CN217763601U - A system of desulfurization slurry flash evaporation and solar energy complementary heating - Google Patents

A system of desulfurization slurry flash evaporation and solar energy complementary heating Download PDF

Info

Publication number
CN217763601U
CN217763601U CN202221998392.1U CN202221998392U CN217763601U CN 217763601 U CN217763601 U CN 217763601U CN 202221998392 U CN202221998392 U CN 202221998392U CN 217763601 U CN217763601 U CN 217763601U
Authority
CN
China
Prior art keywords
desulfurization
slurry
heat pump
absorption heat
solar energy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202221998392.1U
Other languages
Chinese (zh)
Inventor
徐世明
彭烁
商忠宝
周贤
马英禹
安航
刘家男
姚国鹏
黄永琪
白烨
蔡浩飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huaneng Clean Energy Research Institute
Huaneng Yingkou Thermal Power Co Ltd
Original Assignee
Huaneng Clean Energy Research Institute
Huaneng Yingkou Thermal Power Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huaneng Clean Energy Research Institute, Huaneng Yingkou Thermal Power Co Ltd filed Critical Huaneng Clean Energy Research Institute
Application granted granted Critical
Publication of CN217763601U publication Critical patent/CN217763601U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

The utility model provides a system for heating by complementary flash evaporation and solar energy of desulfurized slurry, including desulfurization unit, absorption heat pump and solar collector, wherein, the flash evaporation steam outlet that sets up on the desulfurization unit connects the low temperature heat source entry that sets up on the absorption heat pump; a working medium outlet arranged on the solar heat collector is connected with a high-temperature heat source inlet arranged on the absorption heat pump; a water inlet arranged on the absorption heat pump is connected with a heat supply network water return pipeline; a water outlet arranged on the absorption heat pump is connected with a water supply pipeline of a heat supply network; the utility model discloses can improve unit generated energy and energy utilization efficiency.

Description

一种脱硫浆液闪蒸与太阳能互补供热的系统A system of desulfurization slurry flash evaporation and solar energy complementary heating

技术领域technical field

本实用新型属于煤电领域,具体涉及一种脱硫浆液闪蒸与太阳能互补供热的系统。The utility model belongs to the field of coal power, and in particular relates to a system for complementary heating of desulfurization slurry flash evaporation and solar energy.

背景技术Background technique

燃煤电厂烟气排放是国内大气污染物的主要来源之一,湿法脱硫塔被国内燃煤电厂广泛采用。湿法脱硫装置处理过的烟气温度在45~55℃,烟气中含有大量的水蒸气,且处于饱和状态,携带大量汽化潜热。Flue gas emissions from coal-fired power plants are one of the main sources of air pollutants in China, and wet desulfurization towers are widely used in domestic coal-fired power plants. The temperature of the flue gas treated by the wet desulfurization device is 45-55°C, and the flue gas contains a large amount of water vapor, which is in a saturated state and carries a large amount of latent heat of vaporization.

脱硫浆液闪蒸提热技术是一项新型的烟气余热回收技术。该技术利用湿法烟气脱硫工艺中浆液的沸点会随着环境压力降低而降低的特性,建立一个真空相变环境,使当前负压饱和温度以上的脱硫浆液发生闪蒸,产生负压蒸汽携带汽化潜热输送至吸收式热泵内向低温介质进行冷凝放热,从而实现脱硫浆液余热的清洁、高效、低成本回收。该技术可实现节能、节水、提高脱硫效率、消除烟羽视觉污染的多重目的,可同时兼顾节能与减排。Desulfurization slurry flash heat extraction technology is a new flue gas waste heat recovery technology. This technology utilizes the characteristic that the boiling point of the slurry in the wet flue gas desulfurization process will decrease with the decrease of the ambient pressure, and establishes a vacuum phase change environment, so that the desulfurization slurry above the current negative pressure saturation temperature will flash and generate negative pressure steam. The latent heat of vaporization is transported to the absorption heat pump to condense and release heat to the low-temperature medium, so as to realize the clean, efficient and low-cost recovery of the waste heat of the desulfurization slurry. This technology can realize the multiple purposes of energy saving, water saving, improving desulfurization efficiency, and eliminating visual pollution of smoke plume, and it can take energy saving and emission reduction into consideration at the same time.

而当前的脱硫浆液闪蒸技术需要引入一股汽轮机抽汽作为吸收式热泵的高温热源,该技术导致汽轮机的发电量受到影响。However, the current desulfurization slurry flash technology needs to introduce a steam turbine extraction steam as the high-temperature heat source of the absorption heat pump, which affects the power generation of the steam turbine.

发明内容Contents of the invention

本实用新型的目的在于提供一种脱硫浆液闪蒸与太阳能互补供热的系统,解决了现有技术中存在的上述不足。The purpose of the utility model is to provide a desulfurization slurry flash evaporation and solar energy complementary heat supply system, which solves the above-mentioned shortcomings existing in the prior art.

为了达到上述目的,本实用新型采用的技术方案是:In order to achieve the above object, the technical scheme that the utility model adopts is:

本实用新型提供的一种脱硫浆液闪蒸与太阳能互补供热的系统,包括脱硫单元、吸收式热泵和太阳能集热器,其中,所述脱硫单元上设置的闪蒸蒸汽出口连接吸收式热泵上设置的低温热源入口;所述太阳能集热器上设置的工质出口连接吸收式热泵上设置的高温热源入口;所述吸收式热泵上设置的进水口连接热网回水管道;所述吸收式热泵上设置的出水口连接热网供水管道。The utility model provides a system for complementary heating of desulfurization slurry flash evaporation and solar energy, which includes a desulfurization unit, an absorption heat pump and a solar collector, wherein the flash steam outlet set on the desulfurization unit is connected to the absorption heat pump The low-temperature heat source inlet is set; the working fluid outlet set on the solar collector is connected to the high-temperature heat source inlet set on the absorption heat pump; the water inlet set on the absorption heat pump is connected to the heat network return pipe; the absorption heat pump The water outlet provided on the heat pump is connected to the water supply pipeline of the heating network.

优选地,所述脱硫单元包括脱硫塔和闪蒸罐,其中,所述脱硫塔上设置有烟气入口和浆液出口,所述浆液出口连接闪蒸罐上设置的浆液入口,所述闪蒸罐上设置的闪蒸蒸汽出口连接吸收式热泵上设置的低温热源入口。Preferably, the desulfurization unit includes a desulfurization tower and a flash tank, wherein the desulfurization tower is provided with a flue gas inlet and a slurry outlet, and the slurry outlet is connected to a slurry inlet provided on the flash tank, and the flash tank The flash steam outlet set on the upper part is connected to the low-temperature heat source inlet set on the absorption heat pump.

优选地,所述闪蒸罐上设置的浆液出口连接脱硫塔。Preferably, the slurry outlet provided on the flash tank is connected to a desulfurization tower.

优选地,所述脱硫塔上的浆液出口连接闪蒸罐上的浆液入口之间设置有浆液泵。Preferably, a slurry pump is arranged between the slurry outlet on the desulfurization tower and the slurry inlet on the flash tank.

优选地,所述吸收式热泵上设置的冷凝水出口连接有凝汽器。Preferably, the condensed water outlet provided on the absorption heat pump is connected with a condenser.

优选地,所述凝汽器上设置的进汽口连接有汽轮机上设置的排汽口。Preferably, the steam inlet provided on the condenser is connected to the steam exhaust port provided on the steam turbine.

优选地,所述凝汽器上设置有冷凝水出口。Preferably, the condenser is provided with a condensed water outlet.

与现有技术相比,本实用新型的有益效果是:Compared with the prior art, the beneficial effects of the utility model are:

本实用新型提供的一种脱硫浆液闪蒸与太阳能互补供热的系统,利用脱硫单元回收中低温烟气中的余热,提高能量利用效率;利用太阳能作为吸收式热泵的高温热源,替代汽轮机抽汽,与脱硫单元输出的余热共同驱动吸收式热泵用以加热热网水,提高机组发电量和能量利用效率。The utility model provides a desulfurization slurry flash evaporation and solar energy complementary heat supply system, which uses the desulfurization unit to recover the waste heat in the low-temperature flue gas and improves energy utilization efficiency; uses solar energy as the high-temperature heat source of the absorption heat pump to replace steam turbine extraction , and the waste heat output by the desulfurization unit jointly drive the absorption heat pump to heat the water in the heating network, improving the power generation and energy utilization efficiency of the unit.

附图说明Description of drawings

图1是本实用新型的系统结构示意图。Fig. 1 is a schematic diagram of the system structure of the utility model.

具体实施方式Detailed ways

下面结合附图,对本实用新型进一步详细说明。Below in conjunction with accompanying drawing, the utility model is described in further detail.

本实用新型提供一种脱硫浆液闪蒸与太阳能互补供热的系统,包括脱硫单元、吸收式热泵3和太阳能集热器7,其中,所述脱硫单元上设置的闪蒸蒸汽出口连接吸收式热泵3上设置的低温热源入口;所述太阳能集热器7上设置的工质出口连接吸收式热泵3上设置的高温热源入口;所述吸收式热泵3上设置的进水口连接热网回水管道;所述吸收式热泵3上设置的出水口连接热网供水管道。The utility model provides a complementary heating system for desulfurization slurry flash evaporation and solar energy, which includes a desulfurization unit, an absorption heat pump 3 and a solar heat collector 7, wherein the flash steam outlet provided on the desulfurization unit is connected to the absorption heat pump The low-temperature heat source inlet provided on 3; the working medium outlet provided on the solar collector 7 is connected to the high-temperature heat source inlet provided on the absorption heat pump 3; the water inlet provided on the absorption heat pump 3 is connected to the heat network return pipe ; The water outlet provided on the absorption heat pump 3 is connected to the water supply pipeline of the heating network.

所述脱硫单元包括脱硫塔5和闪蒸罐4,其中,所述脱硫塔5上设置有烟气入口和浆液出口,所述浆液出口连接闪蒸罐4上设置的浆液入口,所述闪蒸罐4上设置的闪蒸蒸汽出口连接吸收式热泵3上设置的低温热源入口。The desulfurization unit includes a desulfurization tower 5 and a flash tank 4, wherein the desulfurization tower 5 is provided with a flue gas inlet and a slurry outlet, and the slurry outlet is connected to the slurry inlet provided on the flash tank 4, and the flash tank The flash steam outlet provided on the tank 4 is connected to the low-temperature heat source inlet provided on the absorption heat pump 3 .

本实用新型提供的一种脱硫浆液闪蒸与太阳能互补供热的方法,包括以下步骤:The utility model provides a method for complementary heating of desulfurization slurry flash evaporation and solar energy, comprising the following steps:

烟气在脱硫单元进行脱硫、闪蒸,生成的闪蒸蒸汽进入吸收式热泵3中作为低温热源;The flue gas is desulfurized and flashed in the desulfurization unit, and the generated flash steam enters the absorption heat pump 3 as a low-temperature heat source;

太阳能集热器7中被太阳能加热的传热工质进入吸收式热泵3作为高温热源;The heat transfer working medium heated by solar energy in the solar heat collector 7 enters the absorption heat pump 3 as a high-temperature heat source;

通过低温热源和高温热源共同驱动吸收式热泵3加热热网回水后对外供热。The absorption heat pump 3 is jointly driven by the low-temperature heat source and the high-temperature heat source to heat the return water of the heat network and supply heat to the outside.

如图1所示,本实用新型提供一种脱硫浆液闪蒸与太阳能互补供热的系统,包括汽轮机1、凝汽器2、吸收式热泵3、闪蒸罐4、脱硫塔5、浆液泵6和太阳能集热器7,其中:As shown in Figure 1, the utility model provides a desulfurization slurry flash evaporation and solar energy complementary heating system, including a steam turbine 1, a condenser 2, an absorption heat pump 3, a flash tank 4, a desulfurization tower 5, and a slurry pump 6 and solar thermal collector 7, wherein:

所述脱硫塔5上设置的烟气入口与引风机的出口连接;所述脱硫塔5的脱硫浆液出口经过浆液泵6连接闪蒸罐4的浆液入口。The flue gas inlet provided on the desulfurization tower 5 is connected to the outlet of the induced draft fan; the desulfurization slurry outlet of the desulfurization tower 5 is connected to the slurry inlet of the flash tank 4 through the slurry pump 6 .

所述闪蒸罐4上设置的冷浆液出口连接脱硫塔5上开设的冷浆液入口。The cold slurry outlet provided on the flash tank 4 is connected to the cold slurry inlet provided on the desulfurization tower 5 .

所述闪蒸罐4上设置的蒸汽出口连接吸收式热泵3上设置的蒸汽入口;所述吸收式热泵3上设置的冷凝水出口连接凝汽器2的补水口。The steam outlet provided on the flash tank 4 is connected to the steam inlet provided on the absorption heat pump 3 ; the condensed water outlet provided on the absorption heat pump 3 is connected to the water supply port of the condenser 2 .

所述吸收式热泵3上设置的进水口连接热网回水管道;所述吸收式热泵3上设置的出水口连接热网水管道。The water inlet provided on the absorption heat pump 3 is connected to the return water pipe of the heat network; the water outlet provided on the absorption heat pump 3 is connected to the water pipe of the heat network.

所述太阳能集热器7上的传热工质出口连接吸收式热泵3上设置的高温热源入口。The heat transfer working medium outlet on the solar heat collector 7 is connected to the high temperature heat source inlet provided on the absorption heat pump 3 .

所述吸收式热泵3上设置的传热工质出口连接太阳能集热器7上的传热工质入口。The heat transfer working medium outlet provided on the absorption heat pump 3 is connected to the heat transfer working medium inlet on the solar heat collector 7 .

所述汽轮机1上设置的排汽口连接凝汽器2上设置的进汽口。The steam outlet provided on the steam turbine 1 is connected to the steam inlet provided on the condenser 2 .

所述汽轮机1上设置有过热蒸汽入口。The steam turbine 1 is provided with a superheated steam inlet.

本实用新型的工作过程是:The working process of the present utility model is:

从引风机来的烟气在脱硫塔5内与顶部喷淋下来的脱硫浆液发生脱硫反应,同时降温增湿。The flue gas from the induced draft fan undergoes a desulfurization reaction with the desulfurization slurry sprayed from the top in the desulfurization tower 5, and the temperature is lowered and the humidity is increased at the same time.

脱硫塔5底部出口的脱硫浆液经过浆液泵6送入闪蒸罐4,闪蒸罐4内的脱硫浆液经过蒸发冷却过程,闪蒸出蒸汽,同时降温成为冷浆液送入脱硫塔5,从顶部喷淋至塔内。The desulfurization slurry at the bottom outlet of the desulfurization tower 5 is sent to the flash tank 4 through the slurry pump 6, and the desulfurization slurry in the flash tank 4 undergoes an evaporative cooling process, flashes out steam, and at the same time cools down to become a cold slurry and sends it to the desulfurization tower 5. Spray into the tower.

过热蒸汽进入汽轮机1后,推动汽轮机1的转子转动做功,做功后的蒸汽从汽轮机1的排汽口排出,进入凝汽器中,并在凝汽器2内被冷却水冷却,凝结成水。After the superheated steam enters the steam turbine 1, it pushes the rotor of the steam turbine 1 to rotate and do work. The steam after work is discharged from the exhaust port of the steam turbine 1, enters the condenser, and is cooled by the cooling water in the condenser 2 to condense into water.

太阳能集热器7中被太阳能加热的传热工质进入吸收式热泵3作为高温热源,闪蒸蒸汽作为吸收式热泵3的低温热源,两者共同驱动吸收式热泵3加热热网水对外供热。The heat transfer medium heated by solar energy in the solar collector 7 enters the absorption heat pump 3 as a high-temperature heat source, and the flash steam serves as a low-temperature heat source for the absorption heat pump 3, and the two jointly drive the absorption heat pump 3 to heat the water in the heat network to supply heat to the outside .

本实用新型的有益效果是:The beneficial effects of the utility model are:

1、利用脱硫浆液闪蒸技术回收中低温烟气余热,提高能量利用效率。1. Use the desulfurization slurry flash technology to recover the waste heat of the medium and low temperature flue gas, and improve the energy utilization efficiency.

2、利用太阳能作为吸收式热泵的高温热源,替代汽轮机抽汽,与闪蒸蒸汽共同驱动吸收式热泵加热热网水,提高机组发电量和能量利用效率。2. Use solar energy as the high-temperature heat source of the absorption heat pump to replace the steam extraction of the steam turbine, and drive the absorption heat pump together with the flash steam to heat the water in the heating network, so as to improve the power generation and energy utilization efficiency of the unit.

Claims (7)

1.一种脱硫浆液闪蒸与太阳能互补供热的系统,其特征在于,包括脱硫单元、吸收式热泵(3)和太阳能集热器(7),其中,所述脱硫单元上设置的闪蒸蒸汽出口连接吸收式热泵(3)上设置的低温热源入口;所述太阳能集热器(7)上设置的工质出口连接吸收式热泵(3)上设置的高温热源入口;所述吸收式热泵(3)上设置的进水口连接热网回水管道;所述吸收式热泵(3)上设置的出水口连接热网供水管道。1. A system for desulfurization slurry flash evaporation and solar energy complementary heating, characterized in that it comprises a desulfurization unit, an absorption heat pump (3) and a solar heat collector (7), wherein the flash evaporation provided on the desulfurization unit The steam outlet is connected to the low-temperature heat source inlet provided on the absorption heat pump (3); the working fluid outlet provided on the solar collector (7) is connected to the high-temperature heat source inlet provided on the absorption heat pump (3); the absorption heat pump The water inlet provided on (3) is connected to the return water pipe of the heat network; the water outlet provided on the absorption heat pump (3) is connected to the water supply pipe of the heat network. 2.根据权利要求1所述的一种脱硫浆液闪蒸与太阳能互补供热的系统,其特征在于,所述脱硫单元包括脱硫塔(5)和闪蒸罐(4),其中,所述脱硫塔(5)上设置有烟气入口和浆液出口,所述浆液出口连接闪蒸罐(4)上设置的浆液入口,所述闪蒸罐(4)上设置的闪蒸蒸汽出口连接吸收式热泵(3)上设置的低温热源入口。2. A system of desulfurization slurry flash evaporation and solar energy complementary heating system according to claim 1, characterized in that, the desulfurization unit comprises a desulfurization tower (5) and a flash tank (4), wherein the desulfurization The tower (5) is provided with a flue gas inlet and a slurry outlet, the slurry outlet is connected to the slurry inlet provided on the flash tank (4), and the flash steam outlet provided on the flash tank (4) is connected to an absorption heat pump (3) The low-temperature heat source inlet provided above. 3.根据权利要求2所述的一种脱硫浆液闪蒸与太阳能互补供热的系统,其特征在于,所述闪蒸罐(4)上设置的浆液出口连接脱硫塔(5)。3 . The system of desulfurization slurry flash evaporation and solar energy complementary heat supply according to claim 2 , characterized in that the slurry outlet provided on the flash tank ( 4 ) is connected to the desulfurization tower ( 5 ). 4.根据权利要求2所述的一种脱硫浆液闪蒸与太阳能互补供热的系统,其特征在于,所述脱硫塔(5)上的浆液出口连接闪蒸罐(4)上的浆液入口之间设置有浆液泵(6)。4. A system for desulfurization slurry flash evaporation and solar energy complementary heating according to claim 2, characterized in that the slurry outlet on the desulfurization tower (5) is connected to the slurry inlet on the flash tank (4) A slurry pump (6) is arranged between them. 5.根据权利要求1所述的一种脱硫浆液闪蒸与太阳能互补供热的系统,其特征在于,所述吸收式热泵(3)上设置的冷凝水出口连接有凝汽器。5. The system of desulfurization slurry flash evaporation and solar energy complementary heat supply according to claim 1, characterized in that the condensed water outlet provided on the absorption heat pump (3) is connected to a condenser. 6.根据权利要求5所述的一种脱硫浆液闪蒸与太阳能互补供热的系统,其特征在于,所述凝汽器(2)上设置的进汽口连接有汽轮机(1)上设置的排汽口。6. A system for desulfurization slurry flash evaporation and solar energy complementary heat supply according to claim 5, characterized in that the steam inlet provided on the condenser (2) is connected to the steam turbine (1) provided exhaust port. 7.根据权利要求5所述的一种脱硫浆液闪蒸与太阳能互补供热的系统,其特征在于,所述凝汽器(2)上设置有冷凝水出口。7. The system of desulfurization slurry flash evaporation and solar energy complementary heat supply according to claim 5, characterized in that, the condenser (2) is provided with a condensed water outlet.
CN202221998392.1U 2022-05-31 2022-07-29 A system of desulfurization slurry flash evaporation and solar energy complementary heating Active CN217763601U (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202221350221 2022-05-31
CN2022213502218 2022-05-31

Publications (1)

Publication Number Publication Date
CN217763601U true CN217763601U (en) 2022-11-08

Family

ID=83878115

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202221998392.1U Active CN217763601U (en) 2022-05-31 2022-07-29 A system of desulfurization slurry flash evaporation and solar energy complementary heating

Country Status (1)

Country Link
CN (1) CN217763601U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115183306A (en) * 2022-05-31 2022-10-14 华能营口热电有限责任公司 System and method for supplying heat by virtue of desulfurization slurry flash evaporation and solar energy complementation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115183306A (en) * 2022-05-31 2022-10-14 华能营口热电有限责任公司 System and method for supplying heat by virtue of desulfurization slurry flash evaporation and solar energy complementation

Similar Documents

Publication Publication Date Title
CN105909330B (en) A kind of flue gas waste heat recovery and smoke processing system based on Organic Rankine Cycle
CN111396913A (en) A system and method for recovering waste heat and moisture from flue gas of coal-fired units
CN104534539A (en) Gas steam combined cycle central heating device and heating method
CN201443978U (en) Carbon calciner waste heat power generation system
CN103372371A (en) System device for carbon capture through solar organic Rankine cycle auxiliary coal-fired power generation
CN103372365A (en) Cement kiln waste heat power generation auxiliary carbon dioxide capture system device
CN110864324A (en) System and method for improving boiler efficiency by using low-temperature waste heat of flue gas
CN111594813A (en) Combined-cycle efficient clean power generation device and method utilizing low-temperature latent heat of flue gas
CN203717051U (en) Combined cycling low-temperature exhaust heat recycling device
CN110425569A (en) Combined cycle thermoelectric system and method adopting deep utilization of flue gas waste heat and flue gas recirculation
CN212057351U (en) A recovery system for waste heat and moisture in flue gas of coal-fired units
CN217763601U (en) A system of desulfurization slurry flash evaporation and solar energy complementary heating
CN115143438A (en) A system and method for generating electricity by recovering flue gas waste heat by flashing of desulfurization slurry
CN211119603U (en) A system for indirect heating of flue gas with low temperature waste heat and water supply for heating network
CN109210969A (en) A kind of residual heat of electric power plant and clean energy resource utilization system
CN211737297U (en) IGCC power generation system for humidifying fuel gas by using low-temperature waste heat of flue gas
CN201723313U (en) Gas turbine combined cycling device for distributed air and fuel humidification
CN218371826U (en) Geothermal energy drive desulfurization thick liquid flash distillation heating system
CN209116822U (en) A kind of residual heat of electric power plant and clean energy resource utilization system
CN219318398U (en) A deep utilization system of waste heat at cold end of power plant based on high back pressure exhaust of steam turbine
CN211146548U (en) A system for improving boiler efficiency by utilizing low temperature waste heat of flue gas
CN204730508U (en) A kind ofly apply the energy-conservation device of lithium bromide
CN212226984U (en) A combined cycle high-efficiency clean power generation device utilizing low-temperature latent heat of flue gas
CN215411804U (en) Process system for deep upgrading and utilizing flue gas waste heat
CN213392298U (en) Supercritical CO2 power generation system integrating lignite vacuum pre-drying

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant