CN209885558U - A biomass boiler denitrification device - Google Patents

A biomass boiler denitrification device Download PDF

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CN209885558U
CN209885558U CN201920350715.8U CN201920350715U CN209885558U CN 209885558 U CN209885558 U CN 209885558U CN 201920350715 U CN201920350715 U CN 201920350715U CN 209885558 U CN209885558 U CN 209885558U
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denitration
layer
tank
biomass boiler
flue gas
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王金
刘超
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Jilin Vientiane Biomass Technology Co Ltd
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Jilin Vientiane Biomass Technology Co Ltd
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Abstract

本实用新型公开了一种生物质锅炉脱硝装置,包括底座、脱硝箱、进气管、烟气过滤机构、脱硝池、温度传感器、保护罩、控制模块、排液管、进液管以及搅拌轴,所述底座上侧固定安装有脱硝箱,所述脱硝箱右下侧设置有进气管。本实用新型通过设置在进气管左侧的烟气过滤机构可以实现对烟气中的灰尘进行吸附,防止灰尘进入脱硝池,浪费脱硝液,造成资源浪费,成本增高,设置的温度传感器可以实现对脱硝池内的温度进行检测,通过设置的发热管可以实现对脱硝液进行加热,使脱硝液反应充分,提高脱硝的效率,设置的搅拌轴可以实现对脱硝液进行均匀搅拌,提高脱硝的效率,设置的第一脱硝层与第二脱硝层可以进一步提高脱硝的效率,降低脱硝的成本。

Figure 201920350715

The utility model discloses a denitrification device for a biomass boiler, which comprises a base, a denitration box, an air inlet pipe, a flue gas filtering mechanism, a denitration tank, a temperature sensor, a protective cover, a control module, a liquid discharge pipe, a liquid inlet pipe and a stirring shaft. A denitration box is fixedly installed on the upper side of the base, and an air intake pipe is arranged on the lower right side of the denitration box. The utility model can realize the adsorption of the dust in the flue gas through the flue gas filter mechanism arranged on the left side of the air inlet pipe, prevent the dust from entering the denitration tank, waste the denitration liquid, cause the waste of resources and increase the cost, and the provided temperature sensor can realize the The temperature in the denitration tank is detected, and the heating tube can be used to heat the denitration solution, so that the denitration solution can fully react and improve the efficiency of denitration. The first denitration layer and the second denitration layer can further improve the efficiency of denitration and reduce the cost of denitration.

Figure 201920350715

Description

一种生物质锅炉脱硝装置A biomass boiler denitrification device

技术领域technical field

本实用新型属于生物质锅炉脱硝技术领域,具体涉及一种生物质锅炉脱硝装置。The utility model belongs to the technical field of biomass boiler denitration, in particular to a biomass boiler denitration device.

背景技术Background technique

我国是能源消耗大国,由于大量使用化石燃料,造成能源短缺和环境恶化等问题,因此可持续、低污染、能耗低的新能源迫在眉睫。生物质能作为一种可持续、低污染的新型燃料,已经在锅炉燃料中占据重要的地位。至2010年,中国生物质能发电装机容量将超过3000MW。生物质是一种可再生资源,产量大,能够实现二氧化碳的“低排放”,符合低碳经济的要求。生物质与煤粉相比,几乎不含硫,所以烟气中的SO2排放也低于最高的环保要求,但是生物质燃料氮含量为1.2%-2.5%,在锅炉燃烧后烟气中的NOx排放浓度一般在250~350mg/Nm3。所以利用生物质作燃料时锅炉环保措施不用担心的污染,但需控制处理烟气中NOx造成的污染。随着我国环保形式的严峻,大多数生物质锅炉是按照锅炉火电厂环保要求执行,但通过传统的脱硝工艺要实现<100mg/Nm3,甚至重点区域超净排放的<50mg/Nm3有一定的困难。my country is a big energy-consuming country. Due to the large-scale use of fossil fuels, energy shortages and environmental degradation are caused. Therefore, sustainable, low-pollution, and low-energy consumption new energy sources are imminent. As a sustainable and low-polluting new fuel, biomass energy has occupied an important position in boiler fuel. By 2010, the installed capacity of biomass power generation in China will exceed 3000MW. Biomass is a renewable resource with large output, which can achieve "low emission" of carbon dioxide and meet the requirements of a low-carbon economy. Compared with pulverized coal, biomass contains almost no sulfur, so the SO2 emission in the flue gas is also lower than the highest environmental protection requirements, but the nitrogen content of biomass fuel is 1.2%-2.5%, and the NOx in the flue gas after boiler combustion The emission concentration is generally 250 ~ 350mg/Nm3. Therefore, when using biomass as fuel, the boiler environmental protection measures do not need to worry about pollution, but it is necessary to control the pollution caused by NOx in the flue gas. With the severe environmental protection in my country, most biomass boilers are implemented in accordance with the environmental protection requirements of boiler thermal power plants, but it is difficult to achieve <100mg/Nm3 through traditional denitrification processes, and even <50mg/Nm3 of ultra-clean emissions in key areas .

现在的脱硝设备不够智能化,脱硝过程相当复杂,脱硝效率一般都很低,而且除尘效率不高,既增加了成本,又浪费了资源,传统的除尘与脱硝技术结合不够完美,而且脱硝设备不够简洁化,实施过程中存在许多问题,并且智能化操作水平不高,导致脱硝的成本提高。The current denitration equipment is not intelligent enough, the denitration process is quite complicated, the denitration efficiency is generally low, and the dust removal efficiency is not high, which not only increases the cost, but also wastes resources. Simplicity, there are many problems in the implementation process, and the intelligent operation level is not high, resulting in an increase in the cost of denitrification.

实用新型内容Utility model content

为解决上述背景技术中提出的问题。本实用新型提供了一种生物质锅炉脱硝装置,具有结构简单,使用方便,脱硝的效率高,降低成本,节约资源。In order to solve the problems raised in the above background art. The utility model provides a biomass boiler denitrification device, which has the advantages of simple structure, convenient use, high denitration efficiency, cost reduction and resource saving.

为实现上述目的,本实用新型提供如下技术方案:一种生物质锅炉脱硝装置,包括底座、脱硝箱、进气管、烟气过滤机构、脱硝池、温度传感器、保护罩、控制模块、排液管、进液管、搅拌轴以及发热管,所述底座上侧固定安装有脱硝箱,所述脱硝箱右下侧设置有进气管,所述进气管左侧固定连接有烟气过滤机构,所述烟气过滤机构内部设置有吸灰板,所述吸灰板左侧固定安装有透气膜,所述进气管末端通入脱硝池,所述脱硝池底部中间固定安装有温度传感器,所述温度传感器下侧安装有控制模块,所述脱硝池左下侧固定连接有排液管,所述脱硝池左上侧固定安装有进液管,所述脱硝池内部设置有搅拌轴,所述搅拌轴顶部通过安装槽固定安装在旋转盘的下侧,所述旋转盘中间开设有连接孔,所述连接孔与转轴底端转动连接,所述转轴左右两侧均设置有分离板,所述分离板上开设有多个透气孔,所述分离板上侧固定安装有第一脱硝层,所述第一脱硝层上侧固定安装有第二脱硝层,所述第二脱硝层上侧开设有集气仓,所述集气仓左侧设置有左出气管,所述集气仓右侧设置有右出气管。In order to achieve the above purpose, the utility model provides the following technical solutions: a biomass boiler denitrification device, comprising a base, a denitration box, an air intake pipe, a flue gas filter mechanism, a denitration tank, a temperature sensor, a protective cover, a control module, and a drain pipe , a liquid inlet pipe, a stirring shaft and a heating pipe, a denitration box is fixedly installed on the upper side of the base, an intake pipe is arranged on the lower right side of the denitration box, and a flue gas filter mechanism is fixedly connected to the left side of the intake pipe. An ash suction plate is arranged inside the flue gas filter mechanism. A breathable membrane is fixedly installed on the left side of the ash suction plate. A control module is installed on the lower side, a drain pipe is fixedly connected to the lower left side of the denitrification tank, a liquid inlet pipe is fixedly installed on the upper left side of the denitration tank, a stirring shaft is arranged inside the denitration tank, and the top of the stirring shaft is installed The groove is fixedly installed on the lower side of the rotating disk, and a connecting hole is opened in the middle of the rotating disk. The connecting hole is rotatably connected with the bottom end of the rotating shaft. The left and right sides of the rotating shaft are provided with separation plates, and the separation plates are provided with a plurality of ventilation holes, a first denitration layer is fixedly installed on the upper side of the separation plate, a second denitration layer is fixedly installed on the upper side of the first denitration layer, and a gas collecting bin is opened on the upper side of the second denitration layer, so A left air outlet pipe is provided on the left side of the gas collecting bin, and a right air outlet pipe is provided on the right side of the gas collecting bin.

优选的,所述脱硝池内部放置有脱硝剂混合而成的脱硝液,所述脱硝剂为液氨、氨气或尿素溶液。Preferably, a denitration solution mixed with a denitration agent is placed inside the denitration tank, and the denitration agent is liquid ammonia, ammonia gas or urea solution.

优选的,所述温度传感器外侧设置有保护罩。Preferably, a protective cover is provided outside the temperature sensor.

优选的,所述控制模块固定安装在底座内部,所述控制模块内部设置有操作面板与PLC控制器,所述PLC控制器的型号为AH-500。Preferably, the control module is fixedly installed inside the base, an operation panel and a PLC controller are arranged inside the control module, and the model of the PLC controller is AH-500.

优选的,所述搅拌轴的数量为三个,所述搅拌轴内部均设置有发热管。Preferably, the number of the stirring shafts is three, and heating pipes are arranged inside the stirring shafts.

优选的,所述转动轴通过输出轴与驱动电机进行传动连接,所述驱动电机外部设置有电机保护罩。Preferably, the rotating shaft is in a transmission connection with a driving motor through an output shaft, and a motor protective cover is provided outside the driving motor.

优选的,所述第一脱硝层与第二脱硝层内部均设置有脱硝剂层,所述第一脱硝层与第二脱硝层均为透气层。Preferably, both the first denitration layer and the second denitration layer are provided with a denitration agent layer, and both the first denitration layer and the second denitration layer are breathable layers.

与现有技术相比,本实用新型的有益效果是:Compared with the prior art, the beneficial effects of the present utility model are:

1、本实用新型通过设置在进气管左侧的烟气过滤机构可以实现对烟气中的灰尘进行吸附,防止灰尘进入脱硝池,浪费脱硝液,造成资源浪费,成本增高,设置的温度传感器可以实现对脱硝池内的温度进行检测,通过设置的发热管可以实现对脱硝液进行加热,使脱硝液反应充分,提高脱硝的效率。1. The present utility model can realize the adsorption of dust in the flue gas through the flue gas filter mechanism arranged on the left side of the air intake pipe, prevent the dust from entering the denitration tank, waste the denitration liquid, cause waste of resources, and increase the cost. The temperature in the denitrification tank can be detected, and the denitrification liquid can be heated through the set heating pipe, so that the denitration liquid can be fully reacted and the efficiency of denitration can be improved.

2、本实用新型设置的搅拌轴可以实现对脱硝液进行均匀搅拌,提高脱硝的效率,设置的第一脱硝层与第二脱硝层可以进一步提高脱硝的效率,降低脱硝的成本,设置的左出气管与右出气管均可进行出气。2. The stirring shaft provided by the utility model can realize uniform stirring of the denitrification liquid, improve the efficiency of denitration, and the set first denitration layer and the second denitration layer can further improve the efficiency of denitration and reduce the cost of denitration. Both the trachea and the right exit trachea can be used for exhalation.

附图说明Description of drawings

图1为本实用新型的整体结构示意图;Fig. 1 is the overall structure schematic diagram of the present utility model;

图2为本实用新型的烟气过滤机构的部分结构示意图;Fig. 2 is the partial structure schematic diagram of the smoke filter mechanism of the present invention;

图3为本实用新型的旋转盘的底部结构示意图。FIG. 3 is a schematic diagram of the bottom structure of the rotary disk of the present invention.

图中:1、底座,2、脱硝箱,3、进气管,4、烟气过滤机构,401、吸灰板,402、透气膜,5、脱硝池,6、温度传感器,7、保护罩,8、控制模块,9、排液管,10、进液管,11、搅拌轴,12、发热管,13、旋转盘,131、安装槽,132、连接孔,14、转轴,15、驱动电机,16、分离板,17、第一脱硝层,18、第二脱硝层,19、集气仓,20、左出气管,21、右出气管。In the picture: 1. Base, 2. Denitrification box, 3. Intake pipe, 4. Flue gas filter mechanism, 401, Ash suction plate, 402, Breathable membrane, 5. Denitrification tank, 6. Temperature sensor, 7. Protective cover, 8. Control module, 9, Drain pipe, 10, Liquid inlet pipe, 11, Stirring shaft, 12, Heating pipe, 13, Rotating plate, 131, Installation slot, 132, Connection hole, 14, Rotating shaft, 15, Drive motor , 16, the separation plate, 17, the first denitration layer, 18, the second denitration layer, 19, the gas collection bin, 20, the left air outlet, 21, the right air outlet.

具体实施方式Detailed ways

下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。The technical solutions in the embodiments of the present utility model will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present utility model. Obviously, the described embodiments are only a part of the embodiments of the present utility model, rather than all the implementations. example. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present invention.

请参阅图1-3,本实用新型提供以下技术方案:一种生物质锅炉脱硝装置,包括底座1、脱硝箱2、进气管3、烟气过滤机构4、脱硝池5、温度传感器6、保护罩7、控制模块8、排液管9、进液管10、搅拌轴11以及发热管12,底座1上侧固定安装有脱硝箱2,脱硝箱2右下侧设置有进气管3,进气管3左侧固定连接有烟气过滤机构4,可以实现对烟气中的灰尘进行处理,提高脱硝的效率,烟气过滤机构4内部设置有吸灰板401,吸灰板401左侧固定安装有透气膜402,进气管3末端通入脱硝池5,脱硝池5底部中间固定安装有温度传感器6,可以检测脱硝液的温度,温度传感器6下侧安装有控制模块8,脱硝池5左下侧固定连接有排液管9,脱硝池5左上侧固定安装有进液管10,脱硝池5内部设置有搅拌轴11,可以实现对脱硝液进行搅拌均匀,提高脱硝速率,搅拌轴11顶部通过安装槽131固定安装在旋转盘13的下侧,旋转盘13中间开设有连接孔132,连接孔132与转轴14底端转动连接,转轴14左右两侧均设置有分离板16,分离板16上开设有多个透气孔,分离板16上侧固定安装有第一脱硝层17,第一脱硝层17上侧固定安装有第二脱硝层18,进一步提高脱硝的效率,第二脱硝层18上侧开设有集气仓19,集气仓19左侧设置有左出气管20,集气仓19右侧设置有右出气管21。1-3, the present utility model provides the following technical solutions: a biomass boiler denitrification device, comprising a base 1, a denitration box 2, an air intake pipe 3, a flue gas filter mechanism 4, a denitration tank 5, a temperature sensor 6, a protection The cover 7, the control module 8, the drain pipe 9, the liquid inlet pipe 10, the stirring shaft 11 and the heating pipe 12, the denitration box 2 is fixedly installed on the upper side of the base 1, and the air inlet pipe 3 is arranged on the lower right side of the denitration box 2. 3. A flue gas filter mechanism 4 is fixedly connected on the left side, which can realize the treatment of dust in the flue gas and improve the efficiency of denitration. The flue gas filter mechanism 4 is provided with an ash suction plate 401, and the left side of the ash suction plate 401 is fixedly installed with a The gas permeable membrane 402, the end of the air inlet pipe 3 leads to the denitration tank 5, the temperature sensor 6 is fixedly installed in the middle of the bottom of the denitration tank 5, which can detect the temperature of the denitrification liquid. A drain pipe 9 is connected, a liquid inlet pipe 10 is fixedly installed on the upper left side of the denitration tank 5, and a stirring shaft 11 is arranged inside the denitration tank 5, which can realize the uniform stirring of the denitrification liquid and improve the denitration rate. The top of the stirring shaft 11 passes through the installation groove 131 is fixedly installed on the lower side of the rotating disk 13, a connecting hole 132 is opened in the middle of the rotating disk 13, and the connecting hole 132 is rotatably connected with the bottom end of the rotating shaft 14. The left and right sides of the rotating shaft 14 are provided with separation plates 16, and the separation plate 16 is provided with There are a plurality of ventilation holes, a first denitration layer 17 is fixedly installed on the upper side of the separation plate 16, and a second denitration layer 18 is fixedly installed on the upper side of the first denitration layer 17 to further improve the efficiency of denitration. The upper side of the second denitration layer 18 is provided with The gas collecting chamber 19 is provided with a left air outlet pipe 20 on the left side of the gas collecting chamber 19 and a right air outlet pipe 21 on the right side of the gas collecting chamber 19 .

进一步的,脱硝池5内部放置有脱硝剂混合而成的脱硝液,可以进行脱硝,脱硝剂为液氨、氨气或尿素溶液。Further, a denitration liquid mixed with a denitration agent is placed inside the denitration tank 5, which can be denitrified, and the denitration agent is liquid ammonia, ammonia gas or urea solution.

进一步的,温度传感器6外侧设置有保护罩7,用于保护温度传感器6。Further, a protective cover 7 is provided outside the temperature sensor 6 for protecting the temperature sensor 6 .

进一步的,控制模块8固定安装在底座1内部,控制模块8内部设置有操作面板与PLC控制器,PLC控制器的型号为AH-500。Further, the control module 8 is fixedly installed inside the base 1 , an operation panel and a PLC controller are arranged inside the control module 8 , and the model of the PLC controller is AH-500.

进一步的,搅拌轴11的数量为三个,搅拌轴11内部均设置有发热管12,可以实现对脱硝液进行加热处理,提高脱硝的速率。Further, the number of stirring shafts 11 is three, and heating pipes 12 are arranged inside the stirring shafts 11, which can realize the heating treatment of the denitrification liquid and improve the denitration rate.

进一步的,转动轴14通过输出轴与驱动电机15进行传动连接,驱动电机15外部设置有电机保护罩。Further, the rotating shaft 14 is in a transmission connection with the driving motor 15 through the output shaft, and a motor protective cover is provided outside the driving motor 15 .

进一步的,第一脱硝层17与第二脱硝层18内部均设置有脱硝剂层,第一脱硝层17与第二脱硝层18均为透气层,可以提高脱硝的效率。Further, both the first denitration layer 17 and the second denitration layer 18 are provided with a denitration agent layer, and the first denitration layer 17 and the second denitration layer 18 are both breathable layers, which can improve the efficiency of denitration.

本实用新型的工作原理及使用流程:本实用新型在使用时,通过设置的进气管3将烟气通入烟气过滤机构4中进行过滤处理,可以实现对烟气中的灰尘进行吸附,防止灰尘影响后续的脱硝,防止灰尘进入脱硝池5,浪费脱硝液,造成资源浪费,成本增高,通过设置的温度传感器6可以实现对脱硝池5内的温度进行检测,利用发热管12可以实现对脱硝液进行加热,使脱硝液反应充分,提高脱硝的效率,通过设置的控制模块8可以实现对脱硝的过程进行控制,通过驱动电机15可以实现对旋转盘13提供动力,设置在旋转盘13下侧的搅拌轴11可以实现对脱硝液进行均匀搅拌,提高脱硝的效率,通过设置的第一脱硝层17与第二脱硝层18可以进一步提高脱硝的效率,降低脱硝的成本。The working principle and use process of the utility model: when the utility model is in use, the flue gas is passed into the flue gas filtering mechanism 4 through the provided air intake pipe 3 for filtering treatment, so as to realize the adsorption of dust in the flue gas and prevent the Dust affects subsequent denitrification, prevents dust from entering denitration tank 5, wastes denitrification liquid, causes waste of resources, and increases cost. The temperature sensor 6 can be used to detect the temperature in denitration tank 5, and the heating pipe 12 can be used to realize denitrification. The denitrification liquid is heated to make the denitration liquid react sufficiently and improve the efficiency of denitration. The control module 8 can be used to control the process of denitration. The drive motor 15 can provide power to the rotating disk 13, which is arranged on the lower side of the rotating disk 13. The stirring shaft 11 can realize the uniform stirring of the denitrification solution and improve the denitration efficiency. The first denitration layer 17 and the second denitration layer 18 can further improve the denitration efficiency and reduce the denitration cost.

尽管已经示出和描述了本实用新型的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本实用新型的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本实用新型的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes and modifications can be made to these embodiments without departing from the principles and spirit of the present invention , alternatives and modifications, the scope of the present invention is defined by the appended claims and their equivalents.

Claims (7)

1. The utility model provides a biomass boiler denitrification facility, includes base (1), denitration case (2), intake pipe (3), flue gas filter mechanism (4), denitration pond (5), temperature sensor (6), safety cover (7), control module (8), fluid-discharge tube (9), feed liquor pipe (10), (mixing) shaft (11) and heating tube (12), its characterized in that: the denitration device is characterized in that a denitration box (2) is fixedly mounted on the upper side of a base (1), an air inlet pipe (3) is arranged on the lower right side of the denitration box (2), a flue gas filtering mechanism (4) is fixedly connected to the left side of the air inlet pipe (3), an ash suction plate (401) is arranged inside the flue gas filtering mechanism (4), a breathable film (402) is fixedly mounted on the left side of the ash suction plate (401), the tail end of the air inlet pipe (3) is introduced into a denitration tank (5), a temperature sensor (6) is fixedly mounted in the middle of the bottom of the denitration tank (5), a control module (8) is mounted on the lower side of the temperature sensor (6), a liquid discharge pipe (9) is fixedly connected to the lower left side of the denitration tank (5), a liquid inlet pipe (10) is fixedly mounted on the upper left side of the denitration tank (5), a stirring shaft (11) is arranged, connecting hole (132) have been seted up in the middle of rotary disk (13), connecting hole (132) are rotated with pivot (14) bottom and are connected, pivot (14) the left and right sides all is provided with separator plate (16), a plurality of bleeder vents have been seted up on separator plate (16), separator plate (16) upside fixed mounting has first denitration layer (17), first denitration layer (17) upside fixed mounting has second denitration layer (18), gas collection storehouse (19) have been seted up to second denitration layer (18) upside, gas collection storehouse (19) left side is provided with left outlet duct (20), gas collection storehouse (19) right side is provided with right outlet duct (21).
2. The denitration device for the biomass boiler according to claim 1, characterized in that: denitration liquid formed by mixing denitration agents is placed in the denitration tank (5), and the denitration agents are liquid ammonia, ammonia gas or urea solution.
3. The denitration device for the biomass boiler according to claim 1, characterized in that: and a protective cover (7) is arranged on the outer side of the temperature sensor (6).
4. The denitration device for the biomass boiler according to claim 1, characterized in that: control module (8) fixed mounting is inside base (1), inside operating panel and the PLC controller of being provided with of control module (8), the model of PLC controller is AH-500.
5. The denitration device for the biomass boiler according to claim 1, characterized in that: the number of the stirring shafts (11) is three, and heating tubes (12) are arranged in the stirring shafts (11).
6. The denitration device for the biomass boiler according to claim 1, characterized in that: the rotating shaft (14) is in transmission connection with the driving motor (15) through an output shaft, and a motor protection cover is arranged outside the driving motor (15).
7. The denitration device for the biomass boiler according to claim 1, characterized in that: the denitration agent layers are arranged inside the first denitration layer (17) and the second denitration layer (18), and the first denitration layer (17) and the second denitration layer (18) are breathable layers.
CN201920350715.8U 2019-03-19 2019-03-19 A biomass boiler denitrification device Expired - Fee Related CN209885558U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113663497A (en) * 2021-08-23 2021-11-19 丁新怡 Industrial denitration flue gas purification device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113663497A (en) * 2021-08-23 2021-11-19 丁新怡 Industrial denitration flue gas purification device
CN113663497B (en) * 2021-08-23 2024-05-03 秦皇岛市徐山口危险废物处理有限公司 Industrial denitration flue gas purification device

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