CN209566482U - Polymer kneading member with different adhesion and extruder including same - Google Patents

Polymer kneading member with different adhesion and extruder including same Download PDF

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CN209566482U
CN209566482U CN201821977349.0U CN201821977349U CN209566482U CN 209566482 U CN209566482 U CN 209566482U CN 201821977349 U CN201821977349 U CN 201821977349U CN 209566482 U CN209566482 U CN 209566482U
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main body
polymer
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extruder
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王泽青
鄢景森
鄂永胜
代文双
孙帅婷
唐俊杰
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Liaoning Institute of Science and Technology
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Abstract

The utility model provides a kind of macromolecule with different adhesion strengths and is kneaded component and including its extruder.It includes: main body that the macromolecule, which is kneaded component, inner cavity with truncated conical shape, main body are open with open first as feed inlet at the smallest first end of cross-sectional area of the rotary table of main body and have open second opening at the maximum the second end of cross-sectional area of the rotary table in main body;And baffle, it is located in inner cavity in the second opening, and with the inner surface of main body with equal spacings, using as discharge port, wherein, main body has doping region and nonpolar area on the inner surface for being alternately arranged at main body on the direction vertical with the axis direction of rotary table.The macromolecule of example embodiment according to the present utility model, which is kneaded component, to replace the screw configuration in existing extruder to reduce time cost so as to avoid the replacement and maintenance to screw rod.

Description

具有不同粘附力的高分子混炼构件和包括其的挤出机Polymer kneading member with different adhesion and extruder including same

技术领域technical field

本实用新型涉及一种挤出机用混炼构件,特别地,涉及一种无螺杆挤出机混炼构件。The utility model relates to a mixing component for an extruder, in particular to a mixing component for a non-screw extruder.

背景技术Background technique

随着高分子材料的发展,合成出一种新型高分子材料越来越困难。因此目前高分子材料的主要研究方向是对已知高分子材料进行各种改性,而目前最常用的改性手段是共混改性。共混改性是指将两种或两种以上的高分子材料一同混炼,通过加入不同的改性剂以及原料之间不同的比例来制备出具有一定特定性质的新型复合高分子材料。而制备这种高分子复合材料所用到的最常用的设备就是挤出机。With the development of polymer materials, it is more and more difficult to synthesize a new polymer material. Therefore, the main research direction of polymer materials at present is to carry out various modifications on known polymer materials, and the most commonly used modification method is blending modification. Blending modification refers to mixing two or more polymer materials together, and preparing new composite polymer materials with certain specific properties by adding different modifiers and different ratios between raw materials. The most commonly used equipment used to prepare this polymer composite material is the extruder.

挤出机通常是将两种或两种以上的物质通过混炼以达到均匀混合或相对均匀混合的目的。常用的挤出机通常有单螺杆挤出机、双螺杆挤出机以及多螺杆挤出机等。挤出机的螺杆通常有着传输和混炼的双重作用,通过螺杆的转动,可以向前输送物质,不仅如此还可以对挤出机套筒中的熔融组分形成一定的剪切搅拌作用,已达到混炼均匀的目的。An extruder usually mixes two or more substances to achieve uniform or relatively uniform mixing. Commonly used extruders usually include single-screw extruders, twin-screw extruders, and multi-screw extruders. The screw of the extruder usually has the dual functions of transmission and mixing. Through the rotation of the screw, the material can be conveyed forward. Not only that, it can also form a certain shearing and stirring effect on the molten components in the extruder sleeve. To achieve the purpose of mixing evenly.

但是由于螺杆的存在,螺杆之间的磨损以及螺杆与套筒之间的磨损是不可避免的,因此此类挤出机通常在使用一段时间后需要进行对螺杆的保养过程。这一过程通常需要拆卸螺杆。拆卸过程将耗费大量时间成本。不仅如此,螺杆的制造材料和制造工艺也相当复杂,因此这将增大螺杆型挤出机的制造成本。However, due to the existence of the screw, the wear between the screw and the wear between the screw and the sleeve is inevitable, so this type of extruder usually needs to carry out the maintenance process of the screw after a period of use. This process usually requires removal of the screw. The disassembly process will consume a lot of time and cost. Not only that, but the manufacturing materials and manufacturing process of the screw are quite complicated, so this will increase the manufacturing cost of the screw extruder.

发明内容Contents of the invention

为了克服上述现有技术中的不足之处,本实用新型的目的在于提供一种无螺杆混炼构件以及包括该混炼构件的挤出机。In order to overcome the deficiencies in the above-mentioned prior art, the purpose of the utility model is to provide a screwless mixing member and an extruder including the mixing member.

根据本实用新型的一方面,提供一种具有不同粘附力的高分子混炼构件,所述高分子混炼构件包括:主体,具有圆台形状的内腔,主体在主体的圆台的横截面积最小的第一端部处具有作为进料口的敞开的第一开口并且在主体的圆台的横截面积最大的第二端部处具有敞开的第二开口;以及挡板,在第二开口处位于内腔中,并且与主体的内表面以等间距间隔开,以作为出料口,其中,主体具有在与圆台的轴方向垂直的方向上交替布置在主体的内表面上的极性区和非极性区。According to one aspect of the present utility model, a polymer kneading member with different adhesion is provided, and the polymer kneading member includes: a main body, an inner cavity having a frustum shape, and the cross-sectional area of the main body at the frustum of the main body having an open first opening as a feed inlet at the smallest first end and an open second opening at the second end with the largest cross-sectional area of the frustum of the body; and a baffle at the second opening Located in the inner cavity and spaced at equal intervals from the inner surface of the main body to serve as a discharge port, wherein the main body has polar regions and non-polar region.

根据本实用新型的示例实施例,第一端部处的圆台的横截面与第二端部处的圆台的横截面的直径比可以为1:2.5-1:10。According to an example embodiment of the present invention, the diameter ratio of the cross-section of the frustum of a cone at the first end to the cross-section of the frustum of a cone at the second end may be 1:2.5-1:10.

根据本实用新型的示例实施例,第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离的比可以为1:10-1:15。According to an example embodiment of the present invention, the ratio of the diameter of the cross-section of the frustum of a cone at the first end to the minimum distance from the first end to the second end may be 1:10-1:15.

根据本实用新型的示例实施例,极性区可以包括羟基,非极性区可以包括不小于10个碳的长直链烷烃。According to an exemplary embodiment of the present invention, the polar region may include a hydroxyl group, and the nonpolar region may include a long linear alkane having not less than 10 carbons.

根据本实用新型的示例实施例,极性区和非极性区在圆台的轴方向上的宽度可以相同。According to an example embodiment of the present invention, the polar region and the nonpolar region may have the same width in the axial direction of the frustum of the cone.

根据本实用新型的示例实施例,主体可以包括铁和铝中的一种。According to an example embodiment of the present invention, the body may include one of iron and aluminum.

根据本实用新型的另一方面,提供一种挤出机,所述挤出机包括:如上所述的高分子混炼构件;装料部,用于将物料加入到高分子混炼构件;以及出料部,用于成型地排出高分子混炼构件中的物料,其中,高分子混炼构件可转动地与装料部和出料部连接。According to another aspect of the present utility model, there is provided an extruder, the extruder comprising: the polymer mixing member as described above; a charging part, used for adding materials to the polymer mixing member; and The discharge part is used to shapely discharge the materials in the polymer mixing component, wherein the polymer mixing component is rotatably connected with the charging part and the discharge part.

根据本实用新型的示例实施例,所述装料部可以包括与混炼构件的进料口连通的加热圆筒以及位于加热圆筒内部的输料螺杆。According to an example embodiment of the present invention, the charging part may include a heating cylinder communicated with the feeding port of the kneading member, and a feeding screw located inside the heating cylinder.

根据本实用新型的示例实施例,所述出料部可以与混炼构件的出料口连通。According to an example embodiment of the present invention, the discharge part may communicate with the discharge port of the kneading member.

根据本实用新型的又一方面,提供一种挤出高分子的方法,所述方法包括:将物料加入到混炼构件内;以及使混炼构件转动,以使物料混合,其中,混炼构件包括:主体,具有圆台形状的内腔,主体在主体的圆台的横截面积最小的第一端部处具有作为进料口的敞开的第一开口并且在主体的圆台的横截面积最大的第二端部处具有敞开的第二开口;以及挡板,在第二开口处位于内腔中,并且与主体的内表面以等间距间隔开,以作为出料口,其中,主体具有在与圆台的轴方向垂直的方向上交替布置在主体的内表面上的极性区和非极性区。According to yet another aspect of the present invention, there is provided a method for extruding polymers, the method comprising: adding materials into a mixing member; and rotating the mixing member to mix the materials, wherein the mixing member Comprising: a main body with an inner cavity in the shape of a frustum of a cone, the main body has an open first opening as a feed inlet at the first end of the frustum of the main body with the smallest cross-sectional area and a first opening at the first end with the largest cross-sectional area of the frustum of the main body There is an open second opening at the two ends; and a baffle plate is located in the inner cavity at the second opening and is spaced at equal intervals from the inner surface of the main body to serve as a discharge port, wherein the main body has a The polar regions and the nonpolar regions are alternately arranged on the inner surface of the main body in a direction perpendicular to the axial direction of the main body.

根据本实用新型的示例实施例,第一端部处的圆台的横截面与第二端部处的圆台的横截面的直径比可以为1:2.5-1:10。According to an example embodiment of the present invention, the diameter ratio of the cross-section of the frustum of a cone at the first end to the cross-section of the frustum of a cone at the second end may be 1:2.5-1:10.

根据本实用新型的示例实施例,第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离的比可以为1:10-1:15。According to an example embodiment of the present invention, the ratio of the diameter of the cross-section of the frustum of a cone at the first end to the minimum distance from the first end to the second end may be 1:10-1:15.

根据本实用新型的示例实施例,极性区可以包括羟基,非极性区可以包括不小于10个碳的长直链烷烃。According to an exemplary embodiment of the present invention, the polar region may include a hydroxyl group, and the nonpolar region may include a long linear alkane having not less than 10 carbons.

根据本实用新型的示例实施例,极性区和非极性区在圆台的轴方向上的宽度可以相同。According to an example embodiment of the present invention, the polar region and the nonpolar region may have the same width in the axial direction of the frustum of the cone.

根据本实用新型的示例实施例,在将物料加入到混炼构件内中,可以通过装料部将物料加入到混炼构件内。According to an exemplary embodiment of the present invention, when adding the material into the mixing member, the material may be added into the mixing member through the charging part.

根据本实用新型的示例实施例,所述装料部可以包括与混炼构件的进料口连通的加热圆筒以及位于加热圆筒上部,用于加料的加料口和位于加热圆筒内部的输料螺杆。According to an exemplary embodiment of the present invention, the charging part may include a heating cylinder communicated with the feeding port of the kneading member and located on the upper part of the heating cylinder, a feeding port for feeding and a conveying port located inside the heating cylinder. Feed screw.

根据本实用新型的示例实施例,可以以式1的角速度来使混炼构件绕圆台的轴转动,According to an exemplary embodiment of the present invention, the kneading member can be rotated around the axis of the circular table at the angular velocity of formula 1,

式1: Formula 1:

其中,在式1中,ω表示混炼构件转动的角速度,g表示重力加速度,d表示第一端部处的圆台的横截面的直径。Here, in Equation 1, ω represents the angular velocity of the rotation of the kneading member, g represents the gravitational acceleration, and d represents the diameter of the cross-section of the truncated cone at the first end.

根据本实用新型的示例实施例,所述方法还可以包括:成型地排出混炼构件中的物料。According to an example embodiment of the present invention, the method may further include: discharge the material in the kneading member in a shaped manner.

根据本实用新型的示例实施例,可以通过排出部成型地排出混炼构件中的物料。According to an exemplary embodiment of the present invention, the material in the kneading member can be discharged in a shaped manner through the discharge part.

根据本实用新型的示例实施例,主体可以包括铁和铝中的一种。According to an example embodiment of the present invention, the body may include one of iron and aluminum.

根据本实用新型的具有不同粘附力的高分子混炼构件和包括其的挤出机具有如下技术效果中的至少一个:According to the utility model, the polymer mixing member with different adhesion and the extruder comprising it have at least one of the following technical effects:

1)本实用新型用具有极性区和非极性区的混炼构件代替现有的挤出机中的螺杆构造,从而避免了对螺杆的更换与保养,降低了时间成本;1) The utility model replaces the screw structure in the existing extruder with a mixing member having a polar area and a non-polar area, thereby avoiding the replacement and maintenance of the screw, and reducing the time cost;

2)本实用新型的混炼构件的结构简单,降低了制造成本;2) The structure of the mixing member of the utility model is simple, which reduces the manufacturing cost;

3)本实用新型提出的新的挤出机用混炼构件为该领域提供新的思路。3) The new mixing member for extruder proposed by the utility model provides new ideas for this field.

附图说明Description of drawings

为了更清楚地说明本实用新型实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following will briefly introduce the drawings required for the description of the embodiments or the prior art.

图1是示出了根据本实用新型的示例实施例的高分子混炼构件的透视图;1 is a perspective view showing a polymer mixing member according to an exemplary embodiment of the present invention;

图2是示出了图1中示出的高分子混炼构件的主体的展开的图;Fig. 2 is a diagram showing the development of the main body of the polymer kneading member shown in Fig. 1;

图3是示出了根据本实用新型的示例实施例的挤出机的平面示意图。FIG. 3 is a schematic plan view showing an extruder according to an example embodiment of the present invention.

具体实施方式Detailed ways

对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本实用新型。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本实用新型的精神或范围的情况下,在其它实施例中实现。因此,本实用新型将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above description of the disclosed embodiments enables those skilled in the art to realize or use the utility model. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. Therefore, the present invention will not be limited to these embodiments shown herein, but will conform to the widest scope consistent with the principles and novel features disclosed herein.

在下文中将参照图1和图2来详细描述根据本实用新型的示例实施例的高分子混炼构件。Hereinafter, a polymer kneading member according to an exemplary embodiment of the present invention will be described in detail with reference to FIGS. 1 and 2 .

图1是示出了根据本实用新型的示例实施例的高分子混炼构件的透视图。图2是示出了图1中示出的高分子混炼构件的主体的展开的图。FIG. 1 is a perspective view showing a polymer kneading member according to an exemplary embodiment of the present invention. FIG. 2 is a diagram showing development of a main body of the polymer kneading member shown in FIG. 1 .

参照图1和图2,具有不同粘附力的高分子混炼构件100可以包括主体110和挡板120。Referring to FIGS. 1 and 2 , the polymer kneading member 100 having different adhesive forces may include a body 110 and a baffle 120 .

主体110可以具有圆台形形状的中空内腔,并且主体110的上端部和下端部可以是敞开的,具体地,主体110在主体110的圆台的横截面积最小的第一端部处具有敞开的第一开口111,其可以作为高分子混炼构件100的进料口;主体110在主体110的圆台的横截面积最大的第二端部处具有敞开的第二开口112,其可以作为高分子混炼构件100的出料口。也就是说,主体110可以是由板体围成的且上下端部是敞开的一体结构的形式。The main body 110 may have a hollow cavity in the shape of a truncated cone, and the upper end and the lower end of the main body 110 may be open, specifically, the main body 110 has an open at the first end where the cross-sectional area of the frustum of the main body 110 is the smallest. The first opening 111 can be used as the feed port of the polymer mixing member 100; the main body 110 has an open second opening 112 at the second end with the largest cross-sectional area of the circular table of the main body 110, which can serve as a polymer The outlet of the mixing member 100. That is to say, the main body 110 may be in the form of an integral structure surrounded by boards with open upper and lower ends.

在本实用新型的示例实施例中,主体110可以由铁或铝形成,从结构强度的角度选择,优选铁作为主体110的材质;然而,本实用新型不限于此。In an exemplary embodiment of the present invention, the main body 110 may be formed of iron or aluminum, and iron is preferred as the material of the main body 110 in terms of structural strength; however, the present invention is not limited thereto.

此外,主体110还可以具有在与圆台的轴方向X垂直的方向上交替地布置在主体110的内表面上的极性区113和非极性区114。此外,极性区113和非极性区114在圆台的轴方向上的宽度可以相同。这里,圆台的轴方向X可以指圆台的高度方向。In addition, the body 110 may also have polar regions 113 and non-polar regions 114 alternately arranged on the inner surface of the body 110 in a direction perpendicular to the axial direction X of the frustum of a cone. In addition, the polar region 113 and the nonpolar region 114 may have the same width in the axis direction of the frustum of a cone. Here, the axial direction X of the truncated cone may refer to the height direction of the truncated circular cone.

在主体110的内表面上沿与圆台的轴方向X垂直的方向交替布置有极性区113与非极性区114,其主要的工作原理在于:主体110在转动的情况下,当熔融态的非极性高分子(例如,聚丙烯)在经由主体110的内腔流经非极性区114时,由于两者极性相同,因此对非极性高分子具有较高的粘附力,此时非极性高分子与主体110的内表面上的非极性区114接触的界面处流速较低,非极性高分子的内部速度梯度分布较大;当非极性高分子流经极性区113时,对非极性高分子所受粘附力较低,界面流速较快,对非极性高分子的内部速度梯度影响较低,因此,当非极性高分子周期性地流经交替布置在主体110的内表面上的极性区113和非极性区114后,主体110内部的速度梯度发生周期性变化,这种变化可以有效地提高混炼效率。这里,由于熔融态的极性高分子流经主体110的内部的工作原理与熔融态的非极性高分子流经主体110的内部的工作原理基本相同,因此将不对其进行赘述。On the inner surface of the main body 110, polar regions 113 and non-polar regions 114 are arranged alternately along the direction perpendicular to the axial direction X of the truncated cone. The main working principle is: when the main body 110 is rotating, when the molten When the non-polar polymer (for example, polypropylene) flows through the non-polar region 114 through the lumen of the main body 110, since the two have the same polarity, it has a higher adhesion to the non-polar polymer. The flow velocity at the interface where the non-polar polymer contacts the non-polar region 114 on the inner surface of the main body 110 is relatively low, and the internal velocity gradient distribution of the non-polar polymer is relatively large; when the non-polar polymer flows through the polar In zone 113, the adhesion force to the non-polar polymer is low, the interface flow velocity is fast, and the influence on the internal velocity gradient of the non-polar polymer is low. Therefore, when the non-polar polymer periodically flows through After the polar regions 113 and non-polar regions 114 are alternately arranged on the inner surface of the main body 110, the velocity gradient inside the main body 110 changes periodically, and this change can effectively improve the mixing efficiency. Here, since the working principle of the molten polar polymer flowing through the interior of the body 110 is basically the same as that of the molten non-polar polymer flowing through the interior of the main body 110 , it will not be described in detail.

在传统的挤出机中,通常使用螺杆进行混炼,这势必会额外地增加对螺杆的维护和更换的工艺,从而现有的挤出机的工作效率相对较低。然而,在本实用新型中,在主体110的内表面上沿与圆台的轴方向X垂直的方向交替布置极性区113与非极性区114来代替现有的挤出机中的螺杆能够在保证混炼效果的同时提高工作效率。In a traditional extruder, a screw is usually used for mixing, which will inevitably increase the maintenance and replacement process of the screw, so that the working efficiency of the existing extruder is relatively low. However, in the present invention, polar regions 113 and non-polar regions 114 are alternately arranged on the inner surface of the main body 110 along the direction perpendicular to the axial direction X of the truncated cone to replace the screw in the existing extruder. Improve work efficiency while ensuring mixing effect.

高分子混炼构件100的主体110对于高分子的混炼效果的影响主要存在三个影响因素,分别包括:第一端部处的圆台的横截面(即,第一开口111)与第二端部处的圆台的横截面(即,第二开口112)的直径比、第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离(也即,圆台的高度)的比以及高分子混炼构件100的极性区113和非极性区114的数量。The main body 110 of the polymer kneading member 100 mainly has three influencing factors on the kneading effect of the polymer, including: the cross section of the truncated cone at the first end (that is, the first opening 111 ) and the second end. The ratio of the diameters of the cross-section of the frustum at the end (i.e., the second opening 112), the diameter of the cross-section of the frustum at the first end to the minimum distance from the first end to the second end (i.e., the frustum height) and the number of polar regions 113 and nonpolar regions 114 of the polymer kneading member 100.

通过试验可知,当第一端部处的圆台的横截面与第二端部处的圆台的横截面的直径比过大,特别是大于1:2.5时,主体的圆台趋向变为圆柱体,这会不利于物料在高分子混炼构件100中从第一端部(即,进料口)向第二端部(即,出料口)的移动;同样地,当第一端部处的圆台的横截面与第二端部处的圆台的横截面的直径比减小,特别是小于1:10时,主体的圆台趋向变为圆锥体,这会使高分子混炼构件100需要高速转动才能将内部的熔融物料从第一端部输送到第二端部,这种情况不仅会增加能耗,而且还会增大高分子混炼构件的磨损。因此,在本实用新型的示例实施例中,第一端部处的圆台的横截面与第二端部处的圆台的横截面的直径比可以为1:2.5-1:10,优选地,可以为1:3.5-1:9、1:4.5-1:8、1:5.5-1:7、1:4-1:7、1:5-1:9或1:6-1:8。It can be known through experiments that when the diameter ratio of the cross-section of the frustum at the first end to the cross-section of the frustum at the second end is too large, especially greater than 1:2.5, the frustum of the main body tends to become a cylinder, which means It will be unfavorable for the movement of the material from the first end (ie, the feed port) to the second end (ie, the discharge port) in the polymer mixing member 100; similarly, when the circular platform at the first end The diameter ratio of the cross-section of the cross-section to the cross-section of the truncated cone at the second end is reduced, especially when it is less than 1:10, the truncated cone of the main body tends to become a cone, which will cause the polymer mixing member 100 to rotate at a high speed. Transporting the internal molten material from the first end to the second end will not only increase energy consumption, but also increase the wear of the polymer mixing components. Therefore, in an exemplary embodiment of the present invention, the diameter ratio of the cross section of the frustum of a cone at the first end to the cross section of the frustum of a second end may be 1:2.5-1:10, preferably, may be 1:3.5-1:9, 1:4.5-1:8, 1:5.5-1:7, 1:4-1:7, 1:5-1:9 or 1:6-1:8.

同样地,通过试验可知,当第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离(也即,圆台的高度)的比过大,特别是大于1:10时,主体110的圆台高度过低,使得物料在主体110内部的混炼时间较短,混炼效果不佳;当第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离的比过小,特别是大于1:15时,主体110的圆台高度过大,物料在主体110内部的混炼时间较长,容易引起物料在高分子混炼构件100内大量堆积,同样不利于混炼效果。因此,在本实用新型的示例实施例中,第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离的比可以为1:10-1:15,优选地,1:9.5-1:14.5、1:9-1:14、1:8.5-1:13.5、1:8-1:13、1:7.5-1:12.5、1:8-1:12、1:8.5-1:11.5、1:9-1:11、1:12-1:14或1:11-1:13。Likewise, it can be seen through experiments that when the ratio of the diameter of the cross-section of the frustum of a cone at the first end to the minimum distance from the first end to the second end (that is, the height of the frustum of a cone) is too large, especially greater than At 1:10, the height of the circular platform of the main body 110 is too low, so that the mixing time of the material inside the main body 110 is short, and the mixing effect is not good; when the diameter of the cross-section of the circular platform at the first end is If the ratio of the minimum distance from the top to the second end is too small, especially when it is greater than 1:15, the height of the round table of the main body 110 is too large, and the mixing time of the material inside the main body 110 is longer, which is likely to cause the material to be mixed in the polymer. A large amount of accumulation in the component 100 is also unfavorable for the mixing effect. Therefore, in an exemplary embodiment of the present invention, the ratio of the diameter of the cross-section of the frustum of a cone at the first end to the minimum distance from the first end to the second end may be 1:10-1:15, Preferably, 1:9.5-1:14.5, 1:9-1:14, 1:8.5-1:13.5, 1:8-1:13, 1:7.5-1:12.5, 1:8-1:12 , 1:8.5-1:11.5, 1:9-1:11, 1:12-1:14 or 1:11-1:13.

同样地,高分子混炼构件100的极性区113和非极性区114的数量过多,将增大高分子混炼构件的制造难度,而且由于主体110的内表面上的极性区113和非极性区114间隔较小,不利于内部流速的传输,使得混炼效果变差;如果高分子混炼构件100的极性区113和非极性区114的数量过少,主体110内部的速度梯度变化周期变长,同样也会降低混炼效果。通常极性区113或非极性区114的数量为从第一端部到第二端部的最小距离的五分之一,记为:n=l/5,其中,n为极性区113或非极性区114的数量,l为从第一端部到第二端部的最小距离。此外,在本实用新型的非限制性示例实施例中,极性区113与非极性区114的数量可以基本相同。Similarly, too many polar regions 113 and non-polar regions 114 of the polymer kneading member 100 will increase the manufacturing difficulty of the polymer kneading member, and because the polar regions 113 on the inner surface of the main body 110 The distance between the non-polar zone 114 and the non-polar zone 114 is small, which is not conducive to the transmission of the internal flow rate, making the mixing effect worse; The speed gradient change period becomes longer, which will also reduce the mixing effect. Usually the number of polar regions 113 or non-polar regions 114 is one-fifth of the minimum distance from the first end to the second end, expressed as: n=l/5, wherein n is the polar region 113 or the number of non-polar regions 114, l is the minimum distance from the first end to the second end. Furthermore, in non-limiting example embodiments of the present invention, the number of polar regions 113 and non-polar regions 114 may be substantially the same.

在本实用新型的示例实施例中,主体110的内表面上的极性区113可以包括羟基,主体110的内表面上的非极性区114可以包括不小于10个碳的长直链烷烃。在本实用新型中,主体110的内表面上的极性区113和非极性区114可以是通过对主体110的内表面进行化学修饰而得到。下面将详细地描述对主体110的内表面进行化学修饰以得到极性区113和非极性区114的方法。In an exemplary embodiment of the present invention, the polar region 113 on the inner surface of the body 110 may include a hydroxyl group, and the non-polar region 114 on the inner surface of the body 110 may include a long linear alkane of not less than 10 carbons. In the present invention, the polar region 113 and the non-polar region 114 on the inner surface of the main body 110 can be obtained by chemically modifying the inner surface of the main body 110 . The method of chemically modifying the inner surface of the body 110 to obtain the polar region 113 and the non-polar region 114 will be described in detail below.

首先,可以使用例如pH为2的盐酸或硫酸的强酸除去主体110的内金属表面上的氧化膜,并用清水冲洗至pH值为中性。First, a strong acid such as hydrochloric acid or sulfuric acid with a pH of 2 can be used to remove the oxide film on the inner metal surface of the main body 110, and rinse with water until the pH is neutral.

接着,用丙酮清洗除去了氧化膜的金属表面,以除去金属表面可能残存的油脂,并用清水冲洗干净,并晾干。Next, wash the metal surface from which the oxide film has been removed with acetone to remove the grease that may remain on the metal surface, rinse it with clean water, and let it dry.

然后,可以在主体110的内金属表面的预定区域上以每平方米15g-20g的不小于10个碳的长直链烷烃类化合物的量来涂覆不小于10个碳的长直链烷烃类化合物,随后晾干,该被涂覆的预定区域即为非极性区114,而未涂覆不小于10个碳的长直链烷烃类化合物的区域即为极性区113,由于金属表面经过处理后可以带有羟基,因此极性区113的极性基团为羟基。Then, the long straight-chain alkanes with not less than 10 carbons may be coated on a predetermined area of the inner metal surface of the main body 110 in an amount of 15g-20g per square meter of long-chain alkanes with not less than 10 carbons compound, then dried, the coated predetermined area is the non-polar area 114, and the area not coated with long straight-chain alkane compounds with not less than 10 carbons is the polar area 113, because the metal surface passes through After treatment, it can have a hydroxyl group, so the polar group in the polar region 113 is a hydroxyl group.

在本实用新型的示例实施例中,不小于10个碳的长直链烷烃类化合物可以是不小于10个碳的长直链烷烃的三甲基硅氧烷,诸如正十二烷基三甲氧基硅烷或正十六烷基三甲氧基硅烷等;然而,本实用新型不限于此。In an exemplary embodiment of the present invention, the long-chain alkane compound of not less than 10 carbons may be trimethylsiloxane of a long-chain alkane of not less than 10 carbons, such as n-dodecyltrimethoxy silane or n-hexadecyltrimethoxysilane, etc.; however, the present invention is not limited thereto.

挡板120可以在主体110的第二端部处位于主体110的内腔中,并且与主体110的内表面以等间距间隔开,从而作为出料口。The baffle 120 may be located in the inner cavity of the main body 110 at the second end of the main body 110 and spaced at equal intervals from the inner surface of the main body 110 to serve as a discharge port.

挡板120可以具有圆形的板构造,当设置在主体110的第二端部处时,挡板120可以与圆台的第二端部处的横截面是同心圆。The baffle 120 may have a circular plate configuration, and when disposed at the second end of the main body 110 , the baffle 120 may be a concentric circle with a cross-section at the second end of the circular frustum.

此外,挡板120可以通过支架经由例如焊接等固定在主体110的第二端部处的内表面上。然而,本实用新型不限于此,例如,可以通过任何合适的方法将挡板120固定在主体110的第二端部处的内表面上。In addition, the baffle 120 may be fixed on the inner surface at the second end of the main body 110 by a bracket via, for example, welding. However, the present invention is not limited thereto, for example, the baffle 120 may be fixed on the inner surface at the second end of the main body 110 by any suitable method.

下面将以示例和对比示例来详细说明本实用新型的示例实施例的高分子混炼构件100的制造方法以及评价标准。The manufacturing method and evaluation criteria of the polymer kneading component 100 of the exemplary embodiment of the present invention will be described in detail below with examples and comparative examples.

[制造示例][Manufacturing example]

示例1Example 1

用pH为2的盐酸的强酸除去主体110的内金属表面上的氧化膜,并用清水冲洗至pH值为中性;接着,用丙酮清洗除去了氧化膜的金属表面,以除去金属表面可能残存的油脂,并用清水冲洗干净,并晾干;然后,可以在主体110的内金属表面的预定区域上以每平方米15g正十二烷基三甲氧基硅烷的量来涂覆正十二烷基三甲氧基硅烷,随后晾干,该被涂覆的预定区域即为非极性区114,而未涂覆正十二烷基三甲氧基硅烷的区域即为极性区。其中,第一端部处的圆台的横截面的直径d1=10cm,第二端部处的圆台的横截面的直径d2=50cm,第一端部到第二端部的最小距离为l=100cm。Use a strong acid of hydrochloric acid with a pH of 2 to remove the oxide film on the inner metal surface of the main body 110, and rinse it with water until the pH value is neutral; then, wash the metal surface from which the oxide film has been removed with acetone to remove possible residues on the metal surface. grease, and rinsed with clean water, and dried; then, on the predetermined area of the inner metal surface of the main body 110, n-dodecyltrimethoxysilane can be coated with n-dodecyltrimethoxysilane in an amount of 15g per square meter oxysilane, and then dried, the coated predetermined area is the non-polar area 114, and the area not coated with n-dodecyltrimethoxysilane is the polar area. Wherein, the diameter d 1 of the cross section of the truncated cone at the first end portion=10cm, the diameter d 2 of the cross section of the circular truncated portion at the second end portion=50cm, and the minimum distance from the first end portion to the second end portion is 1 = 100 cm.

示例2Example 2

除了第二端部处的圆台的横截面的直径d=80cm,第一端部到第二端部的最小距离为l=120cm之外,以与示例1的方法相同的方法来制造高分子混炼构件。Except that the diameter d=80cm of the cross-section of the circular frustum at the second end, the minimum distance from the first end to the second end is l=120cm, the same method as the method of Example 1 is used to manufacture the polymer mixture. Refining components.

示例3Example 3

除了第二端部处的圆台的横截面的直径d=25cm,第一端部到第二端部的最小距离为l=150cm之外,以与示例1的方法相同的方法来制造高分子混炼构件。Except that the diameter d=25cm of the cross-section of the circular frustum at the second end, the minimum distance from the first end to the second end is l=150cm, the same method as the method of Example 1 is used to manufacture the polymer mixture. Refining components.

示例4Example 4

除了第二端部处的圆台的横截面的直径d=100cm,第一端部到第二端部的最小距离为l=130cm之外,以与示例1的方法相同的方法来制造高分子混炼构件。Except that the diameter d=100cm of the cross-section of the circular frustum at the second end, the minimum distance from the first end to the second end is l=130cm, the same method as that of example 1 is used to manufacture the polymer mixture. Refining components.

对比示例1Comparative example 1

除了第二端部处的圆台的横截面的直径d=13cm之外,以与示例1的方法相同的方法来制造高分子混炼构件。A polymer kneading member was manufactured in the same method as that of Example 1 except that the diameter of the cross-section of the truncated cone at the second end was d=13 cm.

对比示例2Comparative example 2

除了第二端部处的圆台的横截面的直径d=140cm之外,以与示例1的方法相同的方法来制造高分子混炼构件。A polymer kneading member was manufactured in the same method as that of Example 1 except that the diameter of the cross-section of the truncated cone at the second end was d = 140 cm.

对比示例3Comparative example 3

除了第一端部到第二端部的最小距离为l=25cm之外,以与示例1的方法相同的方法来制造高分子混炼构件。The polymer kneading member was manufactured in the same manner as in Example 1, except that the minimum distance from the first end to the second end was l=25 cm.

对比示例4Comparative example 4

除了第一端部到第二端部的最小距离为l=190cm之外,以与示例1的方法相同的方法来制造高分子混炼构件。The polymer kneading member was manufactured in the same manner as in Example 1 except that the minimum distance from the first end to the second end was l=190 cm.

[评价示例][Evaluation example]

通常情况下,可以通过DSC测定共混物Tg的数量来评价两种高分子物料的共混效果,也即,当将两种高分子物料共混时,若检测到一个Tg值,则说明共混效果较好;反之,若检测到两个Tg值,则说明共混效果较差。应用这一简易的判断标准可以评价混炼设备的混炼效果。Usually, the blending effect of two polymer materials can be evaluated by measuring the Tg of the blend by DSC, that is, when two polymer materials are blended, if a Tg value is detected, it means that the blend The blending effect is better; on the contrary, if two Tg values are detected, it indicates that the blending effect is poor. Applying this simple criterion can evaluate the mixing effect of mixing equipment.

示例1的评价Evaluation of Example 1

将质量比为85:15的熔融态的聚丙烯(PP)与低密度聚乙烯(LDPE)加入到示例1的混炼构件100中,然而在200℃下进行混炼,混炼后通过DSC进行测定。测定结果示出在下面的表1中。Add molten polypropylene (PP) and low-density polyethylene (LDPE) with a mass ratio of 85:15 to the mixing member 100 of Example 1, and knead at 200°C, and then carry out DSC after kneading Determination. The measurement results are shown in Table 1 below.

示例2至示例4以及对比示例1至对比示例4的评价Evaluation of Example 2 to Example 4 and Comparative Example 1 to Comparative Example 4

以与评价示例1的方式相同的方式来评价示例2至示例4以及对比示例1至对比示例4。测定结果示出在下面的表1中。Examples 2 to 4 and Comparative Examples 1 to 4 were evaluated in the same manner as Example 1 was evaluated. The measurement results are shown in Table 1 below.

表1Table 1

d<sub>1</sub>(cm)d<sub>1</sub>(cm) d<sub>2</sub>(cm)d<sub>2</sub>(cm) l(cm)l (cm) DSC测定值DSC measured value 示例1Example 1 1010 5050 100100 11 示例2Example 2 1010 8080 120120 11 示例3Example 3 1010 2525 150150 11 示例4Example 4 1010 100100 130130 11 对比示例1Comparative example 1 1010 1313 100100 22 对比示例2Comparative example 2 1010 140140 100100 22 对比示例3Comparative example 3 1010 5050 2525 22 对比示例4Comparative example 4 1010 5050 190190 22

从示例1和示例2以及对比示例1和对比示例2可以看出,第一端部处的圆台的横截面的直径d1与第二端部处的圆台的横截面的直径d2的比不在1:2.5-1:10的范围内时,共混效果较差。从示例3和示例4以及对比示例3和对比示例4可以看出,当第一端部处的圆台的横截面的直径d1与第二端部处的圆台的横截面的直径d2的比或是第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离的比不在最优范围内,共混效果都会变差。From Example 1 and Example 2 and Comparative Example 1 and Comparative Example 2, it can be seen that the ratio of the diameter d 1 of the cross-section of the frustum of a cone at the first end to the diameter d 2 of the cross-section of the cone at the second end is not In the range of 1:2.5-1:10, the blending effect is poor. From Example 3 and Example 4 and Comparative Example 3 and Comparative Example 4, it can be seen that when the diameter d 1 of the cross-section of the frustum of a cone at the first end portion is compared to the diameter d 2 of the cross-section of the frustum of a cone at the second end portion Or the ratio of the diameter of the cross-section of the truncated cone at the first end to the minimum distance from the first end to the second end is not within the optimum range, and the blending effect will be deteriorated.

在下文中将参照图3详细地描述根据本实用新型的示例实施例的包括上述高分子混炼构件100的挤出机。Hereinafter, an extruder including the above-described polymer kneading member 100 according to an exemplary embodiment of the present invention will be described in detail with reference to FIG. 3 .

图3是示出了根据本实用新型的示例实施例的挤出机的平面示意图。FIG. 3 is a schematic plan view showing an extruder according to an example embodiment of the present invention.

参照图3,根据本实用新型的示例实施例的挤出机10可以包括如上所述的高分子混炼构件100、装料部200和出料部300。Referring to FIG. 3 , the extruder 10 according to an example embodiment of the present invention may include the polymer kneading member 100 , the charging part 200 and the discharging part 300 as described above.

这里提及的高分子混炼构件100与上面描述的高分子混炼构件基本相同,因此将不再进行赘述。The polymer kneading member 100 mentioned here is basically the same as the polymer kneading member described above, so it will not be described again.

装料部200可以是用于将待混炼的物料加入到高分子混炼构件100中的装置。例如,装料部200可以包括与高分子混炼构件100的第一端部(即,进料口)连通的加热圆筒220以及位于加热圆筒220上部,用于加料的加料口210和位于加热圆筒210内部的输料螺杆230。然而,本实用新型不限于此,装料部200可以包括任何合适的部件,只有各部件装配后的装料部200能够使待混炼的物料熔融且将熔融的待混炼的物料输送到高分子混炼构件100的内腔中即可。The charging part 200 may be a device for adding materials to be kneaded into the polymer kneading member 100 . For example, the charging part 200 may include a heating cylinder 220 communicated with the first end of the polymer kneading member 100 (ie, the feed port) and an upper part of the heating cylinder 220, a feed port 210 for feeding and a The feed screw 230 inside the barrel 210 is heated. However, the utility model is not limited thereto, and the charging part 200 may include any suitable components, only the charging part 200 after the components are assembled can melt the material to be kneaded and transport the molten material to be kneaded to the high The inner cavity of the molecular kneading member 100 is sufficient.

出料部300可以是用于成型地排出高分子混炼构件100中的熔融的物料的装置。出料部300可以与高分子混炼构件100的出料口连通,以接收熔融的物料,从而将熔融的物料成型地排出,以完成物料的混炼。在本实用新型的非限制性实施例中,出料部300可以包括现有的挤出机中包含的任何适合的部件,例如传送部件、冷却部件和切割部件等。在此将不对其进行详细赘述。The discharge unit 300 may be a device for discharging the molten material in the polymer kneading member 100 in a shaped manner. The discharge part 300 can communicate with the discharge port of the polymer mixing component 100 to receive the molten material, so as to discharge the molten material in a shaped form to complete the mixing of the material. In a non-limiting embodiment of the present invention, the discharge unit 300 may include any suitable components included in an existing extruder, such as a conveying component, a cooling component, a cutting component, and the like. It will not be described in detail here.

下面将详细描述根据本实用新型的示例实施例的挤出机10的挤出高分子的方法。A method of extruding a polymer by the extruder 10 according to an exemplary embodiment of the present invention will be described in detail below.

根据本实用新型的挤出高分子的方法包括将物料加入到混炼构件内以及使混炼构件转动以使物料混合。The method for extruding a polymer according to the present invention includes adding materials into a mixing member and rotating the mixing member to mix the materials.

在物料加入到混炼构件内的步骤中,可以通过如上所述的装料部200将待混炼的物料熔融,然后通过输料螺杆230传送至到混炼构件内。这里的混炼构件与如上所述的高分子混炼构件100的构造基本相同,因此将不再进行赘述。In the step of adding materials into the mixing member, the materials to be kneaded can be melted through the charging part 200 as described above, and then conveyed into the mixing member through the feeding screw 230 . The structure of the kneading member here is basically the same as that of the polymer kneading member 100 described above, so it will not be described again.

在使混炼构件转动的步骤中,可以以下面的式1的速度(例如,角速度)来使混炼构件绕圆台的轴转动。In the step of rotating the kneading member, the kneading member may be rotated about the axis of the circular table at a speed (for example, angular velocity) of the following formula 1.

式1: Formula 1:

在式1中,ω表示混炼构件转动的角速度,g表示重力加速度,d表示第一端部处的圆台的横截面的直径。In Equation 1, ω represents the angular velocity at which the kneading member rotates, g represents the gravitational acceleration, and d represents the diameter of the cross-section of the truncated cone at the first end.

此外,根据本实用新型的示例实施例的挤出高分子的方法还可以包括成型地排出混炼构件中的物料。可以通过如上所述的出料部来成型地排出混炼构件中的物料。In addition, the method of extruding a polymer according to an exemplary embodiment of the present invention may further include ejecting the material in the kneading member in a shaped manner. The material in the kneading member can be discharged in a shaped manner through the discharge as described above.

综上所述,根据本实用新型的示例实施例的高分子混炼构件100能够代替现有的挤出机中的螺杆构造,从而避免了对螺杆的更换与保养,降低了时间成本。此外,本实用新型的混炼构件的结构简单,降低了制造成本。而且本实用新型的高分子混炼构件100的混炼效果能够达到螺杆型挤出机的混炼效果。To sum up, the polymer mixing member 100 according to the exemplary embodiment of the present invention can replace the screw structure in the existing extruder, thereby avoiding the replacement and maintenance of the screw, and reducing the time cost. In addition, the structure of the mixing member of the utility model is simple, which reduces the manufacturing cost. Moreover, the mixing effect of the polymer mixing member 100 of the present invention can reach the mixing effect of a screw extruder.

Claims (7)

1.一种具有不同粘附力的高分子混炼构件,其特征在于,所述高分子混炼构件包括:1. A polymer kneading member with different adhesions, characterized in that, said polymer kneading member comprises: 主体,具有圆台形状的内腔,主体在主体的圆台的横截面积最小的第一端部处具有作为进料口的敞开的第一开口并且在主体的圆台的横截面积最大的第二端部处具有敞开的第二开口;以及The main body has an inner cavity in the shape of a truncated cone, the main body has an open first opening as a feed inlet at the first end of the truncated circular cross-sectional area of the main body with the smallest cross-sectional area and a second end with the largest cross-sectional area of the circular truncated circular body of the main body having an open second opening at the top; and 挡板,在第二开口处位于内腔中,并且与主体的内表面以等间距间隔开,以作为出料口,a baffle located in the cavity at the second opening and equally spaced from the inner surface of the main body to serve as a discharge port, 其中,主体具有在与圆台的轴方向垂直的方向上交替布置在主体的内表面上的极性区和非极性区。Wherein, the body has polar regions and non-polar regions alternately arranged on the inner surface of the body in a direction perpendicular to the axial direction of the frustum of a cone. 2.如权利要求1所述的高分子混炼构件,其特征在于,第一端部处的圆台的横截面与第二端部处的圆台的横截面的直径比为1:2.5-1:10。2. Polymer mixing member as claimed in claim 1, is characterized in that, the diameter ratio of the cross-section of the truncated circle at the first end place and the cross-section of the truncated circle at the second end place is 1:2.5-1: 10. 3.如权利要求1或2所述的高分子混炼构件,其特征在于,第一端部处的圆台的横截面的直径与从第一端部到第二端部的最小距离的比为1:10-1:15。3. The polymer mixing member according to claim 1 or 2, wherein the ratio of the diameter of the cross-section of the truncated cone at the first end to the minimum distance from the first end to the second end is 1:10-1:15. 4.如权利要求1所述的高分子混炼构件,其特征在于,极性区和非极性区在圆台的轴方向上的宽度相同。4. The polymer kneading member according to claim 1, wherein the polar region and the nonpolar region have the same width in the axial direction of the truncated cone. 5.一种挤出机,其特征在于,所述挤出机包括:5. an extruder, is characterized in that, described extruder comprises: 如权利要求1至4中任一项所述的高分子混炼构件;The polymer mixing member as claimed in any one of claims 1 to 4; 装料部,用于将物料加入到高分子混炼构件;以及a charging section for adding materials to the polymer mixing member; and 出料部,用于成型地排出高分子混炼构件中的物料,The discharge part is used to discharge the materials in the polymer mixing member in a shaped manner, 其中,高分子混炼构件可转动地与装料部和出料部连接。Wherein, the polymer mixing member is rotatably connected with the charging part and the discharging part. 6.如权利要求5所述的挤出机,其特征在于,所述装料部包括与高分子混炼构件的进料口连通的加热圆筒以及位于加热圆筒内部的输料螺杆。6. The extruder according to claim 5, wherein the charging part comprises a heating cylinder communicated with the feed port of the polymer mixing member and a feeding screw located inside the heating cylinder. 7.如权利要求5所述的挤出机,其特征在于,所述出料部与高分子混炼构件的出料口连通。7. The extruder according to claim 5, characterized in that, the discharge part communicates with the discharge port of the polymer mixing component.
CN201821977349.0U 2018-11-28 2018-11-28 Polymer kneading member with different adhesion and extruder including same Expired - Fee Related CN209566482U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109454846A (en) * 2018-11-28 2019-03-12 辽宁科技学院 Macromolecule with different adhesion strengths is kneaded component and including its extruder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109454846A (en) * 2018-11-28 2019-03-12 辽宁科技学院 Macromolecule with different adhesion strengths is kneaded component and including its extruder
CN109454846B (en) * 2018-11-28 2024-02-13 辽宁科技学院 Polymer mixing member having different adhesion and extruder comprising same

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