CN206266515U - A kind of coupling prepares the system without tar coal gas and calcium carbide - Google Patents

A kind of coupling prepares the system without tar coal gas and calcium carbide Download PDF

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Publication number
CN206266515U
CN206266515U CN201621364151.6U CN201621364151U CN206266515U CN 206266515 U CN206266515 U CN 206266515U CN 201621364151 U CN201621364151 U CN 201621364151U CN 206266515 U CN206266515 U CN 206266515U
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China
Prior art keywords
semicoke
entrance
calcium carbide
furnace
tar
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CN201621364151.6U
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Chinese (zh)
Inventor
许修强
董宾
张顺利
郭启海
赵小楠
任爱林
吴道洪
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Shenwu Environmental Technology Co Ltd
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Shenwu Environmental Technology Co Ltd
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Abstract

The utility model is related to coupling to prepare the system without tar coal gas and calcium carbide.The system includes descending bed gasification furnace, arrangement for catalytic purification, mixing arrangement, high temp modeling appts, furnace of calcium carbide;Descending bed gasification furnace includes that coal entrance, gasification agent inlet, gas exit containing tar, semicoke 1 are exported;Arrangement for catalytic purification includes the entrance of semicoke 1, gas entry containing tar, is exported without tar gas exit, semicoke 2, and the entrance of semicoke 1 is connected with the outlet of semicoke 1;Mixing arrangement includes the entrance of semicoke 2, hot CaO entrances, binding agent entrance, mixed powder outlet, and the entrance of semicoke 2 is connected with the outlet of semicoke 2;High temp modeling appts include mixed powder entrance, mixing moulding mixture outlet, and mixed powder entrance is connected with mixed powder outlet;Furnace of calcium carbide includes mixing moulding mixture entrance, calcium carbide outlet, high temperature calcium carbide furnace gas export, and mixing moulding mixture entrance is connected with mixing moulding mixture outlet.The utility model can make full use of the sensible heat of semicoke and high temperature calcium carbide furnace gas, and high degree reduces loss.

Description

A kind of coupling prepares the system without tar coal gas and calcium carbide
Technical field
The utility model is related to calcium carbide technical field of smelting, and in particular to a kind of coupling is prepared without tar coal gas and calcium carbide System.
Background technology
The coking of coal, gasification, synthesis calcium carbide process, for organic chemical industry's industry provides abundant crude benzol, tar, coke oven Gas, synthesis gas and acetylene, are three core pathways of Coal Chemical Industry.At present, coking of coal technological investment high cost, product purification be not Foot, added value of product be not high.Coal Gasification Technology progress is slow, efficiency is low, small scale, industrialization level are low.And synthesize calcium carbide Technique, route is simple, added value of product is high, good in economic efficiency, has been carried out large-scale industrial production, is that one kind compares and has hair Open up the clean coal technology of potentiality and the approach of Coal Chemical Industry.The calcium carbide (i.e. acetylene) of preparation can be used to synthesize benzene, rubber, polychlorostyrene second The organic products such as alkene, polyacetylene.Compared with oil ethene route, coal synthesis calcium carbide has that raw material sources are extensive, cheap, sets The low advantage of standby investment.Also, acetylene is higher than ethylene action, more conducively the carrying out of organic synthesis.
At present, calcium carbide synthetic method is mainly electrothermal way.The method converts electrical energy into heat energy by electric arc furnaces, and heating is molten Melt lime and carbon raw coke, combination reaction occurs and produces calcium carbide.Electrothermal way is with a long history, with high energy consumption, high pollution Shortcoming.Calcium carbide synthetic reaction is the solid phase endothermic reaction, and raw material mass-and heat-transfer efficiency is low, the chemical dynamics process time it is long, it is necessary to The heating of (2000~2200 DEG C) of high temperature, and high activity coke as raw material.The high temperature heating conditions need substantial amounts of energy, right The heat resistance requirement of equipment is high, and increased cost of investment and energy consumption.Raw coke is typically obtained by the coking of coal, flow Long, organic carbon depletion is high, power consumption is high, environmental pollution is serious.In order to improve containing for calcium carbide in lime-calcium carbide congruent melting speed and product Amount, typically lime excess 20wt% (wt% is mass percent) is required in practical operation, and material consumption and energy consumption are larger.Accessory substance one Carbonoxide effusion reaction system has taken away substantial amounts of heat, causes energy loss.
The electrical efficiency and the thermal efficiency for improving furnace of calcium carbide are to reduce the power consumption in calcium carbide production at present, and improve capacity usage ratio Two big countermeasures.But, calcium carbide is generated with coke direct reaction because electrothermal way technique is based on lime, it is the solid phase endothermic reaction, Improving electrical efficiency and the thermal efficiency anyway cannot all change the technique high energy consumption, high material-consumption, the present situation of high pollution.In order to improve Calcium carbide production energy, the greenization and sustainable development of realizing calcium carbide production, it is necessary to reform electrothermal way synthetic route, using new Calcium carbide synthesis technique and synthetic method.
Gently the gasify amount of byproduct semicoke of generation of coal accounts for 60~90wt% of product.Semicoke is carried out it is economical, Utilization effectively and reasonably, will improve the economy of whole process, and realize industrialization.Wherein, the property of semicoke is depended primarily on The species of coal, ash content and reaction condition etc..
In down-flow fluidized bed using ECT gasification reaction, coal dust autopneumatolysis furnace roof portion is sent into by induction system, with the gasifying agent being passed through by top It is parallel to move downward and haptoreaction, can typically stop the time of several seconds.In the course of reaction, gasification temperature is relatively low, coal dust exists The residence time is shorter in gasification furnace, efficiency of carbon con version is relatively low, contain a large amount of unreacted carbon in residue after gasifying.It is with vapor During gasifying agent, after gasification reaction production hydrogen-rich synthetic gas are carried out in a low temperature of 950 DEG C, (gasification is residual for solid product gasification char Slag) in the still carbon containing 60wt%.At present, gasification char is generally used for combustion power generation, and the level of resources utilization is relatively low.
Middle low-order coal reactivity is higher, rich in volatile matter, is gasified at relatively low temperatures and pressures, can produce more Tar.Influence of the tar to gasification system and gas equipment be:1. coal gas of high temperature carry tar in course of conveying gradually Condensation, is attached on pipeline and equipment inner wall, makes line clogging, containing alkali metal or alkaline-earth metal in tar, meeting etching apparatus, Influence system safety operation.2. contain more polyoxybiontic aldehydes matter in gasification tar, cause secondary waste water to pollute.3. gasify burnt Oil accounts for 3~10wt% of coal for gasification total amount, greatly reduces gasification efficiency, tar and gas fuel burning under cryogenic conditions Not exclusively, the badly damaged combustion gas of the carbon black of generation utilizes equipment, and wastes the energy.Therefore, simple gasification power generation system, it is desirable to Tar content is in 20~50mg/Nm3In the range of;Combustion system, it is desirable to which the content of tar is less than 10mg/Nm3;Production of methanol, It is required that the content of tar is less than 0.1mg/Nm3.To realize the target of low-rank coal in low temperature gasification treatment, it is necessary to study gasification Jiao The removal methods of oil.
There is research to point out, semicoke can be as new tar cracking catalyst or catalyst carrier.Semicoke is to tar Removing has catalysis activity very high, and when the gas containing tar is by hot semicoke bed, most of coke tar cracking produces gas Body and water.At 950 DEG C, tar is almost completely converted into low-BTU gas in semicoke.
Utility model content
The purpose of this utility model is that, using the byproduct semicoke 1 of the gentle gasification of coal, semicoke 1 is urged as catalyst Change, purification synthesis gas containing tar removes tar, the semicoke 2 for obtaining prepares the raw material of calcium carbide as smelting, realizes returning for the energy Receive and utilize, be suitable to commercial Application.
The utility model discloses a kind of coupling and prepares the system without tar coal gas and calcium carbide first, under the system includes Row bed gasification furnace, arrangement for catalytic purification, mixing arrangement, high temp modeling appts, furnace of calcium carbide.
The descending bed gasification furnace includes that coal entrance, gasification agent inlet, gas exit containing tar, semicoke 1 are exported.
The arrangement for catalytic purification includes the entrance of semicoke 1, gas entry containing tar, goes out without tar gas exit, semicoke 2 Mouthful.The entrance of the semicoke 1 is exported with the semicoke 1 of the descending bed gasification furnace and is connected by conveying device.
The mixing arrangement includes the entrance of semicoke 1, hot CaO entrances, binding agent entrance, mixed powder outlet.The semicoke 2 Entrance is exported with the semicoke 2 of the arrangement for catalytic purification and is connected by conveying device.
The high temp modeling appts include mixed powder entrance, mixing moulding mixture outlet.The mixed powder entrance with it is described The mixed powder outlet of mixing arrangement is connected by conveying device.
The furnace of calcium carbide includes mixing moulding mixture entrance, calcium carbide outlet, high temperature calcium carbide furnace gas export.The mixing moulding mixture entrance It is connected by conveying device with the mixing moulding mixture outlet of the high temp modeling appts.
In said system, preheater is further included, the preheater has CaO entrances, hot CaO outlets, high temperature calcium carbide Furnace gas entrance, low temperature calcium carbide furnace gas export.The hot CaO outlets pass through conveying device with the hot CaO entrances of the mixing arrangement Connection, the high temperature calcium carbide furnace gas entrance is connected with the high temperature calcium carbide furnace gas export of the furnace of calcium carbide.
Preferably, it is provided with attemperator in the arrangement for catalytic purification, mixing arrangement, high temp modeling appts.It is described Conveying device is heat-insulation conveying device.
The utility model can make full use of the semicoke 1 that the gentle gasification of coal is produced as catalyst, purification containing Jiao Oily synthesis gas, then the semicoke 2 by the use of generation is used as the raw material for preparing calcium carbide.Also, semicoke 1, semicoke 2 and electricity can be made full use of Stone smelts the sensible heat of the high temperature calcium carbide furnace gas for producing, and high degree reduces loss, energy saving.
Brief description of the drawings
Fig. 1 is that the utility model coupling prepares the system schematic without tar coal gas and calcium carbide.
Fig. 2 is that the utility model embodiment prepares the flow without tar coal gas and calcium carbide using the system coupling shown in Fig. 1 Schematic diagram.
Reference in accompanying drawing is as follows:
1st, descending bed gasification furnace;2nd, arrangement for catalytic purification;3rd, preheater;4th, mixing arrangement;5th, high temp modeling appts;6th, electricity Stone stove.
Specific embodiment
Below in conjunction with drawings and Examples, specific embodiment of the present utility model is described in more details, with Just scheme of the present utility model and the advantage of its various aspects be better understood when.However, specific implementations described below Mode and embodiment are only descriptive purposes, rather than to limitation of the present utility model.
As shown in figure 1, preparing the system schematic without tar coal gas and calcium carbide to be coupled in the utility model.In the system Including descending bed gasification furnace 1, arrangement for catalytic purification 2, preheater 3, mixing arrangement 4, high temp modeling appts 5, furnace of calcium carbide 6.Wherein, Annexation between each device is as follows:
Descending bed gasification furnace 1 is used for the gentle gasification of coal, can obtain coal gas containing tar and accessory substance semicoke 1, and it includes coal Entrance, gasification agent inlet, gas exit containing tar, semicoke 1 are exported.
Arrangement for catalytic purification 2 is used for the removing of tar in coal gas containing tar, during by the use of semicoke 1 as catalyst, can obtain Semicoke 2 and without tar coal gas, it includes the entrance of semicoke 1, gas entry containing tar, is exported without tar gas exit, semicoke 2.Its In, the entrance of semicoke 1 is connected with the outlet of semicoke 1 of descending bed gasification furnace 1.
Preheater 3 is used to preheat CaO, can obtain hot CaO, and it includes CaO entrances, hot CaO outlets, high temperature calcium carbide Furnace gas entrance, low temperature calcium carbide furnace gas export.
Mixing arrangement 4 is used for the mixing of semicoke 2 and hot CaO, can obtain mixed powder, and it includes the entrance of semicoke 2, hot CaO Entrance, binding agent entrance, mixed powder outlet.Wherein, the entrance of semicoke 2 is connected with the outlet of semicoke 2 of arrangement for catalytic purification 2, heat CaO entrances are connected with the hot CaO outlets of preheater 3.
High temp modeling appts 5 are used for the high-temperature molding of mixed powder, can obtain mixing moulding mixture, and it includes that mixed powder enters Mouth, mixing moulding mixture outlet.Wherein, mixed powder entrance is connected with the mixed powder outlet of mixing arrangement 4.
Furnace of calcium carbide 6 is used to smelt the mixing moulding mixture formed by semicoke 2 and CaO, can obtain calcium carbide and high temperature calcium carbide Furnace gas, it includes mixing moulding mixture entrance, calcium carbide outlet, high temperature calcium carbide furnace gas export.Wherein, moulding mixture entrance and high-temperature molding are mixed The mixing moulding mixture outlet connection of device 5, high temperature calcium carbide furnace gas export is connected with the high temperature calcium carbide furnace gas entrance of preheater 3.
In the utility model, insulation is provided with above-mentioned arrangement for catalytic purification 2, mixing arrangement 4, high temp modeling appts 5 Device, also, its internal working environment is fire-retardant environment.In said system, solid material between each device unit Conveying is realized by conveying device, and conveying device is set into attemperator, and ensures that conveying device inside is resistance Combustion environment.Setting the purpose of attemperator is, it is ensured that the temperature into the mixing moulding mixture of furnace of calcium carbide 6 is not less than descending bed gasification furnace Lower 100 DEG C of 1 operation temperature.
As shown in Fig. 2 in the utility model embodiment using the system shown in Fig. 1, coupling prepare without tar coal gas and The schematic flow sheet of calcium carbide, including step:
(1) coal gasification
By in coal and the descending bed gasification furnace 1 of gasifying agent feeding, promoting the circulation of qi is entered under normal pressure, 850~1050 DEG C of temperature conditionss Change reaction, obtain coal gas containing tar and accessory substance semicoke 1.
In the utility model embodiment, from 0.6MPa, 200 DEG C of overheated steam as coal gasification reaction gasification Agent.Wherein, vapor accounts for the percentage≤96wt% of coal, preferably≤80wt% in embodiment.
The utility model select in low order low-grade coal as feed coal, its moisture content≤8wt%, content of ashes≤ 10wt%, volatile matter content >=30wt%, specific surface area >=50m2/ g, ash fusion point >=1200 DEG C, particle diameter≤0.5 ㎜, this practicality The coal of preferable particle size≤0.1 ㎜ in new embodiment.
This step is also added into powdery CaO as catalyst, can be catalyzed coal and steam gasification generation hydrogen-rich synthetic gas.And And, particle diameter≤0.5 ㎜ of powdery CaO, embodiment preferable particle size≤0.1 ㎜, the quality of addition account for the percentage of feed coal≤ 5wt%.Content >=95% of CaO, Al in powdery CaO2O3Content≤1%, content≤1% of MgO, SiO2Content≤1%.
(2) tar is removed
The bottom of the self-catalysis of coal gas containing the tar purifier 2 that above-mentioned steps are obtained is passed through, meanwhile, above-mentioned steps are obtained High-temperature semi-coke 1 feeding arrangement for catalytic purification 2 in.Half focus layer of the coal gas containing tar from bottom to top through overheating carries out Catalytic Cracking Unit of Measure Should, tar therein is removed, the discharge of the top without tar coal gas self-catalysis purifier 2 for obtaining.Semicoke 1 is through catalytic cracking After reaction, semicoke 2 is generated.
(3) material mixing
Powdery CaO heats up in preheater 3, obtains hot CaO, and sends into mixing arrangement 4.Meanwhile, above-mentioned steps are obtained Semicoke 2 be also fed into mixing arrangement 4, and be added thereto to binding agent.Hot CaO, semicoke 2, binding agent are mixed in mixing arrangement 4 Close uniform, obtain mixed powder.In the utility model embodiment, the hot CaO, the quality proportioning of semicoke 2, binding agent is controlled to be:1: 0.60~0.70:0.01~0.03.
In this step, binding agent selects dryness, powder binder, and it has the property of good bonding and solidification at high temperature Can, the calorific intensity after mixed powder shaping can be significantly increased.It is with coal as raw material extracted and purified, devolatilization has Machine thing is main body, then allocates the mixture of a certain amount of inorganic matter into.The binding agent in large temperature range have compared with Thermoplasticity high and dispersive property, can be well dispersed in the liquid carbonized of promotion mixed material in semicoke 2, powdery CaO, improve The softening meltbility of semicoke 2, makes the anisotropy tissue of semicoke 2 become flourishing, the final calorific intensity for improving molding materials.
In this step, CaO, semicoke 2, binding agent be by quantitative helix transporting device send into mixing arrangement 4 in, can lead to The amount of material of the revolution of the whole quantitative conveyer of toning to adding is controlled.
Powdery CaO is preheated to >=850 DEG C after add and mixed with semicoke 2 in mixing arrangement 4, can avoid due to temperature Degree difference causes the temperature of semicoke 2 to reduce, and is follow-up calcium carbide smelting process energy saving.Also, the preheating of powdery CaO is to utilize The sensible heat of the high temperature calcium carbide furnace gas of calcium carbide smelting process generation, realizes the recycling of resource.
(4) shaping of mixed powder
In the mixed powder feeding high temp modeling appts 5 that above-mentioned steps are obtained, after carrying out high-temperature molding treatment, can obtain Block mixing moulding mixture, to meet the feed needs of furnace of calcium carbide 6.
(5) calcium carbide is smelted
In the mixing moulding mixture feeding furnace of calcium carbide 6 that will be mixed to get by semicoke 2 and CaO, in 1900~2100 DEG C of temperature strip Smelted under part, can obtain calcium carbide.Meanwhile, the step can also generate high temperature calcium carbide furnace gas.In embodiment, preferably calcium carbide is smelted Temperature is 1950 DEG C.
Because the system shown in Fig. 1 has done isothermal holding, it is ensured that the mixed type material temperature degree of the step is not less than down-flow fluidized bed using ECT Lower 100 DEG C of the operation temperature of gasification furnace 1.
Also, by the step generate high temperature calcium carbide furnace gas be passed through in preheater 3, with powdery CaO carry out direct heat transfer or Indirect heat exchange, makes full use of the sensible heat of high temperature calcium carbide furnace gas.
Embodiment 1
The moisture content of coal dust is that 8%, content of ashes is that 10%, volatile matter content is that 30%, specific surface area is 50m2/ g, ash Fusing point is 1200 DEG C, particle diameter≤0.5 ㎜.CaO content is that 95%, content of MgO is 1%, Al in powdery CaO2O3Content is 0.8%, SiO2Content is 0.3%.By in above-mentioned coal dust, powdery CaO, the descending bed gasification furnace of vapor feeding.In normal pressure, 1050 DEG C of temperature Gasification reaction is carried out under the conditions of degree.Wherein, the percentage that vapor accounts for coal is 96wt%, and powdery CaO accounts for the percentage of feed coal 5wt%.In coal gas containing tar and the feeding arrangement for catalytic purification of semicoke 1 that gasification reaction is obtained, coal gas containing tar is through catalytic cracking After remove tar, the generation semicoke 2 of semicoke 1.During semicoke 2 sent into mixing arrangement, and it is added thereto to the heat that particle diameter is 0.5 ㎜ CaO and binding agent, hot CaO, the quality proportioning of semicoke 2, binding agent are 1:0.70:0.03, uniformly it is mixed to get mixed powder.It is mixed Close powder carries out forming processes in high temp modeling appts, in the mixing moulding mixture feeding furnace of calcium carbide of 955 for obtaining DEG C, at 2100 DEG C Temperature conditionss under carry out calcium carbide smelting, prepare calcium carbide.Meanwhile, to powdery in the high temperature calcium carbide furnace gas feeding preheating furnace of generation CaO carries out pre-heating temperature elevation.
Embodiment 2
The moisture content of coal dust is that 7%, content of ashes is that 6%, volatile matter content is that 35%, specific surface area is 57m2/ g, ash Fusing point is 1220 DEG C, particle diameter≤0.1 ㎜.CaO content is that 97%, content of MgO is 0.5%, Al in powdery CaO2O3Content is 1%, SiO2Content is 1%.During above-mentioned coal dust, powdery CaO, vapor sent into descending bed gasification furnace, in normal pressure, 950 DEG C of temperature Under the conditions of carry out gasification reaction.Wherein, the percentage that vapor accounts for coal is 80wt%, and the percentage that powdery CaO accounts for feed coal is 4wt%.In coal gas containing tar and the feeding arrangement for catalytic purification of semicoke 1 that gasification reaction is obtained, coal gas containing tar is through catalytic cracking After remove tar, the generation semicoke 2 of semicoke 1.During semicoke 2 sent into mixing arrangement, and it is added thereto to the heat that particle diameter is 0.3 ㎜ CaO and binding agent, hot CaO, the quality proportioning of semicoke 2, binding agent are 1:0.65:0.02, uniformly it is mixed to get mixed powder.It is mixed Close powder carries out forming processes in high temp modeling appts, in the mixing moulding mixture feeding furnace of calcium carbide of 890 for obtaining DEG C, at 1950 DEG C Temperature conditionss under carry out calcium carbide smelting, prepare calcium carbide.Meanwhile, to powdery in the high temperature calcium carbide furnace gas feeding preheating furnace of generation CaO carries out pre-heating temperature elevation.
Embodiment 3
The moisture content of coal dust is that 4%, content of ashes is that 7%, volatile matter content is that 36%, specific surface area is 61m2/ g, ash Fusing point is 1250 DEG C, particle diameter≤0.1 ㎜.CaO content is that 96%, content of MgO is 0.2%, Al in powdery CaO2O3Content is 0.7%, SiO2Content is 0.5%.By in above-mentioned coal dust, powdery CaO, the descending bed gasification furnace of vapor feeding.In normal pressure, 850 DEG C temperature conditionss under carry out gasification reaction.Wherein, the percentage that vapor accounts for coal is 64wt%, and powdery CaO accounts for feed coal Percentage 3wt%.In coal gas containing tar and the feeding arrangement for catalytic purification of semicoke 1 that gasification reaction is obtained, coal gas containing tar is through urging Tar, the generation semicoke 2 of semicoke 1 are removed after changing cracking.During semicoke 2 sent into mixing arrangement, and particle diameter is added thereto to for 0.1 ㎜ Hot CaO and binding agent, hot CaO, semicoke 2, binding agent quality proportioning be 1:0.60:0.01, uniformly it is mixed to get mixed powder Material.Mixed powder carries out forming processes in high temp modeling appts, in the mixing moulding mixture feeding furnace of calcium carbide of 890 for obtaining DEG C, Calcium carbide smelting is carried out under 1900 DEG C of temperature conditionss, calcium carbide is prepared.Meanwhile, it is right in the high temperature calcium carbide furnace gas feeding preheating furnace of generation Powdery CaO carries out pre-heating temperature elevation.
Percentage in above-described embodiment is mass percent.
Finally it should be noted that:Obviously, above-described embodiment is only intended to clearly illustrate the utility model example, And not to the restriction of implementation method.For those of ordinary skill in the field, may be used also on the basis of the above description To make other changes in different forms.There is no need and unable to be exhaustive to all of implementation method.And thus Among the obvious change or variation amplified out are still in protection domain of the present utility model.

Claims (3)

1. it is a kind of coupling prepare the system without tar coal gas and calcium carbide, it is characterised in that the system include descending bed gasification furnace, Arrangement for catalytic purification, mixing arrangement, high temp modeling appts, furnace of calcium carbide;
The descending bed gasification furnace includes that coal entrance, gasification agent inlet, gas exit containing tar, semicoke 1 are exported;
The arrangement for catalytic purification includes the entrance of semicoke 1, gas entry containing tar, is exported without tar gas exit, semicoke 2;Institute State the entrance of semicoke 1 and exported with the semicoke 1 of the descending bed gasification furnace and be connected by conveying device;
The mixing arrangement includes the entrance of semicoke 2, hot CaO entrances, binding agent entrance, mixed powder outlet;The entrance of the semicoke 2 Exported with the semicoke 2 of the arrangement for catalytic purification and be connected by conveying device;
The high temp modeling appts include mixed powder entrance, mixing moulding mixture outlet;The mixed powder entrance mixes with described The mixed powder outlet of device is connected by conveying device;
The furnace of calcium carbide includes mixing moulding mixture entrance, calcium carbide outlet, high temperature calcium carbide furnace gas export;Mixing moulding mixture entrance and the institute The mixing moulding mixture outlet for stating high temp modeling appts is connected by conveying device.
2. system according to claim 1, it is characterised in that also including preheater, the preheater have CaO entrances, Hot CaO outlets, high temperature calcium carbide furnace gas entrance, low temperature calcium carbide furnace gas export;The hot CaO exports the heat with the mixing arrangement CaO entrances are connected by conveying device, and the high temperature calcium carbide furnace gas entrance connects with the high temperature calcium carbide furnace gas export of the furnace of calcium carbide Connect.
3. system according to claim 2, it is characterised in that the arrangement for catalytic purification, mixing arrangement, high-temperature molding dress Attemperator is provided with putting;The conveying device is heat-insulation conveying device.
CN201621364151.6U 2016-12-13 2016-12-13 A kind of coupling prepares the system without tar coal gas and calcium carbide Expired - Fee Related CN206266515U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497608A (en) * 2016-12-13 2017-03-15 神雾环保技术股份有限公司 A kind of coupling prepares the system and method without tar coal gas and calcium carbide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497608A (en) * 2016-12-13 2017-03-15 神雾环保技术股份有限公司 A kind of coupling prepares the system and method without tar coal gas and calcium carbide

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