CN208553617U - A pull-type VOCs adsorption and desorption fixed bed device - Google Patents
A pull-type VOCs adsorption and desorption fixed bed device Download PDFInfo
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- 238000002336 sorption--desorption measurement Methods 0.000 claims abstract 12
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Abstract
Description
技术领域technical field
本实用新型属于废气处理技术领域,具体涉及一种抽拉式VOCs吸附脱附固定床装置。The utility model belongs to the technical field of waste gas treatment, in particular to a drawing-type VOCs adsorption and desorption fixed bed device.
背景技术Background technique
吸附是处理含VOCs废气的主要方法之一,其设备主要为固定床吸附和转轮吸附浓缩装置。固定床装置设备简单可靠,价格低廉,处理废气浓度范围较宽,吸附剂更换方便快捷。转轮吸附浓缩装置由于存在转动部件以及密封性要求,其制造工艺复杂,设备成本高昂,设备可靠性低于固定床装置,吸附剂吸附量要求较高,处理废气浓度不可过高。因此,固定床目前依旧是应用最广泛的吸附装置。但目前,固定床装置也存在以下一系列问题:Adsorption is one of the main methods for treating waste gas containing VOCs, and its equipment is mainly fixed bed adsorption and runner adsorption concentration device. The fixed bed device is simple and reliable, with low price, wide range of waste gas concentration, and convenient and quick replacement of adsorbent. Due to the presence of rotating parts and tightness requirements, the runner adsorption and concentration device has a complex manufacturing process, high equipment cost, lower equipment reliability than fixed bed devices, higher requirements for adsorbent adsorption capacity, and the concentration of treated waste gas should not be too high. Therefore, the fixed bed is still the most widely used adsorption device. But at present, the fixed bed device also has the following series of problems:
(1)更换吸附剂时间过长,影响企业正常生产;(1) The time for replacing the adsorbent is too long, which affects the normal production of the enterprise;
(2)拆装时现场VOCs浓度较高,危害操作人员身体健康;(2) The concentration of on-site VOCs is high during disassembly and assembly, which endangers the health of operators;
(3)有时现场无法实现原位再生,需有资质的厂家提供脱附服务。(3) Sometimes in-situ regeneration cannot be achieved on site, and qualified manufacturers are required to provide desorption services.
针对以上问题,需要开发新型吸附固定床装置,以满足企业高效、安全和便捷的生产需求。In view of the above problems, it is necessary to develop a new type of adsorption fixed bed device to meet the efficient, safe and convenient production needs of enterprises.
实用新型内容Utility model content
发明目的:针对现有技术存在的不足,本实用新型的目的是提供一种易于现场拆装、更换吸附剂时VOCs泄漏少、脱附模式灵活的模块化抽拉式VOCs吸附脱附固定床装置。Purpose of the invention: In view of the deficiencies of the prior art, the purpose of the present utility model is to provide a modular pull-type VOCs adsorption and desorption fixed bed device that is easy to disassemble and assemble on site, has less VOCs leakage when replacing the adsorbent, and has a flexible desorption mode. .
技术方案:为了实现上述发明目的,本实用新型采用的技术方案如下:Technical scheme: In order to realize the above-mentioned purpose of the invention, the technical scheme adopted by the present utility model is as follows:
一种抽拉式VOCs吸附脱附固定床装置,包括固定床壳体单元,在所述固定床壳体单元内设置有可抽拉的床屉,在所述床屉内填充有吸附剂,在固定床壳体单元两侧设置有盖板。A pull-out type VOCs adsorption and desorption fixed bed device, comprising a fixed bed shell unit, a drawable bed drawer is arranged in the fixed bed shell unit, the bed drawer is filled with an adsorbent, and the Cover plates are arranged on both sides of the fixed bed shell unit.
进一步地,在所述盖板与固定床壳体单元之间设置有密封垫圈,所述盖板与固定床壳体单元通过螺栓紧固件连接。Further, a sealing gasket is provided between the cover plate and the fixed bed housing unit, and the cover plate and the fixed bed housing unit are connected by bolt fasteners.
进一步地,所述固定床壳体单元前端与气体扩散器连接,后端与集气罩连接,所述气体扩散器上设置有进气口,所述集气罩上设置有出气口。Further, the front end of the fixed bed shell unit is connected with a gas diffuser, and the rear end is connected with a gas collection cover, the gas diffuser is provided with an air inlet, and the gas collection cover is provided with an air outlet.
进一步地,在所述床屉上设置有封闭吸附剂裸露面的抽板,所述床屉推入固定床壳体单元前,将抽板抽出。Further, a drawer for closing the exposed surface of the adsorbent is provided on the bed drawer, and the drawer is pulled out before the bed drawer is pushed into the fixed bed shell unit.
进一步地,所述吸附剂为方形蜂窝状吸附剂或者层状吸附剂,所述蜂窝状吸附剂通道方向与废气流动方向一致,所述层状吸附剂水平或者垂直堆放。Further, the adsorbent is a square honeycomb adsorbent or a layered adsorbent, the channel direction of the honeycomb adsorbent is consistent with the flow direction of the exhaust gas, and the layered adsorbent is stacked horizontally or vertically.
进一步地,所述床屉的高度小于方形蜂窝状吸附剂的最大堆放高度或层状吸附剂的最大水平堆放高度。Further, the height of the bed drawer is smaller than the maximum stacking height of the square honeycomb adsorbent or the maximum horizontal stacking height of the layered adsorbent.
进一步地,在固定床壳体单元底部内侧和床屉底部外侧设置有配合使用的导轨。Further, matching guide rails are provided on the inner side of the bottom of the fixed bed shell unit and the outer side of the bottom of the bed drawer.
进一步地,所述导轨的形状为长方形、梯形、三角形或者圆弧形。Further, the shape of the guide rail is a rectangle, a trapezoid, a triangle or a circular arc.
进一步地,所述床屉上位于盖板一面设置有若干拉环。Further, a plurality of pull rings are arranged on the bed drawer on one side of the cover plate.
进一步地,所述固定床壳体单元设置有竖直排列的多层,每层设置有至少2个水平排列的固定床壳体单元。Further, the fixed bed shell unit is provided with multiple layers arranged vertically, and each layer is provided with at least two fixed bed shell units arranged horizontally.
有益效果:与现有技术相比,本实用新型具有以下优点:Beneficial effect: Compared with the prior art, the utility model has the following advantages:
本实用新型中的抽拉式VOCs吸附脱附固定床装置将固定床划分为若干模块,每个固定床单元中的床屉可直接抽出,并配以抽板、导轨、拉环等辅助部件。该装置易于拆装,不用现场更换吸附剂,现场操作时间短,便于运输、搬运和储存,运输搬运和储存过程中VOCs无组织排放少,可设计成移动式吸附装置用于间歇性处理废气或处理废气中VOCs突然升高等突发状况。该装置的VOCs脱附可根据实际情况选择现场热空气脱附或更换吸附剂后送至专门的吸附剂处理厂家再生。本实用新型拆卸简单方便,便于运输、安装与更换,正常运行时更换吸附剂无VOCs泄漏,且可设计灵活的吸附脱附方案。The pull-out type VOCs adsorption and desorption fixed bed device in the utility model divides the fixed bed into several modules, the bed drawer in each fixed bed unit can be directly drawn out, and is equipped with auxiliary parts such as a drawer, a guide rail, and a pull ring. The device is easy to disassemble and assemble, no need to replace the adsorbent on site, short on-site operation time, convenient transportation, handling and storage, less fugitive emission of VOCs during transportation, handling and storage, and can be designed as a mobile adsorption device for intermittent treatment of waste gas or Handle emergencies such as sudden increase of VOCs in exhaust gas. The VOCs desorption of the device can be selected according to the actual situation by hot air desorption on site or by replacing the adsorbent and then sending it to a special adsorbent treatment factory for regeneration. The utility model has the advantages of simple and convenient disassembly, convenient transportation, installation and replacement, no VOCs leakage when the adsorbent is replaced during normal operation, and a flexible adsorption and desorption scheme can be designed.
附图说明Description of drawings
图1是本实用新型装置安装完成立体结构示意图。FIG. 1 is a schematic diagram of the three-dimensional structure of the device of the present invention after installation.
图2是本实用新型装置拆装立体结构示意图。Figure 2 is a schematic diagram of the three-dimensional structure of the disassembly and assembly of the device of the present invention.
图3是本实用新型装置安装完成侧视方向截面示意图。FIG. 3 is a schematic cross-sectional view of the device of the present invention in a side view direction after the installation is completed.
图4是本实用新型装置安装完成主视方向截面示意图。FIG. 4 is a schematic cross-sectional view from the front view direction after the installation of the device of the present invention is completed.
图5是床屉拆装立体示意图。Figure 5 is a perspective view of the disassembly and assembly of the bed drawer.
图6是床屉底部导轨示意图。Figure 6 is a schematic diagram of the bottom guide rail of the bed drawer.
图7是床屉结构示意图。Figure 7 is a schematic diagram of the structure of the bed drawer.
图8是盖板示意图。Figure 8 is a schematic diagram of a cover plate.
具体实施方式Detailed ways
下面结合附图进一步阐明本实用新型。The present utility model is further explained below in conjunction with the accompanying drawings.
如图1所示,本申请的抽拉式VOCs吸附脱附固定床装置,主要包括有1、废气及热空气进口1、废气及热空气出口2、气体扩散器3、集气罩4、固定床壳体单元5、盖板6、床屉7、吸附剂8、抽板9、拉环10、导轨11、固定床壳体连接件12、螺栓紧固件13、床屉折边14、抽板挡片15、抽板滑槽16、盖板螺孔17、密封垫圈18,一个固定床壳体单元5、一个床屉7和一个盖板6构成一个固定床单元,固定床壳体单元5设置有竖直排列的多层每层设置有至少2个水平排列的固定床壳体单元5,上下两层固定床壳体单元5之间通过固定床壳体连接件12连接。As shown in Figure 1, the pull-type VOCs adsorption and desorption fixed bed device of the present application mainly includes 1, exhaust gas and hot air inlet 1, exhaust gas and hot air outlet 2, gas diffuser 3, gas collecting cover 4, fixed Bed shell unit 5, cover plate 6, bed drawer 7, adsorbent 8, drawer 9, pull ring 10, guide rail 11, fixed bed shell connector 12, bolt fastener 13, bed drawer fold 14, drawer The plate baffle 15, the drawing plate chute 16, the cover plate screw hole 17, the sealing gasket 18, a fixed bed shell unit 5, a bed drawer 7 and a cover plate 6 constitute a fixed bed unit, and the fixed bed shell unit 5 At least two fixed bed shell units 5 arranged horizontally are arranged on each layer, and the upper and lower layers of the fixed bed shell units 5 are connected by a fixed bed shell connecting piece 12 .
固定床壳体单元5和床屉7均为长方体结构,固定床壳体单元5前端与气体扩散器3连接,后端与集气罩4连接,气体扩散器3上设置有进气口1,集气罩4上设置有出气口2。在固定床壳体单元5内设置有可抽拉的床屉7,在床屉7内填充有吸附剂8,在固定床壳体单元5沿气体流动方向的两侧设置有可拆卸的盖板6。The fixed bed shell unit 5 and the bed drawer 7 are both cuboid structures. The front end of the fixed bed shell unit 5 is connected with the gas diffuser 3, and the rear end is connected with the gas collecting cover 4. The gas diffuser 3 is provided with an air inlet 1, An air outlet 2 is provided on the air collecting hood 4 . A drawable bed drawer 7 is arranged in the fixed bed housing unit 5, the bed drawer 7 is filled with adsorbent 8, and detachable cover plates are arranged on both sides of the fixed bed housing unit 5 along the gas flow direction 6.
在盖板6与固定床壳体单元5之间设置有密封垫圈18,盖板6与固定床壳体单元5通过螺栓紧固件13连接。固定床壳体单元5中放置床屉7时,使用盖板6封闭,两者之间设有密封垫圈18保证固定床装置的气密性,固定床壳体单元5内壁可根据实际使用情况考虑内壁是否增设隔热衬里。A sealing gasket 18 is provided between the cover plate 6 and the fixed bed housing unit 5 , and the cover plate 6 and the fixed bed housing unit 5 are connected by bolt fasteners 13 . When the bed drawer 7 is placed in the fixed bed shell unit 5, the cover plate 6 is used to close it, and a sealing gasket 18 is provided between the two to ensure the air tightness of the fixed bed device. The inner wall of the fixed bed shell unit 5 can be considered according to the actual use situation. Whether to add thermal insulation lining to the inner wall.
在床屉7上与气体扩散器3和集气罩4相邻的面上分别设置有封闭吸附剂8裸露面的抽板9,抽板9与床屉7间可通过折边滑槽与卡扣的方法连接,在抽板9上下两边设置有抽板滑槽16,在床屉7与气体扩散器3和集气罩4相邻的面上下两侧边上设置有床屉折边14,抽板9通过抽板滑槽16与床屉折边14在床屉7上滑入或者抽出,以封闭和漏出床屉7内的吸附剂8的裸露面。床屉折边滑槽的末端设有若干抽板挡片15,对抽板9起限位作用。当床屉7被抽出后,用两个特制的抽板9分别将床屉7的两个吸附剂8裸露面封闭,在储存、运输途中床屉均处于封闭状态,防止在运输、搬运和储存过程中VOCs和吸附剂的泄漏;在床屉7推入固定床壳体单元5之前,将抽板9预先抽出,露出吸附剂床层。On the side of the bed drawer 7 adjacent to the gas diffuser 3 and the gas collecting hood 4 are respectively provided with a drawer 9 for closing the exposed surface of the adsorbent 8, and the drawer 9 and the bed drawer 7 can pass through the folding chute and the card The method of buckle is connected, and the upper and lower sides of the drawer 9 are provided with drawer chute 16, and the bed drawer 7 is provided on the upper and lower sides adjacent to the gas diffuser 3 and the gas collecting hood 4. The drawer 9 is slid in or pulled out on the bed drawer 7 through the drawer sliding groove 16 and the bed drawer flange 14 , so as to seal and leak out the exposed surface of the adsorbent 8 in the bed drawer 7 . The end of the folding chute of the bed drawer is provided with a number of drawer plate blocking pieces 15 , which limit the position of the drawer plate 9 . When the bed drawer 7 is pulled out, the exposed surfaces of the two adsorbents 8 of the bed drawer 7 are closed by two special drawers 9 respectively. During storage and transportation, the bed drawer is in a closed state, preventing the Leakage of VOCs and adsorbents during the process; before the bed drawer 7 is pushed into the fixed bed housing unit 5, the drawer 9 is drawn out in advance to expose the adsorbent bed.
吸附剂8为方形蜂窝状吸附剂或者层状吸附剂,蜂窝状吸附剂通道方向与废气流动方向一致,层状吸附剂水平或者垂直堆放。床屉7的高度小于方形蜂窝状吸附剂的最大堆放高度或层状吸附剂的最大水平堆放高度。The adsorbent 8 is a square honeycomb adsorbent or a layered adsorbent, the channel direction of the honeycomb adsorbent is consistent with the flow direction of the exhaust gas, and the layered adsorbent is stacked horizontally or vertically. The height of the bed drawer 7 is smaller than the maximum stacking height of the square honeycomb adsorbent or the maximum horizontal stacking height of the layered adsorbent.
为了便于将床屉7抽出和推入,床屉7上位于盖板6一面设置有1~4个拉环10,拉环10形状包括但不限于圆弧形和长方形。另外,在固定床壳体单元5底部内侧和床屉7底部外侧分别设置有1~6个配合使用的导轨11,两导轨11形状互补,即当固定床壳体单元5底部内侧为凹槽状时,床屉7底部外侧为突出状,当固定床壳体单元5底部内侧为突出状时,床屉7底部外侧为凹槽状;导轨形状包括但不限于长方形、梯形、三角形以及圆弧形。In order to facilitate pulling out and pushing in the bed drawer 7, one to four pull rings 10 are provided on the bed drawer 7 on one side of the cover plate 6, and the shapes of the pull rings 10 include but are not limited to arc and rectangle. In addition, 1 to 6 guide rails 11 are provided on the inner side of the bottom of the fixed bed shell unit 5 and the outer side of the bottom of the bed drawer 7 respectively. The shapes of the two guide rails 11 are complementary. When the outer side of the bottom of the bed drawer 7 is a protruding shape, when the inner side of the bottom of the fixed bed shell unit 5 is a protrusion shape, the outer side of the bottom of the bed drawer 7 is a groove shape; the shapes of the guide rails include but are not limited to rectangles, trapezoids, triangles and arcs. .
本实用新型中所述VOCs一般来源于石化、制药、印刷、聚合物加工、汽车喷漆、精细化工、芯片制造等行业产生的低浓度有机废气,总VOCs浓度为50~2000mg/Nm3,风量为1,000~200,000Nm3/h,产生的高浓废气VOCs浓度为未处理废气的5~50倍。本实施例中进气口1、排气口2、吸附剂8以及固定床壳体单元5的截面均为矩形,本实施例中进气口1和排气口2截面的长和宽均分别为200~800mm,吸附剂固定床单元5截面的长和宽均为400~1500mm;固定床壳体单元5的长度为400~2000mm。废气通过固定床壳体单元5的流速控制在0.5~3m/s范围内,床层的压降小于2.5kPa,吸附温度为0~40℃,脱附温度为120~180℃。The VOCs mentioned in the utility model generally come from low-concentration organic waste gas produced by petrochemical, pharmaceutical, printing, polymer processing, automotive painting, fine chemical, chip manufacturing and other industries. The total VOCs concentration is 50-2000 mg/Nm 3 1,000~200,000Nm 3 /h, the concentration of VOCs in the generated high-concentration exhaust gas is 5-50 times that of the untreated exhaust gas. In this embodiment, the cross-sections of the air inlet 1, the air outlet 2, the adsorbent 8 and the fixed bed shell unit 5 are all rectangular, and the length and width of the cross-sections of the air inlet 1 and the air outlet 2 in this embodiment are respectively The length and width of the section of the adsorbent fixed bed unit 5 are both 400 to 1500 mm; the length of the fixed bed shell unit 5 is 400 to 2000 mm. The flow rate of the exhaust gas through the fixed bed shell unit 5 is controlled within the range of 0.5-3m/s, the pressure drop of the bed is less than 2.5kPa, the adsorption temperature is 0-40°C, and the desorption temperature is 120-180°C.
下述实施案例是对本实用新型的进一步详细应用说明,其参数只是对某一工况下的说明,并非对本实用的适用范围进行限定。The following examples are further detailed application descriptions of the present invention, and its parameters are only descriptions under a certain working condition, and do not limit the scope of application of the present invention.
实施案例1:某医药中间体生产企业有机废气的吸附净化Implementation Case 1: Adsorption and purification of organic waste gas in a pharmaceutical intermediate production enterprise
本实施案例中,某医药中间体生产企业产生的废气来自反应釜出料时的排气、反应釜进料前的置换气及有机溶剂自然挥发产生的废气,其物性参数和组成如表1所示。In this example, the waste gas generated by a pharmaceutical intermediate manufacturer comes from the exhaust gas when the reactor is discharged, the replacement gas before the reactor is fed, and the waste gas generated by the natural volatilization of organic solvents. Its physical parameters and compositions are shown in Table 1. Show.
表1某医药中间体生产企业废气物性及组成Table 1 Physical properties and composition of waste gas from a pharmaceutical intermediate production enterprise
本实施案例中采用6个固定床单元,1组吸附脱附固定床装置,分为三层,每个单元进气口和排气口截面的长和宽均为350mm,吸附剂固定床单元截面的长和宽均为700mm;吸附剂固定床单元的长度为1500mm。吸附剂采用蜂窝状沸石复合高效吸附剂,孔隙率为0.67。装置的操作参数和处理后废气VOCs组成见表2。In this example, 6 fixed bed units are used, and one set of adsorption and desorption fixed bed devices is divided into three layers. The length and width of the air inlet and exhaust port of each unit are 350mm, and the cross section of the adsorbent fixed bed unit is 350mm. The length and width are both 700mm; the length of the adsorbent fixed bed unit is 1500mm. The adsorbent adopts honeycomb zeolite composite high-efficiency adsorbent with a porosity of 0.67. The operating parameters of the device and the composition of VOCs in the exhaust gas after treatment are shown in Table 2.
表2用于实施例1的装置的操作参数及其处理后废气VOCs组成Table 2 The operating parameters of the device used in Example 1 and the composition of VOCs in the exhaust gas after treatment
实施案例2:某汽车制造企业喷漆有机废气的吸附净化Implementation case 2: Adsorption and purification of organic waste gas from paint spraying in an automobile manufacturing enterprise
本实施案例中,某汽车制造企业涂装工序产生的废气物性及组成见表3。In this example, the physical properties and composition of the exhaust gas produced by the coating process of an automobile manufacturing enterprise are shown in Table 3.
表3某汽车制造企业涂装工序废气物性及组成Table 3 The physical properties and composition of the exhaust gas from the coating process of an automobile manufacturing enterprise
本实施例中采用32个固定床单元,分为4组,每组4层,每个单元进气口和排气口截面的长和宽均为500mm,吸附剂固定床单元截面的长和宽均为1000mm;吸附剂固定床单元的长度为2000mm。吸附剂为正方体形状的蜂窝型活性炭吸附剂,边长为200mm,孔隙率为0.65。装置的操作参数和处理后废气VOCs组成见表4。In this example, 32 fixed bed units are used, which are divided into 4 groups with 4 layers in each group. The length and width of the cross section of the air inlet and exhaust port of each unit are 500 mm, and the length and width of the cross section of the adsorbent fixed bed unit are 500 mm. Both are 1000mm; the length of the adsorbent fixed bed unit is 2000mm. The adsorbent is a honeycomb activated carbon adsorbent in the shape of a cube, with a side length of 200 mm and a porosity of 0.65. The operating parameters of the device and the VOCs composition of the exhaust gas after treatment are shown in Table 4.
表4用于实施例2装置的操作参数及其处理后废气VOCs组成Table 4 is used for the operating parameters of the device of Example 2 and the composition of VOCs in the exhaust gas after treatment
以上所述仅是本实用新型的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本实用新型原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本实用新型的保护范围。The above are only the preferred embodiments of the present invention. It should be pointed out that for those skilled in the art, without departing from the principles of the present invention, several improvements and modifications can be made. These improvements and Retouching should also be regarded as the protection scope of the present invention.
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| CN112075568A (en) * | 2019-06-13 | 2020-12-15 | 杨浅舒 | Ozone disinfection device |
| CN112717622A (en) * | 2020-12-28 | 2021-04-30 | 浙江建设职业技术学院 | Interior decoration toxic gas adsorption device convenient to change inner core |
| CN113101781A (en) * | 2021-05-20 | 2021-07-13 | 萍乡市华顺环保化工填料有限公司 | Novel molecular sieve drying device |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112075568A (en) * | 2019-06-13 | 2020-12-15 | 杨浅舒 | Ozone disinfection device |
| CN112717622A (en) * | 2020-12-28 | 2021-04-30 | 浙江建设职业技术学院 | Interior decoration toxic gas adsorption device convenient to change inner core |
| CN113101781A (en) * | 2021-05-20 | 2021-07-13 | 萍乡市华顺环保化工填料有限公司 | Novel molecular sieve drying device |
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