CN206447734U - A kind of combined type sewage treatment equipment - Google Patents

A kind of combined type sewage treatment equipment Download PDF

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Publication number
CN206447734U
CN206447734U CN201720076378.9U CN201720076378U CN206447734U CN 206447734 U CN206447734 U CN 206447734U CN 201720076378 U CN201720076378 U CN 201720076378U CN 206447734 U CN206447734 U CN 206447734U
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pond
treatment equipment
combined type
sewage treatment
filler
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CN201720076378.9U
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吴万秀
方永旺
蒯学静
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Hangzhou Hua Testing Technology Co Ltd
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Hangzhou Hua Testing Technology Co Ltd
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  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The utility model provides a kind of combined type sewage treatment equipment, including coagulative precipitation tank, biological contact oxidation pond, integrated photo-catalytic oxidation membrane separation reactor, counter-infiltration system;Biological contact oxidation pond includes pond body and filler, the filler is semi-soft bat wool, hang in pond body, the volume of filler accounts for the 70 85% of tank volume, bottom of pond is equipped with micro-hole aerator, nanomorphic photochemical catalyst is delivered in integrated photo-catalytic oxidation membrane separation reactor, interior uniform ultraviolet source, reactor bottom is provided with aerator.Organic matter in waste water is degraded under biochemical and catalysis oxidation double condition, and the removal efficiency of waste water is further increased by the separation of reverse osmosis membrane.

Description

A kind of combined type sewage treatment equipment
Technical field
The utility model is related to a kind of combined type sewage treatment equipment, belongs to water-treatment technology field.
Background technology
Modern sewage treatment technology, is divided by processing mode, can be divided into physical treatment, chemical treatment and biological treatment.Thing Processing method is managed, also known as machinery controls logos.Mainly for separating of the suspension material in waste water.This method biggest advantage is Simply, it is easy, work well, it is and very economical.Conventional physics administering method has:Gravitational separation process, centrifugal separation, mistake Filter method and evaporative crystallization method etc..The main process object of method of chemical treatment is the pollutant of dissolubility or colloidality in waste water Matter.It can both be separated from water pollutant, can also change some polluters and organic matter etc., therefore can reach and compare thing The higher degree of purification of reason method.When particularly reclaiming utility from waste water, or containing certain is poisonous, have in waste water It is most appropriate using chemical harnessing method when doing harm to and being difficult the material being degraded by microorganisms.However, Chemo-Therapy logos often needs to use Chemical agent or material, therefore operating cost is typically all higher, operates and is also compared strict etc. with the requirement managed.Moreover, In the pre-treatment of chemical method or last handling process, generally also need to use cooperatively physics administering method.Utilize microbiological treatment waste water Method, referred to as biological treatment or biochemical treatment process.It is a part of deliquescent organic during microbial life activity Material is used for the plasm and repertory of synthetic cell;It is a part of then be changed into metabolite, and give off energy, supply microorganism Plasmic synthesis and vital movement, enable microorganism to keep ground growth and breeding, so that waste water purify, biology Facture is exactly to utilize this function.According to the respiratory characteristic of microorganism, it is divided into aerobic, anaerobism and facultative three major types microorganism, And the class bioremediation of Aerobic Process for Treatment two.
Biological contact oxidation process belongs to aerobic biological process for treating, it be using be attached to the biomembrane on carrier (filler) as Main, a kind of efficient water treatment technology of purification of organic waste water, the biomembrance process of active sludge feature has activated sludge concurrently The advantage of method and biomembrance process.Its method is that filler is set in pond body, and bottom of pond aeration is oxygenated to sewage, and is made in pond body Sewage is in flow regime, to ensure that sewage is fully contacted with the filler in sewage.Oxygen needed for general biological contact oxidation process Supplied by blast aeration, but be due to that sludge loading in biological contact oxidation process is larger, cause whole biological contact oxidation pond Required aeration quantity is big, and energy consumption is higher;Blast aeration bubble is larger, easily impacts biomembrane, can cause biofilm detachment;And oxygen Gas skewness in water.
High-level oxidation technology (Advanced oxidation process, AOPs) is mainly used in difficult degradation class organic contamination The new technology of thing.It is mainly characterized by (1) and produces a large amount of very active hydroxyl radical free radicals (OH), and it is anti-to produce a large amount of chain types Should;(2) pollutant reaction in the direct and waste water of OH energy non-selectivity, or even mineralising is carbon dioxide and water, is not produced Secondary pollution;(3) reaction can carry out at normal temperatures and pressures, can individually progress processing can also be with other reaction bondeds.Root The oxidant and condition used according to it is different, is generally divided into Fenton, class Fenton oxidation, photochemistry and photocatalytic oxidation, ultrasound Oxidation, electrochemical oxidation process etc..
But for some special waste water, such as high saliferous, the matter of type organic containing difficult for biological degradation, COD concentration are higher Waste water its processing have its limitation using individually biochemical and advanced oxidation.Traditional biochemical treatment is difficult to organic to difficult degradation Thing is effectively removed, and be used alone high-level oxidation technology there may exist fund input and operating cost excessively it is high lack Point.Therefore, there is efficient, economy, nothing for handling above-mentioned waste water with reference to the combined treatment process of biochemical and high-level oxidation technology The many merits such as secondary pollution and have broad prospects.
Utility model content
The purpose of this utility model be in view of the shortcomings of the prior art there is provided a kind of biochemical reaction combination photochemical catalytic oxidation- The device of membrane separation technique.
Device of the present utility model mainly comprising traditional bio-contact oxidation reaction member and with ultraviolet light and adds light Catalyst is the catalytic oxidation unit and membrane separation device of representative.
The utility model is achieved through the following technical measures:Including coagulative precipitation tank, biological contact oxidation pond, one Formula photochemical catalytic oxidation-membrane separation reactor, counter-infiltration system, wherein, sewage enters coagulative precipitation tank by intake pump, described mixed Agitator and polymeric aluminium ferrum silicate chemicals dosing plant, the delivery port connection biological of the coagulative precipitation tank are set in solidifying sedimentation basin The water inlet of oxidation pond, the biological contact oxidation pond includes pond body and filler, and the filler is semi-soft bat wool, is hanged It is hung in pond body, the volume of filler accounts for the 70-85% of tank volume, and bottom of pond is equipped with micro-hole aerator;The bio-contact oxidation The delivery port in pond is integrally connected the water inlet of formula photochemical catalytic oxidation-membrane separation reactor, the integrated photo-catalytic oxidation-film point From nanomorphic photochemical catalyst has been delivered in reactor, interior uniform ultraviolet source, reactor bottom is provided with aerator, the nanometer State photochemical catalyst is in suspended state in the reactor, and sewage carries out film point after photocatalysis oxidation reaction, then by membrane module From the delivery port of membrane module connects the water inlet of reverse osmosis unit, finally gives clear water.Organic matter in waste water is biochemical and urge Degraded under the conditions of change oxidation is dual, the removal efficiency of waste water is further increased by the separation of reverse osmosis membrane.
Further, described ultraviolet source be efficient low-pressure, medium-pressure or high pressure mercury lamp and it is other can efficient transmission it is ultraviolet The light source of light, ultraviolet source launch wavelength is 254~365nm, and the efficiency of ultraviolet light is not less than 50%, to ensure whole photocatalysis The effect of reaction.
Further, described nanomorphic photochemical catalyst is nano titanic oxide catalyst, and membrane module is submerged membrane point From component.Titanium dioxide is strong because of its oxidability, and chemical property stablizes nontoxic, is good nano photocatalyst catalytic material.Membrane module Separation and recovery and reuse for catalyst, under certain pressure effect, water passes through film, nano titanium dioxide photocatalyst envelope Retention, the titanium dioxide circulating and recovering of retention, film filtration effluent travels further into counter-infiltration system.
Described counter-infiltration system is two-stage reverse osmosis system, and two steps ro film is run under a certain pressure, after separation Obtain clean water outlet.Membrane module and reverse osmosis membrane are after operation a period of time, and film surface can deposit a large amount of pollutants, it is to avoid film Blocking, the also non-membrane separation device of the device and counter-infiltration system are equipped with backwash unit.And for the good fortune of whole device Row and control, are controlled by PLC.
The utility model compared with prior art, with following substantive distinguishing features and remarkable advantage:
(1) the specifically chosen polymeric aluminium ferrum silicate of coagulant, it has the dual property of flocculation and sterilization, compared to other nothings Machine flocculant, the amount of sludge with generation is few, and sinking speed is fast, purifies water, low cost and other advantages;
(2) filler is provided with biological contact oxidation pond, to different quality object using means are targetedly tamed, selected Select suitable biological bacteria, biological bacteria is bred in filler surface raised growth, form biomembrane, in this step using BOD, COD as Main pollutant is removed, while going to denitrogenate phosphorus;
(3) sewage enters integrated photo-catalytic oxidation-membrane separation reactor, and the power of ultraviolet light can in photo catalysis reactor Freely to adjust, and in the presence of combination nano-photocatalyst and oxygen so that hard-degraded substance is fully degraded, improve useless Water degradation efficiency, and operation automatically controls, management is convenient.Meanwhile, further separate and recover and make use of by film separation unit Photochemical catalyst.
(4) whole system is controlled by PLC unit, operational excellence, is easy to control.
Brief description of the drawings
Fig. 1 is combined type sewage treatment equipment flow chart of the present utility model.
Identified in figure:1- intake pumps, 2- coagulative precipitation tanks, 3- biological Aerobic Ponds, 4- integrated photo-catalytic oxidations-film Separate reactor, 5- counter-infiltration systems, 6- agitators, 7- polymeric aluminium ferrum silicate chemicals dosing plants, 8- fillers, 9- ultraviolet sources, 10- Nano-photocatalyst, 11- membrane modules, 12- micro-hole aerators, 13- aerators, 14- delivery ports.
Below in conjunction with the drawings and specific embodiments, the utility model is described in further detail.
Embodiment
The technical scheme in the utility model embodiment is clearly and completely described below, it is clear that described reality It is only a part of embodiment of the utility model to apply example, rather than whole embodiments.Based on embodiment of the present utility model, sheet The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to this practicality New protection domain.
The utility model embodiment provides a kind of combined type sewage treatment equipment, and its structure includes coagulative precipitation tank 2, biological Contact-oxidation pool 3, integrated photo-catalytic oxidation-membrane separation reactor 4, counter-infiltration system 5.
Sewage is entered by intake pump 1 sets agitator 6 and polymeric silicicacid in coagulative precipitation tank 2, the coagulative precipitation tank 2 Ferro-aluminum chemicals dosing plant 7, the delivery port of the coagulative precipitation tank 2 connects the water inlet of biological contact oxidation pond 3, the biological Oxidation pond includes pond body and filler 8, and the filler 8 is semi-soft bat wool, is hung in pond body, the volume of filler is accounted for The 70-85% of tank volume, bottom of pond is equipped with micro-hole aerator 12.The biofilm amount of the filler is 220kg/m3To 380kg/m3, it is right Different quality object selects suitable biological bacteria, biological bacteria is in filler surface raised growth using means are targetedly tamed Breeding, forms biomembrane, the pollutant based on BOD, COD is removed in this step, while going to denitrogenate phosphorus.
The delivery port of biological contact oxidation pond 3 is integrally connected the water inlet of formula photochemical catalytic oxidation-membrane separation reactor 4, institute State and nanomorphic photochemical catalyst 10 has been delivered in photocatalysis-membrane separation reactor 4, interior uniform ultraviolet source 9, reactor bottom is provided with Aerator 13, the nanomorphic photochemical catalyst 10 is in the reactor suspended state, and sewage is after light-catalyzed reaction, then leads to Cross membrane module 11 and carry out UF membrane, the delivery port of membrane module connects the water inlet of counter-infiltration system 5, finally gives clear water.
In above-mentioned integrated photo-catalytic oxidation-membrane separation reactor 4, ultraviolet source 9 is efficient low-pressure, medium-pressure or high pressure mercury Lamp and it is other can efficient transmission ultraviolet light light source, ultraviolet source launch wavelength is 254~365nm, and the efficiency of ultraviolet light is low In 50%.
In above-mentioned integrated photo-catalytic oxidation-membrane separation reactor 4, described nanomorphic photochemical catalyst is nanometer titanium dioxide Titanium catalyst, membrane module is submerged membrane separation assembly.
Further, described counter-infiltration system is two-stage reverse osmosis system, obtains clean after two-pass reverse osmosis UF membrane Water outlet.
In order to prevent fouling membrane, it is provided with backwashing unit in membrane separation device and counter-infiltration system.And in order to more preferable Control whole system, design whole device be controlled by PLC.
Its specific implementation process is:Sewage enters coagulative precipitation tank by intake pump, adds polymeric aluminium ferrum silicate dosing wadding Solidifying agent, fully contact mixing is carried out in agitator, occurs coagulating sedimentation reaction, its water outlet enters biological contact oxidation pond, in pond Biofilm is set in body, and sewage carries out biochemical degradation, by micro-hole aerator oxygen supply and make it that activated sludge and waste water are abundant Contact;Sewage enters integrated photo-catalytic-membrane separation reactor after biochemical reaction, is controlling appropriate aeration quantity and ultraviolet In the case of light source, photocatalysis oxidation reaction is further carried out, then sewage is by the further isolation of purified sewage of film separation unit, And photochemical catalyst is trapped in reactor carries out reuse;Clear water after sewage is separated by membrane module enters into reverse osmosis units One step is purified, and finally gives clean water outlet.Reasonable combination and optimization by above-mentioned technique, realize the height of difficult degradation sewage Effect and advanced treating.
It is described above, only the utility model preferably embodiment, but protection domain of the present utility model is not This is confined to, any one skilled in the art can readily occur in the technical scope that the utility model is disclosed Change or replacement, should all cover within protection domain of the present utility model.Therefore, protection domain of the present utility model should It is defined by the protection domain of claims.

Claims (6)

1. a kind of combined type sewage treatment equipment, it is characterised in that including coagulative precipitation tank, biological contact oxidation pond, integral type Photochemical catalytic oxidation-membrane separation reactor and counter-infiltration system, sewage enter coagulative precipitation tank, the coagulating sedimentation by intake pump Agitator and polymeric aluminium ferrum silicate chemicals dosing plant, the delivery port connection biological contact oxidation pond of the coagulative precipitation tank are set in pond Water inlet, the biological contact oxidation pond include pond body and filler, the filler be semi-soft bat wool, hang on pond In body, the volume of filler accounts for the 70-85% of tank volume, and bottom of pond is equipped with micro-hole aerator;The biological contact oxidation pond goes out The mouth of a river is integrally connected the water inlet of formula photochemical catalytic oxidation-membrane separation reactor, the integrated photo-catalytic oxidation-film separation reaction Nanomorphic photochemical catalyst is delivered in device, interior uniform ultraviolet source, reactor bottom is provided with aerator, and the nanomorphic light is urged Agent is in suspended state in the reactor, and sewage carries out UF membrane, film group after photocatalysis oxidation reaction, then by membrane module The delivery port of part connects the water inlet of counter-infiltration system, finally gives clear water.
2. combined type sewage treatment equipment according to claim 1, it is characterised in that described ultraviolet source is efficiently low Pressure, medium-pressure or high pressure mercury lamp and it is other can efficient transmission ultraviolet light light source, ultraviolet source launch wavelength is 254~365nm, purple The efficiency of outer light is not less than 50%.
3. combined type sewage treatment equipment according to claim 2, it is characterised in that described nanomorphic photochemical catalyst is Nano titanic oxide catalyst, membrane module is submerged membrane separation assembly.
4. combined type sewage treatment equipment according to claim 3, it is characterised in that described counter-infiltration system is two grades Clean water outlet is obtained after counter-infiltration system, two-pass reverse osmosis UF membrane.
5. combined type sewage treatment equipment according to claim 1, it is characterised in that membrane separation device and counter-infiltration system It is provided with backwashing unit.
6. combined type sewage treatment equipment according to claim 5, it is characterised in that whole device is controlled by PLC.
CN201720076378.9U 2017-01-17 2017-01-17 A kind of combined type sewage treatment equipment Active CN206447734U (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473471A (en) * 2017-09-18 2017-12-15 成都恒力达科技有限公司 A kind of sewage purifying and treating device
CN107915309A (en) * 2017-11-30 2018-04-17 安徽工业大学 A kind of method that fine catalyst efficiently separates simultaneously automatic cycle during catalytic oxidation treatment sewage
CN108101281A (en) * 2017-12-20 2018-06-01 上海康盛环保能源科技有限公司 A kind of catalytic ceramics membrane reactor
CN108191150A (en) * 2017-12-29 2018-06-22 武汉恒通源环境工程技术有限公司 A kind of vehicle moving sewage treatment equipment
CN111962209A (en) * 2019-05-20 2020-11-20 中国科学院过程工程研究所 Composite catalytic membrane, photocatalytic oxidation-membrane distillation multi-dimensional sewage treatment system and treatment method
CN116253468A (en) * 2023-03-01 2023-06-13 中建三局绿色产业投资有限公司 A photocatalytic oxidation film system applied to sewage treatment and sewage treatment method
CN118026353A (en) * 2024-03-28 2024-05-14 甘肃自然能源研究所(联合国工业发展组织国际太阳能技术促进转让中心) TiO (titanium dioxide)2Microsphere photocatalysis-microfiltration membrane separation integrated reactor

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473471A (en) * 2017-09-18 2017-12-15 成都恒力达科技有限公司 A kind of sewage purifying and treating device
CN107915309A (en) * 2017-11-30 2018-04-17 安徽工业大学 A kind of method that fine catalyst efficiently separates simultaneously automatic cycle during catalytic oxidation treatment sewage
CN107915309B (en) * 2017-11-30 2020-07-31 安徽工业大学 Method for efficiently separating and automatically circulating powder catalyst in sewage catalytic oxidation treatment process
CN108101281A (en) * 2017-12-20 2018-06-01 上海康盛环保能源科技有限公司 A kind of catalytic ceramics membrane reactor
CN108191150A (en) * 2017-12-29 2018-06-22 武汉恒通源环境工程技术有限公司 A kind of vehicle moving sewage treatment equipment
CN111962209A (en) * 2019-05-20 2020-11-20 中国科学院过程工程研究所 Composite catalytic membrane, photocatalytic oxidation-membrane distillation multi-dimensional sewage treatment system and treatment method
CN116253468A (en) * 2023-03-01 2023-06-13 中建三局绿色产业投资有限公司 A photocatalytic oxidation film system applied to sewage treatment and sewage treatment method
CN118026353A (en) * 2024-03-28 2024-05-14 甘肃自然能源研究所(联合国工业发展组织国际太阳能技术促进转让中心) TiO (titanium dioxide)2Microsphere photocatalysis-microfiltration membrane separation integrated reactor

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