CN209602306U - A kind of " main-auxiliary " activated Sludge System coupling deodorization and intensified denitrification and dephosphorization - Google Patents
A kind of " main-auxiliary " activated Sludge System coupling deodorization and intensified denitrification and dephosphorization Download PDFInfo
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Description
技术领域technical field
本实用新型属于污水处理及水环境治理领域,特别是涉及到一种耦合全过程除臭及强化脱氮除磷功能的“主-辅”活性污泥系统。The utility model belongs to the field of sewage treatment and water environment treatment, in particular to a "main-auxiliary" activated sludge system that couples the whole process of deodorization and strengthens the functions of nitrogen and phosphorus removal.
背景技术Background technique
当前,中国水环境问题频出,地表水富营养化严重,局部水域水质甚至丧失饮用水水源功能,水环境质量亟待改善,很多区域水质标准亟待进一步提高,强化脱氮除磷会成为我国今后相当长时期的重要任务。与此同时,由于历史原因,很多城市污水厂建设在城区,污水收集及处理过程释放大量挥发性恶臭气体(如硫化氢、氨等),严重干扰和影响周边城市环境大气质量,污水厂的邻避效应愈加突出。水质稳定达标及恶臭气体控制是当下污水厂面临的共性问题。At present, China's water environment problems are frequent, surface water eutrophication is serious, and the water quality of some water areas even loses the function of drinking water source. important long-term tasks. At the same time, due to historical reasons, many urban sewage plants are built in urban areas. The process of sewage collection and treatment releases a large amount of volatile odorous gases (such as hydrogen sulfide, ammonia, etc.), which seriously interferes and affects the ambient air quality of surrounding cities. The avoidance effect becomes more prominent. Stable water quality compliance and odor control are common problems faced by sewage plants today.
以此同时,我们国家很多地区污水厂进水碳源严重匮乏,现有的常规处理工艺,如各种活性污泥法的变形工艺,AAO及其各种变种工艺、氧化沟、MBR、SBR及其各种变种工艺等,主要依赖传统除磷菌Accumulibacter实现EBPR(强化生物除磷),而Accumulibacter只能依赖摄取进水VFA,同时存在PAO与GAO的基质竞争等;另外,回流硝酸盐及DO对厌氧区的干扰导致厌氧区ORP较难控制在-150mv以下,对于生物除磷并不是一个理想的厌氧环境,上述诸多因素导致传统主流处理工艺生物除磷效果不稳定。此外,污泥处理段污泥脱水液高氨氮回流带来的高污染负荷、低水温季节等多种因素影响致使硝化能力不足导致出水氨氮不达标,上述诸多因素导致传统工艺脱氮除磷效果难以进一步提升,提标改造往往不得不选择对原曝气池改造投加载体形成IFAS工艺,或者新增第三级生化处理单元(如BAF、深床反硝化滤池),大大增加了工程投资,同时也增加了运营期运行成本,环境释放的温室气体也随着流程的延长而指数式上升,冗长的提标改造工艺,总体上是不可持续的。At the same time, many areas of our country suffer from severe shortage of carbon sources for sewage plants. Existing conventional treatment processes, such as deformation processes of various activated sludge methods, AAO and its variant processes, oxidation ditch, MBR, SBR and Its various variant processes mainly rely on the traditional phosphorus removal bacteria Accumulibacter to achieve EBPR (Enhanced Biological Phosphorus Removal), while Accumulibacter can only rely on the ingestion of VFA in the influent, and there is also substrate competition between PAO and GAO; in addition, the reflux of nitrate and DO Interference with the anaerobic zone makes it difficult to control the ORP below -150mv in the anaerobic zone. It is not an ideal anaerobic environment for biological phosphorus removal. Many of the above factors lead to unstable biological phosphorus removal effects of traditional mainstream treatment processes. In addition, the high pollution load caused by the high ammonia nitrogen reflux of the sludge dewatering liquid in the sludge treatment section, the low water temperature season and other factors lead to insufficient nitrification capacity and the ammonia nitrogen in the effluent does not meet the standard. The above factors make it difficult for the traditional process to remove nitrogen and phosphorus. For further improvement, standard upgrading often has to choose to transform the original aeration tank into the IFAS process, or add a third-level biochemical treatment unit (such as BAF, deep-bed denitrification filter), which greatly increases the project investment. At the same time, it also increases the operating cost during the operation period, and the greenhouse gases released by the environment also increase exponentially with the prolongation of the process. The lengthy upgrading and transformation process is generally unsustainable.
活性污泥法历经百余年发展,目前仍然是污水处理最经济有效的方法,但是传统主流活性污泥工艺面对外在扰动(水量、水质、水温变化)存在工艺调控的脆弱性,从微生物学菌群结构调控角度,由于传统主流活性污泥工艺只有在“主线”上的活性污泥工艺,虽然设置了厌氧、缺氧和好氧环境,但是以上环境受多种因素(进水水质水量波动、内回流及外回流)影响,同时要兼顾不同污染物的去除,但是不同微生物的生态位差异很大,因此工艺控制条件难以兼顾不同功能菌群的生境条件,很难实现对活性污泥菌群结构的优化调控,更难实现定向转化与控制。After more than a hundred years of development, the activated sludge process is still the most economical and effective method for sewage treatment. However, the traditional mainstream activated sludge process is vulnerable to external disturbances (water quantity, water quality, and water temperature changes). From the perspective of the control of the bacterial flora structure, because the traditional mainstream activated sludge process only has the activated sludge process on the "main line", although anaerobic, anoxic and aerobic environments are set, the above environments are affected by various factors (influent water quality water fluctuations, internal backflow and external backflow), and the removal of different pollutants must be taken into account, but the ecological niches of different microorganisms are very different, so it is difficult to take into account the habitat conditions of different functional flora under the process control conditions, and it is difficult to realize the removal of active pollutants. It is more difficult to achieve directional transformation and control for the optimization and regulation of the structure of the mud flora.
针对上述问题,目前的技术路线上的解决手段往往利用“多重手段”、“分头解决”,工艺越来越复杂,但没有做到系统性协同考虑,往往是通过冗长的工艺路线叠加解决营养盐达标,但是除臭问题依然没有解决,依然需要伴随污水处理流程的延长而沿程增加全流程的除臭措施,导致除臭系统投资及运行费用随之高昂。对目前常用的一些除臭技术进行了调研,收集法除臭设备及运行费用高,且需要加盖收集臭气形成封闭空间对设备腐蚀大;现有的其它类型的生物除臭技术,如腐殖土除臭或土壤微生物除臭技术,所采用的微生物培养基为成分较为单一的如腐殖土、或黏土及固结物水泥、石灰压制、或其它生物膜载体如火山岩等烧制或压制,上述基质或载体的加工过程使得基质变性、组份生物活性不友好,最关键的是不能定向且难以稳定培养芽孢杆菌等除臭微生物,甚至破坏微生物活性,因此,目前国内实际运行的很多除臭项目,效果不稳定、极不理想。In response to the above problems, the current technical route solutions often use "multiple methods" and "separate solutions". The process is becoming more and more complicated, but systematic and collaborative consideration is not achieved, and nutrients are often solved through the superposition of lengthy process routes. However, the deodorization problem is still not resolved, and it is still necessary to increase the deodorization measures along the whole process along with the extension of the sewage treatment process, resulting in high investment and operating costs for the deodorization system. Some deodorization technologies commonly used at present have been investigated. The collection method deodorization equipment and operating costs are high, and it needs to be covered to collect odors to form a closed space, which will cause great corrosion to the equipment; other types of existing biological deodorization technologies, such as rotting Soil deodorization or soil microbial deodorization technology, the microbial culture medium used is relatively single composition such as humus, or clay and cement cement, lime pressing, or other biofilm carriers such as volcanic rock, etc. fired or pressed The processing process of the above-mentioned matrix or carrier makes the matrix denatured and the biological activity of the components is unfriendly. The most important thing is that it is difficult to directional and stably cultivate deodorant microorganisms such as Bacillus, and even destroy the activity of microorganisms. Therefore, many deodorant microorganisms currently in operation in China Smelly project, the effect is unstable and extremely unsatisfactory.
另外,现有的全流程活性污泥除臭一些做法,如将培养罐置于主曝气池池内,运行MLSS较低(2500-4500mg/L),主曝气池内MLSS较低,也不利于培养罐内微生物的富集;此外在曝气池内为了强化对污染物如COD、N、P的去除往往是连续曝气,DO过高,甚至存在过度曝气,这样不利于除臭微生物的富集的活性保持,也不利于污泥减量,因为一些除臭功能微生物更偏好兼氧状态,或者厌氧/缺氧/好氧交替环境,更有利于刺激这些特殊菌群的生化活性。此外,培养罐在主生物池内,主生物池内活性污泥混合液夹杂含量较高的砂子、纤维类等杂质,极易对罐体的填料层形式堵塞。In addition, some existing deodorization methods of activated sludge in the whole process, such as placing the culture tank in the main aeration tank, the operating MLSS is low (2500-4500mg/L), and the MLSS in the main aeration tank is low, which is not conducive to The enrichment of microorganisms in the culture tank; in addition, in order to strengthen the removal of pollutants such as COD, N, and P in the aeration tank, continuous aeration is often used, and DO is too high, and there is even excessive aeration, which is not conducive to the enrichment of deodorizing microorganisms It is also not conducive to sludge reduction because some deodorizing microorganisms prefer a facultative state, or an anaerobic/anoxic/aerobic alternating environment, which is more conducive to stimulating the biochemical activity of these special flora. In addition, the cultivation tank is in the main biological tank, and the activated sludge mixture in the main biological tank is mixed with impurities such as sand and fibers with a high content, which is very easy to block the filler layer of the tank.
文献“腐植土活性污泥技术的除污效能及除臭效果(中国给水排水,2007,23(14))”中公开的技术方案偏重于理论研究,仅给出了腐植土活性污泥工艺的基本原理和一般工艺特征的介绍,且文献中提及的工艺流程中腐殖土培养池与主曝气池合建,腐殖土培养池的回流量只有3%-10%,且培养池为连续曝气,培养罐内的复合催化填料中没有包埋功能菌种,培养池带有DO的混合液出流直接到生物池的厌氧段破坏了厌氧池的生物释磷效,上述若干问题影响到了实际项目的工艺效果不理想,甚至除臭与除磷出现了矛盾。与此同时,由于回流污泥含有较多的沙砾、纤维类杂质等无机成分,这部分杂质进入培养池后大大降低了微生物活性,堵塞培养罐,甚至导致培养罐无法正常运行。此外,这种单纯的腐殖土活性污泥除臭土壤微生物在生化系统内容培养缓慢,需要2-6个月甚至更长的启动期才能缓慢出现除臭效果,影响了污水厂的运行和环保验收。The technical scheme disclosed in the document "Decontamination Efficiency and Deodorization Effect of Humic Soil Activated Sludge Technology (China Water and Drainage, 2007, 23 (14))" focuses on theoretical research, and only gives the humus soil activated sludge process. The introduction of the basic principles and general process characteristics, and in the process mentioned in the literature, the humus soil cultivation tank and the main aeration tank are jointly built, the return flow of the humus soil cultivation tank is only 3%-10%, and the cultivation tank is Continuous aeration, the composite catalytic filler in the culture tank does not embed functional bacteria, and the mixed solution with DO in the culture tank flows directly to the anaerobic section of the biological tank, which destroys the biological phosphorus release effect of the anaerobic tank. The problem has affected the unsatisfactory process effect of the actual project, and even the contradiction between deodorization and phosphorus removal. At the same time, since the return sludge contains more inorganic components such as sand and fiber impurities, these impurities will greatly reduce the microbial activity after entering the culture tank, block the culture tank, and even cause the culture tank to fail to operate normally. In addition, this kind of simple humus activated sludge deodorization soil microorganisms are slowly cultivated in the biochemical system, and it takes 2-6 months or even longer to start the deodorization effect slowly, which affects the operation and environmental protection of the sewage plant acceptance.
专利CN104150609B(一种原位富集硝化菌耦合污泥水解强化脱氮除磷的方法)中,S-NDN池与S-HY池虽然也是采用侧流模式,并采用两组功能独立的反应器,但是,S-NDN侧重于强化培养硝化菌和脱氮,降低主生物池SRT,进而可以实现生化系统的短SRT运行下提高处理能力,S-NDN不是侧重定向培养和富集除臭功能菌;而S-HY池主要是通过水解过程产生内碳源溶解性COD(SCOD)及挥发性脂肪酸(VFAs)补充进水SCOD及VFAs的匮乏,因此S-HY池对ORP没有过于严格的限制,厌氧环境、缺氧环境甚至微氧曝气环境都可以,是以活性污泥发酵水解产率最高为目标来控制工艺过程,S-HY池目的不是单纯追求深度厌氧条件,也不是单纯追求定向培育Tetrasphaera等发酵类聚磷菌。In the patent CN104150609B (a method for in-situ enrichment of nitrifying bacteria coupled with sludge hydrolysis to enhance denitrification and phosphorus removal), the S-NDN pool and the S-HY pool also use the side flow mode and use two sets of reactors with independent functions However, S-NDN focuses on strengthening the cultivation of nitrifying bacteria and denitrification, reducing the SRT of the main biological pool, and then improving the processing capacity under the short SRT operation of the biochemical system. ; while the S-HY pool mainly produces internal carbon source soluble COD (SCOD) and volatile fatty acids (VFAs) through the hydrolysis process to supplement the shortage of SCOD and VFAs in the influent, so the S-HY pool does not have too strict restrictions on ORP. Anaerobic environment, anoxic environment and even micro-aerobic aeration environment are all available. The process is controlled with the goal of the highest yield of activated sludge fermentation and hydrolysis. The purpose of the S-HY pool is not simply to pursue deep anaerobic conditions, nor to simply pursue Oriented cultivation of fermentative phosphorus-accumulating bacteria such as Tetrasphaera.
因此,针对已有技术的不足和在实际应用中出现的缺欠、结合污水处理深度脱氮除磷、降低商业碳源投加量、实现全过程除臭、污泥减量化等实际多元化需求,开发一种可快速启动、运行更加稳定、高效、能定向培养和富集微生物的耦合除臭及强化脱氮除磷、高效低耗的可持续污水处理工艺,对于提升污水处理系统的运行效果,改善水环境及周边大气质量,尤其是对于满足目前中国的污水厂深度脱氮除磷的技术需求,具有重要和深远的现实意义。Therefore, in view of the deficiencies of the existing technology and the shortcomings in practical application, combined with the deep nitrogen and phosphorus removal of sewage treatment, the reduction of commercial carbon source dosage, the realization of the whole process of deodorization, sludge reduction and other actual diversified needs , to develop a sustainable sewage treatment process with fast start-up, more stable operation, high efficiency, directional cultivation and enrichment of microorganisms, coupled deodorization and enhanced nitrogen and phosphorus removal, high efficiency and low consumption, which will help improve the operation effect of the sewage treatment system , to improve the water environment and the surrounding air quality, especially to meet the technical needs of deep nitrogen and phosphorus removal in China's sewage plants, has important and far-reaching practical significance.
实用新型内容Utility model content
有鉴于此,本实用新型旨在提出一种耦合全过程除臭及强化脱氮除磷功能的“主-辅”活性污泥生物强化系统,“主线”生化系统由主曝气池及二沉池组成,主反应池采用传统AAO,step-feed,氧化沟,多级AO,Bardenpho等活性污泥工艺或其变形工艺中的一种,在“辅线”设置了功能及结构上互相独立的两组侧流活性污泥生物强化反应器,即“S2HBR-S2ASH”(S2HBR与S2HBR合并简称S2池),在S2HBR反应器内设置了培养罐,罐体内上下两层分部设置两种生物培养基,旨在快速启动、接种、培养、富集具有除臭功能的特定功能微生物菌群,并将培养罐置于一个独立的侧流反应器内,侧流池具有高浓度MLSS总量,通过培养罐罐体内“气-液-固”三相紊流扰动局部及罐体内微循环实现罐体内部物质及功能微生物与侧流反应池内污泥混合液的高效传质与交换;在S2HBR侧流反应池内根据ORP、pH、NH3-N等在线仪表控制曝气和搅拌(交替实现硝化、反硝化过程),以实现除臭菌种培养富集同时同步高效脱氮除磷(硝化-反硝化交替),并使得微生物进入内源呼吸状态进一步刺激微生物代谢活性,缺氧/好氧的交替实现了微生物代谢过程的解偶联作用,有效降低了VSS产率,实现了污泥减量化目的;S2ASH作用在于通过对回流污泥浓度及搅拌强度(搅拌器的连续或间歇运行)的控制实现深度厌氧环境(ORP≤-150mv),能有效定向培育Tetrasphaera-PAO类聚磷菌,抑制聚糖菌GAOs(GAOs出现可以恶化生物除磷效果)的生长,形成“Tetrasphaera-Accumulibacter”双PAO协同共生环境,Tetrasphaera类聚磷菌不依赖进水VFAs,其自身可直接利用葡萄糖、氨基酸等大分子有机物进行厌氧发酵释磷,同时其发酵产物形成的VFAs可以作为Accumulibacter底物,双PAOs在实现高效共生协同强化生物除磷功效,经过“辅线”S2反应器生化过程后的活化污泥出流至主生物池和污水厂进水端和需要除臭的部位(如污泥浓缩池、储泥池等)。S2HBR-S2ASH组合反应器结构及功能独立、分工明确,生态协同,根据不同菌属的生态位不同,分别构造各自最适宜的生境,分别定向富集培育功能菌,通过“主-辅”反应器功能的构型安排与功能强化,实现“辅线”反应器向“主线”反应器的高效接种及底物转移和高效利用,组合系统可耦合实现脱臭、强化脱氮除磷及污泥减量,“主-辅”线反应器功能互相促进,“主-辅”生化系统运行更加高效、稳定,耐冲击负荷。In view of this, the utility model aims to propose a "main-auxiliary" activated sludge bioaugmentation system that couples the whole process of deodorization and enhanced denitrification and phosphorus removal. The "main line" biochemical system consists of the main aeration tank and the secondary sedimentation Pool composition, the main reaction pool adopts traditional AAO, step-feed, oxidation ditch, multi-stage AO, Bardenpho and other activated sludge processes or one of its deformation processes, and the "auxiliary line" is equipped with independent functions and structures Two sets of side-flow activated sludge bioaugmentation reactors, namely "S2HBR-S2ASH" (S2HBR and S2HBR combined for short S2 pool), set up a cultivation tank in the S2HBR reactor, and set up two kinds of biological cultivation in the upper and lower layers of the tank. The base is designed to quickly start, inoculate, cultivate, and enrich the specific functional microbial flora with deodorization function, and place the culture tank in an independent side flow reactor. The side flow tank has a high concentration of MLSS total amount, through The "gas-liquid-solid" three-phase turbulence in the culture tank disturbs the local and microcirculation in the tank to realize the efficient mass transfer and exchange of the material and functional microorganisms in the tank and the sludge mixture in the side flow reaction tank; in the S2HBR side flow In the reaction tank, the aeration and agitation are controlled according to online instruments such as ORP, pH, NH3-N (alternate nitrification and denitrification processes), so as to realize the cultivation and enrichment of deodorizing bacteria and simultaneous efficient denitrification and phosphorus removal (alternative nitrification-denitrification ), and make the microorganism enter the endogenous respiration state to further stimulate the metabolic activity of the microorganism, the alternation of anoxic/aerobic realizes the uncoupling of the microbial metabolic process, effectively reduces the VSS yield, and realizes the purpose of sludge reduction; The role of S2ASH is to achieve a deep anaerobic environment (ORP≤-150mv) through the control of the return sludge concentration and agitation intensity (continuous or intermittent operation of the agitator), which can effectively cultivate Tetrasphaera-PAO-like phosphorus-accumulating bacteria and inhibit polysaccharides The growth of bacterial GAOs (the appearance of GAOs can worsen the effect of biological phosphorus removal) forms a "Tetrasphaera-Accumulibacter" double PAO synergistic symbiosis environment. Tetrasphaera-like phosphorus-accumulating bacteria do not rely on VFAs in the water, and they can directly use macromolecular organic substances such as glucose and amino acids. Perform anaerobic fermentation to release phosphorus, and at the same time, the VFAs formed by its fermentation products can be used as Accumulibacter substrates. Double PAOs can achieve high-efficiency symbiosis and synergistic enhancement of biological phosphorus removal. The activated sludge after the biochemical process of the "auxiliary line" S2 reactor flows out To the main biological pool and the water inlet of the sewage plant and the parts that need to be deodorized (such as sludge thickening tank, mud storage tank, etc.). The S2HBR-S2ASH combined reactor has independent structure and function, clear division of labor, and ecological synergy. According to the different ecological niches of different bacterial species, the most suitable habitats are constructed respectively, and functional bacteria are enriched and cultivated separately. Through the "main-auxiliary" reactor The configuration arrangement and function enhancement of functions realize the efficient inoculation, substrate transfer and efficient utilization from the "auxiliary line" reactor to the "main line" reactor. The combined system can be coupled to realize deodorization, enhanced nitrogen and phosphorus removal and sludge reduction , The functions of the "main-auxiliary" line reactors promote each other, and the operation of the "main-auxiliary" biochemical system is more efficient, stable, and resistant to impact loads.
本实用新型具体技术方案如下:The concrete technical scheme of the utility model is as follows:
本实用新型所涉及到系统的生化过程包含至少四个反应器,具体为:在主线上至少包含主生物反应池、二沉池,在辅线污泥回流线上至少包含设有菌种培养罐SBIO-A的污泥生物培养池S2HBR及活性污泥发酵池S2ASH,S2HBR与S2ASH合并简称S2池;主线与辐线通过回流污泥泵房连接;S2HBR和S2ASH串联或者并联运行。The biochemical process of the system involved in the utility model includes at least four reactors, specifically: the main line includes at least the main biological reaction tank and the secondary sedimentation tank, and the auxiliary line sludge return line includes at least a strain cultivation tank. The sludge biological culture tank S2HBR of the tank SBIO-A and the activated sludge fermentation tank S2ASH, S2HBR and S2ASH are combined and referred to as the S2 pool; the main line and the radial line are connected through the return sludge pump room; S2HBR and S2ASH operate in series or in parallel.
进一步的,为了提高侧流段活性污泥的活性,提高MLVSS/MLSS比,减少纤维类、大颗粒杂质对培养罐的堵塞,本实用新型在回流线设置了污泥微筛过滤机,可以一台或多台,优先去除回流污泥中的颗粒性杂质,如砂子,毛发等纤维类杂质。Further, in order to improve the activity of the activated sludge in the side flow section, improve the MLVSS/MLSS ratio, and reduce the clogging of the cultivation tank by fibers and large particles of impurities, the utility model is equipped with a sludge micro-sieve filter in the return line, which can One or more sets, give priority to the removal of granular impurities in the return sludge, such as sand, hair and other fibrous impurities.
上述串联运行模式下,优选步骤为:部分回流污泥经过微筛过滤后再顺序经过S2池接种、富集硝化菌、除臭菌功能微生物,S2生化池的出流可以选择全部从S2ASH出流,或S2HBR、S2ASH池分别出流两种形式其中一:Under the above-mentioned series operation mode, the preferred steps are: part of the return sludge is filtered through a micro-sieve, and then sequentially passed through the S2 pool to inoculate, enrich the nitrifying bacteria, and deodorize the functional microorganisms. The outflow of the S2 biochemical pool can all be selected from the S2ASH outflow , or S2HBR, S2ASH pool outflow respectively in one of two forms:
方式一是S2HBR出流全部进入S2ASH,经过S2ASH进行厌氧水解及增殖PAOs后,混合液一部分进入主生物池厌氧段或缺氧段用于强化生物除磷脱氮,另一部分进入污水厂进水管实现除臭;The first way is that all the outflow of S2HBR enters S2ASH. After S2ASH is anaerobicly hydrolyzed and PAOs multiplied, part of the mixed solution enters the anaerobic or anoxic section of the main biological pool for enhanced biological phosphorus and nitrogen removal, and the other part enters the sewage plant for further processing. Water pipes achieve deodorization;
方式二是S2HBR一部分出流直接至污水厂进水端用于除臭,剩余污泥量进入S2ASH池,这部分污泥量再经过S2ASH生物强化和增殖微生物后进入主生物池。The second method is that a part of the S2HBR outflow is directly sent to the water inlet of the sewage plant for deodorization, and the remaining sludge enters the S2ASH pool, and this part of the sludge enters the main biological pool after S2ASH bioaugmentation and microbial proliferation.
上述并联运行模式下,优选步骤为:S2HBR池和S2ASH池分别采用独立的进流,其中S2HBR池出流一部分去进水管除臭,另一部分进入主生物池缺氧段或好氧段用于补充硝化菌和其它功能微生物,S2ASH池出流直接进入主生物池厌氧段用于强化生物除磷。Under the above-mentioned parallel operation mode, the preferred steps are: the S2HBR pool and the S2ASH pool use independent inflows, of which part of the outflow from the S2HBR pool goes to the water inlet pipe for deodorization, and the other part enters the anoxic section or aerobic section of the main biological pool for replenishment Nitrifying bacteria and other functional microorganisms, the effluent from the S2ASH pool directly enters the anaerobic section of the main biological pool for enhanced biological phosphorus removal.
更优选的步骤为,上述串联或并联运行模式下,部分回流污泥先经过微筛去除砂子、纤维类杂物后再进入S2池。微筛过滤精度150-1000微米,优选的过滤精度是200-600微米。A more preferred step is that, under the above-mentioned series or parallel operation mode, part of the return sludge is first passed through a micro-sieve to remove sand and fiber impurities before entering the S2 pool. The filtration precision of the micro-sieve is 150-1000 microns, and the preferred filtration precision is 200-600 microns.
上述耦合除臭及强化脱氮除磷的“主-辅”活性污泥系统中,控制污泥总的外回流量QRAS为(30%-100%)Q,Q为污水厂进水量,Q RAS为总的外回流污泥量;最优的QRAS为(33%-50%)Q。In the above-mentioned "main-auxiliary" activated sludge system coupled with deodorization and enhanced denitrification and phosphorus removal, the total external return flow rate Q RAS of the control sludge is (30%-100%)Q, and Q is the water inflow of the sewage plant, Q RAS is the total amount of external return sludge; the optimal Q RAS is (33%-50%)Q.
其中回流到S2HBR-S2ASH池的污泥量占QRAS的比例为6%~30%;剩余(70%~94%)QRAS的回流污泥则通过回流泵房直接回流到生物池始端。Among them, the amount of sludge returned to the S2HBR-S2ASH pool accounts for 6% to 30% of the QRAS; the remaining (70% to 94%) QRAS return sludge is directly returned to the beginning of the biological pool through the return pump room.
S2池污泥回流方式可选择下述串联与并联两种模式中一种:S2 tank sludge return mode can choose one of the following two modes: series and parallel:
对于串联模式,有两种具体方式,①方式一:回流污泥顺序经过S2HBR和S2ASH,最终从S2ASH池分流,出流分2个去向,1%-5%的污泥回流到污水厂进水总管用于除臭,5%-29%QRAS进入主生物池用于强化脱氮除磷;②方式二:从S2HBR分流,出流分2个去向,1%-5%的污泥回流到污水厂进水总管用于除臭,其余5%-29%QRAS进入S2ASH池生物强化后再进入主生物池用于强化脱氮除磷。For the series mode, there are two specific methods, ①Method 1: The return sludge passes through S2HBR and S2ASH in sequence, and finally diverts from the S2ASH pool, and the outflow is divided into two destinations, and 1%-5% of the sludge is returned to the sewage plant influent The main pipe is used for deodorization, and 5%-29% Q RAS enters the main biological pool for enhanced nitrogen and phosphorus removal; ②Method 2: divert from the S2HBR, the outflow is divided into two destinations, and 1%-5% of the sludge is returned to The water inlet main of the sewage plant is used for deodorization, and the remaining 5%-29% Q RAS enters the S2ASH pool for bioaugmentation and then enters the main biological pool for enhanced nitrogen and phosphorus removal.
对于并联模式,污泥回流6-30%QRAS分成两路,其中2%-26%QRAS进入S2HBR池,4%-28%进入S2ASH池;S2HBR池的1%-5%QRAS出流量进入污水厂进水管或浓缩/储泥池;其余1%-25%QRAS和SAHS池出流一起进入主生物池。For the parallel mode, sludge return 6-30% Q RAS is divided into two paths, of which 2%-26% Q RAS enters the S2HBR pool, 4%-28% enters the S2ASH pool; 1%-5% Q RAS outflow of the S2HBR pool Enter the water inlet pipe of the sewage plant or the thickening/sludge storage tank; the remaining 1%-25% Q RAS and SAHS tank effluent enter the main biological tank together.
优化的步骤为,上述S2中两种回流方式,回流污泥预先都要经过微筛的处理。The optimization procedure is that, in the above two return methods in S2, the return sludge must be treated with micro-sieves in advance.
优选的工艺参数为:S2HBR-S2ASH池的总HRT为4~30h;S2HBR池HRT为3~24h,最优8~20h;S2ASH池HRT为1~24h,停留时间长有助于菌种的富集与污染物的降解率的提升;活性污泥MLSS浓度为6000~18000mg/L,侧流池污泥浓度高有利于菌种的快速富集,并提高系统的抗冲击能力,但是过高会导致曝气或者搅拌功率的不足,或导致浮泥等问题发生。总体上,外回流比RAS控制在33%-50%较低的区间,有利于侧流反应器运行及单位池容菌群富集效率的提升。The optimal process parameters are: the total HRT of the S2HBR-S2ASH pool is 4-30h; the HRT of the S2HBR pool is 3-24h, the optimal 8-20h; The degradation rate of collection and pollutants is improved; the MLSS concentration of activated sludge is 6000-18000mg/L, and the high concentration of sludge in the side flow tank is conducive to the rapid enrichment of bacteria and improves the impact resistance of the system, but if it is too high, it will Insufficient aeration or stirring power, or problems such as floating mud. In general, the external reflux ratio RAS is controlled at a lower range of 33%-50%, which is conducive to the operation of the side stream reactor and the improvement of the enrichment efficiency of the bacterial population per unit tank volume.
进一步的,S2HBR池采用“好氧/缺氧”交替,实现除臭功能菌的培养与功能强化,同时实现活性污泥的硝化及内源反硝化;此外,同时通过厌氧/缺氧/好氧交替刺激微生物的解偶联作用,可实现活性污泥VSS减量10%-40%;S2HBR运行控制采用高级模式或基本模式,高级模式采用N/DN间歇性曝气,并设置DO/ORP、pH、NH3-N/NO3-N、PO4-P在线仪表控制好氧-缺氧或好氧-缺氧-厌氧过程,实现回流污泥的硝化反硝化脱氮过程;基本模式采用时序N/DN时间控制,旨在实现回流污泥的硝化反硝化脱氮过程及刺激微生物的解偶联作用实现污泥减量。Further, the S2HBR pool adopts "aerobic/anoxic" alternation to realize the cultivation and function enhancement of deodorizing bacteria, and at the same time realize the nitrification and endogenous denitrification of activated sludge; in addition, through anaerobic/anoxic/good Oxygen alternately stimulates the uncoupling of microorganisms, which can reduce the VSS of activated sludge by 10%-40%; S2HBR operation control adopts advanced mode or basic mode, and the advanced mode adopts N/DN intermittent aeration, and set DO/ORP , pH, NH3-N/NO3-N, PO4-P online instruments control the aerobic-anoxic or aerobic-anoxic-anaerobic process, and realize the nitrification and denitrification process of the return sludge; the basic mode adopts time series N /DN time control, aiming to realize the nitrification and denitrification denitrification process of returning sludge and stimulate the uncoupling of microorganisms to achieve sludge reduction.
更进一步的,S2HBR池DO设定值高点为0.5~1.0mg/L,低值0-0.3mg/L;所述NH3-N设定值高点设置为1.2~3.0mg/L,低值0.1-0.5mg/L,根据设定点的高低实现对曝气与搅拌设备的开关控制。Furthermore, the high point of the DO setting value of the S2HBR pool is 0.5-1.0mg/L, and the low value is 0-0.3mg/L; the high point of the NH3-N setting value is set at 1.2-3.0mg/L, and the low value 0.1-0.5mg/L, realize the switch control of aeration and stirring equipment according to the level of the set point.
进一步的,S2ASH通过连续或者间歇性搅拌器或推流器的ON/OFF运行持续时间的控制,通过对回流比及回流污泥浓度的控制,及ORP信号控制搅拌器的启/停,两种方式一种或两种方式联用实现S2ASH池的深度“厌氧”环境;设备配置的搅拌功率密度(1~5)w/m3池容,实际运行最优的功率密度0~3w/m3,功率过高不利于保持厌氧环境;搅拌维持ORP为-150~-400mv,ORP越低越有利于PAOs的种群多样性。S2ASH的“深度厌氧”环境可以有选择性地去定向培育Tetrasphaera具有发酵功能的聚磷菌,并在生化系统内构建出“Tetrasphaera-Accumulibacter”双PAOs协同共生机制。Further, S2ASH controls the ON/OFF operation duration of the continuous or intermittent agitator or flowmaker, and controls the start/stop of the agitator through the control of the reflux ratio and the return sludge concentration, and the ORP signal. One method or two methods combined to realize the deep "anaerobic" environment of the S2ASH pool; the stirring power density of the equipment configuration (1~5) w/m 3 pool capacity, the actual operation optimal power density 0~3w/m 3. Too high power is not conducive to maintaining an anaerobic environment; stirring maintains the ORP at -150 ~ -400mv, and the lower the ORP, the more conducive to the diversity of PAOs. The "deep anaerobic" environment of S2ASH can selectively cultivate Tetrasphaera phosphorus-accumulating bacteria with fermentation function, and build a "Tetrasphaera-Accumulibacter" double PAOs synergistic symbiosis mechanism in the biochemical system.
进一步的,在S2HBR反应器内设置了菌种培养罐(SBIO-A),按照每万吨污水设计规模设置2-4个培养罐,罐体内装设有两层培养基和填料,第一层复核缓释培养基是腐殖土、泥炭、黏土、高岭土、硅酸钙、零价铁、磁铁矿、微量元素(Ca2+、Mg2+、K+等)、活性炭、芽孢杆菌污泥、沸石、火山岩、微生物所需的微量元素、粘合剂、起泡剂等复合物压制成的棒状物或球状物,第一层复核缓释培养基是通过提前包埋固定富含芽孢杆菌、脱硫杆菌的特殊污泥或制剂,添加的组份可以提高微生物活性,能定向培养、富集除臭微生物并向侧流反应池内混合液缓慢释放微生物;复核基质填料需要定期补充,每3-5年补充率1%-10%(重量比);第二层填料是天然球状或块状的轻质浮石,等效直径3-8cm,并呈多孔状,用于释放矿物质并作为生物膜载体富集功能微生物(除臭菌、硝化菌等)。Further, a strain culture tank (SBIO-A) is set in the S2HBR reactor, and 2-4 culture tanks are set according to the design scale per 10,000 tons of sewage. The tank is equipped with two layers of medium and fillers. The first layer The double-check slow-release medium is humus, peat, clay, kaolin, calcium silicate, zero-valent iron, magnetite, trace elements (Ca 2+ , Mg 2+ , K + , etc.), activated carbon, bacillus sludge , zeolite, volcanic rock, trace elements required by microorganisms, adhesives, foaming agents and other compounds pressed into rods or spheres. The special sludge or preparation of Desulfobacillus, the added components can improve the microbial activity, can directional culture, enrich the deodorizing microorganisms and slowly release the microorganisms to the mixed solution in the side flow reaction tank; the check matrix filler needs to be replenished regularly, every 3-5 The annual replenishment rate is 1%-10% (weight ratio); the second layer of filler is natural spherical or massive light pumice, with an equivalent diameter of 3-8cm, and is porous, used to release minerals and act as a biofilm carrier Enrich functional microorganisms (deodorizing bacteria, nitrifying bacteria, etc.).
优选的,菌种培养罐具有内循环“气-液-固”三相循环通道。Preferably, the strain culture tank has an internal circulation "gas-liquid-solid" three-phase circulation channel.
优选的,SBIO-A底部设置微孔曝气头。Preferably, a microporous aeration head is provided at the bottom of the SBIO-A.
进一步的,S2HBR-S2ASH反应池采用矩形、或者圆形结构或氧化沟池型其中一种。Further, the S2HBR-S2ASH reaction pool adopts one of rectangular, circular or oxidation ditch pool types.
进一步的,S2HBR-S2ASH反应池可以选择2-6格串联,其中S2HBR为1-3格,S2ASH为1-3格。Furthermore, the S2HBR-S2ASH reaction pool can be connected in series with 2-6 grids, among which S2HBR is 1-3 grids, and S2ASH is 1-3 grids.
进一步的,S2HBR-S2ASH反应池内设置曝气及搅拌设备;流态可以选择完全混合式或推流式。Further, the S2HBR-S2ASH reaction tank is equipped with aeration and stirring equipment; the flow state can be selected from complete mixing type or push flow type.
相对于现有技术,本实用新型具有如下技术效果和优势:Compared with the prior art, the utility model has the following technical effects and advantages:
本实用新型通过反应器“主-辅”模式的安排,“辅”线上两个功能独立的侧流S2反应池定向富集特异功能微生物菌群,通过向“主”线的接种可以显著改善和优化整个活性污泥系统的菌群结构,并显著提高生化系统对氮磷的去除效率,解决了传统除臭技术功能菌种在系统内培养缓慢,且不能稳定培养富集形成优势菌种的技术缺欠;通过S2ASH深度厌氧环境实现对Tetrasphaera类具有发酵功能的PAO定向增殖,克服了传统活性污泥工艺单纯依赖Accumulibacter类PAO导致除磷效果不稳定的问题,也克服了传统工艺PAOs-GAOs菌种竞争的问题,强化了系统生物除磷效果;并进一步提高了MLSS的硝化菌的含量;同步提升污水处理全过程的除臭效果,也同步实现了MLVSS的减量化,对于我们国家很多地区低C/N比污水的强化脱氮除磷、节省商业碳源的投加具有重要而深远的经济效益和环境效益。In the utility model, through the arrangement of the "main-auxiliary" mode of the reactor, two side flow S2 reaction pools with independent functions on the "auxiliary" line can directionally enrich the special functional microbial flora, and the inoculation to the "main" line can significantly improve the And optimize the bacterial community structure of the entire activated sludge system, and significantly improve the removal efficiency of nitrogen and phosphorus in the biochemical system, and solve the problem that the traditional deodorization technology functional bacteria are slowly cultivated in the system, and cannot be stably cultivated and enriched to form dominant bacteria Technical deficiencies; through the deep anaerobic environment of S2ASH, the directional proliferation of PAOs with fermentation function for Tetrasphaera can be realized, which overcomes the problem of unstable phosphorus removal effect caused by the traditional activated sludge process relying solely on Accumulibacter PAOs, and also overcomes the traditional process of PAOs-GAOs The problem of strain competition has strengthened the effect of biological phosphorus removal in the system; and further increased the content of nitrifying bacteria in MLSS; simultaneously improved the deodorization effect of the whole process of sewage treatment, and simultaneously realized the reduction of MLVSS, which is very important for many in our country. The enhanced denitrification and dephosphorization of sewage with low C/N ratio in the area, and the addition of commercial carbon source saving have important and far-reaching economic and environmental benefits.
通过S2HBR反应器实现除臭菌、硝化菌的定向富集,S2HBR对功能菌的定向性培养和增殖,一方面依靠罐体内复合活性生物基质缓释填料,另一方面依赖于侧流活性污泥反应器内适于除臭功能菌的最优生境因子的生化过程控制,此外,间歇曝气模式可通过活性污泥解偶联作用降低污泥产率10%-30%,有效降低了全厂生化污泥的产量;S2ASH反应器实现新型聚磷菌Tetrasphaera-PAO的定向富集培养,Tetrasphaera-PAO优势在于不依赖进水VFA,可以在厌氧条件下直接以葡萄糖、氨基酸等大分子有机物进行厌氧发酵并释磷,但是需要深度厌氧环境;同时,Tetrasphaera-PAO在后续缺氧环境下具有反硝化除磷功能,可以显著提高低C/N比废水脱氮除磷效果;此外,侧流污泥深度厌氧环境(≤-150mv)同时能压抑GAOs的生长,总之,侧流反应器的设置,一举多得,不仅能大幅度提高对污染物的去除效率,同时实现了处理过程的无臭化。The directional enrichment of deodorizing bacteria and nitrifying bacteria is realized through the S2HBR reactor. The directional cultivation and proliferation of functional bacteria by S2HBR relies on the composite active biological matrix slow-release filler in the tank on the one hand, and on the other hand depends on the side flow activated sludge. The biochemical process control of the optimal habitat factors suitable for deodorizing functional bacteria in the reactor, in addition, the intermittent aeration mode can reduce the sludge yield by 10%-30% through the decoupling of activated sludge, effectively reducing the The production of biochemical sludge; S2ASH reactor realizes the directional enrichment culture of the new phosphorus-accumulating bacteria Tetrasphaera-PAO. The advantage of Tetrasphaera-PAO is that it does not depend on the influent VFA, and can be directly grown with macromolecular organic substances such as glucose and amino acids under anaerobic conditions. Anaerobic fermentation and phosphorus release, but requires a deep anaerobic environment; at the same time, Tetrasphaera-PAO has the function of denitrification and phosphorus removal in the subsequent anoxic environment, which can significantly improve the nitrogen and phosphorus removal effect of low C/N ratio wastewater; In addition, the lateral The deep anaerobic environment of flow sludge (≤-150mv) can suppress the growth of GAOs at the same time. Odorless.
需要特别说明的效果是,本实用新型在污泥回流至S2池前设置了过滤微筛,用于去除回流污泥中的无机性杂质及纤维类杂质,对于提高S2池的有效微生物浓度,保持菌群活性,实现污泥减量,减少杂质对S2HBR罐体内的堵塞及侧流池内机械设备、曝气装置的磨损、进而提高整个“主-辅”生化系统内的活性污泥微生物活性起到了至关重要的作用。与此同时,污水厂排放剩余污泥可以从侧流池排出,这样大大减轻了污泥处理设备如污泥输送螺杆泵、污泥浓缩机污泥脱水机等机械设备的磨损,大大延长污泥处理段的设备使用周期。The effect that needs to be specially explained is that the utility model is provided with a filter micro-sieve before the sludge returns to the S2 pool, which is used to remove inorganic impurities and fiber impurities in the return sludge, and to improve the effective microbial concentration of the S2 pool, maintain Bacterial activity, realize sludge reduction, reduce impurities in the S2HBR tank blockage and wear of mechanical equipment and aeration devices in the side flow tank, thereby improving the microbial activity of activated sludge in the entire "main-auxiliary" biochemical system. Crucial role. At the same time, the excess sludge discharged from the sewage plant can be discharged from the side flow tank, which greatly reduces the wear and tear of sludge treatment equipment such as sludge conveying screw pumps, sludge thickeners, sludge dewaterers and other mechanical equipment, and greatly prolongs sludge production. The device lifetime of the processing segment.
附图说明Description of drawings
构成本实用新型的一部分的附图用来提供对本实用新型的进一步理解,本实用新型的示意性实施例及其说明用于解释本实用新型,并不构成对本实用新型的不当限定。在附图中:The accompanying drawings constituting a part of the utility model are used to provide a further understanding of the utility model, and the schematic embodiments of the utility model and their descriptions are used to explain the utility model, and do not constitute improper limitations to the utility model. In the attached picture:
图1为本实用新型系统S2HBR-S2ASH串联模式一的流程示意图;Fig. 1 is the schematic flow sheet of the utility model system S2HBR-S2ASH serial mode one;
图2为本实用新型系统S2HBR-S2ASH串联模式二的流程示意图;Fig. 2 is the schematic flow chart of the utility model system S2HBR-S2ASH serial mode two;
图3为本实用新型系统S2HBR-S2ASH并联模式的流程示意图;Fig. 3 is a schematic flow chart of the utility model system S2HBR-S2ASH parallel mode;
图4为本实用新型系统S2HBR池内的生物培养罐(SBIO-A)的立面图;Fig. 4 is the elevation view of the biological cultivation tank (SBIO-A) in the utility model system S2HBR pond;
图5为本实用新型系统S2HBR池内的生物培养罐(SBIO-A)的俯视图。Fig. 5 is a top view of the biological culture tank (SBIO-A) in the S2HBR pool of the utility model system.
图中:1-进水泵房及初级预处理设施,2-主生物池,3-二沉池,4-回流污泥泵房,5-S2HBR池,6-菌种培养罐SBIO-A,7-S2ASH池,8-SBIO-A培养罐罐体,9-复核基质填料层,10-浮石填料层,11-曝气头,12-培养罐出泥口不锈钢滤网,13-污泥微筛过滤机。In the figure: 1-influent pump room and primary pretreatment facilities, 2-main biological pool, 3-secondary sedimentation tank, 4-reflux sludge pump room, 5-S2HBR pool, 6-bacteria culture tank SBIO-A, 7 -S2ASH pool, 8-SBIO-A culture tank body, 9-recheck matrix packing layer, 10-pumice packing layer, 11-aeration head, 12-cultivation tank mud outlet stainless steel filter, 13-sludge micro-sieve filter.
具体实施方式Detailed ways
需要说明的是,在不冲突的情况下,本实用新型中的实施例及实施例中的特征可以相互组合。It should be noted that, in the case of no conflict, the embodiments of the present invention and the features in the embodiments can be combined with each other.
下面将参考附图并结合实施例来详细说明本实用新型。The utility model will be described in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
本实用新型的一种耦合除臭及强化脱氮除磷的“主-辅”活性污泥系统,“主线”生化系统由进水泵房及初级预处理设施1、主生物池2及二沉池3依次通过管道连接,在“辅线”设置包含有菌种培养罐SBIO-A 6的污泥生物培养池S2HBR池5及活性污泥发酵池S2ASH池7,S2HBR与S2ASH合并简称S2池;主线与辐线通过回流污泥泵房4连接;在辅线污泥回流线上包含污泥微筛过滤机13,污泥微筛过滤机设置在S2池进口或者进泥管路上;S2HBR和S2ASH串联或者并联运行。具体运行流程为:This utility model is a "main-auxiliary" activated sludge system that couples deodorization and enhanced nitrogen and phosphorus removal. The "main line" biochemical system consists of water inlet pump room, primary pretreatment facility 1, main biological pool 2 and secondary sedimentation tank. 3. Connected by pipelines in turn, set up the sludge biological culture tank S2HBR pool 5 including the strain culture tank SBIO-A 6 and the activated sludge fermentation tank S2ASH pool 7 in the "auxiliary line". The combination of S2HBR and S2ASH is referred to as S2 pool; the main line It is connected with the radial line through the return sludge pump room 4; the sludge return line of the auxiliary line contains a sludge micro-sieve filter 13, and the sludge micro-sieve filter is set at the inlet of the S2 pool or on the sludge inlet pipeline; S2HBR and S2ASH Operate in series or in parallel. The specific operation process is:
串联运行模式下,部分回流污泥经过S2池接种、富集硝化菌、除臭菌功能微生物,S2池的出流选择全部从S2ASH出流,或S2HBR、S2ASH分别出流两种形式中的一种,具体为:In the series operation mode, part of the returned sludge is inoculated through the S2 pool to enrich the functional microorganisms of nitrifying bacteria and deodorizing bacteria. species, specifically:
如图1,方式一是S2HBR出流全部进入S2ASH,经过S2ASH进行厌氧水解及增殖PAOs后,混合液一部分进入主生物池厌氧段、或缺氧段或好氧段,另一部分进入污水厂进水管实现除臭;As shown in Figure 1, the first method is that all the outflow of S2HBR enters S2ASH, and after S2ASH performs anaerobic hydrolysis and multiplication of PAOs, part of the mixed solution enters the anaerobic section, anoxic section or aerobic section of the main biological pool, and the other part enters the sewage plant The water inlet pipe realizes deodorization;
如图2,方式二是S2HBR一部分出流直接至污水厂进水端用于除臭,剩余污泥量进入S2ASH池,这部分污泥量再经过S2ASH生物强化和增殖微生物后进入主生物池;As shown in Figure 2, the second method is that part of the outflow of S2HBR is directly sent to the water inlet of the sewage plant for deodorization, and the remaining sludge enters the S2ASH pool, and this part of the sludge enters the main biological pool after S2ASH bioaugmentation and microbial proliferation;
如图3,并联运行模式下,S2HBR池和S2ASH池分别采用独立的进流,其中S2HBR池出流一部分去进水管除臭,另一部分进入主生物池缺氧段或好氧段用于补充硝化菌和其它功能微生物,S2ASH池出流直接进入主生物池厌氧段用于强化生物除磷。As shown in Figure 3, in the parallel operation mode, the S2HBR pool and the S2ASH pool adopt independent inflows, of which part of the outflow from the S2HBR pool goes to the water inlet pipe for deodorization, and the other part enters the anoxic or aerobic section of the main biological pool for supplementary nitrification Bacteria and other functional microorganisms, the effluent from the S2ASH pool directly enters the anaerobic section of the main biological pool for enhanced biological phosphorus removal.
附图4中的菌种培养罐SBIO-A 6包括SBIO-A培养罐罐体8,罐体内上下两层分部设置两种生物培养基:复核基质填料层9和浮石填料层10,并且在罐体顶部设有培养罐出泥口不锈钢滤网12,在菌种培养罐SBIO-A内设置有曝气头11。The strain culture tank SBIO-A 6 among the accompanying drawings 4 comprises the SBIO-A culture tank tank body 8, and two kinds of biological culture mediums are set up and down in the upper and lower layers of the tank body: check matrix filler layer 9 and pumice filler layer 10, and in The top of the tank body is provided with a stainless steel filter screen 12 at the mud outlet of the culture tank, and an aeration head 11 is arranged in the strain culture tank SBIO-A.
实施例1:Example 1:
以某5万m3/d污水厂提标改造为例,提标改造排放标准由一级A标准提升到“准四类”,进出水标准见下表,但是不能新增征地。Take the upgrade of a 50,000 m 3 /d sewage plant as an example. The discharge standard of the upgrade is upgraded from the first-level A standard to the "quasi-four category".
某污水处理厂进出水质污染物去除率表Removal rate table of pollutants in and out of a sewage treatment plant
为此,本次改造方案工艺流程如图1,选择本实用新型涉及的“S2HBR-S2ASH工艺”,新建一组侧流“S2HBR-S2ASH”,分别采用两个矩形反应池并串联,引回流泵房污泥105m3/h经过2台过滤精度为250微米微筛过滤后至侧流S2池,剩余的RAS直接回流到厌氧池。其中S2HBR池设置了12个微生物培养罐,罐体内上下两层生物培养床分别预充填复核基质填料S和浮石填料层F填料。S2池出流分两路,一路2m3/h去进水管除臭,另一路103m3/h去主生物池厌氧部分,其余的污泥回流量936m3/h不经S2池直接进入主生物池厌氧池。S2HBR停留时间3h,设置曝气及搅拌器,根据在线DO、NH3-N仪表信号控制间歇曝气;S2ASH池停留时间24h,只设置搅拌器,搅拌功率2w/m3,控制S2ASH池运行ORP=-150至-300mv;原生物池构造保持不变,主生物池设计MLSS=3000mg/L,二沉池回流比保持50%-100%,回流污泥浓度控制在6000-9000mg/L。改造后,出水指标优于设计标准,NH3-N全年稳定低于1mg/L,二沉出水TP稳定低于0.4mg/L而无需投加化学除磷药剂;且全程全过程除臭,脱水机房脱水污泥无味,腐殖化明显。For this reason, the process flow of this transformation plan is shown in Figure 1. The "S2HBR-S2ASH process" involved in the utility model is selected, and a new group of side streams "S2HBR-S2ASH" is newly built, and two rectangular reaction pools are connected in series to lead backflow pumps. House sludge 105m 3 /h is filtered by two micro-sieves with a filtration precision of 250 microns and then sent to the side flow S2 tank, and the remaining RAS is directly returned to the anaerobic tank. Among them, the S2HBR pool is equipped with 12 microbial culture tanks, and the upper and lower layers of biological culture beds in the tank are pre-filled with double-check matrix filler S and pumice filler layer F filler respectively. The outflow of S2 tank is divided into two ways, one way is 2m 3 /h to the water inlet pipe for deodorization, the other way is 103m 3 /h to the anaerobic part of the main biological tank, and the remaining sludge return flow of 936m 3 /h directly enters the main biological tank without going through the S2 tank Biological pool anaerobic pool. The residence time of S2HBR is 3h, aeration and agitator are set, and intermittent aeration is controlled according to the online DO and NH3-N instrument signals; the residence time of S2ASH tank is 24h, only agitator is set, the stirring power is 2w/m 3 , and the operation of S2ASH pool is controlled ORP= -150 to -300mv; the structure of the original biological pool remains unchanged, the design of the main biological pool is MLSS=3000mg/L, the reflux ratio of the secondary sedimentation tank is maintained at 50%-100%, and the return sludge concentration is controlled at 6000-9000mg/L. After the transformation, the effluent index is better than the design standard, the NH3-N is stably lower than 1mg/L throughout the year, and the TP of the secondary sedimentation effluent is stably lower than 0.4mg/L without adding chemical phosphorus removal agents; and the whole process of deodorization and dehydration The dewatered sludge in the machine room is odorless and has obvious humification.
实施例2:Example 2:
由于进水污染物浓度提高,某市A污水处理厂不能稳定达标,且对周边环境空气污染较大,引起附近居民投诉,同时地方环保要求进一步提高排放标准到“准四类”,为此进行提标改造及增加除臭措施,该厂规模12万m3/d,采用卡鲁塞尔2000氧化沟工艺。本次改造方案工艺流程如图2,将原4格串联的厌氧池分别改造为S2HBR池(前3格)和S2ASH池(后1格),其中S2HBR池放置24个微生物培养罐,罐体内装填S和F两层填料,并增加曝气装置,设计主生物MLSS为4000mg/L,总回流变频控制在33%-40%,实际回流污泥浓度控制在12000-14000mg/L,引回流污泥总量150m3/h经过2台过滤精度为600微米微筛过滤后再至S2池,其中S2HBR池停留时间24h,S2HBR池内设置在线DO、NH3-N仪表,采用间歇曝气;S2ASH池停留时间1h,S2ASH池搅拌功率3w/m3,ORP控制在-200至-350mv。S2ASH出水5m3/h回流至污水厂进水总管,另外145m3/h进入厌氧池,剩余2350m3/h的RAS跨越S2池直接进入氧化沟。改造后,污水厂出水NH3-N在95%保证率达到2mg/L以下,TP95%保证率达到0.4mg/L,厂界恶臭气体环保检测达标。Due to the increase in the concentration of influent pollutants, the A sewage treatment plant in a certain city cannot meet the standards stably, and the air pollution to the surrounding environment is relatively large, causing complaints from nearby residents. The scale of the plant is 120,000 m 3 /d, and the Carrousel 2000 oxidation ditch process is adopted. The process flow of this transformation plan is shown in Figure 2. The original 4-cell anaerobic tanks in series are transformed into S2HBR pools (the first 3 cells) and S2ASH pools (the last 1 cell), in which 24 microbial culture tanks are placed in the S2HBR pools. Fill two layers of packing S and F, and add an aeration device, design the MLSS of the main organism to be 4000mg/L, control the frequency conversion of the total return flow at 33%-40%, and control the actual return sludge concentration at 12000-14000mg/L, and lead back flow sewage The total amount of mud of 150m 3 /h is filtered by two micro-sieves with a filtration accuracy of 600 microns before being sent to the S2 pool. The residence time of the S2HBR pool is 24h. The online DO and NH3-N instruments are installed in the S2HBR pool and intermittent aeration is adopted; the S2ASH pool stays The time is 1h, the stirring power of the S2ASH pool is 3w/m 3 , and the ORP is controlled at -200 to -350mv. 5m 3 /h of the effluent from S2ASH returns to the main water inlet of the sewage plant, another 145m 3 /h enters the anaerobic tank, and the remaining 2350m 3 /h of RAS crosses the S2 tank and directly enters the oxidation ditch. After the transformation, the 95% guarantee rate of NH 3 -N in the effluent of the sewage plant is below 2mg/L, the TP95% guarantee rate reaches 0.4mg/L, and the environmental protection detection of odorous gas at the factory boundary reaches the standard.
实施例3:Example 3:
某6万m3/d污水厂,由一级B提高到“准四类”标准,要求COD=40mg/L,TN=10mg/L,TP=0.3mg/L,NH3-N=2mg/L。原生物池为奥贝尔氧化沟。本次改造方案工艺流程如图3,将原选择池改造为侧流S2ASH池,新建1座S2HBR池,其中S2HBR池放置18个微生物培养罐(罐体内装填S和F两层填料),两座侧流池采用并联模式运行,设计主生物MLSS为4.5g/L,通过变频调速控制回流比33%-45%,回流污泥浓度控制在14500-18000mg/L,从污泥回流泵房引污泥135m3/h,经过2台300微米微筛过滤后至S2池,其中引回流污泥60m3/h至S2HBR池,S2HBR池停留时间12h;引回流污泥75m3/h至S2ASH池,S2ASH池停留时间12h,S2ASH池搅拌功率2w/m3,ORP控制在-300至-400mv。S2HBR出水25m3/h回流至污水厂进水总管,另外35m3/h进入厌氧池,总外回流量剩余的990m3/h的RAS跨越S2池直接进入氧化沟。改造后,污水厂出水稳定达标,厂界恶臭气体环保检测达标。For a 60,000 m 3 /d sewage plant, the standard was raised from Class I B to "quasi-IV", requiring COD=40mg/L, TN=10mg/L, TP=0.3mg/L, NH3-N=2mg/L . The primary organism pool is the Aubert Oxidation Ditch. The process flow of this transformation plan is shown in Figure 3. The original selection pool was transformed into a side flow S2ASH pool, and a new S2HBR pool was built, of which 18 microbial culture tanks were placed in the S2HBR pool (the tanks were filled with two layers of S and F fillers), and two The side flow tank is operated in parallel mode, the main biological MLSS is designed to be 4.5g/L, the reflux ratio is controlled by frequency conversion speed regulation to 33%-45%, the return sludge concentration is controlled at 14500-18000mg/L, and the sludge is drawn from the sludge return pump room Sludge 135m 3 /h is filtered by two 300 micron micro-sieves to the S2 tank, of which 60m 3 /h of return sludge is sent to S2HBR tank, and the residence time of S2HBR tank is 12h; 75m 3 /h of return flow sludge is sent to S2ASH tank , the residence time of S2ASH pool is 12h, the stirring power of S2ASH pool is 2w/m 3 , and the ORP is controlled at -300 to -400mv. 25m 3 /h of S2HBR effluent returns to the water inlet main of the sewage plant, and another 35m 3 /h enters the anaerobic tank, and the remaining 990m 3 /h of the total external return flow of RAS crosses the S2 tank and directly enters the oxidation ditch. After the transformation, the effluent of the sewage plant has reached the standard stably, and the environmental protection detection of the odorous gas at the factory boundary has reached the standard.
以上所述仅为本发明创造的较佳实施例而已,并不用以限制本发明创造,凡在本发明创造的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明创造的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the Within the scope of protection of the present invention.
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