CN86108655A - Stabilized insecticide formulations - Google Patents
Stabilized insecticide formulations Download PDFInfo
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- CN86108655A CN86108655A CN86108655.4A CN86108655A CN86108655A CN 86108655 A CN86108655 A CN 86108655A CN 86108655 A CN86108655 A CN 86108655A CN 86108655 A CN86108655 A CN 86108655A
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- insecticidal formulation
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- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 238000009472 formulation Methods 0.000 title claims abstract description 28
- 239000002917 insecticide Substances 0.000 title abstract description 10
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 24
- 239000000944 linseed oil Substances 0.000 claims abstract description 17
- 239000003549 soybean oil Substances 0.000 claims abstract description 14
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 14
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 12
- 150000002903 organophosphorus compounds Chemical class 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 230000000749 insecticidal effect Effects 0.000 claims description 24
- 239000004593 Epoxy Substances 0.000 claims description 14
- 229940073608 benzyl chloride Drugs 0.000 claims description 7
- 238000010413 gardening Methods 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 241000238631 Hexapoda Species 0.000 claims description 2
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 claims 1
- 201000010099 disease Diseases 0.000 claims 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims 1
- 229910052925 anhydrite Inorganic materials 0.000 abstract description 2
- OGYFATSSENRIKG-UHFFFAOYSA-N pencycuron Chemical compound C1=CC(Cl)=CC=C1CN(C(=O)NC=1C=CC=CC=1)C1CCCC1 OGYFATSSENRIKG-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 238000003898 horticulture Methods 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000003090 pesticide formulation Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- 238000010298 pulverizing process Methods 0.000 description 13
- -1 carbamide compound Chemical class 0.000 description 11
- 239000000843 powder Substances 0.000 description 8
- 239000010440 gypsum Substances 0.000 description 7
- 229910052602 gypsum Inorganic materials 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 description 6
- 238000009736 wetting Methods 0.000 description 6
- 244000068988 Glycine max Species 0.000 description 4
- 235000010469 Glycine max Nutrition 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000006735 epoxidation reaction Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000013112 stability test Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- JXLLGXPPQRSVOI-UHFFFAOYSA-N ClCC(O)OP(O)(O)=O Chemical class ClCC(O)OP(O)(O)=O JXLLGXPPQRSVOI-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005949 Malathion Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- JQYYTCRAWVKTHZ-UHFFFAOYSA-N N1CCNCC1.[Cl] Chemical compound N1CCNCC1.[Cl] JQYYTCRAWVKTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005814 Pencycuron Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000000152 carbamate pesticide Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- HRBKVYFZANMGRE-UHFFFAOYSA-N chlorpyrifos-methyl Chemical group COP(=S)(OC)OC1=NC(Cl)=C(Cl)C=C1Cl HRBKVYFZANMGRE-UHFFFAOYSA-N 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- FCOAHACKGGIURQ-UHFFFAOYSA-N iprobenfos Chemical compound CC(C)OP(=O)(OC(C)C)SCC1=CC=CC=C1 FCOAHACKGGIURQ-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 229960000453 malathion Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a new stable pesticide formulation, a process for its production and a method of use as a pesticide. The insecticide contains 1- (4-chlorobenzyl) -1-cyclopentyl-3-phenylurea and an organophosphorus compound as active ingredients, and is characterized in that the formula is stabilized by adding type III anhydrous gypsum. The invention also provides an insecticide formulation which is stabilized by the addition of type III anhydrite in combination with epoxidized linseed oil and/or epoxidized soybean oil. The stabilized pesticidal formulations of the present invention have found various uses in agriculture and horticulture.
Description
The invention relates to a kind of new stable insecticidal formulation and production and using method.
Japanese patent application publication No. 23128/1979 and 160707/1980 has been announced a kind of carbamide compound (comprising the 1-(4-benzyl chloride)-1-cyclopenta-3-phenylurea that contains) and a kind of organic phosphorus compound as the combination formula of active component to being useful fungicide on agricultural and the gardening.According to this announcement, because association is used as Jiong, this combination formula is more more effective than using active component wherein separately.Yet this announcement does not comprise the stability of relevant this prescription.
The known road of present inventor 1-(4-benzyl chloride)-when 1-cyclopenta-3-phenylurea mixes in prescription mutually with a kind of organic phosphorus compound, they interact and cause decomposition, and this decomposition is faster during than their independent process preparations, deposits when therefore in fact combination formula can not be grown.Therefore, the stabilisation of this combination formula is the problem that needs solution.
The present invention provides a kind of stable insecticidal formulation now, has contained the 1-(4-benzyl chloride)-1-cyclopenta-3-phenylurea and a kind of organic phosphorus compound be as active component, it is characterized in that this prescription owing to add III type anhydrous gypsum (so-called solubility anhydrite, γ-CaSO
4, " semihard gypsum ") and make it stabilisation.As for the definition of III type anhydrous gypsum, please refer to Gmelins Handbuch der Anorganischen Chemie Calcium, Teil B-Lie ferung3, series number 28,679 pages of Verlag Chemie Weinheim/Bergstra β e1961.The present invention also provides a kind of owing to add III type anhydrous gypsum and epoxy linseed oil and/or epoxidized soybean oil and the insecticidal formulation of stabilisation.
The present invention further provides to producing stable insecticidal formulation III type anhydrous gypsum added the 1-(4-benzyl chloride)-method in the mixture of 1-cyclopenta-3-phenylurea and a kind of organic phosphorus compound.The present invention also is provided as the method for stablizing insecticidal formulation and adding III type anhydrous gypsum and epoxy linseed oil and/or epoxidized soybean oil of producing.
Also find at last, stable insecticidal formulation of the present invention can agricultural and gardening on various uses is arranged.
The present invention adds insecticidal formulation with III type anhydrous gypsum and has stablized the active component that mixes with it, and their physical features is not had adverse effect, this be make us very surprised, because when the used known gypsum of reality such as bassanite are filled a prescription, there is not above-mentioned character.
Making us extremely surprised equally is, the active component of mixing is when adding anhydrous gypsum and epoxy linseed oil and/or epoxidized soybean oil, and stability is further strengthened.The present invention just finishes on the basis of this discovery.
The aforementioned stable effect just just produces when adding III type anhydrous gypsum.Other gypsum such as bassanite (CaSO
40.5H
2O), all strong degrading activity composition of I type or II type anhydrous gypsum.
Stable insecticidal formulation of the present invention provides a kind of technology of innovation in the insecticide production field, so the present invention is industrial useful and have a tangible technical progress.
The 1-(4-benzyl chloride)-and 1-cyclopenta-3-phenylurea (basin Xi Gu swell Pency-curon) is an active component in the stable insecticidal formulation of the present invention, its structural formula is as follows:
Another kind of active component organic phosphorus compound in the stable insecticidal formulation of the present invention is a kind of reactive compound that is generally used for plant protection.It is preferably as insecticide or fungicide.The example of this compound is as follows, yet the present invention is not limited to this,
O-ethyl S, S-diphenyl phosphorodithioate (Hinosan)
S-benzyl-O, O-two-isopropylthio phosphate (iprobenfos IBP)
O, O-dimethyl 0-4-methyl mercapto--tolyl thiophosphate (fenthion)
O, O-dimethyl 0-4-nitro--tolyl thiophosphate (Folithion)
O, O-dimethyl 0-3,5,6-trichloro-2-pyridyl thiophosphate (chlorine piperazine power clothes Chloropyrifos-methyl)
S-1,2-two (carbethoxyl group) ethyl O, O-Methyl disulfide substituted phosphate (malathion)
S-α-ethoxy carbonyl benzyl O, O-Methyl disulfide substituted phosphate (spray rope its Penthoate)
Dimethyl 2,2,2-three chloro-1-hydroxyethyl phosphates (chlorophos)
The anhydrous gypsum that is used for stable insecticidal formulation of the present invention is an III type anhydrous gypsum.This III type anhydrous gypsum can be stablized the active component of mixing, and the physical property of prescription is had no adverse effect.The active component that mixes is with the fusion of III type anhydrous gypsum, and optionally with epoxy linseed oil and/or epoxidized soybean oil fusion, products obtained therefrom adds solid diluent with usual way, carrier or surfactant and be processed into preparation.
The example of solid diluent comprises the plant powder, the mineral powder, and the carclazyte mineral are (as kaolin, imvite and Attagel), talcum, pyrophillite, mica, calcite, vermiculite, mucovi-te, apatite, diatomite, synthetic inorganic matter (as highly dispersible silicic acid and synthetic aluminium oxide) and synthetic resin (as phenol resin, urea resin and polyvinyl chloride).
The example of surfactant comprises anion surfactant (alkyl sulfate such as lauryl sodium sulfate; Arylsulphonate such as alkylaryl sulfonates and Negel, sodium salt with the copolymer of PC such as maleic acid and alkene) and non-ionic surface active agent (polyoxyethylene glycol ether such as polyoxyethylene alkylaryl ether, the polyoxyethylene glycol ester is as polyoxyethylene fatty acid ester; With polyol ester such as polyoxyethylene sorbitan one lauric acid ester).
Prescription can contain a kind of binding agent, and the example of binding agent comprises carboxymethyl cellulose and natural and synthetic polymer (as gum Arabic, polyvinyl alcohol and polyvinyl acetate),
Can contain toner in the prescription.The example of toner comprises inorganic pigment (as iron oxide, titanium oxide and Prussian blue) and organic dyestuff (as alizarin dyes, azo dyes and phthalocyanine dye)
Prescription is further fusion micronutrient also, as iron, and manganese, boron, copper, cobalt, molybdenum and zinc and its esters.
Stable insecticidal formulation of the present invention can be made into common pulvis or wetting powder uses, and pulvis is better.
The amount that above-mentioned prescription contains above-mentioned active component accounts for 0.1 to 90 weight %, is good with 0.5 to 80 weight %.
Stable insecticidal formulation of the present invention contains III type anhydrous gypsum 4 to 95 weight %, is good with 6 to 50 weight %, and in more detail, wp formula contains III type anhydrous gypsum 4 to 50 weight %, is good with 6 to 30 weight %; The wetting powder formulation content is 10 to 95 weight %, is good with 10 to 50 weight %; Also containing epoxy linseed oil and epoxidized soybean oil 0.1 to 30 weight %, is good with 0.5 to 10 weight %.
Active component can share with other known activity compositions in the insecticidal formulation of the present invention, as fungicide, and bactericide, insecticide, miticide, weedicide drives black agent, growth regulator and fertilizer and/or soil improvement material.The example of insecticide includes machine phosphorus insecticide, carbamate pesticide, carboxylate insecticide, the insect killing substance of chlorination hydrocarbons insecticide and microorganisms.
The present invention is elaborated with following example, but the present invention is limited to these examples absolutely not.
Example 1(wetting powder)
Wetting powder can be by pulverizing and mixing following active component and auxiliary material and make
15 parts of Hinosans by weight
Basin Xi Gu swells 8 parts by weight
30 parts of III type anhydrous gypsums by weight
5 parts of lauryl sodium sulfate by weight
Diatomite and kaolin
42 parts in 1: 5 mixture by weight
Example 2(wetting powder)
Wetting powder can be by pulverizing and mixing following active component and auxiliary material and make
15 parts of Hinosans by weight
Basin Xi Gu swells 8 parts by weight
30 parts of III type anhydrous gypsums by weight
8 parts of epoxy linseed oils by weight
5 parts of lauryl sodium sulfate by weight
Diatomite and kaolin
34 parts in 1: 5 mixture by weight
Example 3(pulvis)
This pulvis can be by pulverizing and mixing following active component and auxiliary material and make
2.5 parts of Hinosans by weight
Basin Xi Gu swells 1.5 parts by weight
20.0 parts of III type anhydrous gypsums by weight
0.1 part of PAP by weight
75.9 parts of carclazytes by weight
Example 4(pulvis)
This pulvis can be by pulverizing and mixing following active component and auxiliary material and make
2.5 parts of Hinosans by weight
Basin Xi Gu swells 1.5 parts by weight
20.0 parts of III type anhydrous gypsums by weight
1.5 parts of epoxy linseed oils by weight
0.2 part of PAP by weight
74.3 parts of carclazytes by weight
Example 5(pulvis)
This pulvis can be by pulverizing and mixing following active component and auxiliary material and make
1.5 parts of Hinosans by weight
Basin Xi Gu swells 2.0 parts by weight
20.0 parts of III type anhydrous gypsums by weight
1.0 parts of epoxidized soybean oils by weight
0.2 part of PAP by weight
75.3 parts of carclazytes by weight
Example 6(pulvis)
This pulvis can be by pulverizing and mixing following active component and auxiliary material and make
2.0 parts of fenthions by weight
Basin Xi Gu swells 1.5 parts by weight
10.0 parts of III type anhydrous gypsums by weight
0.1 part of PAP by weight
86.4 parts of carclazytes by weight
Example 7(pulvis)
This pulvis can be by pulverizing and mixing following active component and auxiliary material and make
2.0 parts of fenthions by weight
Basin Xi Gu swells 1.5 parts by weight
10.0 parts of III type anhydrous gypsums by weight
1.5 parts of epoxidized soybean oils by weight
0.1 part of PAP by weight
84.9 parts of carclazytes by weight
Example 8(pulvis)
This pulvis can be by pulverizing and mixing following active component and auxiliary material and make
2.0 parts of Folithions by weight
Basin Xi Gu swells 2.0 parts by weight
20.0 parts of III type anhydrous gypsums by weight
0.1 part of PAP by weight
86.4 parts of carclazytes by weight
Example 9(pulvis)
This pulvis can be by pulverizing and mixing following active component and auxiliary material and make
3.0 parts of malathions by weight
Basin Xi Gu swells 1.5 parts by weight
10.0 parts of III type anhydrous gypsums by weight
2.0 parts of epoxy linseed oils by weight
0.1 part of PAP by weight
83.4 parts of carclazytes by weight
Test the stability test of routine 1(active component)
This pulvis is by pulverizing and mixing following active component and auxiliary material and make
2.5 parts of Hinosans by weight
Basin Xi Gu swells 1.5 parts by weight
Card cloth comes #80(Carplex
#80) 3.0 parts by weight
III type anhydrous gypsum 10 or 20 parts are by weight
Epoxidized soybean oil or
Epoxy linseed oil 0 or 1.5 parts are by weight
0.1 part of PAP by weight
Carclazyte equilibrates to 100 parts by weight
This pulvis put into vial and in the dark 40 ℃ deposited 30 and 60 days, check decomposition rate.The results are shown in Table 1
The anhydrous epoxidation oil mass of III type decomposition rate %(30 days) decomposition rate %(60 day)
(%) the grand Hinosan basin Xi Gu of Hinosan basin Xi Gu is grand for amount of gypsum (%)
Example 10 does not have 4.7 4.9 7.8 10.9
Example 20 does not have 4.1 5.5 5.8 7.7
Example 10 1.5(soya-bean oil) 2.4 3.9 3.4 4.4
Example 10 1.5(Linseed oils) 2.9 2.7 4.5 3.9
Reference examples 20
*1.5(soya-bean oil) 9.2 11.3 11.7 18.6
Reference examples does not have 10.2 17.2 17.0 27.4
Reference examples 20
*Do not have 6.8 14.2 13.1 19.4
Reference examples 20
* *Do not have 7.3 14.4 15.2 23.3
*Bassanite
*I type anhydrous gypsum
* *II type anhydrous gypsum
Test the stability test of routine 2(active component)
This pulvis is by pulverizing and mixing following active component and auxiliary material and make
2.0 parts of fenthions by weight
Basin Xi Gu swells 1.5 parts by weight
Card cloth comes 3.0 parts of #80 by weight
10.0 parts of III type anhydrous gypsums by weight
Epoxidized soybean oil 0 or 1.5 parts are by weight
0.1 part of PAP by weight
The carclazyte balance becomes 100 parts by weight
This pulvis is put into vial and was in the dark deposited 30 and 60 days under 40 ℃, checks its decomposition rate, the results are shown in Table 2.
The anhydrous epoxidation decomposition rate of III type (%) decomposition rate (%)
Amount of gypsum soya-bean oil amount (30 days) (60 days)
(%) the grand fenthion basin Xi Gu of (%) fenthion basin Xi Gu is grand
Example 10 does not have 5.4 4.9 9.8 6.2
Example 10 1.5 4.7 2.6 8.4 3.3
Contrast 0 does not have 8.5 17.6 12.1 28.5
Test the stability test of routine 3(active component)
This pulvis is by pulverizing and mix following active component and auxiliary material and make,
The spray rope it (Penthoate) 2.0 parts by weight
Basin Xi Gu swells 1.5 parts by weight
Card cloth comes 3.0 parts of #80 by weight
20.0 parts of III type anhydrous gypsums by weight
Epoxy linseed oil 0 or 3 parts are by weight
0.1 part of PAP by weight
Carclazyte equilibrates to 100 parts by weight
This pulvis is put into vial and was in the dark deposited 30 and 60 days under 40 ℃, checks that its decomposition separates ratio, the results are shown in Table 3.
Table 3
Inferior decomposition rate (%) decomposition rate (%) of the anhydrous epoxidation of III type
Amount of gypsum pockmarks oil mass (30 days) (60 days)
(%) its basin Xi Gu of the grand spray of (%) spray its basin Xi Gu of rope rope is grand
Example 20 does not have 4.4 3.4 8.1 7.6
Example 20 3.0 3.1 1.8 5.7 2.7
Reference examples 0 does not have 9.2 22.1 16.1 28.6
Test the stability test of routine 4(active component)
This pulvis is by pulverizing and mixing following active component and auxiliary material and make.
2.0 parts of Hinosans by weight
Basin Xi Gu swells 1.0 parts by weight
Card cloth comes 3.0 parts of #80 by weight
15 parts of III type anhydrous gypsums by weight
Epoxidized soybean oil or
Epoxy linseed oil 0 or 0.5 part are by weight
0.1 part of PAP by weight
Carclazyte equilibrates to 100 parts by weight
This pulvis is put into vial and was in the dark deposited 30 and 60 days under 40 ℃, checks its decomposition rate, the results are shown in Table 4.
Table 4
The anhydrous epoxidation decomposition rate of III type (%) decomposition rate (%)
Amount of gypsum oil mass (30 days) (60 days)
(%) the grand Hinosan basin Xi Gu of (%) Hinosan basin Xi Gu is grand
Example 15 does not have 4.3 5.1 7.7 9.2
Example 15 0.5(soya-bean oil) 2.8 2.5 3.2 4.5
Example 15 0.5(Linseed oils) 1.7 3.0 3.0 5.2
Claims (9)
1, a kind of stable insecticidal formulation, this prescription contain 1-(4-benzyl chloride)-1-cyclopenta-3-phenylurea and a kind of organic phosphorus compound as active component, it is characterized in that adding III type anhydrous gypsum and make this prescription stable.
2, the described stable insecticidal formulation of claim 1, wherein the content of the active component of Hun Heing is 0.1 to 90 weight %, is good with 0.5 to 80 weight %.
3, the described stable insecticidal formulation of claim 1, wherein the content of III type anhydrous gypsum is 4 to 95 weight %, is good with 6 to 50 weight %.
4, the described stable insecticidal formulation of claim 1 wherein is mixed with epoxy linseed oil and/or epoxidized soybean oil.
5, the described stable insecticidal formulation of claim 1, wherein the content of epoxy linseed oil and/or epoxidized soybean oil is 0.1 to 30 weight %, is good with 0.5 to 10 weight %.
6, the described stable insecticidal formulation of claim 1, wherein organic phosphorus compound be at least a on agricultural or gardening the compound in order to control disease and harmful insect.
7, a kind of method of producing stable insecticidal formulation, comprise benzyl chloride to 1-(4-)-mix III type anhydrous gypsum and (optionally) epoxy linseed oil and/or epoxidized soybean oil in the mixture of 1-cyclopenta-3-phenylurea and a kind of organic phosphorus compound, solid diluent or carrier also have surfactant in case of necessity.
8, the stable insecticidal formulation of method production according to claim 1.
9, the described stable insecticidal formulation that is used for agricultural and gardening of claim 1 to 6 and claim 8.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP290829/85 | 1985-12-25 | ||
| JP29082985 | 1985-12-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86108655A true CN86108655A (en) | 1987-09-23 |
| CN1022533C CN1022533C (en) | 1993-10-27 |
Family
ID=17761022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN86108655A Expired - Lifetime CN1022533C (en) | 1985-12-25 | 1986-12-22 | Stabilized pesticide formulation |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS62228004A (en) |
| KR (2) | KR870005583A (en) |
| CN (1) | CN1022533C (en) |
| PH (1) | PH23772A (en) |
-
1986
- 1986-04-17 JP JP61087117A patent/JPS62228004A/en active Granted
- 1986-12-22 PH PH34638A patent/PH23772A/en unknown
- 1986-12-22 CN CN86108655A patent/CN1022533C/en not_active Expired - Lifetime
- 1986-12-24 KR KR860011182A patent/KR870005583A/en not_active IP Right Cessation
-
1987
- 1987-12-24 KR KR1019860011182Q patent/KR950002853B1/en active
Also Published As
| Publication number | Publication date |
|---|---|
| PH23772A (en) | 1989-11-03 |
| KR950002853B1 (en) | 1995-03-27 |
| JPH0572885B2 (en) | 1993-10-13 |
| CN1022533C (en) | 1993-10-27 |
| JPS62228004A (en) | 1987-10-06 |
| KR870005583A (en) | 1987-07-06 |
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| C14 | Grant of patent or utility model | ||
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