CN205598960U - Be used for algae moisture stench waste gas pollution control and treatment device leaving from station - Google Patents
Be used for algae moisture stench waste gas pollution control and treatment device leaving from station Download PDFInfo
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Abstract
本实用新型公开了一种专门用于藻水分离站恶臭废气治理的装置,包括有依次设置的恶臭生产源机构、用于收集恶臭生产源机构产生恶臭气体的集气装置、用于处理恶臭气体的低温等离子体协同催化吸附成套装置、以及能够提供动力的引风机和用于排放标准气体的排放塔。本实用新型经过低温等离子体降解后的气体进入催化吸附反应区,在这里吸附剂有选择的吸附未完全降解有机分子,以及低温等离子体中未完全反应的高能分子,在催化剂的作用下,进一步发生化学反应,达到降解污染物的目的。
The utility model discloses a device specially used for the treatment of malodorous waste gas in an algae-water separation station, which comprises a malodorous production source mechanism arranged in sequence, a gas collecting device for collecting the malodorous gas generated by the malodorous production source mechanism, and a device for treating the malodorous gas. The low-temperature plasma synergistic catalytic adsorption complete set, as well as the induced draft fan that can provide power and the discharge tower used to discharge standard gases. In the utility model, the gas degraded by low-temperature plasma enters the catalytic adsorption reaction zone, where the adsorbent selectively adsorbs incompletely degraded organic molecules, and high-energy molecules that have not completely reacted in the low-temperature plasma, and under the action of the catalyst, further A chemical reaction occurs to achieve the purpose of degrading pollutants.
Description
技术领域 technical field
本实用新型涉及环境工程与废气净化技术领域,更具体地说涉及一种用于藻水分离站恶臭废气治理装置。 The utility model relates to the technical field of environmental engineering and waste gas purification, in particular to a device for treating malodorous waste gas in an algae-water separation station.
背景技术 Background technique
现在淡水湖环境要求很高,其水质好坏与环湖流域上千万居民的生产生活息息相关,是沿湖地区工农业生产和人民生活的重要水源。然而近年来,由于环湖农田的化肥残留物以及巢湖流域周边城市的生活污水、工业废水流入湖内,使得很多大江大湖水体富营养化不断加剧,导致蓝藻大规模爆发,极大地破坏了淡水湖的生态环境。为了解决蓝藻问题引入藻水分离技术,很多大湖沿岸建立藻水分离站。但是在藻水分离过程中会产生大量的恶臭废气,从而影响到周边的生态环境。 Now freshwater lakes have very high environmental requirements, and their water quality is closely related to the production and life of tens of millions of residents in the basin around the lake. It is an important water source for industrial and agricultural production and people's lives in the area along the lake. However, in recent years, due to the fertilizer residues from the farmland around the lake and domestic sewage and industrial wastewater from cities around the Chaohu Lake Basin flowing into the lake, the eutrophication of many large rivers and lakes has continued to intensify, leading to large-scale outbreaks of blue-green algae and greatly destroying freshwater. Ecology of the lake. In order to solve the problem of cyanobacteria, algae water separation technology was introduced, and algae water separation stations were established along the coasts of many large lakes. However, during the separation of algae and water, a large amount of malodorous exhaust gas will be generated, which will affect the surrounding ecological environment.
藻水分离站具体工艺流程如下:将铲吸式打捞船或固定式打捞点打捞藻浆通过管道送入藻浆调峰池,将经过调节池的藻水送入脱气设备,对脱气后的蓝藻藻浆进行加药絮凝,使其沉降;将沉积至一定浓度的藻渣送入脱水设备脱水,得到藻泥,送入藻泥池;藻浆经沉积后的上覆水送入气浮设备,处理后的去藻水达标排入派河口,浮渣送入脱水设备脱水,得到的藻泥也送入藻泥池,最终送入环卫车,外运垃 圾填埋场进行无害化填埋。本项目主要产生的气体污染源为调峰池、气浮池、沉淀池、藻泥池、藻渣藻浆池和脱水机回水池。 The specific process flow of the algae water separation station is as follows: send the algae pulp salvaged by the shovel suction salvage ship or fixed salvage point to the algal pulp peak regulation pool through the pipeline, send the algae water that has passed through the adjustment pool to the degassing equipment, and after degassing The cyanobacteria algae pulp is added to the flocculation to make it settle; the algae residue deposited to a certain concentration is sent to the dehydration equipment for dehydration, and the algae mud is obtained and sent to the algae mud pool; the overlying water after the algae pulp is deposited is sent to the air flotation equipment , the treated algae-free water meets the standard and is discharged into the Pai River Estuary, the scum is sent to the dehydration equipment for dehydration, and the obtained algae mud is also sent to the algae mud tank, and finally sent to the sanitation vehicle, and transported to the landfill for harmless landfill . The main sources of gas pollution in this project are peak shaving pools, air flotation pools, sedimentation pools, algae mud pools, algae residue algae pulp pools and dehydrator return pools.
藻类正常时不会有太大的恶臭废气产生,只有死亡后才会产生腥臭的气味。藻水分离港恶臭废气成分复杂,含有恶臭VOCs成分,绝大部分难溶于水,部分属有毒、致癌物质。目前有活性炭吸附、生物降解、化学吸收和燃烧等方法治理恶臭气体,虽然这些技术处理效果比较高,但是运行条件比较复杂、运行维护费用较高、容易产生二次污染。 Normally, algae will not produce too much foul-smelling exhaust gas, and only after death will it produce a foul-smelling smell. The malodorous waste gas in the algal water separation port has complex components, including malodorous VOCs, most of which are insoluble in water, and some are toxic and carcinogenic. At present, there are activated carbon adsorption, biodegradation, chemical absorption and combustion methods to treat malodorous gases. Although these technologies have relatively high treatment effects, the operating conditions are relatively complicated, the operation and maintenance costs are high, and secondary pollution is likely to occur.
实用新型内容 Utility model content
为解决上述技术问题,本实用新型提供一种用于藻水分离站恶臭废气治理装置。 In order to solve the above technical problems, the utility model provides a malodorous waste gas treatment device for algae water separation station.
为了实现上述技术目的,本实用新型采取如下技术方案: In order to achieve the above technical purpose, the utility model takes the following technical solutions:
一种专门用于藻水分离站恶臭废气治理的装置,包括有依次设置的恶臭生产源机构、用于收集恶臭生产源机构产生恶臭气体的集气装置、用于处理恶臭气体的低温等离子体协同催化吸附成套装置、以及能够提供动力的引风机和用于排放标准气体的排放塔。 A device specially used for the treatment of malodorous waste gas in the algae-water separation station, including the malodorous production source mechanism arranged in sequence, the gas collecting device used to collect the malodorous gas generated by the malodorous production source mechanism, and the low-temperature plasma synergy used to treat the malodorous gas. Catalytic adsorption complete set, as well as the induced draft fan that can provide power and the discharge tower used to discharge standard gas.
进一步地,所述恶臭产生源机构为沉淀池、气浮池、藻泥藻浆池、藻泥脱水区域的回用水池、藻泥池、以及调峰池;所述集气装置是把恶臭废气通过集气罩制成密闭空间,且集气罩的顶端与所述低温等离子体协同催化吸附成套装置的进气端通过管道连接,所述低温等离子体协同催化吸附成套装置的出气端与所述引风机的进气端通过管道连接,所述引风机的出气端与所述排放塔的进气端也通过管道连接。 Further, the source mechanism of the stench is a sedimentation tank, an air flotation tank, an algae mud algae slurry pool, a reuse pool in the algae mud dehydration area, an algae mud pool, and a peak regulation pool; the gas collection device passes the malodorous waste gas through The gas collection hood is made into a closed space, and the top of the gas collection hood is connected to the inlet end of the low-temperature plasma cooperative catalytic adsorption complete set through a pipeline, and the gas outlet of the low-temperature plasma cooperative catalytic adsorption complete set is connected to the inlet The inlet end of the fan is connected through a pipeline, and the outlet end of the induced draft fan is also connected with the inlet end of the discharge tower through a pipeline.
进一步地,所述的集气罩采用玻璃钢、玻璃、有机玻璃材质,所 述的管道采用玻璃钢、碳钢或者PP材质。 Further, the gas collecting hood is made of FRP, glass or plexiglass, and the pipeline is made of FRP, carbon steel or PP.
进一步地,所述低温等离子体协同催化吸附成套装置包括依次设置的进气口、预处理区、低温等离子体放电区、协同催化吸附反应区和出气口。 Further, the low-temperature plasma coordinated catalytic adsorption complete set includes an air inlet, a pretreatment area, a low-temperature plasma discharge area, a coordinated catalytic adsorption reaction area and a gas outlet arranged in sequence.
进一步地,所述低温等离子体放电区是采用栅状放电结构,所述低温等离子体放电区通过高频高压电源控制放电,所述低温等离子体协同催化吸附成套装置还包括电源系统和控制系统,所述控制系统控制电源系统,所述电源系统的电源数量与栅状放电结构的放电模块数量相同。 Further, the low-temperature plasma discharge area adopts a grid-shaped discharge structure, and the low-temperature plasma discharge area is controlled by a high-frequency high-voltage power supply. The low-temperature plasma coordinated catalytic adsorption complete set also includes a power system and a control system, The control system controls the power supply system, and the number of power supplies in the power supply system is the same as the number of discharge modules in the grid discharge structure.
进一步地,所述协同催化吸附反应区是采用贵金属催化剂,吸附剂附着固定在吸附剂载体上,所述催化剂采用蜂窝状模块化结构,所述吸附剂包括活性炭、活性氧化铝、分子筛或硅胶。 Further, the synergistic catalytic adsorption reaction zone uses a noble metal catalyst, the adsorbent is attached and fixed on the adsorbent carrier, the catalyst adopts a honeycomb modular structure, and the adsorbent includes activated carbon, activated alumina, molecular sieve or silica gel.
本实用新型的技术特点和效果为:通过上述收集方法,收集废气通过管道汇总后引入低温等离子体协同催化吸附成套装置中,在管道上面安装热电偶用于气体温度测量反馈,安装压力传感器反馈管道内部压力变化,安装流量计反应废气处理量,以及安装浓度传感器用于记录设备运行过程中废气浓度变化,以及通过浓度变化实时调整放电输出功率。废气通过管道进入低温等离子体协同催化吸附成套装置后,首先经过预处理系统,主要采用PP丝网或者纤维棉等过滤材料组成,主要是起到除尘、除湿作用。经过预处理系统处理后的废气进入低温等离子体放电区,低温等离子体放电采用双介质阻挡放电模式,栅状放电结构,在低温等离子体放电区内部形成稳定、均匀、高 效的低温等离子体,等离子体中高能粒子直接对有机分子和产生恶臭的气体分子进行降解反应,对分子键进行破坏重组,形成无害的小分子。经过低温等离子体降解后的气体进入催化吸附反应区,在这里吸附剂有选择的吸附未完全降解有机分子,以及低温等离子体中未完全反应的高能分子,在催化剂的作用下,进一步发生化学反应,达到降解污染物的目的。经过低温等离子体协同催化吸附降解后能够达标排放气体,通过引风机和排放塔排放。整套设备采用PLC控制,可以检测被处理气体在管道内浓度、压力和流量,实现全自动运行,一键启停操作,操作方便。因此运行条件比较简单、运行维护费用较低、不容易产生二次污染。 The technical features and effects of the utility model are as follows: through the above collection method, the collected exhaust gas is collected through the pipeline and then introduced into the low-temperature plasma cooperative catalytic adsorption complete set of devices, a thermocouple is installed on the pipeline for gas temperature measurement and feedback, and a pressure sensor feedback pipeline is installed For internal pressure changes, a flow meter is installed to reflect the amount of exhaust gas treatment, and a concentration sensor is installed to record the change of exhaust gas concentration during the operation of the equipment, and to adjust the discharge output power in real time through the concentration change. After the exhaust gas enters the low-temperature plasma synergistic catalytic adsorption device through the pipeline, it first passes through the pretreatment system, which is mainly composed of PP screen or fiber cotton and other filter materials, mainly for dust removal and dehumidification. The exhaust gas treated by the pretreatment system enters the low-temperature plasma discharge area. The low-temperature plasma discharge adopts a double dielectric barrier discharge mode and a grid-like discharge structure to form a stable, uniform and efficient low-temperature plasma inside the low-temperature plasma discharge area. The high-energy particles in the body directly degrade organic molecules and odorous gas molecules, destroy and reorganize molecular bonds, and form harmless small molecules. The gas degraded by low-temperature plasma enters the catalytic adsorption reaction zone, where the adsorbent selectively adsorbs incompletely degraded organic molecules and incompletely reacted high-energy molecules in the low-temperature plasma, and further chemical reactions occur under the action of the catalyst , to achieve the purpose of degrading pollutants. After low-temperature plasma cooperative catalytic adsorption and degradation, the gas can be discharged up to the standard, and discharged through the induced draft fan and the discharge tower. The whole set of equipment is controlled by PLC, which can detect the concentration, pressure and flow of the gas to be processed in the pipeline, realize fully automatic operation, one-button start and stop operation, and easy operation. Therefore, the operating conditions are relatively simple, the operation and maintenance costs are low, and secondary pollution is not easy to occur.
附图说明 Description of drawings
图1是本实用新型的结构示意图。 Fig. 1 is a structural representation of the utility model.
图中:1、恶臭生产源机构;2、集气罩;3、管道;4、预处理区;5、低温等离子体放电区;6、协同催化吸附反应区;7、引风机;8、排放塔;9、集气装置;10、低温等离子体协同催化吸附成套装置;11、进气口;12、出气口。 In the figure: 1. Odor production source mechanism; 2. Gas collection hood; 3. Pipeline; 4. Pretreatment area; 5. Low temperature plasma discharge area; 6. Cooperative catalytic adsorption reaction area; 7. Induced fan; 8. Emission Tower; 9. Gas collecting device; 10. Low temperature plasma synergistic catalytic adsorption complete set; 11. Air inlet; 12. Gas outlet.
具体实施方式 detailed description
为了使本实用新型的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本实用新型进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本实用新型,并不用于限定本 实用新型。 In order to make the purpose, technical solution and advantages of the utility model clearer, the utility model will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the utility model, and are not intended to limit the utility model.
请参照图1,本实用新型提供一种专门用于前述藻水分离站恶臭废气治理的装置,包括有依次设置的恶臭生产源机构1、用于收集恶臭生产源机构产生恶臭气体的集气装置9、用于处理恶臭气体的低温等离子体协同催化吸附成套装置10、以及能够提供动力的引风机7和用于排放标准气体的排放塔8。 Please refer to Fig. 1, the utility model provides a device specially used for the treatment of the malodorous waste gas of the aforementioned algae-water separation station, including the malodorous production source mechanism 1 arranged in sequence, and the gas collecting device for collecting the malodorous gas generated by the malodorous production source mechanism 9. A low-temperature plasma synergistic catalytic adsorption package 10 for treating malodorous gases, an induced draft fan 7 capable of providing power, and a discharge tower 8 for discharging standard gases.
请参照图1,优选地,恶臭产生源机构1为沉淀池、气浮池、藻泥藻浆池、藻泥脱水区域的回用水池、藻泥池、以及调峰池;集气装置9是把恶臭废气通过集气罩2制成密闭空间,所述的恶臭废气是通过集气系统收集有组织恶臭废气;且集气罩2的顶端与低温等离子体协同催化吸附成套装置10的进气端通过管道3连接,低温等离子体协同催化吸附成套装置10的出气端与引风机7的进气端通过管道3连接,引风机7的出气端与排放塔8的进气端也通过管道3连接。 Please refer to Fig. 1, preferably, the malodorous source mechanism 1 is a sedimentation tank, an air flotation tank, an algae mud algae slurry pool, a reuse pool in an algae mud dehydration area, an algae mud pool, and a peak regulation pool; the gas collecting device 9 is a The malodorous exhaust gas is made into a closed space through the gas collection hood 2, and the malodorous exhaust gas is collected through the gas collection system; and the top of the gas collection hood 2 and the inlet end of the low-temperature plasma cooperative catalytic adsorption complete set Pipeline 3 is connected, and the outlet end of low-temperature plasma cooperative catalytic adsorption complete set 10 is connected with the inlet end of induced draft fan 7 through pipeline 3 , and the outlet end of induced draft fan 7 is also connected with the inlet end of discharge tower 8 through pipeline 3 .
请参照图1,优选地,的集气罩2采用玻璃钢、玻璃、有机玻璃材质,的管道3采用玻璃钢、碳钢或者PP材质。 Please refer to FIG. 1 , preferably, the gas collecting hood 2 is made of FRP, glass, or plexiglass, and the pipeline 3 is made of FRP, carbon steel or PP.
请参照图1,优选地,低温等离子体协同催化吸附成套装置10包括依次设置的进气口11、预处理区4、低温等离子体放电区5、协同催化吸附反应区6和出气口12。 Please refer to FIG. 1 , preferably, the low-temperature plasma coordinated catalytic adsorption complete device 10 includes an air inlet 11 , a pretreatment area 4 , a low-temperature plasma discharge area 5 , a coordinated catalytic adsorption reaction area 6 and a gas outlet 12 .
请参照图1,优选地,低温等离子体放电区5是采用栅状放电结构,低温等离子体放电区5通过高频高压电源控制放电,具有独立的电源控制系统,低温等离子体协同催化吸附成套装置10还包括电源系统和控制系统,控制系统控制电源系统,电源系统的电源数量与栅 状放电结构的放电模块数量相同。 Please refer to Figure 1. Preferably, the low-temperature plasma discharge area 5 adopts a grid-shaped discharge structure. The low-temperature plasma discharge area 5 controls the discharge through a high-frequency and high-voltage power supply. It has an independent power control system and a complete set of low-temperature plasma synergistic catalytic adsorption devices. 10 also includes a power system and a control system, the control system controls the power system, and the number of power sources in the power system is the same as the number of discharge modules in the grid discharge structure.
请参照图1,优选地,协同催化吸附反应区5是采用贵金属催化剂,吸附剂附着固定在吸附剂载体上,催化剂采用蜂窝状模块化结构,吸附剂包括活性炭、活性氧化铝、分子筛或硅胶,制成模块固定安装在设备内部,电控系统包括整个系统的控制部分以及恶臭废气在管道内部流量、压力、温度、浓度监控。 Please refer to Fig. 1, preferably, synergistic catalytic adsorption reaction zone 5 adopts noble metal catalyst, and adsorbent is attached and fixed on the adsorbent carrier, and catalyst adopts honeycomb modular structure, and adsorbent includes activated carbon, activated alumina, molecular sieve or silica gel, The finished module is fixedly installed inside the equipment, and the electronic control system includes the control part of the whole system and the flow, pressure, temperature and concentration monitoring of the malodorous exhaust gas inside the pipeline.
恶臭产生源1主要有沉淀池、气浮池、藻泥藻浆池、藻泥脱水区域的回用水池、藻泥池、以及调峰池,其中部分已经做成密闭空间形成集气罩2,只需要在密闭空间顶部留有引出孔,直接管道3上,还有未做成集气罩的,需要做集气罩2,用于恶臭气体的收集。 Odor generation sources 1 mainly include sedimentation tanks, air flotation tanks, algae mud and algae slurry pools, reuse pools in the algae mud dehydration area, algae mud pools, and peak-shaving pools, some of which have been made into closed spaces to form gas collection hoods It is necessary to leave an outlet hole on the top of the confined space, directly on the pipeline 3, and if it is not made into a gas collection hood, it needs to be a gas collection hood 2 for the collection of malodorous gases.
收集废气通过管道3汇总后引入低温等离子体协同催化吸附成套装置中,在管道3上面安装热电偶用于气体温度测量反馈,安装压力传感器反馈管道3内部压力变化,安装流量计反应废气处理量,以及安装浓度传感器用于记录设备运行过程中废气浓度变化,以及通过浓度变化实时调整放电输出功率。 The collected exhaust gas is collected through the pipeline 3 and then introduced into the complete set of low-temperature plasma synergistic catalytic adsorption device. A thermocouple is installed on the pipeline 3 for gas temperature measurement and feedback, a pressure sensor is installed to feedback the internal pressure change of the pipeline 3, and a flow meter is installed to reflect the waste gas treatment capacity. And install a concentration sensor to record the change of exhaust gas concentration during the operation of the equipment, and adjust the discharge output power in real time through the concentration change.
废气通过管道3进入低温等离子体协同催化吸附成套装置后,首先经过预处理系统4,主要采用PP丝网或者纤维棉等过滤材料组成,主要是起到除尘、除湿作用。 After the exhaust gas enters the low-temperature plasma cooperative catalytic adsorption complete set through the pipeline 3, it first passes through the pretreatment system 4, which is mainly composed of filter materials such as PP screen or fiber cotton, mainly for dust removal and dehumidification.
经过预处理系统4处理后的废气进入低温等离子体放电区5,低温等离子体放电采用双介质阻挡放电模式,栅状放电结构,在低温等离子体放电区5内部形成稳定、均匀、高效的低温等离子体,等离子体中高能粒子直接对有机分子和产生恶臭的气体分子进行降解反应, 对分子键进行破坏重组,形成无害的小分子。 The exhaust gas treated by the pretreatment system 4 enters the low-temperature plasma discharge area 5. The low-temperature plasma discharge adopts a double dielectric barrier discharge mode and a grid-shaped discharge structure to form a stable, uniform, and efficient low-temperature plasma inside the low-temperature plasma discharge area 5. The high-energy particles in the plasma directly degrade the organic molecules and the gas molecules that generate the odor, destroy and reorganize the molecular bonds, and form harmless small molecules.
经过低温等离子体降解后的气体进入催化吸附反应区6,在这里吸附剂有选择的吸附未完全降解有机分子,以及低温等离子体中未完全反应的高能分子,在催化剂的作用下,进一步发生化学反应,达到降解污染物的目的。 The gas degraded by the low-temperature plasma enters the catalytic adsorption reaction zone 6, where the adsorbent selectively adsorbs incompletely degraded organic molecules and high-energy molecules that have not completely reacted in the low-temperature plasma. Under the action of the catalyst, further chemical reactions occur. reaction to achieve the purpose of degrading pollutants.
经过低温等离子体协同催化吸附降解后能够达标排放气体,通过引风机7和排放塔8排放。 After low-temperature plasma cooperative catalytic adsorption and degradation, the gas can be discharged up to the standard, and the gas is discharged through the induced draft fan 7 and the discharge tower 8 .
整套设备采用PLC控制,可以检测被处理气体在管道3内浓度、压力和流量,实现全自动运行,一键启停操作,操作方便; The whole set of equipment is controlled by PLC, which can detect the concentration, pressure and flow of the gas to be processed in the pipeline 3, realize fully automatic operation, one-button start and stop operation, and easy operation;
因此运行条件比较简单、运行维护费用较低、不容易产生二次污染。 Therefore, the operating conditions are relatively simple, the operation and maintenance costs are low, and secondary pollution is not easy to occur.
以上所述仅为本实用新型的较佳实施例而已,并不用以限制本实用新型,凡在本实用新型的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本实用新型的保护范围之内。 The above descriptions are only preferred embodiments of the present utility model, and are not intended to limit the present utility model. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present utility model shall be included in this utility model. within the scope of protection of utility models.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107042039A (en) * | 2017-06-12 | 2017-08-15 | 南京大学盐城环保技术与工程研究院 | The device and processing method of a kind of dielectric barrier discharge low-temperature plasma concerted catalysis processing organic exhaust gas |
| CN108911318A (en) * | 2018-09-03 | 2018-11-30 | 大渊环境技术(厦门)有限公司 | A kind of purification device and purification method of black and odorous water |
| CN108911316A (en) * | 2018-09-03 | 2018-11-30 | 大渊环境技术(厦门)有限公司 | A kind of plasma nitrogen rejection facility and its application method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107042039A (en) * | 2017-06-12 | 2017-08-15 | 南京大学盐城环保技术与工程研究院 | The device and processing method of a kind of dielectric barrier discharge low-temperature plasma concerted catalysis processing organic exhaust gas |
| CN108911318A (en) * | 2018-09-03 | 2018-11-30 | 大渊环境技术(厦门)有限公司 | A kind of purification device and purification method of black and odorous water |
| CN108911316A (en) * | 2018-09-03 | 2018-11-30 | 大渊环境技术(厦门)有限公司 | A kind of plasma nitrogen rejection facility and its application method |
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