CN211411617U - Electrochemistry improved biological filter tower purification device - Google Patents
Electrochemistry improved biological filter tower purification device Download PDFInfo
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- 238000000746 purification Methods 0.000 title claims abstract description 18
- 230000005518 electrochemistry Effects 0.000 title claims 2
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- 239000010405 anode material Substances 0.000 claims description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 239000010406 cathode material Substances 0.000 claims description 17
- 229910002804 graphite Inorganic materials 0.000 claims description 14
- 239000010439 graphite Substances 0.000 claims description 14
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- 239000002245 particle Substances 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
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- 230000004060 metabolic process Effects 0.000 description 8
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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Abstract
本实用新型公开了一种电化学改进的生物过滤塔净化装置,包括营养液系统、电极系统和塔体,本装置采用外加电源对生物过滤塔中的微生物施加微电流,克服了生物过滤塔启动周期长的缺点,缩短了生物过滤塔启动周期,提高了微生物的活性,能够提高生物过滤塔对挥发性有机物以及恶臭气体的处理效果,并能够长时间稳定运行。
The utility model discloses an electrochemically improved biological filter tower purification device, comprising a nutrient solution system, an electrode system and a tower body. The device adopts an external power source to apply micro-current to microorganisms in the biological filter tower, which overcomes the problem of starting the biological filter tower. The shortcoming of long cycle shortens the start-up cycle of the biological filter tower, improves the activity of microorganisms, can improve the treatment effect of the biological filter tower on volatile organic compounds and malodorous gases, and can run stably for a long time.
Description
技术领域technical field
本实用新型属于环保设备及应用,具体涉及一种电化学改进的生物过滤塔净化装置。The utility model belongs to environmental protection equipment and applications, in particular to an electrochemically improved biological filter tower purification device.
背景技术Background technique
挥发性有机化合物(VOCs)挥发性有机物是一类常见且非常重要的大气污染物,主要由苯类、醇类、醛类、烃类等上千种物质组成。其处理主要分为回收技术和分解技术,回收技术包括吸收法、吸附法、冷凝法和膜分离处理技术等,可实现有机废物的回收,但是回收的纯度难以保证,并且处理有机废物的材料再生困难,容易产生二次污染。分解法包括热焚烧法、化学氧化法、催化氧化法和等离子体分解法,生物过滤法等。其中生物过滤工艺是微生物以VOCs为碳源和能源,在适宜的环境条件下通过自身的新陈代谢作用将VOCs转化为一部分细胞组成物质、二氧化碳(CO2)、水(H2O)未完全降解物质和小分子无机物质,与其他物理化学方法相比具有高效、节能、投资成本和运行费用低、操作简单、使用安全等优势,是一种能源节约、环境友好型技术,符合我国节能减排和发展低碳经济的政策要求,因此,在实际工程应用中与传统的物理化学方法相比极具竞争力。Volatile Organic Compounds (VOCs) Volatile organic compounds (VOCs) are a common and very important class of air pollutants, mainly composed of thousands of substances such as benzene, alcohols, aldehydes, and hydrocarbons. Its treatment is mainly divided into recovery technology and decomposition technology. The recovery technology includes absorption method, adsorption method, condensation method and membrane separation treatment technology, etc., which can realize the recovery of organic waste, but the purity of recovery is difficult to guarantee, and the material for processing organic waste is regenerated. It is difficult and prone to secondary pollution. Decomposition methods include thermal incineration, chemical oxidation, catalytic oxidation, plasma decomposition, and biological filtration. Among them, the biological filtration process is that microorganisms use VOCs as carbon source and energy, and convert VOCs into a part of cell constituent substances, carbon dioxide (CO 2 ), and water (H 2 O) incompletely degraded substances through their own metabolism under suitable environmental conditions. Compared with other physical and chemical methods, it has the advantages of high efficiency, energy saving, low investment and operating costs, simple operation, and safe use. It is an energy-saving and environment-friendly technology. The policy requirements for developing a low-carbon economy are, therefore, highly competitive with traditional physical-chemical methods in practical engineering applications.
生物电化学是通过外加电压的条件下对微生物进行微电流的刺激,从而刺激微生物的代谢过程,在污水处理以及食品科学方面已经有诸多研究。Bioelectrochemistry is to stimulate the micro-current of microorganisms under the condition of applied voltage, thereby stimulating the metabolic process of microorganisms. There have been many studies in sewage treatment and food science.
实用新型内容Utility model content
本实用新型的目的在于克服现有技术的不足,提供一种电化学改进的生物过滤塔净化装置,本实用新型采用外加电源对生物过滤塔中的微生物施加微电流,克服了生物过滤塔启动周期长的缺点,缩短了生物过滤塔启动周期,提高了微生物的活性,能够提高生物过滤塔对挥发性有机物以及恶臭气体的处理效果,并能够长时间稳定运行。The purpose of the utility model is to overcome the deficiencies of the prior art and provide an electrochemically improved biological filter tower purification device. The utility model uses an external power supply to apply micro-current to the microorganisms in the biological filter tower, thereby overcoming the start-up cycle of the biological filter tower. It has the disadvantage of shortening the start-up period of the biological filter tower, improving the activity of microorganisms, and improving the treatment effect of the biological filter tower on volatile organic compounds and malodorous gases, and can run stably for a long time.
本实用新型是通过以下技术方案实现的:The utility model is achieved through the following technical solutions:
一种电化学改进的生物过滤塔净化装置,包括营养液系统、电极系统和塔体;An electrochemically improved biological filter tower purification device, comprising a nutrient solution system, an electrode system and a tower body;
所述营养液系统包括营养液罐体、高压泵、营养液管路和喷淋装置;所述营养液罐体与设置于塔体底部的营养液流出口相连,并且通过高压泵、营养液管路与设置于塔体顶部的喷淋装置相连,营养液由营养液罐体内抽出后经过营养液管路喷淋到塔体内,并由营养液流出口处重新收集;The nutrient solution system includes a nutrient solution tank body, a high-pressure pump, a nutrient solution pipeline and a spray device; the nutrient solution tank body is connected with the nutrient solution outflow outlet arranged at the bottom of the tower body, and is connected to the nutrient solution outlet through the high-pressure pump, the nutrient solution pipeline The road is connected to the spray device arranged on the top of the tower body, the nutrient solution is drawn out from the nutrient solution tank and sprayed into the tower body through the nutrient solution pipeline, and collected again from the outlet of the nutrient solution;
所述电极系统包括外接电源、导电阳极材料和导电阴极材料,导电阳极材料和导电阴极材料设置于塔体内并通过电导线与外接电源相连;The electrode system includes an external power source, a conductive anode material and a conductive cathode material, and the conductive anode material and the conductive cathode material are arranged in the tower body and are connected to the external power source through an electric wire;
所述塔体设置有进气口和出气口,所述塔体内设置塑料透气板、承托层填料和导电活性填料,所述塑料透气板位于塔体底部,所述承托层填料位于塑料透气板上,用于承载导电活性填料,所述导电活性填料与导电阳极材料、导电阴极材料发生接触,且其上附着有污泥,污泥内包含用于处理挥发性有机物以及恶臭气体的微生物。The tower body is provided with an air inlet and an air outlet, a plastic ventilation plate, a supporting layer filler and a conductive active filler are arranged in the tower body, the plastic ventilation plate is located at the bottom of the tower body, and the supporting layer filler is located in the plastic ventilation plate. The plate is used to carry conductive active fillers, the conductive active fillers are in contact with conductive anode materials and conductive cathode materials, and sludge is attached thereon, and the sludge contains microorganisms for treating volatile organic compounds and malodorous gases.
在上述技术方案中,所述进气口设置于塔体的底部,出气口设置于塔体的顶端。In the above technical solution, the air inlet is arranged at the bottom of the tower body, and the air outlet is arranged at the top of the tower body.
在上述技术方案中,所述进气口分为3个,分别设置于塔体侧面的下侧、中部和上侧,出气口设置于塔体的顶端;所述塑料透气板分为3块,将塔体内部空间分隔为三部分分别对应3个进气口。In the above technical solution, the air inlet is divided into 3, which are respectively arranged on the lower side, the middle and the upper side of the side of the tower body, and the air outlet is arranged at the top of the tower body; the plastic ventilation plate is divided into 3 pieces, The inner space of the tower body is divided into three parts corresponding to three air inlets respectively.
在上述技术方案中,所述导电阳极材料采用若干根串连的石墨棒,石墨棒竖直排布于塔体内的导电活性填料内,所述阴极材料为塔体的不锈钢内壁。In the above technical solution, the conductive anode material adopts several graphite rods connected in series, the graphite rods are vertically arranged in the conductive active packing in the tower body, and the cathode material is the stainless steel inner wall of the tower body.
在上述技术方案中,所述导电阳极材料采用若干根串连的石墨棒,所述阴极材料为石墨棒,所述导电阳极材料的石墨棒围绕所述阴极材料的石墨棒排布。In the above technical solution, the conductive anode material adopts several graphite rods connected in series, the cathode material is a graphite rod, and the graphite rods of the conductive anode material are arranged around the graphite rods of the cathode material.
在上述技术方案中,所述承托层填料为陶粒。In the above technical solution, the filler of the supporting layer is ceramsite.
在上述技术方案中,所述导电活性填料为改性活性炭颗粒。In the above technical solution, the conductive active filler is modified activated carbon particles.
一种电化学改进的生物过滤塔净化装置在处理挥发性有机物以及恶臭气体中的应用:处理挥发性有机物以及恶臭气体由进气口进入塔体,在通过外接电源对生物过滤塔中的微生物施加微电流,来刺激微生物代谢过程,强化生物过滤塔对挥发性有机物以及恶臭气体的处理效果。The application of an electrochemically improved biological filter tower purification device in the treatment of volatile organic compounds and malodorous gases: the treatment of volatile organic compounds and malodorous gases enters the tower body through the air inlet, and the microorganisms in the biological filter tower are applied through an external power supply. Micro-current is used to stimulate the metabolic process of microorganisms and strengthen the treatment effect of the biological filter tower on volatile organic compounds and malodorous gases.
本实用新型所具备的实质性特点和取得的显著技术进步在于:The substantive features of the present utility model and the remarkable technological progress achieved are:
1、为了促进和增强微生物对挥发性有机物以及恶臭气体的处理效果,在生物过滤塔设置阳极以及阴极,以多孔塑料透气板承托填料层,填料层由承托层填料,活性导电填料和导电阳极材料构成,在通过外接电源对生物过滤塔中的微生物施加微电流,来刺激微生物代谢过程,强化生物过滤塔对挥发性有机物以及恶臭气体的处理效果。1. In order to promote and enhance the treatment effect of microorganisms on volatile organic compounds and malodorous gases, an anode and a cathode are set in the biological filter tower, and the packing layer is supported by a porous plastic breathable plate. It is composed of anode material. Micro-current is applied to the microorganisms in the biological filter tower through an external power supply to stimulate the metabolic process of microorganisms and strengthen the treatment effect of the biological filter tower on volatile organic compounds and malodorous gases.
2、同时,本装置还采用分级进气的方法,在塔体侧面在不同的高度分别设有三个进气口,进气口的进气量由下至上依次降低,使得生物过滤塔对进气有一定的缓冲作用,保证塔内部各个部分微生物群落保持一致,保证对挥发性有机物的处理效果。2. At the same time, the device also adopts the method of graded air intake. There are three air inlets at different heights on the side of the tower body. It has a certain buffering effect to ensure that the microbial community in each part of the tower is consistent and the treatment effect of volatile organic compounds is guaranteed.
附图说明Description of drawings
图1是本实用新型实施例1中净化装置的侧视结构示意图。FIG. 1 is a schematic side view of the structure of the purification device in
图2是本实用新型实施例1中净化装置的俯视结构示意图。2 is a schematic top view of the structure of the purification device in
图3是本实用新型实施例2中净化装置的侧视结构示意图。3 is a schematic side view of the structure of the purification device in
图4是本实用新型实施例2中净化装置的俯视结构示意图。FIG. 4 is a schematic top view of the structure of the purification device in
在图1、图2中:1为进气口,2为出气口,3为营养液罐体,4为高压泵,5为营养液管路,6为喷淋装置,7为营养液流出口,8为导电阳极材料,9为导电活性填料,10 为承托层填料,11为塔体,12为电导线,13为外接电源,14为塑料透气板。In Figure 1 and Figure 2: 1 is an air inlet, 2 is an air outlet, 3 is a nutrient solution tank, 4 is a high-pressure pump, 5 is a nutrient solution pipeline, 6 is a spray device, and 7 is a nutrient solution flow outlet , 8 is the conductive anode material, 9 is the conductive active filler, 10 is the support layer filler, 11 is the tower body, 12 is the electrical wire, 13 is the external power supply, and 14 is the plastic breathable plate.
在图3、图4中:1a为第一进气口,1b为第二进气口,1c为第三进气口,2为出气口,3为营养液罐体,4为高压泵,5为营养液管路,6为喷淋装置,7为营养液流出口, 8为导电阳极材料,9为导电活性填料,10为承托层填料,11为塔体,12为电导线,13 为外接电源,14为塑料透气板,15为导电阴极材料。In Fig. 3 and Fig. 4: 1a is the first air inlet, 1b is the second air inlet, 1c is the third air inlet, 2 is the air outlet, 3 is the nutrient solution tank, 4 is the high pressure pump, 5 6 is the nutrient solution pipeline, 6 is the spray device, 7 is the nutrient solution outlet, 8 is the conductive anode material, 9 is the conductive active filler, 10 is the support layer filler, 11 is the tower body, 12 is the electrical wire, and 13 is the For the external power supply, 14 is a plastic breathable plate, and 15 is a conductive cathode material.
对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,可以根据以上附图获得其他的相关附图。For those of ordinary skill in the art, other related drawings can be obtained from the above drawings without any creative effort.
具体实施方式Detailed ways
为了使本技术领域的人员更好地理解本实用新型方案,下面结合具体实施例进一步说明本实用新型的技术方案。In order to make those skilled in the art better understand the solution of the present invention, the technical solution of the present invention is further described below with reference to specific embodiments.
实施例1Example 1
如图1和图2所示,一种电化学强化的生物过滤技术,包括塔体11和外接电源13,分别开设在塔体下端的进气口1以及塔体11上端的出气口2,位于塔体11顶部有喷淋装置6,喷淋装置6由高压泵4经过营养液管路5从营养液罐体3打入塔体11中,位于进气口1上方的塔体的底部由塑料透气板14支撑,填料床层的下层填有用于支撑的填料层 10,填料层可采用陶粒,上层填有导电活性填料层9,活性层导电填料可采用改性活性炭颗粒,在活性填料层中插有导电阳极材料8,导电阳极材料采用石墨棒,由导线12连接后连于电源阳极13,塔体11由不锈钢制成,由导线12连接于电源阴极13。As shown in FIG. 1 and FIG. 2, an electrochemically enhanced biological filtration technology includes a
由某污水处理厂二沉池污泥作为接种微生物,将污泥反复喷淋于生物过滤塔中,使得微生物能够附着在填料表面。在生物过滤塔启动期,由进气口1通入有机废气或恶臭气体,通过塑料透气板14后均匀进入生物过滤塔中,同时营养液罐体3的营养液由高压泵4经管路5由喷淋装置6喷淋入生物过滤塔,并以一定的周期循环使用,保证生物过滤塔内附着于填料上的微生物所需无机盐等营养物质得到均匀有效供给;将生物过滤塔内的阳极材料8经导线12连接至外接电源阳极13,将生物过滤塔不锈钢外壳11由导线 12连接至外接电源阴极13,打开外接电源13,微电流由电源负极13经不锈钢外壳11、负载微生物的导电活性填料层9、阳极材料8,流入外接电源正极13对生物过滤塔中的微生物以微电流进行刺激,导电活性填料层9上的微生物经过微电流刺激后促进自身的新陈代谢,加速生物过滤塔启动周期中微生物的生物量积累,从而快速提高生物过滤塔处理效率,缩短生物过滤塔启动周期。The sludge in the secondary sedimentation tank of a sewage treatment plant is used as inoculated microorganisms, and the sludge is repeatedly sprayed in the biological filter tower, so that the microorganisms can adhere to the surface of the packing. During the start-up period of the biological filter tower, the organic waste gas or malodorous gas is introduced from the
在生物过滤塔正常运行时,由外接电源13加载微电流可以使得生物过滤塔中的微生物迅速代谢,提高微生物对有机废气及恶臭气体的代谢速率,从而提高生物过滤塔对有机废气及恶臭气体的处理效果;由于微电流的刺激,生物过滤塔中的微生物快速大量繁殖,当生物过滤塔中压降突然增加或生物过滤塔堵塞时,对生物过滤塔在短时间内用大量洁净空气冲击,同时加大对生物过滤塔营养液的喷淋量,冲洗掉一部分导电填料上附着的微生物膜,解决生物过滤塔排气不畅和堵塞的问题。When the biological filter tower is in normal operation, the micro-current loaded by the
实施例2Example 2
如图3和图4所示,一种电化学改进的生物过滤塔净化装置,包括塔体11和外接电源13,塔的下端以及塔的中端分别设有三个进气口:第一进气口1a、第二进气口1b、第三进气口1c以及塔体11上端的出气口4,位于塔体11顶部有喷淋装置6,喷淋装置6 由高压泵4经过营养液管路5从营养液罐体3打入塔体11,位于进气口1a、1b、1c上方的塔内部由塑料透气板14支撑,填料床层的下层填有用于支撑的填料层10,填料层可采用陶粒,上层填有导电活性填料层9,活性层导电填料可采用改性活性炭颗粒,在活性填料层中均匀分布导电阳极材料8,由导线12连接后连于电源阳极13,塔体中间插有导电阴极材料15,由导线12连接于外接电源13的阴极,导电阳极材料以及导电阴极材料均采用石墨棒。As shown in Figures 3 and 4, an electrochemically improved biological filter tower purification device includes a
由某污水处理厂二沉池污泥作为接种微生物,将污泥反复喷淋于生物过滤塔中,使得微生物能够附着在填料表面。在生物过滤塔启动期,由进气口1a、1b、1c分别通入高、中、低量的有机废气,通过塑料透气板14后均匀进入生物过滤塔中,同时营养液罐体3 的营养液由高压泵4经营养液管路5由喷淋装置6喷淋入生物过滤塔,并以一定的周期循环使用,保证生物过滤塔内微生物的无机盐等营养物质得到均匀有效供给;将生物过滤塔内均匀分布的导电阳极材料8经电导线12连接至外接电源13阳极,将生物过滤塔中间的导电阴极材料11由导线12连接至外接电源阴极13,打开外接电源13,微电流由电源13负极经导电阴极材料11、负载微生物的导电活性填料层9、阳极材料8,流入外接电源正极13对生物过滤塔中的微生物以微电流进行刺激,导电活性填料层9上的微生物经过微电流刺激后促进自身的新陈代谢,加速生物过滤塔启动周期中微生物的生物量积累,从而快速提高生物过滤塔处理效率,缩短生物过滤塔启动周期。The sludge in the secondary sedimentation tank of a sewage treatment plant is used as inoculated microorganisms, and the sludge is repeatedly sprayed in the biological filter tower, so that the microorganisms can adhere to the surface of the packing. During the start-up period of the biological filtration tower, high, medium and low amounts of organic waste gas are respectively introduced into the
在生物过滤塔正常运行时,由外接电源13加载微电流可以使得生物过滤塔中的微生物迅速代谢,提高微生物对挥发性有机气体的代谢速率,从而提高生物过滤塔对有机废气及恶臭气体的处理效果;由于微电流的刺激,生物过滤塔中的微生物快速大量繁殖,当生物过滤塔中压降突然增加或生物过滤塔堵塞时,对生物过滤塔在短时间内用大量洁净空气冲击,同时加大对生物过滤塔营养液的喷淋量,冲洗掉一部分导电填料上附着的微生物膜,解决生物过滤塔排气不畅和堵塞的问题。When the biological filter tower is in normal operation, the micro-current loaded by the
本文中为部件所编序号本身,例如“第一”、“第二”等,仅用于区分所描述的对象,不具有任何顺序或技术含义。而本申请所说“连接”、“联接”,如无特别说明,均包括直接和间接连接(联接)。在本实用新型的描述中,需要理解的是,术语“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“顺时针”、“逆时针”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本实用新型和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本实用新型的限制。The serial numbers themselves, such as "first", "second", etc., for the components herein are only used to distinguish the described objects, and do not have any order or technical meaning. The "connection" and "connection" mentioned in this application, unless otherwise specified, include both direct and indirect connections (connections). In the description of the present invention, it should be understood that the terms "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top" , "bottom", "inside", "outside", "clockwise", "counterclockwise" and other indications of orientation or positional relationship are based on the orientation or positional relationship shown in the accompanying drawings, only for the convenience of describing the present utility model and The description is simplified rather than indicating or implying that the device or element referred to must have a particular orientation, be constructed and operate in a particular orientation, and therefore should not be construed as limiting the invention.
在本实用新型中,除非另有明确的规定和限定,第一特征在第二特征“上”或“下”可以是第一和第二特征直接接触,或第一和第二特征通过中间媒介间接接触。而且,第一特征在第二特征“之上”、“上方”和“上面”可是第一特征在第二特征正上方或斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”可以是第一特征在第二特征正下方或斜下方,或仅仅表示第一特征水平高度小于第二特征。In the present invention, unless otherwise expressly specified and defined, a first feature "on" or "under" a second feature may be in direct contact with the first and second features, or the first and second features through an intermediary indirect contact. Also, the first feature being "above", "over" and "above" the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is level higher than the second feature. The first feature being "below", "below" and "below" the second feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature has a lower level than the second feature.
以上对本实用新型做了示例性的描述,应该说明的是,在不脱离本实用新型的核心的情况下,任何简单的变形、修改或者其他本领域技术人员能够不花费创造性劳动的等同替换均落入本实用新型的保护范围。The present invention has been exemplarily described above. It should be noted that, without departing from the core of the present invention, any simple deformations, modifications or other equivalent replacements that can be performed by those skilled in the art without any creative effort will fall into place. into the protection scope of the present invention.
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| CN110559841A (en) * | 2019-09-29 | 2019-12-13 | 天津大学 | Electrochemistry improved biological filter tower purification device and application thereof |
| CN113209813A (en) * | 2021-06-10 | 2021-08-06 | 天津大学 | Reinforcer for reinforcing biofilm formation of waste gas biofiltration device and application thereof |
| CN115475503A (en) * | 2022-10-20 | 2022-12-16 | 延边大学 | Three-dimensional electrode biomembrane reaction device and method for removing chlorobenzene waste gas by using same |
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| CN110559841A (en) * | 2019-09-29 | 2019-12-13 | 天津大学 | Electrochemistry improved biological filter tower purification device and application thereof |
| CN113209813A (en) * | 2021-06-10 | 2021-08-06 | 天津大学 | Reinforcer for reinforcing biofilm formation of waste gas biofiltration device and application thereof |
| CN113209813B (en) * | 2021-06-10 | 2022-06-07 | 天津大学 | A kind of intensifier and application of waste gas biological filter device to strengthen biofilm formation |
| CN115475503A (en) * | 2022-10-20 | 2022-12-16 | 延边大学 | Three-dimensional electrode biomembrane reaction device and method for removing chlorobenzene waste gas by using same |
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