CN205760609U - A kind of device for low-temperature plasma synergistic catalysis treatment organic exhaust gas - Google Patents
A kind of device for low-temperature plasma synergistic catalysis treatment organic exhaust gas Download PDFInfo
- Publication number
- CN205760609U CN205760609U CN201620065657.0U CN201620065657U CN205760609U CN 205760609 U CN205760609 U CN 205760609U CN 201620065657 U CN201620065657 U CN 201620065657U CN 205760609 U CN205760609 U CN 205760609U
- Authority
- CN
- China
- Prior art keywords
- low
- temperature plasma
- exhaust gas
- plasma synergistic
- organic exhaust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 210000002381 Plasma Anatomy 0.000 title claims abstract description 60
- 230000002195 synergetic Effects 0.000 title claims abstract description 35
- 238000006555 catalytic reaction Methods 0.000 title claims abstract description 24
- 230000003197 catalytic Effects 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 239000003054 catalyst Substances 0.000 claims description 20
- 238000007599 discharging Methods 0.000 claims description 7
- 239000000969 carrier Substances 0.000 claims description 5
- 229910000510 noble metal Inorganic materials 0.000 claims description 3
- 239000002912 waste gas Substances 0.000 abstract description 6
- 238000000746 purification Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 description 14
- 239000007789 gas Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound 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[O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Abstract
The utility model discloses a kind of device for low-temperature plasma synergistic catalysis treatment organic exhaust gas, including the pretreatment unit set gradually, low-temperature plasma synergistic catalytic unit, adsorption reaction device and air-introduced machine, the outlet side of described air-introduced machine arranges discharge tower.This utility model is high to organic waste-gas purification efficiency, effective, is affected little by various environment and external condition, the biggest flow, low concentration, the organic exhaust gas of complicated component, and purification efficiency is high.
Description
Technical field
This utility model relates to environmental project and plasma science technical field, more specifically to one for low
The device of organic exhaust gas is administered in isothermal plasma concerted catalysis.
Background technology
Along with socioeconomic development, the continuous quickening of process of industrialization, environment and energy problem are increasingly subject to people
Concern.Large-scale commercial production and the discharge of people's daily life, can produce a large amount of organic exhaust gas in various degree,
The living environment of the mankind is caused serious threat.At present, major part industrial organic exhaust gas has low concentration, Wind Volume, many
The features such as component, traditional Processing tecchnics can not reach to administer requirement.
Traditional administering method includes absorption process, absorption method, condensation method and bioanalysis.The investment cost of activated carbon adsorption is relatively
Low, and high treating effect, it is the most frequently used VOCs treatment engineering.But due to activated carbon adsorption saturated after need
Regeneration, so the operating cost of employing activated carbon adsorption is higher, and operating process is complicated.Bioremediation investment and running cost
With the most relatively low, but running operation complexity, floor space is big, there is the probability of secondary pollution.Catalytic combustion method also exists suction
Attached concentration is desorbed the process of burning again, and equipment volume is relatively big, and catalyst price is high, once invests the problems such as big.
In recent years, lower temperature plasma technology has caused increasing concern, and plasma is referred to as except solid-state, liquid
The 4th kind of material existing forms outside state and gaseous state, is made up of electronics, ion, free radical and neutral particle, overall guarantor
Hold electric neutrality.In low-temperature plasma body, there is O, OH isoreactivity particle that substantial amounts of high energy electron and high energy electron produce,
Then cause the physics of series of complex, chemical reaction, make the macromolecule contaminant of complexity be changed into simple small-molecule substance,
Or make poisonous and harmful substance be changed into nontoxic or low toxicity low pest matter, the removal so that pollutant are degraded.Low temperature etc.
Gas ions technology has that technique is simple, handling process is short, small investment, occupation of land is little, clearance is high, operating cost is low (mainly shows
For the electricity charge), the feature such as applied widely.
When utilizing Low Temperature Plasma Treating organic exhaust gas and foul waste gas, also there is also some problems: 1, put relatively low
Under piezoelectric voltage, inefficient to some constitutionally stable voc_s removals；2, the dusty gas time of staying is short；3, plasma
The higher intermediate product of toxicity can be produced in purification process or it is the intermediate product than original molecule more difficult degradation, there is oxygen
Change not exclusively and ozone remains the problem causing secondary pollution.
For the deficiency of above-mentioned single plasma treatment technique, we have proposed plasma body cooperative catalytic adsorption skill
Art.This utility model is plasma, be catalyzed and adsorb the advantage superposition of three big technology, inferior position is complementary efficiently removes organic waste
Gas technology.The purpose of this utility model is to provide a kind of low temperature plasma and catalyst combined removal organic exhaust gas integrated technology
And application.
Utility model content
For the process of the organic exhaust gas of low concentration, atm number, complicated component in current industrial organic exhaust gas, it is provided that a kind of
Device for low-temperature plasma synergistic catalysis treatment organic exhaust gas.
In order to realize above-mentioned technical purpose, this utility model adopts the following technical scheme that: a kind of for low temperature plasma
The device of organic exhaust gas is administered in concerted catalysis, including the pretreatment unit set gradually, low-temperature plasma synergistic catalysis dress
Put, adsorption reaction device and air-introduced machine, the outlet side of described air-introduced machine arranges discharge tower.
Further, described low-temperature plasma synergistic catalytic unit includes housing, and the bottom of described housing is arranged props up
Spike, one end of described housing arranges air inlet, arranges low-temperature plasma synergistic catalysis region of discharge, described shell in described housing
The other end of body arranges air outlet, and the sidewall of described housing arranges installing port.
Further, low-temperature plasma synergistic catalysis region is low-temperature plasma synergistic catalytic unit and catalyst collection
Integral, the emergence pattern of described low temperature plasma uses double-dielectric barrier discharge pattern, and described catalyst carrier is fixed on
Discharge of plasma in low temperature district.
Further, described low-temperature plasma synergistic catalytic unit uses palisade discharging structure, and described palisade discharges
Structure vertical is placed in organic exhaust gas and enters passage, and described discharge power supply uses high voltagehigh frequency discharge power supply, and described catalyst is
Noble metal.
Further, described high voltagehigh frequency discharge power supply input power is 220VAC, 50Hz, and it exports High Level AC Voltage
Source voltage peak is 10kV, and high-tension transformer includes oil-immersed type transformer and dry-type transformer.
Technical characterstic of the present utility model and effect be:
1) catalyst is placed in plasma discharge by this utility model, and adsorption treatment has been done again in rear end.Avoid
Simple plasma or adsorption system for the abundant not of VOCs treatment and absorb incomplete problem.It is greatly improved
The effect of waste gas pollution control and treatment.
2) this utility model uses technology and device are applicable to the organic exhaust gas of low concentration, atm number, complicated component
Process.
3) react at normal temperatures, it is not necessary to increase burning and heat riser.
4) catalyst plays the effect reducing reaction activity in the middle of low temperature plasma, and provides a reaction
Space so that active substance and organic molecule fast reaction.An adsorption reaction district is added in rear end so that unreacted is completely
Material continues reaction, process more complete, will not produce secondary pollution.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Fig. 2 is the structural representation of low-temperature plasma synergistic catalytic unit.
Wherein, 1, pretreatment system；2, low-temperature plasma synergistic catalytic unit；3, adsorption reaction device；4, air-introduced machine；
5, discharge tower；6, air inlet；7, device case；8, installing port；9, low-temperature plasma synergistic catalysis region of discharge；10, air outlet；
11, device props up spike.
Detailed description of the invention
In order to make the purpose of this utility model, technical scheme and advantage clearer, below in conjunction with embodiment, to this
Utility model is further elaborated.Should be appreciated that specific embodiment described herein is only in order to explain this practicality
Novel, it is not used to limit this utility model.
This utility model provides a kind of device for low-temperature plasma synergistic catalysis treatment organic exhaust gas, its pretreatment
System includes cooling process, dust removal process and dehumidification treatments.
Refer to Fig. 1 and Fig. 2, it is preferable that include pretreatment unit 1, the low-temperature plasma synergistic catalysis set gradually
Device 2, adsorption reaction device 3 and air-introduced machine 4, the outlet side of air-introduced machine 4 arranges discharge tower 5.
Refer to Fig. 1 and Fig. 2, it is preferable that low-temperature plasma synergistic catalytic unit 2 includes housing 7, the end of housing 7
End arranges a spike 11, and one end of housing 7 arranges air inlet 6, arranges low-temperature plasma synergistic catalysis region of discharge 9 in housing 7,
The other end of housing 7 arranges air outlet 10, and the sidewall of housing 7 arranges installing port 8.
Refer to Fig. 1 and Fig. 2, it is preferable that the low-temperature plasma synergistic catalysis region in step 2 is low temperature plasma
Concerted catalysis device 2 and catalyst are integrated, and the emergence pattern of low temperature plasma uses double-dielectric barrier discharge pattern, urges
Agent carrier is fixed on discharge of plasma in low temperature district.
Refer to Fig. 1 and Fig. 2, it is preferable that low-temperature plasma synergistic catalytic unit 2 uses planar discharging structure, planar
Discharging structure vertical pendulum is placed on organic exhaust gas and enters passage, and discharge power supply uses high voltagehigh frequency discharge power supply, and your gold catalyst is
Belong to.
Refer to Fig. 1 and Fig. 2, it is preferable that high voltagehigh frequency discharge power supply input power is 220VAC, 50Hz, it exports height
Pressure AC supply voltage peak value is 10kV, and high-tension transformer includes oil-immersed type transformer and dry-type transformer.
Refer to Fig. 1 and Fig. 2, it is preferable that planar discharging structure is the discharge module of a standard, according to processing waste gas
The parameter determination discharge module quantity such as kind, air quantity, concentration, put the number of plies etc..
Refer to Fig. 1, it is preferable that pretreatment system includes cooling process, dust removal process and dehumidification treatments.
The organic exhaust gas collected is entered in pretreatment system by pipeline, and pretreatment system includes waste gas cooling system, removes
Dirt equipment and dehumidification equipment, can be device systems or how many integration of equipments so that pretreated organic exhaust gas
Temperature, humidity, amount of dust are in optimal condition under low-temperature plasma synergistic catalytic action；
Pretreated gas sends into low-temperature plasma synergistic catalytic unit, utilizes low-temperature plasma synergistic catalysis to make
Decompose with organic exhaust gas, generate harmless little molecule.
Discharge of plasma in low temperature module uses high-frequency and high-voltage power supply electric discharge, high-frequency and high-voltage power supply input requirements civil power
220VAC, 50Hz, export and be connected to face discharge module by high tension cable, and output peak value controls at below 10KV, FREQUENCY CONTROL
At 10KHz 20KHz；This discharge power supply is in hgher efficiency, under the conditions of the low temperature plasma producing same energy density, and energy consumption
Less.
Gas after being processed by low temperature plasma body concerted catalysis equipment sends into adsorption reaction device by airduct, utilizes
Organic molecule that adsorbent reacts the most completely and high energy species, make the further oxidation Decomposition of organic molecule.This adsorption reaction
District uses adsorbent as matrix, generally uses cellular modular structure, windage installation less, more convenient and replacing.
Free of contamination gas after decomposing oxidation by air-introduced machine and discharges tower qualified discharge.
Low-temperature plasma synergistic catalytic unit uses square structure, can use either in a horizontal or vertical structure, enters dress
The gas putting inside is evenly distributed on device interior by shunting, then immediately proceeds to low-temperature plasma synergistic catalysis electric discharge
District, this electric discharge uses double-dielectric barrier discharge pattern, and discharge module uses face discharging structure, the gas face passed through electric discharge mould
Block, face discharge module at least one of which is covered with equipment cross section, and catalyst carrier is fixed on discharge of plasma in low temperature district；Catalyst is adopted
Use noble metal catalyst.A series of touching is there is in the high energy active electrons that electrion produces with the steam in air, oxygen etc.
Hit reaction and generate short-life high activity particle O, HO and superoxide ion etc..Short-life active particle carries out weight further
Group generates such as O3And H2O2On these long-life high activity particles.High activity particle has certain polarization for catalyst surface
Effect so that catalyst surface more uniformly refines, and improves the catalytic performance of catalyst.Catalyst carrier itself also has one
Fixed adsorption, is adsorbed onto surface by contaminant gases and active particle, it is provided that the space needed for reaction, extend reaction time
Between, reduce the activation energy of reaction, organic gas is degraded to small-molecule substance.This utility model is to organic waste-gas purification efficiency
Height, effective, affected little by various environment and external condition, the biggest flow, low concentration, the organic waste of complicated component
Gas, purification efficiency is high.
The foregoing is only preferred embodiment of the present utility model, not in order to limit this utility model, all at this
Any amendment, equivalent and the improvement etc. made within the spirit of utility model and principle, should be included in this utility model
Protection domain within.
Claims (4)
1. the device for low-temperature plasma synergistic catalysis treatment organic exhaust gas, it is characterised in that: include setting gradually
Pretreatment unit (1), low-temperature plasma synergistic catalytic unit (2), adsorption reaction device (3) and air-introduced machine (4), described in draw
The outlet side of blower fan (4) arranges discharge tower (5)；
Described low-temperature plasma synergistic catalytic unit (2) includes housing (7), and the bottom of described housing (7) arranges a spike
(11), one end of described housing (7) arranges air inlet (6), arranges low-temperature plasma synergistic catalysis electric discharge in described housing (7)
District (9), the other end of described housing (7) arranges air outlet (10), and the sidewall of described housing (7) arranges installing port (8).
Device for low-temperature plasma synergistic catalysis treatment organic exhaust gas the most according to claim 1, its feature exists
In: low-temperature plasma synergistic catalysis region be low-temperature plasma synergistic catalytic unit (2) and catalyst integrated, described
The emergence pattern of low temperature plasma uses double-dielectric barrier discharge pattern, and described catalyst carrier is fixed on low temperature plasma
Region of discharge.
Device for low-temperature plasma synergistic catalysis treatment organic exhaust gas the most according to claim 1, its feature exists
In: described low-temperature plasma synergistic catalytic unit (2) uses palisade discharging structure, and described palisade discharging structure is vertically put
Entering passage at organic exhaust gas, described discharge power supply uses high voltagehigh frequency discharge power supply, and described catalyst is noble metal catalyst.
Device for low-temperature plasma synergistic catalysis treatment organic exhaust gas the most according to claim 3, its feature exists
In: described high voltagehigh frequency discharge power supply input power is 220VAC, 50Hz, and its output high-voltage ac power voltage peak is
10kV, high-tension transformer includes oil-immersed type transformer and dry-type transformer.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107126822A (en) * | 2017-07-04 | 2017-09-05 | 长沙稻冰工程技术有限公司 | Gas cleaning plant |
| CN109621706A (en) * | 2018-12-18 | 2019-04-16 | 西安交通大学 | A kind of coal chemical industry VOCs integrated treatment and heat energy utilization system and method |
| CN110302659A (en) * | 2019-07-29 | 2019-10-08 | 中科新天地（合肥）环保科技有限公司 | Low-temperature plasma synergistic biological treating waste gas system |
-
2016
- 2016-01-22 CN CN201620065657.0U patent/CN205760609U/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107126822A (en) * | 2017-07-04 | 2017-09-05 | 长沙稻冰工程技术有限公司 | Gas cleaning plant |
| CN109621706A (en) * | 2018-12-18 | 2019-04-16 | 西安交通大学 | A kind of coal chemical industry VOCs integrated treatment and heat energy utilization system and method |
| CN109621706B (en) * | 2018-12-18 | 2020-05-19 | 西安交通大学 | System and method for comprehensive treatment and heat energy utilization of VOCs in coal chemical industry |
| CN110302659A (en) * | 2019-07-29 | 2019-10-08 | 中科新天地（合肥）环保科技有限公司 | Low-temperature plasma synergistic biological treating waste gas system |
| CN110302659B (en) * | 2019-07-29 | 2022-03-11 | 中科新天地（合肥）环保科技有限公司 | Low-temperature plasma synergistic biological waste gas treatment system |
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