CN209865731U - Advanced Oxidation Coupled Scrubbing Exhaust Gas Purification Tower - Google Patents
Advanced Oxidation Coupled Scrubbing Exhaust Gas Purification Tower Download PDFInfo
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Abstract
本实用新型涉及一种高级氧化耦合洗涤废气净化塔,属于工业废气净化处理技术领域。包括塔体,塔体底部一侧开设进气口,塔体顶部开设出气口;塔体内从下往上依次设有高能粒子束发生器、穿孔布气板、初级喷淋吸收系统、清水喷淋系统、除雾层;高能粒子束发生器设于进气口下方。本实用新型通过对废气氧化、洗涤、除雾后,满足废气治理的排放标准。
The utility model relates to an advanced oxidation coupling washing waste gas purification tower, which belongs to the technical field of industrial waste gas purification treatment. Including the tower body, an air inlet is set on the bottom side of the tower body, and an air outlet is set on the top of the tower body; the tower body is equipped with a high-energy particle beam generator, a perforated air distribution plate, a primary spray absorption system, and a water spraying system from bottom to top. system, defogging layer; the high-energy particle beam generator is located below the air inlet. After the utility model oxidizes, washes and defoggs the waste gas, it meets the discharge standard of the waste gas treatment.
Description
技术领域technical field
本实用新型涉及一种高级氧化耦合洗涤废气净化塔,属于工业废气净化处理技术领域。The utility model relates to an advanced oxidation coupling washing waste gas purification tower, which belongs to the technical field of industrial waste gas purification treatment.
背景技术Background technique
低浓度挥发有机物的的废气处理过程中,如有机硫、有机胺、芳烃类等有机废气,因浓度低,高恶臭、水溶性差、分子稳定等特性,采用燃烧法、生物法、等离子等技术不能满足治理达标的要求。故开发高级耦合氧化废气净化装备尤为必要。In the waste gas treatment process of low-concentration volatile organic compounds, such as organic sulfur, organic amines, aromatics and other organic waste gases, due to the characteristics of low concentration, high odor, poor water solubility, and molecular stability, the combustion method, biological method, plasma and other technologies cannot be used. Meet governance compliance requirements. Therefore, it is particularly necessary to develop advanced coupled oxidation exhaust gas purification equipment.
实用新型内容Utility model content
本实用新型的目的是提供一种高级氧化耦合洗涤废气净化塔,通过对废气氧化、洗涤、除雾后,满足废气治理的排放标准。The purpose of the utility model is to provide an advanced oxidation coupling scrubbing waste gas purification tower, which can meet the discharge standard of waste gas treatment after oxidizing, washing and defogging the waste gas.
本实用新型所述的高级氧化耦合洗涤废气净化塔,包括塔体,塔体底部一侧开设进气口,塔体顶部开设出气口;塔体内从下往上依次设有高能粒子束发生器、穿孔布气板、初级喷淋吸收系统、清水喷淋系统、除雾层;高能粒子束发生器设于进气口下方;The advanced oxidation coupling scrubbing exhaust gas purification tower described in the utility model includes a tower body, an air inlet is provided on one side of the bottom of the tower body, and an air outlet is provided on the top of the tower body; a high-energy particle beam generator, Perforated air distribution plate, primary spray absorption system, clear water spray system, defogging layer; the high-energy particle beam generator is located below the air inlet;
初级喷淋吸收系统包括初级喷淋层,初级喷淋层上设有填料层,初级喷淋层一侧贯穿塔体设有初级喷淋口,初级喷淋口通过管路连接初级循环泵,初级循环泵连通初级循环水箱,初级循环水箱连通塔体底部;The primary spray absorption system includes a primary spray layer, a packing layer is arranged on the primary spray layer, and a primary spray port is provided through the tower body on one side of the primary spray layer, and the primary spray port is connected to the primary circulation pump through a pipeline. The circulating pump is connected to the primary circulating water tank, and the primary circulating water tank is connected to the bottom of the tower body;
清水喷淋系统包括清水喷淋层,清水喷淋层下方沿塔体内壁设有清水采集斜板,清水采集斜板下方设有清水收集盘,清水收集盘对应清水喷淋层和清水采集斜板设置,清水收集盘通过管路连通清水循环水箱,清水循环水箱连通清水循环泵,清水喷淋层一侧贯穿塔体设有清水喷淋口,清水循环泵通过管路连通清水喷淋口。The clean water spray system includes a clean water spray layer, a clean water collection slant plate is arranged along the inner wall of the tower under the clean water spray layer, and a clean water collection plate is arranged under the clean water collection slant plate, and the clean water collection plate corresponds to the clean water spray layer and the clean water collection slant plate The clean water collecting plate is connected to the clean water circulating water tank through the pipeline, and the clean water circulating water tank is connected to the clean water circulating pump. One side of the clean water spray layer runs through the tower body and is provided with a clean water spray port, and the clean water circulating pump is connected to the clean water spray port through the pipeline.
废气从进气口进入,高能粒子束发生器设于进气口下方,高能离子束通过高压放电的形式可产生臭氧、氢基自由基等高能离子,高能离子可对废气中污染分子进行氧化、断链、矿化,然后经过穿孔布气板后,气体分散更均匀,废气继续上升,依次经过初级喷淋层洗涤和填料层吸附,废气从清水收集盘侧边继续上升,经过清水喷淋层洗涤后,再经过除雾层除水,成为满足排放标注的废气,通过出气口排出。Exhaust gas enters from the air inlet, and the high-energy particle beam generator is installed under the air inlet. The high-energy ion beam can generate high-energy ions such as ozone and hydrogen radicals through high-voltage discharge. The high-energy ions can oxidize the pollutant molecules in the exhaust gas, Chain breaking, mineralization, and after passing through the perforated gas distribution plate, the gas is dispersed more evenly, and the exhaust gas continues to rise, and then passes through the primary spray layer for washing and packing layer adsorption, and the exhaust gas continues to rise from the side of the clean water collection plate, and passes through the clean water spray layer After washing, it goes through the demisting layer to remove water, and becomes exhaust gas that meets the emission standards, and is discharged through the air outlet.
所述的初级喷淋层和填料层至少间隔叠放两层。洗涤和吸附效果更好,废气净化效果更好。The primary spray layer and packing layer are at least two layers stacked at intervals. The washing and adsorption effect is better, and the exhaust gas purification effect is better.
所述的初级喷淋层包括一级喷淋层、二级喷淋层和三级喷淋层;填料层包括一级填料层、二级填料层;一级喷淋层上方设置一级填料层;一级填料层上方设置二级喷淋层,二级喷淋层上方设置二级填料层;二级填料层上方设置三级喷淋层;一级喷淋层一侧贯穿塔体设置一级喷淋口,二级喷淋层一侧贯穿塔体设置二级喷淋口,三级喷淋层一侧贯穿塔体设置三级喷淋口,一级喷淋口、二级喷淋口和三级喷淋口分别通过管路并联初级循环泵。The primary spray layer includes a primary spray layer, a secondary spray layer and a tertiary spray layer; the packing layer includes a primary packing layer and a secondary packing layer; a primary packing layer is arranged above the primary spraying layer ;A secondary spraying layer is set above the primary packing layer, and a secondary packing layer is set above the secondary spraying layer; a third spraying layer is set above the secondary packing layer; Spray outlets, one side of the second-level spray layer runs through the tower body to set up a second-level spray outlet, one side of the third-level spray layer runs through the tower body to set up a third-level spray outlet, the first-level spray outlet, the second-level spray outlet and the The three-stage spray ports are respectively connected in parallel with the primary circulation pump through pipelines.
所述的一级填料层、二级填料层的填料为筒制竹炭。The fillers of the primary packing layer and the secondary packing layer are bamboo charcoal made in cylinders.
所述的填料层的填料为筒制竹炭。The filler of the filler layer is bamboo charcoal made in a tube.
所述的初级循环水箱内可以添加喷淋药剂,喷淋药剂为双氧水、硫酸亚铁和稀硫酸的混合液。A spray agent can be added to the primary circulating water tank, and the spray agent is a mixture of hydrogen peroxide, ferrous sulfate and dilute sulfuric acid.
与现有技术相比,本实用新型的有益效果是:Compared with the prior art, the beneficial effects of the utility model are:
1、本实用新型中高能离子束通过高压放电的形式可产生臭氧、氢基自由基等高能离子,高能离子可对废气中污染分子进行氧化、断链、矿化,采用两级喷淋,并对清水喷淋系统的清水进行单独回收利用,并在初级喷淋中设置填料层,增大比表面积,可让气液进行充分接触,对气体进行吸附,经过清水喷淋洗涤后,经过除雾达到废气治理的排放标准。1. The high-energy ion beam in the utility model can generate high-energy ions such as ozone and hydrogen radicals through high-voltage discharge. The high-energy ions can oxidize, break chains, and mineralize pollutant molecules in the exhaust gas. Two-stage spraying is adopted, and Separately recycle the clean water of the clear water spray system, and set a packing layer in the primary spray to increase the specific surface area, allowing the gas and liquid to fully contact and adsorb the gas. Meet emission standards for waste gas treatment.
2、初级喷淋水箱中添加喷淋药剂,采用类芬顿原理,采用双氧水作为氧化剂,采用硫酸亚铁作为液相催化剂,充分激发羟基自由基的氧化性能,同时填料层采用筒制竹炭,增大比表面积,可让气液进行充分接触,通过对初级喷淋水箱中喷淋药剂调整,调节初级喷淋水箱中喷淋液体的PH值,可产生氢氧化铁胶体,可对废气成分进行捕捉,捕捉下的混合物在循环水箱内继续进行二次氧化,从而达到废气治理的排放标准。2. Spray chemicals are added to the primary spray water tank, using the Fenton-like principle, using hydrogen peroxide as the oxidant, and ferrous sulfate as the liquid-phase catalyst to fully stimulate the oxidation performance of hydroxyl radicals. Large specific surface area allows full contact between gas and liquid. By adjusting the spray agent in the primary spray tank and adjusting the pH value of the spray liquid in the primary spray tank, ferric hydroxide colloid can be produced to capture exhaust gas components. , the captured mixture continues to undergo secondary oxidation in the circulating water tank, so as to meet the emission standards for exhaust gas treatment.
3、采用穿孔布气板,确保气体的均匀,便于对气体净化。3. The perforated gas distribution plate is used to ensure the uniformity of the gas and facilitate the purification of the gas.
4、采用多层逆流雾化喷淋,确保气液充分混合。4. Adopt multi-layer countercurrent atomization spraying to ensure full mixing of gas and liquid.
5、设备采用两种介质喷淋,下部采用药剂喷淋,上部采用清水喷淋,可实现对经过氧化后的水溶性小分子酸进行洗涤。5. The equipment is sprayed with two kinds of media, the lower part is sprayed with chemicals, and the upper part is sprayed with water, which can realize the washing of the oxidized water-soluble small molecular acid.
6、顶部除雾采用气旋除雾,确保不出现雾沫夹带。6. The top defogging adopts cyclone defogging to ensure that there is no mist entrainment.
附图说明Description of drawings
图1是本实用新型的一实施例的结构示意图。Fig. 1 is a schematic structural view of an embodiment of the utility model.
图中:1、高能粒子束发生器 2、进气口 3、穿孔布气板 4、一级喷淋层 5、第一带视镜人孔 6、一级填料层 7、二级喷淋层 8、第二带视镜人孔 9、二级填料层 10、三级喷淋层11、第三带视镜人孔 12、人孔 13、除雾层 14、出气口 15、清水喷淋层 16、清水喷淋口 17、清水采集斜板 18、清水收集盘 19、三级喷淋口 20、第二对开视镜 21、二级喷淋口 22、一级喷淋口 23、清水循环泵 24、清水循环水箱 25、初级循环泵 26、初级循环水箱 27、第一对开视镜 28、第三对开视镜 29、塔体。In the figure: 1. High-energy particle beam generator 2. Air inlet 3. Perforated gas distribution plate 4. Primary spray layer 5. First manhole with sight glass 6. Primary packing layer 7. Secondary spray layer 8. The second manhole with mirror 9, the second packing layer 10, the third spray layer 11, the third manhole with mirror 12, the manhole 13, the defogging layer 14, the air outlet 15, and the water spray layer 16. Clean water spray port 17, clean water collection inclined plate 18, clean water collection tray 19, third-stage spray port 20, second pair of mirrors 21, secondary spray port 22, primary spray port 23, clean water circulation Pump 24, clean water circulating water tank 25, primary circulating pump 26, primary circulating water tank 27, first pair of mirrors 28, third pair of mirrors 29, tower body.
图中箭头表示喷淋水和喷淋清水流动方向。Arrows in the figure indicate the flow direction of spray water and spray clear water.
具体实施方式Detailed ways
下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案作进一步清楚、完整地描述:The technical solutions in the embodiments of the present invention will be further clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention:
实施例1Example 1
如图1所示,本实用新型所述的高级氧化耦合洗涤废气净化塔,包括塔体29,塔体29底部一侧开设进气口2,塔体29顶部开设出气口14;塔体29内从下往上依次设有高能粒子束发生器1、穿孔布气板3、初级喷淋吸收系统、清水喷淋系统、除雾层13;高能粒子束发生器1设于进气口2下方;As shown in Figure 1, the advanced oxidation coupling scrubbing exhaust gas purification tower described in the utility model includes a tower body 29, an air inlet 2 is provided on one side of the bottom of the tower body 29, and an air outlet 14 is provided at the top of the tower body 29; A high-energy particle beam generator 1, a perforated air distribution plate 3, a primary spray absorption system, a clear water spray system, and a defogging layer 13 are provided in sequence from bottom to top; the high-energy particle beam generator 1 is located below the air inlet 2;
初级喷淋吸收系统包括初级喷淋层,初级喷淋层上设有填料层,初级喷淋层一侧贯穿塔体29设有初级喷淋口,初级喷淋口通过管路连接初级循环泵25,初级循环泵25连通初级循环水箱26,初级循环水箱26连通塔体29底部;The primary spray absorption system includes a primary spray layer, a packing layer is arranged on the primary spray layer, and a primary spray port is provided through the tower body 29 on one side of the primary spray layer, and the primary spray port is connected to the primary circulating pump 25 through a pipeline. , the primary circulating pump 25 is connected to the primary circulating water tank 26, and the primary circulating water tank 26 is connected to the bottom of the tower body 29;
清水喷淋系统包括清水喷淋层15,清水喷淋层15下方沿塔体29内壁设有清水采集斜板17,清水采集斜板17下方设有清水收集盘18,清水收集盘18对应清水喷淋层15和清水采集斜板17设置,清水收集盘18通过管路连通清水循环水箱24,清水循环水箱24连通清水循环泵23,清水喷淋层15一侧贯穿塔体29设有清水喷淋口16,清水循环泵23通过管路连通清水喷淋口16。清水通过清水循环泵由清水循环箱送入清水喷淋口16,经过清水喷淋层15进行喷淋后,由清水收集盘18收集后,再进入清水循环箱。清水在清水循环泵、清水喷淋层、清水采集斜板、清水收集盘和清水循环箱内循环流动。The clear water spraying system comprises a clear water spraying layer 15, and a clear water collecting sloping plate 17 is arranged along the inner wall of the tower body 29 below the clear water spraying layer 15, and a clear water collecting plate 18 is arranged under the clear water collecting sloping plate 17, and the clear water collecting plate 18 corresponds to the clear water spraying plate. The spray layer 15 and the clean water collection slant plate 17 are set, the clean water collecting plate 18 is connected to the clean water circulating water tank 24 through the pipeline, the clean water circulating water tank 24 is connected to the clean water circulating pump 23, and the clean water spray layer 15 side runs through the tower body 29 and is provided with clean water spraying Port 16, and the clean water circulation pump 23 is connected to the clean water spray port 16 through a pipeline. The clear water is sent into the clear water spray outlet 16 by the clear water circulation tank by the clear water circulation pump, after being sprayed through the clear water spray layer 15, after being collected by the clear water collecting tray 18, it enters the clear water circulation tank. The clean water circulates in the clean water circulation pump, the clean water spray layer, the clean water collecting inclined plate, the clean water collecting pan and the clean water circulation box.
初级喷淋层和填料层至少间隔叠放两层。The primary spray layer and the filler layer are stacked at least two layers apart.
初级喷淋层包括一级喷淋层4、二级喷淋层7和三级喷淋层10;填料层包括一级填料层6、二级填料层9;一级喷淋层4上方设置一级填料层6;一级填料层6上方设置二级喷淋层7,二级喷淋层7上方设置二级填料层9;二级填料层9上方设置三级喷淋层10;一级喷淋层4一侧贯穿塔体29设置一级喷淋口22,二级喷淋层7一侧贯穿塔体29设置二级喷淋口21,三级喷淋层10一侧贯穿塔体29设置三级喷淋口19,一级喷淋口22、二级喷淋口21和三级喷淋口19分别通过管路并联初级循环泵25。The primary spray layer includes a primary spray layer 4, a secondary spray layer 7 and a tertiary spray layer 10; the packing layer includes a primary packing layer 6 and a secondary packing layer 9; Level packing layer 6; a secondary spraying layer 7 is set above the primary packing layer 6; a secondary packing layer 9 is set above the secondary spraying layer 7; a tertiary spraying layer 10 is set above the secondary packing layer 9; One side of the spray layer 4 runs through the tower body 29 to set a first-level spray port 22, one side of the second-level spray layer 7 runs through the tower body 29 to set a second-level spray port 21, and one side of the third-level spray layer 10 runs through the tower body 29. The tertiary spray port 19 , the primary spray port 22 , the secondary spray port 21 and the tertiary spray port 19 are respectively connected in parallel with the primary circulation pump 25 through pipelines.
一级填料层6、二级填料层9的填料为筒制竹炭。The fillers of the primary filler layer 6 and the secondary filler layer 9 are bamboo charcoal made of cylinders.
填料层的填料为筒制竹炭。The filler of the filler layer is bamboo charcoal made in a tube.
所述的初级循环水箱26内可以添加喷淋药剂,喷淋药剂为双氧水、硫酸亚铁和稀硫酸的混合液。喷淋药剂混合液的制备方法如下:每立方废气双氧水添加量0.0004~0.0008升,硫酸亚铁0.0001~0.0008克,稀硫酸仅调PH值,PH值在1~5之间。在广信污泥烘干废气、南京威尔化工废气、鲁花花生油炒籽车间废气均有成功应用。臭气及非甲烷总烃均达标排放。Spray medicament can be added in the primary circulating water tank 26, and the spray medicament is a mixture of hydrogen peroxide, ferrous sulfate and dilute sulfuric acid. The preparation method of the spray agent mixture is as follows: the amount of hydrogen peroxide per cubic meter of waste gas is 0.0004-0.0008 liters, ferrous sulfate is 0.0001-0.0008 grams, and dilute sulfuric acid is only used to adjust the pH value, and the pH value is between 1 and 5. It has been successfully applied in Guangxin sludge drying waste gas, Nanjing Weier chemical waste gas, and Luhua peanut oil fried seed workshop waste gas. Odor and non-methane total hydrocarbons are discharged up to the standard.
设备均采用抗氧化的材料,如不饱和乙烯基树脂玻璃钢等。The equipment is made of anti-oxidation materials, such as unsaturated vinyl resin fiberglass and so on.
第一填料层和第二喷淋层之间塔壁上开设第一带视镜人孔5,塔壁另一侧对应开设第一对开视镜27;第二填料层和第三喷淋层之间塔壁上开设第二带视镜人孔8,塔壁另一侧对应开设第二对开视镜20;第三喷淋层与清水喷淋层之间塔壁上开设第三带视镜人孔11,塔壁另一侧对应开设第三对开视镜28。除雾层13一侧塔壁上开设人孔12。便于工作人员进出和观察。A first manhole 5 with sight glass is provided on the tower wall between the first packing layer and the second spray layer, and the first pair of open sight mirrors 27 are correspondingly opened on the other side of the tower wall; the second packing layer and the third spray layer The second manhole 8 with sight glass is set on the tower wall between them, and the second pair of sight glass 20 is opened correspondingly on the other side of the tower wall; Mirror manhole 11, the other side of the tower wall correspondingly offers the 3rd pair of open-view mirrors 28. A manhole 12 is provided on the tower wall on one side of the mist removal layer 13 . It is convenient for staff to enter and exit and observe.
工作过程或工作原理:Working process or working principle:
废气从进气口进入,高能粒子束发生器设于进气口下方,高能离子束通过高压放电的形式可产生臭氧、氢基自由基等高能离子,高能离子可对废气中污染分子进行氧化、断链、矿化,然后经过穿孔布气板后,气体分散更均匀,废气继续上升,依次经过一级喷淋层洗涤、一级填料层吸附、二级喷淋层洗涤、二级填料层吸附和三级喷淋层洗涤,废气从清水收集盘侧边继续上升,经过清水喷淋层洗涤后,再经过除雾层除水,成为满足排放标注的废气,通过出气口排出。Exhaust gas enters from the air inlet, and the high-energy particle beam generator is installed under the air inlet. The high-energy ion beam can generate high-energy ions such as ozone and hydrogen radicals through high-voltage discharge. The high-energy ions can oxidize the pollutant molecules in the exhaust gas, Chain breaking, mineralization, and after passing through the perforated gas distribution plate, the gas is dispersed more evenly, and the exhaust gas continues to rise, and then goes through the first-level spray layer washing, the first-level packing layer adsorption, the second spray layer washing, and the second-level packing layer adsorption And three-stage spray layer washing, the exhaust gas continues to rise from the side of the clean water collection tray, after being washed by the clean water spray layer, and then dewatered by the demister layer, it becomes exhaust gas that meets the emission standards, and is discharged through the air outlet.
本实用新型中对结构的方向以及相对位置关系的描述,如前后左右上下的描述,不构成对本实用新型的限制,仅为描述方便。The description of the direction and relative position of the structure in the present invention, such as the description of front, back, left, right, up and down, does not constitute a limitation of the present invention, but is only for convenience of description.
Claims (5)
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| CN201920562881.4U CN209865731U (en) | 2019-04-23 | 2019-04-23 | Advanced Oxidation Coupled Scrubbing Exhaust Gas Purification Tower |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116212613A (en) * | 2023-02-16 | 2023-06-06 | 江苏理文造纸有限公司 | Device and method for collecting and treating waste gas generated in anaerobic system of pulping and papermaking |
| CN117753188A (en) * | 2023-12-14 | 2024-03-26 | 湖南华菱涟源钢铁有限公司 | Removing agents, removal methods and equipment for impurities in mixed gas |
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2019
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116212613A (en) * | 2023-02-16 | 2023-06-06 | 江苏理文造纸有限公司 | Device and method for collecting and treating waste gas generated in anaerobic system of pulping and papermaking |
| CN117753188A (en) * | 2023-12-14 | 2024-03-26 | 湖南华菱涟源钢铁有限公司 | Removing agents, removal methods and equipment for impurities in mixed gas |
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