CN210006846U - A lithium battery suitable for a round battery compartment - Google Patents
A lithium battery suitable for a round battery compartment Download PDFInfo
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- CN210006846U CN210006846U CN201920592722.9U CN201920592722U CN210006846U CN 210006846 U CN210006846 U CN 210006846U CN 201920592722 U CN201920592722 U CN 201920592722U CN 210006846 U CN210006846 U CN 210006846U
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 71
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 71
- 238000005452 bending Methods 0.000 claims description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 238000012856 packing Methods 0.000 abstract 2
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 238000004804 winding Methods 0.000 description 15
- 239000011888 foil Substances 0.000 description 8
- 239000002985 plastic film Substances 0.000 description 8
- 229920006255 plastic film Polymers 0.000 description 8
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 239000011267 electrode slurry Substances 0.000 description 6
- 229910001416 lithium ion Inorganic materials 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000004080 punching Methods 0.000 description 4
- 239000011889 copper foil Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000007755 gap coating Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
Description
技术领域technical field
本发明涉及电化学领域,特别是涉及一种锂离子电池及其制造方法。The invention relates to the field of electrochemistry, in particular to a lithium ion battery and a manufacturing method thereof.
背景技术Background technique
锂离子电池作为化学电源中一种能源形式,具有工作电压高、能量密度大、重量轻、体积小、安全性好、循环寿命好、绿色环保等优点,在移动电子电器和电动工具、等方面具有广阔的应用前景。As a form of energy in chemical power sources, lithium-ion batteries have the advantages of high working voltage, high energy density, light weight, small size, good safety, good cycle life, and green environmental protection. with broadly application foreground.
小型的锂离子电池在移动便携的电子产品如智能手表、无线蓝牙耳机等上应用广泛,但现有的移动便携的电子产品其用于安装小型的锂离子电池的电池仓大多为圆型电池仓,而现有的小型的锂离子电池为方形,导致圆型电池仓内存在剩余的空间,而电池仓未被充分利用也会导致安装的锂离子电池的容量偏小影响电子产品的续航能力。移动便携的电子产品的电池仓普遍制作成圆型是因为在批量生产制造过程中,圆型结构相较于其它结构加工过程更简单、成本更低且良品率最好。因此为了提高移动便携的电子产品的续航能力,开发一种性能优良且适用于圆型电池仓的锂电池具有重要意义。Small lithium-ion batteries are widely used in mobile and portable electronic products such as smart watches, wireless Bluetooth headsets, etc. However, most of the battery compartments used to install small lithium-ion batteries in existing mobile and portable electronic products are round battery compartments. , and the existing small lithium-ion batteries are square, resulting in the remaining space in the round battery compartment, and the battery compartment is not fully utilized, the capacity of the installed lithium-ion battery is too small, which affects the battery life of electronic products. The battery compartments of mobile and portable electronic products are generally made in a circular shape because in the mass production process, the circular structure is simpler to process, has a lower cost and has the best yield compared with other structures. Therefore, in order to improve the endurance of mobile and portable electronic products, it is of great significance to develop a lithium battery with excellent performance and suitable for round battery compartments.
发明内容SUMMARY OF THE INVENTION
本发明的目的是提供一种适用于圆型电池仓的锂电池,所述锂电池为圆饼型,与移动便携的电子产品的圆型电池仓相匹配,在相同直径的圆型电池仓内装入本发明提供的圆饼型锂电池相比于装入现有的方形锂电池,电池容量可提高至少25%。具体技方案如下:The purpose of the present invention is to provide a lithium battery suitable for a circular battery compartment. The lithium battery is a round cake type, which matches the circular battery compartment of a mobile and portable electronic product, and is installed in a circular battery compartment of the same diameter Compared with the existing square lithium battery, the battery capacity can be increased by at least 25% when the round cake type lithium battery provided by the present invention is loaded. The specific technical solutions are as follows:
一种锂电池,锂电池为圆饼状,锂电池侧壁外侧环绕有弯折部,弯折部与锂电池的其中一端面一体连接,锂电池的正极极耳、负极极耳由锂电池内部通过弯折部引出。为匹配圆形电池仓内设置的正负极的连接点,锂电池的正极极耳和负极极耳之间的夹角可成任意角度。A lithium battery, the lithium battery is in the shape of a round cake, a bending part is surrounded on the outer side of the side wall of the lithium battery, the bending part is integrally connected with one end surface of the lithium battery, and the positive electrode tab and the negative electrode tab of the lithium battery are formed by the inside of the lithium battery. Lead out through the bending part. In order to match the connection points of the positive and negative electrodes set in the circular battery compartment, the angle between the positive electrode tab and the negative electrode tab of the lithium battery can be any angle.
进一步的,锂电池的电芯为卷绕式结构,卷绕时隔膜与极片的组装方式,可以采用隔膜制袋包覆正极片后与负极卷绕,也可以采用卷对卷双层隔膜与正负极极片卷绕方式。Further, the battery cell of the lithium battery is of a winding structure. When winding, the separator and the pole piece can be assembled in a way that the separator bag can be used to wrap the positive electrode piece and then wound with the negative electrode, or a roll-to-roll double-layer separator can be used with the negative electrode. Positive and negative pole piece winding method.
进一步的,锂电池封装外壳采用铝或铝合金。Further, the lithium battery packaging shell is made of aluminum or aluminum alloy.
进一步的,锂电池采用的电解质,可以是凝胶聚合物固态电解质,也可以是常规的液态电解质。Further, the electrolyte used in the lithium battery may be a gel polymer solid electrolyte or a conventional liquid electrolyte.
本发明公开一种制作上述圆饼状锂电池的方法,具体包括以下步骤:The invention discloses a method for making the above-mentioned round cake-shaped lithium battery, which specifically includes the following steps:
步骤一,按常规方法配制正极浆料,正极片集流体采用长方形铝箔,然后在正极片集流体铝箔两端面沿着宽度方向进行涂覆正极浆料,在正极片尾部端两端面漏出1–5mm铝箔用于连接正极极耳,经干燥、轧膜得到正极片。也可先在大片铝箔上进行间隙式涂料,经干燥、轧膜、分切和裁切,得到正极片;Step 1: Prepare the positive electrode slurry according to the conventional method. The positive electrode current collector is made of rectangular aluminum foil, and then the positive electrode slurry is coated on both ends of the positive electrode current collector aluminum foil along the width direction. The aluminum foil is used to connect the positive electrode tab, and the positive electrode sheet is obtained by drying and rolling. It is also possible to apply gap coating on a large piece of aluminum foil first, and then dry, roll film, slit and cut to obtain a positive electrode sheet;
步骤二,按常规方法配制负极浆料,然后在负极片集流体铜箔沿着宽度方向进行间隙式涂料,经干燥、轧膜、分切和裁切,得到在极片高度方向的一端漏出1-4mm集流体铜箔的负极片,优选的,在负极片的尾部设置漏出用于连接负极极耳;
步骤三,在正极片和负极片的漏出部分分别连接正极极耳和负极极耳,然后将正极片和负极片的漏出部分两端面均贴胶纸;
步骤四,对正极片进行绝缘处理,将正极片放入两层隔膜中间,将两层所述隔膜的边缘处封合将所述正极片除尾部端外的部分套装,正极片的头部与封合的隔膜的端部设置有1-5mm的间隙,设置间隙用于防止锂电池循环充放电时时正极片膨胀导致刺破隔膜;Step 4: Insulate the positive electrode sheet, put the positive electrode sheet in the middle of the two layers of separators, seal the edges of the two layers of the separators, and cover the part of the positive electrode sheet except for the tail end. The end of the sealed diaphragm is provided with a gap of 1-5mm, and the gap is set to prevent the expansion of the positive electrode sheet when the lithium battery is cyclically charged and discharged, causing the diaphragm to be punctured;
步骤五,进行卷绕,将绝缘处理后的正极片与负极片层叠设置,正、负极片用隔膜分隔绝缘,由正极片头部端开始卷绕得到圆柱形卷芯,卷绕采用极耳收尾。卷绕时,正极片在最外层围绕内层的负极片进行卷绕,位于所述圆柱形卷芯外层的所述正、负极片的尾部部设有用于固定的胶纸。卷绕时也可采用双负极片包夹正极片来进行卷绕;Step 5: winding, stacking the insulated positive electrode sheet and the negative electrode sheet, separating the positive electrode sheet and the negative electrode sheet for insulation, starting from the head end of the positive electrode sheet to obtain a cylindrical winding core, and ending the winding with tabs . During winding, the positive electrode sheet is wound around the inner negative electrode sheet at the outermost layer, and the tail portions of the positive and negative electrode sheets located on the outer layer of the cylindrical winding core are provided with adhesive tape for fixing. When winding, double negative electrode sheets can also be used to wrap the positive electrode sheets for winding;
步骤六,进行封装,锂电池封装外壳采用铝或铝合金的片材,片材上设置有圆形的凹槽,将圆柱形卷芯放置入凹槽并将处于竖直方向的正极极耳、负极极耳弯折90°,将片材对折并压合使凹槽封闭,压合可采用应用于软包锂电池的常规技术手段,依次进行顶封和侧封,正极极耳、负极极耳处于两层片材之间的部分两端面均贴有胶纸,再采用常规技术手段依次进行扩口、注液、化成和二封;Step 6, encapsulate, the lithium battery encapsulation shell is made of aluminum or aluminum alloy sheet, the sheet is provided with a circular groove, the cylindrical winding core is placed in the groove, and the positive electrode tabs in the vertical direction, The negative electrode tab is bent at 90°, and the sheet is folded in half and pressed to close the groove. The conventional technical means applied to soft-pack lithium batteries can be used for pressing and sealing. Top sealing and side sealing are performed in sequence. Both ends of the part between the two layers of sheets are pasted with adhesive tape, and then the conventional technical means are used to carry out flaring, liquid injection, formation and two sealing in sequence;
步骤七,锂电池成型,采用冲切的方式将片材的对折连接面冲切成圆形面,圆形面与凹槽为同心圆,圆形面的直径大于凹槽的直径,将圆形面大于凹槽的部分向凹槽方向弯折形成弯折部,将漏出的正极极耳、负极极耳向远离凹槽方向弯折。Step 7: Lithium battery is formed, and the folded connecting surface of the sheet is punched into a circular surface by punching. The circular surface and the groove are concentric circles. The diameter of the circular surface is larger than the diameter of the groove. The part whose surface is larger than the groove is bent in the direction of the groove to form a bending part, and the leaked positive electrode tab and the negative electrode tab are bent in a direction away from the groove.
步骤八,按常规方法对电池进行充放电活化后得到圆饼型锂电池产品。In the eighth step, the battery is charged and discharged according to a conventional method to obtain a round cake type lithium battery product.
优选的,步骤六中锂电池封装外壳采用铝塑膜,铝塑膜厚度在70-90微米之间。Preferably, in step 6, the lithium battery packaging shell is made of aluminum-plastic film, and the thickness of the aluminum-plastic film is between 70-90 microns.
附图说明Description of drawings
附图对本发明作进一步说明,但附图中的实施例不构成对本发明的任何限制。The accompanying drawings further illustrate the present invention, but the embodiments in the accompanying drawings do not constitute any limitation to the present invention.
图1为本发明一实施例1提供的圆饼型锂电池结构示意图。FIG. 1 is a schematic structural diagram of a round cake type lithium battery according to
图2为本发明一实施例1提供的锂电池的正极片结构示意图。FIG. 2 is a schematic structural diagram of a positive electrode sheet of a lithium battery provided in
图3为本发明一实施例1提供的锂电池的封装示意图。FIG. 3 is a schematic diagram of the packaging of the lithium battery provided in
图4为本发明一实施例1提供的锂电池冲切成型的结构示意图。FIG. 4 is a schematic structural diagram of punching and forming a lithium battery according to
图5为本发明一实施例2提供的圆饼型锂电池结构示意图。FIG. 5 is a schematic structural diagram of a round cake type lithium battery provided in
图6为本发明一实施例3提供的圆饼型锂电池结构示意图。FIG. 6 is a schematic structural diagram of a round cake type lithium battery provided in
其中,附图标记为:1.锂电池;10.弯折部;2.正极极耳;3.负极极耳;4.绝缘胶纸;5.正极片;6.隔膜;7.铝塑膜;8.凹槽;9.高温绝缘胶纸。10. Bending part; 2. Positive electrode tab; 3. Negative electrode tab; 4. Insulating tape; 5. Positive electrode sheet; 6. Diaphragm; 7. Aluminum plastic film ; 8. Groove; 9. High temperature insulating tape.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
实施例1Example 1
如图1所示,一种锂电池1,锂电池1为圆饼状,锂电池1侧壁外侧环绕有弯折部10,弯折部10与锂电池1的其中一端面一体连接,锂电池1的正极极耳2、负极极耳3由锂电池1内部通过弯折部10引出。正极极耳2和负极极耳3平行引出。As shown in FIG. 1, a
生产实施例1提供的圆饼状锂电池的生产方法,具体包括以下步骤:The production method of the round cake lithium battery provided by Production Example 1, specifically comprises the following steps:
步骤一,配制正极浆料,正极片5集流体采用长方形铝箔,然后在正极片5铝箔两端面沿着宽度方向进行涂覆正极浆料,在正极片5尾部端两端面漏出3mm铝箔用于连接正极极耳3,经干燥、轧膜得到正极片5;Step 1: Prepare the positive electrode slurry. The current collector of the
步骤二,配制负极浆料,然后在负极片集流体铜箔沿着宽度方向进行间隙式涂料,经干燥、轧膜、分切和裁切得到负极片,在负极片的尾部设置漏出3mm集流体铜箔用于连接负极极耳3;
步骤三,在正极片5和负极片的漏出部分分别连接正极极耳2和负极极耳3,然后将正极片5和负极片的漏出部分两端面均贴高温绝缘胶纸9;
步骤四,如图2所示,对正极片5进行绝缘处理,将正极片5放入两层隔膜6中间,将两层所述隔膜6的边缘处封合将所述正极片5除尾部端外的部分套装,正极片5的头部与封合的隔膜6的端部设置有3mm的间隙;
步骤五,进行卷绕,将绝缘处理后的正极片5与负极片层叠设置,正、负极片用隔膜6分隔绝缘,由正极片5头部端开始卷绕得到圆柱形卷芯,卷绕采用极耳收尾。卷绕时,正极片5在最外层围绕内层的负极片进行卷绕;
步骤六,如图3所示,进行封装,锂电池封装外壳采用铝塑膜7,铝塑膜7上设置有圆形的凹槽8,将圆柱形卷芯放置入凹槽8并将处于竖直方向的正极极耳2、负极极耳3弯折90°,将铝塑膜7对折并热压合使凹槽8封闭,正极极耳2、负极极耳3处于两层铝塑膜7之间的部分两端面均贴有绝缘胶纸4,再依次进行扩口、注液、化成和二封;Step 6, as shown in FIG. 3, encapsulate, the lithium battery packaging shell is made of aluminum-plastic film 7, and the aluminum-plastic film 7 is provided with a circular groove 8, and the cylindrical winding core is placed in the groove 8 and will be in a vertical position. The
步骤七,如图4所示,采用冲切的方式成型,将铝塑膜7的对折连接面冲切成圆形面,圆形面与凹槽8为同心圆,圆形面的直径大于凹槽8的直径,将圆形面大于凹槽8的部分向凹槽8方向弯折形成弯折部10,将漏出的正极极耳2、负极极耳3向远离凹槽方向弯折,得到图1所示的锂电池1。Step 7, as shown in FIG. 4 , forming by punching, punching the folded connecting surface of the aluminum-plastic film 7 into a circular surface, the circular surface and the groove 8 are concentric circles, and the diameter of the circular surface is larger than the concave surface. The diameter of the groove 8, the part of the circular surface larger than the groove 8 is bent in the direction of the groove 8 to form a bending
步骤八,按常规方法对锂电池1进行充放电活化。In the eighth step, the
本实施例1提供的圆饼状锂电池1相比于现有的方形电池,在圆型电池仓的直径不变的情况下,容量对比如下表所示:Compared with the existing square battery, the round cake-shaped
实施例2Example 2
如图5所示,一种锂电池1,锂电池1为圆饼状,锂电池1侧壁外侧环绕有弯折部10,弯折部10与锂电池1的其中一端面一体连接,锂电池1的正极极耳2、负极极耳3由锂电池1内部通过弯折部10引出。正极极耳2和负极极耳3成180°引出。As shown in FIG. 5, a
实施例3Example 3
如图6所示,一种锂电池1,锂电池1为圆饼状,锂电池1侧壁外侧环绕有弯折部10,弯折部10与锂电池1的其中一端面一体连接,锂电池1的正极极耳2、负极极耳3由锂电池1内部通过弯折部10引出。正极极耳2和负极极耳3成90°引出。As shown in FIG. 6, a
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