CN205412632U - 一种sncr+scr联合脱硝超净排放工艺装置 - Google Patents
一种sncr+scr联合脱硝超净排放工艺装置 Download PDFInfo
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- CN205412632U CN205412632U CN201620191896.0U CN201620191896U CN205412632U CN 205412632 U CN205412632 U CN 205412632U CN 201620191896 U CN201620191896 U CN 201620191896U CN 205412632 U CN205412632 U CN 205412632U
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- 238000000034 method Methods 0.000 title abstract description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 60
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound data:image/svg+xml;base64,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[NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 23
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 23
- 239000007921 spray Substances 0.000 claims abstract description 17
- 239000003054 catalyst Substances 0.000 claims abstract description 15
- 238000005516 engineering process Methods 0.000 claims description 12
- 239000006200 vaporizer Substances 0.000 claims description 11
- 238000010790 dilution Methods 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 5
- 238000002347 injection Methods 0.000 abstract description 3
- 239000007924 injection Substances 0.000 abstract description 3
- 238000007865 diluting Methods 0.000 abstract description 2
- 239000003638 reducing agent Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000004202 carbamide Substances 0.000 description 3
- 229960000539 carbamide Drugs 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 238000010531 catalytic reduction reaction Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound 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NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitrogen oxide Substances 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O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- 231100000614 Poison Toxicity 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound 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Abstract
本实用新型提供一种SNCR+SCR联合脱硝超净排放工艺装置，氨水罐通过氨水泵一路经氨水管道与设在氨水蒸发器上的氨水喷射器相连，所述的氨水蒸发器的一端与锅炉一次热风管路的一端相接，锅炉一次热风管路的另一端与锅炉炉膛相接，所述的氨水蒸发器的出口端通过氨气管道分别与催化剂反应器内的喷氨格栅和设置在烟道内的喷枪相连接；另一路经氨水管道与氨水稀释模块相接，稀释后的氨水通过管路与设置在锅炉炉膛内的喷枪相接，锅炉炉膛通过烟道与催化剂反应器相接，催化剂反应器与烟囱相接。具有简洁、实用、高效等优点。
Description
技术领域
[0001 ]本实用新型属于工业烟气脱硝技术领域，涉及一种SNCR+SCR联合脱硝超净排放工
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背景技术
[0002]在工业烟气脱硝项目中，工艺装置的确定和还原剂的选择至关重要。目前常采用脱硝工艺包括催化还原SCR法、非催化还原SNCR法等工艺装置;还原剂通常采用液氨、尿素和氨水。
[0003] SCR法和SNCR法各有优缺点，其中SCR技术是在催化剂作用下，还原剂和烟气中NOx发生还原反应脱除氮氧化物，SCR技术具有脱硝反应效率高、系统运行稳定的优点，缺点是一次性投资高、占地面积大;SNCR技术是将还原剂直接喷入炉膛高温区域直接还原反应，具有投资低、操作管理简单等优点，主要缺点是脱硝效率低，脱硝效率不稳定等。
[0004]还原剂方面，采用液氨做还原剂，具有反应效率高，氨耗低等优点。但由于液氨存在易燃有毒危险性，氨区消防要求高，占地面积大，液氨使用不便;采用尿素做还原剂，优点是运输储存方便，缺点是氨耗较高。
[0005] 对于SCR工艺装置尤其是SNCR法工艺装置，由于其本身脱硝效率限制，针对脱硝效率要求较高的系统有时达不到标准要求，而采用液氨或尿素做还原剂，其缺点也同样限制了推广应用。
[0006]本实用新型是一种SNCR+SCR联合脱硝超净排放工艺组合装置，采用氨水做还原剂，其中SNCR用氨水直喷，SCR用氨水蒸发成氨气喷入催化剂反应器。
[0007]本实用新型充分利用了 SCR工艺和SNCR工艺的优缺点进行有效的工艺装置组合，同时采用氨水做还原剂，将氨水直接喷入炉膛进行SNCR反应，利用锅炉一次风热烟气将氨水蒸发成氨气进行SCR反应，提高了脱硝效率，从而达到超净排放的目的。由于国家对污染排放标准的要求越来越高，同时氨水来源广泛，很多化工企业有剩余氨水可以利用，成本低，因此本发明克服了传统SCR工艺装置或SNCR工艺装置的缺点，具有广泛的推广应用前景。
发明内容
[0008] 本实用新型充分利用了 SCR和SNCR工艺装置的特点，利用锅炉等炉膛高温和一次热风热能和温度，公用氨水做还原剂，发明了一种SNCR+SCR联合脱硝超净排放工艺装置，从而达到锅炉窑炉烟气脱硝超净排放的目的。
[0009]本实用新型是通过以下技术方案实现:一种SNCR+SCR联合脱硝超净排放工艺装置，氨水罐通过氨水栗一路经氨水管道与设在氨水蒸发器上的氨水喷射器相连，所述的氨水蒸发器的一端与锅炉一次热风管路的一端相接，锅炉一次热风管路的另一端与锅炉炉膛相接，所述的氨水蒸发器的出口端通过氨气管道分别与催化剂反应器内的喷氨格栅和设置在烟道内的喷枪相连接;另一路经氨水管道与氨水稀释模块相接，稀释后的氨水通过管路与设置在锅炉炉膛内的喷枪相接，锅炉炉膛通过烟道与催化剂反应器相接，催化剂反应器与烟囱相接。
[0010] 采用氨水做SCR+SNCR组合装置的公用还原剂，氨水经稀释直喷进行SNCR脱硝和经氨水蒸发器蒸发或利用烟道烟气直接蒸发成氨气进行SCR脱硝，本实用新型和现有SCR+SNCR组合装置相比，具有简洁、实用、高效等优点。
附图说明
[0011]图1为本实用新型实施例示意图。
[0012]图中:1、氨水罐，2、氨水栗，3、氨水蒸发器，4、氨水喷射器，5、锅炉一次热风管路，
6、氨水稀释模块，7、锅炉炉膛，8、喷枪，9、催化剂反应器，10、喷氨格栅，11、烟道。
具体实施方式
[0013]下面结合附图说明具体实施方式:
[0014] 一种SNCR+SCR联合脱硝超净排放工艺装置，包括氨水罐I，氨水栗2，氨水蒸发器3，氨水喷射器4，锅炉一次热风管路5，氨水稀释模块6，锅炉炉膛7，喷枪8，催化剂反应器9，喷氨格栅10，烟气烟道11;如图1所示。
[0015] 20-25%浓度氨水储存在氨水罐I中，由氨水栗2分别栗至氨水蒸发器3和氨水稀释模块6中。其中一路氨水进入氨水稀释模块6的氨水，和稀释水混合稀释成10%左右浓度的稀释氨水，经喷枪8直接喷入锅炉炉膛7，在850-1150 °C的温度场区域，进行SNCR反应；另一路氨水由氨水喷射器4上下交错喷入氨水蒸发器3和上部通过锅炉一次热风管路5进入的热风在氨水蒸发器3内混合蒸发，氨气由底部排出，通过喷氨格栅10，进入催化剂反应器9中，进行SCR催化还原反应脱硝。另一路氨气则直接通过喷枪8喷入烟道11内，进入催化剂反应器9中，进行SCR催化还原反应脱硝。
Claims (1)
1.一种SNCR+SCR联合脱硝超净排放工艺装置，其特征在于:氨水罐(I)通过氨水栗(2)一路经氨水管道与设在氨水蒸发器(3)上的氨水喷射器(4)相连，所述的氨水蒸发器(3)的一端与锅炉一次热风管路(5)的一端相接，锅炉一次热风管路(5)的另一端与锅炉炉膛(7)相接，所述的氨水蒸发器(3)的出口端通过氨气管道分别与催化剂反应器(9)内的喷氨格栅(10)和设置在烟道(11)内的喷枪(8)相连接;另一路经氨水管道与氨水稀释模块(6)相接，稀释后的氨水通过管路与设置在锅炉炉膛(7)内的喷枪(8)相接，锅炉炉膛(7)通过烟道(11)与催化剂反应器(9)相接，催化剂反应器(9)与烟囱相接。
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| CN107185376A (zh) * | 2017-06-14 | 2017-09-22 | 山西大学 | 一种烟气回用强化sncr联合scr的脱硝系统 |
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