CN212127920U - Skid-mounted movable treatment device for waste liquid and produced water in oil field comprehensive operation - Google Patents

Skid-mounted movable treatment device for waste liquid and produced water in oil field comprehensive operation Download PDF

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CN212127920U
CN212127920U CN202020819431.1U CN202020819431U CN212127920U CN 212127920 U CN212127920 U CN 212127920U CN 202020819431 U CN202020819431 U CN 202020819431U CN 212127920 U CN212127920 U CN 212127920U
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pump
pipeline
waste liquid
micro
reactor
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陆涛
陈鲁宁
劳伟
杜长玉
宫传奇
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Shandong Defengtai Environmental Protection Energy Co ltd
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Abstract

The utility model provides an oil field integrated operation waste liquid, extraction water sled dress portable treatment device relates to oil field technical field. This portable processing apparatus of oil field integrated operation waste liquid, extraction water sled dress, including first booster pump, first elevator pump, cold plasma hydroxyl radical generator, pressurization mixing reactor, advanced oxidation deoiling gel breaking reactor, catalytic oxidation filler, charge device, second elevator pump, vortex reactor, micro-nano air supporting device, micro-nano bubble pump, nitrogen generator, second booster pump, many first compound filter equipment, backwash pump and electrical apparatus instrument control room. The device has the advantages of simple treatment method, low operating cost, convenient equipment processing and transportation, no limitation of water quantity and field conditions, strong practicability, no filler replacement in the waste liquid treatment process, strong impact resistance of the equipment, low maintenance frequency and stable effluent quality, and the treated water can be recycled in the cleaning industry, thereby saving the civil engineering part.

Description

Skid-mounted movable treatment device for waste liquid and produced water in oil field comprehensive operation
Technical Field
The utility model relates to an oil field technical field, very special be an oil field comprehensive operation waste liquid, extraction water sled dress portable treatment device.
Background
The refractory waste liquid in the development process of oil and gas fields mainly comprises drilling waste liquid, fracturing flow-back liquid, complex-containing surfactant waste liquid for cleaning oil pipes and oil tanks, polymer-containing waste liquid for tertiary oil recovery, acidified well washing waste liquid, heavy oil produced water, high-salinity oil field produced water and the like, wherein the complex-containing surfactant for cleaning the fracturing flow-back liquid, the oil pipes and the oil tanks is taken as an example, the waste liquid is mainly characterized in that the viscosity of an oil-containing high-molecular polymer is high, the stability of colloid particles in water is strong, and natural degradation is not easy; the waste liquid has high oil content and strong emulsification stability, and oil and water are not easy to separate; belongs to high-difficulty waste water with high oil content, high COD, high turbidity and high mineralization.
Aiming at the difficult-to-degrade waste liquid, the conventional oil removal-air flotation-filtration treatment process is difficult to reach the standard of reinjection, recycling and discharge. Therefore, researchers propose a new treatment method, for example, patent CN 101993177B discloses a treatment method of polymer-containing sewage in oil field, which comprises subjecting the polymer-containing sewage to aerobic degradation by microorganism and then to post-stage filtration treatment; patent CN 103043833 a discloses an electrochemical method for polymer-containing sewage treatment in oil field, which comprises the following steps: performing electric flocculation on the polymer-containing sewage of the oil field to be treated; carrying out oil-water separation on the polymer-containing sewage subjected to electric flocculation to obtain a water phase; then filtering the water phase to realize viscosity reduction of polymer-containing sewage in the oil field; patent CN 103011363B discloses a method for treating polymer-containing sewage in oil field, which comprises the following steps: adding block polyether, nonionic surfactant and ethanol into the polymer-containing sewage of the oil field, and then uniformly mixing to remove oil and purify water of the polymer-containing sewage of the oil field; patent CN 203513352U discloses an ozone air flotation device for treating polymer flooding oily sewage; patent CN 202542914U discloses a sewage preprocessor and sewage preprocessor device, including: a water pipe and an ultrasonic vibration device; patent CN 1686851a discloses a new method for treating oil field sewage, which uses iron in water as oxidation catalyst and coagulant, hydrogen peroxide as preoxidant, and active silicic acid series as coagulant aid. However, these methods also have difficulty in meeting practical production requirements.
The method which is widely applied and has obvious treatment effect is a medicament formula innovation at present, and has great effect on treating the difficult-to-degrade waste liquid. Although some chemicals effectively separate oil and water and remove harmful substances when treating waste liquid, safety problems and side effects are also caused, for example, conventional chemical agents are added into an oil-gas field in the pretreatment process of the waste liquid: although the strong acid, the strong base and the hydrogen peroxide can obviously reduce the viscosity of the waste liquid, ensure subsequent coagulation and precipitation and effectively purify the waste liquid through equipment, the two waste liquids belong to dangerous chemical agents, particularly sulfuric acid, not only have adverse effects on a medicine adding person, but also easily cause safety accidents; in the face of the treatment of waste liquid at a remote wellhead, the transportation is inconvenient; when the dosage of the strong acid is not tightly controlled, equipment corrosion is easily caused. In addition, the commonly used composite formula flocculating agent, coagulant aid and other agents in the oil and gas field can effectively separate suspended matters, oil and the like in the waste liquid, but the conventional separator is configured, such as walnut shell filtration or quartz sand filtration and other equipment, so that the separated harmful substances easily block the filler, and the equipment cleaning and filler replacement frequency is increased; a large amount of chemical agents are required to be added for treating the high-difficulty waste liquid, so that the amount of sludge generated is large, and the subsequent sludge is difficult to treat; when the dosage of the medicament is not properly controlled, certain ions in the water body are increased, and the secondary recycling and reinjection of the waste liquid are directly influenced.
SUMMERY OF THE UTILITY MODEL
The utility model provides a utility model aims to provide an oil field is synthesized operation waste liquid, portable processing device is adorned to extraction water sled, the device processing method is simple, the working costs is low, equipment processing and transportation are convenient, do not receive water yield and site conditions restriction, therefore, the clothes hanger is strong in practicability, the change of no filler among the waste liquid processing process, the shock resistance of equipment is strong, maintenance frequency is low, go out water stable in quality, the reuse of washing trade can be realized to the water after handling, waste liquid utilization has been realized, realize sled dress modularization transportation simple to operate, the civil engineering part has been saved, can customize the product for the user.
In order to achieve the above purpose, the utility model discloses a following technical scheme realizes: a skid-mounted movable treatment device for waste liquid and produced water in oil field comprehensive operation comprises a first booster pump, a first lifting pump, a cold plasma hydroxyl radical generator, a pressurization mixing reactor, an advanced oxidation oil and gel breaking reactor, catalytic oxidation fillers, a dosing device, a second booster pump, a vortex reactor, a micro-nano air flotation device, a micro-nano bubble pump, a nitrogen generator, a second booster pump, a multi-element composite filtering device, a backwashing pump and an electrical instrument control chamber, wherein the first booster pump is connected with the cold plasma hydroxyl radical generator through a pipeline, the first booster pump is connected with the first lifting pump through a pipeline, the first booster pump is connected with the pressurization mixing reactor through a pipeline, the pressurization mixing reactor is connected with the advanced oxidation oil and gel breaking reactor through a pipeline, the advanced oxidation oil and gel breaking reactor is connected with the second lifting pump through a pipeline, the second lifting pump is connected with the micro-nano air floatation device through a pipeline, the micro-nano air floatation device is connected with the second booster pump through a pipeline, the second booster pump is connected with the multi-element composite filtering device through a pipeline, and the backwashing pump is connected with the multi-element composite filtering device through a pipeline.
Further, the micro-nano bubble pump is connected with the micro-nano air flotation device and the second booster pump through a pipeline, the micro-nano bubble pump is connected with the vortex reactor through a pipeline, and the micro-nano bubble pump is connected with the nitrogen generator through a pipeline.
Further, the dosing device is connected with a communication pipeline between the advanced oxidation oil removal gel breaking reactor and the second lift pump through a dosing pipe.
Furthermore, the catalytic oxidation filler is connected with the advanced oxidation oil removal gel breaking reactor through a pipeline.
The utility model provides an oil field comprehensive operation waste liquid, produced water sled dress mobile processing device and application method thereof. The method has the following beneficial effects:
(1) this oil field comprehensive operation waste liquid, produced water sled dress portable treatment device, there is not the packing change at the processing waste liquid in-process, and equipment shock resistance is strong, and the maintenance frequency is low, and play water quality of water is stable.
(2) The skid-mounted movable treatment device for the waste liquid and the produced water in the oil field comprehensive operation can realize the reutilization of the cleaning industry of the treated water, and realizes the resource utilization of the waste liquid.
(3) This oil field comprehensive operation waste liquid, produced water sled dress portable treatment device, there is not the packing change at the processing waste liquid in-process, and equipment shock resistance is strong, and the maintenance frequency is low, and play water quality of water is stable.
(4) This oil field is synthesized operation waste liquid, extraction water sled dress portable treatment device realizes sled dress modularization transportation simple to operate, has saved the civil engineering part, can customize the product for the user.
Drawings
Fig. 1 is a schematic view of the present invention.
In the figure: 1. a first booster pump; 2. a first lift pump; 3. a cold plasma hydroxyl radical generator; 4. a pressurized mixing reactor; 5. an advanced oxidation oil removal gel breaking reactor; 6. a catalytic oxidation filler; 7. a dosing device; 8. a second lift pump; 9. a vortex reactor; 10. a micro-nano air flotation device; 11. a micro-nano bubble pump; 12. a nitrogen generator; 13. a second booster pump; 14. a multi-element composite filter device; 15. a backwash pump; 16. an electric appliance instrument control room.
Detailed Description
The invention will be further explained with reference to the following embodiments and drawings:
example 1: referring to fig. 1, a skid-mounted mobile treatment device for waste liquid and produced water in oil field comprehensive operation comprises a first booster pump 1, a first lift pump 2, a cold plasma hydroxyl radical generator 3, a pressurization mixing reactor 4, an advanced oxidation degreasing gel breaking reactor 5, a catalytic oxidation filler 6, a dosing device 7, a second lift pump 8, a vortex reactor 9, a micro-nano air flotation device 10, a micro-nano bubble pump 11, a nitrogen generator 12, a second booster pump 13, a multi-element composite filtering device 14, a backwashing pump 15 and an electrical instrument control chamber 16, wherein the first booster pump 1 is connected with the cold plasma hydroxyl radical generator 3 through a pipeline, the first booster pump 1 is connected with the first lift pump 2 through a pipeline, the first booster pump 1 is connected with the pressurization mixing reactor 4 through a pipeline, the pressurization mixing reactor 4 is connected with the advanced oxidation degreasing gel breaking reactor 5 through a pipeline, the advanced oxidation oil-removal gel-breaking reactor 5 is connected with a second lifting pump 8 through a pipeline, the second lifting pump 8 is connected with a micro-nano air flotation device 10 through a pipeline, the micro-nano air flotation device 10 is connected with a second booster pump 13 through a pipeline, the second booster pump 13 is connected with a multi-element composite filter device 14 through a pipeline, a backwashing pump 15 is connected with the multi-element composite filter device 14 through a pipeline, a micro-nano bubble pump 11 is connected with the micro-nano air flotation device 10 and the second booster pump 13 through a pipeline, the micro-nano bubble pump 11 is connected with a vortex reactor 9 through a pipeline, the micro-nano bubble pump 11 is connected with a nitrogen generator 12 through a pipeline, a dosing device 7 is connected with a communicating pipeline between the advanced oxidation oil-removal gel-breaking reactor 5 and the second lifting pump 8 through a dosing pipe, a catalytic oxidation filler 6 is connected with the advanced oxidation oil-removal gel-breaking reactor 5 through a pipeline, wastewater is, in the process, hydroxyl radicals generated by a cold plasma hydroxyl radical generator 3 are injected into waste liquid, the waste liquid enters a pressurized mixing reactor 4, part of the waste liquid is lifted to an advanced oxidation oil removal and gel breaking reactor 5 by a first lifting pump 2, the waste liquid is subjected to advanced oxidation catalytic reaction in catalytic filler, the waste liquid is subjected to oil removal catalytic oxidation reaction, then a medicament is added by a medicament adding device 7 and lifted to a micro-nano bubble pump 10 by a second lifting pump 8, micro-nano bubbles generated by the micro-nano bubble pump 10 in micro-nano air floatation equipment are subjected to mixed reaction of treated waste water, micro-nano bubbles, the medicament and the like in a vortex reactor 9, then the mixed reaction enters a micro-nano air floatation device to complete the separation of the waste water and impurities, the mixed reaction is lifted to a multi-element composite filtering device 14 by a second booster pump 13 after micro-nano air floatation purification, the filtered waste liquid reaches the standard, and pollutants intercepted by the multi, the whole skid-mounted device electric control is controlled by an electric instrument control room 16.
And the processing amount is less than or equal to 600m for plantation/d, the whole process equipment can be designed into a skid-mounted room with L, B, H, 12, 3 and 3m, and the integration degree is high.
And the processing amount is less than or equal to 3000m for carrying out the year/d, the whole process equipment can be designed into two skid-mounted rooms with the length of L, B, H, 12, 3 and 3m, and the integration degree is high.
Specifically, the utility model discloses when using:
s1, putting the fracturing flow-back fluid, oilfield produced water, oil tank and oil pipe cleaning waste liquid and oily sewage into an advanced oxidation oil removal gel breaking reactor 5, treating the waste liquid under the catalysis of copper activated carbon under the condition that a cold plasma hydroxyl radical generator 3 generates hydroxyl radicals and the waste liquid is pressurized and mixed, lifting the waste water to the advanced oxidation oil removal gel breaking reactor 5 by a first lifting pump 2, dissolving the hydroxyl radicals generated by the cold plasma by a dissolving pump through the cold plasma hydroxyl radical generator 3, then putting the waste liquid into a pressurized reaction tank, and releasing the waste liquid into a copper-loaded activated carbon reactor after the waste liquid is pressurized into a pressurized mixing reactor 4 through a first booster pump 1 for 10min-30min, such as 10min, 15 min, 20 min, 25 min or 30min, wherein the devices used for the catalytic oxidation treatment are respectively a cold plasma hydroxyl radical generator 3, a pressure mixing reactor 4 and the like, A negative pressure dissolving and mixing pump and a pressurizing and mixing reactor 4, the amount of hydroxyl free radicals generated by cold plasma is not less than 50g/min, such as 55 g/min, 65 g/min, 75 g/min, 90 g/min or 100 g/min, the hydroxyl free radicals generated by cold plasma are pressurized, mixed and released with wastewater in the catalytic oxidation copper-carrying activated carbon, the emulsification structure in the wastewater is broken, the emulsion breaking in the emulsification state is realized, meanwhile, the macromolecular chain is broken, the viscosity of the wastewater is rapidly reduced, oil beads are easier to separate from water and float, the recovery of floating oil is realized, S2, the water which is obtained by pressurizing and mixing the hydroxyl free radicals generated by cold plasma with the wastewater after the catalytic oxidation treatment of the copper-carrying activated carbon is subjected to micro-nano air flotation and multi-component composite filtration treatment, the micro-nano air flotation and multi-component filtration treatment is realized by adding a composite flocculant, The composite flocculant is selected from polyaluminium chloride, polyaluminium ferric chloride silicate and a mixture compounded at high temperature, the water scavenger is of a nano structure and is selected from diatomite, bentonite and natural aluminum ore powder, the flotation agent is selected from one or a mixture of at least two of polyacrylamide, cationic polyacrylamide or anionic polyacrylamide, the dosage of the composite flocculant is 100-500mg/L, such as 120 mg/L, 200mg/L, 260 mg/L, 300 mg/L, 380 mg/L, 420 m, 460 mg/L or 500mg/L, the dosage of the water scavenger is 100-200mg/L, such as 105 mg/L, 130 mg/L, 150mg/L, 180 mg/L or 200mg/L, and the dosage of the flotation agent is 1-10mg/L, if 2 mg/L, 6 mg/L, 8 mg/L or 10mg/L, the water after air floatation treatment enters the multi-element composite filtering device 14 through the pressurization of the first lifting pump 2, and a multi-element composite filtering material is used as a filtering medium, so that suspended matters, organic matters, colloidal particles, oil and partial heavy metal ion substances in the water are effectively intercepted and removed; the composite flocculant is preferably compounded by polyaluminium chloride, the aged solution has colloid charges, and has extremely strong adsorption and electrical neutrality on suspended matters in water, the product is superior to a conventional single flocculant, the sludge yield is low, the flotation agent is preferably modified polyacrylamide, and the flotation agent has a strong bridging effect, changes fine dispersed flocs into dense and large alum flocs which are combined with micro-nano bubbles and the flocs to facilitate the separation of pollutants in waste liquid, the waste liquid and the medicament are mixed by a mixer and a pump impeller and enter a micro-nano air floatation system, an air floatation dissolved air source is high-purity nitrogen sucked from negative pressure, and air floatation purified water is obtained by taking gas generated by dissolving a large amount of nitrogen making devices into working liquid under high pressure, enters a dissolved air tank and releases countless micro-fine bubbles (the diameters of the bubbles are respectively 10-20 micrometers) and impurities in water after the mixing reaction when the pressure is suddenly reduced, The agent is adhered together, the foam (i.e. gas, water and particle) three-phase mixture makes the specific gravity of the floc less than 1, and floats on the liquid surface, so that the pollutants are separated from the wastewater to achieve the purification effect, the water after air floatation treatment is pressurized by a first lifting pump 2 and enters a multi-element composite filtering device 14, a multi-element composite filtering material is used as a filtering medium to effectively intercept and remove suspended matters, organic matters, colloidal particles, oil, partial heavy metal ions and the like in the water, and finally the high-efficiency filtering equipment with the effects of reducing water turbidity and purifying water quality is achieved, the water quality of the effluent can reach the oilfield reinjection water standard or enter the micro-nano pretreatment of a microbiological treatment system, S3, air floatation and multi-element composite filtering treatment are carried out to obtain the standard which accords with the oilfield reinjection water, the effluent can reach the discharge standard through a BAF biological filter tank, and the fracturing backflow liquid after gel breaking, oil COD reduction, advanced oxidation, After the cleaning waste liquid of the oilfield produced water, the oil tank and the oil pipe is treated, the toxic and harmful substances with macromolecules are oxidized into short-chain micromolecule structures which are easily degraded by microorganisms, and the integrated BAF microorganism filter tank meets the requirement that COD (chemical oxygen demand) ammonia nitrogen and the like in the water can be directly discharged to a municipal sewage pipe network or directly discharged after reaching the standard after the waste liquid is treated by jointly degrading COD ammonia nitrogen and the like in the water through aerobic microorganisms and anoxic microorganisms in microorganism carriers.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, many modifications and improvements can be made without departing from the inventive concept, and all of them belong to the protection scope of the present invention.

Claims (4)

1. The utility model provides an oil field integrated operation waste liquid, portable processing apparatus is adorned to extraction water sled, including first booster pump (1), first elevator pump (2), cold plasma hydroxyl radical generator (3), pressurization mixing reactor (4), advanced oxidation deoiling gel breaking reactor (5), catalytic oxidation packs (6), charge device (7), second elevator pump (8), vortex reactor (9), micro-nano air supporting device (10), micro-nano bubble pump (11), nitrogen generator (12), second booster pump (13), many compound filter equipment (14), backwash pump (15) and electrical apparatus instrument control room (16), its characterized in that: the first booster pump (1) is connected with the cold plasma hydroxyl radical generator (3) through a pipeline, the first booster pump (1) is connected with the first lifting pump (2) through a pipeline, the first booster pump (1) is connected with the pressurizing mixing reactor (4) through a pipeline, the pressurized mixing reactor (4) is connected with the advanced oxidation oil removal gel breaking reactor (5) through a pipeline, the advanced oxidation oil removal gel breaking reactor (5) is connected with a second lift pump (8) through a pipeline, the second lift pump (8) is connected with the micro-nano air floatation device (10) through a pipeline, the micro-nano air flotation device (10) is connected with a second booster pump (13) through a pipeline, the second booster pump (13) is connected with the multi-element composite filtering device (14) through a pipeline, the backwashing pump (15) is connected with the multi-element composite filtering device (14) through a pipeline.
2. The skid-mounted movable treatment device for the waste liquid and the produced water in the oil field comprehensive operation of claim 1, which is characterized in that: micro-nano bubble pump (11) are connected with micro-nano air supporting device (10) and second booster pump (13) through the pipeline, micro-nano bubble pump (11) are connected with vortex reactor (9) through the pipeline, micro-nano bubble pump (11) are connected with nitrogen generator (12) through the pipeline.
3. The skid-mounted movable treatment device for the waste liquid and the produced water in the oil field comprehensive operation of claim 1, which is characterized in that: the dosing device (7) is connected with a communication pipeline between the advanced oxidation oil removal gel breaking reactor (5) and the second lifting pump (8) through a dosing pipe.
4. The skid-mounted movable treatment device for the waste liquid and the produced water in the oil field comprehensive operation of claim 1, which is characterized in that: the catalytic oxidation filler (6) is connected with the advanced oxidation oil removal gel breaking reactor (5) through a pipeline.
CN202020819431.1U 2020-05-18 2020-05-18 Skid-mounted movable treatment device for waste liquid and produced water in oil field comprehensive operation Active CN212127920U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114314959A (en) * 2022-01-18 2022-04-12 中国矿业大学 Shale gas fracturing flowback fluid treatment method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114314959A (en) * 2022-01-18 2022-04-12 中国矿业大学 Shale gas fracturing flowback fluid treatment method
CN114314959B (en) * 2022-01-18 2023-06-30 中国矿业大学 Shale gas fracturing flowback fluid treatment method

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