CZ299089B6 - Composition for cleaning hard surfaces - Google Patents

Composition for cleaning hard surfaces Download PDF

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Publication number
CZ299089B6
CZ299089B6 CZ20031229A CZ20031229A CZ299089B6 CZ 299089 B6 CZ299089 B6 CZ 299089B6 CZ 20031229 A CZ20031229 A CZ 20031229A CZ 20031229 A CZ20031229 A CZ 20031229A CZ 299089 B6 CZ299089 B6 CZ 299089B6
Authority
CZ
Czechia
Prior art keywords
particles
liquid
composition according
particle size
abrasive
Prior art date
Application number
CZ20031229A
Other languages
Czech (cs)
Inventor
Baggi@Paola
Burgess@Helen
Fontana@Cinzia
Inamura@Takashi
Original Assignee
Unilever N. V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP00203831 priority Critical
Application filed by Unilever N. V. filed Critical Unilever N. V.
Publication of CZ299089B6 publication Critical patent/CZ299089B6/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry, mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials characterised by their shape or physical properties
    • C11D17/0008Detergent materials characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013Liquid compositions with insoluble particles in suspension
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials characterised by their shape or physical properties
    • C11D17/0008Detergent materials characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003Colloidal solutions, e.g. gels; Thixotropic solutions; Pastes

Abstract

The present invention provides liquid abrasive cleaning compositions for hard surfaces, which are clear aqueous liquid gels comprising one or more detergent surfactants and macroscopic abrasive particles, which are dispersed through the liquid. The gel and the particles preferably have different colors. The particles preferably have fairly uniform particle diameters of between 0.3 and 2.5 mm. The invention also provides a process for cleaning hard surfaces comprising the step of applying a composition according to the invention to the surface.

Description

CZ 299089 B6 Cleaning agent for hard surfaces

FIELD OF THE INVENTION The present invention relates to liquid compositions for cleaning hard surfaces. In particular, the present invention relates to clear liquid cleansing gels containing macroscopic solid particles.

Background Art

Liquid abrasive hard surface cleaners are well known in the art. They generally have a milky white color. At low shear, they have sufficient viscosity to keep the fine abrasive particles evenly dispersed in the liquid while behaving as true liquids while pouring from the bottle. The fine abrasive particles (powder) have a particle size of generally less than 200 microns in these compositions, and in most cases less than 100 microns. Well-known abrasives used in these compositions are silica, limestone (calcium carbonate), feldspar, and similar inorganic compounds, as well as some organic polymer particles, all having Mohs scale hardness to 6. Although many consumers widely use these compositions. used, some of them do not like their look or feel, or are worried that they may scratch delicate surfaces. Some liquid abrasive articles on the market consist of a gel opaque liquid in which a variety of coarse and fine, irregularly shaped abrasive polymer particles are dispersed. These particles vary in diameter, moving on one side from a value greater than 1 mm to the diameter barely visible to the naked eye on the other. As a result, the overall appearance of the product is unattractive. Thus, there is a need for a new liquid product for cleaning hard surfaces containing solid particles that is visually appealing to the consumer and at the same time effectively cleaned. In the skin cleansing industry, there are products known as "facial scrubs", which consist of a clear viscous liquid in which coarse abrasive particles are dispersed. Since these products come into intense skin contact, they must have a neutral pH. Generally, they contain little or no detergent surfactant, and within their presence such surfactants are selected from skin-fiendly and generally expensive. Such products are specifically designed for skin cleansing and are generally unsuitable for any other purpose, more particularly for removing hard-wearing, dirt-resistant dirt. US 5,741,770 and WO 97/41204 disclose liquid crystal cleaning compositions which are transparent or slightly cloudy and contain small amounts of abrasive particles. Such particles may be zeolites having a mean particle size of from 8 to 10 microns, amorphous silica of particle size up to 300 microns, or polyethylene powder of particle size up to 500 microns. WO 00/65019 discloses liquid abrasive cleaning compositions comprising a fine particulate abrasive and, in addition, microcapsules comprising various additional ingredients such as perfume, silicone oil and the like. Of course, with respect to the determined amount and particle size of the abrasive, the compositions are opaque or opaque. WO 00/36078 discloses urgently transparent laundry detergent compositions comprising at least 15% surfactant. The compositions are thickened to be capable of suspending macroscopic capsules containing additives that are desirable to keep separate from the thickened and highly alkaline detergent solution. Similar compositions, also for further use, are disclosed in GB 1,303,810. The capsules have no abrasive properties. Thus, although various liquid compositions containing suspended particles in a large particle size range and not shown, for various purposes and uses, are described in the prior art, methods and measures to enhance the visual appeal of such devices to consumers appear to be neglected.

SUMMARY OF THE INVENTION

The present invention provides liquid hard surface cleaning compositions which are clear aqueous liquid gels containing one or more detergent surfactants and macroscopic abrasive particles dispersed therein in a continuous manner. The present invention further provides a method of cleaning hard surfaces comprising the step of applying a clear aqueous liquid gel comprising one or more of the detergent surfactants and macroscopic abrasive particles dispersed therein in a continuous manner to the surface to be cleaned. Unless specifically stated otherwise, all percentages given herein are percent by weight, based on the total composition. The cleaning compositions of the present invention are clear, aqueous, liquid gels. Therefore, all components of these compositions, with the exception of abrasive particles, are, of course, water soluble. The viscosity 20 required to provide the composition with its gel consistency is obtained by adding suitable thickening agents that are capable of providing a clear solution. Such thickeners are known in the art and suitable examples include vegetable or microbial polysaccharide gums such as acacia, xanthan gum, alginates, and the like, and synthetic polymers, such as acrylic, methacrylic or maleic and homopolymers of these acids, and / or copolymers thereof with other monomers such as styrene, vinyl ethers and the like which are administered by various manufacturers under the trade names such as ACUSOL, POLYGEL, CARBOPOL, RHEOVIS and the like.

For the purposes of the present invention, the gel is considered to be clear when transmitting at least 50% of light 30 of any wavelength in the visible spectrum, i.e. from 400 to 800 nm and more preferably from 550 to 700 nm, measured in a 1 cm cell in the absence of dyes and abrasive particles. The light transmittance is preferably at least 70% and more preferably at least 90%.

Gels that are suitable for the purposes of the present invention generally have a viscosity of from 100 to 35,000 mPa · s, more preferably at least 250 mPa · s, more preferably from 300 to 750 mPa · s for 21 s -1 (measured by

With a Haake viscometer at 20 ° C). The low shear viscosity is such that the gel is capable of suspending macroscopic particles. In many liquid abrasive cleaners known in the art, the required visco-rye is achieved by using surfactant (structuring) mixtures, often in combination with electrolytes. Although it has been found that certain specific surfactant combinations under specific circumstances result in a transparent or translucent liquid crystal structure, such thickening systems are generally unsuitable for the purposes of the present invention. Most structured surfactant systems cause liquid quenching.

Abrasive Particles In order for the cleaning compositions of the present invention to visually affect consumers, these particles are macroscopic, that is, clearly visible to the naked eye. This is in contrast to most abrasive powder particles having an average particle size generally well below 0.3 mm and in most cases not more than 0.1 mm (100 microns). Thus, the particles of the present invention have an average particle size in the range of 0.3 to 2.5 mm, more preferably greater than 0.5 and not more than 1.5 mm. Further, the visual appeal of the compositions is substantially increased when the particles have a uniform particle size, meaning that they all have a particle size in the range of plus or minus 70% of the average particle size, preferably in the range of 5 ± 50% and even more preferably ± 30% of the average. particle size.

The abrasive particles are used in an amount of at least 0.1% and more preferably at least 0.5% by weight relative to the entire composition. To maintain the transparent nature of the total composition, the total amount of the particles is 20%, preferably 10% and even more preferably 5% by weight relative to the total composition.

These particles can be made of abrasive materials known in the art. They can thus consist of granules of one or more of the well-known inorganic abrasives such as silica, silicates, calcium carbonate (limestone) and the like. They may also consist of 15 polymer granules, such as polyethylene, polypropylene, polycarbonate granules and the like. Particularly suitable are biodegradable polymer granules, such as starch-derived plastics, well known in the art.

Alternatively, the abrasive particles may be made of softer materials such as hard waxes and 20 fats, hard fatty acids, hard fatty acid soaps, and the like. Such materials may also be mixed with fine particles of any of the known abrasives or other materials, preferably solid materials, suitable for improving the cleaning process and accordingly formed into granules of the desired size. The visual attraction of the particles and therefore of the total composition is further enhanced if the particles have a certain minimum sphericity, so that the ratio of the longest and the shortest diameter of the particle in any direction is at most 3: 1, preferably at most 2: 1 or even 1.5: 1.

Particularly preferred are particles with a rounded, preferably smooth, rounded, round 30 shape. Such particles may be made by a process whereby a melt of particulate material is formed and transferred to droplets which are subsequently cooled in a gas stream (air). Thus, various processes and suitable equipment are known in the art and can be used for organic abrasives provided that they have a sufficiently low melting point. High melting powders, such as inorganic abrasive powders, can be formulated into suitably shaped particles by various agglomeration techniques known in the art and, if necessary, by agglomerating binders. Although the cleaning compositions of the present invention may consist of colorless liquid and solid particles having their natural color (in many cases white), these compositions are considerably more attractive to the consumer when the liquid and particles have distinctly different colors. They may have different shades of the same color, for example, they may be dark blue particles in a light blue liquid, or more preferably have liquid and particles of contrasting color, for example white particles in blue, green or yellow liquid or vice versa, or may be colored particles in otherwise colored liquid. The pH of the detergents may vary over a wide range and will generally be in the range of 2 to 14. Certain surfaces are acid sensitive and in which case a pH of at least 3, preferably 3.5 or up to 4, is recommended. Often, fatty impurities are obtained at an alkaline pH, that is to say at a pH greater than 7 and more preferably greater than 7.5. A pH greater than 12 is generally not desirable. 50

Surfactants

Compositions of the present invention include one or more of a surfactant which may be selected from a wide variety of anionic, nonionic, cationic, amphoteric and zwitterionic surfactants, examples of which are given below. B6

A suitable class of anionic surfactants are water-soluble salts of organic sulfuric acid esters and sulfonic acids having an alkyl group of 8 to 22 carbon atoms or an alkylaryl group containing 6 to 20 carbon atoms in the molecular structure. Examples of such anionic surfactants are the water-soluble salts of: - long chain alcohol sulphates (i.e., having 8 to 22 carbon atoms) (referred to herein as PSA), especially those obtained by sulphating long aliphatic alcohols produced by 10 reduction of tallow glycerides or coconut oil; alkylbenzene sulfonates such as those having 6 to 20 carbon atoms; secondary alkanesulfonates. Also suitable are salts of: alkylglyceryl ether sulfates, especially ethers of long aliphatic alcohols obtained from tallow or coconut oil; - fatty acid monoglyceride sulfates; ethoxylated aliphatic alcohols containing 1 to 8 ethylene oxide units 20 (EO); alkylphenols of ethyleneoxy ether sulfates having from 1 to 8 ethylene oxide units per molecule and the alkyl groups of which contain from 6 to 14 carbon atoms; a reaction product of fatty acids esterified with isethionic acid and neutralized with an alkaline reagent. 25

A suitable class of nonionic surfactants can be broadly described as compounds produced by the condensation of simple alkylene oxides having a hydrophilic nature with an organic hydrophobic compound which may be aliphatic or alkylaromatic. The length of the hydrophilic or polyoxyalkylene chain that is attached to any particular hydrophobic moiety 30 can be readily adapted to provide a water-soluble compound having the desired balance of hydrophilic and hydrophobic elements. This allows the selection of nonionic surfactants with the correct HLB (hydrophilic-lipophilic balance) value. Specific examples include: - condensation products of aliphatic alcohols having 8 to 22 carbon atoms in a 35 (straight) or branched chain configuration with ethylene oxide, such as ethylene oxide and coconut alcohol condensates having 2 to 15 moles of ethylene oxide per mole of coconut alcohol; condensates of alkylphenols having a C 6 -C 15 alkyl group with 5 to 25 moles of ethylene oxide per mole of alkylphenols; condensates of the reaction product of ethylenediamine and propylene oxide with ethylene oxide, wherein the condensates contain from 40 to 80% by weight of ethylene oxide units and have a molecular weight of from 5,000 to 11,000.

Other classes of nonionic surfactants are: - alkyl glycosides, which are the condensation products of long chain aliphatic alcohols and 45 carbohydrates; tertiary amine oxides having the structure RRRNO, wherein one R is an alkyl group of 8 to 20 carbon atoms and the other substituents R are each alkyl or hydroxyalkyl groups of 1 to 3 carbon atoms, for example dimethyldodecylamine oxide; Tertiary phosphine oxides having the structure RRRPO wherein one additional substituent R is each alkyl or hydroxyalkyl groups of 1 to 3 carbon atoms, for example dimethyldodecylphosphine oxide; dialkyl sulfoxides having the structure RRSO, wherein one R is an alkyl group of 10 to 18 carbon atoms and the other substituent R is methyl or ethyl, for example methyl-tetradecylsulfoxide; fatty acid alkylolamides; alkylene oxide condensates of fatty acid alkylolamides; - alkylmercaptans. 10

Suitable amphoteric surfactants are derivatives of aliphatic secondary and tertiary amines containing an alkyl group of 8 to 20 carbon atoms and an aliphatic group substituted by an anionic, water soluble group, for example sodium 3-dodecylaminopropionate, sodium 3-dodecylaminopropanesulfonate and N-2- sodium hydroxydodecyl-N-methyltaurate 15. Examples of suitable cationic surfactants can be found among quaternary ammonium salts having one or two alkyl or aralkyl groups of 8 to 20 carbon atoms and two or three small aliphatic (e.g. methyl) groups such as cetyltrimethylammonium bromide. Examples of suitable zwitterionic surfactants can be found among derivatives of aliphatic quaternary ammonium, sulfonium and phosphonium compounds having an aliphatic group of 8 to 18 carbon atoms and an aliphatic group substituted by an anionic, water soluble group such as 3- (N, N). betaine-N-hexadecylammonium propane-25 betaine propane-1-sulfonate, betaine 3- (dedecylmethylsulfonium) -propane-1-sulfonate and betaine 3- (cetylmethylphosphonium) -ethanesulfonate.

Other examples of suitable surfactants are those commonly used as surfactants and described in well-known textbooks: "Surface Active Agents", Volume 30 1, by Schwartz and Perry, Interscience 1949 and Part 2 of the same publication by Schwartz,

Perry and Berch, Interscience 1958; in the current edition of "mcCutcheon's Emulsifiers and Detergents", published by the Manufacturing Confectioners Company; or in "Tenside-Taschenbuch" by H. Stache (2nd edition), published by Carl Haus Verlag, 1981. Anionic and nonionic surfactants and combinations thereof are particularly preferred. When selecting surfactants or combinations thereof, care should be taken to provide a clear solution. If necessary, hydrotopes such as sodium xylenesulfonate or sodium cumene sulfonate or other hydrotropes known in the art may be added. Surfactants are generally present in an amount of at least 0.1 wt% but less than 15 wt%, preferably 0.5 to 10 wt%, most preferably at least 1.0 wt% of the total composition.

Optionally Added Components 45 The compositions of the present invention may contain various optional ingredients well known in the art that purify the ability or attractiveness to the consumer. Thus, these compositions may contain builders (detergent builders and anti-encrustants because they reduce the level of aqueous calcium ions in the wash liquor and aid in the formation of alkaline pH, suspending loose impurities, etc.), chelating agents, electrolytes, organic solvents, active halogens. new or peroxygen bleaching agents, pH modifying agents, antifoaming agents, antimicrobial agents, preservatives, perfumes, insect repellents, and the like. B6

Way

The method of cleaning a hard surface comprises applying a suitable amount of the composition of the present invention to a hard surface and generally subsequently wiping the surface to be cleaned with the composition using a wipe or washcloth. The composition may be applied directly to the surface, or alternatively, the composition may first be applied to a wipe or washcloth (preferably wet) and then wiped with the surface facing the surface. In the event that the abrasive particles are made of a polymer or other relatively soft material, the compositions of the present invention are very suitable for cleaning delicate surfaces that otherwise would otherwise be scratched. EXAMPLE 1 A clear, liquid, blue-colored gel of the composition set forth below was prepared, containing a range of fatty acid granules having a diameter of 0.8 mm ± 20%. přísada obch. name supplier quantity in% phosphoric acid 0,050 nonionic surface, active substance Neodol 91.8 Condea DAC 3,000 polymer Carbopol 2623 Goodrich 0,280 silicon DB31 0,003 nonionic surface active substance Neodol 91.5 Condea DAC 2,000 sodium bicarbonate Baking Soda Solvay 0,100 preservative Proxel GXL Zeneca 0.020 Simiol 60 fatty acid granules Uniqema 1,000 NaOH to pH 8.0 0.110 perfume 0.270 blue dye Biu Patent Fiori 0.0006 demineraliz. water to 100 Example 20 A lively, liquid, green colored gel of the composition below was prepared, containing dispersed polyethylene granules of 0.8 mm ± 20% diameter.

This product had a viscosity of 380 mPa.s at 21 s < -1 > and at 20 < 0 > C and pH of 11. -6- CZ 299089 B6 additive trade name quantity in% xanthan gum Kelzan ST 0.50 diphosphonic acid Dequest 2010 0.75 NaOH 1.20 nonionic surfactant, ^ 12 " ^ 1S > 7 EO Dobanol 23 6,5 3,30 alkylbenzene sulphonic acid 1,72 monobutyl ether diethylene glycol Butyl Digol 2,00 fatty acid Accent 7907 0,09 dye Biu Patent In perfume 0,50 polyethylene granules AC 316 1,00 I demineralized water up to 100 EXAMPLE 3 A clear acidic gel (pH 4.5) was prepared for hard surfaces containing hydrogen peroxide 5 containing the composition below. In it, small pieces of fatty acid gold was dispersed, containing 10% by weight (relative to the piece or gold) of sodium bicarbonate and a diameter of 1.0 mm ± 20%. ingredient trade name quantity in% sequestering agent Dequest 2046 nonionic surface Lialet 111-5.5EO 2.0 active substance Dobanol 91 8EO 5.0 fatty acid (in solution) 0.30 I polyacrylate polymer Carbopol ETD 2623 0.30 hydrogen peroxide 3 00 citric acid (buffer) 0.08 sodium hydroxide as needed dye perfume gold fatty acids 2,0 -7-

Claims (12)

1. A liquid aqueous abrasive cleaning composition based on an aqueous gel for hard surfaces comprising one or more of a detergent surfactant and an abrasive particle, characterized in that the abrasive particles dispersed in the liquid are macroscopic with an average particle size. greater than 0.5 mm and at most 2.5 mm, and in that all particles have a particle size ranging from minus 70% to plus 70% of the average particle size. 10
The cleaning composition according to claim 1, wherein the average particle size is at most 1.5 mm.
3. A detergent composition according to claims 1 and 2 wherein all particles have a particle size within ± 50% of the average particle size.
4. A detergent composition according to any one of claims 1 to 3 wherein the particles have a roundness such that the ratio of the longest to the shortest particle diameter in any direction is at most 3: 1. 20
5. A cleaning composition according to claim 4 wherein the particles have a smooth round shape.
6. A detergent composition as claimed in any one of claims 1 to 5 having a viscosity of from 25 to 1000 mPa.s in 21 seconds.
7. A cleaning composition according to claim 1, wherein the liquid and the particles have different colors. 30
8. A detergent composition according to claim 7 wherein the liquid and the abrasive particles have contrasting colors.
9. A detergent composition according to claim 1, wherein the detergent composition comprises at least 0.1% but less than 15% by weight of surfactant, based on the total composition. 35
10. A detergent composition according to claim 1, wherein the surfactant is selected from anionic surfactants, nonionic surfactants, and mixtures thereof. 40
11. A detergent composition as claimed in any one of claims 1 to 10 comprising from 0.1 to 20% by weight of abrasive particles based on the total composition.
12. A method of cleaning a hard surface comprising the step of applying a cleaning composition to any surface of any one of claims 1 to 11.
CZ20031229A 2000-11-03 2001-10-15 Composition for cleaning hard surfaces CZ299089B6 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP00203831 2000-11-03

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CZ299089B6 true CZ299089B6 (en) 2008-04-23

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EP (1) EP1337616B1 (en)
JP (1) JP4113429B2 (en)
AR (1) AR031192A1 (en)
AT (1) AT285469T (en)
AU (2) AU2062702A (en)
BR (1) BR0115088A (en)
CA (1) CA2424455C (en)
CZ (1) CZ299089B6 (en)
DE (1) DE60107979T2 (en)
ES (1) ES2230389T3 (en)
HU (1) HU0303574A3 (en)
PL (1) PL196482B1 (en)
RU (1) RU2292386C2 (en)
WO (1) WO2002038720A1 (en)
ZA (1) ZA200302356B (en)

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GB2390097A (en) * 2002-06-28 2003-12-31 Reckitt Benckiser Nv Detergent gels containing coloured particles
WO2004013268A1 (en) * 2002-07-30 2004-02-12 Unilever N.V. Abrasive hard surface cleaning compositions
GB2393908A (en) * 2002-10-12 2004-04-14 Reckitt Benckiser Inc Thickened, abrasive containing, liquid disinfectant
US20050176614A1 (en) 2002-10-16 2005-08-11 Heinz-Dieter Soldanski Transparent abrasive cleaning product, especially manual dishwashing liquid
DE10248313A1 (en) 2002-10-16 2004-05-06 Henkel Kgaa Transparent abrasive cleaners, especially hand dishwashing detergents
SG154438A1 (en) * 2005-12-30 2009-08-28 Lam Res Corp Cleaning compound and method and system for using the cleaning compound
US7799141B2 (en) 2003-06-27 2010-09-21 Lam Research Corporation Method and system for using a two-phases substrate cleaning compound
EP1786392B1 (en) 2004-07-21 2011-08-24 Colgate-Palmolive Company Structured body wash
EP1874914B1 (en) 2005-04-21 2012-09-26 Colgate-Palmolive Company Liquid detergent composition
DK2308957T3 (en) 2006-12-15 2013-05-13 Colgate Palmolive Co Liquid detergent composition
EP2328998A1 (en) 2008-09-30 2011-06-08 The Procter & Gamble Company Liquid hard surface cleaning composition
ES2582573T3 (en) 2008-09-30 2016-09-13 The Procter & Gamble Company Hard surface liquid cleaning compositions
EP2336286A1 (en) * 2009-12-18 2011-06-22 The Procter and Gamble Company Composition comprising microcapsules
JP5658277B2 (en) * 2009-12-22 2015-01-21 ザ プロクター アンド ギャンブルカンパニー Liquid cleaning and / or cleansing composition
JP5559893B2 (en) 2009-12-22 2014-07-23 ザ プロクター アンド ギャンブル カンパニー Liquid cleaning and / or cleansing composition
CA2796947C (en) 2010-04-21 2015-11-24 The Procter & Gamble Company Liquid cleaning and/or cleansing composition
JP5997161B2 (en) * 2010-09-21 2016-09-28 ザ プロクター アンド ギャンブル カンパニー Liquid cleaning composition
EP2431451A1 (en) 2010-09-21 2012-03-21 The Procter and Gamble Company Liquid detergent composition with abrasive particles
JP6091045B2 (en) * 2010-09-30 2017-03-08 小林製薬株式会社 Abrasive composition
CN103608445B (en) 2011-06-20 2016-04-27 宝洁公司 Liquid cleaning and / or cleansing composition
US8852643B2 (en) 2011-06-20 2014-10-07 The Procter & Gamble Company Liquid cleaning and/or cleansing composition
RU2575931C2 (en) 2011-06-20 2016-02-27 Дзе Проктер Энд Гэмбл Компани Liquid composition for cleaning and/or deep purification
EP2537917A1 (en) 2011-06-20 2012-12-26 The Procter and Gamble Company Liquid detergent composition with abrasive particles
EP2719752B1 (en) 2012-10-15 2016-03-16 The Procter and Gamble Company Liquid detergent composition with abrasive particles
RU2656334C1 (en) * 2017-06-13 2018-06-05 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тверской государственный университет" Method of mechanochemical removal of scale deposits

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JP2004514026A (en) 2004-05-13
AT285469T (en) 2005-01-15
ES2230389T3 (en) 2005-05-01
BR0115088A (en) 2003-10-07
PL196482B1 (en) 2008-01-31
HU0303574A2 (en) 2004-03-29
AR031192A1 (en) 2003-09-10
CA2424455A1 (en) 2002-05-16
DE60107979D1 (en) 2005-01-27
PL361062A1 (en) 2004-09-20
RU2292386C2 (en) 2007-01-27
ZA200302356B (en) 2004-03-26
JP4113429B2 (en) 2008-07-09
EP1337616A1 (en) 2003-08-27
CA2424455C (en) 2009-10-06
WO2002038720A1 (en) 2002-05-16
AU2002220627B2 (en) 2006-06-01
AU2062702A (en) 2002-05-21
EP1337616B1 (en) 2004-12-22
HU0303574A3 (en) 2005-11-28
DE60107979T2 (en) 2005-05-19

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