CN205804016U - A PU crystal mirror bonding structure - Google Patents
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Abstract
本实用新型属于皮革技术领域,更具体地说,本实用新型涉及一种PU水晶镜面贴合结构,从下到上,所述PU水晶镜面贴合结构依次包括基布层、湿法PU层、干法PU纹路层、印刷层、透明PU黏着层和透明聚氨酯弹性体层,所述基布层上设置有若干个透气微孔,所述透明聚氨酯弹性体层的厚度为0.001mm‑0.30mm。相对于现有技术,本实用新型采用透明聚氨酯弹性体层作为面层,其光泽柔和、自然,水晶感强,手感柔软,与印刷层粘接性能优异、抗磨损、耐挠曲、抗老化、抗霉菌性好,同时还具备耐寒性好、透气、可洗涤、加工方便、价格优廉等优点。
The utility model belongs to the field of leather technology, and more specifically, the utility model relates to a PU crystal mirror bonding structure, which includes, from bottom to top, a base fabric layer, a wet PU layer, a dry PU texture layer, a printing layer, a transparent PU adhesive layer and a transparent polyurethane elastomer layer in sequence, wherein the base fabric layer is provided with a plurality of breathable micropores, and the thickness of the transparent polyurethane elastomer layer is 0.001mm-0.30mm. Compared with the prior art, the utility model adopts a transparent polyurethane elastomer layer as the surface layer, which has a soft and natural luster, a strong crystal feel, a soft hand feel, excellent bonding performance with the printing layer, good wear resistance, flex resistance, anti-aging, and anti-fungal properties, and also has the advantages of good cold resistance, breathability, washability, convenient processing, and low price.
Description
技术领域technical field
本实用新型属于皮革技术领域,更具体地说,本实用新型涉及一种PU水晶镜面贴合结构。The utility model belongs to the technical field of leather, more specifically, the utility model relates to a PU crystal mirror bonding structure.
背景技术Background technique
PU合成革又称聚氨酯合成革,一般由基布与聚氨酯涂覆层构成,目前已广泛适用于做箱包、服装、鞋、车辆和家具,应用范围之广、数量之大、品种之多是传统的天然皮革无法满足的。PU synthetic leather, also known as polyurethane synthetic leather, is generally composed of a base fabric and a polyurethane coating layer. It has been widely used in luggage, clothing, shoes, vehicles and furniture. The wide range of applications, large quantities, and many varieties are traditional. The natural leather can not be satisfied.
但是现有的PU水晶镜面产品却无法广泛生产使用,主要是因为聚氨酯本身的原因,其生产时易产生气泡空白点,造成通透度不佳、收率低、成本高,而且客户可选择的纹路较少,一般只适用于细致、较浅的纹路,稍深纹路即易发生飞车,容易产生异常。However, the existing PU crystal mirror products cannot be widely produced and used, mainly because of the polyurethane itself, which tends to produce bubbles and blank spots during production, resulting in poor transparency, low yield, high cost, and the texture that customers can choose Less, it is generally only suitable for fine and shallow lines, and slightly deeper lines are prone to speeding and abnormalities.
有鉴于此,确有必要提供一种PU水晶镜面贴合结构,其通过设置干法PU纹路层和聚氨酯弹性体,能够增加产品的水晶感、通透度及舒软感,而且能够提高收率,其能够适用于不同种类的纹路。In view of this, it is indeed necessary to provide a PU crystal mirror bonding structure, which can increase the crystal sense, transparency and softness of the product by setting the dry-process PU texture layer and polyurethane elastomer, and can increase the yield , which can be applied to different kinds of textures.
实用新型内容Utility model content
本实用新型的目的在于:针对现有技术的不足,而提供一种PU水晶镜面贴合结构,其通过设置干法PU纹路层和聚氨酯弹性体,能够增加产品的水晶感、通透度及舒软感,而且能够提高收率,丰富纹路的种类。The purpose of the utility model is to provide a PU crystal mirror bonding structure for the deficiencies of the prior art, which can increase the crystal sense, transparency and comfort of the product by setting a dry-process PU texture layer and polyurethane elastomer. It has a soft feeling, and can increase the yield and enrich the types of textures.
为了达到上述目的,本实用新型采用如下技术方案:In order to achieve the above object, the utility model adopts the following technical solutions:
一种PU水晶镜面贴合结构,从下到上,所述PU水晶镜面贴合结构依次包括基布层、湿法PU层、干法PU纹路层、印刷层、透明PU黏着层和透明聚氨酯弹性体层,所述基布层上设置有若干个透气微孔,所述透明聚氨酯弹性体层的厚度为0.001mm-0.30mm。A PU crystal mirror bonding structure, from bottom to top, the PU crystal mirror bonding structure sequentially includes a base fabric layer, a wet PU layer, a dry PU texture layer, a printing layer, a transparent PU adhesive layer and a transparent polyurethane elastic The body layer, the base fabric layer is provided with several air-permeable micropores, and the thickness of the transparent polyurethane elastomer layer is 0.001mm-0.30mm.
作为本实用新型PU水晶镜面贴合结构的一种改进,所述透气微孔的孔径为100nm-50μm。As an improvement of the bonding structure of the PU crystal mirror surface of the utility model, the diameter of the air-permeable micropores is 100nm-50μm.
作为本实用新型PU水晶镜面贴合结构的一种改进,所述基布层的厚度为0.05mm-0.5mm,所述湿法PU层的厚度为0.03mm-0.3mm,所述干法PU纹路层的厚度为0.03mm-0.3mm、所述印刷层的厚度为0.01mm-0.2mm,所述透明PU黏着层的厚度为0.01mm-0.2mm。As an improvement of the PU crystal mirror bonding structure of the utility model, the thickness of the base cloth layer is 0.05mm-0.5mm, the thickness of the wet-process PU layer is 0.03mm-0.3mm, and the dry-process PU texture The thickness of the layer is 0.03mm-0.3mm, the thickness of the printing layer is 0.01mm-0.2mm, and the thickness of the transparent PU adhesive layer is 0.01mm-0.2mm.
作为本实用新型PU水晶镜面贴合结构的一种改进,所述基布层的厚度为0.1mm-0.3mm,所述湿法PU层的厚度为0.08mm-0.2mm,所述干法PU纹路层的厚度为0.08mm-0.2mm、所述印刷层的厚度为0.05mm-0.15mm,所述透明PU黏着层的厚度为0.05mm-0.15mm,所述透明聚氨酯弹性体层的厚度为0.01mm-0.20mm。As an improvement of the PU crystal mirror bonding structure of the utility model, the thickness of the base cloth layer is 0.1mm-0.3mm, the thickness of the wet-process PU layer is 0.08mm-0.2mm, and the dry-process PU texture The thickness of the layer is 0.08mm-0.2mm, the thickness of the printing layer is 0.05mm-0.15mm, the thickness of the transparent PU adhesive layer is 0.05mm-0.15mm, and the thickness of the transparent polyurethane elastomer layer is 0.01mm -0.20mm.
作为本实用新型PU水晶镜面贴合结构的一种改进,所述基布层的厚度为0.2mm,所述湿法PU层的厚度为0.14mm,所述干法PU纹路层的厚度为0.14mm、所述印刷层的厚度为0.10mm,所述透明PU黏着层的厚度为0.10mm,所述透明聚氨酯弹性体层的厚度为0.12mm。As an improvement of the PU crystal mirror bonding structure of the utility model, the thickness of the base cloth layer is 0.2mm, the thickness of the wet PU layer is 0.14mm, and the thickness of the dry PU texture layer is 0.14mm , The thickness of the printing layer is 0.10mm, the thickness of the transparent PU adhesive layer is 0.10mm, and the thickness of the transparent polyurethane elastomer layer is 0.12mm.
作为本实用新型PU水晶镜面贴合结构的一种改进,所述透气微孔的孔径为1μm-30μm。As an improvement of the bonding structure of the PU crystal mirror surface of the utility model, the diameter of the air-permeable micropores is 1 μm-30 μm.
作为本实用新型PU水晶镜面贴合结构的一种改进,所述透气微孔的孔径为 5μm-15μm。As an improvement of the PU crystal mirror bonding structure of the utility model, the aperture of the air-permeable micropores is 5 μm-15 μm.
相对于现有技术,本实用新型至少具有如下优点:Compared with the prior art, the utility model has at least the following advantages:
第一,本实用新型采用透明聚氨酯弹性体层作为面层,其光泽柔和、自然,水晶感强,手感柔软,与印刷层粘接性能优异、抗磨损、耐挠曲、抗老化、抗霉菌性好,同时还具备耐寒性好、透气、可洗涤、加工方便、价格优廉等优点;First, the utility model uses a transparent polyurethane elastomer layer as the surface layer, which has soft and natural luster, strong crystal feeling, soft hand feeling, excellent adhesion to the printing layer, wear resistance, flex resistance, aging resistance, and mold resistance At the same time, it also has the advantages of good cold resistance, breathability, washability, convenient processing, and low price;
第二,本实用新型中的透明PU黏着层中含有很强极性和化学活泼性的-NCO-(异氰酸根)、-NHCOO-(氨基甲酸酯基团),与含有活泼氢的基材,甚至是表面光洁的材料都有优良的化学粘接力;而且其具备优异的抗剪切强度和抗冲击特性,并具备优异的柔韧特性;其还能适应不同热膨胀系数基材的粘合,其不仅粘接力强,同时还具有优异的缓冲、减震功能;Second, the transparent PU adhesive layer in the utility model contains -NCO-(isocyanate group) and -NHCOO-(carbamate group) with strong polarity and chemical activity, and the group containing active hydrogen Materials, even materials with smooth surfaces, have excellent chemical adhesion; and it has excellent shear strength and impact resistance, and has excellent flexibility; it can also adapt to the bonding of substrates with different thermal expansion coefficients , which not only has strong adhesive force, but also has excellent cushioning and shock absorption functions;
第三,制作本实用新型时,在干法PU纹路层的上方的表面上注入助剂再贴合透明聚氨酯弹性体层,应用化学及物理原理将气泡排挤出PU革表面,可以减少气泡的残留,提高通透度及收率,降低成本。Third, when making the utility model, inject additives on the surface above the dry-process PU texture layer and then paste the transparent polyurethane elastomer layer, apply chemical and physical principles to expel the air bubbles from the surface of the PU leather, which can reduce the residual air bubbles , improve transparency and yield, and reduce costs.
第四,本实用新型可根据客户需求进行调整设置,满足不同客户的不同需求,提供给客户更多的选择性,而且本实用新型可以适用于不同类型的纹路,从而为消费者提供更多的纹路图案选择,增加市场竞争力,满足客户需求。Fourth, the utility model can be adjusted and set according to customer needs to meet the different needs of different customers and provide customers with more options, and the utility model can be applied to different types of textures, thereby providing consumers with more The choice of grain patterns increases market competitiveness and meets customer needs.
第五,本实用新型的基布层具有透气性,从而提高了该结构的使用舒适性。Fifthly, the base fabric layer of the present invention has air permeability, thereby improving the comfort of use of the structure.
附图说明Description of drawings
图1为本实用新型的半成品的剖视结构示意图。Fig. 1 is a schematic cross-sectional structure diagram of a semi-finished product of the present invention.
图2为本实用新型制作过程中的剖视结构示意图。Fig. 2 is a schematic cross-sectional structure diagram during the manufacturing process of the utility model.
图3为本实用新型的成品的剖视结构示意图。Fig. 3 is a schematic cross-sectional structure diagram of the finished product of the present invention.
具体实施方式detailed description
如图1至图3所示,本实用新型提供的一种PU水晶镜面贴合结构,从下到上,PU水晶镜面贴合结构依次包括基布层1、湿法PU层2、干法PU纹路层3、印刷层4、透明PU黏着层5和透明聚氨酯弹性体层6,基布层1上设置有若干个透气微孔7,透明聚氨酯弹性体层6的厚度为0.001mm-0.30mm。其中,基布层1的材质为贝斯,湿法PU层2比较环保,而且生产出的合成革具有良好的透湿、透气性能。As shown in Figure 1 to Figure 3, a PU crystal mirror surface bonding structure provided by the utility model, from bottom to top, the PU crystal mirror surface bonding structure successively includes base cloth layer 1, wet process PU layer 2, dry process PU layer Texture layer 3, printing layer 4, transparent PU adhesive layer 5 and transparent polyurethane elastomer layer 6, the base fabric layer 1 is provided with several air-permeable micropores 7, and the thickness of the transparent polyurethane elastomer layer 6 is 0.001mm-0.30mm. Wherein, the base fabric layer 1 is made of bass, and the wet-process PU layer 2 is more environmentally friendly, and the produced synthetic leather has good moisture permeability and air permeability.
其中,透气微孔7的孔径为100nm-50μm,优选的,透气微孔7的孔径为1μm-30μm。更优选的,透气微孔的孔径为5μm-15μm。透气微孔7分布均匀,大小基本一致。Wherein, the pore diameter of the air-permeable micropore 7 is 100 nm-50 μm, preferably, the pore diameter of the air-permeable micro-pore 7 is 1 μm-30 μm. More preferably, the diameter of the air-permeable micropores is 5 μm-15 μm. The air-permeable micropores 7 are evenly distributed and basically the same in size.
基布层1的厚度为0.05mm-0.5mm,湿法PU层2的厚度为0.03mm-0.3mm,干法PU纹路层3的厚度为0.03mm-0.3mm、印刷层4的厚度为0.01mm-0.2mm,透明PU黏着层5的厚度为0.01mm-0.2mm。The thickness of base fabric layer 1 is 0.05mm-0.5mm, the thickness of wet-process PU layer 2 is 0.03mm-0.3mm, the thickness of dry-process PU texture layer 3 is 0.03mm-0.3mm, and the thickness of printing layer 4 is 0.01mm -0.2mm, the thickness of the transparent PU adhesive layer 5 is 0.01mm-0.2mm.
优选的,基布层1的厚度为0.1mm-0.3mm,湿法PU层2的厚度为0.08mm-0.2mm,干法PU纹路层3的厚度为0.08mm-0.2mm、印刷层4的厚度为0.05mm-0.15mm,透明PU黏着层5的厚度为0.05mm-0.15mm,透明聚氨酯弹性体层6的厚度为0.01mm-0.20mm。Preferably, the thickness of the base fabric layer 1 is 0.1mm-0.3mm, the thickness of the wet-process PU layer 2 is 0.08mm-0.2mm, the thickness of the dry-process PU texture layer 3 is 0.08mm-0.2mm, and the thickness of the printing layer 4 is 0.05mm-0.15mm, the thickness of the transparent PU adhesive layer 5 is 0.05mm-0.15mm, and the thickness of the transparent polyurethane elastomer layer 6 is 0.01mm-0.20mm.
更优选的,基布层1的厚度为0.2mm,湿法PU层2的厚度为0.14mm,干法PU纹路层3的厚度为0.14mm、印刷层4的厚度为0.10mm,透明PU黏着层5的厚度为0.10mm,透明聚氨酯弹性体层6的厚度为0.12mm。More preferably, the thickness of the base fabric layer 1 is 0.2mm, the thickness of the wet PU layer 2 is 0.14mm, the thickness of the dry PU texture layer 3 is 0.14mm, the thickness of the printing layer 4 is 0.10mm, and the transparent PU adhesive layer The thickness of 5 is 0.10mm, and the thickness of transparent polyurethane elastomer layer 6 is 0.12mm.
本实用新型的制作方法包括如下步骤:The preparation method of the present utility model comprises the following steps:
第一,半成品的制作:如图1所示,本实用新型的半成品包括基布层1,基布层1的上方涂覆有湿法PU层2,湿法PU层2的上方设置有干法PU纹路层3, 干法PU纹路层3的上方设置有印刷层4。其制备方法为:先将基布层1预湿,预湿液为10%~25%的DMF水溶液,预湿后,挤干烫平使基布层1含湿率保持在80%~95%,然后在预湿基布层1上涂覆PU湿法浆料再通过凝固―水洗―烘干等制程,制得PU湿法基材。其中,PU湿法浆料配方中的DMF于凝固过程中会与凝固槽中的水产生置换作用(水与DMF会互溶)而产生排列整齐的细泡孔如图1所示,此处凝固槽的浓度需特别保持一定的比例否则容易产生大小不一或过大或过小的泡孔而影响透气效果。基布层1和湿法PU层2的复合还可以提高其拉伸强度、剪切强度和抗撕裂性能。First, the making of semi-finished products: as shown in Figure 1, the semi-finished product of the present utility model comprises base cloth layer 1, and the top of base cloth layer 1 is coated with wet process PU layer 2, and the top of wet process PU layer 2 is provided with dry process The PU texture layer 3 is provided with a printing layer 4 above the dry process PU texture layer 3 . The preparation method is as follows: first pre-wet the base cloth layer 1, the pre-wet liquid is 10%-25% DMF aqueous solution, after pre-wetting, squeeze dry and iron to keep the moisture content of the base cloth layer 1 at 80%-95% , and then coat the PU wet-process slurry on the pre-wet base cloth layer 1, and then pass through coagulation-washing-drying processes to obtain the PU wet-process substrate. Among them, the DMF in the PU wet slurry formula will replace the water in the coagulation tank during the solidification process (water and DMF will dissolve each other) to produce neatly arranged fine cells as shown in Figure 1, where the coagulation tank It is necessary to maintain a certain ratio of concentration, otherwise it is easy to produce cells of different sizes or too large or too small, which will affect the ventilation effect. The compounding of the base cloth layer 1 and the wet-process PU layer 2 can also improve its tensile strength, shear strength and tear resistance.
然后再在湿法PU层2上方涂覆干法PU纹路层3,再在干法PU纹路层3上方套印双色印刷层4即完成本实用新型半成品的制作。Then coat the dry process PU texture layer 3 on the top of the wet process PU layer 2, and then overprint the two-color printing layer 4 on the top of the dry process PU texture layer 3 to complete the production of the semi-finished product of the present invention.
第二,成品的制作:如图2所示,在镜面离型纸上方涂覆透明的聚氨酯弹性体浆料后烘干,然后在透明聚氨酯弹性体层6上方涂覆透明聚氨酯粘合剂烘半干作为透明PU黏着层5,将半成品贴合在透明PU黏着层5之前,于干法PU纹路层3的表面上的印刷层4注入助剂再将印刷层4贴合于透明PU黏着层5,应用化学及物理原理将气泡排挤出PU革表面,即制得成品,如图3所示。The second, the making of finished product: as shown in Figure 2, dry after coating the transparent polyurethane elastomer slurry on the mirror surface release paper, then coat the transparent polyurethane adhesive on the transparent polyurethane elastomer layer 6 and bake half Dry as the transparent PU adhesive layer 5, before attaching the semi-finished product to the transparent PU adhesive layer 5, inject auxiliary agents into the printing layer 4 on the surface of the dry-process PU texture layer 3, and then attach the printing layer 4 to the transparent PU adhesive layer 5 , applying chemical and physical principles to expel the air bubbles out of the surface of PU leather, that is, the finished product is obtained, as shown in Figure 3.
总之,本实用新型至少具有如下优点:In a word, the utility model has the following advantages at least:
第一,本实用新型采用透明聚氨酯弹性体层6作为面层,其光泽柔和、自然,水晶感强,手感柔软,与印刷层粘接性能优异、抗磨损、耐挠曲、抗老化、抗霉菌性好,同时还具备耐寒性好、透气、可洗涤、加工方便、价格优廉等优点;First, the utility model adopts the transparent polyurethane elastomer layer 6 as the surface layer, which has soft and natural luster, strong crystal sense, soft hand feeling, excellent bonding performance with the printing layer, wear resistance, flex resistance, aging resistance and mold resistance Good durability, but also has the advantages of good cold resistance, breathable, washable, convenient processing, and low price;
第二,本实用新型中的透明PU黏着层5中含有很强极性和化学活泼性的-NCO-(异氰酸根)、-NHCOO-(氨基甲酸酯基团),与含有活泼氢的基材,甚 至是表面光洁的材料都有优良的化学粘接力;而且其具备优异的抗剪切强度和抗冲击特性,并具备优异的柔韧特性;其还能适应不同热膨胀系数基材的粘合,其不仅粘接力强,同时还具有优异的缓冲、减震功能;Second, the transparent PU adhesive layer 5 in the utility model contains -NCO-(isocyanate group) and -NHCOO-(carbamate group) of very strong polarity and chemical activity, and contains active hydrogen Substrates, even materials with smooth surfaces, have excellent chemical adhesion; and it has excellent shear strength and impact resistance, and has excellent flexibility; it can also adapt to the adhesion of substrates with different thermal expansion coefficients. It not only has strong adhesive force, but also has excellent cushioning and shock absorption functions;
第三,制作本实用新型时,在干法PU纹路层3的上方的表面上注入助剂再贴合透明聚氨酯弹性体层6,应用化学及物理原理将气泡排挤出PU革表面,可以减少气泡的残留,提高通透度及收率,降低成本。Third, when making the utility model, inject additives on the surface above the dry-process PU texture layer 3 and then paste the transparent polyurethane elastomer layer 6, apply chemical and physical principles to push the air bubbles out of the PU leather surface, which can reduce air bubbles residues, improve permeability and yield, and reduce costs.
第四,本实用新型可根据客户需求进行调整设置,满足不同客户的不同需求,提供给客户更多的选择性,而且本实用新型可以适用于不同类型的纹路,从而为消费者提供更多的纹路图案选择,增加市场竞争力,满足客户需求。Fourth, the utility model can be adjusted and set according to customer needs to meet the different needs of different customers and provide customers with more options, and the utility model can be applied to different types of textures, thereby providing consumers with more The choice of grain patterns increases market competitiveness and meets customer needs.
第五,本实用新型的基布层1具有透气性,从而提高了该结构的使用舒适性。Fifth, the base fabric layer 1 of the present invention has air permeability, thereby improving the comfort of use of the structure.
根据上述说明书的揭示和教导,本实用新型所属领域的技术人员还可以对上述实施方式进行适当的变更和修改。因此,本实用新型并不局限于上面揭示和描述的具体实施方式,对本实用新型的一些修改和变更也应当落入本实用新型的权利要求的保护范围内。此外,尽管本说明书中使用了一些特定的术语,但这些术语只是为了方便说明,并不对本实用新型构成任何限制。According to the disclosure and teaching of the above specification, those skilled in the art to which the present utility model belongs can also make appropriate changes and modifications to the above embodiment. Therefore, the utility model is not limited to the specific embodiments disclosed and described above, and some modifications and changes to the utility model should also fall within the scope of protection of the claims of the utility model. In addition, although some specific terms are used in this specification, these terms are only for convenience of description and do not constitute any limitation to the present utility model.
Claims (7)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620514894.0U CN205804016U (en) | 2016-05-30 | 2016-05-30 | A PU crystal mirror bonding structure |
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| CN201620514894.0U CN205804016U (en) | 2016-05-30 | 2016-05-30 | A PU crystal mirror bonding structure |
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| CN205804016U true CN205804016U (en) | 2016-12-14 |
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| CN201620514894.0U Expired - Fee Related CN205804016U (en) | 2016-05-30 | 2016-05-30 | A PU crystal mirror bonding structure |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107313264A (en) * | 2017-08-18 | 2017-11-03 | 安徽安利材料科技股份有限公司 | A kind of preparation method of the double processing procedure mirror crystal leathers of environmental protection |
| CN108454183A (en) * | 2018-05-22 | 2018-08-28 | 乐昌市翔辉皮革有限公司 | A kind of Water-proof breathable fabric and preparation method thereof |
| CN114474942A (en) * | 2021-12-28 | 2022-05-13 | 盛国(东莞)新材料科技有限公司 | Method for manufacturing crystal mirror leather |
| CN114517416A (en) * | 2021-12-24 | 2022-05-20 | 盛国(东莞)新材料科技有限公司 | PU double-layer crystal mirror surface leather and laminating method thereof |
-
2016
- 2016-05-30 CN CN201620514894.0U patent/CN205804016U/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107313264A (en) * | 2017-08-18 | 2017-11-03 | 安徽安利材料科技股份有限公司 | A kind of preparation method of the double processing procedure mirror crystal leathers of environmental protection |
| CN108454183A (en) * | 2018-05-22 | 2018-08-28 | 乐昌市翔辉皮革有限公司 | A kind of Water-proof breathable fabric and preparation method thereof |
| CN114517416A (en) * | 2021-12-24 | 2022-05-20 | 盛国(东莞)新材料科技有限公司 | PU double-layer crystal mirror surface leather and laminating method thereof |
| CN114474942A (en) * | 2021-12-28 | 2022-05-13 | 盛国(东莞)新材料科技有限公司 | Method for manufacturing crystal mirror leather |
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| C14 | Grant of patent or utility model | ||
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Address after: 523000 Guangdong city in Dongguan Province town of Kau Kau village industrial zone Luo electric Patentee after: Shengguo (Dongguan) New Material Technology Co.,Ltd. Address before: 523000 Guangdong city in Dongguan Province town of Kau Kau village industrial zone Luo electric Patentee before: DONGGUAN SUNGOAL LEATHER Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20161214 |