CN206285690U - A kind of device for eliminating white cigarette - Google Patents
A kind of device for eliminating white cigarette Download PDFInfo
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- CN206285690U CN206285690U CN201621326498.1U CN201621326498U CN206285690U CN 206285690 U CN206285690 U CN 206285690U CN 201621326498 U CN201621326498 U CN 201621326498U CN 206285690 U CN206285690 U CN 206285690U
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Abstract
本实用新型公开了一种消除白烟的装置,包括:水加热器,设置在热烟气管路上;脱硫、湿式静电除尘器,设置经过水加热器后的热烟气管路上;烟气冷凝器,设置在经过脱硫、湿式静电除尘器后的热烟气管路上;空气加热器,通过循环热水泵、循环热水管路与水加热器连接;冷却塔,通过循环冷却水泵、循环冷却水管路与烟气冷凝器连接;热空气管道,设置在烟囱内,其进口端与空气加热器的热风出口端连接。本实用新型采用循环冷却水喷淋冷凝工艺将湿烟气中的水汽减少70~80%,在烟囱内再被加入的热空气混合、加热、干燥后排向大气,热空气的热源采用循环热水工艺,与自烟换热法相比,具有烟气阻力小、能耗低、可靠性高的优点。
The utility model discloses a device for eliminating white smoke, which comprises: a water heater arranged on the hot flue gas pipeline; a desulfurization and wet electrostatic precipitator arranged on the hot flue gas pipeline passing through the water heater; the flue gas condensing The device is set on the hot flue gas pipeline after desulfurization and wet electrostatic precipitator; the air heater is connected with the water heater through the circulating hot water pump and the circulating hot water pipeline; the cooling tower is connected with the circulating cooling water pump and the circulating cooling water pipe The road is connected with the flue gas condenser; the hot air pipe is arranged in the chimney, and its inlet end is connected with the hot air outlet end of the air heater. The utility model adopts the circulating cooling water spray condensation process to reduce the water vapor in the wet flue gas by 70-80%, and the hot air added in the chimney is mixed, heated and dried, and discharged to the atmosphere. The heat source of the hot air adopts circulating heat Compared with the self-smoke heat exchange method, the water process has the advantages of small flue gas resistance, low energy consumption, and high reliability.
Description
技术领域technical field
本实用新型涉及烟气净化技术领域,特别涉及该领域中用于消除燃煤及石化能源后所产生的烟气的一种净化装置。The utility model relates to the technical field of flue gas purification, in particular to a purification device for eliminating the flue gas generated after burning coal and petrochemical energy in this field.
背景技术Background technique
由于我国富煤贫油少气的能源资源禀赋,加之单位热量煤价远远低于油价气价,致使每年40多亿吨原煤,绝大多数通过燃烧转化为冶金、电力、化工等行业的高温热源、动力蒸汽、工艺蒸汽,每年产生大约30多万亿立方米的烟气。现有技术中,烟气净化治理过程中,大部分采用湿法脱硫或湿式静电除尘技术,该技术脱除了烟气中大部分的SO2、烟尘、氮氧化物、重金属,有一定的积极效果。部分企业的烟气治理,还能达到远低于《(GB13223-2011)火电厂大气污染物排放标准》:粉尘≤5mg/m3,二氧化硫≤35mg/m3,氮氧化物(以NO2计)≤50mg/m3,汞≤0.03mg/m3,黑度≤1度指标的燃气轮机排汽标准,为我国的煤炭能源的清洁利用提供了重要保障。Due to my country's energy resource endowment rich in coal, poor in oil and little gas, and the price of coal per unit of heat is far lower than the price of oil and gas, resulting in more than 4 billion tons of raw coal per year, most of which are converted into high-temperature heat in metallurgy, electric power, and chemical industries through combustion. Heat sources, power steam, and process steam produce about 30 trillion cubic meters of flue gas every year. In the prior art, wet desulfurization or wet electrostatic precipitation technology is mostly used in the process of flue gas purification and treatment. This technology removes most of SO2, soot, nitrogen oxides, and heavy metals in the flue gas, and has certain positive effects. The flue gas treatment of some enterprises can reach far below the "(GB13223-2011) Thermal Power Plant Air Pollutant Emission Standard": dust ≤ 5mg/m3, sulfur dioxide ≤ 35mg/m3, nitrogen oxides (calculated as NO2) ≤ 50mg /m3, mercury ≤ 0.03mg/m3, and gas turbine exhaust standards with blackness ≤ 1 degree index provide an important guarantee for the clean utilization of coal energy in my country.
然而烟气净化治理过程中的湿法脱硫或湿式静电除尘,却大量增加了烟气的水汽,达到10~20%浓度,不仅消耗水资源,而且尤其在气温较低、湿度较大的静风天气,烟气中大量的水汽在冷空气的作用下,迅速冷凝为微小的水滴,烟气中CO2等高浓度酸性气体,则伴随着微小水滴形成与成长,不断溶解在水滴之中,并降低水滴表面的水蒸汽分压,使水滴快速长大,成为浓浓的酸性白烟,酸性白烟再被空气中的PM霾粒吸附,会进一步降低其表面的水蒸汽分压,降低空气湿度,并达到其相对稳定的相平衡状态,成为污染环境的雾霾,这就是人们将烟囱冒出的白烟视为雾霾帮凶的原因。因此,尤其在冬季的静风天气,减少烟囱排除的白烟,十分有助于减轻雾霾,这已成为业界共识。However, the wet desulfurization or wet electrostatic precipitator in the process of flue gas purification and treatment has greatly increased the water vapor in the flue gas, reaching a concentration of 10-20%. Under the action of cold air, a large amount of water vapor in the flue gas is rapidly condensed into tiny water droplets, and high-concentration acid gases such as CO2 in the flue gas, along with the formation and growth of tiny water droplets, are continuously dissolved in the water droplets and reduced. The water vapor partial pressure on the surface of the water droplets makes the water droplets grow rapidly and becomes thick acidic white smoke. The acidic white smoke is then absorbed by the PM haze particles in the air, which will further reduce the water vapor partial pressure on the surface and reduce the air humidity. And reach its relatively stable phase equilibrium state, become the smog that pollutes the environment, which is why people regard the white smoke from the chimney as the accomplice of the smog. Therefore, especially in the calm windy weather in winter, reducing the white smoke discharged from the chimney is very helpful to reduce smog, which has become a consensus in the industry.
现行消除白烟常用的方法,本质上就是让出烟囱的烟气在与空气的混合、冷却、扩散过程中,温度还未降到水蒸汽的露点温度以下,就使烟气和其中的水汽扩散到了空气之中。因此,对烟气进行减湿、加温,就是消除烟气白烟的物理基础,常用的方法有:The current method commonly used to eliminate white smoke is essentially to allow the flue gas and the water vapor in it to diffuse before the temperature drops below the dew point temperature of the water vapor during the process of mixing, cooling and diffusing the flue gas out of the chimney with the air. into the air. Therefore, dehumidifying and heating the flue gas is the physical basis for eliminating the white smoke of the flue gas. The commonly used methods are:
①冷凝换热法,见附图1,就是将湿烟气温度从50~60℃降到25左右℃,使烟气中的水汽冷凝为液态水分离出烟气系统,再用换热器将烟气加热后通过烟囱排向大气。但该法有换热器投资大、烟气阻力大、易腐蚀、可靠性、稳定性差的不足。①Condensation heat exchange method, see attached drawing 1, is to lower the temperature of wet flue gas from 50-60°C to about 25°C, condense the water vapor in the flue gas into liquid water and separate the flue gas system, and then use the heat exchanger to After the flue gas is heated, it is discharged to the atmosphere through the chimney. However, this method has the disadvantages of large heat exchanger investment, large flue gas resistance, easy corrosion, poor reliability and stability.
②自烟换热法,见附图2,就是利用脱硫前干烟气的温度,加热脱硫、或湿式静电除尘器后的湿烟气达到80℃以上,该技术不需要外供热源,普遍应用于电力行业,投运初期换热器换热系数高,能够将湿烟气达到80℃以上,大约运行1~3年后,烟气中的胶体、固体微粒附着于换热器表面,最终致使换热系数大幅降低,烟气温度上不去,烟囱照样冒白烟,同时也还有换热器易堵塞、易损坏、烟气阻力大的不足。② Self-smoke heat exchange method, see attached figure 2, is to use the temperature of dry flue gas before desulfurization to heat desulfurization or wet flue gas after wet electrostatic precipitator to reach 80°C or above. This technology does not require external heat source, and is generally Applied in the power industry, the heat exchanger has a high heat transfer coefficient at the initial stage of operation, and can raise the wet flue gas to above 80°C. After about 1 to 3 years of operation, the colloids and solid particles in the flue gas adhere to the surface of the heat exchanger, and finally As a result, the heat transfer coefficient is greatly reduced, the temperature of the flue gas cannot be increased, and the chimney still emits white smoke. At the same time, there are also disadvantages that the heat exchanger is easy to block, easy to be damaged, and the resistance of the flue gas is large.
③电除雾法,由于脱硫后烟气温度下的水汽含量处于饱状态,绝大部分水汽还是以气态存在,并无大量雾滴,所以除雾效果不佳,也还有设备投资大、电耗高、可靠性差等等不足;③Electric demisting method, because the water vapor content at the temperature of the flue gas after desulfurization is in a saturated state, most of the water vapor still exists in a gaseous state, and there are no large amounts of fog droplets, so the demisting effect is not good, and there are also large investment in equipment and electricity. High power consumption, poor reliability, etc.;
④混合干燥法,仅是先将雾状水分离后再混合热烟气,以降低水气含量后再排放,该法需要有干净的热烟气,由于现实中的热烟气尘含量都较高,虽能减少白烟,但却增加了烟尘,该法仅可在环保要求不严,且有热烟气的钢铁厂的地方采用。④The mixed drying method is only to separate the mist water and then mix the hot flue gas to reduce the water vapor content before discharging. This method requires clean hot flue gas, because the dust content of hot flue gas in reality is relatively High, although it can reduce white smoke, it increases smoke and dust. This method can only be used in steel plants where environmental protection requirements are not strict and there is hot smoke.
实用新型内容Utility model content
鉴于现行消除白烟的装置和方法存在的换热器换热系数衰减快、易堵塞、易腐蚀,烟气阻力大,不能完全消除白烟,或消除白烟性能不能长时间保持等等不足,本实用新型提出了一种冷凝脱水+热空气混合干燥装置加以解决。In view of the existing devices and methods for eliminating white smoke, the heat transfer coefficient of the heat exchanger is fast attenuated, easy to block, easy to corrode, and the resistance of the flue gas is large, so that the white smoke cannot be completely eliminated, or the performance of eliminating white smoke cannot be maintained for a long time, etc., The utility model proposes a condensation dehydration + hot air mixed drying device to solve the problem.
本实用新型通过以下技术方案来实现:The utility model is realized through the following technical solutions:
一种消除白烟的装置,包括:A device for eliminating white smoke, comprising:
水加热器,设置在热烟气管路上;Water heater, set on the hot flue gas pipeline;
脱硫、湿式静电除尘器,设置经过水加热器后的热烟气管路上;Desulfurization and wet electrostatic precipitators are installed on the hot flue gas pipeline after passing through the water heater;
烟气冷凝器,设置在经过脱硫、湿式静电除尘器后的热烟气管路上;The flue gas condenser is installed on the hot flue gas pipeline after desulfurization and wet electrostatic precipitator;
空气加热器,通过循环热水泵、循环热水管路与水加热器连接,构成循环体;The air heater is connected with the water heater through the circulating hot water pump and the circulating hot water pipeline to form a circulating body;
冷却塔,通过循环冷却水泵、循环冷却水管路与烟气冷凝器连接,构成循环体;The cooling tower is connected with the flue gas condenser through the circulating cooling water pump and the circulating cooling water pipeline to form a circulating body;
热空气管道,设置在烟囱内,其进口端与空气加热器的热风出口端连接。The hot air pipeline is arranged in the chimney, and its inlet end is connected with the hot air outlet end of the air heater.
进一步地,所述空气加热器的进风口处还设置有风机。Further, a fan is also provided at the air inlet of the air heater.
进一步地,所述冷却塔内设置有烟气冷凝循环水布水装置和烟气冷凝循环水填料,所述烟气冷凝循环水布水装置设置在冷却塔内的进水口下端处,所述烟气冷凝循环水填料设置在烟气冷凝循环水布水装置下端。Further, the cooling tower is provided with a flue gas condensed circulating water distribution device and a flue gas condensed circulating water filler, the flue gas condensed circulating water distribution device is arranged at the lower end of the water inlet in the cooling tower, the flue gas The gas condensate circulating water packing is arranged at the lower end of the flue gas condensate circulating water distribution device.
进一步地,还包括水池隔墙和填料隔墙,所述水池隔墙设置冷却塔下部所形成的水池内,所述填料隔墙设置在烟气冷凝循环水填料Further, it also includes a water pool partition wall and a filler partition wall, the water pool partition wall is arranged in the water pool formed at the lower part of the cooling tower, and the filler partition wall is arranged in the flue gas condensation circulating water filler
进一步地,所述热空气管道顺着烟囱方向垂直布置。Further, the hot air duct is arranged vertically along the direction of the chimney.
本实用新型在烟囱内设了置垂直向上的热空气管道,在烟囱外设置风机和空气加热器,在脱硫前的干烟气通道上设置水加热器;在水加热器和空气加热器之间,设置循环热水泵和循环热水管路,组成热水循环回路结构;用热空气管路连接烟囱内的热空气管道和和空气加热器;在烟气冷凝器外部设置冷却塔,通过循环冷却水泵、循环冷却水管路将冷却塔和烟气冷凝器连接,组成冷却水循环回路结构。The utility model is provided with a vertically upward hot air pipe in the chimney, a fan and an air heater are arranged outside the chimney, and a water heater is arranged on the dry flue gas channel before desulfurization; between the water heater and the air heater , set up a circulating hot water pump and a circulating hot water pipeline to form a hot water circulation loop structure; use a hot air pipeline to connect the hot air pipeline in the chimney and the air heater; set a cooling tower outside the flue gas condenser, and cool it through circulation The water pump and circulating cooling water pipeline connect the cooling tower and the flue gas condenser to form a cooling water circulation loop structure.
由于采用了上述结构,本实用新型冷却塔出口气中CO2、SO2、NOX、烟尘等的浓度远低于烟气数百倍,雾滴表面的水蒸汽分压远高于烟气雾滴的中水蒸汽分压,所以,从冷却塔进入大气的水蒸汽雾滴会更快的消散在大气中,从而将大大减少雾霾的形成;此外,由于烟气与冷却水直接接触,热量主要是通过水蒸汽直接溶解的传质方式,将热量带入冷却水中,不仅传热膜系数高,避免了传热系数K值降低的难题、而且烟气流动阻力远比换热器小,可减少烟气风机电耗,有助于进一步降低烟气中SO2、NOX、Hg、烟尘等有害物质的影响。Due to the adoption of the above structure, the concentration of CO 2 , SO 2 , NO X , smoke dust, etc. in the outlet gas of the cooling tower of the utility model is much lower than that of the smoke by hundreds of times, and the partial pressure of water vapor on the surface of the mist is much higher than that of the smoke Therefore, the water vapor droplets entering the atmosphere from the cooling tower will dissipate faster in the atmosphere, which will greatly reduce the formation of haze; in addition, due to the direct contact between the flue gas and the cooling water, the heat Mainly through the mass transfer method of direct dissolution of water vapor, the heat is brought into the cooling water. Not only the heat transfer film coefficient is high, the problem of reducing the heat transfer coefficient K value is avoided, but also the flow resistance of the flue gas is much smaller than that of the heat exchanger, which can Reducing the power consumption of the flue gas fan will help to further reduce the impact of harmful substances such as SO 2 , NO X , Hg, and smoke in the flue gas.
附图说明Description of drawings
图1为现行的冷凝换热法除白烟工艺原理图;Fig. 1 is the schematic diagram of the existing condensation heat exchange method for removing white smoke;
图2为现行的白烟换热法除白烟工艺原理图;Fig. 2 is the schematic diagram of the existing white smoke heat exchange method for removing white smoke;
图3为本实用新型结构原理图。Fig. 3 is a structural principle diagram of the utility model.
具体实施方式detailed description
下面结合附图及具体实施方式对本实用新型做进一步说明。The utility model will be further described below in conjunction with the accompanying drawings and specific embodiments.
为了使本实用新型的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本实用新型进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本实用新型,并不用于限定本实用新型。In order to make the purpose, technical solution and advantages of the utility model clearer, the utility model will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the utility model, and are not intended to limit the utility model.
本实用新型公开了一种消除白烟的装置,系现有白烟消除装置的改进,包括:The utility model discloses a device for eliminating white smoke, which is an improvement of the existing device for eliminating white smoke, including:
水加热器,设置在热烟气管路上;Water heater, set on the hot flue gas pipeline;
脱硫、湿式静电除尘器,设置经过水加热器后的热烟气管路上;Desulfurization and wet electrostatic precipitators are installed on the hot flue gas pipeline after passing through the water heater;
烟气冷凝器,设置在经过脱硫、湿式静电除尘器后的热烟气管路上;The flue gas condenser is installed on the hot flue gas pipeline after desulfurization and wet electrostatic precipitator;
空气加热器,通过循环热水泵、循环热水管路与水加热器连接,构成循环体;The air heater is connected with the water heater through the circulating hot water pump and the circulating hot water pipeline to form a circulating body;
冷却塔,通过循环冷却水泵、循环冷却水管路与烟气冷凝器连接,构成循环体;The cooling tower is connected with the flue gas condenser through the circulating cooling water pump and the circulating cooling water pipeline to form a circulating body;
热空气管道,设置在烟囱内,其进口端与空气加热器的热风出口端连接。The hot air pipeline is arranged in the chimney, and its inlet end is connected with the hot air outlet end of the air heater.
在本实施例中,烟气冷凝器结构为空塔喷淋结构,或填料结构,在出气端设有气液分离结构。In this embodiment, the structure of the flue gas condenser is an empty tower spray structure, or a packing structure, and a gas-liquid separation structure is provided at the gas outlet.
本实用新型的使用方法如下:The using method of the present utility model is as follows:
在气温30℃以上时,即使水汽浓度13%左右的烟气从烟囱进入大气,由于水蒸汽在大气中扩散速率大,也不会出现白烟,此时可停下风机、循环冷却水泵和循环热水泵,以节约动力电消耗;When the temperature is above 30°C, even if the flue gas with a water vapor concentration of about 13% enters the atmosphere from the chimney, due to the high diffusion rate of water vapor in the atmosphere, white smoke will not appear. At this time, the fan, circulating cooling water pump and circulating cooling water pump can be stopped. Hot water pump to save power consumption;
在气温不太高时,例如25℃左右,湿度较大的天气,烟气略有白烟,此时可仅开启风机,让常温空气在烟囱内先与湿烟气混合,降低烟气中的水汽浓度,即可消除烟囱出口烟气中的白烟;When the temperature is not too high, such as around 25°C and the humidity is high, the flue gas has a slight white smoke. At this time, only the fan can be turned on, so that the normal temperature air can be mixed with the wet flue gas in the chimney to reduce the humidity in the flue gas. The water vapor concentration can eliminate the white smoke in the flue gas at the chimney outlet;
在气温较低时,例如15℃左右,湿度也大的天气,则要同时开启风机和循环热水泵,使干烟气的热量通过循环水转移到热空气中,从而减少烟气在脱硫或湿式静电除尘工艺吸收的水量,热空气在烟囱内与湿烟气混合,又进一步降低烟气中的相对湿度,即可消除烟囱出口的白烟;When the temperature is low, such as around 15°C and the humidity is high, the fan and the circulating hot water pump should be turned on at the same time, so that the heat of the dry flue gas can be transferred to the hot air through the circulating water, thereby reducing the flue gas in the desulfurization or wet process. The amount of water absorbed by the electrostatic precipitator process, the hot air is mixed with the wet flue gas in the chimney, and the relative humidity in the flue gas is further reduced, which can eliminate the white smoke at the chimney outlet;
在气温很低的冬季,则需同时开启烟气冷凝器和循环冷却水泵、风机和循环热水泵,烟气首先在烟气冷凝器中除去大部分水汽后,烟气再在烟囱内与热空气混合干燥后排入大气,即可消除白烟。In winter when the temperature is very low, it is necessary to turn on the flue gas condenser and the circulating cooling water pump, fan and circulating hot water pump at the same time. After mixing and drying, it is discharged into the atmosphere to eliminate white smoke.
上述实施例只是本实用新型的较佳实施例,并不是对本实用新型技术方案的限制,只要是不经过创造性劳动即可在上述实施例的基础上实现的技术方案,均应视为落入本实用新型专利的权利保护范围内。The above-described embodiments are only preferred embodiments of the present utility model, and are not limitations to the technical solutions of the present utility model. As long as the technical solutions that can be realized on the basis of the above-mentioned embodiments without creative work, all should be regarded as falling into the scope of this invention. within the protection scope of utility model patents.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106512637A (en) * | 2016-12-06 | 2017-03-22 | 四川省简阳空冷器制造有限公司 | Device and method for removing white smoke |
| CN107433118A (en) * | 2017-07-21 | 2017-12-05 | 上海交通大学 | A kind of system and method for desulfurization fume eliminating white smoke |
| CN108380033A (en) * | 2018-04-25 | 2018-08-10 | 福建鑫泽环保设备工程有限公司 | Flue gas desulfurization condensation dedusting takes off white integral system and its application method |
| CN108579420A (en) * | 2018-05-21 | 2018-09-28 | 襄阳泽东化工集团有限公司 | Nitrate produces the processing system and treatment process of tail gas |
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2016
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106512637A (en) * | 2016-12-06 | 2017-03-22 | 四川省简阳空冷器制造有限公司 | Device and method for removing white smoke |
| CN106512637B (en) * | 2016-12-06 | 2019-03-26 | 四川省简阳空冷器制造有限公司 | A device and method for eliminating white smoke |
| CN107433118A (en) * | 2017-07-21 | 2017-12-05 | 上海交通大学 | A kind of system and method for desulfurization fume eliminating white smoke |
| CN108380033A (en) * | 2018-04-25 | 2018-08-10 | 福建鑫泽环保设备工程有限公司 | Flue gas desulfurization condensation dedusting takes off white integral system and its application method |
| CN108579420A (en) * | 2018-05-21 | 2018-09-28 | 襄阳泽东化工集团有限公司 | Nitrate produces the processing system and treatment process of tail gas |
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