CN206142964U - Integration high concentration sewage advanced oxidation treatment equipment - Google Patents
Integration high concentration sewage advanced oxidation treatment equipment Download PDFInfo
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- CN206142964U CN206142964U CN201621058020.5U CN201621058020U CN206142964U CN 206142964 U CN206142964 U CN 206142964U CN 201621058020 U CN201621058020 U CN 201621058020U CN 206142964 U CN206142964 U CN 206142964U
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Abstract
The utility model discloses an integration high concentration sewage advanced oxidation treatment equipment, including the device box, inside electric flocculation basin, filtering ponds, micro cell, the three -dimensional electrolytic bath of catalysis supersound of having set gradually from the right side to a left side of device box, be provided with a set of polar plate in the electricity flocculation basin, be provided with the filter in the filtering ponds, it packs to be provided with the electrolysis in the micro cell, the micro cell bottom is provided with a set of supersonic generator and a set of micropore aeration head, be provided with electrolysis polar plate group in the three -dimensional electrolytic bath of supersound. The full flow of this integration high concentration sewage advanced oxidation treatment equipment is basic gives first place to with electrochemistry, and reduced plus oxidant, coagulant, flocculating agent, throwing of catalyst add, and the flow is succinct, and operation management is convenient, can realize full automatic operation, is applicable to very much the difficult biochemical organic wastewater of low discharge high concentrations such as rubbish transfer station leaching solution, cosmetics production washing wastewater, small -size machining cutting fluid.
Description
Technical field
This utility model is related to field of sewage treatment equipment, and specially a kind of integrated high concentration sewage advanced oxidation is processed
Equipment.
Background technology
The high-concentration hardly-degradable that the enterprise such as percolate and chemical industry, pharmacy, printing and dyeing, machining, plating produces is organic
The high concentrations such as waste water, waste liquid, organic wastewater with difficult degradation thereby are always an industry difficult problem, and the universal complicated component of these waste water has containing poisonous
Evil material, difficult for biological degradation, also with flow it is little, concentration is high the features such as, directly should not use biochemical process, if entering conventional dirt
Water treatment system, then can impact to biochemical system, microorganism is caused to poison, causes discharge beyond standards, or even contamination accident
Occur, the especially high concentrated organic wastewater of low discharge difficult degradation, have that supervision difficulty is big, enterprise's mobility is big, treatment cost again
Also there is blank in the reasons such as height so that control is delayed, the part industry of subregion, the market demand is huge.
There are percolate, machining cutting in the typical high concentration in Pearl River Delta region, organic wastewater with difficult degradation thereby at present
Liquid, cosmetic coloration agent emulsifying waste water, the high color waste water from dyestuff of dyeing, the used water difficult to degradate of electroplating industry, food processing and
Cultivation high concentrated organic wastewater etc., the process of above-mentioned waste water at present more adopts materialization coagulating sedimentation+biochemistry anaerobism+aerobic+depth
The technology such as process, as its high-concentration hardly-degradable characteristic causes technological process very long, civil engineering cost is high, and stably can not reach
Mark, especially for the manufacturing and processing enterprise that mobility is larger, for advanced oxidation processes technology and the advanced oxidation of equipment
There is strong demand in sewage disposal device.
Utility model content
The purpose of this utility model is to provide a kind of integrated high concentration sewage advanced oxidation processing equipment, with solution
The problem proposed in stating background technology.
For achieving the above object, this utility model provides following technical scheme：A kind of senior oxygen of integrated high concentration sewage
Change processing equipment, including device box, described device box house is disposed with electric flocculation pond, filtering ponds, micro- from right to left
Electrolyzer, catalysis ultrasonic three-dimensional electrolyzer, are provided with one group of pole plate, filtration are provided with the filtering ponds in the electric flocculation pond
Device, is provided with electrolysis filler in the micro cell, the micro cell bottom is provided with one group of supersonic generator and one group
Micro porous aeration head, is provided with electrolytic pole board group in the ultrasonic three-dimensional electrolyzer.
Preferably, described device box bottom is provided with device pedestal.
Preferably, the electric flocculation pond and the filtering ponds, the filtering ponds and the micro cell pass through communicating pipe
Connection.
Preferably, the ultrasonic three-dimensional electrolyzer is provided with one group of water intaking valve on the inwall fitted with the micro cell
Door, is provided with one group of flowing water Valve on the opposite side inwall of the ultrasonic three-dimensional electrolyzer.
Preferably, the pole plate is made from carbon steel sheet, corrosion resistant plate or using aluminium plate, and the electric flocculation pond is using friendship
Rheology frequency power is used as power supply.
Preferably, the electrolysis filler be ferrum carbon, and the electrolysis filler in containing the copper as catalyst, institute
State ultrasound wave that supersonic generator sends for 20KHZ low-frequency ultrasonic waves.
Preferably, the electrolytic pole board group includes one group of minus plate and one group of positive plate, and the minus plate is made up of graphite,
The positive plate is made up of titanium iridium ruthenium alloy.
Compared with prior art, the beneficial effects of the utility model are：The integrated high concentration sewage advanced oxidation is processed
Equipment use when, first using pending high concentrated organic wastewater according to water-quality constituents during water sample as reference, successively pass through
Through acid out, saltout, the pretreatment such as coagulating sedimentation, pretreated waste water initially enters electric flocculation pond, carries out after treatment
Filter, afterwards into micro cell, waste water further removes oil removal, a huge sum of money by precipitation and air supporting effect in micro cell
Belong to and remove part colourity, waste water is designed as 15-30min in electric flocculation pond residence time, and waste water need not in electric flocculation pond
PH is adjusted, and the water outlet in electric flocculation pond enters micro cell after filter, pH, such as rubbish adjusted according to water quality concrete condition
Terminal percolate can obtain preferable removal efficiency, in this stage design without adjusting pH under the conditions of neutral acidity
Time of staying 3h, COD can reach 30-50% with ammonia nitrogen removal efficiency, and the water outlet of micro cell eventually enters into ultrasonic three-dimensional electrolysis
Pond, the operation section design time of staying are about 3h, with several functions such as three-dimensional electrolysis, ultrasound oxidation technology, concerted catalysis oxidations,
Using graphite cake as minus plate, closed using titanium iridium ruthenium as granule electrode using activated carbon first in ultrasonic three-dimensional electrolyzer
Gold as positive plate, using sodium sulfate, Sodium Chloride etc. as electrolyte supplement, when introduce aeration or using it is ozonation aerated when,
There is the reaction that oxygen reduction generates hydrogen peroxide in minus plate, while the waste water that micro cell flows out can contain certain ferrous iron and three
Valency iron ion, the hydrogen peroxide reaction that ferrous ion can be produced with minus plate produce hydroxyl radical free radical, and ferric ion then can be
Negative electrode is reduced to ferrous ion, and the electrolysis filler in micro cell is ferrum carbon, by adding more than activated carbon powder and 800 mesh
Micron order reproducibility iron powder constitute light electrolysis battery, on the other hand the catalyst required for Fenton's reaction, the 3rd side are supplemented
Face, micron order simple substance iron powder will constitute compound advanced oxidation system with ultrasound wave, strengthen ultrasound wave advanced oxidation efficiency, improve certainly
By base yield, strengthen the removal efficiency of ultrasonic synergistic advanced oxidation, and activated carbon will constitute a heterogeneous reaction system,
Play a part of the certain Organic substance of absorption, adsorbed Organic substance will pass through light electrolysis and advanced oxidation freedom in activated carbon surface
The effect of base is removed, and the water outlet of process can contain certain molysite deposition, adjusts pH to neutrality, can be expired by adding PAC
Full existing mud-water separation completes advanced oxidation overall process；This device is by electric flocculation, light electrolysis and is catalyzed ultrasonic three-dimensional electrolytic combination,
Whole process reduces oxidant applying, coagulant, flocculant, catalyst and adds substantially based on electrochemistry, and flow process is succinct,
Operational management is convenient, is capable of achieving fully automatic operation, be highly suitable for garbage transfer station leachate, Cosmetic Manufacture cleaning waste water,
Small-sized machine processing cutting fluid etc. low discharge high concentration and refractory organic wastewater is processed, can realize in system absorption, electric flocculation,
Various oxidations such as electric floating, class electricity Fenton, the empty quick-fried chemical oxidation of ultrasound, ultrasonically catalyzing chemical oxidation, light electrolysis oxidoreduction are also
Former reaction, it is possible to achieve the thorough mineralising to polluter.
Description of the drawings
Fig. 1 is this utility model structural representation.
In figure：1st, device box, 2, electric flocculation pond, 3, filtering ponds, 4, micro cell, 5, catalysis ultrasonic three-dimensional electrolyzer,
6th, pole plate, 7, filter, 8, electrolysis filler, 9, supersonic generator, 10, micro porous aeration head, 11, electrolytic pole board group, 12, device
Base, 13, communicating pipe, 14, inlet valve, 15, flowing water Valve.
Specific embodiment
Below in conjunction with the accompanying drawing in this utility model embodiment, the technical scheme in this utility model embodiment is carried out
Clearly and completely describe, it is clear that described embodiment is only this utility model a part of embodiment, rather than whole
Embodiment.Based on the embodiment in this utility model, those of ordinary skill in the art are not under the premise of creative work is made
The every other embodiment for being obtained, belongs to the scope of this utility model protection.
Fig. 1 is referred to, this utility model provides a kind of technical scheme：A kind of integrated high concentration sewage advanced oxidation is processed
Equipment, including device box 1, are disposed with electric flocculation pond 2, filtering ponds 3, micro- electricity from right to left inside described device casing 1
Solution pond 4, catalysis ultrasonic three-dimensional electrolyzer 5, are provided with one group of pole plate 6, are provided with the filtering ponds 3 in the electric flocculation pond 2
Filter 7, is provided with electrolysis filler 8 in the micro cell 4,4 bottom of the micro cell is provided with one group of ultrasound wave to be occurred
Device 9 and one group of micro porous aeration head 10, are provided with electrolytic pole board group 11,1 bottom of described device casing in the ultrasonic three-dimensional electrolyzer 5
Portion is provided with device pedestal 12, the electric flocculation pond 2 and the filtering ponds 3, and the filtering ponds 3 and the micro cell 4 lead to
Cross and connect communicating pipe 13, the ultrasonic three-dimensional electrolyzer 5 is provided with one group of water inlet on the inwall fitted with the micro cell 4
Valve 14, is provided with one group of flowing water Valve 15 on the opposite side inwall of the ultrasonic three-dimensional electrolyzer 5, the pole plate 6 selects carbon
Steel plate, corrosion resistant plate are made using aluminium plate, and the electric flocculation pond 2 adopts AC frequency conversion power supply as power supply, the electrolysis
Filler 8 be ferrum carbon, and the electrolysis filler 8 in containing the copper as catalyst, what the supersonic generator 9 sent
Low-frequency ultrasonic waves of the ultrasound wave for 20KHZ, 11 groups of the electrolytic pole board include one group of minus plate and one group of positive plate, the negative electrode
Plate is made up of graphite, and the positive plate is made up of titanium iridium ruthenium alloy.
Operation principle：When using the integrated high concentration sewage advanced oxidation processing equipment, first by pending height
Concentration organic wastewater according to water-quality constituents during water sample as reference, successively through through acid out, saltout, the pre- place such as coagulating sedimentation
Reason, pretreated waste water initially enters electric flocculation pond 2, is filtered after treatment, afterwards into micro cell 4, waste water
In micro cell 4 further go oil removal, heavy metal and remove part colourity by precipitation and air supporting effect, waste water is in electricity
2 residence time of flocculation basin is designed as 15-30min, and waste water need not adjust PH, the water outlet Jing in electric flocculation pond 2 in electric flocculation pond 2
Filtering ponds 3 enter micro cell 4 after filtering, and adjust PH according to water quality concrete condition, and such as leachate in garbage transfer station can be without adjusting
Section pH, can obtain preferable removal efficiency, under the conditions of neutral acidity in this stage design time of staying 3h, COD and ammonia nitrogen
Removal efficiency can reach 30-50%, and the water outlet of micro cell 4 eventually enters into ultrasonic three-dimensional electrolyzer 5, and the operation section design is stopped
Time is about 3h, with several functions, first ultrasonic three-dimensional electrolyzer 5 such as three-dimensional electrolysis, ultrasound oxidation technology, concerted catalysis oxidations
Middle employing activated carbon as granule electrode, using graphite cake as minus plate, using titanium iridium ruthenium alloy as positive plate, with sulphuric acid
, used as electrolyte supplement, when introducing aeration or adopting ozonation aerated, there is oxygen reduction life in minus plate for sodium, Sodium Chloride etc.
Into the reaction of hydrogen peroxide, while the waste water that micro cell 4 flows out can contain certain ferrous and ferric ion, ferrous ion can
Hydroxyl radical free radical is produced with the hydrogen peroxide reaction produced with minus plate, ferric ion then can negative electrode be reduced to ferrous irons from
Son, the electrolysis filler 8 in micro cell 4 are ferrum carbon, by the micron order reproducibility iron powder for adding activated carbon powder and more than 800 mesh
Light electrolysis battery is constituted, the catalyst required for Fenton's reaction is on the other hand supplemented, the 3rd aspect, micron order simple substance iron powder will
Compound advanced oxidation system is constituted with ultrasound wave, strengthens ultrasound wave advanced oxidation efficiency, improve free radical yield, strengthen ultrasound wave
The removal efficiency of collaboration advanced oxidation, and activated carbon will constitute a heterogeneous reaction system, play the certain Organic substance of absorption
Effect, adsorbed Organic substance will be removed by the effect of light electrolysis and advanced oxidation free radical in activated carbon surface, most
Water outlet after processing eventually can contain certain molysite deposition, adjust pH to neutrality, realize that muddy water divides by adding PAC and can meet
From completing advanced oxidation overall process.
While there has been shown and described that embodiment of the present utility model, for the ordinary skill in the art,
Be appreciated that these embodiments can be carried out various changes in the case of without departing from principle of the present utility model and spirit, repair
Change, replace and modification, scope of the present utility model is defined by the appended claims and the equivalents thereof.
Claims (6)
1. a kind of integrated high concentration sewage advanced oxidation processing equipment, including device box, it is characterised in that：Described device case
Portion is disposed with electric flocculation pond, filtering ponds, micro cell, catalysis ultrasonic three-dimensional electrolyzer, the electricity wadding from right to left in vivo
One group of pole plate is provided with solidifying pond, filter in the filtering ponds, is provided with, electrolysis filler, institute in the micro cell, is provided with
State micro cell bottom and be provided with setting in one group of supersonic generator and one group of micro porous aeration head, the ultrasonic three-dimensional electrolyzer
There is electrolytic pole board group.
2. a kind of integrated high concentration sewage advanced oxidation processing equipment according to claim 1, it is characterised in that：It is described
Device box bottom is provided with device pedestal.
3. a kind of integrated high concentration sewage advanced oxidation processing equipment according to claim 1, it is characterised in that：It is described
Electric flocculation pond and the filtering ponds, the filtering ponds and the micro cell are connected by communicating pipe.
4. a kind of integrated high concentration sewage advanced oxidation processing equipment according to claim 1, it is characterised in that：It is described
Ultrasonic three-dimensional electrolyzer is provided with one group of inlet valve, the ultrasonic three-dimensional electrolysis on the inwall fitted with the micro cell
One group of flowing water Valve is provided with the opposite side inwall in pond.
5. a kind of integrated high concentration sewage advanced oxidation processing equipment according to claim 1, it is characterised in that：It is described
Pole plate is selected carbon steel sheet or corrosion resistant plate or is made using aluminium plate, and the electric flocculation pond is using AC frequency conversion power supply as electricity
Source.
6. a kind of integrated high concentration sewage advanced oxidation processing equipment according to claim 1, it is characterised in that：It is described
Electrolytic pole board group includes one group of minus plate and one group of positive plate, and the minus plate is made up of graphite, and the positive plate is by titanium iridium ruthenium
Alloy is made.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201621058020.5U CN206142964U (en) | 2016-09-18 | 2016-09-18 | Integration high concentration sewage advanced oxidation treatment equipment |
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| CN201621058020.5U CN206142964U (en) | 2016-09-18 | 2016-09-18 | Integration high concentration sewage advanced oxidation treatment equipment |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108408999A (en) * | 2018-05-22 | 2018-08-17 | 深圳瑞赛环保科技有限公司 | A kind of preprocess method and device of cutting waste fluid |
| CN108439668A (en) * | 2018-03-07 | 2018-08-24 | 武汉东川自来水科技开发有限公司 | A kind of sea-water reverse osmose apparatus and method |
| CN108975600A (en) * | 2018-07-02 | 2018-12-11 | 长江大学 | Condensed oil sewage floor synthetic processing platform |
| CN109293091A (en) * | 2018-11-26 | 2019-02-01 | 中国矿业大学(北京) | A kind of coupling processing device of steel rolling pickling waste waters |
| CN109867395A (en) * | 2019-03-13 | 2019-06-11 | 宁波协恒环保科技有限公司 | A kind of cutting fluid integrated treatment unit and processing method |
| CN109956594A (en) * | 2019-04-29 | 2019-07-02 | 苏州无为环境科技有限公司 | A kind of integrated waste water treatment system and its processing method of high concentrated organic wastewater |
| CN110342703A (en) * | 2019-06-27 | 2019-10-18 | 浙江森井科技股份有限公司 | A kind of non-biochemical method processing dyeing and printing sewage technique |
| CN110902899A (en) * | 2019-12-20 | 2020-03-24 | 广东工业大学 | Garbage pressing leachate treatment device and method |
| CN111003894A (en) * | 2019-12-25 | 2020-04-14 | 广州市环境保护工程设计院有限公司 | Compound landfill leachate processing system |
| CN112850858A (en) * | 2021-01-12 | 2021-05-28 | 山东中侨启迪环保装备有限公司 | A integrative electric ammonia nitrogen removal device for waste water treatment |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108439668A (en) * | 2018-03-07 | 2018-08-24 | 武汉东川自来水科技开发有限公司 | A kind of sea-water reverse osmose apparatus and method |
| CN108408999A (en) * | 2018-05-22 | 2018-08-17 | 深圳瑞赛环保科技有限公司 | A kind of preprocess method and device of cutting waste fluid |
| CN108408999B (en) * | 2018-05-22 | 2023-08-15 | 深圳瑞赛环保科技有限公司 | Pretreatment method and device for cutting waste liquid |
| CN108975600B (en) * | 2018-07-02 | 2021-05-11 | 长江大学 | Ground comprehensive treatment platform for thickened oil sewage |
| CN108975600A (en) * | 2018-07-02 | 2018-12-11 | 长江大学 | Condensed oil sewage floor synthetic processing platform |
| CN109293091A (en) * | 2018-11-26 | 2019-02-01 | 中国矿业大学(北京) | A kind of coupling processing device of steel rolling pickling waste waters |
| CN109867395A (en) * | 2019-03-13 | 2019-06-11 | 宁波协恒环保科技有限公司 | A kind of cutting fluid integrated treatment unit and processing method |
| CN109956594A (en) * | 2019-04-29 | 2019-07-02 | 苏州无为环境科技有限公司 | A kind of integrated waste water treatment system and its processing method of high concentrated organic wastewater |
| CN110342703A (en) * | 2019-06-27 | 2019-10-18 | 浙江森井科技股份有限公司 | A kind of non-biochemical method processing dyeing and printing sewage technique |
| CN110902899A (en) * | 2019-12-20 | 2020-03-24 | 广东工业大学 | Garbage pressing leachate treatment device and method |
| CN111003894A (en) * | 2019-12-25 | 2020-04-14 | 广州市环境保护工程设计院有限公司 | Compound landfill leachate processing system |
| CN111003894B (en) * | 2019-12-25 | 2022-05-24 | 广州市环境保护工程设计院有限公司 | Compound landfill leachate processing system |
| CN112850858A (en) * | 2021-01-12 | 2021-05-28 | 山东中侨启迪环保装备有限公司 | A integrative electric ammonia nitrogen removal device for waste water treatment |
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