CN217903155U - Combined cycle combined cooling heating and power system integrating fuel cell and solar energy - Google Patents

Combined cycle combined cooling heating and power system integrating fuel cell and solar energy Download PDF

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CN217903155U
CN217903155U CN202221686875.8U CN202221686875U CN217903155U CN 217903155 U CN217903155 U CN 217903155U CN 202221686875 U CN202221686875 U CN 202221686875U CN 217903155 U CN217903155 U CN 217903155U
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卢紫艺
段立强
王秋实
郑楠
李智诚
熊嘉丽
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North China Electric Power University
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Abstract

本实用新型涉及一种集成燃料电池与太阳能的联合循环冷热电联供系统,属于冷热电联供技术领域。该联供系统包括:固体氧化物燃料电池子系统;太阳能热互补燃气蒸汽联合循环子系统,包括燃气轮机子系统和蒸汽循环子系统;以及双效吸收式溴化锂制冷子系统。燃气轮机子系统分别与固体氧化物燃料电池子系统和蒸汽循环子系统连接;蒸汽循环子系统还与双效吸收式溴化锂制冷子系统连接。固体氧化物燃料电池子系统能够进行发电和补燃,太阳能热互补燃气蒸汽联合循环子系统能够进行发电以及向用户侧提供热负荷,双效吸收式溴化锂制冷子系统能够向用户侧提供冷负荷,在满足用户冷、热、电多种用能需求的情况下减少系统的能量损失,提高系统的做功能力。

Figure 202221686875

The utility model relates to a combined cycle combined cooling, heating and power supply system integrating fuel cells and solar energy, which belongs to the technical field of combined cooling, heating and power supply. The cogeneration system includes: a solid oxide fuel cell subsystem; a solar thermal complementary gas-steam combined cycle subsystem, including a gas turbine subsystem and a steam cycle subsystem; and a double-effect absorption lithium bromide refrigeration subsystem. The gas turbine subsystem is respectively connected with the solid oxide fuel cell subsystem and the steam cycle subsystem; the steam cycle subsystem is also connected with the double-effect absorption lithium bromide refrigeration subsystem. The solid oxide fuel cell subsystem can generate power and supplementary combustion, the solar thermal complementary gas-steam combined cycle subsystem can generate electricity and provide heat load to the user side, and the double-effect absorption lithium bromide refrigeration subsystem can provide cooling load to the user side, Reduce the energy loss of the system and improve the working ability of the system while meeting the various energy demands of users for cooling, heating and electricity.

Figure 202221686875

Description

一种集成燃料电池与太阳能的联合循环冷热电联供系统A combined cycle combined cooling, heating and power system integrating fuel cells and solar energy

技术领域technical field

本实用新型涉及固体氧化物燃料电池与冷热电联供技术领域,特别是涉及一种集成燃料电池与太阳能的联合循环冷热电联供系统。The utility model relates to the technical field of solid oxide fuel cells and cogeneration of cooling, heating and power, in particular to a combined cycle cogeneration of cooling, heating and power system integrating fuel cells and solar energy.

背景技术Background technique

近年来,为了解决能源匮乏、环境污染等造成的经济发展问题,需要寻求更加高效的系统耦合方式,致力于提高系统的做功能力,减少系统的能量损失,同时引入可再生能源,合理的构建多能源互补的分布式能源系统。长期以来,在世界能源利用结构中化石能源利用占据主要部分。然而随着化石能源的过量消耗以及日趋突出的环境污染等问题不断恶化,太阳能作为储藏量最大的可再生能源,其大规模高效利用已经成为调整世界能源利用结构以及可持续发展的必然要求。因此,如何高效利用可再生能源—太阳能,提高系统的做功能力,同时满足用户冷、热、电的多种用能需求,是本领域亟需解决的技术问题。In recent years, in order to solve the economic development problems caused by energy shortage and environmental pollution, it is necessary to seek a more efficient system coupling method, to improve the system's working ability, reduce the system's energy loss, and introduce renewable energy at the same time. Reasonable construction Multi-energy complementary distributed energy system. For a long time, the use of fossil energy has occupied a major part of the world's energy utilization structure. However, with the excessive consumption of fossil energy and the increasingly prominent environmental pollution and other problems continue to worsen, solar energy, as the renewable energy with the largest reserves, its large-scale and efficient utilization has become an inevitable requirement for adjusting the world's energy utilization structure and sustainable development. Therefore, how to efficiently utilize renewable energy—solar energy, improve the system's working ability, and simultaneously meet the various energy demands of users for cooling, heating, and electricity is a technical problem that needs to be solved urgently in this field.

实用新型内容Utility model content

本实用新型的目的是提供一种集成燃料电池与太阳能的联合循环冷热电联供系统,以在满足用户冷、热、电多种用能需求的情况下减少系统的能量损失,提高系统的做功能力。The purpose of this utility model is to provide a combined cycle cooling, heating and power supply system integrating fuel cells and solar energy, so as to reduce the energy loss of the system and improve the efficiency of the system while meeting the user's various energy requirements for cooling, heating and electricity. Work ability.

为实现上述目的,本实用新型提供了如下方案:In order to achieve the above object, the utility model provides the following scheme:

一种集成燃料电池与太阳能的联合循环冷热电联供系统,包括:固体氧化物燃料电池子系统、太阳能热互补燃气蒸汽联合循环子系统以及双效吸收式溴化锂制冷子系统;所述太阳能热互补燃气蒸汽联合循环子系统包括燃气轮机子系统和蒸汽循环子系统;所述燃气轮机子系统分别与所述固体氧化物燃料电池子系统和所述蒸汽循环子系统连接;所述蒸汽循环子系统还与所述双效吸收式溴化锂制冷子系统连接;A combined cycle cooling, heating and power generation system integrating fuel cells and solar energy, including: a solid oxide fuel cell subsystem, a solar thermal complementary gas-steam combined cycle subsystem, and a double-effect absorption lithium bromide refrigeration subsystem; the solar thermal The complementary gas-steam combined cycle subsystem includes a gas turbine subsystem and a steam cycle subsystem; the gas turbine subsystem is connected to the solid oxide fuel cell subsystem and the steam cycle subsystem respectively; the steam cycle subsystem is also connected to the The double-effect absorption lithium bromide refrigeration subsystem is connected;

所述固体氧化物燃料电池子系统包括:气体混合器(101)、气体换热器(102)、燃料电池阳极(103)、气体分离器(104)、空气换热器(105)、燃料电池阴极(106)、直流交流转换器(107)以及燃料电池后燃室(108);所述气体混合器(101)的出口与所述气体换热器(102)的第一路入口连接;所述气体换热器(102)的第一路出口与所述燃料电池阳极(103)的入口连接;所述燃料电池阳极(103)的出口与所述气体分离器(104)的入口连接;所述气体分离器(104)的第一路出口与所述气体混合器(101)的第一路入口连接,所述气体分离器(104)的第二路出口与所述燃料电池后燃室(108)的第一路入口连接;所述空气换热器(105)的第一路出口与所述燃料电池阴极(106)的入口连接;所述燃料电池阴极(106)的出口与所述燃料电池后燃室(108)的第二路入口连接;所述燃料电池的出口通过所述直流交流转换器(107)进行电输出;所述燃料电池后燃室(108)的出口与所述气体换热器(102)的第二路入口连接;所述气体换热器(102)的第二路出口与所述空气换热器(105)的第一路入口连接;所述空气换热器(105)的第二路出口与所述燃气轮机子系统连接。The solid oxide fuel cell subsystem includes: a gas mixer (101), a gas heat exchanger (102), a fuel cell anode (103), a gas separator (104), an air heat exchanger (105), a fuel cell cathode (106), DC/AC converter (107) and fuel cell afterburner (108); the outlet of the gas mixer (101) is connected to the first inlet of the gas heat exchanger (102); the The first outlet of the gas heat exchanger (102) is connected to the inlet of the fuel cell anode (103); the outlet of the fuel cell anode (103) is connected to the inlet of the gas separator (104); The first outlet of the gas separator (104) is connected to the first inlet of the gas mixer (101), and the second outlet of the gas separator (104) is connected to the afterburner of the fuel cell ( 108) is connected to the first inlet; the first outlet of the air heat exchanger (105) is connected to the inlet of the fuel cell cathode (106); the outlet of the fuel cell cathode (106) is connected to the fuel The second inlet of the battery post-combustion chamber (108) is connected; the outlet of the fuel cell carries out electrical output through the DC/AC converter (107); the outlet of the fuel cell post-combustion chamber (108) is connected to the gas The second road inlet of the heat exchanger (102) is connected; the second road outlet of the gas heat exchanger (102) is connected with the first road inlet of the air heat exchanger (105); the air heat exchanger The second outlet of (105) is connected with the gas turbine subsystem.

可选地,所述燃料电池为固体氧化物燃料电池。Optionally, the fuel cell is a solid oxide fuel cell.

可选地,所述气体混合器(101)的第二路入口通入甲烷;所述气体混合器(101)的第三路入口通入二氧化碳;所述空气换热器(105)的第二路入口通入空气。Optionally, the second inlet of the gas mixer (101) feeds methane; the third inlet of the gas mixer (101) feeds carbon dioxide; the second inlet of the air heat exchanger (105) The entrance of the road leads to the air.

可选地,所述燃气轮机子系统包括:压气机(201)、燃烧室(202)、燃气透平(203)、第一发电机(204)以及烟气混合器(205);Optionally, the gas turbine subsystem includes: a compressor (201), a combustion chamber (202), a gas turbine (203), a first generator (204), and a flue gas mixer (205);

所述压气机(201)通过所述燃烧室(202)与所述燃气透平(203)连接;所述压气机(201)、所述燃气透平(202)和所述第一发电机(204)共轴连接,通过所述第一发电机(204)进行电输出;所述空气换热器(105)的第二路出口与所述烟气混合器(205)的第一路入口连接;所述燃气透平(203)的出口与所述烟气混合器(205)的第二路入口连接。The compressor (201) is connected with the gas turbine (203) through the combustion chamber (202); the compressor (201), the gas turbine (202) and the first generator ( 204) Coaxial connection, through the first generator (204) for electrical output; the second outlet of the air heat exchanger (105) is connected to the first inlet of the flue gas mixer (205) ; The outlet of the gas turbine (203) is connected to the second inlet of the flue gas mixer (205).

可选地,所述压气机(201)的入口通入空气;所述燃烧室(202)的入口通入甲烷。Optionally, the inlet of the compressor (201) is fed with air; the inlet of the combustion chamber (202) is fed with methane.

可选地,所述蒸汽循环子系统包括:余热锅炉、汽轮机高压缸(306)、汽轮机中压缸(307)、汽轮机低压缸(308)、第二发电机(309)、给水换热器(310)、凝汽器(311)、低压给水泵(312)、中压给水泵(313)、高压给水泵(314)、第一太阳能集热器(316)、第一给水混合器(317)、第二太阳能集热器(318)以及第二给水混合器(319);所述余热锅炉包括第一换热器组(301)、第一级高压省煤器(302)、第二换热器组(303)、第二级高压省煤器(304)和第三换热器组(305);所述第一换热器组(301)由低压省煤器、低压蒸发器组成;所述第二换热器组(303)由中压省煤器、中压蒸发器、低压过热器组成;所述第三换热器组(305)由中压过热器、高压蒸发器、再热器和高压过热器组成;Optionally, the steam cycle subsystem includes: waste heat boiler, steam turbine high pressure cylinder (306), steam turbine medium pressure cylinder (307), steam turbine low pressure cylinder (308), second generator (309), feed water heat exchanger ( 310), condenser (311), low-pressure feedwater pump (312), medium-pressure feedwater pump (313), high-pressure feedwater pump (314), first solar collector (316), first feedwater mixer (317) , the second solar heat collector (318) and the second feedwater mixer (319); the waste heat boiler includes the first heat exchanger group (301), the first stage high-pressure economizer (302), the second Group (303), second-stage high-pressure economizer (304) and third heat exchanger group (305); the first heat exchanger group (301) is composed of low-pressure economizer and low-pressure evaporator; The second heat exchanger group (303) is composed of a medium-pressure economizer, a medium-pressure evaporator, and a low-pressure superheater; the third heat exchanger group (305) is composed of a medium-pressure superheater, a high-pressure evaporator, a reheating device and high pressure superheater;

所述烟气混合器(205)的出口与所述余热锅炉的入口连接;所述第三换热器组(305)的高压过热器出口与所述汽轮机高压缸(306)的第一路入口连接;所述汽轮机高压缸(306)的出口与所述第三换热器组(305)的再热器入口连接;所述第三换热器组(305)的再热器出口与所述汽轮机中压缸(307)的入口连接;所述汽轮机中压缸(307)的第一路出口与所述汽轮机低压缸(308)的入口连接,所述汽轮机中压缸(307)的第二路出口与所述给水换热器(310)的第一路入口连接;所述给水换热器(310)的第二路入口接入常温水;所述给水换热器(310)的第一路出口与所述低压给水泵(312)的入口连接;所述给水换热器(310)的第二路出口进行热输出;所述汽轮机高压缸(306)、所述汽轮机中压缸(307)、所述汽轮机低压缸(308)以及所述第二发电机(309)共轴连接,通过所述第二发电机(209)进行电输出;所述汽轮机低压缸(308)的出口与所述凝汽器(311)的入口连接;所述凝汽器(311)的出口与所述低压给水泵(312)的入口连接;所述低压给水泵(312)的出口与所述第一换热器组(301)的低压省煤器入口连接;The outlet of the flue gas mixer (205) is connected to the inlet of the waste heat boiler; the outlet of the high-pressure superheater of the third heat exchanger group (305) is connected to the first inlet of the steam turbine high-pressure cylinder (306) connected; the outlet of the steam turbine high-pressure cylinder (306) is connected with the reheater inlet of the third heat exchanger group (305); the reheater outlet of the third heat exchanger group (305) is connected with the The inlet of the steam turbine medium pressure cylinder (307) is connected; the first outlet of the steam turbine medium pressure cylinder (307) is connected with the inlet of the steam turbine low pressure cylinder (308), the second of the steam turbine medium pressure cylinder (307) The road outlet is connected to the first road inlet of the feed water heat exchanger (310); the second road inlet of the feed water heat exchanger (310) is connected to normal temperature water; the first road inlet of the feed water heat exchanger (310) The outlet of the outlet is connected to the inlet of the low-pressure feed water pump (312); the outlet of the second outlet of the feed water heat exchanger (310) performs heat output; the high-pressure cylinder (306) of the steam turbine, the medium-pressure cylinder (307 ), the steam turbine low-pressure cylinder (308) and the second generator (309) are coaxially connected, and the electrical output is carried out through the second generator (209); the outlet of the steam turbine low-pressure cylinder (308) is connected to the The inlet of the condenser (311) is connected; the outlet of the condenser (311) is connected with the inlet of the low-pressure feed water pump (312); the outlet of the low-pressure feed water pump (312) is connected with the first pump The low-pressure economizer inlet connection of the heater group (301);

所述第二换热器组(303)的低压过热器出口与所述汽轮机低压缸(308)的入口连接;所述第一换热器组(301)的低压省煤器出口中的第一路与所述高压给水泵(314)的入口连接;所述高压给水泵(314)的第一路出口与所述第一级高压省煤器(302)的第一路入口连接;所述第一换热器组(301)的低压省煤器出口中的第二路通过所述中压给水泵(313)与所述第二换热器组(303)的中压省煤器入口连接;The outlet of the low-pressure superheater of the second heat exchanger group (303) is connected to the inlet of the steam turbine low-pressure cylinder (308); the first of the outlets of the low-pressure economizer of the first heat exchanger group (301) The road is connected to the inlet of the high-pressure feed water pump (314); the first road outlet of the high-pressure feed water pump (314) is connected to the first road inlet of the first-stage high-pressure economizer (302); the first road The second path in the outlet of the low-pressure economizer of a heat exchanger group (301) is connected with the inlet of the medium-pressure economizer of the second heat exchanger group (303) through the medium-pressure feed water pump (313);

所述高压给水泵(314)的第二路出口与所述第一太阳能集热器(316)的入口连接;所述第一太阳能集热器(316)的出口与所述第一给水混合器(317)的第一路入口连接;所述第一级高压省煤器(302)的第二路出口与所述第一给水混合器(317)的第二路入口连接;所述第一给水混合器(317)的第一路出口与所述第二太阳能集热器(318)的入口连接;所述第二太阳能集热器(318)的出口与所述第二给水混合器(319)的第一路入口连接;所述第一给水混合器(317)的第二路出口与所述第二级高压省煤器(304)的第二路入口连接;所述第二级高压省煤器(304)的第二路出口与所述第二给水混合器(319)的第二路入口连接;所述第二给水混合器(319)的出口与所述第三换热器组(305)的高压蒸发器入口连接。The second outlet of the high-pressure feed water pump (314) is connected to the inlet of the first solar heat collector (316); the outlet of the first solar heat collector (316) is connected to the first water feed mixer (317) is connected to the first road inlet; the second road outlet of the first stage high-pressure economizer (302) is connected to the second road inlet of the first water feed mixer (317); the first feed water The first way outlet of the mixer (317) is connected with the inlet of the second solar heat collector (318); the outlet of the second solar heat collector (318) is connected with the second water feed mixer (319) The first road inlet connection; the second road outlet of the first feedwater mixer (317) is connected with the second road inlet of the second-stage high-pressure economizer (304); the second-stage high-pressure economizer The second outlet of the device (304) is connected with the second inlet of the second feedwater mixer (319); the outlet of the second feedwater mixer (319) is connected with the third heat exchanger group (305 ) to the high pressure evaporator inlet connection.

可选地,所述第一太阳能集热器(316)和所述第二太阳能集热器(318)均为槽式太阳能集热器。Optionally, both the first solar collector (316) and the second solar collector (318) are trough solar collectors.

可选地,所述双效吸收式溴化锂制冷子系统包括:双效吸收式溴化锂制冷机(315);Optionally, the double-effect absorption lithium bromide refrigeration subsystem includes: a double-effect absorption lithium bromide refrigerator (315);

所述第一换热器组(301)的低压蒸发器出口中的第一路与所述双效吸收式溴化锂制冷机(315)的第一路入口连接;所述双效吸收式溴化锂制冷机(315)的第一路出口与所述第一换热器组(301)的低压省煤器入口中的第二路连接;所述双效吸收式溴化锂制冷机(315)的第二路入口连接冷冻水进水;所述双效吸收式溴化锂制冷机(315)的第二路出口进行冷输出。The first path in the outlet of the low-pressure evaporator of the first heat exchanger group (301) is connected to the first path inlet of the double-effect absorption lithium bromide refrigerator (315); the double-effect absorption lithium bromide refrigerator The first way outlet of (315) is connected with the second way in the low-pressure economizer inlet of described first heat exchanger group (301); the second way inlet of described double-effect absorption lithium bromide refrigerator (315) Connect the chilled water inlet; the second outlet of the double-effect absorption lithium bromide refrigerator (315) performs cold output.

根据本实用新型提供的具体实施例,本实用新型公开了以下技术效果:According to the specific embodiment provided by the utility model, the utility model discloses the following technical effects:

本实用新型提供了一种集成燃料电池与太阳能的联合循环冷热电联供系统,包括:固体氧化物燃料电池子系统、太阳能热互补燃气蒸汽联合循环子系统以及双效吸收式溴化锂制冷子系统;所述太阳能热互补燃气蒸汽联合循环子系统包括燃气轮机子系统和蒸汽循环子系统;所述燃气轮机子系统分别与所述固体氧化物燃料电池子系统和所述蒸汽循环子系统连接;所述蒸汽循环子系统还与所述双效吸收式溴化锂制冷子系统连接。所述固体氧化物燃料电池子系统能够进行发电和补燃,将燃料电池用于发电,然后利用燃料电池排放的高温废气作为补燃气体,与燃气轮机子系统排气混合后共同驱动蒸汽循环子系统工作,能够有效利用高温燃料电池产生的废热,减少系统中的能量损失;所述太阳能热互补燃气蒸汽联合循环子系统能够进行发电以及向用户侧提供热负荷,所述双效吸收式溴化锂制冷子系统能够向用户侧提供冷负荷,在满足用户冷、热、电多种用能需求的情况下减少了系统的能量损失,提高了系统的做功能力。The utility model provides a combined cycle cooling, heating and power supply system integrating fuel cells and solar energy, comprising: a solid oxide fuel cell subsystem, a solar thermal complementary gas-steam combined cycle subsystem, and a double-effect absorption lithium bromide refrigeration subsystem The solar thermal complementary gas-steam combined cycle subsystem includes a gas turbine subsystem and a steam cycle subsystem; the gas turbine subsystem is connected to the solid oxide fuel cell subsystem and the steam cycle subsystem respectively; the steam The circulation subsystem is also connected with the double-effect absorption lithium bromide refrigeration subsystem. The solid oxide fuel cell subsystem is capable of power generation and supplementary combustion. The fuel cell is used for power generation, and then the high-temperature exhaust gas discharged from the fuel cell is used as supplementary combustion gas, which is mixed with the exhaust gas of the gas turbine subsystem to jointly drive the steam cycle subsystem. work, can effectively utilize the waste heat generated by high-temperature fuel cells, and reduce energy loss in the system; the solar thermal complementary gas-steam combined cycle subsystem can generate electricity and provide heat load to the user side, and the double-effect absorption lithium bromide refrigeration sub-system The system can provide cooling load to the user side, which reduces the energy loss of the system and improves the working ability of the system while meeting the various energy demands of the user for cooling, heating and electricity.

附图说明Description of drawings

为了更清楚地说明本实用新型实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本实用新型的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the accompanying drawings required in the embodiments will be briefly introduced below. Obviously, the accompanying drawings in the following description are only the present invention. For some embodiments of the invention, those skilled in the art can also obtain other drawings according to these drawings without paying creative efforts.

图1为本实用新型一种集成燃料电池与太阳能的联合循环冷热电联供系统的结构示意图。Fig. 1 is a schematic structural diagram of a combined cycle combined cooling, heating and power supply system integrating fuel cells and solar energy of the present invention.

具体实施方式Detailed ways

下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. example. Based on the embodiments of the present utility model, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the scope of protection of the present utility model.

本实用新型的目的是提供一种集成燃料电池与太阳能的联合循环冷热电联供系统,以在满足用户冷、热、电多种用能需求的情况下减少系统的能量损失,提高系统的做功能力。The purpose of this utility model is to provide a combined cycle cooling, heating and power supply system integrating fuel cells and solar energy, so as to reduce the energy loss of the system and improve the efficiency of the system while meeting the user's various energy requirements for cooling, heating and electricity. Work ability.

为使本实用新型的上述目的、特征和优点能够更加明显易懂,下面结合附图和具体实施方式对本实用新型作进一步详细的说明。In order to make the above purpose, features and advantages of the utility model more obvious and understandable, the utility model will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.

图1为本实用新型一种集成燃料电池与太阳能的联合循环冷热电联供系统的结构示意图,如图1所示,所述集成燃料电池与太阳能的联合循环冷热电联供系统(简称联供系统)包括:固体氧化物燃料电池子系统、太阳能热互补燃气蒸汽联合循环子系统以及双效吸收式溴化锂制冷子系统,各子系统之间通过管路和阀门进行连接。所述太阳能热互补燃气蒸汽联合循环子系统包括燃气轮机子系统和蒸汽循环子系统;所述燃气轮机子系统分别与所述固体氧化物燃料电池子系统和所述蒸汽循环子系统连接;所述蒸汽循环子系统还与所述双效吸收式溴化锂制冷子系统连接。Fig. 1 is a structural schematic diagram of a combined cycle combined cooling, heating and power system integrating fuel cells and solar energy of the present invention, as shown in Fig. Cogeneration system) includes: solid oxide fuel cell subsystem, solar thermal complementary gas-steam combined cycle subsystem, and double-effect absorption lithium bromide refrigeration subsystem, and the subsystems are connected through pipelines and valves. The solar thermal complementary gas-steam combined cycle subsystem includes a gas turbine subsystem and a steam cycle subsystem; the gas turbine subsystem is connected to the solid oxide fuel cell subsystem and the steam cycle subsystem respectively; the steam cycle The subsystem is also connected with the double-effect absorption lithium bromide refrigeration subsystem.

所述固体氧化物燃料电池子系统用于发电和补燃,采用固体氧化物燃料电池(Solid Oxide Fuel Cell,SOFC)用于发电,然后利用燃料电池排放的高温废气作为补燃气体,与燃气轮机子系统排气在烟气混合器205中混合后共同驱动太阳能热互补燃气蒸汽联合循环子系统中的蒸汽循环子系统工作。The solid oxide fuel cell subsystem is used for power generation and supplementary combustion, using a solid oxide fuel cell (Solid Oxide Fuel Cell, SOFC) for power generation, and then using the high-temperature exhaust gas discharged from the fuel cell as supplementary combustion gas, and the gas turbine sub-system After the system exhaust is mixed in the flue gas mixer 205, it jointly drives the steam cycle subsystem in the solar heat complementary gas-steam combined cycle subsystem to work.

所述太阳能热互补燃气蒸汽联合循环子系统用于发电以及向用户侧提供热负荷。其中太阳能热互补燃气蒸汽联合循环子系统中的燃气轮机子系统主要用来发电,燃气轮机子系统排气用来驱动太阳能热互补燃气蒸汽联合循环子系统中的蒸汽循环子系统,采用太阳能集热器替代余热锅炉中第一级高压省煤器和第二级高压省煤器的部分热负荷,当太阳能辐照强度达到一定程度时,太阳能集热器开始工作,余热锅炉中的循环工质量增多,从而提高汽轮机发电量;同时本系统从余热锅炉中的汽轮机中压缸排汽处抽汽,用以加热生活热水,向用户侧输出热负荷。The solar thermal complementary gas-steam combined cycle subsystem is used to generate electricity and provide heat load to the user side. Among them, the gas turbine subsystem in the solar thermal complementary gas-steam combined cycle subsystem is mainly used for power generation, and the exhaust gas of the gas turbine subsystem is used to drive the steam cycle subsystem in the solar thermal complementary gas-steam combined cycle subsystem, which is replaced by solar collectors Part of the heat load of the first-stage high-pressure economizer and the second-stage high-pressure economizer in the waste heat boiler, when the solar radiation intensity reaches a certain level, the solar collector starts to work, and the circulating work mass in the waste heat boiler increases, thereby Increase the power generation capacity of the steam turbine; at the same time, the system extracts steam from the exhaust steam of the steam turbine medium pressure cylinder in the waste heat boiler to heat domestic hot water and output heat load to the user side.

所述双效吸收式溴化锂制冷子系统用于向用户侧提供冷负荷。The double-effect absorption lithium bromide refrigeration subsystem is used to provide cooling load to the user side.

具体地,参见图1,所述固体氧化物燃料电池子系统包括:气体混合器101、气体换热器102、燃料电池阳极103、气体分离器104、空气换热器105、燃料电池阴极106、直流交流转换器107以及燃料电池后燃室108。在实际应用中,所述燃料电池为固体氧化物燃料电池。Specifically, referring to FIG. 1, the solid oxide fuel cell subsystem includes: a gas mixer 101, a gas heat exchanger 102, a fuel cell anode 103, a gas separator 104, an air heat exchanger 105, a fuel cell cathode 106, DC to AC converter 107 and fuel cell afterburner 108 . In practical applications, the fuel cell is a solid oxide fuel cell.

其中,所述气体混合器101的第二路入口通入甲烷;所述气体混合器101的第三路入口通入二氧化碳;所述气体混合器101的出口与所述气体换热器102的第一路入口连接;所述气体换热器102的第一路出口与所述燃料电池阳极103的入口连接;所述燃料电池阳极103的出口与所述气体分离器104的入口连接;所述气体分离器104的第一路出口与所述气体混合器101的第一路入口连接,所述气体分离器104的第二路出口与所述燃料电池后燃室108的第一路入口连接;所述空气换热器105的第一路出口与所述燃料电池阴极106的入口连接;所述燃料电池阴极106的出口与所述燃料电池后燃室108的第二路入口连接;所述燃料电池的出口通过所述直流交流转换器107进行电输出;所述燃料电池后燃室108的出口与所述气体换热器102的第二路入口连接;所述气体换热器102的第二路出口与所述空气换热器105的第一路入口连接;所述空气换热器105的第二路入口通入空气;所述空气换热器105的第二路出口与所述燃气轮机子系统的烟气混合器205连接。Wherein, the second inlet of the gas mixer 101 is fed into methane; the third inlet of the gas mixer 101 is fed into carbon dioxide; One inlet is connected; the first outlet of the gas heat exchanger 102 is connected with the inlet of the fuel cell anode 103; the outlet of the fuel cell anode 103 is connected with the inlet of the gas separator 104; the gas The first way outlet of the separator 104 is connected with the first way inlet of the gas mixer 101, and the second way outlet of the gas separator 104 is connected with the first way inlet of the fuel cell afterburner 108; The first outlet of the air heat exchanger 105 is connected to the inlet of the fuel cell cathode 106; the outlet of the fuel cell cathode 106 is connected to the second inlet of the fuel cell afterburner 108; the fuel cell The outlet of the gas heat exchanger 102 is connected to the second path inlet of the gas heat exchanger 102; the second path of the gas heat exchanger 102 is The outlet is connected to the first inlet of the air heat exchanger 105; the second inlet of the air heat exchanger 105 is fed with air; the second outlet of the air heat exchanger 105 is connected to the gas turbine subsystem The flue gas mixer 205 is connected.

所述固体氧化物燃料电池子系统中的高温燃料电池具有清洁高效的工作特点,发电效率理论上可以达到50%以上,电池排出的废气温度较高,具有较高的利用价值且易于与传统动力系统集成。此外固体氧化物燃料电池使用固体陶瓷作为电解质、阴极和阳极材料,可以避免燃料电池电解液流失和热腐蚀等问题,且固体氧化物燃料电池具有高效发电、清洁、燃料利用灵活等优点。The high-temperature fuel cell in the solid oxide fuel cell subsystem has clean and efficient working characteristics, and the power generation efficiency can theoretically reach more than 50%. system integration. In addition, solid oxide fuel cells use solid ceramics as electrolyte, cathode and anode materials, which can avoid problems such as fuel cell electrolyte loss and thermal corrosion, and solid oxide fuel cells have the advantages of high-efficiency power generation, cleanness, and flexible fuel utilization.

所述太阳能热互补燃气蒸汽联合循环子系统是将太阳能引入高效的联合循环系统中,从而提高太阳能的光电转化效率、节约成本、减少化石能源消耗。The solar thermal complementary gas-steam combined cycle subsystem introduces solar energy into a high-efficiency combined cycle system, thereby improving the photoelectric conversion efficiency of solar energy, saving costs, and reducing fossil energy consumption.

参见图1,所述太阳能热互补燃气蒸汽联合循环子系统中的所述燃气轮机子系统包括:压气机201、燃烧室202、燃气透平203、第一发电机204以及烟气混合器205。Referring to FIG. 1 , the gas turbine subsystem in the solar thermal complementary gas-steam combined cycle subsystem includes: a compressor 201 , a combustion chamber 202 , a gas turbine 203 , a first generator 204 and a flue gas mixer 205 .

其中,所述压气机201通过所述燃烧室202与所述燃气透平203连接;所述压气机201的入口通入空气;所述燃烧室202的入口通入甲烷。所述压气机201、所述燃气透平202和所述第一发电机204共轴连接,通过所述第一发电机204进行电输出,即进行发电。所述空气换热器105的第二路出口与所述烟气混合器205的第一路入口连接;所述燃气透平203的出口与所述烟气混合器205的第二路入口连接。Wherein, the compressor 201 is connected with the gas turbine 203 through the combustion chamber 202; the inlet of the compressor 201 is fed with air; the inlet of the combustion chamber 202 is fed with methane. The compressor 201 , the gas turbine 202 and the first generator 204 are coaxially connected, and the first generator 204 is used to output electricity, that is, to generate electricity. The second outlet of the air heat exchanger 105 is connected to the first inlet of the flue gas mixer 205 ; the outlet of the gas turbine 203 is connected to the second inlet of the flue gas mixer 205 .

所述太阳能热互补燃气蒸汽联合循环子系统中的所述蒸汽循环子系统包括:余热锅炉(其包括第一换热器组301、第一级高压省煤器302、第二换热器组303、第二级高压省煤器304、第三换热器组305)、汽轮机高压缸306、汽轮机中压缸307、汽轮机低压缸308、第二发电机309、给水换热器310、凝汽器311、低压给水泵312、中压给水泵313、高压给水泵314、第一太阳能集热器316、第一给水混合器317、第二太阳能集热器318以及第二给水混合器319。所述第一换热器组301由低压省煤器、低压蒸发器组成;所述第二换热器组303由中压省煤器、中压蒸发器、低压过热器组成;所述第三换热器组305由中压过热器、高压蒸发器、再热器和高压过热器组成。在实际应用中,第一换热器组301、第一级高压省煤器302、第二换热器组303、第二级高压省煤器304、第三换热器组305通常为余热锅炉的组成部分。The steam cycle subsystem in the solar thermal complementary gas-steam combined cycle subsystem includes: a waste heat boiler (which includes a first heat exchanger group 301, a first-stage high-pressure economizer 302, a second heat exchanger group 303 , second stage high pressure economizer 304, third heat exchanger group 305), steam turbine high pressure cylinder 306, steam turbine medium pressure cylinder 307, steam turbine low pressure cylinder 308, second generator 309, feed water heat exchanger 310, condenser 311 , low-pressure feedwater pump 312 , medium-pressure feedwater pump 313 , high-pressure feedwater pump 314 , first solar collector 316 , first feedwater mixer 317 , second solar collector 318 and second feedwater mixer 319 . The first heat exchanger group 301 is composed of a low-pressure economizer and a low-pressure evaporator; the second heat exchanger group 303 is composed of a medium-pressure economizer, a medium-pressure evaporator, and a low-pressure superheater; the third The heat exchanger group 305 is composed of a medium pressure superheater, a high pressure evaporator, a reheater and a high pressure superheater. In practical applications, the first heat exchanger group 301, the first stage high-pressure economizer 302, the second heat exchanger group 303, the second stage high-pressure economizer 304, and the third heat exchanger group 305 are usually waste heat boilers made of.

其中,所述烟气混合器(205)的出口与所述余热锅炉的入口连接;所述余热锅炉中流经水、汽水混合物或蒸汽。所述第三换热器组305的高压过热器出口与所述汽轮机高压缸306的第一路入口连接;所述汽轮机高压缸306的出口与所述第三换热器组305的再热器入口连接;所述第三换热器组305的再热器出口与所述汽轮机中压缸307的入口连接;所述汽轮机中压缸307的第一路出口与所述汽轮机低压缸308的入口连接,所述汽轮机中压缸307的第二路出口与所述给水换热器310的第一路入口连接;所述给水换热器310的第二路入口接入常温水;所述给水换热器310的第一路出口与所述低压给水泵312的入口连接。所述给水换热器310的第二路出口进行热输出,即产生热水作为热负荷。所述汽轮机高压缸306、所述汽轮机中压缸307、所述汽轮机低压缸308以及所述第二发电机309共轴连接,通过所述第二发电机209进行电输出;所述汽轮机低压缸308的出口与所述凝汽器311的入口连接;所述凝汽器311的出口与所述低压给水泵312的入口连接;所述低压给水泵312的出口与所述第一换热器组301的低压省煤器入口连接。Wherein, the outlet of the flue gas mixer (205) is connected to the inlet of the waste heat boiler; water, steam-water mixture or steam flows through the waste heat boiler. The outlet of the high pressure superheater of the third heat exchanger group 305 is connected with the first inlet of the steam turbine high pressure cylinder 306; the outlet of the steam turbine high pressure cylinder 306 is connected with the reheater of the third heat exchanger group 305 Inlet connection; the reheater outlet of the third heat exchanger group 305 is connected to the inlet of the steam turbine medium pressure cylinder 307; the first outlet of the steam turbine medium pressure cylinder 307 is connected to the inlet of the steam turbine low pressure cylinder 308 Connected, the second outlet of the medium pressure cylinder 307 of the steam turbine is connected to the first inlet of the feed water heat exchanger 310; the second inlet of the feed water heat exchanger 310 is connected to normal temperature water; the feed water exchange The first outlet of the heater 310 is connected to the inlet of the low-pressure feed water pump 312 . The second outlet of the feedwater heat exchanger 310 performs heat output, that is, hot water is generated as a heat load. The steam turbine high-pressure cylinder 306, the steam turbine medium-pressure cylinder 307, the steam turbine low-pressure cylinder 308, and the second generator 309 are coaxially connected, and the second generator 209 is used for electrical output; the steam turbine low-pressure cylinder The outlet of 308 is connected to the inlet of the condenser 311; the outlet of the condenser 311 is connected to the inlet of the low-pressure feed water pump 312; the outlet of the low-pressure feed water pump 312 is connected to the first heat exchanger group 301 low pressure economizer inlet connection.

所述第二换热器组303的低压过热器出口与所述汽轮机低压缸308的入口连接;所述第一换热器组301的低压省煤器出口中的第一路与所述高压给水泵314的入口连接;所述高压给水泵314的第一路出口与所述第一级高压省煤器302的第一路入口连接;所述第一换热器组301的低压省煤器出口中的第二路通过所述中压给水泵313与所述第二换热器组303的中压省煤器入口连接。The outlet of the low-pressure superheater of the second heat exchanger group 303 is connected to the inlet of the steam turbine low-pressure cylinder 308; the first path in the outlet of the low-pressure economizer of the first heat exchanger group 301 is connected to the high-pressure feed The inlet of the water pump 314 is connected; the first outlet of the high-pressure feed water pump 314 is connected with the first inlet of the first-stage high-pressure economizer 302; the outlet of the low-pressure economizer of the first heat exchanger group 301 The second path is connected to the inlet of the medium-pressure economizer of the second heat exchanger group 303 through the medium-pressure feed water pump 313 .

所述高压给水泵314的第二路出口与所述第一太阳能集热器316的入口连接;所述第一太阳能集热器316的出口与所述第一给水混合器317的第一路入口连接;所述第一级高压省煤器302的第二路出口与所述第一给水混合器317的第二路入口连接;所述第一给水混合器317的第一路出口与所述第二太阳能集热器318的入口连接;所述第二太阳能集热器318的出口与所述第二给水混合器319的第一路入口连接;所述第一给水混合器317的第二路出口与所述第二级高压省煤器304的第二路入口连接;所述第二级高压省煤器304的第二路出口与所述第二给水混合器319的第二路入口连接;所述第二给水混合器319的出口与所述第三换热器组305的高压蒸发器入口连接。The second outlet of the high-pressure feed water pump 314 is connected to the inlet of the first solar heat collector 316; the outlet of the first solar collector 316 is connected to the first inlet of the first water feed mixer 317 connection; the second outlet of the first-stage high-pressure economizer 302 is connected to the second inlet of the first feedwater mixer 317; the first outlet of the first feedwater mixer 317 is connected to the second outlet of the first feedwater mixer 317 The inlet of two solar heat collectors 318 is connected; The outlet of the second solar heat collector 318 is connected with the first road inlet of the second feedwater mixer 319; the second road outlet of the first feedwater mixer 317 It is connected with the second-way inlet of the second-stage high-pressure economizer 304; the second-way outlet of the second-stage high-pressure economizer 304 is connected with the second-way inlet of the second feedwater mixer 319; the The outlet of the second feedwater mixer 319 is connected to the inlet of the high-pressure evaporator of the third heat exchanger group 305 .

所述第一换热器组301、第一级高压省煤器302、第二换热器组303、第二级高压省煤器304、第三换热器组305按照一定位置排列,烟气自烟气混合器205出口流经所述第一换热器组301、第一级高压省煤器302以及第二换热器组303。图1中第一换热器组301、第一级高压省煤器302、第二换热器组303、第二级高压省煤器304、第三换热器组305之间的箭头表示的是烟气方向,换热器由管道组成,汽水在管道中流动,烟气流经管道外表面。所述汽轮机高压缸(306)的出口与所述第三换热器组(305)的再热器入口连接。The first heat exchanger group 301, the first-stage high-pressure economizer 302, the second heat exchanger group 303, the second-stage high-pressure economizer 304, and the third heat exchanger group 305 are arranged in a certain position, and the flue gas From the outlet of the flue gas mixer 205 , it flows through the first heat exchanger group 301 , the first stage high-pressure economizer 302 and the second heat exchanger group 303 . In Fig. 1, the arrows between the first heat exchanger group 301, the first stage high-pressure economizer 302, the second heat exchanger group 303, the second stage high-pressure economizer 304, and the third heat exchanger group 305 indicate is the direction of the flue gas, the heat exchanger is composed of pipes, the soda and water flow in the pipes, and the flue gas flows through the outer surface of the pipes. The outlet of the steam turbine high-pressure cylinder (306) is connected with the reheater inlet of the third heat exchanger group (305).

其中,所述第一太阳能集热器316和所述第二太阳能集热器318均为槽式太阳能集热器。Wherein, both the first solar collector 316 and the second solar collector 318 are trough solar collectors.

参见图1,所述双效吸收式溴化锂制冷子系统包括:双效吸收式溴化锂制冷机315。其中,所述第一换热器组301的低压蒸发器出口中的第一路与所述双效吸收式溴化锂制冷机315的第一路入口连接;所述双效吸收式溴化锂制冷机315的第一路出口与所述第一换热器组301的低压省煤器入口中的第二路连接;所述双效吸收式溴化锂制冷机315的第二路入口连接冷冻水进水;所述双效吸收式溴化锂制冷机315的第二路出口进行冷输出,即产生冷冻水出水作为冷负荷。Referring to FIG. 1 , the double-effect absorption lithium bromide refrigeration subsystem includes: a double-effect absorption lithium bromide refrigerator 315 . Wherein, the first road in the outlet of the low-pressure evaporator of the first heat exchanger group 301 is connected to the first road inlet of the double-effect absorption lithium bromide refrigerator 315; The first road outlet is connected with the second road in the low-pressure economizer inlet of the first heat exchanger group 301; the second road inlet of the double-effect absorption lithium bromide refrigerator 315 is connected with chilled water inlet; The second outlet of the double-effect absorption lithium bromide refrigerator 315 conducts cold output, that is, produces chilled water outlet as a cooling load.

参见图1,本实用新型所述集成燃料电池与太阳能的联合循环冷热电联供系统的工作过程描述如下。Referring to FIG. 1 , the working process of the integrated fuel cell and solar energy combined cycle combined cooling, heating and power supply system described in the present invention is described as follows.

甲烷分别送入固体氧化物燃料电池子系统的气体混合器101以及燃气轮机子系统的燃烧室202中,固体氧化物燃料电池发生电化学反应从而发电;甲烷在燃气轮机子系统的燃烧室202中燃烧,燃烧室202排气驱动燃气透平203工作发电,由第一发电机204进行电输出。固体氧化物燃料电池排气与燃气透平203排气混合后驱动太阳能热互补燃气蒸汽联合循环子系统中的蒸汽循环子系统。所述蒸汽循环子系统中以余热锅炉为受热面载体,采用第一、第二太阳能集热器316、318替代余热锅炉中第一级高压省煤器302和第二级高压省煤器304的部分热负荷,当太阳能辐照强度达到一定程度时,太阳能集热器316、318开始工作,余热锅炉中的循环工质量增多,从而提高汽轮机306、307、308的发电量;同时本联供系统分别从余热锅炉中的第一换热器组(也称低压汽包)301和汽轮机中压缸307排汽处抽汽,用以驱动双效吸收式溴化锂制冷机315工作和加热生活热水,向用户侧输出冷负荷(冷冻水出水)和热负荷(热水)。Methane is fed into the gas mixer 101 of the solid oxide fuel cell subsystem and the combustor 202 of the gas turbine subsystem respectively, and the solid oxide fuel cell undergoes an electrochemical reaction to generate electricity; methane is burned in the combustor 202 of the gas turbine subsystem, The exhaust gas from the combustion chamber 202 drives the gas turbine 203 to generate electricity, and the first generator 204 outputs electricity. The exhaust gas from the solid oxide fuel cell is mixed with the exhaust gas from the gas turbine 203 to drive the steam cycle subsystem in the solar thermal complementary gas-steam combined cycle subsystem. In the steam cycle subsystem, the waste heat boiler is used as the heating surface carrier, and the first and second solar collectors 316 and 318 are used to replace the first-stage high-pressure economizer 302 and the second-stage high-pressure economizer 304 in the waste heat boiler. Part of the heat load, when the solar radiation intensity reaches a certain level, the solar collectors 316, 318 start to work, and the circulating work mass in the waste heat boiler increases, thereby increasing the power generation of the steam turbines 306, 307, 308; at the same time, the combined power supply system Extract steam from the first heat exchanger group (also known as low-pressure steam drum) 301 of the waste heat boiler and the exhaust steam of the medium-pressure cylinder 307 of the steam turbine to drive the double-effect absorption lithium bromide refrigerator 315 to work and heat domestic hot water. Output cooling load (chilled water outlet) and heat load (hot water) to the user side.

具体地,当所述联供系统工作在一定太阳能辐射强度下时,所述高压给水泵314出口处的给水分成两条线路,在一条线路中,高压给水泵314出口给水进入第一太阳能集热器316中吸收太阳光热能,当第一太阳能集热器316出口给水温度与第一级高压省煤器302出口给水温度相同时,第一太阳能集热器316出口给水与第一级高压省煤器302出口给水进入所述第一给水混合器317中进行混合。所述第一给水混合器317出口处的给水分成两条线路,在一条线路中,第一给水混合器317出口给水进入第二太阳能集热器318中吸收太阳光热能,当第二太阳能集热器318出口给水温度与第二级高压省煤器304出口给水温度相同时,第二太阳能集热器318出口给水与第二级高压省煤器304出口给水进入所述第二给水混合器319中混合后进入所述由中压过热器、高压蒸发器、再热器和高压过热器组成的第三换热器组305的高压蒸发器中。Specifically, when the joint supply system works under a certain solar radiation intensity, the feed water at the outlet of the high-pressure feed water pump 314 is divided into two lines, and in one line, the feed water at the outlet of the high-pressure feed water pump 314 enters the first solar collector The heat energy of the sun is absorbed in the device 316. When the temperature of the feed water at the outlet of the first solar collector 316 is the same as that of the outlet feed water of the first stage high-pressure economizer 302, the outlet feed water of the first solar collector 316 is the same as that of the first stage high-pressure economizer. The feed water at the outlet of the tank 302 enters the first feed water mixer 317 for mixing. The feedwater at the outlet of the first feedwater mixer 317 is divided into two lines. In one line, the feedwater at the outlet of the first feedwater mixer 317 enters the second solar heat collector 318 to absorb solar heat energy. When the second solar heat collector When the outlet feedwater temperature of the device 318 is the same as the outlet feedwater temperature of the second-stage high-pressure economizer 304, the outlet feedwater of the second solar collector 318 and the outlet feedwater of the second-stage high-pressure economizer 304 enter the second feedwater mixer 319 After being mixed, it enters the high-pressure evaporator of the third heat exchanger group 305 composed of a medium-pressure superheater, a high-pressure evaporator, a reheater and a high-pressure superheater.

当太阳能辐照强度不足时,联供系统通过燃烧甲烷维持正常工作状态,燃料电池、燃气透平203和蒸汽透平(包括汽轮机高压缸306、汽轮机中压缸307、汽轮机低压缸308)正常发电,同时双效吸收式溴化锂制冷机315和给水换热器310向用户侧提供冷负荷和加热生活热水。When the solar radiation intensity is insufficient, the cogeneration system maintains a normal working state by burning methane, and the fuel cell, gas turbine 203 and steam turbine (including the high-pressure cylinder 306 of the steam turbine, the medium-pressure cylinder 307 of the steam turbine, and the low-pressure cylinder 308 of the steam turbine) generate electricity normally , while the double-effect absorption lithium bromide refrigerator 315 and the feed water heat exchanger 310 provide cooling loads and heat domestic hot water to the user side.

本实用新型公开的一种集成燃料电池与太阳能的联合循环冷热电联供系统,该联供系统包含固体氧化物燃料电池(SOFC)子系统、太阳能热互补燃气蒸汽联合循环(ISCC)子系统和双效吸收式溴化锂制冷子系统。该联供系统首先利用固体氧化物燃料电池产生的高温尾气预热进入燃料电池阴极的空气,然后与燃气轮机子系统排气混合后一起进入余热锅炉中;以余热锅炉作为余热回收载体,利用太阳能替代余热锅炉中第一级高压省煤器和第二级高压省煤器的部分热负荷,增大底循环的做功能力。为了充分满足用户冷、热负荷需求,本联供系统从余热锅炉的低压汽包处抽取部分蒸汽,利用这股蒸汽驱动双效吸收式溴化锂制冷系统工作。此外,本联供系统在中压缸排汽处抽取部分蒸汽,利用这股蒸汽加热生活热水。因此,本实用新型提供的所述联供系统在满足用户冷、热、电的多种用能需求的同时,能够有效利用高温燃料电池产生的废热,减少系统中的能量损失;并且高效利用可再生能源—太阳能,提高系统的做功能力。The utility model discloses a combined cycle cooling, heating and power supply system integrating fuel cells and solar energy. The combined supply system includes a solid oxide fuel cell (SOFC) subsystem and a solar thermal complementary gas-steam combined cycle (ISCC) subsystem. And double-effect absorption lithium bromide refrigeration subsystem. The cogeneration system first uses the high-temperature exhaust gas generated by the solid oxide fuel cell to preheat the air entering the cathode of the fuel cell, and then mixes with the exhaust gas from the gas turbine subsystem and enters the waste heat boiler; the waste heat boiler is used as the waste heat recovery carrier, and the solar energy is used instead Part of the heat load of the first-stage high-pressure economizer and the second-stage high-pressure economizer in the waste heat boiler increases the working capacity of the bottom cycle. In order to fully meet the user's cooling and heating load requirements, the cogeneration system extracts part of the steam from the low-pressure steam drum of the waste heat boiler, and uses this steam to drive the double-effect absorption lithium bromide refrigeration system to work. In addition, the joint supply system extracts part of the steam from the exhaust steam of the medium pressure cylinder, and uses this steam to heat domestic hot water. Therefore, the cogeneration system provided by the utility model can effectively utilize the waste heat generated by the high-temperature fuel cell and reduce the energy loss in the system while meeting the various energy demands of the user for cooling, heating and electricity; and the efficient utilization can Renewable energy - solar energy, to improve the system's ability to work.

下面提供一个具体实施例说明本实用新型提供的所述联供系统的技术效果。该实施例中,燃料选用西气东输天然气,天气数据选用拉萨某一典型日数据;表1列出了所述联供系统的热力学分析基础数据。A specific example is provided below to illustrate the technical effect of the joint supply system provided by the utility model. In this embodiment, the fuel is natural gas from the West-East Gas Pipeline, and the weather data is selected from a typical day in Lhasa; Table 1 lists the basic data of thermodynamic analysis of the joint supply system.

表1联供系统热力学分析基础数据Table 1 Basic data of thermodynamic analysis of cogeneration system

Figure BDA0003726270560000111
Figure BDA0003726270560000111

由表1可知,所述联供系统在拉萨某一典型日稳定工况下运行时,考虑太阳能输入热量,其能量效率达61.9%,

Figure BDA0003726270560000112
效率为52.61%。It can be seen from Table 1 that when the cogeneration system operates under a typical daily stable working condition in Lhasa, considering the heat input from solar energy, its energy efficiency reaches 61.9%.
Figure BDA0003726270560000112
The efficiency is 52.61%.

本实用新型公开的一种集成燃料电池与太阳能的联合循环冷热电联供系统,针对传统热电联产系统热力学优势不足的现状,提出在系统中耦合高温固体氧化物燃料电池的方式,由于燃料电池排气温度与燃气轮机排气温度相当,因此将二者进行混合后通向余热锅炉中可以保证能量的梯级利用,不仅有效利用了固体氧化物燃料电池的高温废热,还减少了系统中的能量损失。所述联供系统结构合理耦合槽式太阳能集热器,利用太阳能集热器替代余热锅炉的部分热负荷,提高了余热锅炉的烟气利用率,增大了蒸汽循环子系统的发电量,进一步提高了系统的做功能力。因此与传统的集成方式相比,本实用新型提供的联供系统具有显著的热力学优势。The utility model discloses a combined cycle combined cooling, heating and power supply system integrating fuel cells and solar energy. Aiming at the current situation of insufficient thermodynamic advantages of traditional cogeneration systems, a method of coupling high-temperature solid oxide fuel cells in the system is proposed. The exhaust temperature of the battery is equivalent to the exhaust temperature of the gas turbine, so mixing the two and leading to the waste heat boiler can ensure the cascade utilization of energy, which not only effectively utilizes the high-temperature waste heat of the solid oxide fuel cell, but also reduces the energy in the system loss. The structure of the cogeneration system is rationally coupled with the trough solar collector, and the solar collector is used to replace part of the heat load of the waste heat boiler, which improves the flue gas utilization rate of the waste heat boiler, increases the power generation of the steam cycle subsystem, and further Improve the working ability of the system. Therefore, compared with the traditional integration method, the joint supply system provided by the utility model has significant thermodynamic advantages.

本说明书中各个实施例采用递进的方式描述,每个实施例重点说明的都是与其他实施例的不同之处,各个实施例之间相同相似部分互相参见即可。Each embodiment in this specification is described in a progressive manner, each embodiment focuses on the difference from other embodiments, and the same and similar parts of each embodiment can be referred to each other.

本文中应用了具体个例对本实用新型的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本实用新型的控制方法及其核心思想;同时,对于本领域的一般技术人员,依据本实用新型的思想,在具体实施方式及应用范围上均会有改变之处。综上所述,本说明书内容不应理解为对本实用新型的限制。In this paper, specific examples are used to illustrate the principle and implementation of the present utility model. The description of the above embodiments is only used to help understand the control method of the present utility model and its core idea; at the same time, for those of ordinary skill in the art, According to the idea of the utility model, there will be changes in the specific implementation and application range. To sum up, the contents of this specification should not be understood as limiting the utility model.

Claims (8)

1. A combined cycle combined cooling, heating and power system integrating a fuel cell and solar energy, comprising: the system comprises a solid oxide fuel cell subsystem, a solar thermal complementary fuel gas and steam combined cycle subsystem and a double-effect absorption type lithium bromide refrigeration subsystem; the solar heat complementation gas and steam combined cycle subsystem comprises a gas turbine subsystem and a steam cycle subsystem; the gas turbine subsystem is respectively connected with the solid oxide fuel cell subsystem and the steam circulation subsystem; the steam circulation subsystem is also connected with the double-effect absorption lithium bromide refrigeration subsystem;
the solid oxide fuel cell subsystem comprises: a gas mixer (101), a gas heat exchanger (102), a fuel cell anode (103), a gas separator (104), an air heat exchanger (105), a fuel cell cathode (106), a direct current-alternating current converter (107) and a fuel cell afterburner (108); the outlet of the gas mixer (101) is connected with the first path of inlet of the gas heat exchanger (102); the first outlet of the gas heat exchanger (102) is connected with the inlet of the fuel cell anode (103); the outlet of the fuel cell anode (103) is connected to the inlet of the gas separator (104); a first outlet of the gas separator (104) is connected with a first inlet of the gas mixer (101), and a second outlet of the gas separator (104) is connected with a first inlet of the fuel cell afterburner (108); the first outlet of the air heat exchanger (105) is connected with the inlet of the fuel cell cathode (106); the outlet of the fuel cell cathode (106) is connected with the second inlet of the fuel cell afterburner (108); the outlet of the fuel cell is electrically output through the DC/AC converter (107); the outlet of the fuel cell afterburner (108) is connected with the second inlet of the gas heat exchanger (102); the second outlet of the gas heat exchanger (102) is connected with the first inlet of the air heat exchanger (105); the second outlet of the air heat exchanger (105) is connected with the gas turbine subsystem.
2. A combined cycle combined heat and power system integrating a fuel cell and solar energy according to claim 1, wherein the fuel cell is a solid oxide fuel cell.
3. The combined cycle combined cooling, heating and power system according to claim 1, wherein the second inlet of the gas mixer (101) is fed with methane; carbon dioxide is introduced into a third inlet of the gas mixer (101); and a second path of inlet of the air heat exchanger (105) is introduced with air.
4. The integrated fuel cell and solar combined cycle combined heat and power system of claim 1, wherein the gas turbine subsystem comprises: a compressor (201), a combustion chamber (202), a gas turbine (203), a first generator (204) and a flue gas mixer (205);
the compressor (201) is connected with the gas turbine (203) through the combustion chamber (202); the compressor (201), the gas turbine (203) and the first generator (204) are coaxially connected, and electric output is carried out through the first generator (204); the second outlet of the air heat exchanger (105) is connected with the first inlet of the flue gas mixer (205); the outlet of the gas turbine (203) is connected with the second path inlet of the flue gas mixer (205).
5. The combined cycle combined cooling, heating and power system integrating a fuel cell and solar energy as claimed in claim 4, wherein an inlet of the compressor (201) is filled with air; methane is introduced into the inlet of the combustion chamber (202).
6. The integrated fuel cell and solar combined cycle combined heat and power system of claim 4, wherein the steam cycle subsystem comprises: the system comprises a waste heat boiler, a high-pressure turbine cylinder (306), a medium-pressure turbine cylinder (307), a low-pressure turbine cylinder (308), a second generator (309), a water feed heat exchanger (310), a condenser (311), a low-pressure water feed pump (312), a medium-pressure water feed pump (313), a high-pressure water feed pump (314), a first solar heat collector (316), a first water feed mixer (317), a second solar heat collector (318) and a second water feed mixer (319); the waste heat boiler comprises a first heat exchanger group (301), a first-stage high-pressure economizer (302), a second heat exchanger group (303), a second-stage high-pressure economizer (304) and a third heat exchanger group (305); the first heat exchanger group (301) consists of a low-pressure economizer and a low-pressure evaporator; the second heat exchanger group (303) consists of a medium-pressure economizer, a medium-pressure evaporator and a low-pressure superheater; the third heat exchanger group (305) consists of a medium-pressure superheater, a high-pressure evaporator, a reheater and a high-pressure superheater;
the outlet of the flue gas mixer (205) is connected with the inlet of the waste heat boiler; the outlet of the high-pressure superheater of the third heat exchanger group (305) is connected with the first path of inlet of the high-pressure turbine cylinder (306); the outlet of the high-pressure turbine cylinder (306) is connected with the inlet of a reheater of the third heat exchanger group (305); the outlet of a reheater of the third heat exchanger group (305) is connected with the inlet of the turbine intermediate pressure cylinder (307); a first path of outlet of the turbine intermediate pressure cylinder (307) is connected with an inlet of the turbine low pressure cylinder (308), and a second path of outlet of the turbine intermediate pressure cylinder (307) is connected with a first path of inlet of the feedwater heat exchanger (310); the second path of inlet of the feed water heat exchanger (310) is connected with normal temperature water; the first path of outlet of the feedwater heat exchanger (310) is connected with the inlet of the low-pressure feedwater pump (312); the second outlet of the feedwater heat exchanger (310) is used for heat output; the turbine high-pressure cylinder (306), the turbine intermediate-pressure cylinder (307), the turbine low-pressure cylinder (308) and the second generator (309) are coaxially connected, and electric output is performed through the second generator (309); the outlet of the turbine low-pressure cylinder (308) is connected with the inlet of the condenser (311); the outlet of the condenser (311) is connected with the inlet of the low-pressure feed water pump (312); the outlet of the low-pressure water feeding pump (312) is connected with the inlet of a low-pressure economizer of the first heat exchanger group (301);
the outlet of the low-pressure superheater of the second heat exchanger group (303) is connected with the inlet of the steam turbine low-pressure cylinder (308); a first path of the outlets of the low-pressure coal economizer of the first heat exchanger group (301) is connected with the inlet of the high-pressure water feeding pump (314); a first path of outlet of the high-pressure feed water pump (314) is connected with a first path of inlet of the first-stage high-pressure economizer (302); a second path in the outlet of the low-pressure economizer of the first heat exchanger group (301) is connected with the inlet of the medium-pressure economizer of the second heat exchanger group (303) through the medium-pressure feed water pump (313);
the second outlet of the high-pressure feed water pump (314) is connected with the inlet of the first solar heat collector (316); the outlet of the first solar heat collector (316) is connected with the first path inlet of the first water feeding mixer (317); a second outlet of the first-stage high-pressure economizer (302) is connected with a second inlet of the first water supply mixer (317); the first outlet of the first water feed mixer (317) is connected with the inlet of the second solar heat collector (318); the outlet of the second solar heat collector (318) is connected with the first path of inlet of the second water feed mixer (319); a second outlet of the first water feed mixer (317) is connected with a second inlet of the second-stage high-pressure economizer (304); a second outlet of the second-stage high-pressure economizer (304) is connected with a second inlet of the second water supply mixer (319); the outlet of the second feed water mixer (319) is connected with the inlet of the high-pressure evaporator of the third heat exchanger group (305).
7. The combined cycle combined cooling heating and power system according to claim 6, wherein the first solar collector (316) and the second solar collector (318) are each trough solar collectors.
8. The integrated fuel cell and solar combined cycle combined heat and power system of claim 6, wherein the dual-effect absorption lithium bromide refrigeration subsystem comprises: a double-effect absorption lithium bromide refrigerator (315);
a first path in the outlet of the low-pressure evaporator of the first heat exchanger group (301) is connected with a first path inlet of the double-effect absorption lithium bromide refrigerator (315); a first path of outlet of the double-effect absorption lithium bromide refrigerator (315) is connected with a second path of inlet of the low-pressure economizer of the first heat exchanger group (301); a second path of inlet of the double-effect absorption lithium bromide refrigerator (315) is connected with chilled water inlet water; and the second outlet of the double-effect absorption lithium bromide refrigerator (315) is used for cold output.
CN202221686875.8U 2022-07-01 2022-07-01 Combined cycle combined cooling heating and power system integrating fuel cell and solar energy Active CN217903155U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115000454A (en) * 2022-07-01 2022-09-02 华北电力大学 Combined cycle combined cooling heating and power system integrating fuel cell and solar energy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115000454A (en) * 2022-07-01 2022-09-02 华北电力大学 Combined cycle combined cooling heating and power system integrating fuel cell and solar energy
CN115000454B (en) * 2022-07-01 2025-09-02 华北电力大学 A combined cycle cooling, heating and power system integrating fuel cells and solar energy

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