CN209530542U - A kind of processing unit of organic exhaust gas - Google Patents

A kind of processing unit of organic exhaust gas Download PDF

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Publication number
CN209530542U
CN209530542U CN201822226741.8U CN201822226741U CN209530542U CN 209530542 U CN209530542 U CN 209530542U CN 201822226741 U CN201822226741 U CN 201822226741U CN 209530542 U CN209530542 U CN 209530542U
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China
Prior art keywords
exhaust gas
microwave
shell
organic exhaust
processing unit
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Expired - Fee Related
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CN201822226741.8U
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Chinese (zh)
Inventor
阮世良
王颂
吴刚
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Shenzhen Gospower Environment Technology Co Ltd
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Shenzhen Gospower Environment Technology Co Ltd
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  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The utility model discloses a kind of processing units of organic exhaust gas.The microwave catalysis reaction unit of processing unit includes shell, microwave emitter and catalyst layer, and catalyst layer is arranged in the inner cavity of shell, the inner cavity of shell is separated out two resonant cavities, the air inlet and air outlet of shell are connected to a resonant cavity respectively;Oxidant adding set taps into port, the microwave entrance of microwave emitter body contact body;Catalyst layer includes plural mica splitting heating sheet and plural layer honeycomb-like cordierite base catalyst, and mica heating sheet and honeycomb-like cordierite base catalyst layer fold interlaced arrangement, and honeycomb-like cordierite base catalyst is heated to 350 DEG C or more by mica heating sheet;The organic exhaust gas enter in processing unit housing cavity, being uniformly mixed with oxidant carries out flameless combustion under the collective effect of microwave field and catalyst, with 200~350 DEG C of initiation temperature, is degraded into carbon dioxide and water.The processing unit integrated level height of the utility model, high treating effect, low energy consumption.

Description

A kind of processing unit of organic exhaust gas
[technical field]
The utility model relates to VOCs treatment more particularly to a kind of processing units of organic exhaust gas.
[background technique]
VOCs exhaust gas is a kind of volatile organic waste gas, is generally existing and complicated composition a kind of organic contamination in air Object, in China, VOCs volatile organic matter refers under room temperature that saturated vapor pressure is greater than under 70Pa, normal pressure boiling point at 260 DEG C or less Organic compound;Its main component is hydro carbons, sulfide, ammonia etc..
The active carbon adsorption of common processing method of organic exhaust gas, concentration adsorption-catalysis incineration method, directly catalysis burning Method, heat storage type combustion method, direct combustion method, torch method, microbial method, solvent absorption etc..Wherein, active carbon adsorption is more It is common.But existing active carbon adsorption there are activated carbon adsorption be saturated after, adsorption efficiency reduction can not finally adsorb and Even if there is the processing equipment adsorbed using double tower, the complicated problem of pipe network connection.
The utility model of Patent No. CN201620441152.X discloses the emission reduction group of microwave catalysis-biochemistry VOCs a kind of Equipment is closed, including the microwave catalysis reaction unit set gradually and biochemical reactor, the microwave catalysis reaction unit includes setting The catalyst layer passed through for exhaust gas in portion disposed within enters microwave for the microwave emitter of heating catalyst layer, for exhaust gas Catalysis air inlet inside catalyst reaction device and the catalytic exhaust gas mouth for exhaust gas outflow, the biochemical reactor is interior to be equipped with biology Purification mechanism, biochemical reactor are equipped with the biochemical exhaust of the biochemical air inlet connecting with catalytic exhaust gas mouth and supplied gas outflow Mouthful.The utility model by the preliminary purification of microwave catalysis reaction unit processing degradation VOCs, then by biochemical reactor purification at Harmful intermediate product that preliminary purification processing generates is managed, which takes up a large area, and device starting is slow, and energy consumption is high, Integrated level is low, proposes higher requirement to site area and installation maintenance.
[summary of the invention]
It is high, the lesser organic exhaust gas of occupied area that the technical problem to be solved by the present invention is to provide a kind of integrated levels Processing unit.
In order to solve the above-mentioned technical problem, the technical solution adopted in the utility model is a kind of processing dress of organic exhaust gas It sets, including microwave catalysis reaction unit, oxidant adding set and control circuit, microwave catalysis reaction unit includes shell, micro- Wave launcher and catalyst layer, shell include microwave entrance, air inlet and air outlet, and catalyst layer is arranged in the inner cavity of shell In, the inner cavity of shell is separated out two resonant cavities, two resonant cavities are arranged in both ends of the shell along main shaft, air inlet It is connected to respectively with a resonant cavity with gas outlet;The outlet of oxidant adding set taps into port, microwave emitter body contact body Microwave entrance;Catalyst layer includes plural mica splitting heating sheet and plural layer honeycomb-like cordierite base catalyst, mica heating sheet Interlaced arrangement is folded with honeycomb-like cordierite base catalyst layer;The level of mica heating sheet plate face and honeycomb-like cordierite base catalyst Parallel with the main shaft of shell, the honeycomb hole of honeycomb-like cordierite base catalyst is connected to two resonant cavities, and mica heating sheet is external Heating power supply.
The processing unit of above-described organic exhaust gas, the microwave emitter are two, and shell includes described in two Microwave entrance, two microwave entrances are arranged in the both ends of shell main shaft, are connected to respectively with the resonant cavity.
The processing unit of above-described organic exhaust gas, the axis of microwave emitter outlet and the main shaft oblique of shell.
The processing unit of above-described organic exhaust gas, the oxidant adding set are ozone generator.
The processing unit of above-described organic exhaust gas, including heat exchanger, the organic exhaust gas channel body contact of heat exchanger The air inlet of body, the gas outlet of the purification gas channel body contact body of heat exchanger.
The processing unit of above-described organic exhaust gas, inner walls include back-fire relief cotton layer, catalyst layer and inner walls Between gap by the layer filling of back-fire relief cotton.
The processing unit of above-described organic exhaust gas, the air inlet and air outlet respectively include preventing microwave leakage Filter plate, the aperture of filter plate is not more than 5mm.
The processing unit of above-described organic exhaust gas, control circuit include the temperature controlled catalyst layer temperature Monitoring and adjusting circuit.
The processing unit integrated level of the utility model is high, occupied area is smaller, high treating effect, low energy consumption.
[Detailed description of the invention]
Utility model will be further described in detail below with reference to the attached drawings and specific embodiments.
Fig. 1 is the structural schematic diagram of the processing unit of the utility model embodiment organic exhaust gas.
Fig. 2 is the perspective view of the utility model embodiment microwave catalysis reaction unit.
Fig. 3 is the top view of the utility model embodiment microwave catalysis reaction unit.
Fig. 4 is the cross-sectional view of the utility model embodiment microwave catalysis reaction unit.
[specific embodiment]
The processing unit of the utility model embodiment organic exhaust gas is as shown in Figures 1 to 4, including microwave catalysis reaction unit 10, heat exchanger 11, electrion ozone machine (ozone generator) 12 and control circuit.
Microwave catalysis reaction unit 10 includes shell 1, two microwave emitter 2 and catalyst layer.
Shell 1 is made of 304 stainless steel materials, including two microwave entrances 101, air inlet 102 and gas outlet 103, Air inlet 102 and gas outlet 103 are respectively provided with the filter plate for preventing microwave leakage, and the aperture of filter plate is not more than 5mm.
Control circuit includes the temperature monitoring controlled catalyst layer temperature and adjusting circuit, temperature monitoring and adjusting The temperature sensor of circuit is separately mounted at air inlet 102 and gas outlet 103,
The purification gas of the air inlet 102 of the 1101 body contact body 1 of organic exhaust gas channel of heat exchanger 11, heat exchanger 11 is logical The gas outlet 103 of 1102 body contact body 1 of road.Heat exchanger 11 is plank frame, and the exhaust gas after low-temperature burning is allowed to fill with processing is entered The organic exhaust gas heat exchange set, improves the thermal efficiency.
Catalyst layer is arranged in the inner cavity of shell 1, and the inner cavity of shell 1 is separated out two resonant cavity 1A and 1B, and two Resonant cavity 1A and 1B are arranged in shell 1 along the both ends of main shaft, and air inlet 102 is connected to resonant cavity 1A, gas outlet 103 with Resonant cavity 1B connection.
Two microwave entrances 101 are arranged in the both ends of 1 main shaft of shell, coaxial with 1 main shaft of shell, two microwave entrances 101 are connected to resonant cavity 1A or 1B respectively.
The outlet of electrion ozone machine 12 taps into port 102 by threeway, and the microwave of 2 body contact body 1 of microwave emitter enters Mouth 101.The main shaft oblique of axis and shell 1 that microwave emitter 2 exports, the angle of the two is 5 °, avoids enter into resonant cavity In microwave be directly reflected back microwave launcher 2, improve microwave absorption efficiency.
Catalyst layer includes multi-disc mica heating sheet 4 and multi-layer honeycomb shape cordierite-base catalyst 3, mica heating sheet 4 Thickness is no more than 2mm, and mica heating sheet 4 is laminated interval-staggered with honeycomb-like cordierite base catalyst 3.Mica heating sheet 4 Plate face and the level of honeycomb-like cordierite base catalyst 3 are parallel with the main shaft of shell 1, honeycomb-like cordierite base catalyst 3 Honeycomb hole is connected to two resonant cavities, the external heating power supply of mica heating sheet 4 and control circuit.
Mica heating sheet 4 is using the good insulation performance of mica sheet and its high temperature resistance, using mica sheet as skeleton and absolutely Edge layer, heating wire are pyrotoxin, and feature is can be rapidly heated, high temperature resistant, and good insulation preformance is at low cost.
Honeycomb-like cordierite base catalyst 3 is one kind using honeycomb-like cordierite as carrier, and Supported CuO/MnO2/RuO2 makees For the catalyst of principle active component, general honeycomb-like cordierite monolithic shape is square, size 100mm × 100mm × 100mm, the size that the utility model embodiment uses are 100mm × 100mm × 20mm, wherein cross sectional dimensions be 100mm × 20mm, the aperture of honeycomb hole are 1.5mm × 1.5mm.
1 inner wall of shell has magnesium/aluminosilicate back-fire relief cotton layer 4, and the gap between 1 inner wall of catalyst layer and shell is by back-fire relief cotton Layer 4 is filled.The back-fire relief cotton air permeability effect of compression is very poor, guarantees organic exhaust gas only from the honeycomb hole of honeycomb-like cordierite base catalyst Between pass through, prevent organic exhaust gas short-circuit between two resonant cavities.
The PLC of control circuit adjusts the whole heating power of catalyst layer by adjusting the working quantity of mica heating sheet 4, It maintains device operating temperature stable and reduces energy consumption.
Under fan action, organic exhaust gas enters microwave catalysis reaction unit shell through heat exchanger 11, from air inlet 102 In 1 inner cavity, ozone generating-device 12 generate ozone connect by heat exchanger 11 with microwave catalysis reaction unit 10 air hose it Between enter into microwave catalysis reaction unit shell 1 inner cavity in, enter 1 inner cavity of microwave catalysis reaction unit shell process It is both middle to be uniformly mixed, 350 DEG C of temperature with it is microwave-assisted under the conditions of, organic exhaust gas and ozone/air are green by honeycomb violet It is chemically reacted during stone loaded catalyst 3, organic exhaust gas is degraded to carbon dioxide and water.
The ventilatory capacity of ozone is adjusted according to actual measurement organic exhaust gas concentration calculation, the quartz heating in microwave catalysis reaction unit The power of thin slice 4 is adjusted according to the reading of the temperature sensor of inlet and outlet and is controlled, since quartz heating thin slice 4 is very thin, honeycomb violet Green stone loaded catalyst 3 is not also thick, adjusts the power of quartz heating thin slice 4, the temperature of honeycomb cordierite loaded catalyst 3 It is swift in response, to guarantee the higher degradation efficiency of organic exhaust gas, general control microwave catalysis reaction unit gas outlet gas temperature Higher than 350 DEG C, in equipment running process, organic exhaust gas+ozone/air, which enters in Microwave-assisted firing catalysis 3, occurs heat release Reaction, and the heat of honeycomb cordierite loaded catalyst 3 is absorbed, the mixed gas temperature after reacting increases, from heat exchange After the heat source opening of device 11 enters, the organic exhaust gas of entrance is preheated in heat exchanger 11, and itself cools down and is discharged.
Compared with traditional heating method, microwave has the characteristics that selectivity heats.Utilize different substance wave-sucking performances Difference, when microwave radiation focuses on catalyst bed surface, due to microwave energy and catalyst (such as national standard method) surface gold Belong to the strong interaction of point, microwave energy is rapidly transformed into thermal energy, to make these surface points selectively by very It is heated to very high temperature fastly.The temperature of these " hot spots " is higher by than the mean temperature of catalyst very much, when reactant molecule and this It can be chemically reacted when a little activity point contacts.In fact due to itself of organic exhaust gas and air/ozone mixed gas temperature It spends not high, mixed gas and surface point time of contact is short and the reasons such as catalyst bulk temperature is not high, easily generation are incomplete Oxidation reaction generates the intermediate products such as aldehyde, ketone, acid and ester during the VOCs that degrades, needs further to be completely oxidized to CO2With H2O。
Low-temperature catalytic burning is typical gas-solid catalysis, and the activation energy that it is reacted by catalyst degradation makes It carries out flameless combustion at 200~350 DEG C of lower initiation temperature, and organic substance oxidation occurs in solid catalyst surface, CO2 and H2O are generated simultaneously, and releases a large amount of heat, because its oxidizing reaction temperature is low, also greatly inhibits nitrogenous organic waste Gas forms high-temperature oxydation and forms NOx.
Subtract with microwave catalysis-biochemistry VOCs of the prior art, the utility model of Patent No. CN201620441152.X It arranges unlike unit equipment, microwave is only used only as unique heat source in microwave catalysis device in the utility model patent, due to Above-mentioned reason, the reaction of Yi Fasheng incomplete oxidation, therefore the patent needs mating biochemical treatment apparatus for handling incomplete oxidation Product.
The utility model above embodiments quickly heat honeycomb-like cordierite base catalyst using mica heating plate, with microwave As supplementary means, using ozone as oxidant, by organic exhaust gas, quick catalysis burning is dropped under the conditions of low temperature (250-350 DEG C) Solution is carbon dioxide and water, and feature is can be rapidly by small-bore honeycomb-like cordierite base catalyzer temperature-elevating to 350 DEG C or more, instead Gas after answering enters heat-exchanger rig to charge heating, solves the self-temperature of organic exhaust gas Yu air/ozone mixed gas Not high, mixed gas and surface point time of contact is short and the poroid cordierite-base catalyst bulk temperature of honeycomb is not high asks Topic.System adjusts the power of heatable catalyst, the stabilization of whole system is kept effectively to run by the temperature of monitoring disengaging gas, Equipment volume is small, treatment process effect is good, low energy consumption, system is intelligently adjustable.

Claims (8)

1. a kind of processing unit of organic exhaust gas, including microwave catalysis reaction unit, oxidant adding set and control circuit, micro- Wave catalyst reaction device includes shell, microwave emitter and catalyst layer, and shell includes microwave entrance, air inlet and air outlet, Catalyst layer is arranged in the inner cavity of shell, the inner cavity of shell is separated out two resonant cavities, two resonant cavities are arranged in Shell is connected to a resonant cavity respectively along the both ends of main shaft, air inlet and air outlet;The outlet of oxidant adding set connects Air inlet, the microwave entrance of microwave emitter body contact body;It is characterized in that, catalyst layer is including plural mica splitting heating sheet and again Several layers of honeycomb-like cordierite base catalyst, mica heating sheet and honeycomb-like cordierite base catalyst layer fold interlaced arrangement;Mica adds Backing plate face and the level of honeycomb-like cordierite base catalyst are parallel with the main shaft of shell, honeycomb-like cordierite base catalyst Honeycomb hole is connected to two resonant cavities, the external heating power supply of mica heating sheet.
2. the processing unit of organic exhaust gas according to claim 1, which is characterized in that the microwave emitter is two A, shell includes microwave entrance described in two, and two microwave entrances are arranged in the both ends of shell main shaft, respectively with it is described Resonant cavity connection.
3. the processing unit of organic exhaust gas according to claim 1, which is characterized in that microwave emitter outlet axis with The main shaft oblique of shell.
4. the processing unit of organic exhaust gas according to claim 1, which is characterized in that the oxidant adding set is Ozone generator.
5. the processing unit of organic exhaust gas according to claim 1, which is characterized in that including heat exchanger, heat exchanger Organic exhaust gas channel body contact body air inlet, the gas outlet of the purification gas channel body contact body of heat exchanger.
6. the processing unit of organic exhaust gas according to claim 1, which is characterized in that inner walls include back-fire relief cotton layer, Gap between catalyst layer and inner walls is by back-fire relief cotton layer filling.
7. the processing unit of organic exhaust gas according to claim 1, which is characterized in that the air inlet and air outlet point The filter plate of microwave leakage Bao Kuo not be prevented, the aperture of filter plate is not more than 5mm.
8. the processing unit of organic exhaust gas according to claim 1, which is characterized in that control circuit includes to catalyst layer The temperature monitoring and adjust circuit that temperature is controlled.
CN201822226741.8U 2018-12-26 2018-12-26 A kind of processing unit of organic exhaust gas Expired - Fee Related CN209530542U (en)

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Application Number Priority Date Filing Date Title
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111408264A (en) * 2020-03-31 2020-07-14 山东产研绿洲环境产业技术研究院有限公司 Purification system and purification method for organic waste gas
CN113209918A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209920A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209919A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209921A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209922A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113522018A (en) * 2021-07-20 2021-10-22 四川大学 A microwave-assisted catalytic oxidation device for gas degradation of VOCs
CN114636161A (en) * 2022-03-24 2022-06-17 山东保蓝环保工程有限公司 VOCS waste gas microwave decomposition furnace

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113209918A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209920A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209919A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209921A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN113209922A (en) * 2020-01-21 2021-08-06 中国石油化工股份有限公司 Microwave coupling catalytic reactor and VOCs treatment facility
CN111408264A (en) * 2020-03-31 2020-07-14 山东产研绿洲环境产业技术研究院有限公司 Purification system and purification method for organic waste gas
CN113522018A (en) * 2021-07-20 2021-10-22 四川大学 A microwave-assisted catalytic oxidation device for gas degradation of VOCs
CN114636161A (en) * 2022-03-24 2022-06-17 山东保蓝环保工程有限公司 VOCS waste gas microwave decomposition furnace

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20191025

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