CN207056338U - The regenerating unit of sour gas trapping solution in a kind of power-plant flue gas - Google Patents
The regenerating unit of sour gas trapping solution in a kind of power-plant flue gas Download PDFInfo
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Abstract
一种电厂烟气中酸性气体捕集溶液的再生装置,装置包括位于加热蒸发室中心的内置循环管,内置循环管的底部入口与吸收装置的富液泵相连,顶部出口位于液体分布器的上部,液体分布器与加热蒸发室内均匀分布的加热管的入口相连,加热管的出口直接与贫液釜连通,贫液釜的底部贫液出口与贫液泵相连,上部气体出口处设置除沫器,气体出口与气液分离器的入口相连,气液分离器的底部液体出口与贫液釜相连,顶部气体出口与抽气泵相连,本实用新型采用管式降膜方式进行富液加热解吸,富液蒸汽流向与液膜流向相同,可使液膜更均匀、更薄、流速更快,有利于减小传热阻力,提高热效率和再生效果,尤其适用于粘度较高的吸收剂体系。
A regeneration device for acid gas trapping solution in power plant flue gas, the device includes a built-in circulation pipe located in the center of the heating evaporation chamber, the bottom inlet of the built-in circulation pipe is connected with the rich liquid pump of the absorption device, and the top outlet is located at the upper part of the liquid distributor , the liquid distributor is connected to the inlet of the uniformly distributed heating pipes in the heating evaporation chamber, the outlet of the heating pipe is directly connected to the lean liquid tank, the lean liquid outlet at the bottom of the lean liquid tank is connected to the lean liquid pump, and a demister is installed at the upper gas outlet , the gas outlet is connected to the inlet of the gas-liquid separator, the bottom liquid outlet of the gas-liquid separator is connected to the lean liquid tank, and the top gas outlet is connected to the air pump. The flow direction of the liquid vapor is the same as that of the liquid film, which can make the liquid film more uniform, thinner, and flow faster, which is beneficial to reduce heat transfer resistance, improve thermal efficiency and regeneration effect, and is especially suitable for absorbent systems with high viscosity.
Description
技术领域technical field
本实用新型属于电厂烟气净化处理技术领域,特别涉及一种电厂烟气中酸性气体捕集溶液的再生装置。The utility model belongs to the technical field of power plant flue gas purification treatment, in particular to a regeneration device for acid gas trapping solution in power plant flue gas.
背景技术Background technique
我国以煤电为主的电力结构中长期内难以改变,燃煤电厂烟气中的SO2和CO2是引起诸如酸雨、大气污染和温室效应等全球环境问题的主要原因,我国对控制SO2和CO2的排放给予高度重视,尤其对SO2排放有严格限制。China's power structure dominated by coal power is difficult to change in the medium and long term. SO 2 and CO 2 in the flue gas of coal-fired power plants are the main causes of global environmental problems such as acid rain, air pollution and greenhouse effect. China's control of SO 2 And CO 2 emissions are highly valued, especially SO 2 emissions are strictly limited.
目前,燃煤电厂CO2脱除技术以可循环再生的醇胺化学吸收法为主,该技术也是有望最快实现大规模商业化的CO2捕集技术。SO2脱除技术以石灰石-石膏法为主,吸收剂不可循环再生。为解决石灰石-石膏法现存问题,针对SO2酸性气体的特性,部分电厂利用弱碱性的缓冲剂实现SO2的吸收和再生。与石灰石-石膏脱硫工艺相比,再生脱硫工艺流程简单,不会产生石膏等固体废弃物,且吸收剂可循环再生并副产SO2、硫酸、硫磺等化工品。At present, the CO 2 removal technology in coal-fired power plants is mainly based on the recyclable alcohol amine chemical absorption method, which is also the CO 2 capture technology that is expected to achieve large-scale commercialization the fastest. The limestone-gypsum method is the main technology for SO 2 removal, and the absorbent cannot be recycled. In order to solve the existing problems of the limestone-gypsum method, according to the characteristics of SO 2 acid gas, some power plants use weakly alkaline buffers to achieve SO 2 absorption and regeneration. Compared with the limestone-gypsum desulfurization process, the regenerative desulfurization process is simple, does not produce solid waste such as gypsum, and the absorbent can be recycled and by-products such as SO 2 , sulfuric acid, sulfur and other chemicals.
电厂烟气中酸性气体的可再生脱除工艺面临的主要问题是吸收剂负载酸性气体后形成的富液需要送去再生塔加热再生,而这一过程需要消耗大量蒸汽,造成系统能耗较大,尤其是对粘度较高的吸收剂,传统再生方式效率较低且能耗高。因此,改进富液再生方式,提高蒸汽利用效率,对可再生脱除技术节能降耗以及在电厂烟气净化领域的推广应用具有重要意义。The main problem faced by the renewable removal process of acid gas in power plant flue gas is that the rich liquid formed after the absorbent is loaded with acid gas needs to be sent to the regeneration tower for heating and regeneration, and this process requires a large amount of steam consumption, resulting in high energy consumption of the system , especially for absorbents with high viscosity, the traditional regeneration method is inefficient and consumes a lot of energy. Therefore, improving the rich liquid regeneration method and improving the steam utilization efficiency are of great significance to the energy saving and consumption reduction of renewable removal technology and the popularization and application in the field of power plant flue gas purification.
发明内容Contents of the invention
为了克服上述现有技术的缺点,本实用新型的目的在于提供一种电厂烟气中酸性气体捕集溶液的再生装置,以提高蒸汽利用效率,降低富液再生能耗。In order to overcome the above-mentioned shortcomings of the prior art, the purpose of this utility model is to provide a regeneration device for acid gas capture solution in power plant flue gas, so as to improve steam utilization efficiency and reduce energy consumption of rich liquid regeneration.
为了实现上述目的,本实用新型采用的技术方案是:In order to achieve the above object, the technical solution adopted by the utility model is:
一种电厂烟气中酸性气体捕集溶液的再生装置,包括位于加热蒸发室1中心的内置循环管2,内置循环管2的底部入口与吸收装置的富液泵3相连,顶部出口位于液体分布器4的上部,液体分布器4与加热蒸发室1内均匀分布的加热管5的入口相连,加热管5的出口直接与贫液釜6连通,贫液釜6的上部气体出口与气液分离器9的入口相连,气液分离器9的底部液体出口回接至贫液釜6,顶部气体出口与抽气泵10相连。A regeneration device for acid gas capture solution in flue gas of a power plant, including a built-in circulation pipe 2 located in the center of the heating evaporation chamber 1, the bottom inlet of the built-in circulation pipe 2 is connected with the rich liquid pump 3 of the absorption device, and the top outlet is located in the liquid distribution On the upper part of the device 4, the liquid distributor 4 is connected to the inlet of the uniformly distributed heating pipe 5 in the heating evaporation chamber 1, and the outlet of the heating pipe 5 is directly connected to the lean liquid tank 6, and the upper gas outlet of the lean liquid tank 6 is separated from the gas and liquid The inlet of the device 9 is connected, the bottom liquid outlet of the gas-liquid separator 9 is connected back to the lean liquid tank 6, and the top gas outlet is connected to the air pump 10.
所述贫液釜6的上部气体出口处设置除沫器8。A demister 8 is provided at the upper gas outlet of the lean liquid tank 6 .
所述贫液釜6的底部贫液出口通过贫液泵7经换热器与吸收装置的吸收剂入口相连。The lean liquid outlet at the bottom of the lean liquid tank 6 is connected to the absorbent inlet of the absorption device through a lean liquid pump 7 through a heat exchanger.
所述加热管5为竖向管,悬在贫液釜6上方,加热管5的顶端为入口,底端为出口。The heating tube 5 is a vertical tube suspended above the lean liquid tank 6, the top of the heating tube 5 is the inlet, and the bottom is the outlet.
所述加热蒸发室1的蒸汽入口位于上部,下部有冷凝水出口。The steam inlet of the heating evaporation chamber 1 is located at the upper part, and the condensed water outlet is located at the lower part.
所述加热管5为降膜加热管。The heating tube 5 is a falling film heating tube.
与现有技术相比,本实用新型采用管式降膜方式进行富液加热解吸,富液蒸汽流向与液膜流向相同,可以使得液膜更加均匀、更薄、流速更快,有利于减小传热阻力,提高热效率和再生效果,尤其适用于粘度较高的吸收剂体系。相对于传统填料塔来说,装置较为简单,且不宜堵塞,不存在塔液泛等情况的发生,同时在维护以及清理方面也相对简单。Compared with the prior art, the utility model adopts the tubular falling film method to heat and desorb the rich liquid, and the flow direction of the rich liquid vapor is the same as that of the liquid film, which can make the liquid film more uniform, thinner and faster, which is beneficial to reduce Heat transfer resistance, improve thermal efficiency and regeneration effect, especially suitable for absorbent systems with high viscosity. Compared with the traditional packed tower, the device is relatively simple, and it is not suitable for clogging, and there is no occurrence of liquid flooding in the tower. At the same time, it is relatively simple in maintenance and cleaning.
附图说明Description of drawings
图1是本实用新型结构示意图。Fig. 1 is the structural representation of the utility model.
具体实施方式Detailed ways
下面结合附图和实施例详细说明本实用新型的实施方式。The implementation of the utility model will be described in detail below in conjunction with the accompanying drawings and examples.
如图1所示,一种电厂烟气中酸性气体捕集溶液的再生装置,包括位于加热蒸发室1中心的内置循环管2,内置循环管2的底部入口与吸收装置的富液泵3相连,顶部出口位于液体分布器4的上部,液体分布器4与加热蒸发室1内均匀分布的加热管5的入口相连,加热管5的出口直接与贫液釜6连通,贫液釜6的底部贫液出口与贫液泵7相连,上部气体出口处设置除沫器8,气体出口与气液分离器9的入口相连,气液分离器9的底部液体出口与贫液釜6相连,顶部气体出口与抽气泵10相连。加热蒸汽由加热蒸发室1上方入口进入,冷凝水由下方出口流出。As shown in Figure 1, a regeneration device for the acid gas capture solution in the flue gas of a power plant includes a built-in circulation pipe 2 located in the center of the heating evaporation chamber 1, and the bottom inlet of the built-in circulation pipe 2 is connected with the rich liquid pump 3 of the absorption device , the top outlet is located at the top of the liquid distributor 4, the liquid distributor 4 is connected to the inlet of the uniformly distributed heating pipe 5 in the heating evaporation chamber 1, the outlet of the heating pipe 5 is directly connected to the lean liquid kettle 6, and the bottom of the lean liquid kettle 6 The lean liquid outlet is connected to the lean liquid pump 7, the demister 8 is installed at the upper gas outlet, the gas outlet is connected to the inlet of the gas-liquid separator 9, the liquid outlet at the bottom of the gas-liquid separator 9 is connected to the lean liquid tank 6, and the top gas The outlet is connected with air pump 10. The heating steam enters from the upper inlet of the heating evaporation chamber 1, and the condensed water flows out from the lower outlet.
本实用新型的工作原理及方法如下:Working principle and method of the present utility model are as follows:
来自吸收装置的富液热交换后通过富液泵3进入加热蒸发室1中心的内置循环管2的下部,并向上流动;富液在内置循环管2中预热后进入加热蒸发室1上部的液体分布器4,经过液体分布器4重新布液后流入各降膜加热管5,沿管道内壁形成液膜向下流动,同时在加热蒸发室1内进行热量传递;富液液膜加热过程中形成蒸气,同时富液中的酸性气体得以再生;含有酸性气体再生气的蒸气在加热管5内快速向下流动,将液膜吹得更薄、更均匀且流速更快,大大降低传热阻力,提高传热效率;再生后的贫液进入贫液釜6,并经贫液泵7抽出作为吸收剂循环使用;气体经过除沫器8后由贫液釜6上部的气体出口流出,经冷凝后进入气液分离器9实现气液分离,冷凝液返回贫液釜6,酸性气体再生气则通过抽气泵10抽出。加热蒸汽由加热蒸发室1上方入口进入,冷凝水由下方出口流出。The rich liquid from the absorption device enters the lower part of the built-in circulation pipe 2 in the center of the heating evaporation chamber 1 through the rich liquid pump 3 after heat exchange, and flows upward; the rich liquid enters the upper part of the heating evaporation chamber 1 after being preheated in the built-in circulation pipe 2 The liquid distributor 4 flows into the falling film heating tubes 5 after being redistributed by the liquid distributor 4, forms a liquid film along the inner wall of the tube and flows downward, and at the same time conducts heat transfer in the heating evaporation chamber 1; during the heating process of the rich liquid film Steam is formed, and the acid gas in the rich liquid is regenerated at the same time; the steam containing the acid gas regeneration gas flows rapidly downward in the heating tube 5, blowing the liquid film thinner, more uniform and faster, greatly reducing the heat transfer resistance , to improve heat transfer efficiency; the regenerated lean liquid enters the lean liquid kettle 6, and is pumped out by the lean liquid pump 7 as an absorbent for recycling; after the gas passes through the demister 8, it flows out from the gas outlet on the upper part of the lean liquid kettle 6, and is condensed After entering the gas-liquid separator 9 to realize gas-liquid separation, the condensate returns to the lean liquid tank 6, and the acid gas regeneration gas is extracted through the air pump 10. The heating steam enters from the upper inlet of the heating evaporation chamber 1, and the condensed water flows out from the lower outlet.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107243258A (en) * | 2017-07-20 | 2017-10-13 | 中国华能集团清洁能源技术研究院有限公司 | The regenerating unit and method of sour gas trapping solution in a kind of power-plant flue gas |
| CN109030126A (en) * | 2018-07-17 | 2018-12-18 | 克拉玛依红山油田有限责任公司 | Tank mouth associated gas enclosed sampling analytical equipment |
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- 2017-07-20 CN CN201720886000.5U patent/CN207056338U/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107243258A (en) * | 2017-07-20 | 2017-10-13 | 中国华能集团清洁能源技术研究院有限公司 | The regenerating unit and method of sour gas trapping solution in a kind of power-plant flue gas |
| CN109030126A (en) * | 2018-07-17 | 2018-12-18 | 克拉玛依红山油田有限责任公司 | Tank mouth associated gas enclosed sampling analytical equipment |
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