CN216897896U - Device for heating circulating mother liquor by using waste heat of alumina evaporation process - Google Patents
Device for heating circulating mother liquor by using waste heat of alumina evaporation process Download PDFInfo
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- CN216897896U CN216897896U CN202220597101.1U CN202220597101U CN216897896U CN 216897896 U CN216897896 U CN 216897896U CN 202220597101 U CN202220597101 U CN 202220597101U CN 216897896 U CN216897896 U CN 216897896U
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- 239000012452 mother liquor Substances 0.000 title claims abstract description 64
- 238000001704 evaporation Methods 0.000 title claims abstract description 63
- 230000008020 evaporation Effects 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000002918 waste heat Substances 0.000 title claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000010438 heat treatment Methods 0.000 title claims abstract description 16
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims abstract description 146
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000010521 absorption reaction Methods 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 239000002699 waste material Substances 0.000 claims abstract description 6
- 239000006096 absorbing agent Substances 0.000 claims description 34
- 238000005086 pumping Methods 0.000 claims description 2
- 238000009833 condensation Methods 0.000 abstract description 5
- 230000005494 condensation Effects 0.000 abstract description 5
- 230000005611 electricity Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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Abstract
Description
技术领域technical field
本实用新型涉及余热回收技术领域,具体涉及一种利用氧化铝蒸发工序余热来加热循环母液的装置。The utility model relates to the technical field of waste heat recovery, in particular to a device for heating a circulating mother liquor by utilizing the waste heat of an alumina evaporation process.
背景技术Background technique
氧化铝生产企业属于高能耗产业,随着低碳生产理念的提出,节能降耗已成为氧化铝生产企业迫切需要解决的问题。Alumina production enterprises belong to high energy consumption industries. With the concept of low-carbon production, energy saving and consumption reduction has become an urgent problem for alumina production enterprises.
在氧化铝生产企业中,蒸汽的消耗量很大,特别是蒸发工序蒸汽消耗量大,约占企业总汽耗的30%左右。氧化铝生产企业的氢氧化钠循环母液蒸发采用六效逆流管式蒸发装置,生产过程中,产生大量的二次蒸汽,其中蒸发装置VI效(末效)的乏汽含有大量的低温余热,但直接进入冷凝器,用水冷却冷凝成水而移除,这个过程不但浪费了蒸发装置VI效(末效)乏汽的热能,还增加了水、电的消耗。因此,能对蒸发装置VI效(末效)乏汽热能进行回收利用,是现阶段本技术人员亟需解决的问题。In alumina production enterprises, the consumption of steam is very large, especially in the evaporation process, which accounts for about 30% of the total steam consumption of the enterprise. A six-effect countercurrent tubular evaporation device is used for the evaporation of sodium hydroxide circulating mother liquor in alumina production enterprises. During the production process, a large amount of secondary steam is generated. Directly enter the condenser, cool it with water and condense it into water and remove it. This process not only wastes the heat energy of the exhausted steam in the VI effect (final effect) of the evaporation device, but also increases the consumption of water and electricity. Therefore, it is an urgent problem to be solved by the technicians at this stage to be able to recover and utilize the heat energy of the exhausted steam of the VI effect (final effect) of the evaporation device.
实用新型内容Utility model content
本实用新型需要解决的技术问题是提供一种利用氧化铝蒸发工序余热加热循环母液的装置,不但能对蒸发装置VI效乏汽热能进行回收利用,还可以降低蒸发装置VI效乏汽冷凝过程中水、电的消耗。The technical problem to be solved by this utility model is to provide a device for heating the circulating mother liquor by utilizing the waste heat of the alumina evaporation process, which can not only recycle the thermal energy of the evaporation device's VI-efficiency exhausted steam, but also reduce the amount of time in the evaporation device's VI-efficiency exhausted steam condensation process. Water and electricity consumption.
为解决上述技术问题,本实用新型所采取的技术方案如下。In order to solve the above-mentioned technical problems, the technical solutions adopted by the present invention are as follows.
利用氧化铝蒸发工序余热加热循环母液的装置,包括母液槽,母液槽的入口连通有用于输送蒸发装置V效出液的母液总管;所述母液总管上设置有用于控制母液总管通断的第一电磁阀,母液总管的出口端设置有温度传感器;所述温度传感器的输出端连接有PLC控制器,PLC控制器的输出端与第一电磁阀的受控端连接,其中,所述母液总管上通过连通的位于第一电磁阀前方的第一管道连接有用于对蒸发装置V效出液进行升温的溴化锂吸收式热泵机组;所述溴化锂吸收式热泵机组的余热进口通过连接的乏汽接入管道连接有蒸发装置VI效乏汽,溴化锂吸收式热泵机组的热水出口通过连通的位于第一电磁阀后方的第二管道与母液总管连通。A device for heating circulating mother liquor by utilizing the waste heat of the alumina evaporation process, including a mother liquor tank, the inlet of the mother liquor tank is connected with a mother liquor main pipe for conveying the V-effect liquid of the evaporation device; Solenoid valve, the outlet end of the mother liquor main pipe is provided with a temperature sensor; the output end of the temperature sensor is connected with a PLC controller, and the output end of the PLC controller is connected with the controlled end of the first solenoid valve, wherein, on the mother liquor main pipe A lithium bromide absorption heat pump unit for heating the V-effect effluent of the evaporation device is connected through the connected first pipeline located in front of the first solenoid valve; the waste heat inlet of the lithium bromide absorption heat pump unit is connected to the pipeline through the connected exhaust steam Evaporation device VI is connected with exhausted steam, and the hot water outlet of the lithium bromide absorption heat pump unit is communicated with the mother liquor main pipe through a connected second pipeline located behind the first electromagnetic valve.
优选的,所述溴化锂吸收式热泵机组包括蒸发器、吸收器、再生器和冷凝器;所述溴化锂吸收式热泵机组的余热进口设置在蒸发器上,蒸发器的低压闪蒸蒸汽出口与吸收器的低压闪蒸蒸汽入口连接;所述吸收器的内部设置有溴化锂浓溶液,溴化锂吸收式热泵机组通过吸收器上设置的冷水入口与第一管道连接,吸收器的溴化锂溶液入口与再生器的溴化锂溶液出口连接,吸收器的溴化锂溶液出口通过连接的第三管道与再生器的溴化锂溶液入口连接,吸收器的热水出口与冷凝器的热水入口连接;所述再生器的驱动蒸汽入口通过连接的驱动蒸汽接入管道连接有高温热源,再生器的溴化锂溶液蒸发二次蒸汽出口与冷凝器的蒸发二次蒸汽入口连接;所述溴化锂吸收式热泵机组的热水出口设置在冷凝器上,冷凝器的二次蒸汽凝结水出口与蒸发器的二次蒸汽凝结水入口连接。Preferably, the lithium bromide absorption heat pump unit includes an evaporator, an absorber, a regenerator and a condenser; the waste heat inlet of the lithium bromide absorption heat pump unit is arranged on the evaporator, and the low pressure flash steam outlet of the evaporator is connected to the absorber. The low-pressure flash steam inlet of the absorber is connected; the inside of the absorber is provided with lithium bromide concentrated solution, the lithium bromide absorption heat pump unit is connected with the first pipeline through the cold water inlet set on the absorber, and the lithium bromide solution inlet of the absorber is connected with the lithium bromide solution of the regenerator. The solution outlet is connected, the lithium bromide solution outlet of the absorber is connected with the lithium bromide solution inlet of the regenerator through the connected third pipeline, and the hot water outlet of the absorber is connected with the hot water inlet of the condenser; the driving steam inlet of the regenerator is connected by connecting The driving steam access pipeline is connected with a high temperature heat source, and the lithium bromide solution evaporation secondary steam outlet of the regenerator is connected with the evaporation secondary steam inlet of the condenser; the hot water outlet of the lithium bromide absorption heat pump unit is arranged on the condenser, and the condensation The secondary steam condensed water outlet of the evaporator is connected with the secondary steam condensed water inlet of the evaporator.
优选的,所述蒸发器的乏汽凝结水出口和再生器的驱动蒸汽凝结水出口分别通过连接的乏汽凝结水出液管道和驱动蒸汽凝结水出液管道连接有凝结水箱。Preferably, the exhaust steam condensate outlet of the evaporator and the driving steam condensate water outlet of the regenerator are respectively connected to a condensate tank through the connected exhaust steam condensate liquid outlet pipe and driving steam condensate liquid outlet pipe.
优选的,所述吸收器与再生器之间连接的第三管道上设置有用于将吸收器中的溴化锂稀溶液输送达再生器的溴化锂溶液循环泵,溴化锂溶液循环泵的受控端连接PLC控制器的输出端。Preferably, a lithium bromide solution circulating pump for transporting the dilute lithium bromide solution in the absorber to the regenerator is provided on the third pipeline connected between the absorber and the regenerator, and the controlled end of the lithium bromide solution circulating pump is connected to PLC control output of the device.
优选的,所述高温热源的受控端与PLC控制器的输出端连接。Preferably, the controlled end of the high temperature heat source is connected to the output end of the PLC controller.
优选的,所述第一管道上设置有用于控制第一管道通断的第三电磁阀和用于将蒸发装置V效出液泵入溴化锂吸收式热泵机组的母液加压泵,第三电磁阀和母液加压泵的受控端均连接PLC控制器的输出端。Preferably, the first pipeline is provided with a third solenoid valve for controlling the on-off of the first pipeline and a mother liquor pressurizing pump for pumping the V-effect effluent of the evaporation device into the lithium bromide absorption heat pump unit. The third solenoid valve Both the controlled end of the mother liquor pressurizing pump are connected to the output end of the PLC controller.
优选的,所述第二管道上设置有用于控制第二管道通断的第二电磁阀,第二电磁阀的受控端连接PLC控制器的输出端。Preferably, the second pipeline is provided with a second solenoid valve for controlling the on-off of the second pipeline, and the controlled end of the second solenoid valve is connected to the output end of the PLC controller.
由于采用了以上技术方案,本实用新型所取得技术进步如下。Due to the adoption of the above technical solutions, the technical progress achieved by the present utility model is as follows.
本实用新型采用溴化锂吸收式热泵机组,回收氧化铝企业蒸发工序VI效乏汽余热,为蒸发装置V效出液升温,使得蒸发装置V效出液输送到母液槽的物料温度达到95℃左右,不仅节省了下一道工序的新蒸汽用量,还可以降低蒸发装置VI效乏汽冷凝过程中水和电的消耗。The utility model adopts a lithium bromide absorption heat pump unit to recover the waste heat of the V-effect exhausted steam in the evaporation process of the alumina enterprise, and heat up the V-effect effluent of the evaporation device, so that the temperature of the material transported to the mother liquor tank by the V-effect effluent of the evaporation device reaches about 95 DEG C. It not only saves the consumption of new steam in the next process, but also reduces the consumption of water and electricity in the condensation process of the VI effect of the evaporation device.
附图说明Description of drawings
图1为本实用新型的结构示意图;Fig. 1 is the structural representation of the utility model;
图2为本实用新型的溴化锂吸收式热泵机组对蒸发装置V效出液升温工艺流程图。Fig. 2 is a flow chart of the heating process of the V-effect effluent of the evaporation device by the lithium bromide absorption heat pump unit of the present invention.
其中:1.溴化锂吸收式热泵机组、11.蒸发器、12.乏汽接入管道、13.乏汽凝结水出液管道、14.吸收器、15.再生器、16.驱动蒸汽接入管道、17.驱动蒸汽凝结水出液管道、18.冷凝器、19.溴化锂溶液循环泵、2.母液加压泵、3.第一管道、4.第二管道、5.母液总管、6.蒸发装置VI效乏汽、7.凝结水箱、8.驱动蒸汽源、9.母液槽。Among them: 1. Lithium bromide absorption heat pump unit, 11. Evaporator, 12. Spent steam access pipeline, 13. Spent steam condensate outlet pipeline, 14. Absorber, 15. Regenerator, 16. Drive steam access pipeline , 17. Drive steam condensate water outlet pipeline, 18. Condenser, 19. Lithium bromide solution circulation pump, 2. Mother liquor pressurization pump, 3. First pipeline, 4. Second pipeline, 5. Mother liquor main pipe, 6. Evaporation Device VI is exhausted steam, 7. Condensate tank, 8. Drive steam source, 9. Mother liquor tank.
具体实施方式Detailed ways
下面将结合附图和具体实施方式对本实用新型进行进一步详细说明。The present utility model will be described in further detail below with reference to the accompanying drawings and specific embodiments.
一种利用氧化铝蒸发工序余热加热循环母液的装置,结合图1所示,包括母液槽9和PLC控制器,其中,母液槽9的入口连通有母液总管5,母液总管5上连通有第一管道3,母液总管5的出口端设置有温度传感器;PLC控制器的输入端连接温度传感器的输出端,PLC控制器用于对流入母液槽9的母液温度进行控制。A device for utilizing the waste heat of the alumina evaporation process to heat the circulating mother liquor, as shown in FIG. 1 , comprising a
母液总管5的入口端连接有蒸发装置V效出液口,从而对蒸发装置V效出液进行输送。第一管道3连接有溴化锂吸收式热泵机组1。溴化锂吸收式热泵机组1是以热能为补偿实现从低温向高温输送热量的设备,是一种回收余热的节能设备,可广泛吸收10—60℃低温余热,制取100℃以下的水或物料,满足工艺用热需求。The inlet end of the mother liquor main pipe 5 is connected with the V-effect liquid outlet of the evaporation device, so as to transport the V-effect liquid of the evaporation device. The
溴化锂吸收式热泵机组1为吸热式热泵机组,如图2所示,包括蒸发器11、吸收器14、再生器15和冷凝器18,其中,蒸发器11内为抽真空状态,蒸发器11的余热进口作为溴化锂吸收式热泵机组1的余热进口,并通过连接的乏汽接入管道12连接有蒸发装置VI效乏汽6;蒸发器11的低压闪蒸蒸汽出口与吸收器14的低压闪蒸蒸汽入口连接;蒸发器11的乏汽凝结水出口通过连接的乏汽凝结水出液管道13连接有凝结水箱7。The lithium bromide absorption
吸收器14的内部设置有溴化锂浓溶液;吸收器14上设置的冷水入口作为溴化锂吸收式热泵机组1的冷水入口与第一管道3连接,第一管道3上设置有母液加压泵2,母液加压泵2用于将母液总管5内的蒸发装置V效出液泵入溴化锂吸收式热泵机组1,母液加压泵2受控端连接PLC控制器的输出端;吸收器14的溴化锂溶液入口与再生器15的溴化锂溶液出口连接;吸收器14的溴化锂溶液出口通过连接的第三管道与再生器15的溴化锂溶液入口连接,第三管道上设置有溴化锂溶液循环泵19,溴化锂溶液循环泵19用于将吸收器14中的溴化锂稀溶液输送达再生器15,溴化锂溶液循环泵19的受控端连接PLC控制器的输出端;吸收器14的热水出口与冷凝器18的热水入口连接。The inside of the
再生器15的驱动蒸汽入口通过连接的驱动蒸汽接入管道16连接有高温热源,本次实施例选用驱动蒸汽源8作为高温热源,高温热源的受控端与PLC控制器的输出端连接;再生器15的溴化锂溶液蒸发二次蒸汽出口与冷凝器18的溴化锂溶液蒸发二次蒸汽入口连接;再生器15的驱动蒸汽凝结水出口通过连接的驱动蒸汽凝结水出液管道17也与凝结水箱7连接。The driving steam inlet of the
冷凝器18的热水出口作为溴化锂吸收式热泵机组1的热水出口,并通过连通的第二管道4与母液总管5连通;冷凝器18的二次蒸汽凝结水出口与吸收器14的二次蒸汽凝结水入口连接。The hot water outlet of the
在使用时,蒸发器11中的水在低压下蒸发吸收蒸发装置VI效乏汽6热量以较低的温度闪蒸为蒸汽,蒸发装置VI效乏汽6形成凝结水送到凝结水箱7,为其他工作或用户用;产生的低压闪蒸蒸汽进入到吸收器14中与溴化锂浓溶液混合,溴化锂浓溶液变为溴化锂稀溶液,并释放热量,对进入吸收器14换热器的蒸发装置V效出液进行一次加热,一次加热后的蒸发装置V效出液进入到冷凝器18换热器;溴化锂溶液循环泵19将吸收器14中的溴化锂稀溶液输送达再生器15,进入再生器15的溴化锂稀溶液被进入再生器15换热器中的驱动蒸汽源8加热,再生器15中的溴化锂稀溶液蒸发浓缩变为溴化锂浓溶液回流到吸收器14,再生器15中溴化锂溶液蒸发二次蒸汽进入冷凝器18,驱动蒸汽源8成为凝结水送到凝结水箱7;冷凝器18中的溴化锂溶液蒸发二次蒸汽对从吸收器14换热器进入冷凝器18换热器的蒸发装置V效出液进行二次加热后,将蒸发装置V效出液通过第二管道4送到母液总管5,最终送到母液槽9;溴化锂溶液蒸发二次蒸汽成为凝结水,进入蒸发器11。When in use, the water in the
母液总管5上设置有第一电磁阀,第一电磁阀用于控制母液总管5的通断,第一电磁阀的受控端连接PLC控制器的输出端。The mother liquor main pipe 5 is provided with a first solenoid valve, the first solenoid valve is used to control the on-off of the mother liquid main pipe 5, and the controlled end of the first solenoid valve is connected to the output end of the PLC controller.
第一管道3位于第一电磁阀的前方,第一管道3上设置有第三电磁阀,第三电磁阀用于控制第一管道3的通断,第三电磁阀的受控端连接PLC控制器的输出端。The
第二管道4位于第一电磁阀的后方,第二管道4上设置有第二电磁阀,第二电磁阀用于控制第二管道4的通断,第二电磁阀的受控端连接PLC控制器的输出端。The
PLC控制器根据温度传感器来监测流入母液槽9的蒸发装置V效出液温度,通过调节母液加压泵2、驱动蒸汽源8、溴化锂溶液循环泵19来控制利用蒸汽驱动吸收蒸发装置VI效乏汽6热量,加热蒸发装置V效出液,使流入母液槽9的蒸发装置V效出液温度达到95℃左右。The PLC controller monitors the temperature of the evaporating device V that flows into the
本实用新型在使用时,第一电磁阀关闭,第二电磁阀和第三电磁阀打开,母液加压泵2开启将蒸发装置V效出液泵入溴化锂吸收式热泵机组1;溴化锂吸收式热泵机组1利用驱动蒸汽源8驱动吸收连通的蒸发装置VI效乏汽6热量,加热蒸发装置V效出液,使蒸发装置V效出液温度达到95℃左右,不但能对蒸发装置VI效乏汽6热能进行回收利用,节省下一道工序的新蒸汽用量,还可以降低蒸发装置VI效乏汽6冷凝过程中水、电的消耗。When the utility model is in use, the first solenoid valve is closed, the second solenoid valve and the third solenoid valve are opened, the mother
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