and the other are C 1 -C 4 lower alkyl (most preferably methyl or ethyl), and

Y represents the same anion as defined for X in formula I.

Typical quaternary ammonium salts of formula II include the following compounds: distearyldimethylammonium chloride, di-dimethylammonium chloride, dihexadecyldimethylammonium chloride, distearyldimethylammonium bromide, dihydrogenated tallowdimethyl ammonium dimethylsulfonate, distearyldimethylammonium, distearyldimethylammonium, distearyldimethylammonium, (hydrogenated tallow) dimethylammonium methosulfate.

Another group of preferred cationic fabric softeners are the di-lower alkyl quaternary ammonium salts of long chain diesterified fatty acids and the lower alkyl-lower hydroxyalkyl quaternary ammonium salts of long chain diesterified fatty acids. This group of cationic softeners for fabric softening can be represented by formula III:

O

II r ₄ ocr o II

L ₃ -NR ₄ OCR (III) wherein:

An RCO fatty acid residue of about 12 to 24 carbon atoms,

R ₂ and R ₃ independently represent a lower alkyl group or a hydroxyalkyl group containing 1 to 4 carbon atoms, and preferably 1 to 3 carbon atoms,

R ₄ represents a lower alkylene group having 1 to 4 carbon atoms, preferably 1 to 3 carbon atoms and most preferably 2 carbon atoms, that is, R ₄ represents a -CH ₂ CH ₂ - group, and

X represents a water-soluble anion as defined above.

The above compounds are commercially available, for example, from Stepan Chemical Co. having the trade name Stepantex, such as Stepantex VHR90, having the general formula IV:

ch ₂ ch ₂ oocr

AND

CH ₃ -N-CH ₂ CH ₂ OOCRX (IV)

AND

CH ₂ CH ₂ OH where:

RCO residue derived from tallow fatty acids or from coconut fatty acids, and

X may be chloride or sulfate.

These quaternary ammonium softening compounds are typically present in an amount of about 5 to about 40% by weight of the softening composition, preferably about 10 to 30% by weight, and most preferably about 15 to about 25% by weight.

Optionally, another softener component for softening textile fabrics is a fatty alcohol in which the hydrophobic moiety may be an alkyl or straight or branched chain alkenyl group containing from about 10 to about 24 carbon atoms, preferably from about 10 to about 10 carbon atoms. about 20 carbon atoms, in a particularly preferred embodiment of the invention about 12 to about 20 carbon atoms. Specific examples of such fatty alcohols include decanol, dodecanol, tetradecanol, pentadecanol, hexadecanol, octadecanol, lauryl alcohol, palmityl alcohol, stearyl alcohol, oleyl alcohol, and mixtures thereof. In addition, the fatty alcohol may be of natural or synthetic origin, such as C16 -C13 alcohols, which are prepared by Ziegler polymerization of ethylene.

The fatty alcohol may be present in the composition of the invention in small amounts relative to the amount of cationic fabric softener, such that the weight ratio of the cationic fabric softener to the fatty alcohol is, for example, in the range of about 6: 1 to 2: 1. a ratio of from about 5: 1 to about 3: 1.

The fatty acid alkanolamides preferably used according to the invention are those derived from fatty acid amides having an alkyl moiety of at least 12 carbon atoms. These compounds preferably have the formula V:

/ ^H

R — C — N II \

C _and H _2n OH wherein n is 2 or 3.

Preferably, the substance is coconut monoethanolamide.

The concentration of the fatty acid alkanolamide in the plasticizer composition of the present invention is generally in the range of from about 1 to about 10% by weight, preferably from about 1 to about 5% by weight. The combination of a fatty acid alkanolamide and a quaternary ammonium softener compound of the present invention provides excellent fabric softening effects.

The basic component of the fabric softening composition of the present invention is urea. The particles of the invention typically contain about 45 to about 85% by weight of urea, with a preferred urea content in the range of about 55 to about 75% by weight, and most preferably in the range of about 60 to about 70% by weight.

Another important component in improving the solubility and dispersibility of the particles is an anionic and / or nonionic surfactant. Anionic surfactants suitable for use herein include those surfactants having an organic hydrophobic group containing from about 8 to about 26 carbon atoms and preferably from about 10 to about 13 carbon atoms in their molecular structure and at least one water-soluble group selected from sulfonate, sulfate, carboxylate, phosphate, and phosphate to form a water-soluble detergent.

Examples of preferred anionic detergents include soaps, such as water-soluble salts (such as sodium, potassium, ammonium and alkanolammonium salts) of higher fatty acids or resin salts containing from about 3 to about 20 carbon atoms, and preferably about 10 to about 18 carbon atoms. Particularly preferred are the sodium and potassium salts of mixtures of fatty acids derived from coconut oil and tallow, such as sodium coconut soap and potassium tallow soap.

Anionic detergents also include water-soluble sulfated and sulfonated detergents containing aliphatic moieties, preferably alkyl moieties of about 3 to about 26 carbon atoms, and preferably about 12 to about 22 carbon atoms. Examples of such sulfonated anionic detergents include higher alkyl aromatic sulfonates such as higher alkylbenzene sulfonates containing from about 10 to about 16 carbon atoms in said straight or branched chain higher alkyl group, such as sodium, potassium and ammonium salts of higher alkylbenzene sulfonates, higher alkyltoluene sulfonates and higher alkylphenol sulfonates.

Other other suitable anionic detergents are olefin sulfonates, including long chain alkene sulfonates, long chain hydroxyalkane sulfonates, or mixtures of alkene sulfonates and hydroxyalkane sulfonates.

Other suitable anionic detergents include sulfated ethoxylated higher fatty alcohols of the formula:

RO (C ₂ H ₄ O) _n SO ₃ M in which it means:

R is a C 10-18 fatty alkyl moiety, m is from 2 to 6 (preferably a number corresponding to about 1/5 to 1/2 the number of carbon atoms in R), and

M represents a soluble salt-forming cation such as an alkali metal, an ammonium cation, a lower alkylamino group or a lower alkanolamine group, or a higher alkylbenzenesulfonate in which the higher alkyl contains 10 to 15 carbon atoms. The proportion of ethylene oxide in the polyethoxylated higher alkane sulphate is preferably 2 to 5 moles of ethylene oxide per mole of anionic detergents, most preferably three moles of ethylene oxide per mole of anionic detergents, especially when the higher alkanol is a compound containing 11 to 15 carbon atoms. A preferred polyethoxylated alcohol sulfate detergent is the product of Shell Chemical Company, marketed under the trade name Neodol 25-3S.

The most preferred water-soluble anionic detergent compounds are ammonium and substituted ammonium salts (such as monoethanolamine, diethanolamine and triethanolamine), alkali metal salts (such as sodium salts and potassium salts) of alkaline earth metal salts (such as calcium salts and magnesium salts) derived from higher alkylbenzene sulfonates, olefin sulfonates and higher alkyl sulfates. Among the above-mentioned anionic substances, the most preferred are sodium alkylbenzene sulfonates with a straight alkyl group (LABS), and particularly preferred are the above compounds wherein the alkyl group is a straight chain alkyl group having 12 or 13 carbon atoms.

Suitable nonionic surfactants include ethoxylated fatty alcohols having 12 to 20 carbon atoms, with an average degree of ethoxylation of 3 to 9. Preferably, the nonionic detergents are coconut alcohols containing an average of 6 or 7 ethoxy groups per molecule, and primary alcohols containing 14 to 15 carbon atoms containing 6 or 7 ethoxy groups per mole of higher fatty alcohol. For the purposes of the present invention, ethoxylated lauryl alcohol containing about 7 moles of ethoxy groups per mole of alcohol is particularly preferred.

Other suitable nonionic detergent compounds include the alkylpolyglycoside and alkylpolysaccharide surfactants as are well known in the art.

The amount of said anionic surfactant in the particulate composition of the invention may range from 0 to 8% by weight, preferably varying the percentage of the cationic softening compound as follows: about 1% to about 4% of the anionic surfactant % of the anionic surfactant when the percentage of the cationic compound is less than about 20%, and about 3% to about 8% of the anionic surfactant when the percentage of the cationic softening compound is in the range of about 20% to 40%, all said percentages are by weight based on the weight of the particulate composition. Typically, the level of anionic surfactant ranges from about 2 to about 4% by weight. Optionally, said nonionic surfactant is present in an amount of from about 0.5% to about 5% by weight, and is preferably present in an amount of at most about 1% by weight.

The fabric softening composition of the present invention may further comprise additional ingredients which do not adversely affect the stability and functional properties of the softening composition. Such other ingredients include perfumes, dyes, pigments, disinfectants, soil release agents, fabric fresheners, antioxidants, and anticorrosive agents.

DETAILED DESCRIPTION OF THE INVENTION

The free-flowing softening composition of the present invention and the process for its preparation will be illustrated by the following non-limiting example.

Example 1

According to this example, a granular fabric softening composition of the present invention was prepared having the following composition:

Component

Weight percent

DSDMAC ¹ 24

Nonionic surfactant ² 2

Sodium dodecylbenzenesulfonate 3

Coconut monoethanolamide 3

Urea 64

Moisture residue. Distearyldimethylammonium chloride ² Ethoxylated lauryl alcohol containing about 7 moles of ethoxylate per mole of alcohol.

In this procedure, 10.5 grams of the above softening composition was added to a top-loading washer in a rinse cycle, with a water temperature of 25 µg and a water hardness of 100 to 320 ppm. The dispersion time of the granular product in water was about 1.5 minutes.

The softness and hydrophilicity of the resulting fabric was then measured, and the values were compared with the measured softness of the fabric treated in the same scrubber with top loading with 42 grams of a conventional liquid fabric softener containing 6% quaternary ammonium softener. The fabrics treated with the granular softener composition of the present invention were noticeably softer, having equivalent hydrophilic properties to those treated with a commercially available liquid plasticizer.

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Claims (7)

PATENTOVÉ CLAIMS • Po i> 1. A process for preparing a free-flowing particulate kompoziceJ fabric softening obtained sputter ^{οη 3λπ} Ava drying which is readily dispersible in water, j · characterized in that it comprises; (a) preparing a slurry by blending with a crutcher, comprising: (i) about 5 to about 40% by weight of a cationic quaternary ammonium softening compound, (ii) about 0.5 to about 15% by weight of an anionic and / or non-ionic detergent compound, (iii) about 1 to about 10% by weight of alkane amide, and ( iv) about 45 to about 85% by weight of urea, the above percentages being based on the solids content of the slurry in the absence of water; (b) mixing the slurry obtained in step (a) to prepare a homogeneous mixture or dispersion having an average particle size. smaller than. about 1.0 microns, followed by (c) spray drying the above mixture or dispersion in a spray tower where substantially all of the water contained in the mixture is evaporated to form a free-flowing particulate softening composition that is readily dispersible in a water. 2. The method of claim 1, wherein the slurry further comprises about 1 to about 10% of the fatty acid alkanolamide. The method of claim 1, wherein: Said alkanolamide is coco monoethanolamide. 4. The process of claim 1 wherein the slurry comprises about 1 to about 8% of an anionic detergent compound and about 10 to about 40% of a cationic softening agent, wherein the above percentages are based on the solids content of said suspension. . > 5. The method of claim 1 wherein the slurry comprises up to about 2% by weight of a nonionic detergent compound. The method of claim 1, wherein the amount of anionic detergent varies according to the percentage of cationic compound as follows: about 1 to about 4% of the anionic detergent when the percentage of cationic softener compound is less than about% and about 3 up to about 8% of an anionic detergent when the percentage of cationic softening compound is in the range of about 20 to about 40%. 7. The process of claim 1 wherein the cationic softening compound is distearyldimethylammonium chloride.