CN207445963U - A kind of high effective flue gas oxidation and denitration tower - Google Patents

A kind of high effective flue gas oxidation and denitration tower Download PDF

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CN207445963U
CN207445963U CN201721059214.1U CN201721059214U CN207445963U CN 207445963 U CN207445963 U CN 207445963U CN 201721059214 U CN201721059214 U CN 201721059214U CN 207445963 U CN207445963 U CN 207445963U
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flue gas
denitrification
tower
oxidation
denitrification tower
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胡赟
邵春岩
王维宽
张广鑫
于晓东
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Shenyang Academy Environmental Sciences
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Shenyang Academy Environmental Sciences
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Abstract

一种高效烟气氧化脱硝塔,涉及烟气处理装置。该高效烟气氧化脱硝塔,通过设置分隔板将脱硝塔内腔分隔成进烟气区和净烟气区,烟气进入脱硝浆液池后,杜绝了常规氧化脱硝出现二次NO的现象,具有设计合理、结构简单、安全环保的优点。

A high-efficiency flue gas oxidation and denitration tower relates to a flue gas treatment device. The high-efficiency flue gas oxidation denitrification tower divides the inner cavity of the denitrification tower into a flue gas inlet area and a clean flue gas area by setting a partition plate. After the flue gas enters the denitrification slurry pool, the secondary NO phenomenon of conventional oxidation denitrification is eliminated. The utility model has the advantages of reasonable design, simple structure, safety and environmental protection.

Description

一种高效烟气氧化脱硝塔A high-efficiency flue gas oxidation denitrification tower

技术领域technical field

本实用新型涉及烟气处理装置,特别涉及一种高效烟气氧化脱硝塔。The utility model relates to a flue gas treatment device, in particular to a high-efficiency flue gas oxidation and denitrification tower.

背景技术Background technique

当前,我国大气环境空气质量形势严峻,冬季多地连续出现持续性的灰霾天气,夏季出现臭氧超标天气,给人民群众的生活带来不利影响。研究发现灰霾和臭氧超标均与空气中氮氧化物有关,而空气中的氮氧化物主要来源于燃煤锅炉、炉窑和机动车等设施的尾气排放。为此,政府已连续出台多项与控制氮氧化物排放相关的政策法规、标准规范等,全面启动氮氧化物治理工程。燃煤电厂锅炉(SCR、SNCR)和机动车(SCR)的氮氧化物治理技术成熟,能够很好地控制氮氧化物排放。然而由于燃煤工业锅炉、工业炉窑等设施的工况与电厂锅炉的不同,电厂锅炉脱硝技术难以在工业锅炉和炉窑上复制应用,因此开发一种适用于燃煤工业锅炉和工业炉窑的氮氧化物净化技术和装置迫在眉睫。At present, the air quality situation in my country's atmospheric environment is severe. There are persistent haze weather in many places in winter and ozone exceeding the standard in summer, which has a negative impact on the lives of the people. Studies have found that both haze and ozone exceeding standards are related to nitrogen oxides in the air, and nitrogen oxides in the air mainly come from exhaust emissions from facilities such as coal-fired boilers, kilns, and motor vehicles. To this end, the government has successively issued a number of policies, regulations, standards and specifications related to the control of nitrogen oxide emissions, and fully launched the nitrogen oxide treatment project. The nitrogen oxide treatment technology of coal-fired power plant boilers (SCR, SNCR) and motor vehicles (SCR) is mature, and can well control nitrogen oxide emissions. However, because the working conditions of coal-fired industrial boilers, industrial furnaces and other facilities are different from those of power plant boilers, it is difficult to replicate and apply the power plant boiler denitrification technology to industrial boilers and furnaces. Advanced nitrogen oxide purification technology and devices are imminent.

发明内容Contents of the invention

针对现有技术存在的不足,本实用新型的目的是提供一种高效烟气氧化脱硝塔,该装置设计合理、结构简单,便于安装和维护,节约了大量的人力及物力。Aiming at the deficiencies of the existing technology, the purpose of this utility model is to provide a high-efficiency flue gas oxidation and denitrification tower. The device has a reasonable design, a simple structure, is easy to install and maintain, and saves a lot of manpower and material resources.

本实用新型所采用的技术方案是:一种高效烟气氧化脱硝塔,其技术要点是,包括带有烟气入口和出口的脱硝塔,在脱硝塔内部壁设有分隔板,分隔板将脱硝塔内腔分隔成进烟气区和净烟气区,在净烟气区的下部设有用于使烟气进行氧化脱硝反应的脱硝浆液池,烟气下降管一端通过分隔板后浸入在脱硝浆液池内,烟气下降管底端设有用于使烟气喷入脱硝浆液池的气泡出口,在靠近脱硝塔出口的位置还设有除雾器。The technical solution adopted by the utility model is: a high-efficiency flue gas oxidation denitrification tower, the technical point of which is to include a denitrification tower with a flue gas inlet and an outlet, and a partition plate is arranged on the inner wall of the denitrification tower. The inner cavity of the denitrification tower is divided into a flue gas inlet area and a flue gas clean area, and a denitrification slurry pool for oxidizing and denitrifying the flue gas is provided at the lower part of the flue gas clean area, and one end of the flue gas downcomer passes through the partition plate and is immersed in the In the denitrification slurry tank, the bottom of the flue gas downcomer is provided with a bubble outlet for spraying the flue gas into the denitrification slurry tank, and a demister is also provided near the outlet of the denitrification tower.

上述方案中,在脱硝塔内还设有带有防爆阀的防爆管,防爆管插接在分隔板上,防爆管的一端伸出脱硝塔外与空气接触,防爆管的另一端通过分隔板与净烟气区连通。In the above scheme, an explosion-proof pipe with an explosion-proof valve is also provided in the denitrification tower. The explosion-proof pipe is plugged into the partition plate. One end of the explosion-proof pipe extends out of the denitrification tower to contact with the air. The plate communicates with the clean flue gas area.

上述方案中,所述的烟气下降管插入脱硝浆液池150-200mm。In the above solution, the flue gas downpipe is inserted into the denitrification slurry pool by 150-200 mm.

上述方案中,在脱硝浆液池内还设有紫外灯和曝气管。In the above scheme, an ultraviolet lamp and an aeration tube are also provided in the denitrification slurry tank.

上述方案中,所述的曝气管设在距脱硝浆液池底部100-150mm处。In the above solution, the aeration pipe is set at a distance of 100-150 mm from the bottom of the denitrification slurry tank.

上述方案中,在脱硝塔底部还设有氧化电位计和液位计。In the above scheme, an oxidation potentiometer and a liquid level gauge are also provided at the bottom of the denitrification tower.

本实用新型的有益效果是:该高效烟气氧化脱硝塔,通过设置分隔板将脱硝塔内腔分隔成进烟气区和净烟气区,烟气进入脱硝浆液池后,杜绝了常规氧化脱硝出现二次NO的现象,具有设计合理、结构简单、安全环保的优点。The beneficial effects of the utility model are: the high-efficiency flue gas oxidation denitrification tower divides the inner chamber of the denitrification tower into a flue gas inlet area and a clean flue gas area by setting a partition plate. After the flue gas enters the denitrification slurry pool, the conventional oxidation The phenomenon of secondary NO in denitrification has the advantages of reasonable design, simple structure, safety and environmental protection.

附图说明Description of drawings

为了更清楚地说明本实用新型实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本实用新型的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the accompanying drawings required in the embodiments will be briefly introduced below. Obviously, the accompanying drawings in the following description are only the present invention. For some embodiments of the present invention, those skilled in the art can also obtain other drawings based on these drawings without creative work.

图1为本实用新型实施例中高效烟气氧化脱硝塔的结构示意图;Fig. 1 is a schematic structural view of a high-efficiency flue gas oxidation and denitrification tower in an embodiment of the present invention;

图中序号说明如下:1脱硝塔、2烟气入口、3分隔板、4烟气下降管、5紫外灯、6PH计、7氧化电位计、8液位计、9碱液喷入口、10曝气管、11除雾器、12出口、13防爆管、14氧化剂催化剂入口、15脱硝浆液池、16气泡出口、17防爆阀。The serial numbers in the figure are as follows: 1 denitrification tower, 2 flue gas inlet, 3 partition plate, 4 flue gas downpipe, 5 ultraviolet lamp, 6PH meter, 7 oxidation potentiometer, 8 liquid level meter, 9 lye spray inlet, 10 Aeration pipe, 11 demister, 12 outlet, 13 explosion-proof pipe, 14 oxidant catalyst inlet, 15 denitrification slurry tank, 16 air bubble outlet, 17 explosion-proof valve.

具体实施方式Detailed ways

使本实用新型的上述目的、特征和优点能够更加明显易懂,下面结合附图1和具体实施方式对本实用新型作进一步详细的说明。To make the above purpose, features and advantages of the utility model more obvious and easy to understand, the utility model will be further described in detail below in conjunction with the accompanying drawing 1 and specific embodiments.

实施例1:Example 1:

本实施例采用的高效烟气氧化脱硝塔,包括带有烟气入口2和出口12的脱硝塔1,在脱硝塔1内部壁设有分隔板3,分隔板3将脱硝塔1内腔分隔成进烟气区和净烟气区,在净烟气区的下部设有用于使烟气进行氧化脱硝反应的脱硝浆液池15,烟气下降管4一端通过分隔板3后浸入在脱硝浆液池15内150mm,烟气下降管4底端设有供烟气喷入脱硝浆液池15的气泡出口16,经脱硝浆液池15反应后的烟气充满脱硝净烟气区,在靠近脱硝塔出口12的位置还设有除雾器11。The high-efficiency flue gas oxidation denitrification tower adopted in this embodiment includes a denitrification tower 1 with a flue gas inlet 2 and an outlet 12, and a partition plate 3 is arranged on the inner wall of the denitrification tower 1, and the partition plate 3 separates the inner cavity of the denitrification tower 1. Separated into a flue gas inlet area and a clean flue gas area, a denitrification slurry pool 15 for oxidizing and denitrifying the flue gas is provided at the lower part of the clean flue gas area. The inside of the slurry pool 15 is 150 mm, and the bottom end of the flue gas downcomer 4 is provided with a bubble outlet 16 for the flue gas to be sprayed into the denitrification slurry pool 15. The position of the outlet 12 is also provided with a mist eliminator 11 .

在脱硝塔1内还设有带有防爆阀17的防爆管13,防爆管13插接在分隔板3上,防爆管13的一端伸出脱硝塔1外与空气接触,防爆管13的另一端通过分隔板3与脱硝净烟气区连通。An explosion-proof pipe 13 with an explosion-proof valve 17 is also provided in the denitrification tower 1. The explosion-proof pipe 13 is plugged on the partition plate 3. One end of the explosion-proof pipe 13 extends out of the denitrification tower 1 to contact with the air. The other end of the explosion-proof pipe 13 One end communicates with the denitrification and clean flue gas area through the partition plate 3 .

在脱硝浆液池15内还设有紫外灯5、PH计6、氧化电位计7、液位计8和曝气管10。曝气管设在距脱硝浆液池底部100mm处。An ultraviolet lamp 5 , a pH meter 6 , an oxidation potentiometer 7 , a liquid level meter 8 and an aeration pipe 10 are also arranged in the denitrification slurry tank 15 . The aeration pipe is located 100mm from the bottom of the denitrification slurry tank.

在脱硝浆液池底部还设有碱液喷入口9和氧化剂催化剂入口14。An alkali spray inlet 9 and an oxidant catalyst inlet 14 are also provided at the bottom of the denitrification slurry tank.

本实施例中高效烟气氧化脱硝塔对烟气处理的过程如下:In this embodiment, the flue gas treatment process of the high-efficiency flue gas oxidation and denitrification tower is as follows:

来自锅炉或炉窑的烟气除尘脱硫后,在增压风机的作用下进入高效氧化脱硝塔。脱硝塔是一个高效鼓泡塔, 除尘脱硫后过来的烟气先进入脱硝塔内的进烟气区,然后经烟气下降管进入净烟气区的脱硝浆液池。烟气下降管浸入液面之下,在烟气压力的作用下,烟气呈气泡的形式从烟气下降管排出进入浆液池内,气泡中NO与浆液中强氧化剂(羟基﹣OH)接触发生氧化反应,NO被氧化成NO2,NO2溶解于水形成硝酸, 硝酸再与脱硝塔外的脱硝剂(碱性物质)发生中和脱硝反应。脱硝后的净烟气经烟气上升管进入净烟气区后,再经过两级除雾器除雾后,排出脱硝塔。After the flue gas from the boiler or kiln is dedusted and desulfurized, it enters the high-efficiency oxidation and denitrification tower under the action of the booster fan. The denitrification tower is a high-efficiency bubbling tower. The flue gas after dedusting and desulfurization first enters the flue gas inlet area in the denitrification tower, and then enters the denitrification slurry pool in the clean flue gas area through the flue gas downpipe. The flue gas downcomer is immersed under the liquid surface, and under the action of the flue gas pressure, the flue gas is discharged from the flue gas downcomer into the slurry pool in the form of bubbles, and the NO in the bubbles contacts with the strong oxidant (hydroxyl-OH) in the slurry to oxidize Reaction, NO is oxidized to NO2, NO2 dissolves in water to form nitric acid, and then the nitric acid reacts with the denitration agent (alkaline substance) outside the denitration tower for neutralization and denitration reaction. After denitrification, the clean flue gas enters the clean flue gas area through the flue gas rising pipe, and then passes through the two-stage demister for demisting, and then exits the denitrification tower.

实施例2:Example 2:

本实施例与实施例1的区别在于,所述的曝气管设在距脱硝浆液池底部130mm处。所述的烟气下降管插入脱硝浆液池180mm。The difference between this embodiment and Embodiment 1 is that the aeration pipe is set at a distance of 130 mm from the bottom of the denitrification slurry tank. The flue gas downpipe is inserted into the denitrification slurry tank by 180mm.

实施例3:Example 3:

本实施例与实施例1的区别在于,所述的曝气管设在距脱硝浆液池底部150mm处。所述的烟气下降管插入脱硝浆液池200mm。The difference between this embodiment and Embodiment 1 is that the aeration pipe is set at a distance of 150 mm from the bottom of the denitrification slurry tank. The flue gas downpipe is inserted into the denitrification slurry tank by 200 mm.

以上所述,仅为本实用新型的具体实施方式,但本实用新型的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本实用新型揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本实用新型的保护范围之内。因此,本实用新型的保护范围应以所述权利要求的保护范围为准。The above is only a specific embodiment of the present utility model, but the scope of protection of the present utility model is not limited thereto. Anyone familiar with the technical field can easily think of changes or changes within the technical scope disclosed by the utility model Replacement should be covered within the protection scope of the present utility model. Therefore, the protection scope of the present utility model should be based on the protection scope of the claims.

Claims (6)

1.一种高效烟气氧化脱硝塔,其特征在于,包括带有烟气入口和出口的脱硝塔,在脱硝塔内部壁设有分隔板,分隔板将脱硝塔内腔分隔成进烟气区和净烟气区,在净烟气区的下部设有用于使烟气进行氧化脱硝反应的脱硝浆液池,烟气下降管一端通过分隔板后浸入在脱硝浆液池内,烟气下降管底端设有用于使烟气喷入脱硝浆液池的气泡出口,在靠近脱硝塔出口的位置还设有除雾器。1. A high-efficiency flue gas oxidation denitrification tower is characterized in that it includes a denitrification tower with a flue gas inlet and an outlet, and a partition plate is provided on the inner wall of the denitrification tower, and the partition plate separates the inner cavity of the denitrification tower into smoke inlets. Gas zone and clean flue gas zone, in the lower part of the clean flue gas zone, there is a denitrification slurry pool for the oxidation and denitrification reaction of flue gas. The bottom end is provided with a bubble outlet for spraying flue gas into the denitrification slurry tank, and a demister is also provided near the outlet of the denitrification tower. 2.如权利要求1所述的高效烟气氧化脱硝塔,其特征在于,在脱硝塔内还设有带有防爆阀的防爆管,防爆管插接在分隔板上,防爆管的一端伸出脱硝塔外与空气接触,防爆管的另一端通过分隔板与净烟气区连通。2. The high-efficiency flue gas oxidation denitrification tower as claimed in claim 1, characterized in that, an explosion-proof pipe with an explosion-proof valve is also provided in the denitrification tower, the explosion-proof pipe is inserted on the partition plate, and one end of the explosion-proof pipe extends The outside of the denitrification tower is in contact with the air, and the other end of the explosion-proof pipe communicates with the clean flue gas area through the partition plate. 3.如权利要求1或2所述的高效烟气氧化脱硝塔,其特征在于,所述的烟气下降管插入脱硝浆液池150-200mm。3. The high-efficiency flue gas oxidation and denitrification tower according to claim 1 or 2, characterized in that the flue gas downcomer is inserted into the denitrification slurry pool by 150-200 mm. 4.如权利要求3所述的高效烟气氧化脱硝塔,其特征在于,在脱硝浆液池内还设有紫外灯和曝气管。4. The high-efficiency flue gas oxidation denitrification tower as claimed in claim 3, characterized in that an ultraviolet lamp and an aeration tube are also provided in the denitrification slurry tank. 5.如权利要求4所述的高效烟气氧化脱硝塔,其特征在于,所述的曝气管设在距脱硝浆液池底部100-150mm处。5. The high-efficiency flue gas oxidation and denitrification tower according to claim 4, characterized in that, the aeration pipe is arranged at a distance of 100-150 mm from the bottom of the denitrification slurry tank. 6.如权利要求5所述的高效烟气氧化脱硝塔,其特征在于,在脱硝塔底部还设有氧化电位计和液位计。6. The high-efficiency flue gas oxidation denitrification tower as claimed in claim 5, characterized in that an oxidation potentiometer and a liquid level gauge are also provided at the bottom of the denitrification tower.
CN201721059214.1U 2017-08-23 2017-08-23 A kind of high effective flue gas oxidation and denitration tower Expired - Fee Related CN207445963U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109316940A (en) * 2018-12-03 2019-02-12 张烈玉 Desulphurization denitration gas wash tower
CN111068501A (en) * 2020-01-17 2020-04-28 珠海益佳生物科技有限公司 Absorption decomposition liquid, method and device for simultaneously removing hydrogen sulfide and ammonia waste gas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109316940A (en) * 2018-12-03 2019-02-12 张烈玉 Desulphurization denitration gas wash tower
CN111068501A (en) * 2020-01-17 2020-04-28 珠海益佳生物科技有限公司 Absorption decomposition liquid, method and device for simultaneously removing hydrogen sulfide and ammonia waste gas
CN111068501B (en) * 2020-01-17 2023-10-20 珠海益佳生物科技有限公司 Absorption decomposition liquid, method and device for simultaneously removing hydrogen sulfide and ammonia waste gas

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