A kind of pyrolysis of coal and cracking tube cracking production of synthetic gas system
Technical field
This utility model belongs to the pyrolysis of coal and cracking tube cracks aerogenesis technical field and in particular to a kind of be based on heat accumulating type
Radial canal heated particle pyrolysis of coal and cracking tube cracking system are with producing synthesis gas system.
Background technology
Rich coal resources in China, in addition to part is used for coking, conversion processing, the overwhelming majority is for directly firing for raw coal
Burn.Coal directly burns, and leads to the petroleum resources being rich in coal also sufficiently not refined utilization, and the direct combustion heat
Efficiency is low, serious to environmental disruption.The pyrolysis of coal is to heat coal under an inert atmosphere, produces semicoke, coal gas and tar etc. and produces
Product, these products obtaining, the synthesis of coal with cascade utilization, while petroleum resources is fully extracted, can be improve again again
Utilization ratio.Pyrolytic process of coal can be divided into external-heat and internal heat type two class.External heating type heat efficiency is low, and volatility product twice decomposition is tight
Weight;Internal heat type technique overcomes the shortcoming of external-heat, by heat carrier(Solid thermal carriers and gas heat carrier)Heat transfer
To coal., there are carbonization gas and rushed dilute, condensate recovery system is huge in gas heat carrier technique, gas heating value low it is difficult to comprehensive further
Close the shortcoming utilizing.Comparatively solid thermal carriers technique have certain advantage, but there is complex process operation link too
Many, the shortcomings of manufacturing cost is high.The existing pyrolysis type of furnace is all to produce oil product as main purpose, but is mostly pyrolyzed the type of furnace,
Especially to process the type of furnace as raw material for the fine coal, contain a large amount of dirt in pyrolysis oil, cause pyrolysis oil to be difficult to effectively utilizes, pyrolysis oil
The problems such as be worth high.Therefore, how to design all simple pyrolysis of coal of a kind of high-effective dust-removing, system structure and technological process and split
Solution production of synthetic gas system becomes the problem of this area urgent need to resolve.
Utility model content
This utility model is directed to the deficiencies in the prior art, designs and develops a kind of pyrolysis of coal and synthesis is produced in cracking tube cracking
Gas system, this response system can be pyrolyzed and be cracked two kinds of operations, the oil gas that pyrolysis chamber produces, and can enter cracking interior
Cracking tube carries out deep pyrolytic, and oil gas time of staying in cracking tube is long, and the tar molecules of macromole are cracked into the gas of small molecule
State hydro carbons, this reactor can produce substantial amounts of cracking gas, and cracking gas enters in reburner, can be by methane and minority many carbon gaseous hydrocarbon
It is converted into carbon monoxide and hydrogen, synthesis gas can do industrial basic synthetic raw gas, produce various methanol, ethylene glycol, vinegar
Acid product.This system obviates the problem producing pyrolysis oil dust-laden, the clean and effective being truly realized coal utilizes.This system adopts
Heat accumulation type radiant tube heating technique, without gas, solid heat carrier heating, simplifies while the thermal efficiency that improve reactor and to be
System technique.
For solving above-mentioned technical problem, the technical solution adopted in the utility model is:
This utility model provides a kind of pyrolysis of coal and cracking production of synthetic gas system.According to embodiment of the present utility model,
This system includes:Pyrolysis hopper;First feed arrangement, described first feed arrangement is connected with described pyrolysis hopper;It is pyrolyzed and split
Solution reactor, including:Charging aperture, pyrolysis chamber, cracking room and cracking gas outlet, described charging aperture is arranged on the top of described pyrolysis chamber
On wall, described cracking gas outlet is arranged on the side wall of described cracking room, and:Heat accumulation type radiant tube, described heat accumulating type radiation
Pipe along described reactor short transverse multi-tier arrangement inside described pyrolysis chamber and described cracking room, every layer has many along water
Square to arrangement described heat accumulation type radiant tube;Heat-insulated brick wall, described heat-insulated brick wall is arranged on described reactor transverse width
At 2/3, vertically through in described reactor, the inner space of described reactor is separated into described pyrolysis chamber and described splits
Solution room;Communication member, described communication member is arranged on the bottom of described heat-insulated brick wall, for the oil producing described pyrolysis chamber
Gas, by described communication member, is passed into described cracking room;Cracking passage, described cracking passage is located at described cracking interior, institute
One end and the described communication member of stating cracking passage are located at one end of described cracking room and are connected, the described other end cracking passage and
Described cracking gas outlet connects;Spray column, described spray column is connected with the outlet of described cracking gas;Reburner, described reburner with
Described spray column connects;Fuel cartridge, described fuel cartridge is connected with described reburner.
Inventor finds, simple according to the synthesis gas system structure of this utility model embodiment, easy to operate, Temperature Distribution
Uniformly, heats are good.Reactor is divided into pyrolysis chamber and cracking room, and this response system can be pyrolyzed and be cracked two kinds of operations,
The oil gas that pyrolysis chamber produces, can enter the indoor cracking tube of cracking and carry out deep pyrolytic, oil gas time of staying in cracking tube
Long, the tar molecules of macromole are cracked into the gaseous hydrocarbons of small molecule, and this reactor can produce substantial amounts of cracking gas, and cracking gas enters
Enter in reburner, methane and minority many carbon gaseous hydrocarbons can be carbon monoxide and hydrogen, synthesis gas can do industrial base
Plinth synthetic raw gas, produce various methanol, ethylene glycol, acetate products.This system obviates the problem producing pyrolysis oil dust-laden, very
The clean and effective just achieving coal utilizes.Additionally, two kinds of operations can be carried out in a body of heater, unite two into one, save construction cost
And floor space, and, this reactor employs heat accumulation type radiant tube heating technique without gas, solid heat carrier heating, improves
System process is simplified while the thermal efficiency of reactor.
According to embodiment of the present utility model, described communication member is the multiple hole of inclusion being arranged on described heat-insulated brick wall
Pore area;Or described communication member is on described heat-insulated brick wall longitudinal length, positioned at the opening of lower position.
According to embodiment of the present utility model, the thickness of described heat-insulated brick wall is 5-15cm, and the height of described pore area is 3-
15cm, a diameter of 1-3cm in described hole, the height of described opening is 3-15cm.
According to embodiment of the present utility model, further include combustion gas pressure fan and combustion gas air-introduced machine, wherein, described combustion gas
One end of pressure fan is connected with the outlet of described spray column, and the other end is connected with the fuel gas inlet of described heat accumulation type radiant tube;Institute
State combustion gas air-introduced machine to be arranged between described spray column and described reburner.
According to embodiment of the present utility model, also include loading hopper;Second feed arrangement, it is connected with described loading hopper;
Drying device, it is connected with the exhanst gas outlet on described second feed arrangement and described heat accumulation type radiant tube respectively;Gas solid separation
Device, it is connected with described drying device and described pyrolysis hopper respectively;Exhaust gas cleaner, it is filled with described gas solid separation
Put and be connected.
According to embodiment of the present utility model, described cracking passage is cracking tube it is preferred that cracking tube is the material that readily conducts heat
Material, described cracking tube spirals and is distributed in described cracking interior, it is furthermore preferred that described cracking tube is round described heat accumulation type radiant tube
Wriggle and be distributed, multi-tier arrangement;It is furthermore preferred that the other end of described cracking tube is welded in described cracking gas outlet.
According to embodiment of the present utility model, described pyrolysis hopper is by described first feed arrangement and described charging aperture phase
Even;Further include that semicoke exports, described semicoke outlet is arranged on the bottom of described pyrolysis chamber, described semicoke outlet and described half
Burnt conveyer device connects.
In other side of the present utility model, this utility model provides one kind and carries out coal using foregoing system
The method of pyrolysis and cracking production of synthetic gas is it is characterised in that comprise the following steps:A. particulate coal is added to by charging aperture
In reactor, in the pyrolysis chamber of described reactor, complete pyrolytic process;B. it is pyrolyzed the oil gas of generation, by described reactor
The communication member of setting on heat-insulated brick wall, in the cracking passage of the cracking room entering into described reactor;C. it is pyrolyzed the oil of generation
Gas, in the described cracking passage of described cracking room, carries out deep pyrolytic, produces cracking gas;D. described cracking gas passes through cracking gas
Outlet enters in spray column, carries out purified treatment to described cracking gas;E. a purified net cracking gas part is sent through combustion gas
The fuel gas inlet of heat accumulation type radiant tube sent into by blower fan, and net cracking gas another part sends into reburner through combustion gas air-introduced machine, described
In reburner, in cracking gas, methane and many carbon hydrocarbon are converted into carbon monoxide and Hydrogen synthesis gas;F. described synthesis gas enters combustion gas
Store in tank.
According to embodiment of the present utility model, in described step a, described particulate coal is from the charging aperture on described reactor top
It is added in described reactor, and is broken up by the described heat accumulation type radiant tube in described reactor, pyrolysis char is from described reaction
The semicoke outlet of device bottom is discharged;In described step a, described particulate coal is by the described heat accumulating type spoke in described reactor pyrolysis chamber
Penetrate pipe and be heated to 500-600 DEG C, in described step b, described pyrolysis oil gas is by the described heat accumulating type in described reactor cracking room
Radial canal is heated to 650-900 DEG C.
According to embodiment of the present utility model, the granularity of described particulate coal is below 10mm.
The beneficial effects of the utility model are:
1)Take heat accumulation type radiant tube moving bed process heating 10mm particles below and powder coal, uniformity of temperature profile,
Heats are good, and response system structure is simple, easy to operate, and feed coal utilization rate is high, are suitable to promote.
2)Reactor is divided into pyrolysis chamber and cracking room, and cracking room inside turn is dispersed with cracking tube, and cracking tube is round radiation
Pipe wriggles and is distributed, the oil gas that pyrolysis chamber produces, and can enter the indoor cracking tube of cracking and carry out deep pyrolytic, oil gas is in cracking tube
The middle time of staying is long, and the tar molecules of macromole are cracked into the gaseous hydrocarbons of small molecule;This response system can produce substantial amounts of splitting
Vent one's spleen product, it is to avoid the problem of pyrolysis oil dust-laden, combustion gas incendivity generates electricity, be truly realized the clean and effective profit of Fossil fuel
With.
3)Two kinds of operations can be carried out in one body of heater, unite two into one, save construction cost and floor space.
4)Cracking gas enters in reburner, can be carbon monoxide and hydrogen by methane and minority many carbon gaseous hydrocarbons, close
Become multiple product.
Brief description
Fig. 1 is this utility model pyrolysis of coal and cracking tube cracks production of synthetic gas system construction drawing.
Fig. 2 is the structure of reactor figure that this utility model pyrolysis of coal and cracking tube crack production of synthetic gas system.
Fig. 3 is the front view of the heat-insulated brick wall in this utility model reactor.
Wherein, 1. loading hopper;2. riser exsiccator;3. thermal storage type moving bed reactor;310th, cracking gas outlet;311、
Exhanst gas outlet;320th, charging aperture;321st, air intake;322nd, fuel gas inlet;330th, semicoke outlet;340th, cracking room;350th, heat
Solution room;360th, communication member;370th, heat-insulated brick wall;380th, heat accumulation type radiant tube;4. cyclone separator is dried;5. it is pyrolyzed hopper;
6. tail gas air-introduced machine;7. exhaust gas cleaner;8. chimney;9. rotary feeder;10. spray column;11. combustion gas air-introduced machines;12. combustions
Pneumatic transmission blower fan;13. reburners;14. conveying worms;15. fuel cartridges;16. cracking tubes.
Specific embodiment
In order that those skilled in the art more fully understand the technical solution of the utility model, with reference to specific embodiment
The utility model is described in further detail.The embodiments described below is exemplary, is only used for explaining that this practicality is new
Type, and it is not intended that to restriction of the present utility model.Unreceipted particular technique or condition in embodiment, according in the art
The technology described by document or condition or carry out according to product description.
According to one side of the present utility model, this utility model provides a kind of pyrolysis of coal and synthesis is produced in cracking tube cracking
Gas system, Fig. 1 is the structure chart that this pyrolysis of coal and cracking tube crack production of synthetic gas system, as shown in figure 1, pyrolysis of coal and cracking tube
Cracking production of synthetic gas system includes:Pyrolysis hopper 5;First feed arrangement 9, described first feed arrangement 9 and described pyrolysis hopper 5
Connect;Pyrolysis and cracking reactor 3, including:Charging aperture 320, pyrolysis chamber 350, cracking room 340, cracking gas outlet 310, accumulation of heat
Formula radial canal 380, heat-insulated brick wall 370, communication member 360 and cracking passage 16, wherein, described charging aperture is arranged on described pyrolysis
On the roof of room, described cracking gas outlet is arranged on the side wall of described cracking room, and described heat-insulated brick wall is vertically through in institute
State in reactor, the inner space of described reactor is separated into described pyrolysis chamber and described cracking room;Described communication member sets
Put on described heat-insulated brick wall, pyrolysis chamber is connected with cracking room it is preferred that described communication member is arranged on described heat-insulated brick wall
Bottom, for the oil gas producing described pyrolysis chamber, by described communication member, be passed into described cracking room;Described cracking
Passage is located at described cracking interior, and one end that described one end cracking passage is located at described cracking room with described communication member is even
Connect, the other end of described cracking passage is connected with the outlet of described cracking gas;Spray column 10, described spray column is gone out with described cracking gas
Mouth connects;Reburner 13, described reburner is connected with described spray column;Fuel cartridge 15, described fuel cartridge is with described reburner even
Connect.
Inventor finds, simple according to the synthesis gas system structure of this utility model embodiment, easy to operate, Temperature Distribution
Uniformly, heats are good.Reactor is divided into pyrolysis chamber and cracking room, and this response system can be pyrolyzed and be cracked two kinds of operations,
The oil gas that pyrolysis chamber produces, can enter the indoor cracking tube of cracking and carry out deep pyrolytic, oil gas time of staying in cracking tube
Long, the tar molecules of macromole are cracked into the gaseous hydrocarbons of small molecule, and this reactor can produce substantial amounts of cracking gas, and cracking gas enters
Enter in reburner, methane and minority many carbon gaseous hydrocarbons can be carbon monoxide and hydrogen, synthesis gas can do industrial base
Plinth synthetic raw gas, produce various methanol, ethylene glycol, acetate products.This system obviates the problem producing pyrolysis oil dust-laden, very
The clean and effective just achieving coal utilizes.Additionally, two kinds of operations can be carried out in a body of heater, unite two into one, save construction cost
And floor space.
According to specific embodiment of the utility model it is adaptable to the particle diameter of the coal of this synthesis gas system process is not especially limited
System, can also be able to be small-particle coal for lumped coal, in some preferred embodiments of the present utility model, this synthesis gas system is adopted
With particle diameter 10mm particles below coal, thus, it is possible to make full use of little particle pyrolysis material, resource utilization is high, and can solve the problem that
Bulk deposition pollutes the problem of environment.
According to specific embodiment of the utility model it is adaptable to the type of furnace of the described reactor 3 of this synthesis gas system is not subject to
Especially restriction, can be thermal storage type moving bed pyrolysis and cracking reactor 3 can also be other types, such as non-heat accumulating type or non-shifting
Dynamic formula etc., as long as pyrolysis chamber and cracking room can be divided into by the integration of heat-insulated brick wall.
According to specific embodiment of the utility model, Fig. 2 is the heat that this pyrolysis of coal and cracking tube crack production of synthetic gas system
Solution and cracking reactor 3 structure chart, as shown in Fig. 2 described heat-insulated brick wall is arranged in reactor it is preferred that being located at reactor
At the 2/3 of transverse width, the thickness of heat-insulated brick wall is 5-15cm, heat-insulated brick wall vertically through in reactor, by reactor
Inner space be separated into pyrolysis chamber and cracking room, this structure makes to be provided with pyrolysis chamber and cracking room in a body of heater, heat
The oil gas that solution room produces, can enter and carry out deep pyrolytic in the cracking passage of cracking room, when oil gas stops in cracking passage
Between long, the tar molecules of macromole being cracked into the gaseous hydrocarbons of small molecule, producing substantial amounts of cracking gas, thus avoiding production
The problem of pyrolysis oil dust-laden.And, two kinds of operations can be carried out in a body of heater, unite two into one, save construction cost and take up an area face
Long-pending.
According to specific embodiment of the utility model, the concrete species of described communication member 360 is not particularly limited, as long as
Pyrolysis chamber can be connected with cracking room, thus the oil gas that pyrolysis chamber is produced is passed into cracking room.In this utility model
Some embodiments in, when Fig. 3 is in terms of the from left to right of reactor, the front view of heat-insulated brick wall, as shown in figure 3, communication member
Can be for being arranged on the pore area in the multiple holes of inclusion on heat-insulated brick wall, under preferable case, the height of described pore area is 3-15cm, institute
State a diameter of 1-3cm in hole.Communication member can also be on heat-insulated brick wall longitudinal length, positioned at the opening of lower position, preferably
In the case of, the height of described opening is 3-15cm.
According to specific embodiment of the utility model, the concrete species of described cracking passage 16 is not particularly limited.Preferably
, cracking passage 16 is cracking tube, and cracking tube 16 is the material that readily conducts heat, and cracking tube spirals and is distributed in cracking interior, more preferably
, cracking tube wriggles round radial canal and is distributed, multi-tier arrangement.Thus, when the oil gas that pyrolysis produces can be long in cracking tube
Between stop, carry out deep pyrolytic.Additionally, one end that one end of cracking tube is located at cracking room with described pore area or opening is connected, institute
The other end stating cracking tube can be fixed in described cracking gas outlet by modes such as welding.
According to specific embodiment of the utility model, as shown in figure 1, described charging aperture is arranged on the roof on pyrolysis chamber top
On, pyrolysis hopper is connected with described charging aperture by the first feed arrangement;The concrete species of the first feed arrangement is not especially limited
System, as long as the pyrolysis material in hopper can be effectively delivered in reactor.In some embodiments of the present utility model
In, the first feed arrangement 9 can be rotary feeder or conveying worm.Defeated to the automatization of pyrolysis material thereby, it is possible to realize
Send, conveying capacity is controlled, and device structure is simple, easy to operate.
According to specific embodiment of the utility model, as shown in figure 1, reactor further comprises semicoke outlet 330, institute
State the bottom that semicoke outlet is arranged on described pyrolysis chamber, described semicoke outlet is connected with described semicoke conveyer device 14.Thus, may be used
The semicoke obtaining in reactor to be conveyed using semicoke conveyer device.The concrete species of semicoke conveyer device 14 is not subject to spy
Do not limit, including but not limited to star or conveying worm.Thereby, it is possible to realize the Automatic Conveying to semicoke, and conveying capacity
Controlled, device structure is simple, easy to operate.
According to specific embodiment of the utility model, as shown in Fig. 2 described inside reactor has multilamellar along described reactor
Short transverse be arranged in heat accumulation type radiant tube within described pyrolysis chamber and described cracking room, every layer of heat accumulation type radiant tube is permissible
Heat accumulation type radiant tube including multiple parallel to each other and horizontally spaced distribution.According to embodiment of the present utility model, institute
State pyrolysis chamber and cracking interior and distributed at least one described heat accumulation type radiant tube respectively it is preferred that described at least one accumulation of heat
Formula radial canal is uniformly distributed.Heat accumulation type radiant tube can heat effective for the oil gas indoor to pyrolysis material and cracking, makes
It is pyrolyzed and cracking reaction, specifically, can be passed through combustible gas and air into heat accumulation type radiant tube, so that combustible gas is burnt
Realize the heating function to pyrolysis material.This equipment adopts heat accumulation type radiant tube heating technique, without gas, solid heat carrier heating, heat
Vent one's spleen and will not be diluted, calorific value is high, and reactor temperature is evenly distributed, surface temperature difference is little, and exhaust gas temperature is low, the thermal efficiency is high,
System process is simplified, response system structure is simple, easy to operate while the thermal efficiency that improve reactor.
In described reactor, pyrolysis material moves from top to bottom, and in described reactor, the heat accumulation type radiant tube of setting is permissible
Pyrolysis material is broken up makes it be uniformly distributed, and pyrolysis material stops 1-40 minute in the reactor from top to bottom, and is heated to 500-600
℃.According to embodiment of the present utility model, the shape of heat accumulation type radiant tube is not particularly limited, in some realities of the present utility model
Apply in example, can be cylinder, thus be conducive to being pyrolyzed breaing up of material, realize uniform point in the reactor of mixed pyrolysis material
Dissipate.Radial canal adopts the round tube of DN200-300, and the level interval of radial canal is 200-500mm, and vertical interval is 200-
700mm, the radial canal number of plies is 10-25 layer, and reactor width is 2-6m, and height for reactor is 3-20m.In addition, heat accumulating type radiation
Pipe can be controlled in 450-1000 by gas control valve for the unidirectional heat accumulation type radiant tube being evenly arranged, the temperature of tube wall
DEG C scope, heat accumulation type radiant tube can take the combustion system of regular commutation so that the surface temperature difference of single heat accumulation type radiant tube
Only 30 DEG C about, there is no area of localized hyperthermia, thus, be conducive to improving the thermal efficiency.
According to specific embodiment of the utility model, described reactor be provided with fuel gas inlet 322, air intake 321 and
Exhanst gas outlet 311, wherein, fuel gas inlet and exhanst gas outlet are connected with heat accumulation type radiant tube respectively, are respectively used to be passed through combustible gas
With discharge flue gas, air intake is connected with source of the gas and heat accumulation type radiant tube respectively, and the air for producing source of the gas is passed through accumulation of heat
In formula radial canal.
According to embodiment of the present utility model, as shown in figure 1, this synthesis gas system may further include:Loading hopper 1;
The second feed arrangement being connected with loading hopper;It is connected with the exhanst gas outlet 311 of the second feed arrangement and heat accumulation type radiant tube respectively
Drying device 2;The gas-solid separating device 4 being connected with drying device and pyrolysis hopper 5 respectively;It is connected with gas-solid separating device
Exhaust gas cleaner 7.Thus, it is possible to the pyrolysis material in loading hopper be added in drying device by the second feed arrangement, dry
In dry device, pyrolysis material is being dried in the presence of the flue gas (temperature is about 150-250 DEG C) of heat accumulation type radiant tube, so
The mixture of dried pyrolysis material and flue gas enters gas-solid separating device afterwards, and (temperature is about 70-130 to separate the flue gas obtaining
DEG C) enter in exhaust gas cleaner and carry out purified treatment, to realize qualified discharge, separate the pyrolysis material obtaining and be delivered to pyrolysis material
In bucket, it is used for carrying out pyrolytic reaction.
According to embodiment of the present utility model, the concrete species of the second pay-off is not particularly limited, as long as being applied to
Pyrolysis material in loading hopper is delivered in drying device.In some embodiments of the present utility model, the second feeding dress
Putting can be star feeder or feed screw.Thereby, it is possible to realize the Automatic Conveying to pyrolysis material, and conveying capacity can
Control, device structure is simple, easy to operate.
According to embodiment of the present utility model, the concrete species of drying device 2 is not particularly limited, if be capable of right
The drying of pyrolysis material and the function of preheating.In some embodiments of the present utility model, drying device 2 can be riser
Exsiccator 2, thus, pyrolysis material is dried in the presence of flue gas and is lifted, the mixture of dried pyrolysis material and flue gas
Discharge riser exsiccator, be conducive to subsequent step to carry out.In drying device, while pyrolysis material is dried, also
Achieve the function of preheating, be conducive to improving speed and the efficiency of follow-up pyrolytic reaction, and using heat accumulation type radiant tube discharge
Flue gas is dried to pyrolysis material and preheats the comprehensive utilization it is achieved that heat energy, effectively reduces energy consumption, has reached energy-conserving and environment-protective
Purpose.
According to embodiment of the present utility model, the concrete species of gas-solid separating device 4 is not particularly limited, as long as can be by
Pyrolysis material separates with flue gas.In some embodiments of the present utility model, gas-solid separating device 4 can divide for whirlwind is dried
From device 4, thus, it is possible to quickly and efficiently pyrolysis material and flue gas be carried out separating, and good separating effect, simple to operation, become
This is relatively low.
According to embodiment of the present utility model, can also be further between gas-solid separating device 4 and exhaust gas cleaner 7
It is provided with tail gas air-introduced machine 6, tail gas air-introduced machine quickly and efficiently can will separate the flue gas conveying obtaining in gas-solid separating device
To exhaust gas cleaner, be conducive to improving work efficiency.
According to embodiment of the present utility model, this pyrolysis plant is also provided with the chimney being connected with exhaust gas cleaner
8, the flue gas after exhaust gas cleaner purified treatment empties through chimney, thus, is conducive to environmental protection, reduces pollution.
According to embodiment of the present utility model, as shown in figure 1, this synthesis gas system further includes combustion gas pressure fan 12,
Wherein, one end of described combustion gas pressure fan is connected with the outlet of described spray column, the combustion of the other end and described heat accumulation type radiant tube
Gas entrance 322 connects.Thus, the fuel gas inlet of the radial canal of pyrolysis reactor sent into by a part of combustible gas through combustion gas pressure fan
322.
According to embodiment of the present utility model, as shown in figure 1, this synthesis gas system further includes combustion gas air-introduced machine 11,
Wherein, described combustion gas air-introduced machine is arranged between described spray column and described reburner.The outlet of spray column and combustion gas air-introduced machine
Entrance connects, and the outlet of combustion gas air-introduced machine is connected with reburner entrance, and conversion outlet of still is connected with fuel cartridge entrance.
In other side of the present utility model, this utility model provides one kind and carries out coal using foregoing system
Pyrolysis and the method for cracking tube cracking production of synthetic gas.According to embodiment of the present utility model, the method may comprise steps of:
A. particulate coal is added in reactor by charging aperture, completes to be pyrolyzed in the pyrolysis chamber of described reactor
Journey.Wherein, described particulate coal is added to reactor from the charging aperture on reactor top, and is radiated by the heat accumulating type in reactor
Pipe is broken up, and pyrolysis char is discharged from the semicoke outlet of reactor bottom, and through semicoke conveyer device(Preferably conveying worm)Row
Go out.
According to specific embodiment of the utility model it is adaptable to the particle diameter of the coal of this synthesis gas system process is not especially limited
System, can also be able to be small-particle coal for lumped coal, in some preferred embodiments of the present utility model, this synthesis gas system is adopted
With particle diameter 10mm particles below coal, thus, it is possible to make full use of little particle pyrolysis material, resource utilization is high, and can solve the problem that
Bulk deposition pollutes the problem of environment.
According to embodiment of the present utility model, in the pyrolysis chamber of reactor, the heat accumulation type radiant tube of setting can be by pyrolysis material
Break up and so that it is uniformly distributed, particulate coal stops 1-40 minute in the reactor from top to bottom, and particulate coal is by reactor pyrolysis chamber
Heat accumulation type radiant tube be heated to 500-600 DEG C, specifically, can by gas valve control heat accumulation type radiant tube tube wall temperature
For 500-700 DEG C, particulate coal is heated to rapidly 500-600 DEG C in the reactor, completes pyrolytic process.
B. it is pyrolyzed the oil gas of generation, by the communication member of setting on the heat-insulated brick wall of described reactor, enter into described anti-
Answer in the cracking passage of cracking room of device.
According to embodiment of the present utility model, heat-insulated brick wall is arranged in reactor it is preferred that to be located at reactor laterally wide
At the 2/3 of degree, the thickness of heat-insulated brick wall is 5-15cm, heat-insulated brick wall vertically through in reactor, by the inside of reactor
Space is separated into pyrolysis chamber and cracking room, and this structure makes to be provided with pyrolysis chamber and cracking room in a body of heater, and is produced from pyrolysis chamber
Raw oil gas, can enter the indoor cracking tube of cracking and carry out deep pyrolytic, oil gas time of staying in cracking tube is long, will divide greatly
The tar molecules of son are cracked into the gaseous hydrocarbons of small molecule.Thus, two kinds of operations can be carried out in a body of heater, unite two into one, section
Save construction cost and floor space.According to embodiment of the present utility model, communication member can be for being arranged on heat-insulated brick wall
On pore area including multiple holes or heat-insulated brick wall longitudinal length, positioned at the opening of lower position.Specifically, cracking tube
One end and described pore area or opening be located at one end of cracking room and be connected, the oil gas of pyrolysis generation, by the heat-insulated brick wall of reactor
The pore area of bottom or opening, enter in the cracking tube of cracking room.
C. the oil gas being pyrolyzed generation, in the described cracking passage of described cracking room, carries out deep pyrolytic, produces cracking
Gas.
According to embodiment of the present utility model, described cracking interior distributed at least one described heat accumulation type radiant tube, excellent
Choosing, described at least one heat accumulation type radiant tube is uniformly distributed.Heat accumulation type radiant tube can be effective for the oil in cracking tube
Gas is heated so as to be carried out cracking reaction.Cracking tube is the material that readily conducts heat, preferential iron pipe, and cracking tube total length is 5-50m,
Cracking tube wriggles round radial canal and is distributed, multi-tier arrangement, and oil gas time of staying in thermal decomposition tube is long, carries out deep pyrolytic.Split
The available steel rivet of solution pipe is fixed on heat-insulated brick wall, the other end of cracking tube(Outlet)It is connected to the cracking of reactor cracking room
In gas outlet, for example, weld.Specifically, pyrolysis oil gas is heated to 650-900 by the heat accumulation type radiant tube in reactor cracking room
DEG C, specifically, can be 650-900 DEG C by the temperature that gas valve controls heat accumulation type radiant tube tube wall, particulate coal is in reactor
In be heated to rapidly 650-900 DEG C, complete thermal cracking processes, thus, the tar molecules of macromole are cracked into the gas of small molecule
State hydro carbons, produces substantial amounts of cracking gas, it is to avoid the problem of pyrolysis oil dust-laden, is truly realized the clean and effective profit of Fossil fuel
With.
D. described cracking gas is entered in spray column by cracking gas outlet, carries out purified treatment to described cracking gas.
E. a purified net cracking gas part sends into the fuel gas inlet of heat accumulation type radiant tube, net cracking through combustion gas pressure fan
Gas another part sends into reburner through combustion gas air-introduced machine, and in described reburner, in cracking gas, methane and many carbon hydrocarbon are converted into one
Carbonoxide and Hydrogen synthesis gas.
F. described synthesis gas enters in fuel cartridge and stores.
Embodiment one:
(1)The particulate coal being crushed to granularity≤10mm enters riser exsiccator 2 by loading hopper 1, is dried in riser
In device, the 150-250 DEG C of flue gas using the radial canal smoke outlet from thermal storage type moving bed reactor 3 is done to coal
Dry and lifting, coal enter cyclone separator 4 is dried, the coal dust separating enter into pyrolysis hopper 5 in, 70-130 DEG C about
Flue gas is then admitted to exhaust gas cleaner 7 through tail gas air-introduced machine 6, reaches the flue gas after discharge standard and discharges through chimney 8.
(2)Coal enters thermal storage type moving bed reactor 3, moving-burden bed reactor 3 through rotary feeder 9 in pyrolysis hopper 5
Pyrolysis chamber and cracking room are divided into by clathrate.
(3)It has been evenly arranged unidirectional heat accumulation type radiant tube, tube wall temperature is controlled 500 using gas control valve in pyrolysis chamber
~700 DEG C of scopes, material stops 1-40 minute in the reactor from top to bottom, and is heated to 500~600 DEG C, completes to be pyrolyzed
Journey.
(4)The oil gas that pyrolysis produces, by the opening of reactor lower part grid brick wall, enters into the indoor cracking tube of cracking
In 16, cracking tube is the material that readily conducts heat, preferential iron pipe, and cracking tube total length is 5-50m, and cracking tube wriggles round radial canal and divides
Cloth, multi-tier arrangement, oil gas time of staying in thermal decomposition tube is long, carries out deep pyrolytic.It has been evenly arranged unidirectional accumulation of heat in cracking room
Formula radial canal, tube wall temperature is controlled in 650~900 DEG C of scopes using gas control valve, and pyrolysis oil gas is indoor heated in cracking
To 650-900 DEG C, complete thermal cracking processes, the tar molecules of macromole are cracked into the gaseous hydrocarbons of small molecule, produce substantial amounts of
Cracking gas, it is to avoid the problem of pyrolysis oil dust-laden, the clean and effective being truly realized Fossil fuel utilizes.Cracking tube 16 can steel
Rivet is fixed on grid brick wall.Cracking tube outlet is connected in gas reactor outlet.For example weld.
(5)Cracking gas passes through reactor outlet, enters in spray column 10 and washs, and the net cracking gas after washing is blown through combustion gas
Reburner 13 sent into by machine 11, and in reburner 13 cracking gas, methane and minority many carbon hydrocarbon are converted into carbon monoxide and hydrogen synthesis
Gas, synthesis gas enters in fuel cartridge 15 and stores, and can produce the multiple products such as methanol, ethylene glycol, acetic acid.
(6)A part of combustible gas sends into the radial canal fuel gas inlet of pyrolysis reactor 3 through combustion gas pressure fan 12.
(7)The semicoke that pyrolysis of coal produces is discharged by conveying worm 14, and semicoke can be used for combustion power generation or makes moulded coal.
Inventor finds, simple according to the synthesis gas system structure of this utility model embodiment, easy to operate, Temperature Distribution
Uniformly, heats are good.Reactor is divided into pyrolysis chamber and cracking room, and this response system can be pyrolyzed and be cracked two kinds of operations,
The oil gas that pyrolysis chamber produces, can enter the indoor cracking tube of cracking and carry out deep pyrolytic, oil gas time of staying in cracking tube
Long, the tar molecules of macromole are cracked into the gaseous hydrocarbons of small molecule, and this reactor can produce substantial amounts of cracking gas, and cracking gas enters
Enter in reburner, methane and minority many carbon gaseous hydrocarbons can be carbon monoxide and hydrogen, synthesis gas can do industrial base
Plinth synthetic raw gas, produce various methanol, ethylene glycol, acetate products.This system obviates the problem producing pyrolysis oil dust-laden, very
The clean and effective just achieving coal utilizes.Additionally, two kinds of operations can be carried out in a body of heater, unite two into one, save construction cost
And floor space.
Using this utility model pyrolysis of coal and cracking tube cracking production of synthetic gas system, brown coal are processed, the basis of raw material
Data is shown in Table 1.
Table 1:Brown coal basic data
Process brown coal using this system, the factor of created gase obtaining is up to 25%, far above the product obtained by the pyrolysis of laboratory aluminum rice steamer
Gas rate, pyrolytic tar almost all is cracked into gaseous products, and factor of created gase is high.Synthesis gas purity reaches more than 95%.
It is to be understood that term " first ", " second " are only used for describing purpose in description of the present utility model, and
It is not intended that instruction or hint relative importance or the implicit quantity indicating indicated technical characteristic.Thus, define
The feature of " first ", " second " can be expressed or implicitly include one or more this feature.
In this utility model, unless otherwise clearly defined and limited, term " installation ", " being connected ", " connection ", " Gu
Fixed " etc. term should be interpreted broadly, for example, it may be being fixedly connected or being detachably connected or integral;Can be
It is mechanically connected or electrically connect;Can be to be joined directly together it is also possible to be indirectly connected to by intermediary, can be two
The connection of element internal or the interaction relationship of two elements.For the ordinary skill in the art, can basis
Concrete condition understands concrete meaning in this utility model for the above-mentioned term.
In this utility model, unless otherwise clearly defined and limited, fisrt feature second feature " on " or D score
Can be the first and second feature directly contacts, or the first and second features pass through intermediary mediate contact.And, first is special
Levy second feature " on ", " top " and " above " but fisrt feature directly over second feature or oblique upper, or only
Represent that fisrt feature level height is higher than second feature.Fisrt feature second feature " under ", " lower section " and " below " permissible
Be fisrt feature immediately below second feature or obliquely downward, or be merely representative of fisrt feature level height and be less than second feature.
In the description of this specification, reference term " embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or the spy describing with reference to this embodiment or example
Point is contained at least one embodiment of the present utility model or example.In this manual, the schematic table to above-mentioned term
State that be not necessarily referring to is identical embodiment or example.And, the specific features of description, structure, material or feature can be
Combine in an appropriate manner in any one or more embodiments or example.Additionally, in the case of not conflicting, this area
Technical staff the feature of the different embodiments described in this specification or example and different embodiment or example can be entered
Row combines and combines.
Although of the present utility model embodiment has been shown and described above it is to be understood that above-described embodiment is
Exemplary it is impossible to be interpreted as that those of ordinary skill in the art is in scope of the present utility model to restriction of the present utility model
Interior above-described embodiment can be changed, change, replacing and modification, simultaneously for one of ordinary skill in the art, foundation
The thought of the application, all will change in specific embodiments and applications.