CN219891899U - A radioactive waste liquid partitioned heat pump evaporation system - Google Patents
A radioactive waste liquid partitioned heat pump evaporation system Download PDFInfo
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- CN219891899U CN219891899U CN202320777575.9U CN202320777575U CN219891899U CN 219891899 U CN219891899 U CN 219891899U CN 202320777575 U CN202320777575 U CN 202320777575U CN 219891899 U CN219891899 U CN 219891899U
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- 239000007788 liquid Substances 0.000 title claims abstract description 205
- 238000001704 evaporation Methods 0.000 title claims abstract description 108
- 230000008020 evaporation Effects 0.000 title claims abstract description 103
- 239000002901 radioactive waste Substances 0.000 title claims abstract description 63
- 239000002699 waste material Substances 0.000 claims abstract description 52
- 238000007906 compression Methods 0.000 claims abstract description 28
- 238000000926 separation method Methods 0.000 claims abstract description 27
- 230000006835 compression Effects 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 239000002994 raw material Substances 0.000 claims description 20
- 239000007791 liquid phase Substances 0.000 claims description 12
- 239000012071 phase Substances 0.000 claims description 12
- 238000011084 recovery Methods 0.000 claims description 9
- 239000012141 concentrate Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 239000012808 vapor phase Substances 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 abstract description 18
- 238000009835 boiling Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 238000005192 partition Methods 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000004880 explosion Methods 0.000 abstract description 4
- 238000007907 direct compression Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 15
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 238000010992 reflux Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000941 radioactive substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000002926 intermediate level radioactive waste Substances 0.000 description 1
- 239000002925 low-level radioactive waste Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003758 nuclear fuel Substances 0.000 description 1
- 238000005025 nuclear technology Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
本实用新型提供一种放射性废液间壁式热泵蒸发系统,应用到放射性废液处理的技术领域,包括废液蒸发子系统以及热交换子系统,废液蒸发子系统用于将放射性废液加热蒸发并分离出二次蒸汽;热交换子系统包括以二次蒸汽作为热源的热量交换装置、汽液分离装置以及蒸汽压缩装置,热量交换装置能够存储清洁的蒸发工质;蒸发工质受热蒸发后产生的蒸汽通过蒸汽压缩装置压缩提升温度及压力后输入到废液蒸发子系统中并作为废液蒸发子系统的热源;废液受热蒸发出的二次蒸汽与蒸发工质进行间壁换热,解决了含低沸点物质的放射性废液热泵蒸发时,二次蒸汽直接压缩造成的压缩机污染问题以及压缩过程的存在的泄漏、爆炸、腐蚀等风险。
The utility model provides a radioactive waste liquid partition type heat pump evaporation system, which is applied to the technical field of radioactive waste liquid treatment and includes a waste liquid evaporation subsystem and a heat exchange subsystem. The waste liquid evaporation subsystem is used to heat and evaporate the radioactive waste liquid. And separate the secondary steam; the heat exchange subsystem includes a heat exchange device using the secondary steam as a heat source, a vapor-liquid separation device and a vapor compression device. The heat exchange device can store clean evaporation working fluid; the evaporation working fluid is heated and evaporated to produce The steam is compressed and raised in temperature and pressure by the vapor compression device and then input into the waste liquid evaporation subsystem and used as the heat source of the waste liquid evaporation subsystem; the secondary steam evaporated by the waste liquid is heated and evaporated and performs wall heat exchange with the evaporation working medium, solving the problem When the radioactive waste liquid containing low-boiling point substances evaporates in the heat pump, the direct compression of the secondary vapor will cause compressor pollution problems and the risks of leakage, explosion, corrosion and other risks in the compression process.
Description
技术领域Technical field
本实用新型涉及放射性废液处理的技术领域,尤其涉及一种放射性废液间壁式热泵蒸发系统。The utility model relates to the technical field of radioactive waste liquid treatment, and in particular to a radioactive waste liquid partition type heat pump evaporation system.
背景技术Background technique
核燃料的生产、核技术的推广应用等过程中不可避免的产生大量放射性废液,由于来源广泛、成分复杂,并且含有一定放射性,为后期处理带来了一定困难。其中,低放及中放废液体积庞大、所含放射性总量较高,是废液治理的重点与难点。A large amount of radioactive waste liquid is inevitably produced during the production of nuclear fuel and the promotion and application of nuclear technology. Due to its wide range of sources, complex composition, and certain radioactivity, it brings certain difficulties to post-processing. Among them, low-level and intermediate-level waste liquids are bulky and contain a high total amount of radioactivity, which is the focus and difficulty of waste treatment.
为了解决上述问题,在现有技术中行之有效并被广泛采用的是蒸发浓缩法。其中,单效蒸发是目前放射性废液蒸发浓缩法处理的主要工艺手段,该方式在系统运行过程需要消耗大量外界生蒸汽,热能利用率较低,导致运行能耗及废液处理成本偏高。为了解决该单效蒸发的问题,研究人员设计了机械蒸汽再压缩(MVR)热泵蒸发工艺,机械蒸汽再压缩(MVR)热泵蒸发可实现废液蒸发过程二次蒸汽潜热的完全回收及再利用,可以有效减少系统能耗,是目前较为突出且行之有效的节能方法。In order to solve the above problems, the evaporation concentration method is effective and widely used in the prior art. Among them, single-effect evaporation is currently the main process method for the evaporation and concentration of radioactive waste liquids. This method requires a large amount of externally generated steam during system operation, and the heat energy utilization rate is low, resulting in high operating energy consumption and waste liquid treatment costs. In order to solve the problem of single-effect evaporation, researchers designed a mechanical vapor recompression (MVR) heat pump evaporation process. Mechanical vapor recompression (MVR) heat pump evaporation can realize the complete recovery and reuse of the latent heat of secondary steam in the waste liquid evaporation process. It can effectively reduce system energy consumption and is currently a prominent and effective energy-saving method.
但在机械蒸汽再压缩(MVR)热泵蒸发处理工艺中是将二次蒸汽进行直接压缩,虽然该工艺具有较高的节能效果,但是当废液中含有低沸点物质时,蒸发过程中低沸物会随着二次蒸汽进入压缩机,导致压缩机被放射性物质污染、造成压缩机自身放射性水平升高,为后期维护保养带来不便,同时低沸物直接压缩也存在泄漏、爆炸、腐蚀等隐患。However, in the mechanical vapor recompression (MVR) heat pump evaporation treatment process, the secondary steam is directly compressed. Although this process has a high energy-saving effect, when the waste liquid contains low-boiling substances, the low-boiling substances in the evaporation process It will enter the compressor with the secondary steam, causing the compressor to be contaminated by radioactive substances, causing the radioactivity level of the compressor itself to increase, which will bring inconvenience to later maintenance. At the same time, direct compression of low-boiling substances also has hidden dangers such as leakage, explosion, and corrosion. .
实用新型内容Utility model content
本实用新型提供一种放射性废液间壁式热泵蒸发系统,用以解决现有MVR热泵蒸发技术在处理含低沸点物质的放射性废液时存在放射性物质容易污染蒸汽压缩设备以及极易出现泄露、爆炸、腐蚀的缺陷,实现系统高效、安全可靠的运行。The utility model provides a wall-type heat pump evaporation system for radioactive waste liquid, which is used to solve the problem that when the existing MVR heat pump evaporation technology handles radioactive waste liquid containing low-boiling point substances, radioactive substances are easy to contaminate the vapor compression equipment and are prone to leakage and explosion. , corrosion defects to achieve efficient, safe and reliable operation of the system.
本实用新型提供一种放射性废液间壁式热泵蒸发系统,包括废液蒸发子系统以及热交换子系统,所述废液蒸发子系统接入放射性废液,用于将放射性废液加热蒸发浓缩并将蒸发产生的二次蒸汽进行分离;所述热交换子系统包括以所述二次蒸汽作为热源的热量交换装置、汽液分离装置以及蒸汽压缩装置,所述汽液分离装置分别与所述热量交换装置、所述蒸汽压缩装置相连通,所述热量交换装置内能够存储清洁的蒸发工质;其中,所述蒸汽压缩装置与所述废液蒸发子系统相连通,使得所述蒸发工质受热蒸发后产生的蒸汽通过所述蒸汽压缩装置压缩提升温度及压力后输入到所述废液蒸发子系统中并作为所述废液蒸发子系统的热源。The utility model provides a wall-type heat pump evaporation system for radioactive waste liquid, which includes a waste liquid evaporation subsystem and a heat exchange subsystem. The waste liquid evaporation subsystem is connected to the radioactive waste liquid and is used to heat, evaporate, and concentrate the radioactive waste liquid. Separate the secondary steam generated by evaporation; the heat exchange subsystem includes a heat exchange device using the secondary steam as a heat source, a vapor-liquid separation device and a vapor compression device. The vapor-liquid separation device is respectively connected with the heat The exchange device and the vapor compression device are connected, and the heat exchange device can store clean evaporation working fluid; wherein the vapor compression device is connected with the waste liquid evaporation subsystem, so that the evaporation working fluid is heated The steam generated after evaporation is compressed by the vapor compression device to raise the temperature and pressure, and then is input into the waste liquid evaporation subsystem and serves as a heat source for the waste liquid evaporation subsystem.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,还包括原料储罐以及进料预热子系统,所述进料预热子系统分别与所述原料储罐、所述废液蒸发子系统、所述热交换子系统相连,以用于对放射性废液预热并将预热的放射性废液输入到所述废液蒸发子系统中。According to the utility model, a wall-type heat pump evaporation system for radioactive waste liquid also includes a raw material storage tank and a feed preheating subsystem. The feed preheating subsystem is connected to the raw material storage tank and the waste liquid respectively. The evaporation subsystem and the heat exchange subsystem are connected to preheat the radioactive waste liquid and input the preheated radioactive waste liquid into the waste liquid evaporation subsystem.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述热量交换装置上连通有第二冷凝水储罐,所述第二冷凝水储罐通过冷凝泵与所述进料预热子系统相连通。According to a radioactive waste liquid partition type heat pump evaporation system provided by the utility model, the heat exchange device is connected with a second condensed water storage tank, and the second condensed water storage tank is preheated with the feed material through a condensation pump. Subsystems are connected.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述废液蒸发子系统包括蒸发器、第一汽液分离器、第二汽液分离器以及第一冷凝水储罐,所述蒸发器分别与所述第一汽液分离器、所述第一冷凝水储罐、所述蒸汽压缩装置相连通,所述第二汽液分离器分别与所述第一汽液分离器、所述热量交换装置相连通。According to a radioactive waste liquid dividing wall heat pump evaporation system provided by the utility model, the waste liquid evaporation subsystem includes an evaporator, a first vapor-liquid separator, a second vapor-liquid separator and a first condensed water storage tank. The evaporator is connected to the first vapor-liquid separator, the first condensed water storage tank, and the vapor compression device respectively, and the second vapor-liquid separator is connected to the first vapor-liquid separator, The heat exchange devices are connected.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述进料预热子系统包括顺序连通的一级预热器、二级预热器、三级预热器;所述三级预热器分别与所述第一汽液分离器、所述第一冷凝水储罐、所述汽液分离装置相连通,所述二级预热器与所述第二冷凝水储罐连通。According to a wall-type heat pump evaporation system for radioactive waste liquid provided by the utility model, the feed preheating subsystem includes a first-level preheater, a second-level preheater, and a third-level preheater that are connected in sequence; the three-level preheater The first-stage preheater is connected to the first vapor-liquid separator, the first condensed water storage tank, and the vapor-liquid separation device respectively, and the second-stage preheater is connected to the second condensed water storage tank. .
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述一级预热器配置有不凝气输出管路,所述不凝气输出管路分别与所述蒸发器、所述第一冷凝水储罐相连通。According to a radioactive waste liquid partitioned heat pump evaporation system provided by the utility model, the first-level preheater is equipped with a non-condensable gas output pipeline, and the non-condensable gas output pipeline is connected to the evaporator and the The first condensate storage tank is connected.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述二级预热器上配置有用于蒸发冷凝液回收的冷凝液回收输出管路。According to a wall-type heat pump evaporation system for radioactive waste liquid provided by the utility model, the secondary preheater is equipped with a condensate recovery output pipeline for evaporation condensate recovery.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述汽液分离装置至少配置有用于所述蒸发工质循环流动的汽液两相介质入口、汽相介质出口、液相介质入口、液相介质出口;其中,所述液相介质入口与所述三级预热器相连通,所述液相介质出口通过第二下循环管路与所述热量交换装置相连通,以使得所述蒸发工质能够循环进入到所述热量交换装置中。According to a wall-type heat pump evaporation system for radioactive waste liquid provided by the utility model, the vapor-liquid separation device is configured with at least a vapor-liquid two-phase medium inlet, a vapor-phase medium outlet, and a liquid-phase medium for the cyclic flow of the evaporation working medium. Inlet, liquid medium outlet; wherein, the liquid medium inlet is connected to the three-stage preheater, and the liquid medium outlet is connected to the heat exchange device through the second lower circulation pipeline, so that The evaporation working fluid can be circulated into the heat exchange device.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述第一汽液分离器上至少配置有废液输入口、废液出口、汽液两相进口、二次蒸汽出口、液相回流口;其中,所述废液出口与所述蒸发器通过第一下循环管路相连通,以使得放射性废液循环蒸发实现浓缩。According to a radioactive waste liquid dividing wall heat pump evaporation system provided by the utility model, the first vapor-liquid separator is equipped with at least a waste liquid input port, a waste liquid outlet, a vapor-liquid two-phase inlet, a secondary steam outlet, a liquid Phase reflux port; wherein, the waste liquid outlet and the evaporator are connected through the first lower circulation pipeline, so that the radioactive waste liquid can be cyclically evaporated to achieve concentration.
根据本实用新型提供的一种放射性废液间壁式热泵蒸发系统,所述第一下循环管路上配置有用于浓缩液排出的浓缩液排出管路。According to a wall-type heat pump evaporation system for radioactive waste liquid provided by the utility model, a concentrated liquid discharge pipeline for discharging concentrated liquid is arranged on the first lower circulation pipeline.
本实用新型提供的一种放射性废液间壁式热泵蒸发系统的有益效是,通过在二次蒸汽的后端接入了热交换子系统,使得通过热交换子系统将放射性废液蒸发产生的二次蒸汽与清洁的蒸发工质进行间壁式换热,解决了含低沸点物质的放射性废液热泵蒸发时,二次蒸汽直接压缩造成的压缩装置污染问题以及压缩过程的存在的泄漏、爆炸、腐蚀等风险,同时,由于完全回收了二次蒸汽潜热,提高了蒸发过程能源利用率,降低了运行能耗。The beneficial effect of the wall-type heat pump evaporation system for radioactive waste liquid provided by the utility model is that by connecting a heat exchange subsystem at the back end of the secondary steam, the secondary steam produced by evaporating the radioactive waste liquid is evaporated through the heat exchange subsystem. The secondary steam and the clean evaporation working fluid perform partition-type heat exchange, which solves the pollution problems of the compression device caused by the direct compression of the secondary steam when the radioactive waste liquid containing low boiling point substances is evaporated by the heat pump, as well as the leakage, explosion, and corrosion during the compression process. and other risks. At the same time, due to the complete recovery of the latent heat of the secondary steam, the energy utilization rate of the evaporation process is improved and the operating energy consumption is reduced.
附图说明Description of the drawings
为了更清楚地说明本实用新型或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本实用新型的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to explain the technical solutions of the present invention or the prior art more clearly, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings in the following description are: For some embodiments of the present invention, those of ordinary skill in the art can also obtain other drawings based on these drawings without exerting creative efforts.
图1是本实用新型提供的放射性废液间壁式热泵蒸发系统的结构示意图;Figure 1 is a schematic structural diagram of the radioactive waste liquid partition type heat pump evaporation system provided by the utility model;
图2是本实用新型一实施例提供的汽液分离装置的具体结构图;Figure 2 is a specific structural diagram of a vapor-liquid separation device provided by an embodiment of the present invention;
图3是本实用新型一实施例提供的第一汽液分离器的具体结构图。Figure 3 is a specific structural diagram of a first vapor-liquid separator provided by an embodiment of the present invention.
附图标记:Reference signs:
100:原料储罐;200:进料预热子系统;201:原料泵;202:一级预热器;203:二级预热器;204:三级预热器;300:废液蒸发子系统;301:冷凝液回流泵;302:第一冷凝水储罐;303:蒸发器;304:第一下循环管路;305:第一汽液分离器;305-1:废液输入口;305-2:汽液两相进口;305-3:废液出口;305-4:液相回流口;305-5:二次蒸汽出口;306:第二汽液分离器;307:第一上循环管路;400:热交换子系统;401:冷凝泵;402:第二冷凝水储罐;403:第二下循环管路;404:热量交换装置;405:汽液分离装置;405-1:汽液两相介质入口;405-2:汽相介质出口;405-3:液相介质入口;405-4:液相介质出口;406:蒸汽压缩装置;407:第二上循环管路;500:冷凝液回收输出管路;600:不凝气输出管路;700:浓缩液排出管路;800:浓缩液泵。100: Raw material storage tank; 200: Feed preheating subsystem; 201: Raw material pump; 202: First-level preheater; 203: Second-level preheater; 204: Third-level preheater; 300: Waste liquid evaporator System; 301: condensate return pump; 302: first condensate storage tank; 303: evaporator; 304: first lower circulation pipeline; 305: first vapor-liquid separator; 305-1: waste liquid input port; 305-2: Vapor-liquid two-phase inlet; 305-3: Waste liquid outlet; 305-4: Liquid phase reflux port; 305-5: Secondary steam outlet; 306: Second vapor-liquid separator; 307: First upper Circulation pipeline; 400: heat exchange subsystem; 401: condensation pump; 402: second condensate storage tank; 403: second lower circulation pipeline; 404: heat exchange device; 405: vapor-liquid separation device; 405-1 : Vapor-liquid two-phase medium inlet; 405-2: Vapor-phase medium outlet; 405-3: Liquid-phase medium inlet; 405-4: Liquid-phase medium outlet; 406: Vapor compression device; 407: Second upper circulation pipeline; 500: Condensate recovery output pipeline; 600: Non-condensable gas output pipeline; 700: Concentrate discharge pipeline; 800: Concentrate pump.
具体实施方式Detailed ways
为使本实用新型的目的、技术方案和优点更加清楚,下面将结合本实用新型中的附图,对本实用新型中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。In order to make the purpose, technical solutions and advantages of the present utility model clearer, the technical solutions in the present utility model will be clearly and completely described below in conjunction with the drawings of the present utility model. Obviously, the described embodiments are the embodiments of the present utility model. Some, not all, of the new embodiments. Based on the embodiments of the present utility model, all other embodiments obtained by those of ordinary skill in the art without making creative efforts fall within the scope of protection of the present utility model.
本申请的描述中,“相连通”可以理解为两设备之间能够通过一条或多条管道传输汽体或液体。液体或汽体在传输过程过程都可以通过驱动装置或加压或减压等方式来实现。其中,汽体是液体在受热而形成的一种形态。In the description of this application, "connected" can be understood as being able to transmit gas or liquid between two devices through one or more pipelines. The transmission process of liquid or gas can be realized by driving device or by pressurizing or depressurizing. Among them, vapor is a form formed by liquid being heated.
下面结合图1描述本实用新型的一种放射性废液间壁式热泵蒸发系统,包括原料储罐100,原料储罐100构造为圆桶状结构,在原料储罐100中存储有待处理的放射性废液,在储料罐的底部配置有原料出口,原料出口连接有具有阀门的管路。The following is a description of a radioactive waste liquid partition type heat pump evaporation system of the present invention in conjunction with Figure 1, which includes a raw material storage tank 100. The raw material storage tank 100 is configured as a barrel-shaped structure, and radioactive waste liquid to be processed is stored in the raw material storage tank 100. , a raw material outlet is configured at the bottom of the storage tank, and the raw material outlet is connected to a pipeline with a valve.
进料预热子系统200,与原料出口连通,在连通时设置原料泵201,通过原料泵201将放射性原料输入到进料预热子系统200中进行预热。The feed preheating subsystem 200 is connected to the raw material outlet. When connected, a raw material pump 201 is provided. The radioactive raw materials are input into the feed preheating subsystem 200 through the raw material pump 201 for preheating.
废液蒸发子系统300,用于将放射性废液加热蒸发浓缩并将蒸发产生的二次蒸汽进行汽液分离。例如,可以通过加热装置对放射性废液进行加热使得放射性废液沸腾产生蒸汽,然后通过两个汽液分离机构进行蒸汽的二次分离净化,得到较纯净的二次蒸汽。在废液蒸发子系统300中可以配置能够为进料预热子系统200提供热源的管路或组件等,具体可通过在后的实施例进行说明。当然为了提高放射性废液的处理效率,可以对接入的放射性废液预先进行预热。The waste liquid evaporation subsystem 300 is used to heat, evaporate and concentrate the radioactive waste liquid and separate the secondary steam generated by evaporation into vapor and liquid. For example, the radioactive waste liquid can be heated by a heating device so that the radioactive waste liquid boils to generate steam, and then the steam is secondary separated and purified through two vapor-liquid separation mechanisms to obtain purer secondary steam. Pipes or components that can provide a heat source for the feed preheating subsystem 200 may be configured in the waste liquid evaporation subsystem 300, and the details may be explained in the following embodiments. Of course, in order to improve the treatment efficiency of radioactive waste liquid, the connected radioactive waste liquid can be preheated in advance.
热交换子系统400;热交换子系统400包括以二次蒸汽作为热源的热量交换装置404、汽液分离装置405以及蒸汽压缩装置406,汽液分离装置405分别与热量交换装置404、蒸汽压缩装置406相连通,热量交换装置404内能够存储清洁的蒸发工质,例如,将清水作为蒸发工质,便于取材且成本低廉。热量交换装置404可以是管壳式换热器或板式换热器,优选管壳式换热器。在热交换子系统400中可以配置能够进一步为进料预热子系统200提供预热的管路或组件等,具体可通过在后的实施例进行说明。Heat exchange subsystem 400; the heat exchange subsystem 400 includes a heat exchange device 404 using secondary steam as a heat source, a vapor-liquid separation device 405, and a vapor compression device 406. The vapor-liquid separation device 405 is respectively connected with the heat exchange device 404 and the vapor compression device. 406 is connected, and the heat exchange device 404 can store clean evaporation working fluid, for example, clean water is used as the evaporation working fluid, which is easy to obtain materials and has low cost. The heat exchange device 404 may be a shell and tube heat exchanger or a plate heat exchanger, preferably a shell and tube heat exchanger. The heat exchange subsystem 400 may be configured with pipelines or components that can further provide preheating for the feed preheating subsystem 200 , as will be explained in detail in the following embodiments.
进料预热子系统200分别与原料储罐100、废液蒸发子系统300、热交换子系统400相连,以用于对放射性废液预热并将预热的放射性废液输入到废液蒸发子系统300中,蒸汽压缩装置406与废液蒸发子系统300相连通,使得沸腾汽化的蒸发工质的蒸汽通过蒸汽压缩装置406提升温度和压力后输入到废液蒸发子系统300中并作为所述废液蒸发子系统300的热源。The feed preheating subsystem 200 is connected to the raw material storage tank 100, the waste liquid evaporation subsystem 300, and the heat exchange subsystem 400, respectively, for preheating the radioactive waste liquid and inputting the preheated radioactive waste liquid to the waste liquid evaporation. In the subsystem 300, the vapor compression device 406 is connected to the waste liquid evaporation subsystem 300, so that the vapor of the boiling and vaporized evaporation working medium is raised in temperature and pressure through the vapor compression device 406 and then input into the waste liquid evaporation subsystem 300 and used as the required vapor. The heat source of the waste liquid evaporation subsystem 300.
可以理解的是,在上述实施例中,关键提供了热交换子系统400,通过热交换子系统400与二次蒸汽发生热能的交换,例如,间壁式换热,使得蒸发工质被加热蒸发并通过蒸汽压缩装置406进行压缩升温,最后进入到废液蒸发子系统中,实现了压缩机清洁安全的工作环境,避免了放射性物质的污染以及泄漏等安全隐患。It can be understood that in the above embodiments, the key point is to provide the heat exchange subsystem 400, through which the heat exchange subsystem 400 exchanges thermal energy with the secondary steam, for example, partition-type heat exchange, so that the evaporation working medium is heated and evaporated and evaporated. The vapor compression device 406 performs compression and temperature rise, and finally enters the waste liquid evaporation subsystem, achieving a clean and safe working environment for the compressor and avoiding safety hazards such as contamination and leakage of radioactive materials.
在一实施例中,热量交换装置404上连通有第二冷凝水储罐402,第二冷凝水储罐402通过冷凝泵401与所述进料预热子系统200相连通,以此实现热交换子系统400对进料预热子系统200的热源提供。更具体地实施例为,进料预热子系统200包括顺序连通的一级预热器202、二级预热器203、三级预热器204;二级预热器203与第二冷凝水储罐402连通,使得热量交换装置404的冷凝水作为二级预热器203的热源,实现放射性废液的二级预热,且在二级预热器上配置有用于蒸发冷凝液回收的冷凝液回收输出管路500。具体地,一级预热器202为不凝汽预热器、二级预热器203为蒸发冷凝液预热器、三级预热器204为清水预热器。进一步地实施例,废液蒸发子系统300包括蒸发器303、第一汽液分离器305、第二汽液分离器306以及第一冷凝水储罐302,其中,蒸发器303可以是管壳式换热器或板式换热器,优选管壳式换热器。蒸发器303分别与第一汽液分离器305、第一冷凝水储罐302、蒸汽压缩装置406相连通,第二汽液分离器306分别与第一汽液分离器305、热量交换装置404相连通;三级预热器204分别与第一汽液分离器305、第一冷凝水储罐302、汽液分离装置405相连通,第一冷凝水储罐302与所述蒸发器303的壳程连通,使得蒸发器303的冷凝水作为三级预热器204的热源,实现三级预热器204的预热。进一步地的实施例,一级预热器202配置有不凝气输出管路600,所述不凝气输出管路600分别与蒸发器303、第一冷凝水储罐302相连通,即是,将蒸发器303内的不凝汽、第一冷凝水储罐302内的不凝气集中输入到一级预热器202中,使得不凝汽能够作为热源来对放射性废液进行一级预热。In one embodiment, the heat exchange device 404 is connected to a second condensate storage tank 402, and the second condensate storage tank 402 is connected to the feed preheating subsystem 200 through a condensation pump 401, thereby realizing heat exchange. Subsystem 400 provides a heat source for feed preheating subsystem 200 . A more specific embodiment is that the feed preheating subsystem 200 includes a first-level preheater 202, a second-level preheater 203, and a third-level preheater 204 connected in sequence; the second-level preheater 203 and the second condensed water The storage tank 402 is connected, so that the condensed water of the heat exchange device 404 is used as the heat source of the secondary preheater 203 to realize the secondary preheating of the radioactive waste liquid, and the secondary preheater is equipped with a condensate for recovery of the evaporated condensate. Liquid recovery output line 500. Specifically, the first-level preheater 202 is a non-condensing steam preheater, the second-level preheater 203 is an evaporative condensate preheater, and the third-level preheater 204 is a clean water preheater. In a further embodiment, the waste liquid evaporation subsystem 300 includes an evaporator 303, a first vapor-liquid separator 305, a second vapor-liquid separator 306, and a first condensed water storage tank 302, wherein the evaporator 303 may be a shell-and-tube type. Heat exchanger or plate heat exchanger, preferably shell and tube heat exchanger. The evaporator 303 is connected to the first vapor-liquid separator 305, the first condensed water storage tank 302, and the vapor compression device 406 respectively, and the second vapor-liquid separator 306 is connected to the first vapor-liquid separator 305 and the heat exchange device 404 respectively. The three-stage preheater 204 is connected to the first vapor-liquid separator 305, the first condensed water storage tank 302, and the vapor-liquid separation device 405 respectively. The first condensed water storage tank 302 is connected to the shell side of the evaporator 303. Connected, so that the condensed water of the evaporator 303 serves as the heat source of the three-stage preheater 204 to realize the preheating of the three-stage preheater 204. In a further embodiment, the first-stage preheater 202 is configured with a non-condensable gas output pipeline 600, which is connected to the evaporator 303 and the first condensed water storage tank 302 respectively, that is, The non-condensable steam in the evaporator 303 and the non-condensable gas in the first condensed water storage tank 302 are collectively input into the primary preheater 202, so that the non-condensable steam can be used as a heat source to perform primary preheating of the radioactive waste liquid. .
上述实施例中,通过设计管路将废液蒸发子系统中的蒸发器303、第一冷凝水储罐302与三级预热器204以及一级预热器202相连通,三级预热器204与第一冷凝水储罐302连接的管路通过冷凝液回流泵301将冷凝液输入作为三级预热器204的热源,一级预热器202连接的管路通过不凝汽的输入作为热源;通过设计管路将热交换子系统400中的热量交换装置404、第二冷凝储罐连通,二级预热器203的连接管路通过冷凝泵401将热量交换装置404中的冷凝液输入作为热源。可以理解的是,系统中冷凝液回流泵301中流经的冷凝液为冷凝后的蒸发工质;每一级的预热器的热源均是利用后续废液蒸发子系统300和热交换子系统400中的热能,使得整个系统的中的热能得到充分利用,达到高效和节能目的。In the above embodiment, the evaporator 303 and the first condensate storage tank 302 in the waste liquid evaporation subsystem are connected to the third-stage preheater 204 and the first-stage preheater 202 through designed pipelines. The third-stage preheater 204 The pipeline connected to the first condensate storage tank 302 uses the condensate return pump 301 to input the condensate as the heat source of the third-stage preheater 204. The pipeline connected to the first-stage preheater 202 uses the input of non-condensable steam as the heat source. Heat source; the heat exchange device 404 in the heat exchange subsystem 400 and the second condensation storage tank are connected through the designed pipeline, and the connecting pipeline of the secondary preheater 203 inputs the condensate in the heat exchange device 404 through the condensation pump 401 as a heat source. It can be understood that the condensate flowing through the condensate return pump 301 in the system is the condensed evaporation working fluid; the heat source of each stage of the preheater is to utilize the subsequent waste liquid evaporation subsystem 300 and the heat exchange subsystem 400 The heat energy in the whole system can be fully utilized to achieve high efficiency and energy saving.
如图2所示,在一具体的实施例中,汽液分离装置405至少配置有用于所述蒸发工质循环流动的汽液两相介质入口405-1、汽相介质出口405-2、液相介质入口405-3、液相介质出口405-4;其中,汽液两相介质入口405-1与汽相介质出口405-2用于汽化的清洁的蒸发工质流通,也即是清水蒸汽流通,具体地,汽化的蒸发工质由热量交换装置404通过汽液两相介质入口405-1进入到汽液分离装置405中,通过汽液分离装置405将液相分离,汽化的蒸发工质由汽液分离装置405进入到蒸汽压缩装置406中;液相介质入口405-3与三级预热器204相连通,液相介质出口405-4通过第二下循环管路403与热量交换装置404相连通,以使得所述蒸发工质能够循环进入到所述热量交换装置404中。如图3所示,进一步地实施例中,第一汽液分离器305上至少配置有废液输入口305-1、废液出口305-3、汽液两相进口305-2、二次蒸汽出口305-5、液相回流口305-4;其中废液出口305-3与蒸发器303通过第一下循环管路304相连通使得废液循环蒸发实现浓缩;废液输入口305-1接入到三级预热器204中,使得预热后的放射性废液进入第一汽液分离器305中。在另一具体实施例中,在第一循环管路上配置有用于浓缩液排出的浓缩液排出管路700,浓缩液排出管路700上设置由浓缩液泵800,以使得当浓缩到预定浓度时便可以将浓缩液通过浓缩液排出管路700排出。As shown in Figure 2, in a specific embodiment, the vapor-liquid separation device 405 is configured with at least a vapor-liquid two-phase medium inlet 405-1, a vapor-phase medium outlet 405-2, and a liquid medium for circulating flow of the evaporation working medium. Phase medium inlet 405-3, liquid phase medium outlet 405-4; among them, vapor-liquid two-phase medium inlet 405-1 and vapor phase medium outlet 405-2 are used for the circulation of clean evaporation working medium for vaporization, that is, clean water vapor Circulation, specifically, the vaporized evaporation working fluid enters the vapor-liquid separation device 405 from the heat exchange device 404 through the vapor-liquid two-phase medium inlet 405-1, and the liquid phase is separated by the vapor-liquid separation device 405. The vaporized evaporation working fluid It enters the vapor compression device 406 from the vapor-liquid separation device 405; the liquid medium inlet 405-3 is connected to the three-stage preheater 204, and the liquid medium outlet 405-4 is connected to the heat exchange device through the second lower circulation pipeline 403. 404 is connected to enable the evaporation working fluid to circulate into the heat exchange device 404 . As shown in Figure 3, in a further embodiment, the first vapor-liquid separator 305 is equipped with at least a waste liquid input port 305-1, a waste liquid outlet 305-3, a vapor-liquid two-phase inlet 305-2, and a secondary steam The outlet 305-5 and the liquid phase reflux port 305-4; the waste liquid outlet 305-3 is connected to the evaporator 303 through the first lower circulation pipeline 304 so that the waste liquid circulates and evaporates to achieve concentration; the waste liquid input port 305-1 is connected into the three-stage preheater 204, so that the preheated radioactive waste liquid enters the first vapor-liquid separator 305. In another specific embodiment, a concentrated liquid discharge pipe 700 for discharging concentrated liquid is disposed on the first circulation pipe, and a concentrated liquid pump 800 is provided on the concentrated liquid discharge pipe 700, so that when concentrated to a predetermined concentration The concentrated liquid can then be discharged through the concentrated liquid discharge pipe 700.
结合上述实施例,蒸汽压缩装置406与蒸发器303连通,并通过压缩升温后的汽化的蒸发工质作为蒸发器303的热源,换热冷凝后的蒸发工质通过连通的第一冷凝水储罐302进入到三级预热器204进一步作为三级预热器204的热源,预热废液进料后通过液相介质入口405-3与三级预热器204的连通管路将蒸发工质输入到汽液分离装置405中,由此实现蒸发工质在系统中的循环。In combination with the above embodiment, the vapor compression device 406 is connected to the evaporator 303, and uses the compressed and heated vaporized evaporation working fluid as the heat source of the evaporator 303, and the condensed evaporation working fluid passes through the connected first condensed water storage tank. 302 enters the three-stage preheater 204 and further serves as the heat source of the three-stage preheater 204. After preheating the waste liquid, the evaporated working fluid is evaporated through the connecting pipeline between the liquid medium inlet 405-3 and the three-stage preheater 204. It is input into the vapor-liquid separation device 405, thereby realizing the circulation of the evaporated working fluid in the system.
在本申请的实施例中,第一汽液分离器305、汽液分离装置405均是用于对蒸发过程得到的汽液混合物进行汽液分离,可采用重力分离形式,具体可在分离器汽相部分设置旋流板或丝网填料去除夹带液滴,提高净化效果。第二汽液分离器306,用于进一步对蒸发过程得到的二次蒸汽进行汽液分离,进一步提高净化效果,可采用填料过滤、喷淋洗涤等净化方式。原料泵201、冷凝液回流泵301、浓缩液泵800以及冷凝泵401在系统中用于流体传送;优选,进料泵、冷凝水泵、冷凝液泵、浓缩液泵等选用变频泵,也可选用工频泵。In the embodiment of the present application, the first vapor-liquid separator 305 and the vapor-liquid separation device 405 are both used to separate the vapor-liquid mixture obtained during the evaporation process. Gravity separation can be used. Specifically, the vapor-liquid separation device can be used in the separator. The phase part is equipped with a swirl plate or mesh filler to remove entrained droplets and improve the purification effect. The second vapor-liquid separator 306 is used to further separate the vapor and liquid of the secondary steam obtained during the evaporation process to further improve the purification effect. Purification methods such as packing filtration and spray washing can be used. The raw material pump 201, the condensate return pump 301, the concentrate pump 800 and the condensate pump 401 are used for fluid transmission in the system; preferably, the feed pump, condensate pump, condensate pump, concentrate pump, etc. use variable frequency pumps, or alternatively Power frequency pump.
下面对本实用新型的放射性废液间壁式热泵蒸发系统的具体工作流程进行描述,下文描述的工作流程与上文描述的放射性废液间壁式热泵蒸发系统可相互对应参照。The specific work flow of the radioactive waste liquid partitioned heat pump evaporation system of the present invention is described below. The work flow described below and the radioactive waste liquid divided wall heat pump evaporation system described above can be mutually referenced.
参照图1所示,放射性废液由原料储罐100原料出口排出,经进原料泵201打入一级预热器202的冷流进口进行初步预热;随后,物料进入二级预热器203继续预热后由二级预热器203上的冷流出口排出;进一步,物料进入三级预热器204后继续进行预热,完成预热后由三级预热器204上的冷流出口排出。预热后的放射性废液由第一汽液分离器305的物料进口进入第一汽液分离器305中,随后放射性废液随着第一下循环管路304内的流体由蒸发器303下部进入蒸发器303的管程,管程内的放射性废液经过与壳程蒸发工质的蒸汽换热后沸腾蒸发成为汽液混合物,随后由第一上循环管路307进入第一汽液分离器305中进行汽液分离;分离得到的二次蒸汽由第一汽液分离器305顶部排出后进入到第二汽液分离器306中,剩余的浓缩液由第一汽液分离器305底部进入第一下循环管路304继续参与循环与蒸发。二次蒸汽在第二汽液分离器306内进一步去除夹带液滴后,汽相的二次蒸汽进入热量交换装置404的壳程中作为热源加热管程内的清水,液相的二次蒸汽回流至第一汽液分离器305内。二次蒸汽与热量交换装置404中的清水换热后成为冷凝液进入第二冷凝水储罐402中;进一步,第二冷凝水储罐402中的高温的冷凝液由冷凝泵401打入二级预热器203热流进口,作为热源预热进料后排出系统进行后续处理;热量交换装置404的管程清水受热后沸腾蒸发,产生的汽液混合物由第二上循环管路407进入汽液分离装置405,经过分离得到的二次清水蒸汽由顶部排出后进入蒸汽压缩装置406中,剩余清水液体进入第二下循环管路403继续参与循环蒸发。蒸汽经蒸汽压缩装置406压缩提高温度及压力后进入蒸发器303中的壳程作为热源加热管程中的废液,换热后高温蒸汽成为冷凝水进入第一冷凝水储罐302中,高温的冷凝水由冷凝水回流泵打入三级预热器204的热流进口,作为热源预热放射性废液后由出口排出并返回到汽液分离装置405中。在第一下循环管路304上设置有浓缩液排料口,当系统内废液浓缩到设定浓度时,由浓缩液泵800将浓缩液打出系统进行后续处理。考虑到运行过程中系统内部可能存在少量不凝结气体,因此在蒸发器303壳程和第一冷凝水储罐302的顶部设置不凝气排口,通过管路连接后接入一级预热器202的热流进口,预热进料后排出系统接入不凝汽处理装置。Referring to Figure 1, the radioactive waste liquid is discharged from the raw material outlet of the raw material storage tank 100, and is driven into the cold flow inlet of the primary preheater 202 through the raw material pump 201 for preliminary preheating; then, the material enters the secondary preheater 203 After continuing to preheat, it is discharged from the cold outflow outlet on the second-level preheater 203; further, the material enters the third-level preheater 204 and continues to be preheated. After completing the preheating, it is discharged through the cold outflow outlet on the third-level preheater 204. discharge. The preheated radioactive waste liquid enters the first vapor-liquid separator 305 through the material inlet of the first vapor-liquid separator 305, and then the radioactive waste liquid enters from the lower part of the evaporator 303 along with the fluid in the first lower circulation pipe 304. On the tube side of the evaporator 303, the radioactive waste liquid in the tube side boils and evaporates into a vapor-liquid mixture after exchanging heat with the steam of the evaporation working medium on the shell side, and then enters the first vapor-liquid separator 305 through the first upper circulation pipe 307. Vapor-liquid separation is performed in The lower circulation pipeline 304 continues to participate in circulation and evaporation. After the secondary steam further removes entrained droplets in the second vapor-liquid separator 306, the secondary steam in the vapor phase enters the shell side of the heat exchange device 404 as a heat source to heat the clean water in the tube side, and the secondary steam in the liquid phase refluxes to the first vapor-liquid separator 305. The secondary steam exchanges heat with the clean water in the heat exchange device 404 and becomes condensate, which enters the second condensate storage tank 402; further, the high-temperature condensate in the second condensate storage tank 402 is pumped into the secondary stage by the condensation pump 401. The heat flow inlet of the preheater 203 is used as a heat source to preheat the feed and then discharge it into the system for subsequent processing; the clear water in the tube side of the heat exchange device 404 boils and evaporates after being heated, and the generated vapor-liquid mixture enters the vapor-liquid separation through the second upper circulation pipe 407 In device 405, the separated secondary clean water vapor is discharged from the top and then enters the vapor compression device 406. The remaining clean water liquid enters the second lower circulation pipe 403 to continue to participate in cyclic evaporation. The steam is compressed by the vapor compression device 406 to increase the temperature and pressure, and then enters the shell side of the evaporator 303 as a heat source to heat the waste liquid in the tube side. After heat exchange, the high-temperature steam becomes condensed water and enters the first condensed water storage tank 302. The high-temperature The condensate water is pumped into the heat flow inlet of the three-stage preheater 204 by the condensate water reflux pump. It is used as a heat source to preheat the radioactive waste liquid and is then discharged from the outlet and returned to the vapor-liquid separation device 405. The first lower circulation line 304 is provided with a concentrated liquid discharge port. When the waste liquid in the system is concentrated to a set concentration, the concentrated liquid pump 800 will pump the concentrated liquid out of the system for subsequent processing. Considering that there may be a small amount of non-condensable gas inside the system during operation, non-condensable gas outlets are provided on the shell side of the evaporator 303 and the top of the first condensate storage tank 302, and are connected through pipelines and then connected to the first-level preheater. 202's heat flow inlet, preheating the feed and then the discharge system is connected to the non-condensable steam treatment device.
通过以上的实施方式的描述,本领域的技术人员可以清楚地了解到各实施方式能够充分利用系统的热能,整个系统设计合理、结构简单、热能利用率高。Through the above description of the embodiments, those skilled in the art can clearly understand that each embodiment can fully utilize the thermal energy of the system, and the entire system has a reasonable design, a simple structure, and a high thermal energy utilization rate.
最后应说明的是:以上实施例仅用以说明本实用新型的技术方案,而非对其限制;尽管参照前述实施例对本实用新型进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本实用新型各实施例技术方案的精神和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention, but not to limit it; although the present utility model has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: The technical solutions described in the foregoing embodiments can still be modified, or some of the technical features can be equivalently replaced; and these modifications or substitutions do not deviate from the essence of the corresponding technical solutions from the spirit of the technical solutions of the various embodiments of the present invention. and scope.
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