CN211734353U - Small-scale non-mixed inoculation continuous solid anaerobic fermentation device - Google Patents

Small-scale non-mixed inoculation continuous solid anaerobic fermentation device Download PDF

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CN211734353U
CN211734353U CN201922266525.0U CN201922266525U CN211734353U CN 211734353 U CN211734353 U CN 211734353U CN 201922266525 U CN201922266525 U CN 201922266525U CN 211734353 U CN211734353 U CN 211734353U
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sleeve
fermentation
bacteria cake
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hinge
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杜连柱
张克强
高文萱
梁军锋
李丹妮
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Agro Environmental Protection Institute Ministry of Agriculture
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Abstract

本实用新型涉及一种小规模非混合接种连续固体厌氧发酵装置,套筒侧壁径向对称安装一对铰座,铰座内同轴密封铰装铰柄,铰柄一端延伸至套筒内,在套筒内中部水平间隔安装发酵菌饼盘,发酵菌饼盘两侧水平铰装转柄,转柄同轴与延伸至套筒内的转柄固装,当转动铰柄时,转柄随着铰柄一起同轴转动,在发酵菌饼盘中部均布通孔,通孔内放置甲烷菌菌粉,发酵菌饼盘的两侧密封密封膜,密封膜可被分阶段开启,露出通孔。本申请针对现有固体发酵中存在的迟滞期长、乙酸化、效率低等问题,改变接种方式,通过逐步加入接种物的方式,使甲烷菌在特定区域内处于绝对优势,充分发挥甲烷菌作用,从而避免有机酸积累和酸抑制,提高产气效率。

Figure 201922266525

The utility model relates to a small-scale non-mixed inoculation continuous solid anaerobic fermentation device. A pair of hinge seats are installed radially symmetrically on the side wall of a sleeve. A hinge handle is coaxially sealed in the hinge seat, and one end of the hinge handle extends into the sleeve , Install the fermented bacteria cake plate at a horizontal interval in the middle of the sleeve. The two sides of the fermentation bacteria cake plate are horizontally hinged with the rotating handle. The rotating handle is coaxially fixed with the rotating handle extending into the sleeve. When the hinged handle is rotated, the rotating handle With the coaxial rotation of the hinged handle, through holes are evenly distributed in the middle of the fermenting bacteria cake plate, methane bacteria powder is placed in the through holes, and the two sides of the fermentation bacteria cake plate are sealed with sealing films, which can be opened in stages to expose the hole. Aiming at the problems of long lag period, acetic acid, and low efficiency in the existing solid fermentation, the present application changes the inoculation method and gradually adds inoculum to make methanogens have an absolute advantage in a specific area and give full play to the role of methanogens , thereby avoiding organic acid accumulation and acid inhibition and improving gas production efficiency.

Figure 201922266525

Description

小规模非混合接种连续固体厌氧发酵装置Small-scale non-mixed inoculation continuous solid anaerobic fermentation device

技术领域technical field

本实用新型属于发酵装置领域,主要涉及一种小规模非混合接种连续固体厌氧发酵装置。The utility model belongs to the field of fermentation devices, and mainly relates to a small-scale non-mixed inoculation continuous solid anaerobic fermentation device.

背景技术Background technique

我国是有机废弃物产生量最大的国家。每年畜禽粪便排放量约38亿吨,农作物秸秆产量达到8.0亿吨,但无害化处理与资源利用率极低,约90.0%以上的畜禽粪污未经处理直接排放到周围环境中,55.0%的秸秆被直接焚烧或随意丢弃,使“资源”成为“污染源”。厌氧发酵产沼气是上述农业有机废弃物处理与资源化利用的有效途径。my country is the country with the largest amount of organic waste. The annual discharge of livestock and poultry manure is about 3.8 billion tons, and the output of crop straw reaches 800 million tons. However, the harmless treatment and resource utilization rate are extremely low. About 90.0% of the livestock and poultry manure is directly discharged into the surrounding environment without treatment. 55.0% of the straw is directly incinerated or discarded at will, making "resources" a "pollution source". Anaerobic fermentation to produce biogas is an effective way for the above-mentioned agricultural organic waste treatment and resource utilization.

在发酵工艺方面:农作物秸秆、畜禽粪便和有机生活垃圾等固体废弃物处理中,堆肥和湿式厌氧发酵应用最广泛,但堆肥周期长、占地面积大。湿式厌氧发酵存在水资源浪费严重、沼液产生量大,容易产生二次污染等问题。固体厌氧发酵装置体积小、无沼液排放、容积产气率高,已经成为厌氧发酵新的发展趋势。In terms of fermentation process: in the treatment of solid waste such as crop straw, livestock and poultry manure, and organic domestic waste, composting and wet anaerobic fermentation are the most widely used, but the composting cycle is long and covers a large area. Wet anaerobic fermentation has problems such as serious waste of water resources, large amount of biogas slurry, and easy to produce secondary pollution. The solid anaerobic fermentation unit has a small volume, no biogas slurry discharge, and high volumetric gas production rate, which has become a new development trend of anaerobic fermentation.

在发酵过程方面:厌氧发酵过程主要包括水解产酸、乙酸化和产甲烷三个阶段,其中水解产酸和已酸化(产酸发酵)的主要微生物和产甲烷主要微生物种类不同,代谢繁殖速率相差几倍,导致水解产酸速率和产甲烷速率差异较大。在固体发酵中,因为容积有机负荷高,导致有机酸积累现象比较严重,使pH<6.0,甚至更低,从而抑制产甲烷微生物的活性(适宜的pH在6.5-7.5范围内),采用非混合接种的方式可有效避免发酵过程有机酸的积累,使pH在7.2以上,从而保证产甲烷菌活性和产甲烷发酵的正常进行。In terms of fermentation process: the anaerobic fermentation process mainly includes three stages of hydrolysis acid production, acetic acid production and methane production. Among them, the main microorganisms of hydrolysis acid production and acidification (acid production fermentation) and the main microorganisms of methane production are different, and the metabolic reproduction rate is different. The difference is several times, resulting in a large difference in the rate of hydrolysis acid production and methane production. In solid fermentation, due to the high volume organic load, the accumulation of organic acids is more serious, so that the pH is less than 6.0 or even lower, thereby inhibiting the activity of methanogenic microorganisms (the suitable pH is in the range of 6.5-7.5). The method of inoculation can effectively avoid the accumulation of organic acids in the fermentation process, so that the pH is above 7.2, so as to ensure the activity of methanogens and the normal progress of methanogenic fermentation.

实用新型内容Utility model content

本申请为了克服现有技术的不足之处,提供了一种分批加料、逐步更新微生物的小规模非混合接种连续固体厌氧发酵装置。In order to overcome the shortcomings of the prior art, the present application provides a small-scale non-mixed inoculation continuous solid anaerobic fermentation device with batch feeding and gradual renewal of microorganisms.

本实用新型采取的技术方案是:The technical scheme adopted by the utility model is:

一种避免固体厌氧发酵酸化的发酵装置,包括底座、套筒以及上盖,在底座上同轴固装套筒,套筒上端密封盖装上盖,在套筒和上盖之间套装密封圈,进一步密封和加强,上盖上制有出气管和压力平衡口,出气管上安装阀门,底座中部制有中空液腔,侧壁制有排液管,所述套筒侧壁径向对称安装一对铰座,铰座内同轴密封铰装铰柄,铰柄一端延伸至套筒内,在套筒内中部水平间隔安装发酵菌饼盘,发酵菌饼盘两侧水平铰装转柄,转柄同轴与延伸至套筒内的转柄固装,当转动铰柄时,转柄随着铰柄一起同轴转动,在发酵菌饼盘中部均布通孔,通孔内放置甲烷菌菌粉,发酵菌饼盘的两侧密封密封膜,在发酵菌饼盘、两侧密封膜上对应位置制有连通发酵菌饼盘上下空间的通液孔。A fermentation device for avoiding acidification by solid anaerobic fermentation, comprising a base, a sleeve and an upper cover, a sleeve is coaxially fixed on the base, an upper cover is installed with a sealing cover at the upper end of the sleeve, and a sleeve is sealed between the sleeve and the upper cover The upper cover is provided with a gas outlet pipe and a pressure balance port, a valve is installed on the gas outlet pipe, a hollow liquid cavity is formed in the middle of the base, and a drain pipe is formed on the side wall, and the side wall of the sleeve is radially symmetrical Install a pair of hinge bases, the hinged hinges are coaxially sealed in the hinge bases, one end of the hinged handle extends into the sleeve, and the fermentation bacteria cake tray is installed horizontally in the middle of the sleeve, and the two sides of the fermentation bacteria cake tray are hinged horizontally. , the rotating handle is fixed coaxially with the rotating handle extending into the sleeve. When the hinged handle is rotated, the rotating handle rotates coaxially with the hinged handle. Through holes are evenly distributed in the middle of the fermentation bacteria cake plate, and methane is placed in the through holes. For the bacterial powder, the two sides of the fermentation bacteria cake plate are sealed with sealing films, and the corresponding positions on the fermentation bacteria cake plate and the sealing films on both sides are provided with liquid through holes connecting the upper and lower spaces of the fermentation bacteria cake plate.

而且,所述密封膜为间隔设置的两个半圆形。Moreover, the sealing film is two semicircles arranged at intervals.

而且,密封膜可被分阶段开启的方式为:在每一个半圆的密封膜上表面靠近轴心的位置间隔固装拉绳一端,拉绳的另一端部固装在转柄上,当转动转柄时,拉绳被缠绕在转柄上,将密封膜拉开。In addition, the sealing film can be opened in stages: one end of the pull rope is fixed at a distance from the upper surface of each semi-circular sealing film close to the axis, and the other end of the pull rope is fixed on the turning handle. When the handle is turned, the drawstring is wrapped around the handle, pulling the sealing film apart.

本实用新型的优点和积极效果:Advantages and positive effects of the present utility model:

1、本申请针对现有固体发酵中存在的迟滞期长、乙酸化、效率低等问题,改变接种方式,通过逐步加入接种物的方式,使甲烷菌在特定区域内处于绝对优势,充分发挥其甲烷菌作用,避免有机酸积累和酸抑制,从而提高产气效率。1. Aiming at the problems such as long lag period, acetic acidization and low efficiency in existing solid fermentation, the application changes the inoculation method and gradually adds inoculum to make methanogens have an absolute advantage in a specific area and give full play to their advantages. Methanogens act to avoid organic acid accumulation and acid inhibition, thereby improving gas production efficiency.

2、本申请中首次采用发酵饼的形式分批加入甲烷菌,甲烷菌的加入方式变成逐步更新,始终保持优势菌种的地位,加入方式简单,不影响任何发酵过程,不开启装置,保持原发酵环境。2. For the first time in this application, the form of fermented cake is used to add methanogens in batches. The method of adding methanogens has become gradually updated, and the status of the dominant strains is always maintained. The addition method is simple, does not affect any fermentation process, does not open the device, and maintains original fermentation environment.

3、本申请采用非混合接种的方法,避免传统固体发酵前原料与接种物混匀过程。另外,在发酵过程中无需采用机械搅拌,减少了大量的能源消耗。3. The present application adopts the method of non-mixed inoculation to avoid the mixing process of raw materials and inoculants before traditional solid fermentation. In addition, there is no need to use mechanical stirring in the fermentation process, which reduces a lot of energy consumption.

附图说明Description of drawings

图1为本实用新型的系统的结构示意图。FIG. 1 is a schematic structural diagram of the system of the present invention.

图2为发酵饼的结构示意图。Figure 2 is a schematic structural diagram of a fermented cake.

图3为带覆膜的发酵饼结构示意图。Figure 3 is a schematic diagram of the structure of a fermented cake with a coating.

图4为图3的A-A向剖视图。FIG. 4 is a cross-sectional view taken along the line A-A in FIG. 3 .

具体实施方式Detailed ways

现在结合附图对本实用新型作进一步详细的说明,附图为简化的示意图,仅以示意方式说明本实用新型的基本结构,因此其仅显示与本实用新型有关的构成。The present utility model will now be described in further detail with reference to the accompanying drawings. The accompanying drawings are simplified schematic diagrams, and only illustrate the basic structure of the present utility model in a schematic manner, so only the structures related to the present utility model are shown.

一种避免固体厌氧发酵酸化的发酵装置,包括底座6、套筒4以及上盖2,在底座上同轴固装套筒,套筒上端密封盖装上盖,在套筒和上盖之间套装密封圈,进一步密封和加强,上盖上制有出气管1和压力平衡口3,出气管上安装阀门,底座中部制有中空液腔,侧壁制有排液管7。A fermentation device for avoiding acidification by solid anaerobic fermentation, comprising a base 6, a sleeve 4 and an upper cover 2, the sleeve is coaxially fixed on the base, the upper end of the sleeve is sealed with an upper cover, and the upper cover is installed between the sleeve and the upper cover. A sealing ring is installed in the space for further sealing and strengthening. The upper cover is provided with an air outlet pipe 1 and a pressure balance port 3, a valve is installed on the air outlet pipe, a hollow liquid cavity is formed in the middle of the base, and a drain pipe 7 is formed on the side wall.

所述套筒侧壁径向对称安装一对铰座,铰座内同轴密封铰装铰柄5,铰柄一端延伸至套筒内,在套筒内中部水平间隔安装发酵菌饼盘8,发酵菌饼盘两侧水平铰装转柄10,转柄同轴与延伸至套筒内的转柄固装,当转动铰柄时,转柄随着铰柄一起同轴转动,在发酵菌饼盘中部均布通孔9,通孔内放置甲烷菌菌粉,发酵菌饼盘的两侧密封密封膜11,密封膜为间隔设置的两个半圆形,在每一个半圆的密封膜上表面靠近轴心的位置间隔固装拉绳12一端,拉绳的另一端部固装在转柄上,当转动转柄时,拉绳被缠绕在转柄上,将密封膜拉开,实现密封拉开部分密封膜的通孔内的菌被释放到发酵物中,完成新菌种的添加。为了将发酵液从上层漏到下层,在发酵菌饼盘、两侧密封膜上对应位置制有连通发酵菌饼盘上下空间的通液孔13,通液孔将上部的液体导入下部,继续发酵。A pair of hinge seats are installed radially symmetrically on the side wall of the sleeve, and the hinge handle 5 is coaxially sealed in the hinge seat. One end of the hinge handle extends into the sleeve. The rotating handle 10 is horizontally hinged on both sides of the fermentation bacteria cake plate, and the rotating handle is coaxially fixed with the rotating handle extending into the sleeve. The through holes 9 are evenly distributed in the middle of the plate, and the methane bacteria powder is placed in the through holes. The two sides of the fermentation bacteria cake plate are sealed with sealing films 11. The sealing films are two semicircles arranged at intervals. One end of the pull rope 12 is fixed at intervals close to the axis, and the other end of the pull rope is fixed on the handle. When the handle is rotated, the rope is wrapped around the handle, and the sealing film is pulled apart to realize the sealing pull. The bacteria in the through holes of the partially sealed membrane are released into the fermented material to complete the addition of new bacteria species. In order to leak the fermentation liquid from the upper layer to the lower layer, a liquid through hole 13 connecting the upper and lower spaces of the fermentation bacteria cake plate is made in the corresponding position on the fermentation bacteria cake plate and the sealing film on both sides. .

本装置能够及时将有机酸排出至产甲烷主要区域,降低pH从而使降低游离氨浓度,因发酵过程产生的有机酸会对氨氮的形态产生影响,因此既能避免传统固体发酵的酸积累、酸抑制,又能避免氨积累、氨抑制,提高发酵效率。The device can timely discharge organic acid to the main area of methane production, reduce pH and thus reduce the concentration of free ammonia. The organic acid produced in the fermentation process will affect the form of ammonia nitrogen, so it can not only avoid the accumulation of acid and acid in traditional solid fermentation Inhibition, but also to avoid ammonia accumulation, ammonia inhibition, improve fermentation efficiency.

主要装置:固体发酵反应器,有效容积10L,发酵方法如下:Main device: solid fermentation reactor, effective volume 10L, fermentation method as follows:

发酵前准备:猪场干清粪(TS=25%-31%),秸秆(TS=88%-90%),接种物 (TS=17%-19%),将猪粪与秸秆按VS比为1:1混合。加入上清沼液将上述物质调至TS为20%-25%。Preparation before fermentation: pig farm dry manure (TS=25%-31%), straw (TS=88%-90%), inoculum (TS=17%-19%), pig manure and straw are compared according to VS For a 1:1 mix. Add the supernatant biogas slurry to adjust the above substances to TS of 20%-25%.

发酵过程:在固体发酵反应器内填充接种物1400g,填充猪粪与秸秆混合物1200g,按照此添加量和添加顺序继续添加2次,形成接种物+猪粪秸秆混合物结构共3层,停止进料,密封,充氮气5min创造厌氧环境,密封反应器,将反应器出气口与沼气收集袋相连,在37℃进行厌氧发酵。Fermentation process: Fill the solid fermentation reactor with 1400g of inoculum and 1200g of pig manure and straw mixture. Continue to add 2 times according to this addition amount and order to form a three-layer structure of inoculum + pig manure and straw mixture, and stop feeding. , sealed, filled with nitrogen for 5 minutes to create an anaerobic environment, sealed the reactor, connected the outlet of the reactor with the biogas collection bag, and carried out anaerobic fermentation at 37°C.

发酵过程中每天计量产气体积,每3天取样检测pH,分析是否产生酸抑制。发酵进行至40天时结束。将发酵后残渣取出,重新填充猪粪与秸秆的混合物,如上分别间隔填充三次。继续厌氧发酵。During the fermentation process, the gas production volume was measured every day, and the pH was measured every 3 days to analyze whether acid inhibition occurred. Fermentation ends at 40 days. The residue after fermentation was taken out, and the mixture of pig manure and straw was refilled, and filled three times at intervals as above. Continue anaerobic fermentation.

结果表明:the result shows:

(1)非混合接种中发酵过程中有机酸浓度达到:总酸19.6-33.0mg/g,乙酸 5.7-6.9mg/g,丙酸3.0-4.1mg/g,但未发生酸抑制,发酵能够快速启动,迟滞期为1-2天,比传统混合固体发酵减少7-8天。(1) The organic acid concentration during the fermentation process in the non-mixed inoculation reaches: total acid 19.6-33.0 mg/g, acetic acid 5.7-6.9 mg/g, propionic acid 3.0-4.1 mg/g, but no acid inhibition occurs, and fermentation can be performed quickly Start-up, the lag period is 1-2 days, which is 7-8 days less than traditional mixed solids fermentation.

(2)厌氧发酵中,底物VS甲烷日产率最高达到9.5ml/(g·d),沼气产率是传统猪粪秸秆混合发酵的1.5倍,是猪粪单独发酵的3.5倍。(2) In anaerobic fermentation, the maximum daily yield of substrate VS methane reached 9.5 ml/(g·d), and the biogas yield was 1.5 times that of traditional pig manure and straw mixed fermentation, and 3.5 times that of pig manure fermentation alone.

Claims (3)

1. The utility model provides a continuous solid anaerobic fermentation device of non-mixed inoculation of small-scale, includes base, sleeve and upper cover, and the sleeve is adorned admittedly to the coaxial company on the base, and the sealed lid of cover in sleeve upper end is adorned the upper cover, and the suit sealing washer is further sealed and is strengthened between sleeve and upper cover, and it has outlet duct and pressure balance mouth to cover the system on, installs the valve on the outlet duct, and the base middle part system has the cavity sap cavity, and the lateral wall system has fluid-discharge tube, its characterized in that:
the fermentation bacteria cake tray comprises a sleeve and is characterized in that a pair of hinged supports are symmetrically and radially arranged on the side wall of the sleeve, hinge handles are coaxially and hermetically hinged in the hinged supports, one end of each hinge handle extends into the sleeve, fermentation bacteria cake trays are horizontally arranged in the middle of the sleeve at intervals, rotary handles are horizontally hinged on two sides of each fermentation bacteria cake tray and are coaxially fixed with the rotary handles extending into the sleeve, when the hinge handles are rotated, the rotary handles coaxially rotate along with the hinge handles, through holes are uniformly distributed in the middle of the fermentation bacteria cake trays, bacteria powder is placed in the through holes, sealing films are sealed on two sides of each fermentation bacteria cake tray, and liquid through holes communicated with the upper space and the lower space of each fermentation bacteria cake tray are formed in corresponding positions on the fermentation bacteria cake trays and the.
2. The small-scale non-mixed inoculation continuous solid anaerobic fermentation apparatus according to claim 1, characterized in that: the sealing films are two semicircles arranged at intervals.
3. The small-scale unmixed inoculation continuous solid anaerobic fermentation apparatus according to claim 1 or 2, characterized in that: the sealing membrane can be opened in stages in the following way: one end of a pull rope is fixedly arranged on the upper surface of each semicircular sealing film at a position close to the axis at intervals, the other end of the pull rope is fixedly arranged on the rotating handle, and when the rotating handle is rotated, the pull rope is wound on the rotating handle to pull the sealing film open.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040936A (en) * 2019-12-17 2020-04-21 农业农村部环境保护科研监测所 Small-scale non-mixed inoculation continuous solid anaerobic fermentation device and fermentation method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040936A (en) * 2019-12-17 2020-04-21 农业农村部环境保护科研监测所 Small-scale non-mixed inoculation continuous solid anaerobic fermentation device and fermentation method
CN111040936B (en) * 2019-12-17 2024-12-03 农业农村部环境保护科研监测所 Small-scale non-mixed inoculation continuous solid anaerobic fermentation device and fermentation method

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