CS258421B1 - Kompozioe na básl homo «or. copolymers of conjugated components - Google Patents

Kompozioe na básl homo «or. copolymers of conjugated components Download PDF

Info

Publication number
CS258421B1
CS258421B1 CS842270A CS227084A CS258421B1 CS 258421 B1 CS258421 B1 CS 258421B1 CS 842270 A CS842270 A CS 842270A CS 227084 A CS227084 A CS 227084A CS 258421 B1 CS258421 B1 CS 258421B1
Authority
CS
Czechoslovakia
Prior art keywords
copolymers
homo
πρημβρ
rpynn
kompozioe
Prior art date
Application number
CS842270A
Other languages
Czech (cs)
Other versions
CS227084A1 (en
Inventor
Vladimir V Mojsejev
Vladimir V Kosovcev
Olga K Popova
Zinaida N Markova
Vasilij A Sapronov
Ljudmila V Masagutova
Ivan F Sotnikov
Adrian P Trojickij
Viktor N Polumestnyj
Vladimir S Nenachov
Nadezda G Sosnovskaja
Irina L Plutalova
Felix J Kuperman
Faina S Kantor
Original Assignee
Vladimir V Mojsejev
Vladimir V Kosovcev
Olga K Popova
Zinaida N Markova
Vasilij A Sapronov
Ljudmila V Masagutova
Ivan F Sotnikov
Adrian P Trojickij
Viktor N Polumestnyj
Vladimir S Nenachov
Nadezda G Sosnovskaja
Irina L Plutalova
Felix J Kuperman
Faina S Kantor
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vladimir V Mojsejev, Vladimir V Kosovcev, Olga K Popova, Zinaida N Markova, Vasilij A Sapronov, Ljudmila V Masagutova, Ivan F Sotnikov, Adrian P Trojickij, Viktor N Polumestnyj, Vladimir S Nenachov, Nadezda G Sosnovskaja, Irina L Plutalova, Felix J Kuperman, Faina S Kantor filed Critical Vladimir V Mojsejev
Priority to CS842270A priority Critical patent/CS258421B1/en
Publication of CS227084A1 publication Critical patent/CS227084A1/en
Publication of CS258421B1 publication Critical patent/CS258421B1/en

Links

Landscapes

  • Materials For Photolithography (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

Řešení se týká výroby syntetických kaučuků, a přesněji komposice na bázi homo- nebo kopolymerů konjugovanýoh dlenů, která zahrnuje kaučuk a stabilizátor, v jehož funkci Je použit bílkovinný hydrolyzát kolagenu a obsahem karboxylových skupin 0,7 až 20 % v množství 0,01 až 3 >í Z hmoty kaučuku.The solution relates to the production of synthetic rubbers, and more precisely to a composition based on homo- or copolymers of conjugated elements, which includes rubber and a stabilizer, in the function of which is used a protein hydrolyzate of collagen and a carboxyl group content of 0.7 to 20% in an amount of 0.01 to 3% of the rubber mass.

Description

1 OIIHCAHHE H30BPETEHHH K ABTOPCKOMY CBHflETEJlhCTBY3aHBJieHo: 09.09.823a«BKa: R> 3489633/23-05MKH3: C 08 L 9/00| C 08 L 89/00 ABTOpbi: B.B.MowceeB, B.B.KocÓBuee, O.K.IIonoBa, 3,H.MapKOBa, B.A.CanpoHOB, JI. B.MacaryTOBa, Η.Φ.Cothhkob, Α.Π,ΤροΗΗΚΗή, B.H.IIonyMecTHbiň,B.C.HeHaxoB, Η.Γ.CocHOBCKaa, H, Jl.ílnyTanoBa, $.E.KynepMaHη Φ.Ο.Κβητορ 3aHBHTejib: aBTopbi

HaaeaHHe Η3θ6ρβτβΗΗ«: Κ0ΜΠ03ΗΙΙΗΗ HA OCHOBE ΚΑΡΒΟΗΕΠΗΟΓΟ KAYHYKA IIpeanojiaraeMoe Η3θ6ρβτβΗΗε othochtch x npoHSBOftCTBy CHHTeTHHecxMx xaywyxoB, B HaCTHOCTH X CTa6witI3aUHH ΚΟΜΠΟ3ΗΙΧΗΗ Ha HX OCHOBe. .

HsBecTHa κομποβηηηη Ha ocHoee xapConenHoro KaynyKa, BxmoManataH cTaCiuiHsa-

Top, HanpHMep N-$eHHn-2-Ha$THTiaMHH, ΟΗΟΚΤΗΛδγΤΗΠφβΗΟίΙ, Η-(ηΗΜβΤΗΠφβΗΗΠ)-2-ΗβφτιυιβΜΗΗ, 4,4-6HC-(2,6-nH-TpeT-f>yTHJi<t>eHoji) (1).

OffHaKO HSBecTHbie cTaCHnusaTopbi ΜβηοΒφφβκτΗΒΗΜ, oneHb noporn h toxchmhm.UeJib Η3θ6ρβτβΗΗΗ coctoht b noBbmieHHH cTaĎHJibHOcTH xayHyxa h ynymneHHH ca- HHTapHMX yCJIOBHň ΗΒΓΟΤΟΒΠβΗΗΗ ΚΟΜΠ03ΗΗΗΗ (3a CMeT CHHXeHHH TOKCHMHOCTH CT8-.SwiHsaTOpa). - nocTaBJíeHHaa uejib nocTHraeTca τβΜ, mto κομποβηηηη Ha OCHOBe xapConenHoroxayMyxa, BXjnoMatontafl CTa6»nH3aTop, conepxHT b xaw&amp;cTBe CTaGunKsaropa 6&amp;πκο-Bwft rHAPCuiHsaT Kon/iareHa c coflep*aHHeM xapGoxcHnbHux rpynn 0,7-20% b xojih-uecTBĚ 0,01-3% ot Maccu xayMyxa. yxasaHHuň rn^pojiKsaT xojuiareHa MoxeT BBOBHTbcn coBMecťHO h c flpyrHMH CTa-6WIH3aTOp3MH, HanpHMep aMHHHblMH, φεΗΟΠΒΗΜΜΗ, φΟοφΟρΗΜΜΗ Η ΤβΧ ΑβΠββ. Η3θ6ρβΤβΗΗβ HJUMOCTpHpyiOT npHMepbl. ΠρΗΜβρ 1.

Hrnce πρΗΒοηητ τηπημηηΛ πρκΜβρ nonyMeHHH 6enxosoro rnflpoJiH3aTa. B xon6y cMemanxoft noMemaioT 120 r HSMenbMeHHbix otipeaxoB GejixoBoň xonÓacHoň οΘοπομκη,nonyneHHoň H3 οπηπκοβοΗ o6pe3H, noCaBnator 200 μπ 0,2% βοαηογο pacTBopa cep- 258421 2

Hoň KHCJioTbi. TeMnepaTypy noflHHMaioT jqo 120°C b τβΜβΗΗβ 0,5 naca h 9tot mo-ΜβΗΤ npHHHMaioT aa HyneBoft OTcneT. B TeneHHe rtwpojiHaa OT6npa»T npo6bi pačT-Bopa Oenxa, aHajiH3npyioT nx Ha co/xepxaHHe xap6oxcnnbHbix rpyrin πβτεΗΐίΗΟΜβτρΗ-qecKHM τΗτροββΗΗβΜ b pac^eTe Ha cyxoft οοτβτοκ paCTBopa.

Hepes nac HarpeBaHHH CHCTeMa cTana roMoreHHoft. B TaCmme 1 πρΗΒβββιο,ι flaH-Hbie nonyueHHH Cenxoeoro rnffponn3aTa. AHanornuHbíM cnocoCoM nonyHaror rnflponHaaT c co,aepxaHHeM - COOH rpynn 0,7 hj20Z. AHajiorHHHO nonyuaioT npoMbiraneHHbie o6pa3iu>i 6enxoBoro rHflponHsaTa, Hcnojib-sya ajih rHfípojiHsa conHHyto xncnoTy. TaxHM xe oSpasoM nonyMawr 6enxoBbiň rn/ipo-JiHaaT H9 cnHJiKOBoň oCpesH, we3flpbi, xpoMOBOň cTpyxKH, xpoMOBoň o6pesH, xoxe-BeHHoň nbUiH, ΗβκοτορΗβ oCpasubi CenxoBoro rHflpojmaaTa nonynajiH ρηηροπη3ομCnHJlKOBOft O0pe3H H MeSApbl BOfloft. ΠρΗΜβρ 2. Κ I 80 mji naTexca "yTa^HeH - CTHponbHoro xayuyxa c cyxHM ocTaTKOM 92,4% Ηβcoflepxamero cTaCnnHaaiop, noSaannioT b BHfle 5% βοαηογο paCTBopa BenxoBbift rmr-pojiHaaT H3 οτχοηοβ xonCacHoft o6ojiohkh c pasnmHbíM coAepxaHHeM xap6oKCnnbHbixrpynn, nonyneHHhiň no npHMepy 1. B xoHTponbHbift oCpaseu CenxoBbiň ΓΗηρσηκββτ nefloCaBJíHWT. nocne Bbi#eneHHH xaywyxa oSbWHbíM cnocoOoM c πρΗΜβΗβΗΗβΜ cepHoftKHCJioTbi xpomxy xayuyxa cyrnaT πρκ 60°C b cyniHnhHOM πικβφγ. HcnbiTaHHe παπΗΜβρ-HOtt ΚΟΜΠΟ3ΗΗΚΗ ΠρθΒΟ«ΗΤ ΠρΗ ΤβΠΠΟΒΟΜ CTapeHHH ΠΡΗ 1 40°C Β ΤβΗβΗΗβ 30 ΜΗΗ CnocnegyHMUMM 3βΜβροΜ HHfleKca coxpaHeHHH nnacTHUHOcTH (ΗΟΠ)

nnacTHHHOcTb nocne cropaHHH HCI1 ------------------------------- x 100%.

nnacTH^HOcTb flo CTapeHHH

IlnacTHHHOcTb onpeflenHeTCH Ha CbicTpoAeftcTBynnieM nnacTOMeTpe yonneca. Pe-aynbTaTbi npHBeneHbí b Ta&amp;nnpe 2. Βτοροή KOHTpojibHbiň oCpaseu 3τογο x^ xaynyxa, nonyneHHbift c TpaflHimoHHbíMCTa6nnH3aTOpOM Ν-φβΗΗΠ-2-Η3φΤΗΠβΜΗΗΟΜ (1%), ΗΜββΤ HCII, paBHbtft 63%.

Kax BHflHO H3 ΤββΠΗΙφΙ 2, nOJIHMepHaH Κ0ΜΠ03ΗΗΗΗ 6β3 GeJIKOBOrO rnaponnsaTah 6ea CTa6nnH3aTopa aacTpyxTypHpOBanacb u He npHroflHa κ ynoTpeÓneHHio. Ποπη-MepHaa κομπο3ηι{ηη c CenxoBbíM γηλροπη33Τομ, πρΗΗβΜ jjaxe πρκ Manoň ero aosh-poBxe, ΗΜβετ Bbicoxyio cTaOiuibHocTb Ha ypoBHe TpannynoHnoro, ho τοχοηηηογοcTa6Hnn3aTopa. ΠρΗΜβρ 3. H3 naTexca CyTaflHeH - CTHponbHoro xayvyxa nonyHaioT o6pa3iy>i c paBHbíM xo-JlHHeCTBOM TpaflHHHOHHOrO CTa6HnH3aTOpa - ΤρΗ~(ί/-ΜβΤΗΠ6βΗ3ΗΠ)-φβΗΗπφθθφΗΤβ, aTaxxe b CMecH c SenxoBbíM γηαροπη33Τομ oSpesKOB KonSacHoň ββηκοΒοή ο6οποηχηc coflepxaHneM xap6oxcHnbHbix rpynn 5,1% H3 pacneTa 0,15% no OTHomeHHW κ xay-Hyxy. Β TaSnHqe 3 πρΗΒβΑβΗΜ pe3yjibTaTW no TennoBOMy cTapeumo nonuMepHMx κομπο-3nu,nň.

Kax BHflHO H3 Ta&amp;nnubi 3, onbrrnaa nonHMepHan χομπο3Ηηηη HaMHoro npeBocxo-'flHT CTa6lUIbHOCTb CepHftHOft ΚΟΜΠΟ3ΗΗΜΗ, ΠρΗΗβΜ flJXH flOCTHXeHHH BblCOXOft CTa~eiOTbHOCTH MOXHO yMeHbUIHTb ftOSHpOBKy ΤρββΗΗΗΟΗΗΟΓΟ CTa6HJIH3aTOpa. ΠρΗΜβρ 4« Κ 100 mji cepHňHoro naTexca δγτβ^ΗβΗ - CTHponbHoro xaynyxa «oGaBnaioT τρβ-AHUHOHHbie CTa6HJIH3aTOPbI ΗΠΗ HX CMecH Β COneTaHHH C BOflHblM paCTBOpOM 6&amp;ΠΚΟΒΟ-ro γηαροπη33Τ3 ,npH nonyneHHH κοτοροΓΟ Hcnojib3y»T cojiHHyio KHCJioTy c coflepxa-ΗΗβΜ Kap6oKCHJibHbix rpynn 5,1. Β Tafínnne 4 ripHBe/jeiibi nanHbie no HHflexcy coxpa-ΗβΗΗΗ nnacTHMHocTH (HCT) nocne CTapeHHH npH 140°C β τβηβΗΗβ 30 mhh.

Kax βηληο H3 Ta6jiHHW 4, floCaeneHHe ÓenxoBoro ΓΗβροπΗ3βτβ x TpanmíHOHHhiM cTa6HnH3aTopaM pe3xo noBbnuaeT CTa6«nbHocTb nojiHMepHoň κομπο3ηηηη. 258421 3 ΠρΗΜβρ 5. Β npoMhuaneHHbzx ycnoBHax κ naTexcy ΰγτβκηβΗ - cTHponbHoro xayqyxa Henpe-|PblBHO nOJjaiOT paeTBOp TpaflHIÍHOHHOrO CTa6HJIH3aTOpa - ΟΚΤΗΠφβΗΟΠΒΜΗΗΗοΠ CMOJIblb Macjie H3 pacqeTa 0,15% Ha nonuMepnyio κομπο3ηηηιο. Β τάβπΗμβ 5 npHBefleHti ^aHHbie no rennoBOMy CTapeHHio nojiyneHHoň ποπΗΜβρηοΠΚΟΜΠΟ3ΗΗΗΗ b cpaBHeHHH c xayqyxoM, b KOTopbiň 6enKOBbiň ΓΗΑροπΗ3βτ He no.ua-BancH. ΠρΗΜβρ 6. < K 100 μπ pácTBopa ncuiHHšonpeHOBoro xayqyxa b HsoneHTaHe c cyxHM οατατχοΗ9,2% ΑοββΒΠΗίοτ TpaflHuiHOHHbrii cTaCunnaaTop - N,NZ-«ΗφβΗΗΠ-Ι,4-φβΗΚΠβΗΛΗ3ΜΗΗb KOJiHnecTBe 0,2% Ha xayqyx b suflé TonyojibHO-MeTaHonbHoro pacTBopa κ 2%-HUft > BOflHbJň paeTBOp GejiKOBoro rHflponnaaTa, πρ» rnflpojiHse κοτοροro HcnojibSoaaHacojiHHan KHcnoTa, cogepxantero 5,1% xap6oxcHJibHbtx rpynn. CMecb TmareJthHO nepe-MemHBawT h BbiflejisiOT nojiHMepHyw xoMnosHiviio nápoM oCuuhum cnocoOoM. ΠαΑκΜβρ-nyio xoMno3HUHK> o6pa6aTbiBa»T npn 140°C β τβηβΗΗβ 30 mhu η onpeflenHioT HjvxexccoxpaHeHHB nnacTHHHOCTH (*ra6n.6) b cpaBHeHHH c KOHTponbHUM oOpasuoM xayqyxa,nonyqeHHoro 6ea OejixoBoro rutapojiHaaT a. ΠρΗΜβρ 7. K 200 μπ naTexca 6yTa#HeH —o/—MeTmicTHpojibHoro xayqyxa noCaBrtaioT SMyntcH»CTaCwiHSaTopa - οκτΗπφβΗοηβΜΗΗΗο# cmcjim b Macne H3 pacnera 0,17% Ha xayqyxh paBHoe KojiHnecTBo 1%-Horo pacTBopa CenxoBoro runpojiHsaTa, npjK nwponHsexoToporo HcnonbaoBana cojihHan KHcnoTa c coflepxaHHeM KapCoxcHJibHwx rpynn4,7%. BbmejieHHbiň xayqyx HarpeBawT řípu 140°C b TeneHHe 30 mhh η onpeaenHWTHHjflexc coxpaHeHHH nnacTHHHocTH (HCII). PesynbTaTM npHBefléwj b TaOjlHue 7. ΠρκΜβρ 8. K 100 μπ SMynbCHOHHoro nonnCyTanHeHa c cyxHM octhtkom 14,2%, coflepxamero1% N—φβΗΗΠ-2~ΗΒφΤΗΠ3ΜΗΗΒ, «oGaSJlHIOT 2%~Hblft paeTBOp CejlKOBOrO ΓΗΑρθΠΗ3βΤ8, .ηρκ ΓκηροπΗ3β κοτοροΓΟ HcnojibaoBaHa conaiian χηοποτθ, c conepxaHHeM xapGox-cwibHbix rpynn 5,1% (0,5% Ha xayqyx). HHflexc coxpaHeHHH nnacTHHHOcTH nocjie HarpeBa nonnMepHoň ΚΟΜΠΟ3ΗΚΗΗ ηρκ140°C b TeneHne 30 mhh Gbin paeen 69%, y χοητροπβηοΛ κομπο3ηηηη Gea GeJixoBQ-ro rHflpojiH3aTa - 40%. ΠρΗΜβρ 9. K 100 μπ naTexca CyTaflHeH —oř—MeTHncTHponbHoro xayqyxa, He coflepxanterocTa6njin3aTop, floĎaBnHWT 2%-HMft pacTBop GenxoBoro rHflpunHsaTa H3 Meaflpu ηπηxpoMOBoň cTpyxxH H3 pacneTa 0,7% na xayqyx. IIojiyqeHHyio noJiHMepHyx> komhosh-hhio Harpesax>T npn 140°C b Tenenne 30 mhh h aaMepnioT HHflexc coxpaHeHHH nnac-thhhocth c noMombio nnacTOMeTpa Yonneca. PesynbTaTbi npHBefleHbí BTaGnHfle 8. ΠρΗΜβρ 10. Κ 100 μπ naTexca GyTaflHeHHHTpwibHoro xayqyxa c cyxHM οετβτκοΜ 14,2%,coflepxaiqero 1% Φθηοπβηογο cTaGiuuiaaTopa 4,4'-6Ηθ-(2,6-ΑΗ-τρβτ-6γτΗπφβΗθπβ),flo6aejiHK)T 2%-Huň pacmop Genxosoro rnnponn33Tan3 pacqeTa 0,3% GenxoBororHřJj*ponnsaTa Ha nooiHMep. BbifleneHHyio nonHMepHyn κομποβηηηιο o6pa0aTbffla»T ηρκ 140Cb TeqeHHe-60 mhh b cpaBHeHHH c κοητροπβημμ oCpasijoM, coflepxantHM τοηΒΧΟ φβ-HonbHbiň cTaCHnHsaTop. KoMnosHHHfl c ββπκοΒΜΜ rHApantoaroM Gbina ΗβΜΗΟΓΟ CTa- • CwibHee: Η0Π paBHo 89%, y xoHTpojibHoň komhoshhhh Η0Π paBHo - 71%. * ΠρΗΜβρ 11. B 100 μπ naTexca cononHMépa GyTaflHeHa, CTHpona h MeTaxpHnoBoft KHcnoTU c25,2% cBHsaHHoro CTHpona h 1,9% xapGoxcHHbHbix rpynn, cyxHM οοτβτχομ 19,3% 258421 4 floCaariHioT 2,1%-Hbiň pacTsop 6&amp;πκοβογο rHAponHsaTa, nonyneHHoro πρκ Hcnontso-BSHHH COnHHOft KHCJIOTfel, C CORepXaHMeM KapČOKCHBbHMX rpynn 4,7%i B KOHTpOJlb“HMň oCpaaey cTaOnriHaaTop He AoCasjísMT. Πρκ τβπποβΟΜ crapeHHH (140°C, 30 mhh)ΠΟΠΗΜβρΗΟΗ ΚΟΜΠΟ3ΗΗΗΗ C fieJlKOBMM rHAPOJlHSaTOM βΜΠΉ ΗβΜΗΟΓΟ CTae«JlbHee: HCII paBHO 65%, κοητρολμηΛ oBpaaeu aacTpyKTypHBancn - HCII paBHHJioc* 171%. ΠρΗΜβρ 12. K 100 μπ cepHňHoro naTeKca CyTaflHeH-cTHpojibHoro xayqyxa, coflepxaetero1,1% craÓHJiHsaTopa - Ν-φβΗΗΛ-2-Η3φτκπβΜΗΗβ, flo6aBnH»T b BHffe 2%-ηογο pacTBO-pa CenKOBbiň rHApojiHaar c coftepxaKHeM KapOoKcanbHbK rpynn 7,0%, nonyneHHbjftΓΗΑροηΗΒΟΜ crouiKOBoft ronbeBoň οβρεβΗ γηαροοκηοηο xanbUHA na pacyera 0,5%na KaywyK.

IlonyueHHyio κομπο3ηαηκ» BWflenHWT h cyuaT oCumhmm cnocoOoM. B KOHTponbHbiň o6pa?eu CenKOBwň rnApojiHaaT Ηβ nonajoT. Ilocne TennosorocTapeHHH πρκ 140°C b Tenemie 30 mhh KOHTponbHbfó oCpagey HMen hkackc coxpa- ΗβΗΗΗ nnacTHHHOCT» paiiHbift 63%, onbiTHMň oCpasen - 89%. ΠρΗΜβρ 13. CBoňcTBa nojiHMepHoň κομποβμκηη na ocHoee KaynyKOB h Οβηκοβοτο nmponHsa-Ta c coAepxaHHeM KapfioKCHnbHbix rpynn 5,3%, nonyneHHoro γηαροπη9ΟΜ oOpesxoBronbH conHHoň KHcnoToň, nccnep,ywT b cTaimapTHott pesHHe κ b προτεκτορΗοΛipesHHe..

YcTaHOBjíeHO, hto pesHHbí Ha ocHoee xayqyxoB, nonyneHHbix c HcnojibSOBaHHeMCejiKOBbix rHAPOnusaTOB, to ecTb προτβκτορΗβη pesima xapaxTepH9yx>TCH Hecxonb-*ko 6onee BbicoKoň TeMnepaTypocTOňKocTb», conpoTHBneHHeM TennoBOMy cTapemm,MeHbmeň non3yuecTbw, nynmHMH ycTanocTHbíMH CBoňcTBaMH npn noBbsneHHbix TeMnepa-Typax no cpaBHeHH» c KOHTponbHoň (TaCrauibi 9, 10).

KpoMe oTMeqeHHbix npeuMyntecTB, onuTHHe peamtbi oCnanajoT Taxxe nynmHMH ynpy-ro - rHCTepe3HCHb!MH CBOÍtcTBaMH η ocoC^hho npn noBbímeHHfatx TeMneparypax, H 6o-nee bmcokoA KoresHOHHoň npoHHocTb». ΦΟΡΜΥΛΑ H30BPETEHH8 Κομπο3HUHH Ha ocHOBe KapGoyenKoro xaynyxa, BKrnoHaiamaa cTaCnunoaTop, οτπη-naromaaca τβΜ, ητο, c nenwo noBumemut cTaCuntHocTH xaynyxa h ynynoeHHa caHH-TapHbtx ycnoBHft HaroTOBneHHH κομπο3ηηηη, nocnenHHH conepMHT b xanecTBe CTa- .CuriHaaTopa δβηκοΒωή γηαροπη9Βτ xonnarena c coflepacamieM xapCoxcHnbHbix rpynn0,7-20% b xojiHuecTBe 0,01-3% οτ Maccbi xayyyxa.

HcTOWHHKH ΗΗφορΜβΠΗΗ, npHHHTbie ΒΟ ΒΗΗΜβΗΗβ npH 3KcnepTH3e: 1. ΟτβρβΗΗβ h cTaCiviHSanHH CyTaftHen - cTHponbHbix xayHyxoB, M., UHHHT3-ΗβφτβχΗΜ, 1976 r., c.3-22 - προτοτκπ.

P E Φ E P A T

Κ0ΜΠ03ΗΙΙΗΗ HA OCHOBE ΚΑΡΒΟΙΙΕΠΗΟΓΟKAYHYKA Η3ο6ρβτβΗΗβ othochtch X npoH3BOflcTBy cHHTeTHwecxHx KaynyKOB, a TOHHeeK ΚΟΜΠΟ3ΗΗΗΜ Ha ocHOBe KapČouenHoro Kaynyxa. npefljiaraeMaa κομποohijhh BKjnouaeT xapConenHuň xaynyK h οτβ6ΗΠΗ3βτορ, bxanecTBe κοτορορο HcnojibsoBaH 6ejixosuh rHAponnsaT Konnarena c co^epacanHeMxapGoxcHJibHbix rpynn 0,7-20% b KojnmecTBe 0,01-3% οτ Maccbi xayHyxa. IIpH9HaHO Η3θ6ρβτβΗΗβΜ no pesynbTaTaM 3KcnepTH3M, ocymecTBneHHoft FocynapcT-

BeHHbíM ΚοΜΗτετοΜ CCCP no AenaM Η3θ6ρβτβΗΗϋ η οτκρωτκή. 258421 5

TaCmnia I ΚΗΗβτΗκβ nojiyMeHHH OejiKoro rnflpojiH3ara

BpeMH rHApojiHaa, Cyxoft οοτβτοκ ConepxaHHe Mac rHflpcwiHaaTa,/? KapOOKCHJlbHbIXrpynn, Z 0 27,7 2,6 0,5 32,6 3,2 2,0 36,7 3,6 7 36,7 5,3 23 36,7 6,7 30 36,7 7,5

TaftnHua 2 CTa6nJlbHOCTb ΚΟΜΠΟ3HUHH Ha ocHOBe KayMyxá,ΗΒ3ΒβΗΗΟΓΟ B npHMepe 2, H SeJIKOBOTO ΓΗ«ρθΠΗ3ΒΤβ CoflepxaHHe Kap-6oKCHJIbHblXrpynn, % flóSHpoBKa CejiKo-ΒΟΓΟ ΓΗΑροηΗΒβΤβ, z UCTI, Z 0 0 106 (KOHTpOJIbHblň) 2,6 0,15 61 2,6 0,5 51 3,2 0,1 67 3,2 0,25 63 4,1 0,11 65 5,3 0,11 70 5,3 0,01 53

TaCjiHua 3 Βπηηηηθ 6ejiKoro rHAPonnsaTa Ha cTaCnnbHOCTbnOJIHMepHbK KOMnOSHIjHft

CTaCKnnsaTOP, Z ΗΟΠ,Ζ CoflepacaHMerenn, Z(150°C; 60 mhh)’ rpH“ (οΙ-ΜΘΤΗΠΟβΗ-3ΗΠ )-φβΗΗΠφΟϋφΗΤ BenKOBuft rHAponnaaT 1,2 0 4 8,3 0,6 0 34 10,2 1,2 0,15 76 3,7 0,6 0,15 75 3,9 0 0,15 41 , 6,5 258421

TaCjiHiia 4.

BnHHHue SenKOBoro rHjqpojiHsaTa Ha CTaGwibHocTb Kayqyxa, HaaBaHHoro bnpHMepe 4 IP onbiTa 1. CTaCwmaaTop

pioBupoBKa, Z “j~ BClI, Z

BejiKOBbiíi rmxponttaaT, npw nojiyue-HHH ΚΟΤΟΡΟΓΟ HCnOJIbSyWT COJIHHyK) KHCJiOTy 0,4 64 2. N-(ηΗΜβΤΗΠφβΗΗη)-2-ΗβφτηηβΜΗΗ 1.2 54 3. N- (ΑΜΜβΤΗΠφβΗΗπ) -2“Ha4)THnaMHH 1.2 CenKOBbiň rnflpoJiH3aTt πρκ nonyve- 82 HHH ΚΟΤΟΡΟΓΟ HCnOJIb3y»T COJlHHyK) KHCJiOTy 0,4 4. ,HHOKTHJi6yTHn<i>eHOJi 1.0 33 5. JÍHOKTHJl6yTHJI<J>eHOJI 1,0 fieJiKOBuň rHAPOJiHsaT, npw nojiyne-. 87 HHH ΚΟΤΟΡΟΓΟ HCHOJlbSyiOT COJlHHyn KHCJIOTH 0,4 6. Ν“φβΗΗ1Ι—2—ΗβφΤΗΙΙβΜΗΗ 1,2 63 7. Ν-φβΗΗΠ-2-ΗβφΤΗΠβΜΗΗ 1,2 CeJiKOBuň rMApojiusaT, πρκ nojiyue- 88 HHH ΚΟΤΟΡΟΓΟ HCnOJIb3yWT COJlHHyH) KHCJiOTy j 0,4 8. βΗφβΗΗJiaMHH, ajlKHJlHpOBaHHblft CTHpO - JIOM 1,0 29 9. ΑΗφβΗΗΠβΜΗΗ, ajlKWlHpOBaHHblň CTHpO „· JIOM 1,0 CejiKOBbiň rHApojiHsaT, npH nojiyue- 85 HHH ΚΟΤΟΡΟΓΟ HcnojibsyioT COnBHyiO KHCJiOTy - 0,4 10. NNř“6HC(ΑΗΜβΤΗΠφβΗΗΠ)-Ι,4-φβΗΗΠβΗ - A«aMHH. 0,3 . 30 11. NNř -6Hc(flHMeTHml>eHHJi)-1,4-φβΗΗΠβΗ - «ΗβΜΗΗ 0,3 GeJiKOBbiň rHApojlH3aT, npH nojiyHeHHH > 86 ΚΟΤΟΡΟΓΟ HcnOJlb3yiOT COJIHHyiO KHC“ jioTy 0,42 258421 7

TaOmma 5. ΚηκΗΗΗβ δ&amp;πκοΒΟΓΟ rnflpo.nH3aTa aa cTaCnnbHocTb

KaywyKa, Ha3BaHHoro b -------------------- 1 npHMepe 5 ————i Ν’ CTa0KJiH3aTop AosHpoBKa, X HCn, X(140°C,30 mhh) Ί. 0κΤΚΠφβΗΟΠ3ΜΗΗΗ3Η CMona 0,16 79 2. ΟκΤΚΠφβΗΟΠβΜΗΗΗβΗ CMona ČejiKOBbiň rHApoHHsaT,npH nonyqeHHM κοτορο-ro HcnojibayioT cojiHHyioKHcnory « 0,16 0,15 96

Ta6nHqa 6. CTa6nnbHocTb nojiHHSonpeHOBoro Kayuyxa Iřlř CTaOiuiHaaTop flOSHpOBKa , X ] Hcn» 1. N,N(“ ΑΗφβΗΚΠ -

1,4 - φβΗΚΠβΗΑΗβ“MHH 2. Ν,Ν1- ΑΗφβΗΚΗ”1,4“ φβΗΚΠβΗ“ΑΗβΜΗΗ

OanxoBuň γηαροπη-• 33Τ, πρκ ΓΗΑραΠΜ3β κοτορογο Hčnohbso“BaMa cojiHHaa khc-ηοτβ 0,2 50 0,2 93 3,0

TaCmma 7.

BnHHHHe CenxoBoro rHAPOAHsaTa Ha cTaOwibHocTb6yTaA»eH - 2 - MeTWicTHpojibHoro Kayqyxa N>N>

flo3HpoBKa cTaCHAHaaTopa, X

HCII, X ΟκΤΚΠφβΗΟΠβΜΗΗ“Haa CMona

EejiKOBbiň γηλρο,πμ-33T, ΠΡΗ ΓΗΑΡΟΠΗ”ae κοτορογο Hcnonb-soeaHa coiiHMaa khc-JiOTa 1. 2. 0,17 0,17 0,01 60 68 258421 8

ΠροΑοπχβΗΗβ Ťa6n,7, flo3npoBKa cTaOtunisaTopa. X HCn, X ΟκΤΗΠφβΗΟΠβΜΗΗ-Han CMona BenxoBuft rsmpojjH“a ar, npw rompojiH-3β ΚΟΤΟρΟΓΟ HCnOAb**soBaHa conMHaa khc,- nora • * 3. 0,17 0,10 70 4. 0,17 0,20 84 5. 0,17 0,31 89 Ta&amp;nHua 8. BnnHHHe GejiKOBux rnflpajiHsaTOB Ha CTa6unbHocTi> OyTaflHeH - cTupontHoro xayuyKa 4 Hctomhhk KOjuiareHa ftna CóAepxaHHe Kap- ββπκοΒΟΓο rHApojiuaaTa 6OKCIUlbHblXrpynn, 7, HCfl, Z 1. KoHTpojibHbiň, oTcyTCTBHe OTcyTCTBHe Kap- 106 KOJuiarena 6OKCHJIbHblX rpynn 2. Me3ftPa, ΓΗΑΡ0ΠΗ3ΟΒ8ΗΗ8Η 16,1 67 •' cepHoň KHcnoToň 6es 17,9 61 o6e3XHpHBaHHH 20,0 . 59 3. XpoMOBaa cTpy«Ka 0,7 63 1,1 65 2,0 70 6,4 53 4. Meaflpa, rHflpojiHSoaaHHaHBofloň 2,4 ¢3

Ta&amp;roma 9.

CsoftcTBa cTanflapTHbix pe3HH, nonyneHHux Ha ocHose KaynyKOB,HSrOTOBJíeHHUX C ΠρΗΜβΗβΗΗβΜ 6&amp;ΠΚΟΒΟΓΟ ΓΗΑρΟΠΗΒβΤΘ N>N> ΠΠ noKaaaT&amp;nn OnuTHue KayuyKH KOHTpOJlbHUe KaynyKH 1 2 3 4 1. YcnoBHoe HanpaxeHHe npn300Z pacTHxeHHH, Míla 4,3 4,6 2. ýcnoBHafl npoMHocTb npupacTflxeHHH, Míla 23,6 22,8 3. OTHOCHTenbHoe y^BHHeHHenpn paspuBe, Z 742 695 258421 "Ί, ΠροΛΟΠΜβΗΗβ TaQji.9 1 2 3 * ' · ' 4. ConpoTHBneKHe paaxjHpy, kH/m 41 45 5. TeepflocTb no IDopy, ycn. efl. 52 54 6. 3nacTMMMocTb no OTcKoxy, X, npn 20°C 27 32 7. K/E 0,49 0,48 8. nojiayqecTb, X (120°C, 100 γ/μμ2) 33 4! 9.. ΚοΒφφκμΗβητ TennoBoro cTapeHna (1OO°Cx72h) 0,29 0,22 10. KoreaHOHHafl nponHocTb, Krc/cM 1,2 0,40

TaCximja 10. CBoňcTsa προτεκτορΗΜΧ pesu» N*N> nn ΠθΚ83βΤ6ΑΗ OnuTHue xaynyxH KoHTponbHue,xaynyxH 1 1 3 + 1. YcnoBHoe HanpaxeHHe řípu 300X pacTHxeHKa,ΜΠβ 5,5 4,9 . 2. YcnOBHaa npOMHOCTbnpH'pacTaxeHHU, ΜΠβ 18,3 18,5 3. OTHOCHTejihHoe yflnnHe-HHe npn paspuBe, X 635 709 4. ConpoTHBneHHe paannpy,kH/m 63 62 5. TBepAoerb, ycn. efl. 58 57 6. □nacTHMHocTb no otcko-xy, X πρκ 20°C 35 32 πρκ 100°C 45 42 7. K/E: npn 20°C 0,51 0,53 πρκ tOO°C 0,36 0,39 8. TeMnepaTýpocToňKocTb (100°C) 0,38 0,30 9. ΚοΒφφκΰκβΗτ TennoBorocTapnnHH: 72qxlOO°C 0,54 0,51 120nxl00eC 0,41 0,39 25842) 10 ΠροΑοηχβΗΗβ Ta6n.10 1 2 3 4 to. KcTHpaeMocTb M3/Tflx 53 46 11. rio/iayqecTb, 2(12O°C, 100 γ/μμ2) 74 92 12. YcTanocTMaa euHocntr-BocTb (100°C, 202), κμ 17698 10015 13. ConpoTHBJíeHHe μμογο-KpaTHOMy pacTHKeHHio, κιχ: 20°C, 1502 2,10 2,85 70°C, 1002 46,5 27,3 14. Kore9HOHHax npoMnocTb,KTc/cM 1,0 0,30 258421

1 OIIHCAHHE H30BPETEHHH TO ABTOPCKOMY CBHflETEJlhCTBY3aHBJieHo: 09.09.823a «BKa: R> 3489633 / 23-05MKH3: C 08 L 9/00 | C 08 L 89/00 ABTOpbi: BBMowceeB, BBKocÓBuee, OKIIonoBa, 3, H.MapKOBa, BACanpoHOB, JI. B.MacaryTOBa, oth.Φ.Cothhkob, Α.Π, ΤροΗΗΚΗή, BHIIonyMecTHbion, BCHeHaxoB, Η.Γ.CocHOBCKaa, H, Jl.ynyTanoBa, $ .E.KynepMaHη Φ.Ο.Κβητορ 3aHBHTejib: aBTopbi

HaaeaHHe Η3θ6ρβτβΗΗ «: Μ0ΜΠ03ΗΙΙΗΗ HA OCHOBE ΚΑΡΒΟΗΕΠΗΟΓΟ KAYHYKA IIpeanojiaraeMoe Η3θ6ρβτβΗΗε othochtch x npoHSBOftCTBy CHHTeTHHecxMx xaywyxoB, B HaCTHOCTH X CTa6witI3aUHH ΚΟΜΠΟ3Ο Ha HX OCHOBe. .

HsBecTHa κομποβηηηη Ha ocHoee xapConenHoro KaynyKa, BxmoManataH cTaCiuiHsa-

Top, HanpHMep N $ eHHn-2-Ha $ THTiaMHH, ΤΗδγΤΗΠφβΗΟίΙ, Η- (ηΗΜβΤΗΠφβΗΗΠ) -2-φβφτιυιβΜΗΗ, 4,4-6HC- (2,6-nH-TpeT-f> yTHJi <t> eHoji) ( 1).

OffHaKO HSBecTHbie cTaCHnusaTopbi ΜβηοΒφφβκτΗΒΗΜ, oneHb noporn h toxchmhm.UeJib Η3θ6ρβτβΗΗΗ coctoht b noBbmieHHH cTaĎHJibHOcTH xayHyxa h ynymneHHH Ca- HHTapHMX yCJIOBHň ΗΒΓΟΤΟΒΠβΗΗΗ ΚΟΜΠ03ΗΗΗΗ (3a cMet CHHXeHHH TOKCHMHOCTH CT8-.SwiHsaTOpa). - nocTaBJíeHHaa uejib nocTHraeTca τβΜ MTO κομποβηηηη Ha OCHOBe xapConenHoroxayMyxa, BXjnoMatontafl CTa6 »nH3aTop, conepxHT b xaw &amp; cTBe CTaGunKsaropa 6 &amp; πκο-BWFI rHAPCuiHsaT Kon / iareHa c coflep * aHHeM xapGoxcHnbHux rpynn 0,7-20% b xojih-uecTBĚ 0 01-3% ot Maccu xayMyxa. yxasaHHnHnHcHcHbH CTa-6WIH3aTOp3MH, HanpHMep aMHHHblMH, φεΗΟΠΒΗΜΜΗ, φΟοφΟρΗΜΜΗ ΤβΧ ΑβΠββ. Θ3θ6ρβΤβΗΗβ HJUMOCTpHpyiOT npHMepbl. ΠρΗΜβρ 1.

Pots πρΗΒοηητ τηπημηηΛ πρκΜβρ nonyMeHHH 6enxosoro rnflpoJiH3aTa. B xon6y cMemanxoft noMemaioT 120 r HSMenbMeHHbix otipeaxoB GejixoBoň xonÓacHoň οΘοπομκη, nonyneHHoK H3 οπηπκοβοΗ o6pe3H, noCaBnator 200 μπ 0.2% βοαηογο pacTBopa cep- 258421 2

Hoň KHCJioTbi. TeMnepaTypes noflHHMaioT jqo 120 ° C b τβΜβΗΗβ 0.5 naca h 9tot mo-ΜβΗΤ npHHHMaioT aa HyneBoft OTcneT. B TeneHHe rtwpojiHaa OT6npa »T npo6bi ptT-Bopa Oenxa, aHajiH3npyioT nx Ha co / xepxaHHe xap6oxcnnbHbix rpyrin πβτεΗΐίΗΟΜβτρΗ-qecKHM τΗτροββΗΗβΜ b pac ^ eTe Ha cyxoft οοτβτοκ paCTBopa.

Hepes nac HarpeBaHHH CHCTeMa cTana roMoreHHoft. B TaCmme 1 πρΗΒβββιο, ι flaH-Hbie nonyueHHH Cenxoeoro rnffponn3aTa. AHanornuHcM cnCoM nonyHaror rnflponHaaTc co, aepxaHHeM - COOH rpynn 0.7 hj20Z. AHajiorHHHO nonyuaioT npoMbiraneHHbie o6pa3iu> i 6enxoBoro rHflponHsaTa, Hcnojib-sya ajih rHfipojiHsa conHHyto xncnoTy. TaxHM XE oSpasoM nonyMawr 6enxoBbiň rn / IPO JIHA H9 cnHJiKOBoň oCpesH, we3flpbi, xpoMOBOň cTpyxKH, xpoMOBoň o6pesH, xoxe-BeHHoň nbUiH, ΗβκοτορΗβ oCpasubi CenxoBoro rHflpojmaaTa nonynajiH ρηηροπη3ομCnHJlKOBOft O0pe3H H MeSApbl BOfloft. ΠρΗΜβρ second Κ I 80 mk naTexca "YTA HEH ^ - c CTHponbHoro xayuyxa cyxHM ocTaTKOM 92.4% Ηβcoflepxamero cTaCnnHaaiop, noSaannioT b BHfle 5% βοαηογο paCTBopa BenxoBbift RMR-H3 pojiHaaT οτχοηοβ xonCacHoft o6ojiohkh c pasnmHbíM coAepxaHHeM xap6oKCnnbHbixrpynn, but nonyneHHhiň npHMepy first b xoHTponbHbift oCpaseu CenxoBbiň ΓΗηρσηκββτ nefloCaBJíHWT. nocne BBI # eneHHH xaywyxa oSbWHbíM cnocoOoM c πρΗΜβΗβΗΗβΜ cepHoftKHCJioTbi xpomxy xayuyxa cyrnaT πρκ 60C b cyniHnhHOM πικβφγ. HcnbiTaHHe παπΗΜβρ-Hotta ΚΟΜΠΟ3ΗΗΚΗ ΠρθΒΟ «ΗΤ ΠρΗ ΤβΠΠΟΒΟΜ CTapeHHH ΠΡΗ 1 40 ° C Β ΤβΗβΗΗβ 30 ΜΗΗ CnocnegyHMUMM 3βΜβροΜ HHfleKca coxpaHeHHH nnacTHUHOcTH (ΗΟΠ)

nnacTHHHOcTb nocne cropaHHH HCl1 ------------------------------- x 100%.

nnacTH ^ HOcTb flo CTapeHHH

IlnacTHHHOcTb onpeflenHeTCH Ha CbicTpoAeftcTBynnieM nnacTOMeTpe yonneca. Pe-aynbTaTbi npHBeneHb b Ta &amp; nnpe 2. KOHTpojibHbiB oCpaseu 3το x ^ xaynyxa, nonyneHHbift c TpaflHimoHHbMCTa6nnH3aTOpOM Ν-φβΗΗΠ-2-Η3φΤΗΠβΜΗΗΟΜ (1%), ΤββΤ HCII, paBHbtft 63%.

Kax BHflHO H3 βββΠΗΙφΙ 2, nOJIHMepHaH Κ0ΜΠ03ΗΗΗΗ 6β3 GeJIKOBOrO rnaponnsaTah 6ea CTa6nnH3aTopa aacTpyxTypHpOBanacb u He npHroflHa κ ynoTpeÓneHHio. Ποπη-MepHaa κομπο3ηι {ηη c CenxoBbíM γηλροπη33Τομ, πρΗΗβΜ jjaxe πρκ Manoň ero aosh-poBxe, bβετ Bbicoxyio cTaOiuibHocTb Ha ypoBHe TpannynoHnoro, ho τοχοηηηογοcTa6Hnn3aTopa. ΠρΗΜβρ third H3 naTexca CyTaflHeH - CTHponbHoro xayvyxa nonyHaioT o6pa3iy> ic paBHbíM oxo-JlHHeCTBOM TpaflHHHOHHOrO CTa6HnH3aTOpa - ΤρΗ ~ (ί / -ΜβΤΗΠ6βΗ3ΗΠ) -φβΗΗπφθθφΗΤβ, Ataxx b c CMecH SenxoBbíM γηαροπη33Τομ oSpesKOB KonSacHoň ββηκοΒοή ο6οποηχηc coflepxaHneM xap6oxcHnbHbix rpynn 5.1% H3 Pacnet 0.15% no OTHomeHHW κ x yy-Hyxy. TaSnHqe 3 πρ πβΑβΗΜ pe3yjibTaTW no TennoBOMy cTapeumo nonuMepHMx κομπο-3nu, nn.

Kax BHflHO H3 Ta &amp; nnubi 3 onbrrnaa nonHMepHan χομπο3Ηηηη HaMHoro npeBocxo-'flHT CTa6lUIbHOCTb CepHftHOft ΚΟΜΠΟ3ΗΗΜΗ, ΠρΗΗβΜ flJXH flOCTHXeHHH BblCOXOft CTA ~ eiOTbHOCTH Moxhe yMeHbUIHTb ftOSHpOBKy ΤρββΗΗΗΟΗΗΟΓΟ CTa6HJIH3aTOpa. ΠρΗΜβρ 4 «Κ 100 mk cepHňHoro naTexca δγτβ ^ ΗβΗ - CTHponbHoro xaynyxa« oGaBnaioT τρβ-AHUHOHHbie CTa6HJIH3aTOPbI ΗΠΗ HX CMecH Β COneTaHHH C BOflHblM paCTBOpOM 6 &amp; ΠΚΟΒΟ-ro γηαροπη33Τ3, NPH nonyneHHH κοτοροΓΟ Hcnojib3y »T cojiHHyio KHCJioTy c coflepxa-ΗΗβΜ Kap6oKCHJibHbix rpynn 5 , 1. Af Tafinne 4 ripHBe / jeiibi nanHbie no HHflexcy coxpa-ΗβΗΗΗ nnacTHMHocTH (HCT) nocne CTapeHHH npH 140 ° C β τβηβΗΗβ 30 mhh.

Kax βηληο H3 Ta6jiHHW 4, floCaeneHHe ÓenxoBoro ΓΗβροπΗ3βτβ x TpanmiHOHHhiM cTa6HnH3aTopaM pe3xo noBbnuaeT CTa6 «nbHocTb nojiHMepHoň κομπο3ηηηη. 258421 3 ΠρΗΜβρ 5. Β npoMhuaneHHbzx ycnoBHax κ naTexcy ΰγτβκηβΗ - cTHponbHoro xayqyxa Henpe- | N τάβπΗμβ 5 npHBefleHti ^ aHHbie no rennoBOMy CTapeHHio nojiyneHHoon ποπΗΜβρηοΠΚΟΜΠΟ3ΗΗΗΗ b cpaBHeHHH c xayqyxoM, b KOTopbien 6enKOBbi ΓΗΑροπΗ3βτ He no.ua-BancH. ΠρΗΜβρ 6. <100 K μπ pácTBopa ncuiHHšonpeHOBoro xayqyxa b c HsoneHTaHe cyxHM οατατχοΗ9,2% ΑοββΒΠΗίοτ TpaflHuiHOHHbrii cTaCunnaaTop - N NZ- «ΗφβΗΗΠ Ι-4-φβΗΚΠβΗΛΗ3ΜΗΗb KOJiHnecTBe 0.2% Ha xayqyx b souffle TonyojibHO MeTaHonbHoro pacTBopa-κ 2% -HUft> BOflHbJn paeTBOp GejiKOBoro rHflponnaaTa, rnflpojiHse κοτοροro HcnojibSoaaHacojiHHan KHcnoTa, cogepxantero 5.1% xap6oxcHJibHbtx rpynn. CMecb TmareJthHO nepe-MemHBawT h BbiflejisiOT nojiHMepHyw xoMnosHiviio nápoM oCuuhum cnocoOoM. ΠαΑκΜβρ-nyio xoMno3HUHK> o6pa6aTbiBa »T npn 140C β τβηβΗΗβ 30 Fog η onpeflenHioT HjvxexccoxpaHeHHB nnacTHHHOCTH (* ra6n.6) b c cpaBHeHHH KOHTponbHUM oOpasuoM xayqyxa, nonyqeHHoro 6ea OejixoBoro and rutapojiHaaT. ΠρΗΜβρ 7. 200 μπ naTexca 6yTa # HEH - o / -MeTmicTHpojibHoro xayqyxa noCaBrtaioT SMyntcH »CTaCwiHSaTopa - οκτΗπφβΗοηβΜΗΗΗο # cmcjim b mation Pacner 0.17% H3 Ha xayqyxh paBHoe KojiHnecTBo 1% -Horo pacTBopa CenxoBoro runpojiHsaTa, npjK nwponHsexoToporo HcnonbaoBana cojihHan KHcnoTa c coflepxaHHeM KapCoxcHJibHwx rpynn4,7%. HarpBawT xyqyx HbbejTh 140 ° C b TeneHHe 30 mhh η onpeaenHWTHHjflexc coxpaHeHHH nnacTHHHocTH (HCII). PesynbTaTM npHBefléwj b TaOjlHue seventh ΠρκΜβρ 8. 100 μπ SMynbCHOHHoro nonnCyTanHeHa cyxHM octhtkom C 14.2%, N% coflepxamero1 φβΗΗΠ-2-ΗΒφΤΗΠ3ΜΗΗΒ, "oGaSJlHIOT 2% ~ Hblft paeTBOp CejlKOBOrO ΓΗΑρθΠΗ3βΤ8, .ηρκ ΓκηροπΗ3β κοτοροΓΟ HcnojibaoBaHa conaiian χηοποτθ, c conepxaHHeM xapGox-cwibHbix rpynn 5.1% (0.5% Ha xyqyx). HHflexc coxpaHeHHH nnacTHHHOcTH nocjie HarpeBa nonnMepHoň ΚΟΜΠΟ3ΗΚΗΗ ηρκ140 ° C b TeneHne 30 mh Gbin paeen 69%, y χοητροπβηοΛ κομπο3ηηηη Gea GeJixoBQ-ro rHflpojiH3aTa - 40%. ΠρΗΜβρ 9. K 100 μπ naTexca CyTaflHeH —or — MeTHncTHponbHoro xayqyxa, He coflepxanterocTa6njin3aTop, floĎaBnHWT 2% -HMft pacTBop GenxoBoro rHflpunHsaTa H3 Meaflpu ηπηxpoMOBon cTpyxxH H3 pacneTa 0.7% on xayqyx. IIojiyqeHHyio noJiHMepHyx> comhosh-hhio Harpesax> T npn 140 ° C b Tenenne 30 mhh h aaMepnioT HHflexc coxpaHeHHH nnac-thhhocth c noMombio nnacTOMeTpa Yonneca. PesynbTaTbi npHBefleHbí BTaGnHfle eighth ΠρΗΜβρ 10th Κ 100 μπ naTexca GyTaflHeHHHTpwibHoro xayqyxa cyxHM οετβτκοΜ C 14.2% 1% coflepxaiqero Φθηοπβηογο cTaGiuuiaaTopa 4,4 6Ηθ- (2,6-ΑΗ-τρβτ-6γτΗπφβΗθπβ) flo6aejiHK) T 2 % -Group pacmop Genxosoro rnnponn33Tan3 pacqeTa 0.3% GenxoBororHøJj * ponnsaTa Ha nooiHMep. BbifleneHHyio nonHMepHyn κομποβηηηιο o6pa0aTbffla »T ηρκ 140Cb TeqeHHe-60 mhh b cpaBHeHHH c κοητροπβημμ oCpasijoM, coflepxantHM τοηΒΧΟ φβ-HonbHbion cTaCHnHsaTop. KoMnosHHHfl c ββπκοΒΜΜ rHApantoaroM Gbina ΗβΜΗΟΓΟ CTa- • CwibHee: Π0Π paBHo 89%, y xoHTpojibHoň komhoshhhh Η0Π paBHo - 71%. * ΠρΗΜβρ 11. B 100 μπ TTcacacaexexex GyTexexTTTTTTTTTTTTT GyTT252525252525TTTTTTTTTTTTTTTTTTT,3,3,3,3,3,3,3,3,3,3,3,3 nonyneHHoro πρκ Hcnontso-BSHHH COnHHOft KHCJIOTfel, C CORepXaHMeM KapCHOKCHBbHMX rpynn 4.7% i B KOHTpojlb “HMn oCpaaey cTaOnriHaaTop He AoCasjísMT. Π κ β ρ ra 140 140 140 140 140 ae ae ae ae Ο ae ae ae ae Ο ae ae ae ae ae ae ae ae ae ae ae ae ae ae ae ae ae 171 171 171 171%% 12. In ΠρΗΜβρ 100 μπ cepHňHoro naTeKca CyTaflHeH-cTHpojibHoro xayqyxa, coflepxaetero1,1% craÓHJiHsaTopa - Ν-2-φβΗΗΛ Η3φτκπβΜΗΗβ, flo6aBnH »T b BHffe 2% -ηογο pacTBO PA CenKOBbiň rHApojiHaar c coftepxaKHeM KapOoKcanbHbK rpynn 7.0% nonyneHHbjftΓΗΑροηΗΒΟΜ crouiKOBoft ronbeBoň οβρεβΗ γηαροοκηοηο xanbUHA on pacyera 0.5% on KaywyK.

IlonyueHHyio κομπο3ηαηκ BWflenHWT h cyuaT oCumhmm cnocoOoM. B KOHTponbHBy o6pa? Eu CenKOBwň rnApojiHaaT Ηβ nonajoT. Ilocne TennosorocTapeHHH πρκ 140 ° C b Tenemie 30 mhh KOHTponbHbfó oCpagey HMen hkackc coxpa- ΗβΗΗΗ nnacTHHHOCT »paiiHbift 63%, onbiTHMn oCpasen - 89%. ΠρΗΜβρ 13th CBoňcTBa nojiHMepHoň κομποβμκηη to ocHoee KaynyKOB h Οβηκοβοτο nmponHsa-Ta c coAepxaHHeM KapfioKCHnbHbix rpynn 5.3% nonyneHHoro γηαροπη9ΟΜ oOpesxoBronbH conHHoň KHcnoToň, nccnep, ywT b cTaimapTHott pesHHe προτεκτορΗοΛipesHHe κ b ..

YcTaHOBjíeHO, hto pesHHbí Ha ocHoee xayqyxoB, nonyneHHbix c HcnojibSOBaHHeMCejiKOBbix rHAPOnusaTOB, it ecTb προτβκτορΗβη infantry xapaxTepH9yx> TCH Hecxonb- * ca 6onee BbicoKoň TeMnepaTypocTOňKocTb », conpoTHBneHHeM TennoBOMy cTapemm, MeHbmeň non3yuecTbw, nynmHMH ycTanocTHbíMH CBoňcTBaMH noBbsneHHbix TeMnepa npn-amino Typax cpaBHeHH» c KOHTponbHoň ( TaCrauibi 9, 10).

KpoMe oTMeqeHHbix npeuMyntecTB, onuTHHe peamtbi oCnanajoT Taxxe nynmHMH ynpy-ro - rHCTepe3HCHb! ΦΟΡΜΥΛΑ H30BPETEHH8 Κομπο3HUHH Ha ocHOBe KapGoyenKoro xaynyxa, BKrnoHaiamaa cTaCnunoaTop, οτπη-naromaaca τβΜ, ητο c nenw noBumemut cTaCuntHocTH xaynyxa h ynynoeHHa caHH-TapHbtx ycnoBHft HaroTOBneHHH κομπο3ηηηη, nocnenHHH conepMHT b xanecTBe CTa- .CuriHaaTopa δβηκοΒωή γηαροπη9Βτ xonnarena c coflepacamieM xapCoxcHnbHbix rpynn0,7- 20% b xojiHuecTBe 0.01-3% οτ Maccbi xayyxx.

HcTOWHHKH οφορΜβΠΗΗ, npHHHTbie ΒΟβΗΗβ npH 3KcnepTH3e: 1.

PE Φ EPAT

Κ0ΜΠ03ΗΙΙΗΗ HA OCHOBE ΚΑΡΒΟΙΙΕΠΗΟΓΟKAYHYKA Η3ο6ρβτβΗΗβ othochtch X npoH3BOflcTBy cHHTeTHwecxHx KaynyKOB, and TOHHeeK ΚΟΜΠΟ3ΗΗΗΜ Ha ocHOBe KapCouenHoro Kaynyxa. npefljiaraeMaa κομποohijhh BKjnouaeT xapConenHuñ xaynyK h οτβ6ΗΠΗ3βτορ, bxanecTBe κοτορορο HcnojibsoBaH 6ejixosuh rHAponnsaT konnarena c co ^ epacanHeMxapGoxcHJibHbix rpynn 0.7-20% b KojnmecTBe 0.01-3% οτ Maccbi xayHyxa. IIpH9HaHO Η3θ6ρβτβΗΗβΜ no pesynbTaTaM 3KcnepTH3M, ocymecTBneHHoft FocynapcT-

BeHHbíM ΚοΜΗτετοΜ CCCP no AenaM Η3θ6ρβτβΗΗϋ η οτκρωτκή. 258421 5

TaCmnia I ΚΗΗβτΗκβ nojiyMeHHH OejiKoro rnflpojiH3ara

BpeMH rHApojiHaa, Cyxoft οοτβτοκ ConepxaHHe Mac rHflpcwiHaaTa, /? KapOOKCHJlbHbIXrpynn, Z 0 27.7 2.6 0.5 32.6 3.2 2.0 36.7 3.6 7 36.7 5.3 23 36.7 6.7 30 36.7 7.5

TaftnHua 2 CTa6nJlbHOCTb ΚΟΜΠΟ3HUHH Ha ocHOBe KayMyxá, ΗΒ3ΒβΗΗΟΓΟ npHMepe B 2 H SeJIKOBOTO ΓΗ «ρθΠΗ3ΒΤβ CoflepxaHHe Kap-6oKCHJIbHblXrpynn,% flóSHpoBKa CejiKo-ΒΟΓΟ ΓΗΑροηΗΒβΤβ of honors, 0 0106 (KOHTpOJIbHblň) 2.6 0.15 61 2.6 0.5 51 3.2 0.1 67 3.2 0.25 63 4.1 0.11 65 5.3 0.11 70 5.3 0.01 53

TaCjiHua 3 Βπηηηηθ 6ejiKoro rHAPonnsaTa Ha cTaCnnbHOCTbnOJIHMepHbK KOMnOSHIjHft

CTaCKnnsaTOP, Z ΗΟΠ, of CoflepacaHMerenn, Z (150 ° C; 60 mhh) 'rpH' (οΙ-ΜΘΤΗΠΟβΗ-3ΗΠ) 0.15 76 3.7 0.6 0.15 75 3.9 0 0.15 41, 6.5 258421

TaCjiHiia 4.

BnHHHue SenKOBoro rHjqpojiHsaTa Ha CTaGwibHocTb Kayqyxa HaaBaHHoro bnpHMepe 4 IP onbiTa 1. CTaCwmaaTop

pioBupoBKa, Z 'j ~ BClI, Z

BejiKOBbiíi rmxponttaaT, npw nojiyue-HHH ΚΟΤΟΡΟΓΟ HCnOJIbSyWT COJIHHyK) KHCJiOTy 0.4 64 2. N- (ηΗΜβΤΗΠφβΗΗη) -2-Ha4) THnaMHH 1.2 CenKOBbiň rnflpoJiH3aTt πρκ nonyve- 82 HHH N n n 3 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 4. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. H H 1.0 87 HHH ΚΟΤΟΡΟΓΟ HCHOJlbSyiOT COJlHHyn KHCJIOTH 0.4 6. Ν “φβΗΗ1Ι — 2 — ΤΗΙΙβφΤΗΙΙβΜΗΗ 1,2 63 7. Ν-φβΗΗΠ-2-ΤΗβφΤΗΠβΜΗΗ 1,2 HHH ΚΟΤΟΡΟΓΟ HCnOJIb3yWT COJlHHyH) KHCJiOTy j 0, 4 8. βΗφβΗΗJiaMHH, ajlKHJlHpOBaHHblft CTHpO - JIOM 1.0 29 9. ΑΗφβΗΗΠβΜΗΗ, ajlKWlHpOBaHHblň CTHpO "· JIOM 1,0 CHiBBB rHApojiHsaT, npH nojiyue- 85 HHH ΚΟΤΟΡΟΓΟ HcnojibsyioT COnBHyiO KHCJiOTy - 0,4 10. NNR“ 6HC (ΑΗΜβΤΗΠφβΗΗΠ) - Ι, 4-φβΗΗΠβΗ - A «and MHH. 0.3. 30 11. NNL -6Hc (flHMeTHml> eHHJi) -1,4-φβΗΗΠβΗ - «ΗβΜΗΗ 0,3 GeJiKOBBi rHApHl3aT, npH nojiyHeHHH> 86 ΚΟΤΟΡΟΓΟ HcnOJlb3yiOT COJIHHyiO KHC“ jioTy 0,42 258421 7

TaOmma 5. ΚηκΗΗΗβ δ & rnflpo.nH3aTa aa cTaCnnbHocTb

KaywyKa, Ha3BaHHoro b -------------------- 1 npHMepe 5 ———— i Ν 'CTa0KJiH3aTop AosHpoBKa, X HCn, X (140 ° C, 30mhh) Ί . 0κΤΚΠφβΗΟΠ3ΜΗΗΗ3Η CMona 0.16 79 2. ΟκΤΚΠφβΗΟΠβΜΗΗΗβΗ CMona ČejiKOBbiň rHApoHHsaT, npH nonyqeHHM κοτορο-ro HcnojibayioT cojiHHyioKHcnory «0.16 0.15 96

Ta6nHqa 6. CTa6nnbHocTb nojiHHSonpeHOBoro Kayuyxa IRLl CTaOiuiHaaTop flOSHpOBKa, X] Hcn »N, N (ΑΗφβΗΚΠ -

1,4 - φβΗΚΠβΗΑΗβ “MHH 2. Ν, Ν1- ΑΗφβΗΚΗ” 1,4 “φβΗΚΠβΗ” ΑΗβΜΗΗ

OanxoBuň γηαροπη- • 33Τ, πρκ ΓΗΑραΠΜ3β κοτορογο Hčnohbso “BaMa cojiHHaa khc-ηοτβ 0.2 50 0.2 93 3.0

TaCmma 7.

BnHHHHe CenxoBoro rHAPOAHsaTa Ha cTaOwibHocTb6yTaA »eH - 2 - MeTWicTHpojibHoro Kayqyxa N>N>

flo3HpoBKa cTaCHAHaaTopa, X

HCII, X ΟκΤΚΠφβΗΟΠβΜΗΗ “Haa CMona

EejiKOBbiň γηλρο, πμ-33T, ΠΡΗ ΓΗΑΡΟΠΗ ”Hcnonb-soeaHa coiiHMaa khc-JiOTa 1. 2. 0,17 0,17 0,01 60 68 258421 8

ΠροΑοπχβΗΗβ aa6n, 7, flo3npoBKa cTaOtunisaTopa. X HCn, X ΟκΤΗΠφβΗΟΠβΜΗΗ-Han CMona BenxoBuft rsmpojjH “and ar, npw rompojiH-3β ΚΟΤΟρΟΓΟ HCnOAb ** soBaHa conMHaa khc, - nora • * 3. 0.17 0.10 70 4. 0.17 0.20 84 5. 0.17 0.31 89 Ta &amp; nHua eighth BnnHHHe GejiKOBux rnflpajiHsaTOB Ha CTa6unbHocTi> OyTaflHeH - cTupontHoro xayuyKa 4 Hctomhhk KOjuiareHa ftna CóAepxaHHe a pocket ββπκοΒΟΓο rHApojiuaaTa 6OKCIUlbHblXrpynn, 7, HCFL, Z KoHTpojibHbiň first, a pocket 106 oTcyTCTBHe oTcyTCTBHe KOJuiarena 6OKCHJIbHblX rpynn 2. Me3ftPa, ΓΗΑΡ0ΠΗ3ΟΒ8ΗΗ8Η 16.1 67 'cepHoň ň ň es es es es es ,9 ,9 ,9 ,9 ,9 ,9 ,9 ,9 ,9 ,9 ,9 ,9 ,9 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0. 59 3. XpoMOBaa cTpy «Ka 0.7 63 1.1 65 2.0 70 6.4 53 4. Meaflpa, rHflpojiHSoaaHHaHBofloom 2.4 ¢ 3

Ta &amp; roma 9.

CsoftcTBa cTanflapTHbix pe3HH, nonyneHHux Ha ochos KaynyKOB, HSrOTOBJíeHHUX ΠρΗΜβΗβΗΗβΜ C 6 &amp; ΠΚΟΒΟΓΟ ΓΗΑρΟΠΗΒβΤΘ N>N> ΠΠ noKaaaT &amp; nn OnuTHue KayuyKH KOHTpOJlbHUe KaynyKH 1 2 3 4 1. YcnoBHoe HanpaxeHHe npn300Z pacTHxeHHH Mila 4.3 4.6 2nd ýcnoBHafl npoMHocTb npupacTflxeHHH, Mila 23.6 22.8 3. OTHOCHTenbHoe y ^ BHHeHHenpn paspuBe, Z 742 695 258421 "Ί, ΠροΛΟΠΜβΗΗβ TaQji.9 1 2 3 * '·' 4. ConpoTHBneKHe paaxjHpy, kH / m 41 45 5. TeepflocTb no IDopy 52 54 6. 3nacTMMMocTb no OTcKoxy, X, npn 20 ° C 27 32 7. K / E 0.49 0.48 8. nojiayqecTb, X (120 ° C, 100 γ / μμ2) 33 4! 9 .. noοΒφφκμΗβητ TennoBoro cTapeHna (1000 ° Cx72h) 0.29 0.22 10. KoreaHOHHafl nponHocTb, Krc / cM 1.2 0.40

TaCximja 10. CBoňTTs προτεκτορΗΜΧ pesu »N * N> nn ΠθΚ83βΤ6ΑΗ OnuTHue xaynyxH KoHTponbHue, xaynyxH 1 1 3 + 1. YcnoBHoe HanpaxeHHe 300X pacTHxeHKa, ΜΠβ 5.5 4.9. 2. YcnOBHaa npOMHOCTbnpH'pacTaxeHHU, βΠβ 18,3 18,5 3. OTHOCHTTeHHy ynHe-HHe npn paspuBe, X 635 709 4. ConpoTHBneHHe paannpy, kH / m 63 62 5. TBepAoerb, ycn. efl. 58 57 6. ac nacTHMHocTb no otcko-xy, X πρκ 20 ° C 35 32 πρκ 100 ° C 45 42 7. K / E: npn 20 ° C 0.51 0.53 πρκ t00 ° C 0.36 0.39 8. TeMnepaTýpocToňKocTb (100 ° C) 0.38 0.30 9. ΚοΒφφκΰκβΗτ TennoBorocTapnnHH: 72qx100 ° C 0.54 0.51 120nxl00eC 0.41 0.39 25842) 10 ΠροΑοηχβΗΗβ Ta6n.10 1 2 3 4 to. KcTHpaeMocTb M3 / Tflx 53 46 11. χιχ: 20 ° C, 1502 2.10 2.85 70 ° C, 1002 46.5 27.3 14. Kore9HOHHax npoMnocTb, KTc / cM 1.0 0.30 258421

Claims (1)

pSedmžt vynálezu Kompozice na bázi homo- nebo kopolymerŮ konjugovanýchdienů, zahrnující stabilizátor, Vyznačující se tím, že zaúčelem zvýšení stability kaučuku a zlepšení hygienickýchpodmínek přípravy kompozice, tato kompozice obsahuje jakostabilizátor bílkovinný hydrolyzát kolagenu s obsahem kar-boxylových skupin 0,7 až 20 % v množství 0,01 až 3 % z hmotykaučuku. Uzgorodský výrobně-noligrafický podnik, Proektnaja 4, Uzgorod* 6060, Cena 2,40 KcSSUMMARY OF THE INVENTION Compositions based on conjugated homo- or copolymers, comprising a stabilizer, characterized in that, in order to increase rubber stability and improve the hygiene conditions for the preparation of the composition, the composition comprises a collagen protein hydrolyzate containing carboxy groups of 0.7 to 20% in quantity 0.01 to 3% by weight of rubber. Uzgorod Manufacturing and Noligraphic Enterprise, Proektnaja 4, Uzgorod * 6060, Price 2,40 KcS
CS842270A 1984-03-28 1984-03-28 Kompozioe na básl homo «or. copolymers of conjugated components CS258421B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CS842270A CS258421B1 (en) 1984-03-28 1984-03-28 Kompozioe na básl homo «or. copolymers of conjugated components

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CS842270A CS258421B1 (en) 1984-03-28 1984-03-28 Kompozioe na básl homo «or. copolymers of conjugated components

Publications (2)

Publication Number Publication Date
CS227084A1 CS227084A1 (en) 1986-12-18
CS258421B1 true CS258421B1 (en) 1988-08-16

Family

ID=5359333

Family Applications (1)

Application Number Title Priority Date Filing Date
CS842270A CS258421B1 (en) 1984-03-28 1984-03-28 Kompozioe na básl homo «or. copolymers of conjugated components

Country Status (1)

Country Link
CS (1) CS258421B1 (en)

Also Published As

Publication number Publication date
CS227084A1 (en) 1986-12-18

Similar Documents

Publication Publication Date Title
CY1112139T1 (en) A PHARMACEUTICAL COMPOSITION INCLUDING CRYSTALL RITONAVIR FORM II AND A PREPARATION THEREOF
NL940001I2 (en) Carboxyalkyl dipeptides, processes for their preparation and pharmaceutical preparations containing them.
ATE200078T1 (en) METHOD FOR PRODUCING AMIDE DERIVATIVES FROM HALOAMINOTRIAZINES AND ACID HALIDES
TR199902528T2 (en) Flowable oil compositions containing a thickener.
ES2125477T3 (en) CONCENTRATED, LIQUID OR GELIFIED DISHWASHER DETERGENT COMPOSITION, CONTAINING CALCIUM XYLENE-SULPHONATE.
EA200400243A1 (en) CRYSTAL COMPOSITION CONTAINING ESCITALOPRAMS
IL175319A0 (en) Novel phosphate-binding protein, pharmaceutical compositions containing same and use thereof
TW200508366A (en) Perfluoroallyloxy compound and liquid crystal composition containing the compound
GB518596A (en) Improvements in or relating to materials for taking impressions for dental or other purposes
CS258421B1 (en) Kompozioe na básl homo «or. copolymers of conjugated components
WO2007101546A3 (en) Combinations of active ingredients with insecticidal and acaricidal properties, containing phthalic acid diamides
CO2024013582A2 (en) Lyophilized formulation comprising a fusion protein that includes α-galactosidase a
BR0002508B1 (en) alpha, beta unsaturated ketones, mixture and adorably composition.
GB1216945A (en) Novel imidazoline derivatives, the preparation thereof and compositions containing the same
ES8702916A1 (en) A PROCEDURE FOR THE PREPARATION OF 6-METHYLENE SUBSTITUTED PENICILANIC ACIDS AND DERIVATIVES THEREOF
JPS5236196A (en) Process for preparing cured compositions based on modified epoxy resin s
SU836039A1 (en) Hermetic based on butyl rubber
DK0618875T3 (en) Composition for the preparation of a at least partially biodegradable film as well as a film thus prepared
JPS51125126A (en) Adhesive composition
SU531840A1 (en) Electrochemiluminescent Composition
JPS5378250A (en) Chlorine-containing resin composition
JPS5367756A (en) Composition of resin containing chlorine
ATE315600T1 (en) COMPOSITION BASED ON RENEWABLE RAW MATERIALS
SU101992A1 (en) The method of preparation of compositions of spices
JPS51123255A (en) Preparation of polyuinyl chloride resin composition