CN205676349U - Ozone microbubble floatation thickening device - Google Patents
Ozone microbubble floatation thickening device Download PDFInfo
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- CN205676349U CN205676349U CN201620580538.9U CN201620580538U CN205676349U CN 205676349 U CN205676349 U CN 205676349U CN 201620580538 U CN201620580538 U CN 201620580538U CN 205676349 U CN205676349 U CN 205676349U
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Abstract
本实用新型公开了一种臭氧微气泡气浮浓缩装置。该装置包括反应槽、臭氧发生器、除渣机、集渣槽,在反应槽上方并排设置4‑6组串联的涡流三相混合器。污泥通过加压进水泵送入多级涡流三相混合器中形成涡流;臭氧通过气体增压泵或空压机送入第一级涡流三相混合器内;PAM药剂通过药剂投加泵送入第二级或第三级涡流三相混合器内;在多级涡流三相混合器中,药剂与污染物颗粒、水、气三相接触混合,涡流产生微气泡形成絮体;絮体中夹带气泡上浮到液面上形成浮渣。本实用新型通过多级涡流三相混合器以及臭氧的强化氧化作用实现了污泥调质,同时能够获得含水率90~95%的气浮浮渣,利于后续超高压弹性压榨机或板框脱水机脱水。
This invention discloses an ozone microbubble flotation concentration device. The device includes a reaction tank, an ozone generator, a sludge remover, and a sludge collection tank. Four to six sets of series-connected vortex three-phase mixers are arranged side-by-side above the reaction tank. Sludge is fed into the multi-stage vortex three-phase mixers via a pressurized inlet pump to form vortices. Ozone is fed into the first-stage vortex three-phase mixer via a gas booster pump or air compressor. PAM reagent is fed into the second or third-stage vortex three-phase mixer via a reagent dosing pump. In the multi-stage vortex three-phase mixers, the reagent comes into contact with and mixes with pollutant particles, water, and gas, generating microbubbles that form flocs. The flocs, carrying bubbles, float to the liquid surface to form scum. This invention achieves sludge conditioning through the multi-stage vortex three-phase mixer and the enhanced oxidation effect of ozone, while simultaneously obtaining flotation scum with a moisture content of 90-95%, which is beneficial for subsequent dewatering by an ultra-high pressure elastic press or plate and frame dewatering machine.
Description
技术领域technical field
本实用新型属于污泥处理技术领域,涉及一种臭氧微气泡气浮浓缩装置,适用于污泥调质、浓缩,经过调质浓缩后的浮渣进入超高压弹性压榨机进行压榨脱水。The utility model belongs to the technical field of sludge treatment, and relates to an ozone micro-bubble air flotation concentration device, which is suitable for conditioning and concentration of sludge, and the scum after conditioning and concentration enters an ultra-high pressure elastic press for pressing and dehydration.
背景技术Background technique
污泥是污水处理后的产物,是一种由有机残片、细菌菌体、无机颗粒、胶体等组成的极其复杂的非均质体。污泥的主要特性是含水率高(可高达99%以上),有机物含量高,容易腐化发臭,并且颗粒较细,比重较小,呈胶状液态,它是介于液体和固体之间的浓稠物。近年来,随着我国经济和污水处理技术的快速发展,产生的污泥量也随之快速提高,由此带来的污泥处理处置问题日益引起重视。由于污水处理厂污泥含水率高,产生量大,体积大、易产生恶臭,在污泥处理中最重要的环节就是进行污泥脱水,将污泥中的固、液相分离,目前污水处理厂的污泥大部分采用机械脱水,尤其是超高压弹性压榨机或板框脱水机脱水。一般的活性污泥(指活性污泥法处理工艺二沉池产生的沉淀物),其含水率高达99%左右。当污泥含水率由99%降至95%时,污泥的体积可缩小到原来的1/5。对污泥有效地、经济地进一步处理,减少其储存占地,须先进行污泥浓缩。Sludge is the product of sewage treatment, which is an extremely complex heterogeneous body composed of organic debris, bacterial cells, inorganic particles, colloids, etc. The main characteristics of sludge are high water content (up to 99%), high organic content, easy to rot and smell, and fine particles, small specific gravity, colloidal liquid, it is between liquid and solid Thickness. In recent years, with the rapid development of my country's economy and sewage treatment technology, the amount of sludge produced has also increased rapidly, and the resulting sludge treatment and disposal issues have attracted increasing attention. Due to the high moisture content of sludge in sewage treatment plants, large volume, large volume, and easy to produce foul odor, the most important link in sludge treatment is to dehydrate the sludge and separate the solid and liquid phases in the sludge. Currently, sewage treatment Most of the sludge in the plant is dewatered mechanically, especially with ultra-high pressure elastic presses or plate and frame dehydrators. Ordinary activated sludge (referring to the sediment produced in the secondary sedimentation tank of the activated sludge treatment process) has a moisture content of about 99%. When the water content of the sludge is reduced from 99% to 95%, the volume of the sludge can be reduced to 1/5 of the original. To effectively and economically further treat sludge and reduce its storage area, sludge concentration must be carried out first.
为了提高超高压弹性压榨机或板框脱水机脱水的效率,也要先对污泥进行浓缩。国内最早采用的是重力浓缩(沉淀)方式,该种浓缩方式浓缩后的污泥含水率一般为95~97%,存在占地面积较大、浓缩效果较差、浓缩后污泥含水率高,易发酵产生臭气等缺陷,限制了其发展。目前污水处理厂常用的污泥浓缩方式是采用机械浓缩,如螺旋压榨式、带式浓缩机等,该种浓缩方式虽然占地面积小,周围环境影响小,但其造价高,电耗高,尤其是该种浓缩方式的出泥含水率高,PAM投加率高,设备故障率高,还存在冲洗水量大等问题,也限制了其发展。In order to improve the dehydration efficiency of the ultra-high pressure elastic press or the plate and frame dehydrator, the sludge should also be concentrated first. The gravity concentration (precipitation) method was first adopted in China. The moisture content of the sludge after concentration in this concentration method is generally 95 to 97%. However, it occupies a large area, the concentration effect is poor, and the sludge moisture content after concentration is high. Defects such as easy fermentation to produce odor limit its development. At present, the sludge concentration method commonly used in sewage treatment plants is to use mechanical concentration, such as screw press type, belt type thickener, etc. Although this concentration method occupies a small area and has little impact on the surrounding environment, it has high cost and high power consumption. In particular, this kind of concentration method has problems such as high water content of mud output, high PAM dosing rate, high equipment failure rate, and large amount of flushing water, which also limits its development.
为了改善污泥的脱水性能,在污泥泵入超高压弹性压榨机或板框脱水机脱水前,还要进行污泥调质处理。常用的调理方式为铁盐+石灰的调理方式,但这种调理方式引入了重金属铁离子、钙离子,并增加了污泥干基,不利于后续的污泥处理和处置。In order to improve the dewatering performance of the sludge, before the sludge is pumped into the ultra-high pressure elastic press or the plate and frame dehydrator for dehydration, the sludge conditioning treatment is also carried out. The commonly used conditioning method is the conditioning method of iron salt + lime, but this conditioning method introduces heavy metal iron ions and calcium ions, and increases the dry basis of sludge, which is not conducive to subsequent sludge treatment and disposal.
随着我国城市发展需要,土地资源紧缺,极其需要一种占地面积小,处理效果显著,处理后污泥含水率低的新型污泥浓缩装置及污泥调质浓缩方法。With the need of urban development in our country and the shortage of land resources, a new type of sludge thickening device and sludge conditioning and thickening method with small footprint, remarkable treatment effect and low water content of treated sludge is extremely needed.
实用新型内容Utility model content
本实用新型的目的在于克服现有技术的不足,提供一种臭氧微气泡气浮浓缩装置,以解决现有技术中的污泥调质方法不合理、污泥浓缩干度不高的问题,实现污泥调质+高干度浓缩同步进行,以利于后续污泥的超高压弹性压榨或板框脱水机脱水。The purpose of the utility model is to overcome the deficiencies of the prior art, and provide an ozone micro-bubble air flotation concentration device to solve the problems of the unreasonable sludge conditioning method and the low dryness of the sludge concentration in the prior art, and realize Sludge conditioning + high dryness concentration are carried out simultaneously to facilitate subsequent sludge ultra-high pressure elastic pressing or plate and frame dehydrator dehydration.
本实用新型的技术方案如下:The technical scheme of the utility model is as follows:
一种臭氧微气泡气浮浓缩装置,它包括一反应槽,在反应槽上方并排设置4~6组(4~6级)串联的涡流三相混合器,靠出水侧为第一级,靠进水侧为最后一级,(即从出水侧到进水侧依次排列为第一级、第二级……第N级),每级涡流三相混合器内设有一级反应器;反应槽从进水侧到出水侧由堰板分隔成三个室:接触室、分离室和清水收集室;分离室上方设置除渣机,除渣机另一端下方设置集渣槽;总进水管一端与进水泵出口连接,另一端与第一级涡流三相混合器的侧面进水口连接;第一级涡流三相混合器的底部出水口与第二级涡流三相混合器的侧面进水口连接;……以此类推,前一级涡流三相混合器的底部出水口与后一级涡流三相混合器的侧面进水口连接;最后一级涡流三相混合器的底部出水口直接连接一根释放管;释放管出口位于反应槽接触室下部;每一级涡流三相混合器的侧面进水口处的进水管上设有旁通注入管;药剂制备装置出口与药剂投加泵入口连接;进药管一端与药剂投加泵出口连接,进药管另一端分别与第二级、第三级涡流三相混合器的侧面进水口处的旁通注入管连接;臭氧发生器出口与气体增压泵或空压机入口连接;进气管一端与气体增压泵或空压机出口连接,另一端与第一级涡流三相混合器的顶部进气口连接;第三级涡流三相混合器的顶部出气口连接一根排气管;排气管上设有排气阀。An ozone micro-bubble air flotation concentration device, which includes a reaction tank, 4 to 6 groups (4 to 6 stages) of vortex three-phase mixers connected in series are arranged side by side above the reaction tank, the first stage is the side near the water outlet, and the first stage is near the inlet. The water side is the last stage, (that is, the first stage, the second stage...the Nth stage are arranged in sequence from the water outlet side to the water inlet side), and each stage of the vortex three-phase mixer is equipped with a first-stage reactor; the reaction tank is from The water inlet side and the water outlet side are divided into three rooms by the weir plate: the contact room, the separation room and the clean water collection room; the slag remover is set above the separation room, and the slag collection tank is set under the other end of the slag remover; one end of the main water inlet pipe is connected to the water inlet The outlet of the water pump is connected, and the other end is connected to the side water inlet of the first-stage vortex three-phase mixer; the bottom water outlet of the first-stage vortex three-phase mixer is connected to the side water inlet of the second-stage vortex three-phase mixer;... By analogy, the bottom water outlet of the previous stage vortex three-phase mixer is connected to the side water inlet of the latter stage vortex three-phase mixer; the bottom water outlet of the last stage vortex three-phase mixer is directly connected to a release pipe; The outlet of the release pipe is located at the lower part of the contact chamber of the reaction tank; the water inlet pipe at the side water inlet of each stage of the vortex three-phase mixer is provided with a bypass injection pipe; the outlet of the drug preparation device is connected to the inlet of the drug dosing pump; one end of the drug inlet pipe is It is connected to the outlet of the chemical dosing pump, and the other end of the drug inlet pipe is respectively connected to the bypass injection pipe at the side water inlet of the second and third stage vortex three-phase mixers; the outlet of the ozone generator is connected to the gas booster pump or air The inlet of the compressor is connected; one end of the inlet pipe is connected to the outlet of the gas booster pump or air compressor, and the other end is connected to the top air inlet of the first-stage vortex three-phase mixer; the top air outlet of the third-stage vortex three-phase mixer Connect an exhaust pipe; the exhaust pipe is provided with an exhaust valve.
进一步地,分离室上方设置除渣机,除渣机另一端水平延伸至集渣槽上方;集渣槽的顶部低于涡流三相混合器的底部;集渣槽下部一大半是倾斜的,倾斜底位于清水收集室上方。Further, a slag remover is installed above the separation chamber, and the other end of the slag remover extends horizontally above the slag collection tank; the top of the slag collection tank is lower than the bottom of the vortex three-phase mixer; more than half of the lower part of the slag collection tank is inclined, The bottom is located above the clean water collection chamber.
进一步地,每一级涡流三相混合器的侧面进水口处的进水管与旁通注入管垂直。Further, the water inlet pipe at the side water inlet of each stage vortex three-phase mixer is perpendicular to the bypass injection pipe.
更进一步地,总进水管上设有流量计;每一级涡流三相混合器顶部均设有压力表。进气管上设有进气阀,进气阀之后还设有单向阀。进药管上也设有单向阀。集渣槽上设有液位计。Furthermore, a flow meter is provided on the main water inlet pipe; a pressure gauge is provided on the top of each vortex three-phase mixer. An intake valve is arranged on the intake pipe, and a check valve is also arranged behind the intake valve. A one-way valve is also arranged on the drug inlet pipe. A liquid level gauge is provided on the slag collecting tank.
一种利用上述臭氧微气泡气浮浓缩装置进行的污泥调质浓缩方法如下:A method for conditioning and concentrating sludge using the above-mentioned ozone microbubble air flotation concentration device is as follows:
污泥(包括生活污水污泥、工业废水污泥、给水污泥)使用加压进水泵,通过进水管,输送入多级涡流三相混合器中形成涡流,即从第一级涡流三相混合器依次逐个进入后面几级涡流三相混合器中;臭氧由臭氧发生器制备完成后,通过气体增压泵或空压机压缩,提升臭氧气体的压力后,通过进气管输送入第一级涡流三相混合器内;PAM药剂(聚丙烯酰胺)经药剂制备装置制备好后,使用加压药剂投加泵,通过进药管,投加在第二级和第三级涡流三相混合器上,从涡流三相混合器的侧面进水口处的旁通注入管注入(垂直于水流方向注入或斜向注入);在反应槽的接触室内的多级涡流三相混合器中,加压臭氧直接溶解在入流废水中,紧接着PAM药剂直接投加至溶气液中,药剂与污染物颗粒(固体)、水、气三相接触混合,涡流产生微气泡并植入污染物中,污染物被捕集,形成絮体;在分离室內,絮体中夹带气泡,上浮到液面上形成浮渣,完成固液分离;利用除渣机自动去除浮渣,浮渣进入集渣槽收集或处理;在清水收集室收集清水,由反应槽底部排出。Sludge (including domestic sewage sludge, industrial wastewater sludge, and water supply sludge) is transported into a multi-stage vortex three-phase mixer through a water inlet pipe through a pressurized water inlet pump to form a vortex, that is, from the first stage vortex three-phase mixing After the ozone is prepared by the ozone generator, it is compressed by a gas booster pump or an air compressor to increase the pressure of the ozone gas, and then it is transported into the first-stage vortex through the intake pipe. In the three-phase mixer; after the PAM agent (polyacrylamide) is prepared by the agent preparation device, the pressurized agent dosing pump is used to add it to the second-stage and third-stage vortex three-phase mixer through the drug inlet pipe , injected from the bypass injection pipe at the side water inlet of the vortex three-phase mixer (injection perpendicular to the water flow direction or oblique injection); in the multi-stage vortex three-phase mixer in the contact chamber of the reaction tank, the pressurized ozone is directly Dissolved in the influent wastewater, and then the PAM agent is directly added to the air-dissolved liquid. The agent contacts and mixes with the pollutant particles (solid), water, and gas in three-phase contact. The eddy current generates microbubbles and implants them in the pollutants. Collect and form flocs; in the separation chamber, air bubbles are entrained in the flocs, which float up to the liquid surface to form scum and complete solid-liquid separation; use the scum remover to automatically remove the scum, and the scum enters the slag collection tank for collection or treatment; The clean water is collected in the clean water collection chamber and discharged from the bottom of the reaction tank.
含水率为98.5~99.5%的污泥(生活污水污泥、工业废水污泥或给水污泥),经过该臭氧微气泡气浮浓缩装置进行调质、浓缩处理后,获得较高干度的浮渣,该气浮浮渣的含水率为90~95%;该调质后的浮渣无需添加任何药剂,可直接输送至超高压弹性压榨机进行压榨,压榨后的泥饼含水率能达到55~65%。Sludge with a water content of 98.5-99.5% (domestic sewage sludge, industrial wastewater sludge or water supply sludge), after conditioning and concentration treatment by the ozone micro-bubble air flotation concentration device, a higher dryness flotation concentration can be obtained. The water content of the air-floated scum is 90-95%. The scum after conditioning can be directly transported to the ultra-high pressure elastic press for pressing without adding any chemicals. The water content of the mud cake after pressing can reach 55%. ~65%.
进水泵设置在总进水管路上,进水泵压力为0.6~0.9Mpa;第一级涡流三相混合器的压力最高(0.6~0.9Mpa),后面几级涡流三相混合器内的压力依次逐个递减。The water inlet pump is set on the main water inlet pipeline, and the pressure of the water inlet pump is 0.6-0.9Mpa; the pressure of the first-stage vortex three-phase mixer is the highest (0.6-0.9Mpa), and the pressure in the following vortex three-phase mixers decreases one by one. .
PAM药剂(聚丙烯酰胺)制备好后,使用加压药剂投加泵,投加在第二级或第三级涡流三相混合器上;PAM药剂投加泵的投加压力稍大于进水泵压力(即稍大于0.6~0.9MPa)。PAM药剂的投加量为0.002~0.006gPAM/gDS(干污泥)。After the PAM agent (polyacrylamide) is prepared, use the pressurized agent dosing pump to add it to the second or third stage vortex three-phase mixer; the dosing pressure of the PAM agent dosing pump is slightly higher than the pressure of the water inlet pump (ie slightly larger than 0.6 ~ 0.9MPa). The dosage of PAM agent is 0.002~0.006gPAM/gDS (dry sludge).
该气浮浓缩装置中设有臭氧制备投加装置—臭氧发生器。臭氧(O3)是氧的同位素,在水中的氧化还原电位为2.07V,氧化能力强。通过向剩余活性污泥中投加臭氧,将部分细菌氧化为细胞碎片,细胞破碎后,蛋白质、核酸等被释放出来,使污泥达到调质,增强后续污泥脱水的性能。由于臭氧极不稳定,不能象其它气体那样装入瓶中使用,只能随生产随使用。故在该气浮浓缩装置及工艺中,设置有臭氧发生器,臭氧制备完成后,通过气体增压泵或空压机压缩,提升臭氧气体的压力后,通过输气管路输送入第一级涡流三相混合器内。臭氧气体的压力(即气体增压泵或空压机出口的压力)稍大于进水泵压力(即稍大于0.6~0.9MPa)。臭氧投加量为0.006~0.010gO3/gDS(干污泥)。The air flotation concentration device is equipped with an ozone preparation and dosing device—ozone generator. Ozone (O 3 ) is an isotope of oxygen, its redox potential in water is 2.07V, and it has a strong oxidation ability. By adding ozone to the remaining activated sludge, some bacteria are oxidized into cell fragments. After the cells are broken, proteins, nucleic acids, etc. are released, so that the sludge can be conditioned and the subsequent sludge dehydration performance can be enhanced. Because ozone is extremely unstable, it cannot be used in bottles like other gases, and can only be used with production. Therefore, in the air flotation concentration device and process, an ozone generator is installed. After the ozone is prepared, it is compressed by a gas booster pump or an air compressor to increase the pressure of the ozone gas, and then it is transported into the first-stage vortex through the gas pipeline. in a three-phase mixer. The pressure of the ozone gas (that is, the pressure at the outlet of the gas booster pump or the air compressor) is slightly greater than the pressure of the water inlet pump (that is, slightly greater than 0.6-0.9MPa). The dosage of ozone is 0.006~0.010gO 3 /gDS (dried sludge).
本实用新型的有益效果:The beneficial effects of the utility model:
本实用新型的臭氧微气泡气浮浓缩装置,用于对污泥进行调质浓缩。本实用新型的气浮浓缩装置及污泥调质浓缩方法,通过将一种特殊的涡流三相混合器应用于污泥的气浮浓缩工艺,并提出气浮所用的气源为臭氧,能够获得高干度、被调质的浮渣,该浮渣可直接泵入后续超高压弹性压榨机或板框压榨机内进行脱水。The ozone micro-bubble air flotation concentration device of the utility model is used for conditioning and concentrating sludge. The air flotation concentration device and the sludge conditioning and concentration method of the utility model can obtain High-dryness, tempered scum, which can be directly pumped into subsequent ultra-high pressure elastic presses or plate and frame presses for dehydration.
本实用新型的臭氧微气泡气浮浓缩装置及污泥调质浓缩方法,能够实现污泥调质(将PAM药剂和废水、臭氧同时加入涡流三相混合器,通过多级涡流三相混合器的物理作用以及臭氧对污泥的强化氧化作用实现了污泥调质),可替代铁盐+石灰调质方式,改善污泥的脱水性能;同时能够获得较高干度的气浮浮渣(含水率90~95%),以利于后续的超高压弹性压榨机或板框脱水机脱水。The ozone micro-bubble air flotation concentration device and the sludge conditioning and concentration method of the utility model can realize sludge conditioning (add PAM agent, waste water and ozone to the vortex three-phase mixer at the same time, and pass through the multi-stage vortex three-phase mixer. The physical effect and the enhanced oxidation of ozone on the sludge realize the sludge conditioning), which can replace the iron salt + lime conditioning method and improve the dehydration performance of the sludge; at the same time, it can obtain air-floated scum with a higher dryness (water content rate of 90 to 95%), in order to facilitate the follow-up ultra-high pressure elastic press or plate and frame dehydrator dehydration.
本实用新型的臭氧微气泡气浮浓缩装置,具有以下几个特性:The ozone microbubble air flotation concentration device of the utility model has the following characteristics:
A、臭氧微气泡气浮浓缩装置中的核心部件为一种特殊构造的水、气、固三相涡流混合反应器(即涡流三相混合器),集溶气、差速搅拌、颗粒附着、絮体加气、溶气晶核生成和气泡释放功能于一体;通过涡流三相混合器,絮体形成与气泡晶核在同一时间形成,导致絮体巨大且多孔,上升迅速;所有入流废水被100%加气,无需循环水泵和清水池;反应槽由堰板分隔成三个室:接触室、分离室和清水收集室;在接触室内的涡流三相混合器中,药剂与污染物颗粒(固体)、水、气三相接触混合,涡流产生微气泡并植入污染物中,污染物被捕集,形成絮体;在分离室內,絮体中夹带气泡,上浮到液面上,完成固液分离,后部仅需刮渣即可;在清水收集室收集清水出水。该装置PAM药剂用量少,浮渣的含水率更干;A. The core component of the ozone microbubble air flotation concentration device is a special structure of water, gas and solid three-phase vortex mixing reactor (ie vortex three-phase mixer), which can collect dissolved gas, differential stirring, particle adhesion, The functions of floc aeration, dissolved gas nucleation and bubble release are integrated; through the vortex three-phase mixer, floc formation and bubble nucleation are formed at the same time, resulting in huge and porous flocs that rise rapidly; all influent wastewater is 100% gas filling, no circulating water pump and clear water tank; the reaction tank is divided into three chambers by the weir plate: contact chamber, separation chamber and clean water collection chamber; in the vortex three-phase mixer in the contact chamber, the medicament and pollutant particles ( Solid), water, and gas three-phase contact and mixing, the vortex generates microbubbles and implants them in the pollutants, the pollutants are captured and form flocs; in the separation chamber, the flocs are entrained with air bubbles and float to the liquid surface to complete solidification The liquid is separated, and the rear part only needs to scrape the slag; the clean water is collected in the clean water collection chamber. The device uses less PAM agent, and the water content of the scum is drier;
B、臭氧微气泡气浮浓缩装置的气源为稍大于0.6~0.9MPa压力的臭氧,利用臭氧的强氧化性使气浮浮渣得到调质;B. The gas source of the ozone micro-bubble air flotation concentration device is ozone with a pressure slightly higher than 0.6-0.9MPa, and the air flotation scum is tempered by using the strong oxidation of ozone;
C、污泥的高干度浓缩和污泥加药调质同时进行,气浮浮渣后续无需再加药调质,直接进入超高压弹性压榨机或板框脱水机脱水。C. The high-dryness concentration of sludge and the conditioning and tempering of the sludge are carried out at the same time. The air-floated scum does not need to be tempered afterward, and it is directly dehydrated in an ultra-high pressure elastic press or a plate and frame dehydrator.
本实用新型的臭氧微气泡气浮浓缩装置的技术特性在于,实现了设备一体化、污泥调质、污泥上浮的革新,省略了溶气水制备、循环水系统和缓慢低效的气泡附着过程,实现了前所未有的浮渣去除效率(浮渣去除率达99%以上),节省了90%以上的占地面积和大量基建投资费用。由于去除效率高,可以大大降低后级处理工艺的负荷并增加其稳定性。由于所产生的浮渣含水少且密实,可以大大地降低浮渣收容池的体积。使得整个工艺更为可靠、占地面积和运行成本都大大降低。The technical characteristics of the ozone micro-bubble air flotation concentration device of the utility model are that it realizes the innovation of equipment integration, sludge conditioning and sludge flotation, and omits the preparation of dissolved air water, circulating water system and slow and inefficient bubble attachment. The process has achieved unprecedented scum removal efficiency (the scum removal rate is over 99%), saving more than 90% of the floor area and a large amount of infrastructure investment costs. Due to the high removal efficiency, the load of the subsequent treatment process can be greatly reduced and its stability can be increased. Since the generated scum contains less water and is compact, the volume of the scum storage tank can be greatly reduced. The whole process is more reliable, and the floor area and operating costs are greatly reduced.
本实用新型的臭氧微气泡气浮浓缩装置的原理与重力浓缩相反,气泡粘附在悬浮物上作为载体,形成密度比水轻的气固混合物,上浮到水面,从而使悬浮物杂质与水分离,然后用刮板将浓缩污泥刮入排泥槽,污泥水则从池底排出。本实用新型的具有污泥调质作用的臭氧微气泡气浮浓缩装置,相比重力浓缩,具有浓缩速度快,停留时间短、浮渣含水率低、出水水质高、占地面积小等特点。The principle of the ozone micro-bubble air flotation concentration device of the utility model is opposite to that of gravity concentration. Bubbles adhere to the suspended matter as a carrier to form a gas-solid mixture with a density lighter than water, which floats to the water surface, thereby separating suspended matter impurities from water. , and then use a scraper to scrape the concentrated sludge into the sludge discharge tank, and the sludge water is discharged from the bottom of the tank. Compared with gravity concentration, the ozone micro-bubble air flotation concentration device of the utility model has the characteristics of fast concentration speed, short residence time, low water content of scum, high quality of effluent, and small floor area.
附图说明Description of drawings
图1是本实用新型一种臭氧微气泡气浮浓缩装置的结构示意图;Fig. 1 is the structural representation of a kind of ozone microbubble air flotation concentration device of the utility model;
图2是本实用新型的臭氧微气泡气浮浓缩装置的工作流程示意图;Fig. 2 is the working flow diagram of the ozone microbubble air flotation concentration device of the utility model;
图3是本实用新型中的六级串联的涡流三相混合器的结构示意图。Fig. 3 is a schematic structural view of a six-stage series-connected vortex three-phase mixer in the present invention.
图中:1.进水泵 2.流量计 3.空压机 4.进气阀 5.反应槽 A、接触室 B、分离室C、清水收集室 6.集渣槽 7.液位计 8.除渣机 9.排气阀 10.压力表 11.涡流三相混合器12.进药管 13.总进水管 14.涡流三相混合器的侧面进水口处的进水管15.旁通注入管16、臭氧发生器 17、药剂投加泵 18、药剂制备装置In the figure: 1. Inlet pump 2. Flow meter 3. Air compressor 4. Intake valve 5. Reaction tank A, contact chamber B, separation chamber C, clean water collection chamber 6. Slag collection tank 7. Liquid level gauge 8. Deslagging machine 9. Exhaust valve 10. Pressure gauge 11. Vortex three-phase mixer 12. Drug inlet pipe 13. Main water inlet pipe 14. Water inlet pipe at the side water inlet of the vortex three-phase mixer 15. Bypass injection pipe 16. Ozone generator 17. Chemical dosing pump 18. Chemical preparation device
具体实施方式detailed description
以下结合附图和实施例对本实用新型作进一步的说明。Below in conjunction with accompanying drawing and embodiment the utility model is described further.
实施例1Example 1
如图1、图3所示,本实用新型一种臭氧微气泡气浮浓缩装置,它包括一反应槽5,在反应槽上方并排设置六组(六级)串联的涡流三相混合器11(从出水侧到进水侧依次排列为第一级、第二级……第六级),每级涡流三相混合器内设有一级反应器;反应槽从进水侧到出水侧由堰板分隔成三个室,即:接触室A、分离室B和清水收集室C;分离室B上方设置除渣机8,除渣机8另一端水平延伸至集渣槽6上方;集渣槽6的顶部低于涡流三相混合器11的底部;集渣槽6下部一大半是倾斜的,倾斜底位于清水收集室C上方;总进水管13一端与进水泵1出口连接;总进水管13另一端与第一级涡流三相混合器的侧面进水口连接;总进水管13上设有流量计2;第一级涡流三相混合器的底部出水口与第二级涡流三相混合器的侧面进水口连接;……以此类推,前一级涡流三相混合器的底部出水口与后一级涡流三相混合器的侧面进水口连接;最后一级(第六级)涡流三相混合器的底部出水口直接连接一根释放管;释放管出口位于反应槽接触室A下部;每一级涡流三相混合器的侧面进水口处的进水管14上设有垂直的旁通注入管15;药剂制备装置18出口与药剂投加泵17入口连接;进药管12一端与药剂投加泵17出口连接,进药管12另一端分别与第二级、第三级涡流三相混合器的侧面进水口处的旁通注入管15连接;臭氧发生器16出口与空压机3入口连接;进气管一端与空压机3出口连接,另一端与第一级涡流三相混合器的顶部进气口连接;第三级涡流三相混合器的顶部出气口连接一根排气管;排气管上设有排气阀9。每一级涡流三相混合器顶部均设有压力表10。进气管上设有进气阀4,进气阀4之后还设有单向阀。进药管12上也设有单向阀。集渣槽6上设有液位计7,用于控制后续排渣泵的启停。As shown in Fig. 1 and Fig. 3, a kind of ozone microbubble air flotation concentration device of the present utility model, it comprises a reaction tank 5, and six groups (six stages) vortex three-phase mixer 11 ( From the water outlet side to the water inlet side, they are arranged in sequence as the first stage, the second stage...the sixth stage), and each stage of the vortex three-phase mixer is equipped with a first-stage reactor; the reaction tank is formed by a weir plate from the water inlet side to the water outlet side It is divided into three chambers, namely: contact chamber A, separation chamber B and clean water collection chamber C; a slag remover 8 is set above the separation chamber B, and the other end of the slag remover 8 extends horizontally to the top of the slag collection tank 6; the slag collection tank 6 The top of the vortex three-phase mixer is lower than the bottom of the vortex three-phase mixer 11; more than half of the lower part of the slag collection tank 6 is inclined, and the inclined bottom is located above the clear water collection chamber C; one end of the main water inlet pipe 13 is connected to the outlet of the water inlet pump 1; One end is connected to the side water inlet of the first-stage vortex three-phase mixer; the total water inlet pipe 13 is provided with a flowmeter 2; the bottom water outlet of the first-stage vortex three-phase mixer is connected to the side of the second-stage vortex three-phase mixer Water inlet connection;...and so on, the bottom water outlet of the previous stage vortex three-phase mixer is connected to the side water inlet of the latter stage vortex three-phase mixer; the last stage (sixth stage) vortex three-phase mixer The outlet at the bottom of the outlet is directly connected to a release pipe; the outlet of the release pipe is located at the lower part of the contact chamber A of the reaction tank; the water inlet pipe 14 at the side water inlet of each stage vortex three-phase mixer is provided with a vertical bypass injection pipe 15; The outlet of the medicine preparation device 18 is connected to the inlet of the medicine dosing pump 17; one end of the medicine feeding pipe 12 is connected to the outlet of the medicine dosing pump 17, and the other end of the medicine feeding pipe 12 is respectively connected to the sides of the second-stage and third-stage vortex three-phase mixers. The bypass injection pipe 15 at the water inlet is connected; the outlet of the ozone generator 16 is connected to the inlet of the air compressor 3; one end of the inlet pipe is connected to the outlet of the air compressor 3, and the other end is connected to the top of the first-stage vortex three-phase mixer. The top outlet of the third-stage vortex three-phase mixer is connected to an exhaust pipe; the exhaust pipe is provided with an exhaust valve 9. A pressure gauge 10 is provided on the top of each vortex three-phase mixer. The intake pipe is provided with an intake valve 4, and a check valve is also provided behind the intake valve 4. The medicine feeding pipe 12 is also provided with a one-way valve. A liquid level gauge 7 is provided on the slag collection tank 6 for controlling the start and stop of the subsequent slag discharge pump.
本实用新型的臭氧微气泡气浮浓缩装置是压力溶气气浮的一种,这种由微气泡与微絮体同时形成并结合在一起,进而共同成长为带气絮体的过程称为“共聚”。气泡越小,越容易进入絮体,或者被絮体捕捉,从而形成稳定的共聚絮体。它在延时释放出高度密集的微气泡,在与投药混合后的反应水充分混合时,两者同时成长,这样形成的带气絮体在上浮过程中,具有上浮快,浮渣稳定,耗用的气量少等优点。The ozone micro-bubble air flotation concentration device of the utility model is a kind of pressure-dissolved air flotation. This process of forming and combining micro-bubbles and micro-flocs at the same time, and then growing together into gas-bearing flocs is called " Co-gathering". The smaller the air bubbles, the easier it is to enter the flocs or be captured by the flocs, thus forming a stable co-polymerized flocs. It releases highly dense micro-bubbles in a delayed manner. When it is fully mixed with the reaction water mixed with the drug, the two grow at the same time. The advantages of using less gas.
本实用新型的臭氧微气泡气浮浓缩装置的设计原理是:利用涡流三相混合器,在废水中直接加入气与药剂,同时完成溶气与搅拌,最后实现自动除渣。涡流三相混合器集溶气、差速搅拌、絮体加气、颗粒附着、溶气晶核生成和气泡释放功能于一体。其工作流程包括:①高压溶气②伸展药剂③充分搅拌④晶核形成⑤气泡凝聚⑥絮体合并⑦浮渣调质⑧循环絮凝。涡流三相混合器与传统溶气气浮的区别:最大限度地利用化学药剂;形成超轻中空絮体,使絮体含水率和比重降低,絮体结实且具有很强的自行上浮能力,有利于自动除渣。The design principle of the ozone micro-bubble air flotation concentration device of the utility model is: use the vortex three-phase mixer to directly add gas and medicine into the wastewater, complete the gas dissolution and stirring at the same time, and finally realize automatic slag removal. The vortex three-phase mixer integrates the functions of dissolved air, differential stirring, floc aeration, particle attachment, dissolved air crystal nucleation and bubble release. Its working process includes: ① high-pressure dissolved air ② stretching agent ③ full stirring ④ crystal nucleus formation ⑤ air bubble aggregation ⑥ floc merging ⑦ scum conditioning ⑧ circulation flocculation. The difference between the vortex three-phase mixer and the traditional dissolved air flotation: maximize the use of chemicals; form ultra-light hollow flocs, reduce the water content and specific gravity of the flocs, and the flocs are strong and have a strong self-floating ability. Conducive to automatic slag removal.
如图2所示,本实用新型的臭氧微气泡气浮浓缩装置的工作过程为:(1)进水:使用加压进水泵将废水从调节池输入多级涡流三相混合器中形成涡流;(2)加气/加药混合搅拌:在多级涡流三相混合器中,将加压臭氧直接溶解在入流废水中,紧接着化学药剂直接投加至溶气液中,完成药剂与污染物颗粒(固体)、水、气三相混合;药剂分子初始为盘绕状,涡流将药剂分子拉伸提效,充分搅拌;(3)涡流产生微气泡并植入悬浮物中:药剂与污染物颗粒、水、气混合物释放到反应槽的接触室A内后,再堰流进入分离室B,涡流产生微气泡并植入污染物中,污染物被捕集,絮体形成并上浮;(4)释放悬浮物;(5)利用除渣机自动去除浮渣;浮渣(污泥)进入集渣槽6收集或处理;在清水收集室C收集清水,由反应槽底部排出。As shown in Figure 2, the working process of the ozone micro-bubble air flotation concentration device of the present utility model is: (1) water intake: use the pressurized water intake pump to input the waste water from the regulating tank into the multi-stage vortex three-phase mixer to form a vortex; (2) Aeration/dosing mixing and stirring: In the multi-stage vortex three-phase mixer, the pressurized ozone is directly dissolved in the influent wastewater, and then the chemical agent is directly added to the dissolved gas liquid to complete the chemical agent and pollutants. Particles (solid), water, and gas are mixed in three phases; the drug molecules are initially coiled, and the vortex stretches the drug molecules to improve the effect and fully stir; (3) The vortex generates microbubbles and implants them in the suspension: drug and pollutant particles After the mixture of water and gas is released into the contact chamber A of the reaction tank, the weir flow enters the separation chamber B, and the vortex generates microbubbles and implants them in the pollutants, the pollutants are captured, and the flocs are formed and floated; (4) Release suspended solids; (5) Use a scum remover to automatically remove scum; scum (sludge) enters the scum tank 6 for collection or treatment; clean water is collected in the clean water collection chamber C and discharged from the bottom of the reaction tank.
本实用新型的臭氧微气泡气浮浓缩装置,通过涡流三相混合器产生微气泡,粘附在悬浮物上作为载体,形成密度比水轻的气固混合物,上浮到水面,从而使悬浮物杂质与水分离;能有效去除复杂污水中的固体悬浮颗粒物、油类、浊度和有机物等;有效促进污染物的高效处理,达到优秀的节能减排效果。The ozone micro-bubble air flotation concentration device of the utility model generates micro-bubbles through a vortex three-phase mixer, adheres to the suspended matter as a carrier, forms a gas-solid mixture with a density lighter than water, and floats to the water surface, thereby making the suspended matter impurity Separated from water; can effectively remove solid suspended particles, oil, turbidity and organic matter in complex sewage; effectively promote the efficient treatment of pollutants, and achieve excellent energy saving and emission reduction effects.
本实用新型的臭氧微气泡气浮浓缩装置引用国外涡流三相混合技术,在涡流三相混合器中水流产生激烈的涡流,从而达到药剂、水、气的差速搅拌及混合。采用旁通注入管将絮凝剂注入原水管(即进水管)接近反应区的进口处(即涡流三相混合器的侧面进水口处),旁通注入管的管径比原水管的管径小许多,旁通注入管的小孔以很大的速度垂直于原水管水流的方向射出,絮凝剂射入在原水水流紊动强度最大的时候(在缺口和节点附近位置),此时最易与原水快速混合。絮凝剂混合可分为三段,第一段为势流段,在此段中射流的流速不变,射流开始与周围原水混合;第二段为偏折段,在原水管中水流的作用下射流向水流方向偏折,并进一步与原水混合;第三段为漩涡段,射流的水流截面上面发生若干股漩涡,使射流迅速扩散,与原水完全混合。总之,经过缺口和节点时,发生剧烈的汇聚、分散、转向、撕裂,故形成无数小漩涡,使介质紊动和表面更新速度大大加快,液膜阻力大为降低,所以传质速率很高。The ozone micro-bubble air flotation concentration device of the utility model adopts the foreign vortex three-phase mixing technology, and the water flow in the vortex three-phase mixer generates a fierce vortex, thereby achieving differential stirring and mixing of medicine, water and gas. Use the bypass injection pipe to inject the flocculant into the raw water pipe (that is, the water inlet pipe) close to the inlet of the reaction zone (that is, the side water inlet of the vortex three-phase mixer), and the diameter of the bypass injection pipe is smaller than that of the raw water pipe. Many, the small holes of the bypass injection pipe shoot out at a high speed perpendicular to the direction of the water flow of the raw water pipe. Raw water is mixed quickly. The flocculant mixing can be divided into three sections. The first section is the potential flow section. In this section, the flow velocity of the jet remains unchanged, and the jet begins to mix with the surrounding raw water. The second section is the deflection section, which is injected under the action of water flow in the raw water pipe. The flow is deflected in the direction of the water flow and further mixed with the raw water; the third section is the vortex section, and several vortices occur on the water flow section of the jet, so that the jet spreads rapidly and completely mixes with the raw water. In short, when passing through gaps and nodes, violent convergence, dispersion, turning, and tearing occur, so countless small eddies are formed, which greatly accelerates the medium turbulence and surface renewal speed, and greatly reduces the liquid film resistance, so the mass transfer rate is very high. .
本实用新型的臭氧微气泡气浮浓缩装置的特点如下:The characteristics of the ozone microbubble air flotation concentration device of the present utility model are as follows:
1、高压溶气:将加压臭氧100%溶解于入流污水中,依照传统气浮的气泡附着理论,该步骤实现污染物分子与气泡的最小极限接触气体在溶解状态下的附着;1. High-pressure dissolved air: Dissolve 100% of the pressurized ozone in the influent sewage. According to the bubble attachment theory of traditional air flotation, this step realizes the attachment of pollutant molecules and air bubbles in the dissolved state with the minimum limit contact gas;
2、伸展药剂:通常高分子物投加时处于分子链绞缠成团状态,本产品特有的高效混合器能将绞缠成团分子链拉伸变为长条分子链,使药剂分子链所带电荷能被充分暴露利用,减少浪费;2. Stretching agent: Usually, when the polymer is added, the molecular chain is twisted into a group. The unique high-efficiency mixer of this product can stretch the twisted molecular chain into a long molecular chain, so that the molecular chain of the agent The charge can be fully exposed and utilized, reducing waste;
3、充分搅拌:多级高效混合器通过各种有效速率实现药剂与污染物的充分接触与混合。使污染物能够被药剂分子链所携带并暴露的电荷牢固地吸附;3. Fully stirring: the multi-stage high-efficiency mixer realizes the full contact and mixing of the medicament and the pollutant through various effective speeds. To enable pollutants to be firmly adsorbed by the charges carried and exposed by the molecular chain of the agent;
4、浮渣形成:随着压力的降低,溶解态的气体借助污染物絮体逐渐形成无数的极细气泡,直接生长在污泥絮体之中;4. Scum formation: As the pressure decreases, the dissolved gas gradually forms numerous fine bubbles with the help of pollutant flocs, which grow directly in the sludge flocs;
5、气泡凝聚:气泡不断合并膨胀,产生海绵状絮体的颗粒;5. Bubble agglomeration: Bubbles merge and expand continuously to produce spongy floc particles;
6、絮体合并:在絮体上浮过程中,细小絮体迅速合并长大,同时气泡也急剧膨胀,挤占絮体内间隙水的空间,使絮体含水率和比重进一步降低,絮体结实且具有很强的自行上浮能力;6. Floc merging: During the floating process of flocs, small flocs merge and grow rapidly, and at the same time, the bubbles also expand rapidly, occupying the interstitial water space in the flocs, further reducing the moisture content and specific gravity of the flocs, and the flocs are strong and have Strong self-floating ability;
7、调质浮渣:浮渣上浮至池面上,相互堆积,粘结成浮渣毯,形成整体上浮,含水率进一步降低;7. Refined and tempered scum: The scum floats up to the surface of the pool, accumulates with each other, and bonds into a scum blanket, forming an overall floating, and the water content is further reduced;
8、出水收集:气浮浓缩的出水由反应槽底部排出,进入集水管收集到清水区;8. Water collection: the effluent concentrated by air flotation is discharged from the bottom of the reaction tank, enters the water collection pipe and is collected to the clean water area;
9、浮渣层控制:通过调节堰板控制出水液面高度,从而控制浮渣层的厚度。9. Control of scum layer: Control the height of the effluent liquid level by adjusting the weir plate, so as to control the thickness of the scum layer.
实施例2-5Example 2-5
本实用新型一种利用实施例1所述的臭氧微气泡气浮浓缩装置进行污泥调质浓缩的方法如下:(实施例2-5均按该方法处理)A method of using the ozone microbubble air flotation concentration device described in Embodiment 1 of the utility model to carry out sludge conditioning and concentration is as follows: (Embodiments 2-5 are all processed according to this method)
污泥(生活污水污泥、工业废水污泥、给水污泥)使用加压进水泵,通过进水管,输送入多级涡流三相混合器中形成涡流,即从第一级涡流三相混合器依次逐个进入后面几级涡流三相混合器中;臭氧由臭氧发生器制备完成后,通过气体增压泵或空压机压缩,提升臭氧气体的压力后,通过进气管输送入第一级涡流三相混合器内;PAM药剂经药剂制备装置制备好后,使用加压药剂投加泵,通过进药管,投加在第二级和第三级涡流三相混合器上,从涡流三相混合器的侧面进水口处的旁通注入管注入(垂直于水流方向注入);在反应槽的接触室内的多级涡流三相混合器中,加压臭氧直接溶解在入流废水中,紧接着PAM药剂直接投加至溶气液中,药剂与污染物颗粒(固体)、水、气三相接触混合,涡流产生微气泡并植入污染物中,污染物被捕集,形成絮体;在分离室內,絮体中夹带气泡,上浮到液面上形成浮渣,完成固液分离;利用除渣机自动去除浮渣,浮渣进入集渣槽收集或处理;在清水收集室收集清水,由反应槽底部排出。Sludge (domestic sewage sludge, industrial wastewater sludge, water supply sludge) is transported into a multi-stage vortex three-phase mixer through a water inlet pipe to form a vortex using a pressurized water inlet pump, that is, from the first stage vortex three-phase mixer Enter the following several stages of vortex three-phase mixer one by one; after the ozone is prepared by the ozone generator, it is compressed by a gas booster pump or an air compressor to increase the pressure of the ozone gas, and then it is transported into the first stage of the vortex three-phase mixer through the intake pipe. In the phase mixer; after the PAM agent is prepared by the agent preparation device, the pressurized agent dosing pump is used to pass through the drug inlet pipe and added to the second and third stage vortex three-phase mixers, and the vortex three-phase mixing The bypass injection pipe at the water inlet on the side of the device is injected (injection perpendicular to the direction of water flow); in the multi-stage vortex three-phase mixer in the contact chamber of the reaction tank, the pressurized ozone is directly dissolved in the influent wastewater, followed by the PAM agent Dosing directly into the gas-dissolved liquid, the agent is mixed with pollutant particles (solid), water and gas in three-phase contact, the vortex generates microbubbles and implants them in the pollutants, the pollutants are captured and form flocs; in the separation chamber , the air bubbles are entrained in the flocs, which float up to the liquid surface to form scum and complete the solid-liquid separation; the scum is automatically removed by the scum remover, and the scum enters the scum tank for collection or treatment; the clean water is collected in the clean water collection room, and the reaction tank Bottom drain.
含水率为98.5~99.5%的污泥,经过该臭氧微气泡气浮浓缩装置进行调质、浓缩处理后,获得较高干度的浮渣,该气浮浮渣的含水率为90~95%;该调质后的浮渣无需添加任何药剂,可直接输送至超高压弹性压榨机进行压榨,压榨后的泥饼含水率能达到55~65%。Sludge with a water content of 98.5-99.5%, after conditioning and concentration treatment by the ozone micro-bubble air flotation concentration device, a relatively dry scum is obtained, and the water content of the air flotation scum is 90-95%. The scum after conditioning can be directly transported to an ultra-high pressure elastic press for pressing without adding any chemicals, and the water content of the mud cake after pressing can reach 55-65%.
PAM药剂投加量为0.002~0.006gPAM/gDS(干污泥),臭氧投加量为0.006~0.010gO3/gDS(干污泥)。进水泵压力为0.6~0.9Mpa;臭氧气体的压力(即气体增压泵或空压机出口的压力)稍大于进水泵压力(即稍大于0.6~0.9MPa);PAM药剂投加泵的投加压力稍大于进水泵压力(即稍大于0.6~0.9MPa)。第一级涡流三相混合器的压力最高(0.6~0.9Mpa),后面几级涡流三相混合器内的压力依次逐个递减。The dosage of PAM agent is 0.002-0.006gPAM/gDS (dry sludge), and the dosage of ozone is 0.006-0.010gO 3 /gDS (dry sludge). The pressure of the water inlet pump is 0.6-0.9Mpa; the pressure of the ozone gas (that is, the pressure at the outlet of the gas booster pump or the air compressor) is slightly greater than the pressure of the water inlet pump (that is, slightly greater than 0.6-0.9MPa); the dosing of the PAM agent dosing pump The pressure is slightly higher than the inlet pump pressure (that is, slightly higher than 0.6-0.9MPa). The pressure of the first-stage vortex three-phase mixer is the highest (0.6-0.9Mpa), and the pressures in the following stages of vortex three-phase mixers decrease gradually one by one.
实施例2:处理对象为某个生活污水水源为主的污水处理厂的二沉池排出的剩余污泥(含水率99%),采用实施例1的臭氧微气泡气浮浓缩装置进行调质、浓缩处理:PAM投加量为0.003gPAM/gDS(干污泥),臭氧投加量为0.00625gO3/gDS(干污泥);进水泵压力为0.8Mpa左右;臭氧气体的压力(即气体增压泵或空压机出口的压力)稍大于进水泵压力(稍大于0.8MPa);PAM药剂投加泵的投加压力稍大于进水泵压力(稍大于0.8 MPa)。第一级涡流三相混合器的压力最高(约0.8Mpa),后续涡流三相混合器内的压力逐个递减(如0.7Mpa、0.6Mpa、0.5Mpa、0.4Mpa、0.3Mpa或0.2Mpa不等,实测值可能与上述数据有偏差)。Embodiment 2: the processing object is the remaining sludge (water content 99%) discharged from the secondary sedimentation tank of a sewage treatment plant based on a certain domestic sewage water source, and the ozone microbubble air flotation concentration device of embodiment 1 is adopted to carry out conditioning, Concentration treatment: the dosage of PAM is 0.003gPAM/gDS (dry sludge), the dosage of ozone is 0.00625gO 3 /gDS (dry sludge); the pressure of the water inlet pump is about 0.8Mpa; The pressure at the outlet of the pump or air compressor) is slightly greater than the pressure of the water inlet pump (slightly greater than 0.8 MPa); the dosing pressure of the PAM agent dosing pump is slightly greater than the pressure of the water inlet pump (slightly greater than 0.8 MPa). The pressure of the first-stage vortex three-phase mixer is the highest (about 0.8Mpa), and the pressure in the subsequent vortex three-phase mixer decreases gradually (such as 0.7Mpa, 0.6Mpa, 0.5Mpa, 0.4Mpa, 0.3Mpa or 0.2Mpa, The measured value may deviate from the above data).
经过本实用新型的臭氧微气泡气浮浓缩装置调质、浓缩处理后,获得的气浮浮渣含水率为93%。该调质后的浮渣不再添加任何药剂,直接输送至超高压弹性压榨机压榨,压榨后的泥饼含水率达到59%。After tempering and concentration treatment by the ozone micro-bubble air flotation concentration device of the utility model, the water content of the obtained air flotation scum is 93%. The tempered scum does not add any chemicals, and is directly transported to an ultra-high pressure elastic press for pressing, and the water content of the mud cake after pressing reaches 59%.
实施例3:处理对象为某个食品业废水为主的工业废水处理厂的二沉池排出的剩余污泥(含水率98.7%),采用实施例1的臭氧微气泡气浮浓缩装置进行调质、浓缩处理:PAM投加量为0.0035gPAM/gDS,臭氧投加量为0.008gO3/gDS(干污泥);进水泵压力为0.6Mpa左右;臭氧气体的压力稍大于进水泵压力(稍大于0.6MPa);PAM药剂投加泵的投加压力稍大于进水泵压力(稍大于0.6 MPa)。第一级涡流三相混合器的压力最高(约0.6Mpa),后续涡流三相混合器内的压力逐个递减。Embodiment 3: the processing object is the surplus sludge (water content 98.7%) discharged from the secondary settling tank of an industrial wastewater treatment plant based on certain food industry wastewater, and the ozone microbubble air flotation concentration device of embodiment 1 is used for conditioning , concentration treatment: the dosage of PAM is 0.0035gPAM/gDS, the dosage of ozone is 0.008gO 3 /gDS (dry sludge); the pressure of the water inlet pump is about 0.6Mpa; the pressure of ozone gas is slightly higher than the pressure of the water inlet pump (slightly higher than 0.6MPa); the dosing pressure of the PAM agent dosing pump is slightly higher than the inlet pump pressure (slightly greater than 0.6 MPa). The pressure of the first-stage vortex three-phase mixer is the highest (about 0.6Mpa), and the pressure in the subsequent vortex three-phase mixer decreases gradually.
经过本实用新型的臭氧微气泡气浮浓缩装置调质、浓缩处理后,获得的气浮浮渣含水率为94%。该调质后的浮渣不再添加任何药剂,直接输送至超高压弹性压榨机压榨,压榨后的泥饼含水率达到62%。After tempering and concentration treatment by the ozone micro-bubble air flotation concentration device of the utility model, the water content of the obtained air flotation scum is 94%. The tempered scum does not add any chemicals, and is directly transported to an ultra-high pressure elastic press for pressing, and the water content of the mud cake after pressing reaches 62%.
实施例4:处理对象为某个生活污水水源为主的污水处理厂的二沉池排出的剩余污泥(含水率98.5%),采用实施例1的臭氧微气泡气浮浓缩装置进行调质、浓缩处理:PAM投加量为0.006gPAM/gDS,臭氧投加量为0.010gO3/gDS(干污泥);进水泵压力为0.7Mpa左右;臭氧气体的压力稍大于进水泵压力(稍大于0.7MPa);PAM药剂投加泵的投加压力稍大于进水泵压力(稍大于0.7 MPa)。第一级涡流三相混合器的压力最高(约0.7Mpa),后续涡流三相混合器内的压力逐个递减。Embodiment 4: the processing object is the remaining sludge (water content 98.5%) discharged from the secondary sedimentation tank of a sewage treatment plant based on a certain domestic sewage water source, adopting the ozone microbubble air flotation concentration device of embodiment 1 to carry out conditioning, Concentration treatment: PAM dosage is 0.006gPAM/gDS, ozone dosage is 0.010gO 3 /gDS (dry sludge); inlet pump pressure is about 0.7Mpa; ozone gas pressure is slightly higher than inlet pump pressure (slightly greater than 0.7 MPa); the dosing pressure of the PAM agent dosing pump is slightly higher than the inlet pump pressure (slightly greater than 0.7 MPa). The pressure of the first-stage vortex three-phase mixer is the highest (about 0.7Mpa), and the pressure in the subsequent vortex three-phase mixer decreases gradually.
经过本实用新型的臭氧微气泡气浮浓缩装置调质浓缩处理后,获得的气浮浮渣含水率为90%。该调质后的浮渣不再添加任何药剂,直接输送至超高压弹性压榨机压榨,压榨后的泥饼含水率达到55%。After being tempered and concentrated by the ozone micro-bubble air flotation concentration device of the utility model, the water content of the obtained air flotation scum is 90%. The tempered scum does not add any chemicals, and is directly transported to an ultra-high pressure elastic press for pressing, and the water content of the mud cake after pressing reaches 55%.
实施例5:处理对象为某个食品业废水为主的工业废水处理厂的二沉池排出的剩余污泥(含水率99.5%),采用实施例1的臭氧微气泡气浮浓缩装置进行调质、浓缩处理:PAM投加量为0.002gPAM/gDS,臭氧投加量为0.006gO3/gDS(干污泥);进水泵压力为0.9Mpa左右;臭氧气体的压力稍大于进水泵压力(稍大于0.9MPa);PAM药剂投加泵的投加压力稍大于进水泵压力(稍大于0.9 MPa)。第一级涡流三相混合器的压力最高(约0.9Mpa),后续涡流三相混合器内的压力逐个递减。Embodiment 5: The processing object is the surplus sludge (water content 99.5%) discharged from the secondary sedimentation tank of an industrial wastewater treatment plant based on certain food industry wastewater, and the ozone microbubble air flotation concentration device of Embodiment 1 is used for conditioning , concentration treatment: the dosage of PAM is 0.002gPAM/gDS, the dosage of ozone is 0.006gO 3 /gDS (dry sludge); the pressure of the water inlet pump is about 0.9Mpa; the pressure of ozone gas is slightly higher than the pressure of the water inlet pump (slightly higher than 0.9MPa); the dosing pressure of the PAM agent dosing pump is slightly higher than the inlet pump pressure (slightly greater than 0.9 MPa). The pressure of the first-stage vortex three-phase mixer is the highest (about 0.9Mpa), and the pressure in the subsequent vortex three-phase mixer decreases gradually.
经过本实用新型的臭氧微气泡气浮浓缩装置调质浓缩处理后,获得的气浮浮渣含水率为95%。该调质后的浮渣不再添加任何药剂,直接输送至超高压弹性压榨机压榨,压榨后的泥饼含水率达到65%。After being tempered and concentrated by the ozone micro-bubble air flotation concentration device of the utility model, the water content of the obtained air flotation scum is 95%. The tempered scum does not add any chemicals, and is directly transported to an ultra-high pressure elastic press for pressing, and the water content of the mud cake after pressing reaches 65%.
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| CN109851091A (en) * | 2019-01-18 | 2019-06-07 | 中国石油工程建设有限公司 | High-efficiency micro-bubble air flotation degreasing and suspended solids removal system and process for salty wastewater in oil and gas fields |
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| CN105859076A (en) * | 2016-06-14 | 2016-08-17 | 上海同臣环保有限公司 | Ozone microbubble air floating concentration device and sludge conditioning and concentration method |
| CN109851091A (en) * | 2019-01-18 | 2019-06-07 | 中国石油工程建设有限公司 | High-efficiency micro-bubble air flotation degreasing and suspended solids removal system and process for salty wastewater in oil and gas fields |
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