CN206418077U - Biohazard Waste harmless treatment and the special equipment of recycling - Google Patents

Biohazard Waste harmless treatment and the special equipment of recycling Download PDF

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Publication number
CN206418077U
CN206418077U CN201720026827.9U CN201720026827U CN206418077U CN 206418077 U CN206418077 U CN 206418077U CN 201720026827 U CN201720026827 U CN 201720026827U CN 206418077 U CN206418077 U CN 206418077U
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gas
biohazard waste
special equipment
cracking
recycling
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CN201720026827.9U
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Chinese (zh)
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杨成志
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Abstract

The utility model is related to the special equipment of a kind of Biohazard Waste harmless treatment and recycling, including feeder, cracker, the gas heated type screw feeding device with microwave bacteria degermer and the room that deaerates, averager, spray dryer, the cracking still with heating furnace, slag-discharging device, catalytic tower, fractionating column, condensing tower, lift pump, compressor, burner, circulating water cooling tower, PLC controlling organizations and the integrated open frame for support former components.The utility model reasonable in design, automaticity is high, via apparatus and method of the present utility model, and the virus in Biohazard Waste, germ can thoroughly can be killed, and final recycling can be made to the utility in Biohazard Waste, the diesel oil, gasoline and carbon black for having value are obtained, Biohazard Waste is turned waste into wealth, in addition, equipment of the present utility model considers heat integration utilization, capacity usage ratio is high, and processing Biohazard Waste energy consumption is low, except vapor and CO2Discharge is outer, and without other emissions, the feature of environmental protection is good.

Description

Biohazard Waste harmless treatment and the special equipment of recycling
Technical field
The utility model is related to the special equipment and its processing method of a kind of Biohazard Waste processing, more particularly, to one kind Environment is not polluted during processing Biohazard Waste, the virus in Biohazard Waste, germ can thoroughly be killed, and energy Biohazard Waste harmless treatment and the recycling for making final recycling to the utility in Biohazard Waste are special Use device and method.
Background technology
At present, a kind of known medical wastes treatment technologies are killed to the virus in Biohazard Waste, germ Processing, but it carries out final process method to the residue after sterilizing to burn and filling, and environmental-protecting performance is not ideal enough, and can not Final recycling is made to Recyclable therein.
Utility model content
One of the purpose of this utility model is to solve the deficiencies in the prior art there is provided one kind in processing Biohazard Waste Environment is not polluted in journey, the virus in Biohazard Waste, germ can thoroughly be killed, and can be to having in Biohazard Waste Make Biohazard Waste harmless treatment and the special equipment of recycling of final recycling with material.
The two of the purpose of this utility model are to provide a kind of method for treating discarded object harmless treatment and recycling.
The utility model solves the technical scheme that its technical problem used:
Biohazard Waste harmless treatment and the special equipment of recycling, the special equipment include feeder, broken Glassware, the gas heated type screw feeding device with microwave bacteria degermer and the room that deaerates, averager, spray dryer, splitting with heating furnace Solve kettle, slag-discharging device, catalytic tower, fractionating column, condensing tower, lift pump, compressor, burner, circulating water cooling tower, PLC control machines Structure and the integrated open frame for support former components;
The feeder, cracker with microwave bacteria degermer and deaerate room gas heated type screw feeding device feed end into Upper, middle and lower are connected and connect into a semi-closed system;With microwave bacteria degermer and deaerate room gas heated type screw feeding device with Cracking still, slag-discharging device are axially connected, and are combined into a totally-enclosed system, the catalytic tower, fractionation with foregoing semi-closed system Tower, condensing tower order are arranged on cracking still top;
The spray dryer is arranged on the gas heated type screw feeding device top with microwave bacteria degermer and degassing room, institute State averager, lift pump, compressor, burner to be separately mounted in integrated open frame lower frame, averager is connected with degassing room, with Absorb the hydrogen chloride gas for neutralizing the abjection of degassing room;
The averager, slag-discharging device, the cooling water outlet and inlet and circulating water cooling tower of fractionating column and condensing tower are connected with pipeline It is logical;
The PLC controlling organizations respectively with feeder, cracker, the gentle heated type screw feeding device of microwave bacteria degermer drive Move motor, averager, spray dryer, cracking still, slag-discharging device, catalytic tower, fractionating column, lift pump, compressor, burner and follow Ring water cooling tower is connected, by PLC controlling organizations realize charging, particle, feeding, sterilizing, degassing, neutralization, drying, heating, The automatic detection of each technological parameter and control in cracking, deslagging, catalysis, fractionation, condensation process.
It is preferred that, the feeder is broken to avoid the gas leak in discarded object using sealing and micro-negative pressure operation Material in feeder is captured and torn into fragment by glassware squeezes inlet gas heating screw feeding device feed end.
It is preferred that, the microwave bacteria degermer is in the material that will be brought from gas heated type screw feeding device feed end by screw rod In entrained bacterium, virus while make thoroughly to kill, temperature of charge is heated to the technological temperature needed for dechlorination, then by gas Hydrogen chloride gas is introduced averager life by material feeding degassing room removing hydrogen chloride gas by heated type screw feeding device screw rod Into sodium chloride solution.
It is preferred that, the heating arrangements of the spray dryer are provided using the tail gas after gas heated type screw feeding device is heated Xeothermic air-flow, powdering is dried in order to collect and utilize by the sodium chloride solution sent from averager, and will be dried by tail gas When the vapor that produces bring blast pipe into.
It is preferred that, the discharge end of the gas heated type screw feeding device heats the tail gas heating after cracking still by burner, It will continue to be warming up to from the material that comes of degassing room to close on and be sent to cracking still after the technological temperature needed for cracking and cracked, Cracking still uses atmospheric operation, and the cracking gas that material cracking is produced enters catalytic tower, cracks the residue carbon black produced by deslagging Device is discharged.
It is preferred that, cracking gas is converted into low molecule oil gas in catalytic tower and enters fractionating column in the presence of catalyst, distillate Diesel oil component, remaining oil gas separates gasoline component into condensing tower, and fixed gas part is then deposited after pipeline importing compressor compresses Enter air accumulator.
It is preferred that, the PLC controlling organizations include PLC, pressure sensor, temperature sensor, flow sensor, The various data that sensor is collected are shown and gone forward side by side by monitor and actuator, PLC controlling organizations in real time on a monitor Row record, while after the data that these data and PLC are set are compared, instruction, automatic school are sent to actuator Positive implementation deviation amount, makes special equipment keep normal operation, when special equipment breaks down, and PLC controlling organizations will alarm simultaneously Voluntarily start safety device or autostop.
It is preferred that, the PLC controlling organizations are additionally provided with wireless network remote monitoring mechanism.
The method of Biohazard Waste harmless treatment and recycling based on described special equipment, the medical treatment is useless The method of gurry harmless treatment and recycling is as follows:
(1)The Biohazard Waste of reproducible utilization after categorized recovery enters after feeder hopper, and hopper cover is closed, Cracker tears up Biohazard Waste under micro-vacuum state, it is to avoid the air-liquid in Biohazard Waste is excessive;
(2)Biohazard Waste after tearing up is moved backward under the push of gas heated type screw feeding device, in moving process by Microwave bacteria degermer kills virus therein and bacterium and the technological temperature that is heated to needed for dechlorination, into degassing room after medical treatment Hydrogen chloride gas and steam in discarded object are removed and sent into averager in degassing room, are neutralized generation sodium chloride molten Liquid;
(3)The Biohazard Waste for removing gas further pushes and is progressively heated to closing on simultaneously the process warm of cracking backward Push in cracking still and cracked after degree, cracking still uses atmospheric operation, the cracking gas that Biohazard Waste cracking is produced enters Catalytic tower, the residue carbon black that cracking is produced is discharged by slag-discharging device;
(4)Cracking gas is converted into low molecule oil gas in catalytic tower and enters fractionating column, distillate diesel fuel in the presence of catalyst Component, remaining oil gas separates gasoline component into condensing tower, and fixed gas part then is imported to be stored in after compressor compresses and stored up by pipeline Gas tank.
It is preferred that, step(1)Middle Biohazard Waste enters after feed appliance hopper, sprays into medical waste amount of substance 2.0- 3.5% bactericidal agent, synchronous chemistry disinfection during being torn up for negative pressure, the bactericidal agent by following parts by weight raw material Process:10-20 parts of bee glue powder, 1-2 parts of emulsifying agent, 80-100 parts of volume fraction 75-85% alcohol solvents, pH adjusting agent is fitted Amount, the pH value of bactericidal agent is 6-6.8, and the bee glue powder of formula ratio and emulsifying agent are added in alcohol solvent, fully stirred in 25-35 DEG C Mix 0.5-1h to emulsify to form stable mixture system, adjusted and impurity acquisition bactericidal agent, the pH value regulator are filtered off after pH value For citric acid or acetic acid or organic base.
Propolis is the viscous secretion that honeybee gathers from tree bud or bark, and research finds that propolis has the chemical group of complexity Into planting fragrant fat, more than 30 kinds of flavonoids, more than ten including more than 30 and plant aromatic acids etc., propolis is described as " natural Small Drug Storage ", be precious natural wide spectrum antibiotics, have to various bacteria, fungi, germ etc. and significantly suppress and kill work With step(1)The bactericidal agent of the appropriate propolis-containing powder of middle addition(Powder is obtained after propolis suitably purification), utilize its natural wide spectrum Synchronous sterilizing is torn up in antibiotic and sterilizing performance, realization, mitigates the pressure of follow-up second step microwave bacteria degermer physical sterilization, chemical sterilization Organically combined with both physical sterilizations, collaboration, is realized sterilized mutually.
The beneficial effects of the utility model are:The utility model reasonable in design, automaticity is high, via this practicality New apparatus and method, can thoroughly be killed to the virus in Biohazard Waste, germ, and can be in Biohazard Waste Utility makees final recycling, obtains the diesel oil, gasoline and carbon black for having value, Biohazard Waste is become give up into Treasured, in addition, equipment of the present utility model considers heat integration utilization, capacity usage ratio is high, and processing Biohazard Waste energy consumption is low, In addition to vapor and CO2 emission, without other emissions, the feature of environmental protection is good.
Brief description of the drawings
Fig. 1 is the structural representation of special equipment of the present utility model;
Fig. 2 is Fig. 1 left view.
Fig. 3 is the FB(flow block) of Application way of the present utility model.
In figure:The integrated open frames of 1-, 2- electric appliance control boxes, 3- gas heated type screw feeding devices, 4- feeders, 5- uncaps Machine, 6- crackers, 7- microwave bacteria degermers, 8- degassings room, 9- spray dryers, 10- catalytic towers, 11- safety valves, 12- fractionating columns, 13- condensing towers, 14- cracking stills, 15- slag-discharging devices, 16- closures, 17- monitors, 18- cracker motors, 19- feed appliances electricity Machine, 20- heating furnaces, 21- burners, 22- collecting tanks, 23- lift pumps, 24- cooling water pumps, 25- pans, 26- vavuum pumps, 27- compressors, 28- averagers, 29- high-pressure pumps, 30- air accumulators.
Embodiment
Below by specific embodiment, with reference to accompanying drawing, method scheme of the present utility model is described in further detail.
Embodiment 1:
As depicted in figs. 1 and 2, Biohazard Waste harmless treatment of the present utility model and the special of recycling set Standby, the special equipment includes feeder 4, cracker 6, the gas heated type screw feeding device with microwave bacteria degermer 7 and the room 8 that deaerates 3rd, averager 28, spray dryer 9, the cracking still 14 with heating furnace 20, slag-discharging device 15, catalytic tower 10, fractionating column 12, condensing tower 13rd, lift pump 23, compressor 27, burner 21, circulating water cooling tower, PLC controlling organizations and for support former components Integrated open frame 1, cracker 6 driven by cracker electrical equipment 18, and gas heated type screw feeding device 3 is driven by feed appliance motor 19 It is dynamic;
The feeder 4, cracker 6 are connected and are connected into upper, middle and lower with the feed end of gas heated type screw feeding device 3 Into a semi-closed system;Gas heated type screw feeding device 3 is axially connected with cracking still 14, slag-discharging device 15, and is sealed with foregoing half System in combination is closed into a totally-enclosed system, the catalytic tower 10, fractionating column 12, the order of condensing tower 13 are arranged on cracking still 14 Portion;
The spray dryer 9 is arranged on the top of gas heated type screw feeding device 3 with microwave bacteria degermer 7 and degassing room 8, The averager 28, lift pump 23, compressor 27, burner 21 are separately mounted in the integrated lower frame of open frame 1, averager 28 with Degassing room 8 is connected, and the hydrogen chloride gas that degassing room 8 is deviate from is neutralized to absorb;
The averager 28, slag-discharging device 15, fractionating column 12, the cooling water outlet and inlet of condensing tower 13 and circulating water cooling tower are used Pipeline is connected with cooling water pump 24 forms recyclable loop;
The PLC controlling organizations respectively with feeder 4, cracker 6, the gentle heated type screw feeding device of microwave bacteria degermer 7 3rd, averager 28, spray dryer 9, cracking still 14, slag-discharging device 15, catalytic tower 10, fractionating column 12, lift pump 23, compressor 27, Burner 21 and circulating water cooling tower are connected, by PLC controlling organizations realize charging, particle, feeding, sterilizing, degassing, in With the automatic detection of each technological parameter and control in, drying, heating, cracking, deslagging, catalysis, fractionation, condensation process.
Specific to the present embodiment, the feeder 4 is using sealing and micro-negative pressure operation, to avoid the gas in discarded object Let out, be embodied in structure in vitro, the hopper of feeder 4 is automatic by the machine of uncapping 5 provided with closure 16 and machine 5 of uncapping The open and close of closure 16 are controlled, cracker 6 captures the material in feeder 4 simultaneously under the driving of cracker motor 18 Torn into fragment and squeeze the feed end of inlet gas heating screw feeding device 3.
In the scheme of the present embodiment, the microwave bacteria degermer 7 by from the feed end of gas heated type screw feeding device 3 by spiral shell While entrained bacterium, virus are made thoroughly to kill in the material that bar is brought, temperature of charge is heated to needed for dechlorination Technological temperature, then material feeding degassing room 8 removed into hydrogen chloride gas by the screw rod of gas heated type screw feeding device 3, and by chlorination Hydrogen introduces the generation sodium chloride solution of averager 28, and the heating arrangements of the spray dryer 9, which are utilized, heats gas heated type spiral shell Tail gas after bar feed appliance 3 provides xeothermic air-flow, and the sodium chloride solution sent by high-pressure pump 29 from averager 28 is dried to Powdery brings the vapor produced when drying into blast pipe in order to collect and utilize by tail gas.
In the scheme of the present embodiment, the discharge end of the gas heated type screw feeding device 3 heats cracking still by burner 21 Tail gas heating after 14, will continue to be warming up to from the material that comes of degassing room 8 close on the technological temperature needed for cracking after given Enter cracking still 14 to be cracked, cracking still 14 uses atmospheric operation, the cracking gas that material cracking is produced enters catalytic tower 10, catalysis Tower 10 is provided with safety valve 11, and the security for providing catalytic cracking reaction cracks the residue carbon black produced by slag-discharging device 15 Discharge.
In the scheme of the present embodiment, cracking gas is converted into the entrance of low molecule oil gas in catalytic tower 10 in the presence of catalyst Pans 25, are pumped low molecule oil gas into fractionating column 12 by vavuum pump 26, distillate diesel fuel component, remaining oil gas enters condensing tower 13 separate gasoline component, and fixed gas part is then imported after compressor 27 compresses by pipeline and is stored in air accumulator 30.
PLC controlling organizations described in the present embodiment includes PLC, pressure sensor, temperature sensor, flow sensing Device, monitor 17 and actuator, the various data that PLC controlling organizations collect sensor are shown in real time on monitor 17 Come and recorded, while after the data that these data and PLC are set are compared, instruction is sent to actuator, Automatic correction implementation deviation amount, makes special equipment keep normal operation, when special equipment breaks down, and PLC controlling organizations will Alarm simultaneously voluntarily starts safety device or autostop.
On the basis of such scheme, the PLC controlling organizations are additionally provided with wireless network remote monitoring mechanism.For passing through The operation of wireless network remote monitoring special equipment.In the specific installation process of equipment of the present utility model, an electrical equipment is also configured Control cabinet 2 and touch control flow, for circuit arrangement of the present utility model and control.
The utility model reasonable in design, automaticity is high, can be right via apparatus and method of the present utility model Virus, germ in Biohazard Waste can be killed thoroughly, and can make final recycling profit to the utility in Biohazard Waste With acquisition has the diesel oil, gasoline and carbon black of value, Biohazard Waste is turned waste into wealth, in addition, equipment of the present utility model Heat integration utilization is considered, capacity usage ratio is high, and processing Biohazard Waste energy consumption is low, except vapor and carbon dioxide row Put outer, without other emissions, the feature of environmental protection is good.
Embodiment 2:
As shown in figure 3, the method for Biohazard Waste harmless treatment and recycling based on described special equipment, The method of the Biohazard Waste harmless treatment and recycling is as follows:Biohazard Waste enters after the hopper of feeder 4, will Hopper cover is closed, and cracker 6 tears up Biohazard Waste under micro-vacuum state, it is to avoid the air-liquid in Biohazard Waste is excessive, Biohazard Waste after tearing up enters feed appliance and moved backward under the push of gas heated type screw feeding device 3, in moving process Virus therein and bacterium and the technological temperature needed for being heated to dechlorination are killed as microwave bacteria degermer 7, into after degassing room 8 Hydrogen chloride gas and steam in Biohazard Waste are removed and sent into averager 28 in degassing room 8, are neutralized generation chlorine Change sodium solution, the Biohazard Waste for removing gas further pushes and be progressively heated to closing on simultaneously the technological temperature of cracking backward After push to and cracked in cracking still 14, cracking still 14 uses atmospheric operation, and the cracking gas that Biohazard Waste cracking is produced enters Enter catalytic tower 10, the residue carbon black that cracking is produced is discharged by slag-discharging device 15, the effect of cracking gas catalyst in catalytic tower 10 Under be converted into low molecule oil gas into fractionating column 12, distillate diesel fuel component, remaining oil gas separates gasoline component into condensing tower 13, Fixed gas part is then imported after compressor 27 compresses by pipeline and is stored in air accumulator 30.
Specific to the present embodiment, step(1)Middle Biohazard Waste enters after feed appliance hopper, sprays into medical waste material 2.0-3.5% bactericidal agent is measured, synchronous chemistry disinfection during being torn up for negative pressure, the bactericidal agent is by following parts by weight Raw material processing form:10-20 parts of bee glue powder, 1-2 parts of emulsifying agent, 80-100 parts of volume fraction 75-85% alcohol solvents, pH is adjusted Save agent in right amount, the pH value of bactericidal agent is 6-6.8, the bee glue powder of formula ratio and emulsifying agent is added in alcohol solvent, in 25-35 DEG C It is sufficiently stirred for 0.5-1h to emulsify to form stable mixture system, has adjusted and impurity acquisition bactericidal agent, the pH value are filtered off after pH value Conditioning agent is citric acid or acetic acid or organic base.
Embodiment described above is a kind of preferably scheme of the present utility model, not makees any to the utility model Formal limitation, also has other variants and remodeling on the premise of without departing from the method scheme described in claim.

Claims (8)

1. Biohazard Waste harmless treatment and the special equipment of recycling, it is characterised in that:The special equipment includes Feeder, cracker, the gas heated type screw feeding device with microwave bacteria degermer and the room that deaerates, averager, spray dryer, band add The cracking still of hot stove, slag-discharging device, catalytic tower, fractionating column, condensing tower, lift pump, compressor, burner, circulating water cooling tower, PLC controlling organizations and the integrated open frame for support former components;
The feeder, cracker with microwave bacteria degermer and deaerate room gas heated type screw feeding device feed end into it is upper, In, lower be connected and connect into a semi-closed system;Gas heated type screw feeding device with microwave bacteria degermer and the room that deaerates is with splitting Solve kettle, slag-discharging device axially to connect, and a totally-enclosed system be combined into foregoing semi-closed system, the catalytic tower, fractionating column, Condensing tower order is arranged on cracking still top;
The spray dryer be arranged on microwave bacteria degermer and degassing room gas heated type screw feeding device top, it is described in It is separately mounted to device, lift pump, compressor, burner in integrated open frame lower frame, averager is connected with degassing room, to absorb Neutralize the hydrogen chloride gas of degassing room abjection;
The averager, slag-discharging device, the cooling water outlet and inlet and circulating water cooling tower pipeline communication of fractionating column and condensing tower;
Driving of the PLC controlling organizations respectively with feeder, cracker, the gentle heated type screw feeding device of microwave bacteria degermer is electric Machine, averager, spray dryer, cracking still, slag-discharging device, catalytic tower, fractionating column, lift pump, compressor, burner and recirculated water Cooling tower is connected, by PLC controlling organizations realize charging, particle, feeding, sterilizing, degassing, neutralization, drying, heating, cracking, The automatic detection of each technological parameter and control in deslagging, catalysis, fractionation, condensation process.
2. Biohazard Waste harmless treatment according to claim 1 and the special equipment of recycling, its feature exist In:The feeder is using sealing and micro-negative pressure operation, to avoid the gas leak in discarded object, and cracker is by feeder In material capture and torn into fragment and squeeze inlet gas heating screw feeding device feed end.
3. Biohazard Waste harmless treatment according to claim 1 and the special equipment of recycling, its feature exist In:The microwave bacteria degermer is thin entrained by the material that will be brought from gas heated type screw feeding device feed end by screw rod While bacterium, virus are made thoroughly to kill, temperature of charge is heated to the technological temperature needed for dechlorination, then sent by gas heated type screw rod Material feeding degassing room is removed hydrogen chloride gas by glassware screw rod, and hydrogen chloride gas introducing averager generation sodium chloride is molten Liquid.
4. Biohazard Waste harmless treatment according to claim 1 and the special equipment of recycling, its feature exist In:The heating arrangements of the spray dryer provide xeothermic air-flow using the tail gas after gas heated type screw feeding device is heated, will The sodium chloride solution sent from averager dries powdering in order to collect and utilize, and is steamed the water produced when drying by tail gas Gas brings blast pipe into.
5. Biohazard Waste harmless treatment according to claim 1 and the special equipment of recycling, its feature exist In:The discharge end of the gas heated type screw feeding device is heated the tail gas heating after cracking still by burner, will be from degassing room mistake The material come, which continues to be warming up to close on, to be sent to cracking still after the technological temperature needed for cracking and is cracked, and cracking still is using normal Press operation, the cracking gas that material cracking is produced enters catalytic tower, and the residue carbon black that cracking is produced is discharged by slag-discharging device.
6. Biohazard Waste harmless treatment according to claim 1 and the special equipment of recycling, its feature exist In:Cracking gas is converted into low molecule oil gas in catalytic tower and enters fractionating column in the presence of catalyst, distillate diesel fuel component, remaining Oil gas separates gasoline component into condensing tower, and fixed gas part is then stored in air accumulator after pipeline importing compressor compresses.
7. Biohazard Waste harmless treatment according to claim 1 and the special equipment of recycling, its feature exist In:The PLC controlling organizations include PLC, pressure sensor, temperature sensor, flow sensor, monitor and execution Device, the various data that PLC controlling organizations collect sensor show and recorded in real time on a monitor, simultaneously will After the data that these data are set with PLC are compared, instruction is sent to actuator, automatic correction implementation deviation amount, Special equipment is set to keep running well, when special equipment breaks down, PLC controlling organizations will alarm and voluntarily start safety and fill Put or autostop.
8. Biohazard Waste harmless treatment according to claim 7 and the special equipment of recycling, its feature exist In:The PLC controlling organizations are additionally provided with wireless network remote monitoring mechanism.
CN201720026827.9U 2017-01-11 2017-01-11 Biohazard Waste harmless treatment and the special equipment of recycling Withdrawn - After Issue CN206418077U (en)

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CN201720026827.9U CN206418077U (en) 2017-01-11 2017-01-11 Biohazard Waste harmless treatment and the special equipment of recycling

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Application Number Priority Date Filing Date Title
CN201720026827.9U CN206418077U (en) 2017-01-11 2017-01-11 Biohazard Waste harmless treatment and the special equipment of recycling

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106701139B (en) * 2017-01-11 2018-08-07 杨成志 The special equipment and method of Biohazard Waste harmless treatment and recycling
CN108994050A (en) * 2018-07-23 2018-12-14 安徽中陆环保设备科技有限公司 A kind of rubbish processing to be harmless device and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106701139B (en) * 2017-01-11 2018-08-07 杨成志 The special equipment and method of Biohazard Waste harmless treatment and recycling
CN108994050A (en) * 2018-07-23 2018-12-14 安徽中陆环保设备科技有限公司 A kind of rubbish processing to be harmless device and method

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Granted publication date: 20170818

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