CN206152600U - Flue gas system distribution apparatus of high -efficient denitration of ozone in low temperature section absorption tower - Google Patents

Flue gas system distribution apparatus of high -efficient denitration of ozone in low temperature section absorption tower Download PDF

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Publication number
CN206152600U
CN206152600U CN201621094036.1U CN201621094036U CN206152600U CN 206152600 U CN206152600 U CN 206152600U CN 201621094036 U CN201621094036 U CN 201621094036U CN 206152600 U CN206152600 U CN 206152600U
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China
Prior art keywords
ozone
absorption tower
straight tube
flue gas
distribution apparatus
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Expired - Fee Related
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CN201621094036.1U
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Chinese (zh)
Inventor
从明耀
何利
范喜法
李玲
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Beijing Changxintaihe Energy-Saving Science & Technology Co Ltd
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Beijing Changxintaihe Energy-Saving Science & Technology Co Ltd
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Publication of CN206152600U publication Critical patent/CN206152600U/en
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Abstract

The utility model relates to a flue gas system distribution apparatus of high -efficient denitration of ozone in low temperature section absorption tower installs including the absorption tower, mixes the unit body anticorrosive coating, the circular person in charge of ozone gas mixture and ozone gas mixture nozzle component, and the absorption tower inner wall adheres to muddy first body anticorrosive coating. The circular person in charge of ozone gas mixture pastes the volt at the absorption tower inner wall, has the lower supreme direction of the two sets of above circular person in charge's subassemblies of ozone gas mixture follows to arrange in proper order. Ozone gas mixture nozzle component includes that ozone blowout straight tube and level spout the ozone pipe chute, and two levels are spouted ozone pipe chute symmetry and are set up in the ozone straight tube top both sides of spouting, and the rear end that the ozone pipe chute is spouted to every level is connected with ozone blowout straight tube. The utility model discloses well ozone pressure stability, the jet velocity is even, improves ozone flue gas system's nitrogen oxide oxygenation efficiency and improves the utilization ratio of ozone in the low temperature section.

Description

The flue gas system distribution apparatus of ozone NO_x Reduction by Effective in a kind of low-temperature zone absorption tower
Technical field
This utility model is related to technical field of waste gas treatment, and in particular to ozone NO_x Reduction by Effective in a kind of low-temperature zone absorption tower Flue gas system distribution apparatus.
Background technology
Constantly lifted based on attention of the China currently to atmosphere polluting problem, nowadays to nitrogen oxides in atmosphere pollution Discharge standard there has also been and significantly improve, and the nitrogen oxides of strict control atmosphere pollution already become solution atmosphere polluting problem One of necessary means.
Now, denitration mainly includes that room temperature organic catalysis ultra-clean circulates (LOCR) technology, SCR (SCR) Technology, SNCR (SNCR) technology, active CAM, electron beam irradiation method and low-temperature oxidation absorption process and Other joint gas denitrifying technologies etc..
Wherein, as room temperature organic catalysis ultra-clean circulation (LOCR) technology has, desulphurization denitration dedusting etc. is various to reduce discharging spy Point, which adopts ozone for low-temperature flue gas Denitration in Boiler, and controllability is strong, can reach the discharge standard of ultra-clean, and the technique has Good market development prospect.The cardinal principle of room temperature organic catalysis ultra-clean circulation (LOCR) technology is aoxidized using ozone etc. Agent is mixed and gaseous oxidation NOx with being uniformly distributed for NOx, the NOx of high-valence state is then absorbed with absorbing liquid, is had using a kind of room temperature Machine catalyst, it can be with reference to HNO2And H2SO3Etc. unstable product into stable comple, by oxidizing into stable Product, and complex decomposition, so that catalyst freely combines the new lysigenous unstable intermediate product of physical molecular, can Integration removes SO therein2And NOx, and other pollutant of part.The wherein oxidant such as ozone and NOx it is uniform mix with And flue gas flow field distribution is to affect one of key factor of NOX oxidation efficiency, flue gas system distribution apparatus is its important step.
Therefore, research and develop a kind of flue gas system distribution apparatus for being capable of NO_x Reduction by Effective particularly important.
Utility model content
The purpose of this utility model is to solve current boiler smoke air contaminant treatment nitrogen oxides to use ozone as oxygen Agent allows ozone gaseous mixture to spray into mixed flue gas system problem pockety in absorption tower efficiently removing NOx.
To achieve these goals, concrete technical scheme of the present utility model is as follows:Ozone in a kind of low-temperature zone absorption tower The flue gas system distribution apparatus of NO_x Reduction by Effective, including absorption tower, based element mixing body anticorrosive coat, the circular supervisor of ozone gaseous mixture and ozone is mixed Close gas blowout nozzle member, it is characterised in that also straight tube, level spray ozone inclined tube and horizontal shower nozzle, the absorption are sprayed including ozone Tower is vertically placement and absorbs inner wall of tower attachment based element mixing body anticorrosive coat, and the ozone gaseous mixture circular supervisor have in flue Two groups, the ozone gaseous mixture circle administration component is arranged in order in direction from bottom to up, the ozone mixture gas nozzle component bag Include ozone and spray straight tube, the wherein axis of ozone ejection straight tube is perpendicular with the tangent line of the circular supervisor of the ozone gaseous mixture, institute The level that there are 15 ° of the axis angles of two and ozone ejection straight tube the termination for stating ozone ejection straight tube sprays ozone inclined tube, the water Flat spray ozone inclined tube is symmetrically set in ozone and sprays straight tube top both sides, and the angle between the horizontal shower nozzle into 30 °, spray by the level The rear end of ozone inclined tube connects with ozone ejection straight tube and front end termination is provided with nozzle.
Further, the ozone inlet arranges stainless-steel seamless pipe and its end face can arrange flange.
Further, inside ozone gaseous mixture supervisor insertion absorption tower, one end and seamless stainless steel sealing of tube conduct Ozone import, the circular supervisor of other end connection ozone mixing, which is also fixedly connected with ozone pipeline fixing bracket, is fixed on absorption On inner wall of tower.
Further, in the level spray ozone inclined tube is generally aligned in the same plane, its nozzle arrangement is set to 2, the spray Mouth opening direction is vertical with axis in vertical absorption tower, and they spray straight tube one end in ozone, and ozone sprays straight tube described It is evenly arranged on the circular supervisor of ozone gaseous mixture.
Further, the circular supervisor internal diameter 30mm of the ozone gaseous mixture, external diameter is 35mm, is arranged on inner wall of tower is absorbed There is the ozone pipeline fixing bracket of the circular supervisor of ozone gaseous mixture, its stent length is 75mm, and width is 35mm, thick 5mm, per two Individual set spacing 500mm, along one week inside absorption tower, the distance between two adjacent groups ozone gaseous mixture circle administration component was 2800mm。
Further, the circular supervisor of the ozone gaseous mixture, ozone mixture gas nozzle component are seamless stainless using 316L Steel pipe.
The beneficial effects of the utility model:In distribution apparatus of the present utility model, ozone be from ozonator export into Enter the circular supervisor of ozone gaseous mixture, then the circular supervisor of Jing ozone gaseous mixture reaches ozone and sprays straight tube, Maximum Concentration of Ozone is stable, injection Speed is uniform, and ozone sprays straight tube by the different ozone of angle more than two and is injected in absorption tower, makes ozone in fume pipe Road uniform spatial distribution, is conducive to that ozone is full and uniform with flue gas gaseous mixture to be mixed, so as to improve ozone flue gas mixed flue gas system The nitrogen oxides rate of system, and improve the utilization rate of ozone.
This utility model is the physicochemical property based on ozone strong oxidizing agent, and the cigarette of ozone NO_x Reduction by Effective is installed in absorption tower Gas system distribution apparatus.The physicochemical property of described ozone, is primarily referred to as ozone 1s in the case where exhaust gas temperature is not higher than 140 DEG C Interior resolution ratio is less than 30%, and higher its resolution ratio of temperature is bigger, so flue gas will be controlled through this ozone mixed flue gas system point When cloth apparatus, temperature will be less than 140 DEG C.Through the conclusion that many experiments room and engineering experiment draw, in exhaust gas temperature At 140 DEG C, the response time between ozone and nitrogen oxides, less than 10ms, so designs the flue gas of ozone NO_x Reduction by Effective for us Ozone pipeline in system distribution apparatus provides foundation, advises that temperature control, at 65 DEG C or so, makes ozone and nitrogen in absorption tower Oxide fully can be reacted without being decomposed into oxygen quickly.The flue gas system of low-temperature zone ozone NO_x Reduction by Effective, to prevent ozone Into absorption tower low temperature under its inwall situation about being corroded occur, based element mixing body anticorrosive coat is arranged to this absorption inner wall of tower.
This utility model provides a kind of flue gas system distribution apparatus of ozone NO_x Reduction by Effective in low-temperature zone absorption tower, fully examines Spacing between the reasonable Arrangement in ozone pipeline and flue gas direction, the ozone conduit assembly, arrangement mode of ozone pipeline, smelly is considered The direction of nozzle is installed on oxygen pipeline, the flue gas system distribution apparatus of this ozone NO_x Reduction by Effective combines room temperature organic catalysis denitration Feature, is evenly distributed on ozone in absorption tower using special electrical system control software, is filled with lower nitrogen oxides The reaction for dividing.Also, distribution apparatus does not need electric energy, and operating cost is low, safeguard simple, is adapted to further popularization.
Description of the drawings
Fig. 1 is the main view of the flue gas system distribution apparatus of ozone NO_x Reduction by Effective in a kind of low-temperature zone absorption tower of this utility model Figure;
Fig. 2 is the vertical view of the flue gas system distribution apparatus of ozone NO_x Reduction by Effective in a kind of low-temperature zone absorption tower of this utility model Figure;
Fig. 3 is the side-looking of the flue gas system distribution apparatus of ozone NO_x Reduction by Effective in a kind of low-temperature zone absorption tower of this utility model Figure;
Fig. 4 is the nozzle of the flue gas system distribution apparatus of ozone NO_x Reduction by Effective in a kind of low-temperature zone absorption tower of this utility model Element structure schematic diagram.
In accompanying drawing, 1 is ozone inlet, and 2 is absorption tower, and 3 is based element mixing body anticorrosive coat, and 4 is stainless-steel seamless pipe, and 5 are spray Head, 6 is the circular supervisor of ozone gaseous mixture, and 7 is ozone pipeline fixing bracket.
This utility model is conducted further description below in conjunction with Figure of description.
Specific embodiment
As shown in Figure 1, Figure 2, Figure 3, Figure 4, in a kind of low-temperature zone absorption tower, the flue gas system distribution of ozone NO_x Reduction by Effective is filled Put, including absorption tower (2), based element mixing body anticorrosive coat (3), the circular supervisor (6) of ozone gaseous mixture and ozone mixture gas nozzle component, inhale It is vertically placement to receive tower (2), and its absorption tower (2) inwall attachment based element mixing body anticorrosive coat (3), the circular supervisor (6) of ozone gaseous mixture exist There are two groups in flue, circular supervisor's (6) component of ozone gaseous mixture is arranged in order in direction from bottom to up;Ozone mixture gas nozzle Component includes:Ozone sprays straight tube, and the ozone sprays the axis of straight tube and the tangent line of the circular supervisor (6) of ozone gaseous mixture mutually hangs down Directly, there is the level spray ozone inclined tube of two 15 ° of axis angles that straight tube is sprayed with ozone termination, and two levels spray ozone inclined tube pair Title is arranged on ozone and sprays straight tube top both sides, the angle between two horizontal shower nozzles into 30 °, after each level spray ozone inclined tube End sprays straight tube with ozone and connects, and front end termination carries nozzle.
Ozone inlet (1) arranges stainless-steel seamless pipe (4) and its end face can arrange flange.Ozone gaseous mixture is responsible for (6) absorption tower (2) inside is inserted, one end is welded as ozone import with stainless-steel seamless pipe (4), and other end connection ozone is mixed Circular supervisor (6) is closed, which is also fixedly connected with ozone pipeline fixing bracket (7), be fixed on absorption inner wall of tower.Level sprays ozone In inclined tube is generally aligned in the same plane, its nozzle arrangement is set to 2, and nozzle opening direction is vertical with axis in vertical absorption tower, They spray straight tube one end in ozone, and ozone sprays straight tube and is evenly arranged on the circular supervisor (6) of ozone gaseous mixture.
Circular supervisor (6) the internal diameter 30mm of ozone gaseous mixture, external diameter is 35mm, on absorption tower (2) inwall is provided with ozone The ozone pipeline fixing bracket (7) of the circular supervisor of gaseous mixture, its stent length is 75mm, and width is 35mm, thick 5mm, each two Set spacing 500mm, two adjacent groups ozone gaseous mixture circular supervisor (6) component the distance between internal a week along absorption tower (2) It is 2800mm.The circular supervisor (6) of ozone gaseous mixture, ozone mixture gas nozzle component adopt 316L gapless stainless steel tubes.
Specific workflow of the present utility model is as follows:Ozone gaseous mixture is through ozone inlet (1) into ozone gaseous mixture In circular supervisor (6), then the shower nozzle (5) through aligned orderly reach have in the absorption tower (2) of based element mixing body anticorrosive coat (3) make it is smelly Oxygen is fully contacted with flue gas, aoxidizes the lower nitrogen oxides in flue gas, and absorption tower (2) inwall is not corroded.
This utility model is the physicochemical property based on ozone strong oxidizing agent, and the cigarette of ozone NO_x Reduction by Effective is installed in absorption tower Gas system distribution apparatus.The physicochemical property of described ozone, is primarily referred to as ozone 1s in the case where exhaust gas temperature is not higher than 140 DEG C Interior resolution ratio is less than 30%, and higher its resolution ratio of temperature is bigger, so flue gas will be controlled through this ozone mixed flue gas system point When cloth apparatus, temperature will be less than 140 DEG C.Through the conclusion that many experiments room and engineering experiment draw, in exhaust gas temperature At 140 DEG C, the response time between ozone and nitrogen oxides, less than 10ms, so designs the flue gas of ozone NO_x Reduction by Effective for us Ozone pipeline in system distribution apparatus provides foundation, advises that temperature control, at 65 DEG C or so, makes ozone and nitrogen in absorption tower Oxide fully can be reacted without being decomposed into oxygen quickly.
This utility model provides a kind of flue gas system distribution apparatus of ozone NO_x Reduction by Effective in low-temperature zone absorption tower, fully examines Spacing between the reasonable Arrangement in ozone pipeline and flue gas direction, the ozone conduit assembly, arrangement mode of ozone pipeline, smelly is considered The direction of nozzle is installed on oxygen pipeline, the flue gas system distribution apparatus of this ozone NO_x Reduction by Effective combines room temperature organic catalysis denitration Feature, is evenly distributed on ozone in absorption tower using special electrical system control software, is filled with lower nitrogen oxides The reaction for dividing.Also, distribution apparatus does not need electric energy, and operating cost is low, safeguard simple, is adapted to further popularization.
Above example is only unrestricted to illustrate the technical solution of the utility model, although with reference to preferred embodiment pair This utility model has been described in detail, it will be understood by those within the art that, can be to technology of the present utility model Scheme is modified or equivalent, and without deviating from the spirit and scope of technical solutions of the utility model, which all should be covered In the middle of right of the present utility model.

Claims (6)

1. in a kind of low-temperature zone absorption tower ozone NO_x Reduction by Effective flue gas system distribution apparatus, including absorption tower, based element mixing body anti-corrosion The circular supervisor of layer, ozone gaseous mixture and ozone mixture gas nozzle component, it is characterised in that also spray straight tube, level including ozone Spray ozone inclined tube and horizontal shower nozzle, the absorption tower are vertically placements and absorb inner wall of tower attachment based element mixing body anticorrosive coat, described smelly The circular supervisor of oxygen gas mixture has two groups in flue, and direction is successively from bottom to up for the ozone gaseous mixture circle administration component Arrangement, the ozone mixture gas nozzle component include that ozone sprays straight tube, and wherein ozone sprays the axis and the ozone of straight tube The tangent line of the circular supervisor of gaseous mixture is perpendicular, and the ozone sprays the termination of straight tube two axis folders that straight tube is sprayed with ozone The level spray ozone inclined tube that 15 ° of angle, the level spray ozone inclined tube are symmetrically set in ozone and spray straight tube top both sides, the level , into 30 °, the level sprays the rear end of ozone inclined tube, and and ozone ejection straight tube is connected and front end termination is provided with spray for angle between shower nozzle Mouth.
2. in a kind of low-temperature zone absorption tower according to claim 1 ozone NO_x Reduction by Effective flue gas system distribution apparatus, its It is characterised by, the ozone inlet arranges stainless-steel seamless pipe and its end face can arrange flange.
3. in a kind of low-temperature zone absorption tower according to claim 1 ozone NO_x Reduction by Effective flue gas system distribution apparatus, its Be characterised by, inside ozone gaseous mixture supervisor's insertion absorption tower, one end with seamless stainless steel sealing of tube as ozone import, The circular supervisor of other end connection ozone mixing, which is also fixedly connected with ozone pipeline fixing bracket, is fixed on absorption inner wall of tower.
4. in a kind of low-temperature zone absorption tower according to claim 1 ozone NO_x Reduction by Effective flue gas system distribution apparatus, its It is characterised by, in level spray ozone inclined tube is generally aligned in the same plane, its nozzle arrangement is set to 2, the nozzle opening side To vertical with axis in vertical absorption tower, they spray straight tube one end in ozone, and ozone sprays straight tube and mixes in the ozone It is evenly arranged on the circular supervisor of gas.
5. in a kind of low-temperature zone absorption tower according to claim 1 ozone NO_x Reduction by Effective flue gas system distribution apparatus, its It is characterised by, the circular supervisor internal diameter 30mm of the ozone gaseous mixture, external diameter is 35mm, is provided with ozone and mixes on inner wall of tower is absorbed The ozone pipeline fixing bracket of the circular supervisor of gas is closed, its stent length is 75mm, and width is 35mm, thick 5mm, between each two support Away from 500mm, along one week inside absorption tower, the distance between two adjacent groups ozone gaseous mixture circle administration component was 2800mm.
6. in a kind of low-temperature zone absorption tower according to claim 1 ozone NO_x Reduction by Effective flue gas system distribution apparatus, its It is characterised by, the circular supervisor of the ozone gaseous mixture, ozone mixture gas nozzle component adopt 316L gapless stainless steel tubes.
CN201621094036.1U 2016-09-30 2016-09-30 Flue gas system distribution apparatus of high -efficient denitration of ozone in low temperature section absorption tower Expired - Fee Related CN206152600U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107158910A (en) * 2017-06-28 2017-09-15 青岛国林环保科技股份有限公司 A kind of denitrating flue gas ozone reaction device
CN107308812A (en) * 2017-08-03 2017-11-03 北京长信太和节能科技有限公司 The system and method for low temperature organic catalysis oxidizing and denitrating ozone
CN108479325A (en) * 2018-05-16 2018-09-04 山东志伟环保科技有限公司 A kind of mixing arrangement of oxidation and denitration
CN111514724A (en) * 2020-03-24 2020-08-11 江苏峰业科技环保集团股份有限公司 Desulfurization and denitrification device based on ozone

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107158910A (en) * 2017-06-28 2017-09-15 青岛国林环保科技股份有限公司 A kind of denitrating flue gas ozone reaction device
CN107308812A (en) * 2017-08-03 2017-11-03 北京长信太和节能科技有限公司 The system and method for low temperature organic catalysis oxidizing and denitrating ozone
CN108479325A (en) * 2018-05-16 2018-09-04 山东志伟环保科技有限公司 A kind of mixing arrangement of oxidation and denitration
CN111514724A (en) * 2020-03-24 2020-08-11 江苏峰业科技环保集团股份有限公司 Desulfurization and denitrification device based on ozone

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