CN211920999U - Recovery system of ammonia nitrogen resource in biogas slurry - Google Patents
Recovery system of ammonia nitrogen resource in biogas slurry Download PDFInfo
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- CN211920999U CN211920999U CN202020157566.6U CN202020157566U CN211920999U CN 211920999 U CN211920999 U CN 211920999U CN 202020157566 U CN202020157566 U CN 202020157566U CN 211920999 U CN211920999 U CN 211920999U
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Abstract
The utility model discloses a recovery system of ammonia nitrogen resource in natural pond liquid, recovery system includes: the reaction tank is used for loading biogas slurry; the ammonia nitrogen collecting tank is used for loading an ammonia nitrogen extracting agent and the extracting agent after ammonia nitrogen recovery; the hydrophobic membrane reaction absorption tube is used for enabling the ammonia nitrogen extracting agent to react with ammonia nitrogen in the biogas slurry and extracting the ammonia nitrogen; the peristaltic pump is used for conveying the ammonia nitrogen extracting agent in the ammonia nitrogen collecting tank to the hydrophobic membrane reaction absorption pipe; and a micro aeration pump for aerating the inside of the reaction tank. According to the utility model discloses a recovery system is under the common drive of natural pond liquid and extractant both ends ammonia nitrogen concentration gradient and micro-aeration, and the ammonia nitrogen resource in the natural pond liquid is deviate from with gaseous ammonia molecular form, sees through hydrophobic membrane wall and extractant reaction formation ammonium salt. Can realize the quick recovery of ammonia nitrogen in the natural pond liquid with high efficiency, has no membrane pollution risk, and the nitrogen element of retrieving exists in the form of liquid ammonium salt, can direct resource utilization.
Description
Technical Field
The utility model belongs to the chemical industry field particularly, relates to a recovery system of ammonia nitrogen resource in natural pond liquid, and this recovery system adopts hydrophobic membrane tubular product, utilizes ammonia nitrogen extraction agent, has realized extracting of ammonia nitrogen resource in natural pond liquid effectively.
Background
The nitrogen recovery of the biogas slurry is an important content of high-added-value development and treatment of the biogas slurry, and nitrogen resources of the biogas slurry are recovered through corresponding technical measures, so that a product with high added value is obtained, and the economic benefit is improved. The prior art mainly comprises a precipitation method, a membrane concentration method, an adsorption method, a biological absorption method and the like.
Wherein the precipitation method is struvite precipitation method, which recovers nitrogen and phosphorus in the sewage to form magnesium ammonium phosphate (MgNH)4PO4·6H2O, MAP, commonly known as struvite). However, the ratio of nitrogen to phosphate in the biogas slurry is not balanced, and the struvite precipitation method is usually used for recovering nitrogen and phosphorus in the biogas slurry by adding magnesium salt and hydrate thereof as magnesium source, adding phosphate and hydrate thereof as phosphorus source and regulating Mg2+、NH4 +、PO4 3-The ion ratio realizes nitrogen recovery, the process is more complicated, the dosage of the medicament is increased along with the improvement of nitrogen and phosphorus concentration of the biogas slurry, the cost is not easy to control, in addition, other anions and cations are added along with the medicament, and adverse effects may exist on the subsequent treatment or utilization of the liquid phase part of the biogas slurry after nitrogen recovery.
The membrane concentration method is a technique of filtering, separating and concentrating particles, molecules or ions in water under the action of a driving force by utilizing the permeability of a membrane. In the aspect of wastewater treatment, the membrane concentration technology is mainly used for treatment of industrial wastewater, treatment of drinking water, preparation of ultrapure water and sterile water. However, the method for recovering nutrients in the biogas slurry still has the following problems: 1) membrane fouling, which makes it difficult to enable long-term, sustainable operation of the membrane; 2) the biogas slurry treatment is high in investment and production cost in the early stage and difficult to industrialize.
The adsorption method is to utilize some porous media with affinity to nitrogen and phosphorus or media with large specific surface area to realize the adsorption of nitrogen and phosphorus, so as to separate nitrogen and phosphorus from sewage, and then make the adsorbed nitrogen and phosphorus enter the solution again through a desorbent to form a high-nitrogen and phosphorus solution. However, the adsorption method has problems that the adsorption efficiency is low, it is necessary to develop an adsorbent having a high efficiency and a low cost, and the regeneration of the adsorbate after the adsorption saturation or how to reuse the nitrogen may further increase the cost and the nitrogen loss.
The biological absorption method uses the biogas slurry to culture algae, can remove eutrophic elements such as nitrogen, phosphorus and the like in the biogas slurry, and can be reused in the form of biomass energy of algae cells, thereby achieving the purpose of resource utilization of waste. However, the dependence of the biological absorption process on natural conditions such as illumination, temperature and the like is strong, and the recovery efficiency is often limited; the realization of biological absorption of nitrogen and phosphorus recycling often needs subsequent further treatment; in addition, algae also has strong biological enrichment capacity on a plurality of heavy metals, and the existence of the heavy metals influences the economic development of algae cells.
Therefore, a more efficient biogas slurry treatment method is still needed to be developed so as to effectively recover eutrophic elements such as nitrogen and phosphorus in the biogas slurry.
SUMMERY OF THE UTILITY MODEL
To the problem that above-mentioned prior art exists, according to the utility model discloses an aspect, an object of the utility model is to provide a recovery system of ammonia nitrogen resource in natural pond liquid, recovery system includes:
the reaction tank is used for loading biogas slurry, and is provided with a stock solution injection port and a treatment solution discharge port, wherein the stock solution injection port is used for injecting the biogas slurry, and the treatment solution discharge port is used for discharging the biogas slurry after the reaction is finished;
the ammonia nitrogen collecting tank is used for loading an ammonia nitrogen extracting agent and the extracting agent after ammonia nitrogen recovery;
the system comprises a reaction tank, a hydrophobic membrane reaction absorption pipe, a nitrogen-containing gas-liquid separation pipe and a nitrogen-containing gas-liquid separation pipe, wherein the hydrophobic membrane reaction absorption pipe is arranged in the reaction tank, is immersed in the biogas slurry in the reaction tank and is used for enabling an ammonia nitrogen extracting agent to react with ammonia nitrogen in the biogas slurry and extract the ammonia nitrogen;
one end of the peristaltic pump extends into the ammonia nitrogen collecting tank through a pipeline, and the other end of the peristaltic pump is connected with the inlet end of the hydrophobic membrane reaction absorption tube and is used for conveying the ammonia nitrogen extractant in the ammonia nitrogen collecting tank to the hydrophobic membrane reaction absorption tube;
and the micro aeration pump is connected with an aeration head arranged in the reaction tank through a pipeline and is used for aerating the reaction tank.
Preferably, the ammonia nitrogen collecting tank is provided with an exhaust hole for adjusting the air pressure of the ammonia nitrogen collecting tank.
Preferably, the hydrophobic membrane reaction absorption tube may be selected from a polytetrafluoroethylene membrane material tube.
Advantageous effects
According to the utility model discloses a recovery system is under the common drive of natural pond liquid and extractant both ends ammonia nitrogen concentration gradient and little aeration, and the dirty natural pond liquid ammonia nitrogen of beasts and birds excrement is deviate from with gaseous ammonia molecular form, sees through hydrophobic membrane wall and extractant reaction formation ammonium salt. Can realize the quick recovery of ammonia nitrogen in the natural pond liquid with high efficiency, has no membrane pollution risk, and the nitrogen element of retrieving exists in the form of liquid ammonium salt, can direct resource utilization.
Drawings
Figure 1 is according to the utility model discloses a natural pond liquid ammonia nitrogen recovery system's schematic structure.
Figure 2 shows the ammonia nitrogen content of the extractant as a function of time in the recovery process using the recovery system of the invention in example 1 and comparative example 1.
Figure 3 shows the ammonia nitrogen content of the extractant as a function of time in the recovery process using the recovery system of the invention in example 2 and comparative example 2.
Reference numerals
1-a reaction tank, 2-an ammonia nitrogen collecting tank, 3-a hydrophobic membrane reaction absorption tube, 4-a micro aeration pump, 5-an aeration head, 6-a peristaltic pump, 7, 8-exhaust holes, 9-a stock solution filling opening and 10-a treatment solution discharge opening.
Detailed Description
Hereinafter, preferred embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. Before the description, it should be understood that the terms used in the specification and the appended claims should not be construed as limited to general and dictionary meanings, but interpreted based on the meanings and concepts corresponding to technical aspects of the present invention on the basis of the principle that the inventor is allowed to define terms appropriately for the best explanation. Accordingly, the description herein is intended as a preferred example for the purpose of illustration only and is not intended to limit the scope of the present invention, so it should be understood that other equivalent implementations and modifications could be made without departing from the spirit and scope of the present invention.
For the purpose of illustrating the present invention, portions that are not relevant to the description are omitted in the drawings, and the same or similar components are denoted by the same reference numerals throughout the specification.
In addition, the size and thickness of each component shown in the drawings are arbitrarily illustrated for convenience of explanation, and thus the present invention is not necessarily limited to those illustrated in the drawings.
Throughout the specification, when an element is referred to as being "connected" to another element, it includes not only "direct connection" but also "indirect connection" between other members. In addition, when an element is referred to as "comprising" a component, it means that the element may further comprise other components rather than excluding other components, unless expressly stated to the contrary.
The terms "first", "second", and the like, as used herein are used to explain various constituent elements, and they are used only for the purpose of distinguishing one constituent element from another constituent element.
Also, the terminology used herein is for the purpose of describing example embodiments only and is not intended to be limiting of the invention. Singular references also include plural references unless the context clearly dictates otherwise. Terms such as "comprising," "including," or "having," as used herein, are used to specify the presence of stated features, numbers, steps, components, or combinations thereof, and should be understood not to preclude the addition or presence of one or more other features, numbers, steps, components, or combinations thereof.
Also, if a layer or an element is referred to as being formed "on" or "over" a layer or an element, it means that each layer or element is directly formed on the layer or element, or other layers or elements may be formed between layers, bodies, or substrates.
The technical solution of the present invention will be described in detail with reference to fig. 1.
According to the utility model discloses a recovery system of ammonia nitrogen resource in natural pond liquid includes:
the reaction tank 1 is used for loading biogas slurry, and the reaction tank 1 is provided with a stock solution injection port 9 and a treatment solution discharge port 10 which are respectively used for injecting the biogas slurry and discharging the reacted biogas slurry. In addition, the reaction tank 1 can be designed in a sealing manner and is provided with an exhaust hole 7, and the exhaust hole 7 enables part of overflowed ammonia nitrogen and other gases in the reaction process of the air or the biogas slurry in the reaction tank 1 to enter the ammonia nitrogen collecting tank 2 from the reaction tank 1 through an exhaust pipe, so that ammonia nitrogen resources in the biogas slurry can be recovered to the maximum extent and the pressure in the reaction tank 1 can be adjusted to be kept within a reasonable range.
And the ammonia nitrogen collecting tank 2 is used for loading an ammonia nitrogen extracting agent and the extracting agent after ammonia nitrogen recovery.
The device comprises a hydrophobic membrane reaction and absorption pipe 3, wherein the hydrophobic membrane reaction and absorption pipe 3 is arranged in the reaction tank 1, is immersed in biogas slurry in the reaction tank 1 and is used for enabling an ammonia nitrogen extracting agent to react with ammonia nitrogen in the biogas slurry and extracting the ammonia nitrogen, the outlet end of the hydrophobic membrane reaction and absorption pipe 3 is connected with the ammonia nitrogen collecting tank 2 through a pipeline, and the ammonia nitrogen extracting agent flowing through the hydrophobic membrane reaction and absorption pipe 3 returns to the ammonia nitrogen collecting tank 2.
And one end of the peristaltic pump 6 extends into the ammonia nitrogen collecting tank 2 through a pipeline, and the other end of the peristaltic pump 6 is connected with the inlet end of the hydrophobic membrane reaction absorption tube 3 and is used for conveying the ammonia nitrogen extractant in the ammonia nitrogen collecting tank 2 to the hydrophobic membrane reaction absorption tube 7, wherein the peristaltic pump 6 is inserted into a position where the pipeline of the ammonia nitrogen collecting tank 2 extends deeper below the surface of the extractant (liquid) in the ammonia nitrogen collecting tank 2, and the pipeline from the outlet end of the hydrophobic membrane reaction absorption tube 3 extends into the ammonia nitrogen collecting tank 2, so that the end part of the pipeline is immersed below the surface of the extractant, for example, the end part of the pipeline extends below 3-5 cm below the surface of the extractant.
And a micro aeration pump 4, wherein the micro aeration pump 4 is connected with an aeration head 5 arranged in the reaction tank through a pipeline and is used for aerating the reaction tank 1.
Preferably, the reaction tank 1 is provided with an exhaust hole 7, and the exhaust hole 7 is connected to the ammonia nitrogen collecting tank 2 through an exhaust pipe which extends to the position below the surface of the extractant in the ammonia nitrogen collecting tank 2. Through the exhaust pipe, air in the reaction tank 1 or gas such as ammonia nitrogen partially overflowing in the reaction process of the biogas slurry can enter the ammonia nitrogen collecting tank 2 from the reaction tank 1, so that the normal pressure of the reaction tank is ensured, and the ammonia nitrogen in the biogas slurry is recovered to the maximum extent.
Preferably, the ammonia nitrogen collecting tank 2 is provided with an exhaust hole 8 for adjusting the air pressure of the ammonia nitrogen collecting tank 2.
The following examples are given by way of illustration of embodiments of the invention and are not intended to limit the invention, and those skilled in the art will appreciate that modifications within the scope of the invention do not depart from the spirit and scope of the invention. Unless otherwise specified, reagents and equipment used in the following examples are commercially available products.
Example 1: recovery of ammonia nitrogen resource in high ammonia nitrogen content biogas slurry
1) Injecting ammonia nitrogen-rich biogas slurry (the ammonia nitrogen content of the biogas slurry reaches 4416mg/L) into a reaction tank 1 through a stock solution injection port 9 of the reaction tank 1 until the volume of the reaction tank 1 is about 80%, starting a micro aeration pump 4 to aerate the reaction tank 1 at room temperature and normal pressure, filling 0.5mol/L sulfuric acid as an ammonia nitrogen extracting agent into an ammonia nitrogen collecting tank 2, setting the volume ratio of the biogas slurry to the ammonia nitrogen extracting agent to be 5:1, and setting the aeration intensity to be 0.36L/min (micro aeration);
2) starting a peristaltic pump 6 to convey the ammonia nitrogen extractant in the ammonia nitrogen collecting tank 2 to a hydrophobic membrane reaction absorption tube 3 in the reaction tank 1, and enabling the extractant to circularly flow between the biogas slurry reaction tank 1 and the ammonia nitrogen collecting tank 2 at a flow rate of 4 mL/min;
3) enabling an ammonia nitrogen extractant to react with ammonia nitrogen in the biogas slurry through the hydrophobic membrane reaction absorption tube 3 made of polytetrafluoroethylene membrane material to generate ammonia salt, and conveying the ammonia salt into the ammonia nitrogen collecting tank 2 along with the ammonia nitrogen extractant;
4) after the system runs for a period of time at room temperature, discharging the ammonia nitrogen extractant after the pH value of the ammonia nitrogen extractant reaches 7, and simultaneously replacing a new ammonia nitrogen extractant;
5) the discharged ammonia nitrogen extractant is ammonium salt rich in nitrogen, and is directly stored and used as a nutrient required by plant growth.
Comparative example 1:
the recovery treatment was carried out in the same manner as in example 1 except that aeration was not employed.
Figure 2 shows the ammonia nitrogen content of the extractant as a function of time in the recovery process of example 1 and comparative example 1. As a result, according to the utility model discloses a recovery unit and method can realize the recovery of ammonia nitrogen resource in the natural pond liquid of high ammonia nitrogen content, form ammonium salt solution. Under the micro-aeration treatment, after the device runs for 72 hours, the ammonia nitrogen concentration of the extractant reaches over 12000mg/L, and the recovery rate of the ammonia nitrogen is 79-85% (embodiment 1); under the condition of non-aeration treatment, after the device runs for 276h, the ammonia nitrogen concentration of the extractant is close to 12000mg/L, and the ammonia nitrogen recovery rate is about 71 percent (comparative example 1). Compared with the comparative example 1, the method has the advantages that 73.9% of time can be saved when the ammonia nitrogen concentration of the extractant reaches the highest value, and the nitrogen recovery rate of the high ammonia nitrogen biogas slurry can be increased.
Example 2: recovery of ammonia nitrogen resource in low ammonia nitrogen content biogas slurry
1) Injecting low ammonia nitrogen content biogas slurry (the ammonia nitrogen content of the biogas slurry reaches 92.5mg/L) into a reaction tank 1 through a stock solution injection port 9 of the reaction tank 1 until the volume of the reaction tank 1 is about 80%, starting a micro aeration pump 4 to aerate the reaction tank 1 at room temperature and normal pressure, filling 0.5mol/L sulfuric acid as an ammonia nitrogen extracting agent into an ammonia nitrogen collecting tank 2, setting the volume ratio of the biogas slurry to the ammonia nitrogen extracting agent to be 5:1, and setting the aeration intensity to be 0.36L/min (micro aeration);
2) starting a peristaltic pump 6 to convey the ammonia nitrogen extractant in the ammonia nitrogen collecting tank 2 to a hydrophobic membrane reaction absorption tube 3 in the reaction tank 1, and enabling the extractant to circularly flow between the biogas slurry reaction tank 1 and the ammonia nitrogen collecting tank 2 at a flow rate of 4 mL/min;
3) enabling an ammonia nitrogen extractant to react with ammonia nitrogen in the biogas slurry through the hydrophobic membrane reaction absorption tube 3 made of polytetrafluoroethylene membrane material to generate ammonia salt, and conveying the ammonia salt into the ammonia nitrogen collecting tank 2 along with the ammonia nitrogen extractant;
4) after the system runs for a period of time at room temperature, discharging the ammonia nitrogen extractant after the pH value of the ammonia nitrogen extractant reaches 7, and simultaneously replacing a new ammonia nitrogen extractant;
5) the discharged ammonia nitrogen extractant is ammonium salt rich in nitrogen, and is directly stored and used as a nutrient required by plant growth.
Comparative example 2:
the recovery treatment was carried out in the same manner as in example 2 except that aeration was not employed.
Figure 3 shows the ammonia nitrogen content of the extractant as a function of time in the recovery process of example 2 and comparative example 2. As a result, according to the utility model discloses a recovery unit and method can realize the recovery of ammonia nitrogen resource in the natural pond liquid of low ammonia nitrogen content, form ammonium salt solution. Under the micro-aeration treatment, after the device runs for 93.5 hours, the ammonia nitrogen concentration of the extractant reaches 326.3mg/L, and the ammonia nitrogen recovery rate is 73.6 percent (example 2); under the condition of no aeration treatment, the ammonia nitrogen concentration of the extractant reaches the highest value of 86.3mg/L after the device operates for 189.5 hours, and the ammonia nitrogen recovery rate is about 15 percent (comparative example 2). Compared with the comparative example 2, the method has the advantages that 50.7% of time can be saved when the ammonia nitrogen concentration of the extracting agent reaches a high value, the nitrogen recovery rate of the low ammonia nitrogen biogas slurry can be increased, the ammonia nitrogen recovery rate is improved by 58.6%, and the ammonia nitrogen recovery effect is enhanced.
Claims (3)
1. A recovery system of ammonia nitrogen resource in biogas slurry, characterized in that the recovery system comprises:
the reaction tank is used for loading biogas slurry, and is provided with a raw liquid injection port and a treatment liquid discharge port, wherein the injection port is used for injecting the biogas slurry, and the discharge port is used for discharging the biogas slurry after the reaction is finished;
the ammonia nitrogen collecting tank is used for loading an ammonia nitrogen extracting agent and the extracting agent after ammonia nitrogen recovery;
the system comprises a reaction tank, a hydrophobic membrane reaction absorption pipe, a nitrogen-containing gas-liquid separation pipe and a nitrogen-containing gas-liquid separation pipe, wherein the hydrophobic membrane reaction absorption pipe is arranged in the reaction tank, is immersed in the biogas slurry in the reaction tank and is used for enabling an ammonia nitrogen extracting agent to react with ammonia nitrogen in the biogas slurry and extract the ammonia nitrogen;
one end of the peristaltic pump extends into the ammonia nitrogen collecting tank through a pipeline, and the other end of the peristaltic pump is connected with the inlet end of the hydrophobic membrane reaction absorption tube and is used for conveying the ammonia nitrogen extractant in the ammonia nitrogen collecting tank to the hydrophobic membrane reaction absorption tube;
and the micro aeration pump is connected with an aeration head arranged in the reaction tank through a pipeline and is used for aerating the reaction tank.
2. The recycling system according to claim 1, wherein the ammonia nitrogen collecting tank is provided with an exhaust hole for adjusting the air pressure of the ammonia nitrogen collecting tank.
3. The recycling system according to claim 1, wherein the hydrophobic membrane reaction absorber tube is selected from a polytetrafluoroethylene membrane material tube.
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| CN111153483A (en) * | 2020-02-10 | 2020-05-15 | 北京市农林科学院 | System and method for recovering ammonia nitrogen resource in biogas slurry |
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| CN111153483A (en) * | 2020-02-10 | 2020-05-15 | 北京市农林科学院 | System and method for recovering ammonia nitrogen resource in biogas slurry |
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