CN217490332U - A low partial pressure and low energy consumption flue gas CO2 capture system - Google Patents

A low partial pressure and low energy consumption flue gas CO2 capture system Download PDF

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CN217490332U
CN217490332U CN202220085408.3U CN202220085408U CN217490332U CN 217490332 U CN217490332 U CN 217490332U CN 202220085408 U CN202220085408 U CN 202220085408U CN 217490332 U CN217490332 U CN 217490332U
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absorption tower
output end
reboiler
energy consumption
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郑勇
吴瑞
陈天明
吕文彬
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Anhui Fangxin Lihua Environmental Protection Technology Co ltd
Tongxing Environmental Protection Technology Co ltd
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Anhui Fangxin Lihua Environmental Protection Technology Co ltd
Tongxing Environmental Protection Technology Co ltd
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Abstract

The utility model provides a low partial pressure low energy consumption flue gas CO2 entrapment system relates to CO 2 Field of capture technology, the CO 2 Trapping systemComprises an absorption tower and a liquid-rich pump, wherein the absorption tower is internally provided with a device for absorbing CO in the raw material gas 2 The bottom of the absorption tower is communicated with a regeneration tower, material conveying resistance between the absorption tower and the regeneration tower is overcome by a pregnant solution pump, the outlet end of the top of the regeneration tower is connected with a steam compressor, the output end of the steam compressor is connected with a reboiler II, the steam compressor pressurizes acid gas generated by the regeneration tower and then is used for heating the reboiler II, and the output end of the reboiler II is connected with a separation device; the acid gas that produces to the regenerator through vapor compressor pressurizes, makes its pressure and temperature rise, and the steam that has increased the enthalpy is sent the heating chamber of reboiler II to and is used as heating steam, compares prior art and converts steam into the electric energy, will convert the operation that the electric energy was used for entire system again, and this scheme steam heat energy interest rate is higher, makes the relative traditional handicraft of regeneration energy consumption lower.

Description

一种低分压低能耗烟气CO2捕集系统A low partial pressure and low energy consumption flue gas CO2 capture system

技术领域technical field

本实用新型涉及CO2捕集技术领域,尤其涉及一种低分压低能耗烟气 CO2捕集系统。The utility model relates to the technical field of CO2 capture, in particular to a low partial pressure and low energy consumption flue gas CO2 capture system.

背景技术Background technique

碳达峰、碳中和是国家的重大战略,CO2捕集技术是实现碳中和的重要环节,是CCUS(二氧化碳的捕集、利用、储存)的前提,对减少CO2的排放具有至关重要的作用。Carbon peaking and carbon neutralization are major national strategies. CO 2 capture technology is an important link to achieve carbon neutrality. important role.

以MDEA、MEA、AMP为代表的有机胺系列吸收剂被广泛用于烟道气二氧化碳捕集工艺流程中,相关公开专利有:美国专利公开号US4336233A、中国专利申请号为CN92113637.4公开的从混合气体中脱除二氧化碳的方法;而再生能耗偏高一直行业内的痛点,约占总运行成本的三分之二以上。The organic amine series absorbents represented by MDEA, MEA and AMP are widely used in the flue gas carbon dioxide capture process. The method of removing carbon dioxide from the mixed gas; and the high energy consumption of regeneration has always been a pain point in the industry, accounting for more than two-thirds of the total operating cost.

专利CN103566712B提出了一种二氧化碳捕集工艺,利用高温烟气余热副产蒸汽用于装置的再沸器加热;采用加热膨胀驱动透平机发电的方式利用再生塔顶气余热,所发电可满足整个净化系统的动设备供电。使得整个装置和传统工艺相比,再沸器能耗降低15-25%。高温烟气余热副产蒸汽只是利用了外部的能量,没有从根本上降低再生能耗。利用再生塔顶气余热加热膨胀驱动透平机发电的这种方式,能量转化效率比较低。Patent CN103566712B proposes a carbon dioxide capture process, which utilizes high-temperature flue gas waste heat by-produced steam for the reboiler heating of the device; uses the waste heat of the regeneration tower top gas by means of heating and expanding to drive the turbine to generate electricity, and the generated electricity can meet the needs of the whole system. Power supply to the active equipment of the purification system. Compared with the traditional process, the energy consumption of the reboiler is reduced by 15-25%. High-temperature flue gas waste heat by-product steam only utilizes external energy, and does not fundamentally reduce regeneration energy consumption. The energy conversion efficiency is relatively low by using the residual heat of the regeneration tower top gas to heat and expand the turbine to drive the power generation.

在国家大力提倡降低能耗的前提下,如何有效地降低再生能耗、降低二氧化碳捕集成本,成为二氧化碳捕集技术的关键问题。Under the premise that the state strongly advocates reducing energy consumption, how to effectively reduce renewable energy consumption and reduce the cost of carbon dioxide capture has become a key issue in carbon dioxide capture technology.

实用新型内容Utility model content

本实用新型针对现有技术的不足,提供了一种低分压低能耗烟气CO2捕集系统,包括吸收塔与富液泵,所述吸收塔内设有用于吸收原料气中 CO2的吸收剂,所述吸收塔底部与再生塔连通,所述吸收塔与再生塔之间物料输送阻力由富液泵克服,所述再生塔顶部出口端连接有蒸汽压缩机,所述蒸汽压缩机输出端连接有再沸器Ⅱ,所述蒸汽压缩机将再生塔产生的酸性气加压后用于加热再沸器Ⅱ,所述再沸器Ⅱ输入端与再生塔连通,所述再沸器Ⅱ输出端与分离设备连接,分离设备将酸性气体中的水分与CO2分离。Aiming at the deficiencies of the prior art, the utility model provides a low partial pressure and low energy consumption flue gas CO 2 capture system, which includes an absorption tower and a rich liquid pump. Absorbent, the bottom of the absorption tower is communicated with the regeneration tower, the material conveying resistance between the absorption tower and the regeneration tower is overcome by the rich liquid pump, the outlet end of the top of the regeneration tower is connected with a steam compressor, and the steam compressor outputs The end is connected with a reboiler II, and the steam compressor pressurizes the acid gas produced by the regeneration tower to heat the reboiler II, and the input end of the reboiler II is communicated with the regeneration tower, and the reboiler II The output end is connected to a separation device, which separates the moisture in the acid gas from CO 2 .

进一步的,所述富液泵输入端与吸收塔底部连接,所述富液泵输出端再生塔上部连通。Further, the input end of the rich liquid pump is connected to the bottom of the absorption tower, and the output end of the rich liquid pump is connected to the upper part of the regeneration tower.

进一步的,所述再生塔底部还连接有贫液泵,所述富液泵输出端与再生塔之间设置有贫富液换热器,所述富液泵输出端与贫富液换热器冷端入口端连接,所述贫富液换热器冷端出口端与再生塔上部连通;所述贫液泵输出端与贫富液换热器热端输入端连接,所述贫富液换热器热端输出端与水冷器输入端连接,所述水冷器输出端与吸收塔连通。Further, a lean liquid pump is also connected to the bottom of the regeneration tower, a lean and rich liquid heat exchanger is arranged between the output end of the rich liquid pump and the regeneration tower, and the output end of the rich liquid pump is connected to the lean and rich liquid heat exchanger. The cold end inlet end is connected, the cold end outlet end of the lean and rich liquid heat exchanger is connected with the upper part of the regeneration tower; the output end of the lean liquid pump is connected with the hot end input end of the lean rich liquid heat exchanger, and the lean rich liquid exchange The output end of the hot end of the heater is connected with the input end of the water cooler, and the output end of the water cooler is communicated with the absorption tower.

进一步的,所述再生塔底部与再沸器Ⅰ输入端连接,所述再沸器Ⅰ输出端与再生塔连通。Further, the bottom of the regeneration tower is connected to the input end of the reboiler I, and the output end of the reboiler I is connected to the regeneration tower.

进一步的,捕集系统还包括设置在吸收塔内顶部的回收装置,所述回收装置对经过吸收塔内净化气中的吸收剂进行回收。Further, the capture system further includes a recovery device arranged at the top of the absorption tower, and the recovery device recovers the absorbent in the purified gas passing through the absorption tower.

进一步的,所述回收装置包括与吸收塔内顶部连接的水洗设备,所述水洗设备通过水液洗除原料气中吸收剂;所述水洗设备包括循环水槽,所述循环水槽出液端与循环水泵输入端连接,所述循环水泵输出端与吸收塔水冷器输入端连接,所述循环水槽进液端以及吸收塔水冷器输出端均与吸收塔内顶部连通,所述循环水槽进液端位于吸收塔水冷器输出端底部。Further, the recovery device includes a water washing device connected to the top of the absorption tower, and the water washing device removes the absorbent in the raw gas through the water liquid; the water washing device includes a circulating water tank, and the liquid outlet end of the circulating water tank is connected to the circulating water The input end of the water pump is connected, the output end of the circulating water pump is connected to the input end of the water cooler of the absorption tower, the liquid inlet end of the circulating water tank and the output end of the water cooler of the absorption tower are both connected with the top of the absorption tower, and the liquid inlet end of the circulating water tank is located at the top of the absorption tower. Bottom of the output end of the water cooler of the absorption tower.

进一步的,所述吸收塔顶部出口端设置叶片式高效除沫器。Further, a vane type high-efficiency demister is arranged at the outlet end of the top of the absorption tower.

进一步的,所述分离设备包括连接在再沸器Ⅱ输出端的分离器,所述分离器输出端连接有酸性气水冷器。Further, the separation device includes a separator connected to the output end of the reboiler II, and an acid gas water cooler is connected to the output end of the separator.

进一步的,所述预处理塔底端与水洗泵输入端连接,所述水洗泵输出端与预处理塔水冷器输入端连接,所述预处理塔水冷器输出端与预处理塔顶部连接。Further, the bottom end of the pretreatment tower is connected to the input end of the water washing pump, the output end of the water washing pump is connected to the input end of the water cooler of the pretreatment tower, and the output end of the water cooler of the pretreatment tower is connected to the top of the pretreatment tower.

本实用新型的有益效果:The beneficial effects of the present utility model:

(1)通过在再生塔顶部出口端连接有蒸汽压缩机,通过蒸汽压缩机对再生塔产生的酸性气加压,使其压力和温度上升,蒸气的热焓也随之增加,把增加了热焓的蒸汽送到再沸器的加热室当作加热蒸汽使用,使再沸器内富液维持沸腾状态,相比现有技术将蒸汽转换为电能,再将转换电能用于整个系统的运行,多次转换,本实用新型方案蒸汽热能利率更高,使再生能耗相对传统工艺更低。(1) By connecting a steam compressor at the outlet end of the top of the regeneration tower, the acid gas generated by the regeneration tower is pressurized by the steam compressor, so that the pressure and temperature rise, and the enthalpy of the steam also increases, which increases the heat The enthalpy steam is sent to the heating chamber of the reboiler to be used as heating steam to keep the rich liquid in the reboiler in a boiling state. After multiple conversions, the steam thermal energy rate of the scheme of the utility model is higher, so that the energy consumption of regeneration is lower than that of the traditional process.

(2)通过回收贫液的热量,并将回收的热量对进入再生塔前的富液升温,使富液进入再生塔前具有较高的温度,进入再生塔后,通过加热使用汽提解吸富液中吸收剂部分CO2,此时由于富液具有较高的温度,减少再沸器低压蒸汽的消耗,降低CO2的捕捉成本。(2) By recovering the heat of the lean liquid, and heating the recovered heat to the rich liquid before entering the regeneration tower, so that the rich liquid has a higher temperature before entering the regeneration tower, and after entering the regeneration tower, the rich liquid is desorbed and desorbed by heating The absorbent part in the liquid contains CO 2 . At this time, because the rich liquid has a higher temperature, the consumption of low-pressure steam in the reboiler is reduced, and the cost of capturing CO 2 is reduced.

(3)通过在吸收塔顶部出口端设置叶片式高效除沫器,叶片式高效除沫器,当原料气夹带着小尺寸液滴进入叶片式高效除毛器,将被叶片分隔成多个区域,气体在通过各个区域的过程中将被叶片进行多次快速的流向转变,在惯性力的作用下,液体将与叶片发生动能碰撞,借助分子的布朗运动和细丝毛细管效应,液滴之间通过聚结效应附着在叶片表面,液滴在自身重力下在下方进行汇集;高效回收原料气中的吸收剂,使吸收剂消耗降低到0.6kg/tCO2左右,进一步有效降低了二氧化碳捕集成本。(3) By setting a vane-type high-efficiency demister at the outlet end of the top of the absorption tower, the vane-type high-efficiency demister, when the raw gas entrains small-sized droplets into the vane-type high-efficiency hair remover, it will be divided into multiple areas by the blades , in the process of passing through each area, the gas will be transformed by the blade for many times. Under the action of the inertial force, the liquid will collide with the blade with kinetic energy. With the help of the Brownian motion of the molecules and the filament capillary effect, the liquid droplets The droplets adhere to the surface of the blade through the coalescence effect, and the droplets are collected below under their own gravity; the absorbent in the raw gas is efficiently recovered, and the consumption of the absorbent is reduced to about 0.6kg/tCO 2 , which further effectively reduces the cost of carbon dioxide capture .

附图说明Description of drawings

图1为实施例1的CO2捕集系统示意图;Fig. 1 is the CO2 capture system schematic diagram of embodiment 1;

图2为实施例2的CO2捕集系统示意图;Fig. 2 is the CO2 capture system schematic diagram of embodiment 2;

图3为CO2捕集方法示意图。Figure 3 is a schematic diagram of the CO capture method.

附图编号说明:1、预处理塔,2、水洗泵,3、预处理塔水冷器,4、吸收塔,5、循环水槽,6、循环水泵,7、吸收塔水冷器,8、中间冷却器, 9、富液泵,10、贫富液换热器,11、再生塔,12、再沸器Ⅰ,13、再沸器Ⅱ,14、贫液泵,15、水冷器,16、过滤器,17、胺净化系统,18、蒸汽压缩机,19、分离器,20、酸性气水冷器,21、酸性气冷却器,22、回流泵。Description of drawing numbers: 1, pretreatment tower, 2, water washing pump, 3, water cooler of pretreatment tower, 4, absorption tower, 5, circulating water tank, 6, circulating water pump, 7, water cooler of absorption tower, 8, intermediate cooling device, 9, rich liquid pump, 10, lean and rich liquid heat exchanger, 11, regeneration tower, 12, reboiler I, 13, reboiler II, 14, lean liquid pump, 15, water cooler, 16, filtration device, 17, amine purification system, 18, steam compressor, 19, separator, 20, acid gas water cooler, 21, acid gas cooler, 22, reflux pump.

具体实施方式Detailed ways

为使本实用新型实施例的目的、技术方案和优点更加清楚,下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。In order to make the purposes, technical solutions and advantages of the embodiments of the present utility model clearer, the technical solutions in the embodiments of the present utility model will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present utility model. The embodiments described above are a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present invention.

需要说明的是,当元件被称为“固定于”另一个元件,它可以直接在另一个元件上或者也可以存在居中的元件。当一个元件被认为是“连接”另一个元件,它可以是直接连接到另一个元件或者可能同时存在居中元件。It should be noted that when an element is referred to as being "fixed to" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present.

实施例1Example 1

下面将结合本实用新型实施例中的附图1,对本实用新型实施例中的技术方案进行清楚、完整地描述,过程如下:Below in conjunction with accompanying drawing 1 in the embodiment of the present utility model, the technical solution in the embodiment of the present utility model will be clearly and completely described, and the process is as follows:

请参阅图1所示,一种低分压低能耗烟气CO2捕集系统,包括预处理塔1、吸收塔4、再生塔11以及贫富液换热器10;原料气首先进入预处理塔1,预处理塔1底端与水洗泵2输入端连接,水洗泵2输出端与预处理塔水冷器3输入端连接,预处理塔水冷器3输出端与预处理塔1顶部连接,即预处理塔水冷器3输出端延伸至预处理塔1内。Referring to Figure 1, a low partial pressure and low energy consumption flue gas CO 2 capture system includes a pretreatment tower 1, an absorption tower 4, a regeneration tower 11 and a lean-rich liquid heat exchanger 10; the raw material gas first enters the pretreatment Tower 1, the bottom end of the pretreatment tower 1 is connected to the input end of the water washing pump 2, the output end of the water washing pump 2 is connected to the input end of the pretreatment tower water cooler 3, and the output end of the pretreatment tower water cooler 3 is connected to the top of the pretreatment tower 1, namely The output end of the pretreatment tower water cooler 3 extends into the pretreatment tower 1 .

使用时,启动水洗泵2,经过预处理塔水冷器3溶液从预处理塔1顶部落入,将原料气引入预处理塔1内,原料气与溶液逆流接触,以达到对原料气除杂和降温的目的,预处理塔1中的溶液由预处理塔1塔底流出,经预处理塔水冷器3却后重新返回至预处理塔1循环使用,对进入预处理塔1 原料气进行洗涤,形成净化气;其中,溶液可以是水,也可以是其它能够代替水实现对原料气的除杂和降温的液体,避免温度过高的原料进入吸收塔4内,降低后续吸收剂吸收CO2的效率。When in use, start the water washing pump 2, and the solution falls from the top of the pretreatment tower 1 through the water cooler 3 of the pretreatment tower, and the raw material gas is introduced into the pretreatment tower 1, and the raw material gas is in countercurrent contact with the solution to achieve the removal of impurities from the raw material gas. For the purpose of cooling, the solution in the pretreatment tower 1 flows out from the bottom of the pretreatment tower 1, and is cooled by the pretreatment tower water cooler 3 and returned to the pretreatment tower 1 for recycling, and the raw gas entering the pretreatment tower 1 is washed, A purified gas is formed; wherein, the solution can be water, or other liquids that can replace water to realize the impurity removal and cooling of the raw material gas, so as to prevent the raw materials with too high temperature from entering the absorption tower 4 and reduce the subsequent absorption of CO by the absorbent. efficiency.

降温除杂后的原料气引入吸收塔4下部,进入吸收塔4内的原料气与吸收剂接触时,由吸收剂吸收原料气中的CO2The raw material gas after cooling and impurity removal is introduced into the lower part of the absorption tower 4, and when the raw material gas entering the absorption tower 4 contacts with the absorbent, the CO 2 in the raw material gas is absorbed by the absorbent;

在吸收塔4内顶部设置吸收剂回收装置,回收装置对经过吸收塔4内顶部净化气中的吸收剂进行回收;其中回收装置包括与吸收塔4内顶部连接的水洗设备,水洗设备通过水液洗除净化气中吸收剂,吸收剂融于水液,然后洗除吸收剂的净化气经吸收塔4塔顶排入大气。An absorbent recovery device is arranged at the top of the absorption tower 4, and the recovery device recovers the absorbent in the purified gas passing through the top of the absorption tower 4; wherein the recovery device includes a water washing device connected to the top of the absorption tower 4, and the water washing device passes through the water liquid The absorbent in the purified gas is washed away, the absorbent is melted into the water, and then the purified gas from which the absorbent has been washed is discharged into the atmosphere through the top of the absorption tower 4.

水洗设备包括循环水槽5,循环水槽5出液端与循环水泵6输入端连接,循环水泵6输出端与吸收塔水冷器7输入端连接,其中循环水槽5进液端以及吸收塔水冷器7输出端均与吸收塔4内顶部连通,循环水槽5进液端位于吸收塔水冷器7输出端底部,方便对吸收塔水冷器7输出端喷出的清洗液进行回收;水液还可以是其它能够代替液态水洗除净化气中吸收剂的液体,且与吸收剂相融。The washing equipment includes a circulating water tank 5, the liquid outlet end of the circulating water tank 5 is connected with the input end of the circulating water pump 6, the output end of the circulating water pump 6 is connected with the input end of the absorption tower water cooler 7, wherein the liquid inlet end of the circulating water tank 5 and the output end of the absorption tower water cooler 7 are connected. The ends are all communicated with the inner top of the absorption tower 4, and the liquid inlet end of the circulating water tank 5 is located at the bottom of the output end of the absorption tower water cooler 7, which is convenient for recycling the cleaning liquid sprayed from the output end of the absorption tower water cooler 7; Instead of liquid water, the liquid of the absorbent in the purified gas is washed away, and it is melted with the absorbent.

使用时,吸收塔水冷器7对进入其内的水液温度设置在39-40℃左右,保证水液吸收吸收剂的效果。When in use, the temperature of the water liquid entering into the water cooler 7 of the absorption tower is set at about 39-40° C. to ensure the effect of the water liquid absorbing the absorbent.

为加强吸收塔4内顶部的水液吸收净化气中夹带的吸收剂的气液传质效率,提升水液的清洗效果,我们在吸收塔水冷器7输出端与循环水槽5 进液端设置了三层筛板式塔板。In order to strengthen the gas-liquid mass transfer efficiency of the absorbent entrained in the water-liquid absorption and purification gas at the top of the absorption tower 4, and improve the cleaning effect of the water-liquid, we set up the output end of the water cooler 7 of the absorption tower and the liquid inlet end of the circulating water tank 5. Three-layer sieve tray.

为进一步回收净化气中的吸收剂,降低吸收剂的消耗,我们在吸收塔4 顶部出口端设置叶片式高效除沫器,叶片式高效除沫器,原理是:气相(即原料气)夹带着小尺寸液滴进入叶片式高效除毛器,将被叶片分隔成多个区域,气体在通过各个区域的过程中将被叶片进行多次快速的流向转变,在惯性力的作用下,液体将与叶片发生动能碰撞,借助分子的布朗运动和细丝毛细管效应,液滴之间通过聚结效应附着在叶片表面,液滴在自身重力下在下方进行汇集;高效回收原料气中的吸收剂,使吸收剂消耗降低到 0.6kg/tCO2左右,有效降低了二氧化碳捕集成本。In order to further recover the absorbent in the purified gas and reduce the consumption of the absorbent, we set up a vane-type high-efficiency demister and a vane-type high-efficiency demister at the outlet end of the top of the absorption tower 4. The principle is: the gas phase (ie the raw material gas) is entrained with Small-sized droplets enter the blade-type high-efficiency hair remover, which will be divided into multiple areas by the blades. During the process of passing through each area, the gas will be rapidly transformed by the blades for many times. Under the action of inertial force, the liquid will The blades collide with kinetic energy. With the help of the Brownian motion of molecules and the capillary effect of filaments, the droplets are attached to the surface of the blade through the coalescence effect, and the droplets are collected below under their own gravity; the absorbent in the raw gas is efficiently recovered, so that the The consumption of absorbent is reduced to about 0.6kg/ tCO2 , which effectively reduces the cost of carbon dioxide capture.

请参阅图1所示,富液泵9输入端与吸收塔4底部连接,富液泵9输出端与再生塔11上部连通,所述再生塔11顶部出口端连接有蒸汽压缩机18,所述蒸汽压缩机18输出端与再沸器连接,再沸器包括与再生塔11底部连接的再沸器Ⅱ13与再沸器Ⅰ12,所述蒸汽压缩机18将再生塔11顶产生的酸性气加压后用于加热再沸器Ⅱ13,维持再沸器Ⅱ13中贫液沸腾状态,所述再生塔11输出端与分离设备连接,分离设备将酸性气体中的水分与 CO2分离,得到CO2;再沸器Ⅱ13采用管壳热虹吸式;其中再沸器Ⅰ12输出端与再生塔11连通。1, the input end of the rich liquid pump 9 is connected to the bottom of the absorption tower 4, the output end of the rich liquid pump 9 is communicated with the upper part of the regeneration tower 11, and the top outlet end of the regeneration tower 11 is connected with a steam compressor 18. The output end of the steam compressor 18 is connected to a reboiler, and the reboiler includes a reboiler II13 and a reboiler I12 connected to the bottom of the regeneration tower 11. The steam compressor 18 pressurizes the acid gas generated at the top of the regeneration tower 11. It is then used to heat the reboiler II13 to maintain the boiling state of the lean liquid in the reboiler II13. The output end of the regeneration tower 11 is connected to a separation device, and the separation device separates the moisture in the acid gas from CO 2 to obtain CO 2 ; Boiler II13 adopts shell-and-tube thermosyphon type; the output end of reboiler I12 is communicated with regeneration tower 11.

使用时,吸收剂在吸收塔4中吸收CO2后形成富液,通过富液泵9输送至再生塔11内,富液从再生塔11上部进入,富液在再生塔11内,通过汽提解吸富液中吸收剂CO2,富液中水分蒸发成水蒸气;酸性气经过蒸汽压缩机18对酸性气压缩加压;将酸性气加压至2.5~3.5bar.g后,用于加热再沸器Ⅱ13,充分回收了酸性气的潜热,相对现有工艺,能量利用效率高,大大降低了再生用低压蒸汽用量,使再生能耗相对传统工艺降低30%左右。When in use, the absorbent absorbs CO2 in the absorption tower 4 to form a rich liquid, which is transported to the regeneration tower 11 through the rich liquid pump 9, and the rich liquid enters from the upper part of the regeneration tower 11, and the rich liquid is in the regeneration tower 11. The absorbent CO 2 in the rich liquid is desorbed, and the water in the rich liquid is evaporated into water vapor; the acid gas is compressed and pressurized by the steam compressor 18; after the acid gas is pressurized to 2.5-3.5 bar.g, it is used for heating again Boiler II13 fully recovers the latent heat of acid gas. Compared with the existing process, the energy utilization efficiency is high, which greatly reduces the consumption of low-pressure steam for regeneration, and reduces the energy consumption of regeneration by about 30% compared with the traditional process.

蒸汽压缩机18原理:因为酸性气中含有70%左右的水蒸气,此股汽体经过压缩机压缩,使其压力和温度上升,酸性气的热焓也随之增加,把增加了热焓的酸性气送到再生塔11的再沸器Ⅱ13当作加热蒸汽使用,使再沸器Ⅱ13内的贫液维持沸腾状态,酸性气中的水蒸气冷凝成水,这样二次蒸汽中的潜热得到了充分的利用,从而达到了节能的目的。The principle of steam compressor 18: Because the acid gas contains about 70% water vapor, this gas is compressed by the compressor to increase its pressure and temperature, and the enthalpy of the acid gas also increases, which increases the enthalpy of the gas. The acid gas is sent to the reboiler II13 of the regeneration tower 11 as heating steam, so that the lean liquid in the reboiler II13 is kept in a boiling state, and the water vapor in the acid gas is condensed into water, so that the latent heat in the secondary steam is obtained. Make full use of it, so as to achieve the purpose of energy saving.

请参阅图1所示,分离设备包括与再沸器Ⅱ13输出端连接的分离器19 连接,分离器19输出端连接有酸性气水冷器20,酸性气水冷器20输出端连接有酸性气分离器21,酸性气分离器21液相出口连接有回流泵22。Referring to Figure 1, the separation device includes a separator 19 connected to the output end of the reboiler II 13, the output end of the separator 19 is connected to an acid gas water cooler 20, and the output end of the acid gas water cooler 20 is connected to an acid gas separator 21. A reflux pump 22 is connected to the liquid phase outlet of the acid gas separator 21.

出再沸器Ⅱ13的酸性气经过分离器19后,液相通过自身压力去酸性气分离21回收吸收剂,气相减压至50kPa.g后,进入酸性气水冷器20进一步冷却后进入酸性气分离器21,液相通过回流泵22打回再生塔11,气相得到纯度99.5%的CO2产品气送入后序工段使用。After the acid gas from the reboiler II13 passes through the separator 19, the liquid phase passes through its own pressure to remove the acid gas separation 21 to recover the absorbent, and after the gas phase is decompressed to 50 kPa.g, it enters the acid gas water cooler 20 for further cooling and then enters the acid gas separation. Device 21, the liquid phase is pumped back to the regeneration tower 11 through the reflux pump 22, and the gaseous phase obtains CO 2 product gas with a purity of 99.5%, which is sent to the subsequent process section for use.

请参阅图1所示,为保证吸收剂吸收CO2吸收效率,我们在吸收塔4 中部增设中间水冷器8,将富液的温度降至39~40℃左右,消除吸收剂因吸收CO2后升温造成吸收效率下降的影响,使吸收剂的吸收率增加10%左右。Please refer to Figure 1. In order to ensure the absorption efficiency of the absorbent to absorb CO 2 , we add an intermediate water cooler 8 in the middle of the absorption tower 4 to reduce the temperature of the rich liquid to about 39-40 ° C. The effect of increasing the temperature on the decrease of the absorption efficiency increases the absorption rate of the absorbent by about 10%.

使用时,吸收剂在吸收塔4上部吸收CO2后,吸收剂温度会上升,吸收剂在低温时吸收系数比较高,经过中间水冷器8降温后,在吸收塔4下部继续吸收CO2,提升吸收剂的吸收率,提升捕捉CO2效率。When in use, after the absorbent absorbs CO 2 in the upper part of the absorption tower 4 , the temperature of the absorbent will rise, and the absorption coefficient of the absorbent at low temperature is relatively high. The absorption rate of the absorbent improves the CO2 capture efficiency.

实施例2Example 2

请参阅图2所示,为了对贫液的热量进行回收再利用,在富液泵9输出端与再生塔11之间设置有贫富液换热器10,富液泵9输出端与贫富液换热器10冷端入口端连接,贫富液换热器10冷端出口端与再生塔11上部连通;贫液泵14输出端与贫富液换热器10热端入口连接,贫富液换热器10 热端出口与水冷器15输入端连接。Please refer to FIG. 2 , in order to recover and reuse the heat of the lean liquid, a lean-rich liquid heat exchanger 10 is arranged between the output end of the rich liquid pump 9 and the regeneration tower 11 . The cold end inlet end of the liquid heat exchanger 10 is connected, the cold end outlet end of the lean and rich liquid heat exchanger 10 is connected with the upper part of the regeneration tower 11; the output end of the lean liquid pump 14 is connected with the hot end inlet of the lean rich liquid heat exchanger 10, The outlet of the hot end of the liquid heat exchanger 10 is connected to the input end of the water cooler 15 .

使用时,贫液泵14先将贫液输送至贫富液换热器10换热,贫富液换热器10采用低温差贫富液换热器,冷端的温差小于等于5℃,充分回收了贫液的显热,贫富液换热器10加热上述即将进入再生塔11的富液,使富液进入再生塔11前具有更高的温度,减少再生塔11底部低压蒸汽的消耗,提升解吸CO2的效率,降低CO2的捕捉成本;然后将贫液送至水冷器15冷却,冷却后输送至吸收塔4内。When in use, the lean liquid pump 14 first transports the lean liquid to the lean-rich liquid heat exchanger 10 for heat exchange, and the lean-rich liquid heat exchanger 10 adopts a low-temperature difference lean-rich liquid heat exchanger. In order to reduce the sensible heat of the lean liquid, the lean-rich liquid heat exchanger 10 heats the above-mentioned rich liquid that is about to enter the regeneration tower 11, so that the rich liquid has a higher temperature before entering the regeneration tower 11, reduces the consumption of low-pressure steam at the bottom of the regeneration tower 11, and improves the The efficiency of desorption of CO 2 is reduced, and the cost of CO 2 capture is reduced; then the lean liquid is sent to the water cooler 15 for cooling, and then sent to the absorption tower 4 after cooling.

实施例3Example 3

请参阅图3所示,一种低分压低能耗烟气CO2捕集系统,包括以下步骤:Please refer to Figure 3, a low partial pressure and low energy consumption flue gas CO2 capture system, including the following steps:

S1、吸收CO2,将原料气通过吸收剂,吸收剂吸收原料气中的CO2形成富液,S1. Absorb CO 2 , pass the feed gas through the absorbent, and the absorbent absorbs CO 2 in the feed gas to form a rich liquid,

S2、富液解吸,产生酸性气,酸性气中主要含有CO2、H2O、吸收剂;S2. Desorption of rich liquid to produce acid gas, which mainly contains CO 2 , H 2 O and absorbent;

S3、压缩酸性气,将酸性气加压至2.5~3.5bar.g,使其压力和温度上升,回收酸性气的潜热,并将回收的潜热作用于加热再生塔底的再沸器;S3. Compress the acid gas, pressurize the acid gas to 2.5-3.5 bar.g, increase its pressure and temperature, recover the latent heat of the acid gas, and apply the recovered latent heat to the reboiler for heating the bottom of the regeneration tower;

S4、冷却分离,将酸性气冷却,饱和蒸汽冷凝成液相,将液相与CO2分离得到CO2S4, cooling and separation, the acid gas is cooled, the saturated steam is condensed into a liquid phase, and the liquid phase is separated from CO 2 to obtain CO 2 .

为减少吸收剂的消耗,在执行步骤S1后,回收吸收剂,向净化气中喷洒水液,回收原料气中夹带的吸收剂,吸收剂溶于水液。In order to reduce the consumption of the absorbent, after step S1 is performed, the absorbent is recovered, the water liquid is sprayed into the purified gas, the absorbent entrained in the raw gas is recovered, and the absorbent is dissolved in the water liquid.

执行步骤S1前,先对原料气水洗,除去原料气中的杂质,降低原料气的温度,在对原料气水洗时,水与原料气逆流接触,清洗效果更好。Before performing step S1, the raw material gas is first washed with water to remove impurities in the raw material gas, and the temperature of the raw material gas is lowered. When the raw material gas is washed with water, the water and the raw material gas are in countercurrent contact, and the cleaning effect is better.

对步骤S1中的制得的富液降温,将富液的温度降至39~40℃。The temperature of the rich liquid prepared in step S1 is lowered, and the temperature of the rich liquid is lowered to 39-40°C.

为充分利用贫液的显热,执行步骤S2后,解吸CO2后的富液形成贫液,对贫液热量进行回收,将回收的热量用于对步骤S2中解吸前的富液升温。In order to make full use of the sensible heat of the lean liquid, after step S2 is performed, the rich liquid after desorption of CO 2 forms a lean liquid, the heat of the lean liquid is recovered, and the recovered heat is used to warm the rich liquid before desorption in step S2.

对回收显热后的贫液进行冷却到39~40℃,冷却后的贫液进入吸收塔喷淋吸收CO2The lean liquid after recovering sensible heat is cooled to 39-40°C, and the cooled lean liquid enters the absorption tower to spray and absorb CO 2 .

富液在再生塔11解吸,在再生塔11塔顶产生酸性气,与再生塔11连接有再沸器Ⅱ13以及蒸汽压缩机18,酸性气经蒸汽压缩机18压缩加压,将回收的酸性气潜热,作用于加热再沸器Ⅱ13内的富液。The rich liquid is desorbed in the regeneration tower 11, and the acid gas is generated at the top of the regeneration tower 11. The reboiler II 13 and the steam compressor 18 are connected to the regeneration tower 11. The acid gas is compressed and pressurized by the steam compressor 18, and the recovered acid gas is The latent heat acts on the rich liquid in the heating reboiler II13.

需要说明的是,在本文中,如若存在第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that, in this document, if there are relational terms such as first and second, etc., it is only used to distinguish one entity or operation from another entity or operation, and does not necessarily require or imply these entities or operations There is no such actual relationship or order between them. Moreover, the terms "comprising", "comprising" or any other variation thereof are intended to encompass a non-exclusive inclusion such that a process, method, article or device that includes a list of elements includes not only those elements, but also includes not explicitly listed or other elements inherent to such a process, method, article or apparatus. Without further limitation, an element qualified by the phrase "comprising a..." does not preclude the presence of additional identical elements in a process, method, article or apparatus that includes the element.

以上实施例仅用以说明本实用新型的技术方案,而非对其限制;尽管参照前述实施例对本实用新型进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本实用新型各实施例技术方案的精神和范围。The above embodiments are only used to illustrate the technical solutions of the present utility model, but not to limit them; although the present utility model has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: it can still be used for the foregoing implementations. The technical solutions described in the examples are modified, or some technical features thereof are equivalently replaced; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims (9)

1.一种低分压低能耗烟气CO2捕集系统,包括吸收塔(4)与富液泵(9),所述吸收塔(4)内设有用于吸收原料气中CO2的吸收剂,其特征在于,所述吸收塔(4)底部与再生塔(11)连通,所述吸收塔(4)与再生塔(11)之间物料输送阻力由富液泵(9)克服,所述再生塔(11)顶部出口端连接有蒸汽压缩机(18),所述蒸汽压缩机(18)输出端连接有再沸器Ⅱ(13),所述蒸汽压缩机(18)将再生塔(11)内产生的酸性气加压后用于加热再沸器Ⅱ(13),所述再沸器Ⅱ(13)输入端与再生塔(11)连通,所述再沸器Ⅱ(13)输出端与分离设备连接,分离设备将酸性气体中的水分与CO2分离。1. a low partial pressure and low energy consumption flue gas CO capture system, comprising an absorption tower (4) and a rich liquid pump (9), and the absorption tower (4) is provided with an absorption for absorbing CO in the raw material gas It is characterized in that the bottom of the absorption tower (4) is communicated with the regeneration tower (11), and the material conveying resistance between the absorption tower (4) and the regeneration tower (11) is overcome by the rich liquid pump (9), so the A steam compressor (18) is connected to the top outlet end of the regeneration tower (11), and a reboiler II (13) is connected to the output end of the steam compressor (18). The acid gas generated in 11) is pressurized and used to heat the reboiler II (13), the input end of the reboiler II (13) is communicated with the regeneration tower (11), and the output of the reboiler II (13) The end is connected with a separation device, which separates the moisture in the acid gas from CO2 . 2.根据权利要求1所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,所述富液泵(9)输入端与吸收塔(4)底部连接,所述富液泵(9)输出端再生塔(11)上部连通。2. A low partial pressure and low energy consumption flue gas CO 2 capture system according to claim 1, wherein the input end of the rich liquid pump (9) is connected to the bottom of the absorption tower (4), and the rich liquid pump (9) is connected to the bottom of the absorption tower (4). The upper part of the regeneration tower (11) at the output end of the liquid pump (9) is communicated. 3.根据权利要求2所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,所述再生塔(11)底部还连接有贫液泵(14),所述富液泵(9)输出端与再生塔(11)之间设置有贫富液换热器(10),所述富液泵(9)输出端与贫富液换热器(10)冷端入口端连接,所述贫富液换热器(10)冷端出口端与再生塔(11)上部连通;所述贫液泵(14)输出端与贫富液换热器(10)热端输入端连接,所述贫富液换热器(10)热端输出端与水冷器(15)输入端连接,所述水冷器(15)输出端与吸收塔(4)连通。3. A low partial pressure and low energy consumption flue gas CO 2 capture system according to claim 2, wherein a lean liquid pump (14) is also connected at the bottom of the regeneration tower (11), and the rich liquid A lean-rich liquid heat exchanger (10) is arranged between the output end of the pump (9) and the regeneration tower (11), and the output end of the rich liquid pump (9) is connected to the cold end inlet end of the lean-rich liquid heat exchanger (10). connection, the outlet end of the cold end of the lean-rich liquid heat exchanger (10) is communicated with the upper part of the regeneration tower (11); the output end of the lean liquid pump (14) is connected to the input end of the hot end of the lean-rich liquid heat exchanger (10) The output end of the hot end of the lean and rich liquid heat exchanger (10) is connected to the input end of the water cooler (15), and the output end of the water cooler (15) is communicated with the absorption tower (4). 4.根据权利要求1所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,所述再生塔(11)底部与再沸器Ⅰ(12)输入端连接,所述再沸器Ⅰ(12)输出端与再生塔(11)连通。4. A low partial pressure and low energy consumption flue gas CO 2 capture system according to claim 1, wherein the bottom of the regeneration tower (11) is connected to the input end of the reboiler I (12), and the The output end of the reboiler I (12) is communicated with the regeneration tower (11). 5.根据权利要求1所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,捕集系统还包括设置在吸收塔(4)内顶部的回收装置,所述回收装置对经过吸收塔(4)内净化气中的吸收剂进行回收。5. A low partial pressure and low energy consumption flue gas CO2 capture system according to claim 1, characterized in that the capture system further comprises a recovery device arranged at the top of the absorption tower (4), the recovery device The absorbent in the purified gas passing through the absorption tower (4) is recovered. 6.根据权利要求5所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,所述回收装置包括与吸收塔(4)内顶部连接的水洗设备,所述水洗设备通过水液洗除净化气中吸收剂;所述水洗设备包括循环水槽(5),所述循环水槽(5)出液端与循环水泵(6)输入端连接,所述循环水泵(6)输出端与吸收塔水冷器(7)输入端连接,所述循环水槽(5)进液端以及吸收塔水冷器(7)输出端均与吸收塔(4)内顶部连通,所述循环水槽(5)进液端位于吸收塔水冷器(7)输出端底部。6. A low partial pressure and low energy consumption flue gas CO 2 capture system according to claim 5, wherein the recovery device comprises a water washing device connected to the inner top of the absorption tower (4), the water washing device The absorbent in the purified gas is removed by water washing; the water washing equipment includes a circulating water tank (5), the liquid outlet end of the circulating water tank (5) is connected to the input end of the circulating water pump (6), and the circulating water pump (6) outputs The end is connected with the input end of the absorption tower water cooler (7), the liquid inlet end of the circulating water tank (5) and the output end of the absorption tower water cooler (7) are both communicated with the inner top of the absorption tower (4), and the circulating water tank (5) ) The liquid inlet end is located at the bottom of the output end of the absorption tower water cooler (7). 7.根据权利要求1所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,所述吸收塔(4)顶部出口端设置叶片式高效除沫器。7 . The flue gas CO 2 capture system with low partial pressure and low energy consumption according to claim 1 , wherein a vane type high-efficiency demister is arranged at the outlet end of the top of the absorption tower ( 4 ). 8 . 8.根据权利要求1所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,所述分离设备包括连接在再沸器Ⅱ(13)输出端的分离器(19),所述分离器(19)输出端连接有酸性气水冷器(20)。8. The flue gas CO 2 capture system with low partial pressure and low energy consumption according to claim 1, wherein the separation device comprises a separator (19) connected to the output end of the reboiler II (13), An acid gas water cooler (20) is connected to the output end of the separator (19). 9.根据权利要求1-8任一项所述的一种低分压低能耗烟气CO2捕集系统,其特征在于,捕集系统还包括预处理塔(1),所述预处理塔(1)底端与水洗泵(2)输入端连接,所述水洗泵(2)输出端与预处理塔水冷器(3)输入端连接,所述预处理塔水冷器(3)输出端与预处理塔(1)顶部连接。9. A low partial pressure and low energy consumption flue gas CO 2 capture system according to any one of claims 1-8, characterized in that the capture system further comprises a pretreatment tower (1), the pretreatment tower (1) The bottom end is connected to the input end of the water washing pump (2), the output end of the water washing pump (2) is connected to the input end of the pretreatment tower water cooler (3), and the output end of the pretreatment tower water cooler (3) is connected to the The top of the pretreatment tower (1) is connected.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116672851A (en) * 2023-05-26 2023-09-01 国家能源集团新能源技术研究院有限公司 Carbon trapping system for improving utilization rate of waste heat
CN116764388A (en) * 2023-06-08 2023-09-19 华东理工大学 Gas concentration and absorption liquid regeneration device and method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116672851A (en) * 2023-05-26 2023-09-01 国家能源集团新能源技术研究院有限公司 Carbon trapping system for improving utilization rate of waste heat
CN116764388A (en) * 2023-06-08 2023-09-19 华东理工大学 Gas concentration and absorption liquid regeneration device and method thereof
CN116764388B (en) * 2023-06-08 2026-01-23 华东理工大学 Gas concentration and absorption liquid regeneration device and method thereof

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