CN207980838U - A kind of reciprocating two-region spray absorber - Google Patents

A kind of reciprocating two-region spray absorber Download PDF

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CN207980838U
CN207980838U CN201721891040.5U CN201721891040U CN207980838U CN 207980838 U CN207980838 U CN 207980838U CN 201721891040 U CN201721891040 U CN 201721891040U CN 207980838 U CN207980838 U CN 207980838U
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uptake
uptake zones
zones
area
slurry
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赵博
周伟
孙莹
李天才
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Zhejiang Tuna Environmental Science and Technology Co Ltd
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Abstract

The utility model is related to desulfurization and dedusting fields, refer in particular to a kind of reciprocating two-region spray absorber, including cylinder, the uptake zones L and the uptake zones H are divided by partition board in the cylinder, it is respectively arranged with several spraying layers in the uptake zones L and the uptake zones H, L stock tanks area and H stock tanks area are corresponded to respectively below the uptake zones L and the uptake zones H, and the spraying layer of the uptake zones L extracts slurries by circulating pump from L stock tanks area, and the spraying layer of the uptake zones H extracts slurries by circulating pump from H stock tanks area.Under the premise of meeting CaSO3 oxidations and gypsum crystallization, SO2 removal efficiencies are increased substantially.

Description

一种往复式双区喷淋吸收塔A reciprocating double-zone spray absorption tower

技术领域technical field

本实用新型涉及脱硫除尘领域,特指一种往复式双区喷淋吸收塔。The utility model relates to the field of desulfurization and dust removal, in particular to a reciprocating double-zone spray absorption tower.

背景技术Background technique

目前,在燃煤烟气湿法脱硫工艺中多采用石灰石-石膏空塔喷淋技术或双塔(单塔)双循环技术。喷淋空塔技术由于受制于直接产物CaSO3氧化及石膏结晶所要求的酸性环境,其浆池PH值一般需控制在6以下,因此提高脱硫效率主要依靠增加液气比(L/G)即增加喷淋层的数量来实现;双塔(单塔)双循环技术依靠两个吸收塔串联(或设独立塔外浆池)实现浆液PH分区,分别满足SO2吸收的碱性浆液和氧化结晶反应的酸性浆液要求。增加喷淋层数量相应的增加了浆液循环泵数量及吸收塔高度;双塔串联不仅增加了吸收塔及配套设备数量,同时也使得系统占地面积大幅度增加,均会导致造价及运行费用的提高。因此,本发明人对此做进一步研究,研发出一种往复式双区喷淋吸收塔,本案由此产生。At present, limestone-gypsum empty-tower spray technology or double-tower (single-tower) double-cycle technology is mostly used in the coal-fired flue gas wet desulfurization process. Due to the restriction of the direct product CaSO3 oxidation and the acidic environment required by gypsum crystallization, the spray empty tower technology generally needs to control the pH value of the slurry tank below 6, so the improvement of desulfurization efficiency mainly depends on increasing the liquid-gas ratio (L/G), that is, increasing The number of spray layers can be realized; the double-tower (single-tower) double-circulation technology relies on two absorption towers connected in series (or an independent slurry tank outside the tower) to realize the PH partition of the slurry, which satisfies the alkaline slurry and oxidation crystallization reaction for SO2 absorption respectively. acid slurry requirements. Increasing the number of spraying layers increases the number of slurry circulating pumps and the height of the absorption tower; the series connection of two towers not only increases the number of absorption towers and supporting equipment, but also greatly increases the area occupied by the system, which will lead to a decrease in construction and operating costs. improve. Therefore, the inventor has made further research on this, and developed a reciprocating double-zone spray absorption tower, and this case results from this.

实用新型内容Utility model content

本实用新型的目的在于提供一种往复式双区喷淋吸收塔,在满足CaSO3氧化及石膏结晶的前提下,大幅度提高SO2脱除效率。The purpose of the utility model is to provide a reciprocating double-zone spray absorption tower, which greatly improves the SO2 removal efficiency under the premise of satisfying CaSO3 oxidation and gypsum crystallization.

为了实现上述目的,本实用新型的技术方案如下:In order to achieve the above object, the technical scheme of the utility model is as follows:

一种往复式双区喷淋吸收塔,包括筒体,所述筒体内通过吸收区隔板分为L吸收区和H吸收区,所述L吸收区和H吸收区中分别设置有若干喷淋层,所述L吸收区和H吸收区下方分别对应L浆池区和H浆池区,所述L吸收区的喷淋层通过循环泵从L浆池区中抽取浆液,所述H吸收区的喷淋层通过循环泵从H浆池区中抽取浆液。A reciprocating double-zone spray absorption tower, including a cylinder body, the cylinder body is divided into an L absorption zone and an H absorption zone through an absorption zone partition, and a number of sprays are respectively arranged in the L absorption zone and the H absorption zone. layer, the L absorption zone and the H absorption zone correspond to the L slurry tank area and the H slurry tank area respectively, the spray layer of the L absorption zone draws slurry from the L slurry tank area through a circulating pump, and the H absorption zone The spray layer draws the slurry from the H slurry tank area through the circulation pump.

进一步,所述L吸收区上部设置有入口烟道,H吸收区上方设置有出口烟道。Further, the upper part of the L absorption zone is provided with an inlet flue, and the upper part of the H absorption zone is provided with an outlet flue.

进一步,所述出口烟道与H吸收区之间设置有烟气导流板,所述烟气导流板上设置有除雾器。Further, a smoke deflector is arranged between the outlet flue and the H absorption area, and a mist eliminator is arranged on the smoke deflector.

进一步,所述L浆池区和H浆池区底部设置有脉冲悬浮装置和氧化空气管网。Further, pulse suspension devices and oxidation air pipe networks are provided at the bottom of the L slurry pool area and the H slurry pool area.

进一步,所述L吸收区中的喷淋层喷淋方向向上,H吸收区中的喷淋层喷淋方向向下。Further, the spraying direction of the spraying layer in the L absorption zone is upward, and the spraying direction of the spraying layer in the H absorption zone is downward.

采用上述方案后,本实用新型与现有技术相比,具有以下优点:After adopting the above scheme, the utility model has the following advantages compared with the prior art:

在一个吸收塔内实现烟气、浆液双分区,在满足CaSO3氧化及石膏结晶的前提下,大幅度提高SO2脱除效率。The flue gas and slurry dual partitions are realized in one absorption tower, and the SO2 removal efficiency is greatly improved under the premise of satisfying CaSO3 oxidation and gypsum crystallization.

附图说明Description of drawings

图1是本实用新型的示意图;Fig. 1 is the schematic diagram of the utility model;

标号说明Label description

筒体1,吸收区隔板2,L吸收区3,H吸收区4,喷淋层5,Cylinder 1, absorption zone partition 2, L absorption zone 3, H absorption zone 4, spray layer 5,

L浆池区6,H浆池区7,循环泵8,入口烟道9,出口烟道10,L slurry pool area 6, H slurry pool area 7, circulation pump 8, inlet flue 9, outlet flue 10,

烟气导流板11,脉冲悬浮泵12,氧化风机13。Smoke deflector 11, pulse suspension pump 12, oxidation blower 13.

具体实施方式Detailed ways

下面结合附图和具体实施例对本实用新型作进一步的说明。Below in conjunction with accompanying drawing and specific embodiment the utility model is described further.

如图所示,一种往复式双区喷淋吸收塔,包括筒体1,筒体1内通过吸收区隔板2分为L吸收区3和H吸收区4,L吸收区3和H吸收区4下方分别对应L浆池区6和H浆池区7,用以储存吸收SO2所需要的吸收剂-石灰石浆液以及反应生成的副产生亚硫酸钙、硫酸钙及石膏浆液,浆池区被浆池隔板分隔,其中H浆池区7液位不做主动控制,可漫过浆池隔板自主溢流入L浆池区6,L浆池区6通过外排泵控制液位低于浆池隔板高度约1m,以保持L、H浆池区7恒定液位差。两个浆池区底部设脉冲悬浮装置,通过脉冲悬浮泵12的脉冲鼓动保持浆液中的固体成份不产生沉积;同时设有氧化空气管网,通过外设氧化风机13持续鼓入空气,以强制氧化SO2吸收反应生成的亚硫酸钙。As shown in the figure, a reciprocating double-zone spray absorption tower includes a cylinder body 1, and the cylinder body 1 is divided into an L absorption zone 3 and an H absorption zone 4 through an absorption zone partition 2, and the L absorption zone 3 and the H absorption zone The lower part of area 4 corresponds to the L slurry pool area 6 and the H slurry pool area 7, which are used to store the absorbent required for absorbing SO 2 - limestone slurry and the by-products of calcium sulfite, calcium sulfate and gypsum slurry generated by the reaction. The slurry pool area Separated by the pulp tank partition, the liquid level in the H pulp tank area 7 is not actively controlled, it can overflow the pulp tank partition and flow into the L pulp tank area 6 autonomously, and the L pulp tank area 6 controls the liquid level below the level through the efflux pump The height of the pulp tank partition is about 1m to maintain a constant liquid level difference in the L and H pulp tank areas 7. A pulse suspension device is installed at the bottom of the two slurry tank areas, and the pulse agitation of the pulse suspension pump 12 keeps the solid components in the slurry from depositing; at the same time, an oxidation air pipe network is provided, and the air is continuously blown in through the external oxidation fan 13 to force Oxidizes calcium sulfite generated by the SO2 absorption reaction.

吸收塔中部为吸收区,通过吸收区隔板2均分为L吸收区3和H吸收区4,分别与L浆池区6、H浆池区7对应。L吸收区3下部设两层或多层喷淋层5,喷淋方向向上;H吸收区4上部设两层或多层喷淋层5,喷淋方向向下。通过塔外设置的浆液循环泵8分别从L浆池区6、H浆池区7抽取浆液输送至对应吸收区喷淋层5用以洗涤烟气,洗涤过烟气的浆液通过重力作用,自由落至对应的L浆池区6、H浆池区7。The middle part of the absorption tower is the absorption zone, which is equally divided into the L absorption zone 3 and the H absorption zone 4 through the absorption zone separator 2, corresponding to the L slurry tank zone 6 and the H slurry tank zone 7 respectively. The lower part of the L absorption zone 3 is provided with two or more spray layers 5, and the spraying direction is upward; the upper part of the H absorption zone 4 is provided with two or more layers of spray layers 5, and the spraying direction is downward. The slurry circulation pump 8 provided outside the tower extracts the slurry from the L slurry pool area 6 and the H slurry pool area 7 and transports it to the spray layer 5 in the corresponding absorption area to wash the flue gas. Fall to the corresponding L pulp pool area 6, H pulp pool area 7.

吸收塔上部为除雾区,除雾区中设置有烟气导流板11,且安装有两级或三级平板式或屋脊式除雾器。The upper part of the absorption tower is a defogging area, in which a flue gas deflector 11 is installed, and two-stage or three-stage plate type or roof type mist eliminators are installed.

工作时,原烟气由入口烟气进入吸收塔,在L吸收区3内自上向下运行,并与向上喷淋的浆液逆流接触、碰撞发生吸收反应,去除大部分的SO2;通过L吸收区3后折返,在H吸收区4内自下向上运行,与向下喷淋的浆液逆流接触、碰撞发生吸收反应,去除残余SO2;烟气在喷淋洗涤过程中会夹带少量的液滴,在通过H区喷淋层5后进入筒体1扩径段,此时烟气流速急速降低至原流速的50%,通过重力作用大部分夹带的液滴会自由沉降,少量液滴随烟气进入除雾器,在物理撞击过程中被吸附,洁净烟气通过出口烟道10外排。When working, the raw flue gas enters the absorption tower from the inlet flue gas, runs from top to bottom in the L absorption zone 3, and contacts and collides with the slurry sprayed upwards in countercurrent, and absorbs and reacts to remove most of the SO 2 ; After the absorption zone 3, it turns back and runs from bottom to top in the H absorption zone 4. It contacts and collides with the downwardly sprayed slurry to undergo an absorption reaction to remove residual SO 2 ; the flue gas will entrain a small amount of liquid in the process of spraying and washing. After passing through the spray layer 5 in the H area, it enters the expansion section of the cylinder body 1. At this time, the flue gas flow rate drops rapidly to 50% of the original flow rate. The flue gas enters the demister and is adsorbed during physical impact, and the clean flue gas is discharged through the outlet flue 10 .

吸收SO2所消耗的石灰石浆液通过管道补充至H浆池区7,并进一步通过溢流部分补充至L浆池区6,通过进浆量的调整,控制H浆池浆液PH值保持在6~6.5范围,L浆液区浆液PH值保持在5.5~5.8范围,通过H喷淋区的高PH值浆液喷淋实现SO2的进一步吸收,提高脱硫效率;通过L浆池区6的低PH值浆液实现亚硫酸钙的氧化和石膏的结晶。 The limestone slurry consumed by absorbing SO2 is replenished to the H slurry tank area 7 through the pipeline, and further replenished to the L slurry tank area 6 through the overflow part. By adjusting the amount of slurry, the pH value of the slurry in the H slurry tank is controlled at 6~ In the range of 6.5, the pH value of the slurry in the L slurry area is kept in the range of 5.5 to 5.8, and the further absorption of SO2 is realized through the high pH value slurry spraying in the H spray area, and the desulfurization efficiency is improved ; the low pH value slurry in the L slurry tank area 6 Oxidation of calcium sulfite and crystallization of gypsum are realized.

吸收塔筒体1、入口烟道9、出口烟道10可以采用碳钢衬玻璃鳞片制作;浆池隔板、吸收区隔板2、烟气导流板11可采用碳钢衬玻璃鳞片制作或至少耐受20000ppm Cl-腐蚀的其他金属材质制作;脉冲悬浮装置,氧化空气管网,L区喷淋层5,H区喷淋层5可采用玻璃钢或至少耐受20000ppm Cl-腐蚀的其他金属材质制作;除雾器采用PP材质制作。The absorption tower body 1, the inlet flue 9, and the outlet flue 10 can be made of carbon steel-lined glass flakes; Made of other metal materials resistant to at least 20,000ppm Cl-corrosion; pulse suspension device, oxidizing air pipe network, spray layer 5 in L area, and spray layer 5 in H area can be made of glass fiber reinforced plastic or other metal materials resistant to at least 20,000ppm Cl- corrosion Production; the demister is made of PP material.

上述仅为本实用新型的具体实施例,同时凡本实用新型中所涉及的如“上、下、左、右、中间”等词,仅作参考用,并非绝对限定,凡利用本实用新型进行非实质性的改动,均应属于侵犯本实用新型保护范围的行为。Above-mentioned is only the concrete embodiment of the present utility model, and all the words such as " up, down, left, right, middle " involved in the present utility model are only used for reference, are not absolutely limited, all utilize the present utility model to carry out Non-substantial changes shall all be acts of violating the protection scope of the present utility model.

Claims (2)

1. a kind of reciprocating two-region spray absorber, it is characterised in that:Including cylinder, pass through uptake zone partition board point in the cylinder For the uptake zones L and the uptake zones H, several spraying layers, the uptake zones L and H are respectively arranged in the uptake zones L and the uptake zones H L stock tanks area and H stock tanks area are corresponded to respectively below uptake zone, and the spraying layer of the uptake zones L is taken out by circulating pump from L stock tanks area Slurries, the spraying layer of the uptake zones H are taken to extract slurries from H stock tanks area by circulating pump, the uptake zones L top is provided with Gas approach, the uptake zones H top are provided with exhaust pass, smoke deflector are provided between the exhaust pass and the uptake zones H, Demister is provided on the smoke deflector, L stock tanks area and H stock tanks area bottom are provided with pulse suspension device and oxidation Air pipe network.
2. a kind of reciprocating two-region spray absorber according to claim 1, it is characterised in that:In the uptake zones L Spraying layer spray direction is upward, and the spraying layer spray direction in the uptake zones H is downward.
CN201721891040.5U 2017-12-29 2017-12-29 A kind of reciprocating two-region spray absorber Active CN207980838U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110180370A (en) * 2019-05-10 2019-08-30 华电电力科学研究院有限公司 A kind of System and method for being bubbled the integrative coordinated removing multiple pollutant of spray
CN110404394A (en) * 2019-09-25 2019-11-05 山东润扬环保设备有限公司 Ultraviolet catalytic oxidation-Fenton high efficiency composition organic waste gas treatment device and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110180370A (en) * 2019-05-10 2019-08-30 华电电力科学研究院有限公司 A kind of System and method for being bubbled the integrative coordinated removing multiple pollutant of spray
CN110404394A (en) * 2019-09-25 2019-11-05 山东润扬环保设备有限公司 Ultraviolet catalytic oxidation-Fenton high efficiency composition organic waste gas treatment device and method

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Assignee: Zhejiang Detuo Intelligent Control Equipment Co.,Ltd.

Assignor: ZHEJIANG TUNA ENVIRONMENTAL SCIENCE & TECHNOLOGY Co.,Ltd.

Contract record no.: X2025980021544

Denomination of utility model: A reciprocating two-zone spray absorption tower

Granted publication date: 20181019

License type: Common License

Record date: 20250910